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At least 145 records · Page 8Linked to original sources

Quantifying riverine surface currents from time sequences of thermal infrared imagery

River surface currents are quantified from thermal and visible band imagery using two methods. One method utilizes time stacks of pixel intensity to estimate the streamwise velocity at multiple locations. The other method uses particle image velocimetry to solve for optimal two-dimensional pixel displacements between successive frames. Field validation was carried out on the Wolf River, a small coastal plain river near Landon, Mississippi, United States, on 26-27 May 2010 by collecting imagery in association with in situ velocities sampled using electromagnetic current meters deployed 0.1 m below the river surface. Comparisons are made between mean in situ velocities and image-derived velocities from 23 thermal and 6 visible-band image sequences (5 min length) during daylight and darkness conditions. The thermal signal was a small apparent temperature contrast induced by turbulent mixing of a thin layer of cooler water near the river surface with underlying warmer water. The visible-band signal was foam on the water surface. For thermal imagery, streamwise velocities derived from the pixel time stack and particle image velocimetry technique were generally highly correlated to mean streamwise current meter velocities during darkness (r 2 typically greater than 0.9) and early morning daylight (r 2 typically greater than 0.83). Streamwise velocities from the pixel time stack technique had high correlation for visible-band imagery during early morning daylight hours with respect to mean current meter velocities (r 2 > 0.86). Streamwise velocities for the particle image velocimetry technique for visible-band imagery had weaker correlations with only three out of six correlations performed having an r 2 exceeding 0.6. Copyright 2012 by the American Geophysical Union.

Water Resources Research

Identifying spatial variability of groundwater discharge in a wetland stream using a distributed temperature sensor

Discrete zones of groundwater discharge in a stream within a peat‐dominated wetland were identified on the basis of variations in streambed temperature using a distributed temperature sensor (DTS). The DTS gives measurements of the spatial (±1 m) and temporal (15 min) variation of streambed temperature over a much larger reach of stream (>800 m) than previous methods. Isolated temperature anomalies observed along the stream correspond to focused groundwater discharge zones likely caused by soil pipes within the peat. The DTS also recorded variations in the number of temperature anomalies, where higher numbers correlated well with a gaining reach identified by stream gauging. Focused zones of groundwater discharge showed essentially no change in position over successive measurement periods. Results suggest DTS measurements will complement other techniques (e.g., seepage meters and stream gauging) and help further improve our understanding of groundwater–surface water dynamics in wetland streams.

Water Resources Research

Using diurnal temperature signals to infer vertical groundwater-surface water exchange

Heat is a powerful tracer to quantify fluid exchange between surface water and groundwater. Temperature time series can be used to estimate pore water fluid flux, and techniques can be employed to extend these estimates to produce detailed plan-view flux maps. Key advantages of heat tracing include cost-effective sensors and ease of data collection and interpretation, without the need for expensive and time-consuming laboratory analyses or induced tracers. While the collection of temperature data in saturated sediments is relatively straightforward, several factors influence the reliability of flux estimates that are based on time series analysis (diurnal signals) of recorded temperatures. Sensor resolution and deployment are particularly important in obtaining robust flux estimates in upwelling conditions. Also, processing temperature time series data involves a sequence of complex steps, including filtering temperature signals, selection of appropriate thermal parameters, and selection of the optimal analytical solution for modeling. This review provides a synthesis of heat tracing using diurnal temperature oscillations, including details on optimal sensor selection and deployment, data processing, model parameterization, and an overview of computing tools available. Recent advances in diurnal temperature methods also provide the opportunity to determine local saturated thermal diffusivity, which can improve the accuracy of fluid flux modeling and sensor spacing, which is related to streambed scour and deposition. These parameters can also be used to determine the reliability of flux estimates from the use of heat as a tracer.

Groundwater

Dry Stream Reaches in Carbonate Terranes: Surface Indicators of Ground-Water Reservoirs

In areas where dry stream reaches occur, subsurface drainage successfully competes with surface drainage, and sheet-like dissolution openings have developed parallel to bedding creating the ground-water reservoir. Union Hollow in south-central Tennessee is the setting for a case study that illustrates the application of the dry stream reach technique. In this technique, dry stream reach identification is based on two types of readily acquired information: remotely sensed black and white infrared aerial photography; and surface reconnaissance of stream channel characteristics. Test drilling in Union Hollow subsequent to identification of the dry reach proved that a localized ground-water reservoir was present.

