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At least 145 records · Page 8Linked to original sources

Real-time piscicide tracking using Rhodamine WT dye for support of application, transport, and deactivation strategies in riverine environments

Piscicide applications in riverine environments are complicated by the advection and dispersion of the piscicide by the flowing water. Proper deactivation of the fish toxin is required outside of the treatment reach to ensure that there is minimal collateral damage to fisheries downstream or in connecting and adjacent water bodies. In urban settings and highly managed waterways, further complications arise from the influence of industrial intakes and outfalls, stormwater outfalls, lock and dam operations, and general unsteady flow conditions. These complications affect the local hydrodynamics and ultimately the transport and fate of the piscicide. This report presents two techniques using Rhodamine WT dye for real-time tracking of a piscicide plume—or any passive contaminant—in rivers and waterways in natural and urban settings. Passive contaminants are those that are present in such low concentration that there is no effect (such as buoyancy) on the fluid dynamics of the receiving water body. These methods, when combined with data logging and archiving, allow for visualization and documentation of the application and deactivation process. Real-time tracking and documentation of rotenone applications in rivers and urban waterways was accomplished by encasing the rotenone plume in a plume of Rhodamine WT dye and using vessel-mounted submersible fluorometers together with acoustic Doppler current profilers (ADCP) and global positioning system (GPS) receivers to track the dye and map the water currents responsible for advection and dispersion. In this study, two methods were used to track rotenone plumes: (1) simultaneous injection of dye with rotenone and (2) delineation of the upstream and downstream boundaries of the treatment zone with dye. All data were logged and displayed on a shipboard laptop computer, so that survey personnel provided real-time feedback about the extent of the rotenone plume to rotenone application and deactivation personnel. Further, these strategies facilitate adjustment of rotenone application and deactivation strategies in real time if necessary based on the observed advection and dispersion of the rotenone plume. Two large-scale and complex applications of rotenone in the Chicago Area Waterway System (CAWS) in 2009 and 2010 to combat invasive Asian carp are documented in this report. The application in Chicago Sanitary and Ship Canal (CSSC) in December 2009 involved more than 1,800 gallons of rotenone injected at multiple stations through a 6.2-mile reach of the canal near Lockport, Illinois. The rotenone plume was encased in Rhodamine WT dye so that two survey boats provided real-time feedback to shore personnel regarding the plume extent as it advected downstream. Real-time tracking of the rotenone was essential in this large-scale application because of the multistage injection strategy and the numerous deactivation points required to minimize collateral damage to fisheries in surrounding and receiving water bodies. All timing of application and deactivation operations relied on dye tracking. A second application of rotenone in May 2010 to the Little Calumet River near O’Brien Lock and Dam (Illinois) provided another opportunity for dye-tracking support operations; however, application and deactivation strategies were designed considering zero-flow conditions within the reach of interest. Therefore, dye was injected at the upstream and downstream boundaries of the rotenone application reach and was used to track movement of water in and out of a treatment reach, allowing proper deactivation to occur and avoiding unnecessary damage to fisheries downstream. The data collected during the real-time tracking operations for both applications allowed full documentation of the rotenone treatment for archival purposes and provided information for future applications. The methods presented in this report for real-time tracking and documentation of piscicide applications in riverine environments worked exceptionally well and allowed the multiagency Asian Carp Rapid Response Workgroup to carry out large-scale rotenone applications in urban waterways in an environmentally responsible manner with minimal collateral damage to fisheries outside the treatment reach. Traveltime information extracted from the boat-mounted and fixed-position fluorometers agrees well with empirical predictions from a preliminary dye study (mock rotenone injection) on this system completed in November 2009 on the CSSC and with previously published methods for estimating traveltimes of the peak, leading edge, and trailing edge of the plume. Although the rotenone application strategy called for zero-flow conditions on the Little Calumet River in 2010, downstream advection of treated water did occur, and dye tracing combined with velocity mapping allowed this advection to be documented and exposed the unique hydrodynamics and mixing within this reach. The large volumes of data collected during the operations allow documentation and visualization of the rotenone applications, thus providing feedback to planners and archival of the treatments for future reference. The methods developed in this report are directly transferrable to piscicide applications in water bodies in other locations, including rivers, ponds, or lakes, and can be used for real-time tracking of any passive contaminant that may enter a water body.