Water Resources Bulletin

Evaluation of stream and wetlands restoration using UAS-based thermal infrared mapping

Large-scale wetland restoration often focuses on repairing the hydrologic connections degraded by anthropogenic modifications. Of these hydrologic connections, groundwater discharge is an important target, as these surface water ecosystem control points are important to thermal stability, among other ecosystem services. However, evaluating the effectiveness of the restoration activities on establishing groundwater discharge connection is often difficult over the vast area and often challenging or inaccessible terrain of wetlands. Unoccupied aerial systems (UAS) are now routinely used for collecting aerial imagery and creating digital surface models (DSM). Lightweight thermal infrared (TIR) sensors provide another payload option for generation of sub-meter resolution aerial TIR orthophotos. This technology allows for the rapid and safe survey of groundwater discharge areas. Aerial TIR water-surface data were collected March 2019 at Tidmarsh Farms, a former commercial cranberry peatland located in coastal Massachusetts, USA (41°54'17.6"N 70°34'17.4"W), where stream and wetland restoration actions were completed in 2016. Here we present a 0.4 km2 georeferenced, temperature calibrated TIR orthophoto of the area. The image represents a mosaic of nearly 900 TIR images captured by UAS in a single morning with a total flight time of 36 minutes, and is supported by a DSM derived from UAS visible imagery. The survey was conducted in winter to maximize temperature contrast between relatively warm groundwater and colder ambient surface environment; lower-density groundwater rises above cool surface waters and thus can be imaged by a UAS. The resulting TIR orthomosaic shows fine detail of seepage distribution and downstream influence along the several restored channel forms, which was an objective of the ecological restoration design. The restored stream channel has increased connectivity to peatland groundwater discharge, reducing the ecosystem thermal stressors. Such aerial techniques can be used to guide ecological restoration design and assess post-restoration outcomes, especially in settings where ecosystem structure and function is governed by groundwater and surface water interaction.

Water

Bathymetric Surveys of Lake Arthur and Raccoon Lake, Pennsylvania, June 2007

In spring of 2007, bathymetric surveys of two Pennsylvania State Park lakes were performed to collect accurate data sets of lake-bed elevations and to develop methods and techniques to conduct similar surveys across the state. The lake-bed elevations and associated geographical position data can be merged with land-surface elevations acquired through Light Detection and Ranging (LIDAR) techniques. Lake Arthur in Butler County and Raccoon Lake in Beaver County were selected for this initial data-collection activity. In order to establish accurate water-surface elevations during the surveys, benchmarks referenced to NAVD 88 were established on land at each lake by use of differential global positioning system (DGPS) surveys. Bathymetric data were collected using a single beam, 210 kilohertz (kHz) echo sounder and were coupled with the DGPS position data utilizing a computer software package. Transects of depth data were acquired at predetermined intervals on each lake, and the shoreline was delineated using a laser range finder and compass module. Final X, Y, Z coordinates of the geographic positions and lake-bed elevations were referenced to NAD 83 and NAVD 88 and are available to create bathymetric maps of the lakes.

Data Series

Perchlorate isotope forensics

Perchlorate has been detected recently in a variety of soils, waters, plants, and food products at levels that may be detrimental to human health. These discoveries have generated considerable interest in perchlorate source identification. In this study, comprehensive stable isotope analyses ( 37 Cl/ 35 Cl and 18 O/ 17 O/ 16 O) of perchlorate from known synthetic and natural sources reveal systematic differences in isotopic characteristics that are related to the formation mechanisms. In addition, isotopic analyses of perchlorate extracted from groundwater and surface water demonstrate the feasibility of identifying perchlorate sources in contaminated environments on the basis of this technique. Both natural and synthetic sources of perchlorate have been identified in water samples from some perchlorate occurrences in the United States by the isotopic method.

Analytical Chemistry

Artificial Recharge — State of the Art

The largest potential reservoir for the storage of potable water is in the unsaturated zone. Use of this space for the storage and retrieval of potable water is a multifaceted problem which requires application of the best talent from the scientific community. Artificial recharge has many similarities to liquidwaste disposal through deep wells. In both, the problem is to place liquid in a permeable lithologic unit at an economic rate, to predict movement and the chemical reactions and physical changes that take place while the liquid is in the reservoir. Differences between the two operations are principally in the type of fluid injected and the ultimate objective. In artificial recharge the objective is to store and retrieve water of good quality; in waste disposal the objective is to store permanently water of objectionable quality. In both artificial recharge and liquid-waste storage, the nature of the storage must be known, particularly that of the unsaturated zone. The techniques of investigation for recharge and waste disposal are generally the same. Water commonly is recharged by surface spreading through basins or by induced recharge from adjacent streams and lakes or through injection wells. Research in recharge through basins has been dominated by mathematical models based on idealized conditions and empirical relations, derived by experimental sequencing of recharge operations, and operational controls in the pretreatment of recharge water. Recharge by injection wells has been undertaken in a variety of hydrologic environments. In Israel efforts have been directed toward the analyses of diffusion and dispersion of the injected water. Much research in the United States has been directed toward the movement of bacteria and organic matter through an aquifer and toward the chemical modeling of changes in recharged water as it moves. Much more research is needed on the basic properties of aquifers, particularly in the unsaturated zone, and on all aspects of recharge-water quality. Research and the use of data produced are increasingly the responsibility of interdisciplinary teams which consider the geologic, hydraulic, and economic aspects of the system.

Groundwater

Estimates of ground-water recharge, base flow, and stream reach gains and losses in the Willamette River basin, Oregon

Precipitation-runoff models, base-flow-separation techniques, and stream gain-loss measurements were used to study recharge and ground-water surface-water interaction as part of a study of the ground-water resources of the Willamette River Basin. The study was a cooperative effort between the U.S. Geological Survey and the State of Oregon Water Resources Department. Precipitation-runoff models were used to estimate the water budget of 216 subbasins in the Willamette River Basin. The models were also used to compute long-term average recharge and base flow. Recharge and base-flow estimates will be used as input to a regional ground-water flow model, within the same study. Recharge and base-flow estimates were made using daily streamflow records. Recharge estimates were made at 16 streamflow-gaging-station locations and were compared to recharge estimates from the precipitation-runoff models. Base-flow separation methods were used to identify the base-flow component of streamflow at 52 currently operated and discontinued streamflow-gaging-station locations. Stream gain-loss measurements were made on the Middle Fork Willamette, Willamette, South Yamhill, Pudding, and South Santiam Rivers, and were used to identify and quantify gaining and losing stream reaches both spatially and temporally. These measurements provide further understanding of ground-water/surface-water interactions.

Water-Resources Investigations Report

A method to estimate groundwater depletion from confining layers

Although depletion of storage in low‐permeability confining layers is the source of much of the groundwater produced from many confined aquifer systems, it is all too frequently overlooked or ignored. This makes effective management of groundwater resources difficult by masking how much water has been derived from storage and, in some cases, the total amount of water that has been extracted from an aquifer system. Analyzing confining layer storage is viewed as troublesome because of the additional computational burden and because the hydraulic properties of confining layers are poorly known. In this paper we propose a simplified method for computing estimates of confining layer depletion, as well as procedures for approximating confining layer hydraulic conductivity ( K ) and specific storage ( S s ) using geologic information. The latter makes the technique useful in developing countries and other settings where minimal data are available or when scoping calculations are needed. As such, our approach may be helpful for estimating the global transfer of groundwater to surface water. A test of the method on a synthetic system suggests that the computational errors will generally be small. Larger errors will probably result from inaccuracy in confining layer property estimates, but these may be no greater than errors in more sophisticated analyses. The technique is demonstrated by application to two aquifer systems: the Dakota artesian aquifer system in South Dakota and the coastal plain aquifer system in Virginia. In both cases, depletion from confining layers was substantially larger than depletion from the aquifers.

Water Resources Research

Potential for Small Unmanned Aircraft Systems applications for identifying groundwater-surface water exchange in a meandering river reach

The exchange of groundwater and surface water (GW-SW), including dissolved constituents and energy, represents a critical yet challenging characterization problem for hydrogeologists and stream ecologists. Here, we describe the use of a suite of high spatial-resolution remote-sensing techniques, collected using a small unmanned aircraft system (sUAS), to provide novel and complementary data to analyze GW-SW exchange. sUAS provided centimeter-scale resolution topography and water surface elevations, which are often drivers of exchange along the river corridor. Additionally, sUAS-based vegetation imagery, vegetation-top elevation, and normalized difference vegetation index (NDVI) mapping indicated GW-SW exchange patterns that are difficult to characterize from the land surface and may not be resolved from coarser satellite-based imagery. We combined these data with estimates of sediment hydraulic conductivity to provide a direct estimate of GW “shortcutting” through meander necks, which was corroborated by temperature data at the riverbed interface.