Illinois↗

Hydraulic and water-quality indicators of aquifer zones contributing groundwater flow to wells in the Santa Fe Group aquifer system near southeast Albuquerque, New Mexico, 2013–16

An ethylene dibromide (EDB) plume extends approximately 5,880 feet northeast from the Bulk Fuels Facility on Kirtland Air Force Base. The leading edge of the EDB plume is about 3,700 feet upgradient from several water-supply wells. The water-supply wells are screened in the upper Santa Fe Group aquifer system. Within the upper Santa Fe Group, two primary clay-rich layers, the A1 and A2 units, separate water-producing zones. The U.S. Geological Survey, in cooperation with the Albuquerque Bernalillo County Water Utility Authority and the U.S. Air Force, installed four sentinel well nests and two aquifer-test pumping wells between the EDB plume and the water-supply wells. The purpose of the sentinel wells is to provide early warning of EDB plume migration towards water-supply wells. The sentinel well nests include at least three wells that are screened above, in between, and below the A1 and A2 units. The two aquifer-test pumping wells, installed for performing hydraulic tests on the aquifer system, are screened across both clay layers, as are the nearby water-supply wells. Well-bore flow logging indicated that greater than 60 percent of groundwater flow to the wells was through the deepest interval below the lowermost clay layer (A1 unit). The interval between the A1 and A2 units is the second most productive interval. Water-quality data also indicated that water drawn from the aquifer-test pumping wells and previously studied nearby water-supply wells is most similar in composition to water from the sentinel wells screened in the middle and deep intervals.

New Mexico↗

Comparison of passive and pumped sampling methods for analysis of groundwater quality, Kirtland Air Force Base, Albuquerque, New Mexico, 2019

A plume of ethylene dibromide (EDB) dissolved in groundwater extends northeast from the Bulk Fuels Facility on Kirtland Air Force Base, New Mexico. The leading edge of the EDB plume is upgradient from several water-supply wells. In 2013, the U.S. Geological Survey (USGS), in cooperation with the Albuquerque Bernalillo County Water Utility Authority and the U.S. Air Force, installed four sentinel well nests and two aquifer-test pumping wells between the EDB plume and the water-supply wells to serve as an early warning if the plume travels toward the water-supply wells. Since 2015, the USGS has used submersible pumps to sample the sentinel wells quarterly. In February 2017, the USGS began using dual-membrane passive diffusion bag samplers for quarterly sampling in the wells. To ensure that the passive samplers are obtaining representative samples of the groundwater contaminants, the USGS, in cooperation with the U.S. Air Force, initiated a study in 2019 to compare results from pump sampling and passive samplers and to use vertical profiling to determine the optimal depth for passive sampler placement in the screened interval to better inform long-term monitoring of the site. Vertical profiling included deploying passive samplers throughout the submerged screened interval of four shallow sentinel wells. After retrieval of the passive samplers, pump samples were collected. The results of analyses of both types of samples were compared. Volatile organic compound results for this study were all below the raised reporting levels, which is a level five times the maximum concentration detected in a blank and determined by an in-depth quality assessment; therefore, this study focused on inorganic constituent results, including major ions, trace elements, and stable isotopes of water, to calculate the relative percent difference (RPD) between the pump and passive sampling method results as a way to determine where passive samplers would be best placed in each of the wells. Several analytes had an RPD of more than plus or minus 50 percent, and several analytes were not within the estimated variability for each sampling method. Additionally, the variability within each sampling method was quantified and compared. Factors that likely contributed to the lack of comparison between each sampling method included temporal variability, flow regime, volume of sample integrated through different aquifer intervals, and reduction/oxidation processes. RPD and method variability were used to determine the intervals within each well with the greatest agreement between sampling methods. Optimal sampling depths for each well were then correlated to the intervals where quarterly sampling has been occurring.