Geophysical Research Letters

Hydrogeologic facies characterization of an alluvial fan near Fresno, California, using geophysical techniques

DBCP (1,2-dibromo-3-chloropropane) contamination in the sole source aquifer near Fresno, California, has significantly affected drinking-water supplies. Borehole and surface geophysical data were integrated with borehole textural data to characterize the Kings River alluvial fan sediments and to provide a framework for computer modeling of pesticide transport in ground water. Primary hydrogeologic facies units, such as gravel, coarse sand or gravel, fine sand, and silt and clay, were identified in cores collected from three borings located on a 4.6-kilometer transect of multilevel monitoring wells. Borehole geophysical logs collected from seven wells and surface geophysical surveys were used to extrapolate hydrogeologic facies to depths of about 82meters and to correlate the facies units with neighboring drilling sites. Thickness ranged from 0.3to 13 meters for sand and gravel units, and from 0.3 to 17 meters for silt and clay. The lateral extent of distinct silt and clay layers was mapped using shallow seismic reflection and ground-penetrating radar techniques. About 3.6 kilometers of seismic reflection data were collected; at least three distinct fine-grained layers were mapped. The depth of investigation of the seismic survey ranged from 34 to 107 meters below land surface, and vertical resolution was about 3.5 meters. The ground-penetrating radar survey covered 3.6kilometers and imaged a 1.5-meters thick, continuous fine-grained layer located at a depth of about 8 meters. Integrated results from the borehole sediment descriptions and geophysical surveys provided a detailed characterization over a larger areal extent than traditional hydrogeologic methods alone.

Open-File Report

A comparison of surface-grab and cross sectionally integrated stream-water-quality sampling methods

Stream sampling for water quality data has commonly employed simple surface-grab procedures as opposed to more involved, cross sectionally integrated techniques. Paired samples for analysis of selected constituents were collected over various flow conditions at four sites to evaluate differences between the two sampling methods. Concentrations of dissolved constituents were not consistently different. However, concentrations of suspended sediment and the total forms of some sediment-associated constituents, such as phosphorus, iron, and manganese, were significantly lower in the surface-grab samples than in the cross sectionally integrated samples. The largest median percent difference in concentration for a site was 60% (total recoverable manganese). Median percent differences in concentration for sediment-associated constituents considering all sites grouped were in the range of 20-25%. The surface-grab samples underrepresented concentrations of suspended sediment and some sediment-associated constituents, thus limiting the applicability of such data for certain purposes. An association was also demonstrated between site streamflow characteristics and the observed differences.

Water Environment Research

Magnetic resonance sounding survey data collected in the North Platte, Twin Platte, and South Platte Natural Resource Districts, Western Nebraska, Fall 2012

This report is a release of digital data and associated survey descriptions from a series of magnetic resonance soundings (MRS, also known as surface nuclear magnetic resonance) that was conducted during October and November of 2012 in areas of western Nebraska as part of a cooperative hydrologic study by the North Platte Natural Resource District (NRD), South Platte NRD, Twin Platte NRD, the Nebraska Environmental Trust, and the U.S. Geological Survey (USGS). The objective of the study was to delineate the base-of-aquifer and refine the understanding of the hydrologic properties in the aquifer system. The MRS technique non-invasively measures water content in the subsurface, which makes it a useful tool for hydrologic investigations in the near surface (up to depths of approximately 150 meters). In total, 14 MRS production-level soundings were acquired by the USGS over an area of approximately 10,600 square kilometers. The data are presented here in digital format, along with acquisition information, survey and site descriptions, and metadata.

Nebraska

Identifying characteristics of actionable science for drought planning and adaptation: Final report to the North Central Climate Adaptation Science Center

Changing climate conditions can make water management planning and drought preparedness decisions more complicated than ever before. Resource managers can no longer rely solely on historical data and trends to base their actions, and are in need of science that is relevant to their specific needs and can directly inform important planning decisions. Questions remain, however, regarding the most effective and efficient methods for extending scientific knowledge and products into management and decision-making. This study analyzed two unique cases of water management to better understand how science can be translated into resource management actions and decision-making. In particular, this project sought to understand 1) the characteristics that make science actionable and useful for water resource management and drought preparedness, and 2) the ideal types of scientific knowledge or science products that facilitate the use of science in management and decision-making. The first case study focused on beaver mimicry, an emerging nature-based solution that increases the presence of wood and woody debris in rivers and streams to mimic the actions of beavers. This technique has been rapidly adopted by natural resource managers as a way to restore riparian areas, increase groundwater infiltration, and slow surface water flow so that more water is available later in the year during hotter and dryer months. The second case study focused on an established research program, Colorado Dust on Snow, that provides water managers with scientific information explaining how the movement of dust particles from the Colorado Plateau influences hydrology and the timing and intensity of snow melt and water runoff into critical water sources. This program has support from and is being used by several water conservation districts in the state. Understanding how scientific knowledge translates into action and decision-making in these cases is expected to strengthen our knowledge of actionable science in the context of drought and its impacts on ecosystems. The project team gathered qualitative data through stakeholder interviews and will conduct an extensive literature review. Findings from these efforts will also be incorporated into a broader Intermountain West synthesis effort to determine and assess commonalities and differences among socio-ecological aspects of drought adaptation and planning.

Colorado, Kansas, Montana, Nebraska, North Dakota,

Effects of low-impact-development (LID) practices on streamflow, runoff quantity, and runoff quality in the Ipswich River Basin, Massachusetts: A summary of field and modeling studies

Low-impact-development (LID) approaches are intended to create, retain, or restore natural hydrologic and water-quality conditions that may be affected by human alterations. Wide-scale implementation of LID techniques may offer the possibility of improving conditions in river basins, such as the Ipswich River Basin in Massachusetts, that have run dry during the summer because of groundwater withdrawals and drought. From 2005 to 2008, the U.S. Geological Survey, in a cooperative funding agreement with the Massachusetts Department of Conservation and Recreation, monitored small-scale installations of LID enhancements designed to diminish the effects of storm runoff on the quantity and quality of surface water and groundwater. Funding for the studies also was contributed by the U.S. Environmental Protection Agency’s Targeted Watersheds Grant Program through a financial assistance agreement with Massachusetts Department of Conservation and Recreation. The monitoring studies examined the effects of replacing an impervious parking-lot surface with a porous surface on groundwater quality, installing rain gardens and porous pavement in a neighborhood of 3 acres on the quantity and quality of stormwater runoff, and installing a 3,000-ft2 (square-foot) green roof on the quantity and quality of rainfall-generated roof runoff. In addition to these small-scale installations, the U.S. Geological Survey’s Ipswich River Basin model was used to simulate the basin-wide effects on streamflow of several changes: broad-scale implementation of LID techniques, reduced water-supply withdrawals, and water-conservation measures. Water-supply and conservation scenarios for application in model simulations were developed with the assistance of two technical advisory committees that included representatives of State agencies responsible for water resources, the U.S. Environmental Protection Agency, the U.S. Geological Survey, water suppliers, and non-governmental organizations. From June 2005 to June 2007, groundwater quality was monitored at the Silver Lake town beach parking lot in Wilmington, Massachusetts, prior to and following the replacement of the conventional, impervious-asphalt surface with a porous surface consisting primarily of porous asphalt and porous pavers designed to enhance rainfall infiltration into the groundwater and to minimize runoff to Silver Lake. Concentrations of phosphorus, nitrogen, cadmium, chromium, copper, lead, nickel, zinc, and total petroleum hydrocarbons in groundwater were monitored. Enhancing infiltration of precipitation did not result in discernible increases in concentrations of these potential groundwater contaminants. Concentrations of dissolved oxygen increased slightly in groundwater profiles following the removal of the impervious asphalt parking-lot surface. In Wilmington, Massachusetts, in a 3-acre neighborhood, stormwater runoff volume and quality were monitored to determine the ability of selected LID enhancements (rain gardens and porous paving stones) to reduce flows and loads of the selected constituents to Silver Lake. Water-quality samples were analyzed for nutrients, metals, total petroleum hydrocarbons, and total-coliform and E. coli bacteria. A decrease in runoff quantity was observed for storms of 0.25 inch or less of precipitation. Water-quality-monitoring results were inconclusive; there were no statistically significant differences in concentrations or loads when the pre- and post-installation-period samples were compared. In a third field study, the characteristics of runoff from a vegetated "green" roof and a conventional, rubber-membrane roof were compared. The two primary factors affecting the green roof’s water-storage capacity were the amount of precipitation and antecedent dry period. Although concentrations of many of the chemicals in roof runoff were higher from the green roof than from the conventional roof, the ability of the green roof to retain water generally resulted in decreased differences between the total amounts (loads) of the chemicals that ran off the roofs. Land-use and water-management changes associated with LID implementation were investigated at multiple spatial scales, using the U.S. Geological Survey’s Ipswich River Basin model, to evaluate the effects of updated water-supply withdrawals for the towns of Reading and Wilmington (representing new baseline conditions for all simulations), potential land-use changes at buildout (potential future development), widespread implementation of retrofitting LID techniques, basin-scale water withdrawal reductions based on water-conservation pilot programs conducted by the Massachusetts Department of Conservation and Recreation, and land-use change and LID applications at a local scale. The new baseline simulation indicated that reduced water-supply withdrawals for the towns of Reading and Wilmington led to substantially higher medium and low flows in most of the reaches upstream from the South Middleton streamgage in the upper Ipswich River basin. Overall, simulations pointed to the importance of spatial scale in determining the effects of land-use change and LID practices on streamflow. Potential land-use changes at buildout had modest effects on streamflow in most subbasins (percent differences of less than 20 percent) because relatively little land in the basin was available for development. Results of the simulations conducted to evaluate widespread effective-impervious-area reductions upstream from the South Middleton streamgage indicated that the percentages of urban land use and associated effective impervious area were too small for even a 50-percent reduction of effective impervious area to appreciably affect streamflow in most subbasins. In contrast, the results of the hypothetical local-scale simulations indicated that for smaller streams, with high percentages of urban land use and associated effective impervious area, land-use change, development patterns, and LID practices may have substantial effects on streamflow. Modeling studies concurred with the results of fieldwork in the assessment that LID enhancements would likely have the greatest effect on decreasing stormwater runoff when broadly applied to highly impervious urban areas.