New Mexico↗

Natural attenuation of chlorinated volatile organic compounds in ground water at Area 6, Naval Air Station Whidbey Island, Washington

Natural attenuation is a viable alternative to pump and treat for meeting remediation objectives in the vicinity of the southern contaminant plume. The combination of historically low contaminant concentrations in ground water, a landfill cap that limits source area contributions, favorable conditions for degradation of VC, and a relatively long downgradient distance to potential receptors are all favorable for natural attenuation as a remediation alternative. Natural attenuation could effectively meet all but one remediation goal that extraction wells PW- 2, PW-4, PW-6, PW-7, PW-8 and PW-9 are currently being employed to meet. The goal of preventing migration of all VC across the site boundary could not be met by natural attenuation. Some VC would migrate south of the Navy boundary, but the potential for subsequent VC mineralization downgradient of the base and the existing institutional controls would result in minimal additional risk from using natural attenuation. In the western contaminant plume natural attenuation is not currently a viable alternative to pump and treat for meeting remediation objectives. There is a possibility that rates for reductive dechlorination of TCE and TCA could increase substantially if the plume was allowed to migrate beneath the Oak Harbor landfill, but there are not enough data to be certain of such an increase. TCA and TCE concentrations at the leading edge of the western plume need to be reduced to at least 25 and 40 µg/L, respectively, to be protective of potential downgradient receptors. Source area TCA and TCE concentrations have decreased substantially over the past ten years, and the extraction wells PW-3 and PW-5 in particular are removing a significant mass of contaminants from ground water, so natural attenuation may be a viable alternative for the western plume in the future. There would be some possible side benefits of using natural attenuation as an alternative to pump and treat in the southern contaminant plume. The first would be that the resulting decrease in the amount of treated water that would need to be recharged in the swale north of the landfill would result in less off-base migration of contamination across the western site boundary. The second benefit would be a substantial reduction in the amount of dissolved iron and manganese being extracted from the shallow aquifer and run through the treatment system. Removing that source of operation and maintenance problems would result in more effective containment and removal of contamination in the western contaminant plume. The most critical data gap identified in this evaluation is the paucity of contaminant chemistry information downgradient of the Navy boundary in the vicinity of the southern contaminant plume. Without such data, the behavior of the plume and the protectiveness of natural attenuation to downgradient receptors cannot be verified, and field attenuation rates for VC cannot be determined directly. The existing long-term monitoring plan would need to be reviewed and revised if natural attenuation is selected as a remedy for the contamination in the southern plume. In particular, additional performance monitoring wells may be required downgradient of the property.

Washington↗

Traveltime characteristics of Gore Creek and Black Gore Creek, upper Colorado River basin, Colorado

In the Rocky Mountains of Colorado, major highways are often constructed in stream valleys. In the event of a vehicular accident involving hazardous materials, the close proximity of highways to the streams increases the risk of contamination entering the streams. Recent population growth has contributed to increased traffic volume along Colorado highways and has resulted in increased movement of hazardous materials, particularly along Interstate 70. Gore Creek and its major tributary, Black Gore Creek, are vulnerable to such contamination from vehicular accidents along Interstate 70. Gore Creek, major tributary of the Eagle River, drains approximately 102 square miles, some of which has recently undergone significant urban development. The headwaters of Gore Creek originate in the Gore Range in the eastern part of the Gore Creek watershed. Gore Creek flows west to the Eagle River. Beginning at the watershed boundary on Vail Pass, southeast of Vail Ski Resort, Interstate 70 parallels Black Gore Creek and then closely follows Gore Creek the entire length of the watershed. Interstate 70 crosses Gore Creek and tributaries 20 times in the watershed. In the event of a vehicular accident involving a contaminant spill into Gore Creek or Black Gore Creek, a stepwise procedure has been developed for water-resource managers to estimate traveltimes of the leading edge and peak concentration of a conservative contaminant. An example calculating estimated traveltimes for a hypothetical contaminant release in Black Gore Creek is provided. Traveltime measurements were made during May and September along Black Gore Creek and Gore Creek from just downstream from the Black Lakes to the confluence with the Eagle River to account for seasonal variability in stream discharge. Fluorometric dye injection of rhodamine WT and downstream dye detection by fluorometry were used to measure traveltime characteristics of Gore Creek and Black Gore Creek. During the May traveltime measurements, discharges ranged from 82 cubic feet per second (ft 3 /s) at Black Gore Creek near Minturn (U.S. Geological Survey station number 09066000) to 724 ft 3 /s at Gore Creek at mouth near Minturn (U.S. Geological Survey station number 09066510), whereas during the September traveltime measurements, discharges ranged from 3.6 ft 3 /s at Black Gore Creek near Minturn to 62 ft 3 /s at Gore Creek at mouth near Minturn. Cumulative traveltimes for the peak dye concentration during the May traveltime measurements ranged from 3.45 hours (site 1 to site 3) in Black Gore Creek to 2.50 hours (site 8 to site 12) in Gore Creek, whereas cumulative traveltimes for the peak dye concentration during the September traveltime measurements ranged from 15.33 hours (site 1 to site 3) in Black Gore Creek to 8.65 hours (site 8 to site 12) in Gore Creek. During the September dye injections, beaver dams on Black Gore Creek, between site 1 and the confluence with Gore Creek, substantially delayed movement of the rhodamine WT. Estimated traveltimes were developed using relations established from linear-regression methods of relating measured peak traveltime to discharge during those measurements, which were obtained at Black Gore Creek near Minturn and Gore Creek at mouth near Minturn. Resulting estimated peak traveltimes for Black Gore Creek (sites 1 to 5) ranged from 5.4 to 0.4 hour for 20 to 200 ft 3 /s and for Gore Creek (sites 5 to 12), 5.5 to 0.3 hour for 20 to 800 ft 3 /s. Longitudinal-dispersion coefficients that were calculated for selected stream reaches ranged from 17.2 square feet per second at 4 ft 3 /s between sites 2 and 3 to 650 square feet per second at 144 ft 3/ s between sites 7 and 8. Longitudinal-dispersion coefficients are necessary variables for future stream-contaminant modeling in the Gore Creek watershed.

Colorado↗

Time of travel and dispersion of solutes in a 36.4-mile reach of the North Platte River downstream from Casper, Wyoming

Time-of-travel and dispersion measurements made during a dye study November 7-8, 1978, are presented for a reach of the North Platte River from Casper, Wyo., to a bridge 2 miles downstream from below the Dave Johnston Power Plant. Rhodamine WT dye was injected into the river at Casper, and the resultant dye cloud was traced by sampling as it moved downstream. Samples were taken in three equal-flow sections of the river 's lateral transect at three sites, then analyzed in a fluorometer. The flow in the river was 940 cubic feet per second. The data consist of measured stream mileages and time, distance, and concentration graphs of the dye cloud. The peak concentration traveled through the reach in 24 hours, averaging 1.5 miles per hour; the leading edge took about 22 hours, averaging 1.7 miles per hour; and the trailing edge took 35 hours, averaging 1.0 mile per hour. Data from this study were compared with methods for estimating time of travel for a range of stream discharges.

Wyoming↗

Traveltime and dispersion in the Shenandoah River and its tributaries, Waynesboro, Virginia, to Harpers Ferry, West Virginia

Two traveltime and dispersion measurements using rhodamin dye were conducted on a 178-mile reach of the Shenandoah River between Waynesboro, Virginia, and Harpers Ferry, West Virginia. The flows during the two measurements were at approximately the 85% and 45% flow durations. The two sets of data were used to develop a generalized procedure for predicting traveltimes and downstream concentrations resulting from spillage of water soluble substances at any point along the river reach studied. The procedure can be used to calculate traveltime and concentration data for almost any spillage that occurs during relatively steady flow between a 40% to 95% flow duration. Based on an analogy between the general shape of a time concentration curve and a scalene triangle, the procedures can be used on long river reaches to approximate the conservative time concentration curve for instantaneous spills of contaminants. The triangular approximation technique can be combined with a superposition technique to predict the approximate, conservative time concentration curve for constant rate and variable rate injections of contaminants. The procedure was applied to a hypothetical situation in which 5,000 pounds of contaminants is spilled instantaneously at Island Ford, Virginia. The times required for the leading edge, the peak concentration, and the trailing edge of the contaminant cloud to reach the water intake at Front Royal, Virginia (85 miles downstream), are 234,280, and 340 hrs, respectively, for a flow at an 80% flow duration. The conservative peak concentration would be approximately 940 micrograms/L at Front Royal. The procedures developed cannot be depended upon when a significant hydraulic wave or other unsteady flow condition exists in the flow system or when the spilled material floats or is immiscible in water. (Author 's abstract)

Water-Resources Investigations Report↗

Traveltime and dispersion in the New River, Hinton to Gauley Bridge, West Virginia