Massachusetts

Ground-water research in the U.S.A.

Ground-water reservoirs and the overlying unsaturated zone-collectively, the "subsurface"-have an enormous capacity to supply water to wells and useful plants, to store water to meet future needs for the same purposes, and, under suitable precautions, to accept wastes. This capacity can be exploited on a maximum scale, however, only on the basis of information one or more orders of magnitude greater than that available at present on the distribution, recoverability, and replenishability of subsurface water. Because usable water must be made available, and waste water must be disposed of, at costs of only a cent or a few cents per cubic meter, there is a critical need for research to devise methods of accomplishing these water-management tasks at reasonable cost. Among the chief target areas for research in subsurface hydrology are permeability distribution, including vertical permeability; prediction of the departure of the storage coefficient from the theoretically "instantaneous" property assumed in flow equations; theory of unsaturated flow based on fundamental soil characteristics that can be measured practicably; geochemical relations including the effects of injecting water of one composition into zones occupied by waters of different composition, generation of acid mine water, occurrence of saline water, and salt-fresh-water relations in coastal and other areas; prediction of the fate of wastes injected underground; geophysical techniques both surface and subsurface to extend, at low cost, information obtained by other means; and practical techniques of artificial recharge, especially through wells. ?? 1967.

Earth-Science Reviews

Data-driven modeling of background and mine-related acidity and metals in river basins

A novel application of self-organizing map (SOM) and multivariate statistical techniques is used to model the nonlinear interaction among basin mineral-resources, mining activity, and surface-water quality. First, the SOM is trained using sparse measurements from 228 sample sites in the Animas River Basin, Colorado. The model performance is validated by comparing stochastic predictions of basin-alteration assemblages and mining activity at 104 independent sites. The SOM correctly predicts (>98%) the predominant type of basin hydrothermal alteration and presence (or absence) of mining activity. Second, application of the Davies–Bouldin criteria to k-means clustering of SOM neurons identified ten unique environmental groups. Median statistics of these groups define a nonlinear water-quality response along the spatiotemporal hydrothermal alteration-mining gradient. These results reveal that it is possible to differentiate among the continuum between inputs of background and mine-related acidity and metals, and it provides a basis for future research and empirical model development.

Environmental Pollution