Traveltime and dispersion studies were conducted on a 65-mile-long reach of the New River between Hinton and Gauley Bridge, West Virginia. Four sets of measurements were made from August 1985 to May 1986 at river discharges of about 2,220, 3 ,200, 9,200, and 18,000 cu ft/sec, which correspond to flow durations of 85, 70, 26, and 9%, respectively. The four sets of data were used to develop generalized procedures for estimating traveltime and peak concentrations that result from spillage of water-soluble substances at any point within the study reach. The procedure will provide the approximate traveltimes and concentrations of soluble substances during periods of relatively steady flow from 1,500 to 30,000 cu ft/sec. A sample problem and solution are presented for hypothetical situation in which 500 lbs of soluble contaminant are spilled at a highway bridge near Sandstone. The river flow was 3,000 cu ft/sec for this example. The estimated times required for the leading edge and peak concentration of the solute cloud to reach Stone Cliff (25.9 river mi) were determined to be 23 and 28.5 hours. The cloud would take about 17 hours to pass Stone Cliff and the peak concentration would be 100 micrograms/L.

West Virginia↗

Ground-water flow and the potential effects of remediation at Graces Quarters, Aberdeen Proving Ground, Maryland

Ground water in the east-central part of Graces Quarters, a former open-air chemical-agent test facility at Aberdeen Proving Ground, Maryland, is contaminated with chlorinated volatile organic compounds. The U.S. Geological Survey's finite- difference model was used to help understand ground-water flow and simulate the effects of alternative remedial actions to clean up the ground water. Scenarios to simulate unstressed conditions and three extraction well con- figurations were used to compare alternative remedial actions on the contaminant plume. The scenarios indicate that contaminants could migrate from their present location to wetland areas within 10 years under unstressed conditions. Pumping 7 gal/min (gallons per minute) from one well upgradient of the plume will not result in containment or removal of the highest contaminant concentrations. Pumping 7 gal/min from three wells along the central axis of the plume should result in containment and removal of dissolved contami- nants, as should pumping 7 gal/min from three wells at the leading edge of the plume while injecting 7 gal/min back into an upgradient well.

Water-Resources Investigations Report↗

Hydrographic and sedimentation survey of Kajakai Reservoir, Afghanistan

A hydrographic and sedimentation survey of Band-e Kajakai (Kajakai Reservoir) on the Darya-ye Hirmand (Helmand River) was carried out during the period September through December 1968. Underwater mapping techniques were used to determine the reservoir capacity as of 1968. Sediment range lines were established and monumented to facilitate future sedimentation surveys. Afghanistan engineers and technicians were trained to carry out future reservoir surveys. Samples were obtained of the reservoir bed and in the river upstream from the reservoir. Virtually no sediments coarser than about 0.063 millimeter were found on the reservoir bed surface. The median diameter of sands being transported into the reservoir ranged from 0.040 to 0.110 millimeter. The average annual rate of sedimentation was 7,800 acre-feet. Assuming an average density of 50 pounds per cubic foot (800 kilograms per cubic meter), the estimated average sediment inflow to the reservoir was about 8,500,000 tons (7,700,000 metric tons) per year. The decrease in capacity at spillway elevation for the period 1953 to 1968 due to sediment deposition was 7.8 percent, or 117,700 acre-feet. Redefinition of several contours above the fill area resulted in an increase in capacity at spillway elevation of 13,600 acre-feet; thus, the net change in capacity was 7.0 percent, or 104,800 acre-feet. Based on current data and an estimated rate of compaction of deposited sediment, the assumption of no appreciable change in hydrologic conditions in the drainage area, the leading edge of the principal delta will reach the irrigation outlet in 40-45 years. It is recommended that a resurvey of sediment range lines be made during the period 1973-75.

Water Supply Paper↗

Water quality of the Neuse River, North Carolina - Variability, pollution loads, and long-term trends

Interpretation of water-quality data collected by the U.S. Geological Survey for the Neuse River, North Carolina, has identified water-quality variations, charactrized the current condition of the river in reference to water-quality standards, estimated the degree of pollution caused by man, and evaluated long-term trends in concentrations of major dissolved constituents. Two sampling stations, Neuse River near Clayton (02087500) and Neuse River at Kinston (02089500) have more than 12 years of water-quality data collected during the period from 1955 to 1978. The Clayton station provides information on the upper fourth of the basin (1,129 mi 2) which includes several urbanized areas, including Raleigh, N.C., and part of Durham, N.C. The Kinston station provides information from the predominantly rural midsection of the basin (2,690 mi2). A network of temporary stations on small rural streams in the Neuse River and adjacent basins provide an estimate of baseline or es- sentially unpolluted water quality. Overall, the water quality of the Neuse River is satisfactory for most uses. However, dissolved-oxygen, iron, and manganese concentrations, pH, and bacterial concentrations often reach undesirable levels. Concentrations of cadmium, and lead also periodically peak at or above criterion levels for domestic water supply sources. Nutrient levels are generally high enough to allow rich algal growth. Sediment concentrations in the Neuse are high in comparison to pristine streams, however, the impacts of these high levels are difficult to quantify. Sediment and nutrient concentrations peak on the leading edge of flood discharges at Clayton. At Kinston, however, the discharge and sediment concentration peak almost simultaneously. Changes in algal dominance, from genera usually associated with organically enriched waters to genera that are less tolerant to organic enrichment, indicate improvement in water qualiy of the Neuse since 1973. These changes, along with a reduction in total organic carbon concentrations, coincide with activation in 1976 of a new waste-water treatment plant for the Raleigh metropolitan area. The amount of dissolved inorganic pollution in the Neuse was determined by subtacting estimated natural loads of dissolved constituents from measured total loads. Pollution makes up approximately 50 percent of the total dissolved material transported by the Neuse. Two different data transformation methods allowed trends to be identified in constituent concentrations. Both methods recomputed concentrations as if they were determined at a constant discharge over the period of record. Although little change since 1956 can be seen in many constituents, increases of over 50 percent are shown for potassium and sulfate concentrations. These long-term rises indicate the increasing impact that man has had on the Neuse River, in spite of improved waste-water treatment in the basin. The increase in sulfate is probably largely due to increased long-term imputs of sulfur compounds from acid precipitation.

North Carolina↗

Low-level radioactive-waste burial at the Palos Forest Preserve, Illinois: Geology and hydrology of the glacial drift, as related to the migration of tritium

A low-level radioactive-waste burial site is located in Palos Forest Preserve, about 22 kilometers southwest of Chicago, Illinois. Between 1943 and 1949 the site, named Plot M, was filled with radioactive waste from the first Argonne National Laboratory and from the University of Chicago Metallurgical Laboratory. Since 1973, tritium concentration levels up to 14 nanocuries per liter have been measured in water samples collected from a well 360 meters from the burial site. The U.S. Geological Survey is studying the geologic, hydrologic, and geochemical properties of the glacial drift and underlying bedrock at the Plot M site to determine the factors that control the movement of radionuclides. Test wells were drilled into the drift to collect water and core samples for laboratory analysis, to gather geologic and hydrologic data, and to conduct geophysical surveys. Plot M is located in drift that ranges in thickness from 25 to 45 meters. The drift is a stratified sequence of clay- and silt-rich sediments that contain thin, interstratified sand layers. The silt content of the drift increases with depth. The permeability of the drift, as indicated by field and laboratory hydraulic conductivity tests, ranges from 1.0 x 10 -6 to 1.0 ? 10 -8 centimeters per second. A tritium plume, the contaminated zone in the drift in which tritium concentration levels exceed 10 nanocuries per liter of water, extends horizontally northward from Plot M at least 50 meters and vertically downward to bedrock. The center of the plume, where tritium concentration levels are as high as 50,000 nanocuries per liter, is approximately 15 meters beneath the burial site. The size, shape, and 'bull's-eye' concentration pattern indicate that the plume is a single slug and that the site no longer releases tritium into the drift. The leading edge, or front, of the plume (the 10 nanocuries per liter boundary) left the burial site in either the late 1940's or the early 1950's and intersected the underlying bedrock surface before 1973. The calculated movement rate of the front is 6.3 x 10 -6 centimeters per second. Several key factors that control both the concentration level and the extent of migration of tritium in the drift at Plot M are 1. The limited amount of tritiated waste buried at Plot M. 2. The long period of time that has elapsed since the waste was buried (30-35 years) relative to the radioactive half-life of tritium (12.3 years). 3. The great thickness and low permeability of the glacial drift at the site.

Illinios↗

Traveltime and dispersion in the Potomac River, Cumberland, Maryland, to Washington, D.C.

A travel-time and dispersion study using rhodamine dye was conducted on the Potomac River between Cumberland, Maryland, and Washington, D.C., a distance of 189 miles. The flow during the study was at approximately the 90-percent flow-duration level. A similar study was conducted by Wilson and Forrest in 1964 at a flow duration of approximately 60 percent. The two sets of data were used to develop a generalized procedure for predicting travel-times and downstream concentrations resulting from spillage of water-soluble substances at any point along the river. The procedure will allow the user to calculate travel-time and concentration data for almost any spillage problem that occurs during periods of relatively steady flow between 50- and 95-percent flow duration. A new procedure for calculating unit peak concentration was derived. The new procedure depends on an analogy between a time-concentration curve and a scalene triangle. As a result of this analogy, the unit peak concentration can be expressed in terms of the length of the _lye or contaminant cloud. The new procedure facilitates the calculation of unit peak concentration for long reaches of river. Previously, there was no way to link unit peak concentration curves for studies in which the river was divided into subreaches for study. Variable dispersive characteristics caused mainly by low-head dams precluded useful extrapolation of the unit peak-concentration attenuation curves, as has been done in previous studies. The procedure is applied to a hypothetical situation in which 20,000 pounds of contaminant is spilled at a railroad crossing at Magnolia, West Virginia. The times required for the leading edge, the peak concentration, and the trailing edge of the contaminant cloud to reach Point of Rocks, Maryland (110 river miles downstream), are 295, 375, and 540 hours respectively, during a period when flow is at the 80-percent flow-duration level. The peak conservative concentration would be approximately 340 micrograms per liter at Point of Rocks.

District of Columbia, Maryland↗

Hydroacoustic, meteorologic and seismic observations of the 2016 Nansen Ice Shelf calving event and iceberg formation

On 7 April 2016, the Nansen Ice Shelf (NIS) front calved into two icebergs, the first large-scale calving event in >30 years. Three hydrophone moorings were deployed seaward of the NIS in December 2015 and over the following months recorded hundreds of short duration, broadband (10-400 Hz) cryogenic signals, likely caused by fracturing of the ice-shelf. The majority of these icequakes occur between January and early March 2016, several weeks prior to the calving observed by satellite on 7 April. Barometric pressure and wind speed records show the day the icebergs drifted from the NIS coincided with the largest low-pressure storm system recorded in the previous 7 months. A nearby seismic station also shows an increase in low-frequency energy, harmonic tremor, and microseisms on 7 April. Our interpretation is the northern segment of the NIS leading edge broke free during mid-January to February, producing high acoustic energy, but the icebergs remained stationary until the combination of a strong low-pressure system, with high winds freed the icebergs. As the unpinning of Antarctic ice shelves is not a well-documented process, our observations show that storm systems may play an under-appreciated role in Antarctic ice shelf break-up.

Frontiers in Earth Science↗

Is the timing, pace and success of the monarch migration associated with sun angle?

A basic question concerning the monarch butterfly’s fall migration is which monarchs succeed in reaching overwintering sites in Mexico, which fail—and why. We document the timing and pace of the fall migration, ask whether the sun’s position in the sky is associated with the pace of the migration, and whether timing affects success in completing the migration. Using data from the Monarch Watch tagging program, we explore whether the fall monarch migration is associated with the daily maximum vertical angle of the sun above the horizon (Sun Angle at Solar Noon, SASN) or whether other processes are more likely to explain the pace of the migration. From 1998 to 2015, more than 1.38 million monarchs were tagged and 13,824 (1%) were recovered in Mexico. The pace of migration was relatively slow early in the migration but increased in late September and declined again later in October as the migrating monarchs approached lower latitudes. This slow-fast-slow pacing in the fall migration is consistent with monarchs reaching latitudes with the same SASN, day after day, as they move south to their overwintering sites. The observed pacing pattern and overall movement rates are also consistent with monarchs migrating at a pace determined by interactions among SASN, temperature, and daylength. The results suggest monarchs successfully reaching the Monarch Butterfly Biosphere Reserve (MBBR) migrate within a “migration window” with an SASN of about 57° at the leading edge of the migration and 46° at the trailing edge. Migrants reaching locations along the migration route with SASN outside this migration window may be considered early or late migrants. We noted several years with low overwintering abundance of monarchs, 2004 and 2011–2014, with high percentages of late migrants. This observation suggests a possible effect of migration timing on population size. The migration window defined by SASN might serve as a framework against which to establish the influence of environmental factors on the size, geographic distribution, and timing of past and future fall migrations.

Frontiers in Ecology and Evolution↗

Current distribution of the nine-banded armadillo (Dasypus novemcinctus) in the United States

The nine-banded armadillo ( Dasypus novemcinctus : hereafter armadillo) was first recorded in the United States (U.S.) in the state of Texas in 1849 and has been expanding its range northward and eastward since then. With the widespread adoption of participatory science as well as the proliferation of nationwide wildlife game camera studies, occurrence data of armadillos can be compiled more rapidly and thoroughly than at any time in the past. Here, we use disparate data sources to update the current geographic distribution of the armadillo in the United States and use occurrence data from the leading edge of its range expansion to create a species distribution model to understand their relationship with landscape and bioclimatic factors. Since the last report on the geographic distribution of the armadillo in 2014, we show that armadillos have expanded to cover the entirety of Missouri and established in southern Iowa, expanded modestly within Kansas and Illinois, expanded northward and eastward in Indiana, expanded eastward in both Kentucky and Tennessee, established throughout the entirety of South Carolina and Georgia and established in the western third of North Carolina. Our species distribution model indicates that there is substantial opportunity for the species to continue to expand its geographic range, particularly in the Eastern United States. These results provide information to managers who are now or might soon be co-existing with the armadillo to proactively manage the species or inform the public regarding potential conflicts.

Diversity↗

Arsenic in petroleum-contaminated groundwater near Bemidji, Minnesota is predicted to persist for centuries

We used a reactive transport model to investigate the cycling of geogenic arsenic (As) in a petroleum-contaminated aquifer. We simulated As mobilization and sequestration using surface complexation reactions with Fe(OH) 3 during petroleum biodegradation coupled with Fe-reduction. Model results predict that dissolved As in the plume will exceed the U.S. and EU 10 µg/L drinking water standard for ~400 years. Non-volatile dissolved organic carbon (NVDOC) in the model promotes As mobilization by exerting oxygen demand, which maintains anoxic conditions in the aquifer. After NVDOC degrades, As re-associates with Fe(OH) 3 as oxygenated conditions are re-established. Over the 400-year simulation, As transport resembles a “roll front” in which: (1) arsenic sorbed to Fe(OH) 3 is released during Fe-reduction coupled to petroleum biodegradation; (2) dissolved As resorbs to Fe(OH) 3 at the plume’s leading edge; and (3) over time, the plume expands, and resorbed As is re-released into groundwater. This “roll front” behavior underscores the transience of sorption as an As attenuation mechanism. Over the plume’s lifespan, simulations suggest that As will contaminate more groundwater than benzene from the oil spill. At its maximum, the model simulates that ~5.7× more groundwater will be contaminated by As than benzene, suggesting that As could pose a greater long-term water quality threat than benzene in this petroleum-contaminated aquifer.

Minnesota↗

Environmental DNA reveals invasion of Puerto Rican waterways by non-native Clarias catfish

The Sharptooth walking catfish ( Clarias gariepinus ) is native to parts of the Middle East, Asia, and Africa but is one of the world's most invasive freshwater fish species. The species’ ability to invade is partly due to its ability to breathe atmospheric oxygen, thereby avoiding hypoxia or poor water quality in receiving waterbodies; further, it can crawl over moist land to disperse to new systems. In 2018, two individuals purported to be Sharptooth walking catfish were collected and identified within the Canal de Patillas, a canal in the Guayama municipality in southeastern Puerto Rico. Several other specimens were also collected the following year. Given that this invasion was in its infancy, environmental DNA (eDNA) surveillance was employed as a rapid and efficient surveillance tool to help delineate the extent of this invasion. Water samples were collected and analyzed for Clarias eDNA from 66 sites encompassing a wide range of habitats in canals, lakes, and a river surrounding the area where they were first reported. Using eDNA-metabarcoding, we detected Clarias eDNA at 40 of the 63 sites throughout the sampled waterbodies. Furthermore, our molecular analysis indicated that the Whitespotted Clarias ( C. fuscus ) is the likely invader, and the original specimens, classified as C. gariepinus , were misidentified based on the use of morphological rather than genetic features for species classification. Environmental DNA surveillance indicated that the distribution of Clarias catfish in this system is substantially more extensive than previously documented. These findings suggest that additional survey efforts could help determine the invasion's full spatial extent and leading edge to inform the scope and scale of any potential management responses.

Puerto Rico↗