Rapid toluene mineralization by aquifer microorganisms at Adak, Alaska: Implications for intrinsic bioremediation in cold environments
No abstract available.
Environmental Science & Technology↗
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Links between tectonics, magmatism, and mineralization in the formation of Late Cretaceous porphyry systems in the Yukon-Tanana upland, eastern Alaska, USA
Cretaceous-Paleocene porphyry Cu(±Mo±Au) occurrences are scattered throughout the Yukon-Tanana upland in eastern Alaska. Known occurrences in eastern Alaska are poorly characterized, despite a resurgence in exploration. Porphyry deposits in the upland are emplaced into structurally complex metamorphic rocks representing a variety of tectonic environments, resulting in diverse alteration and mineralization assemblages. New mapping, drill core logging, petrography, geochemistry, geochronology, and structural analysis allow improved characterization of the parameters of porphyry systems and identify key linkages to regional tectonic and magmatic events. New sericite 40 Ar/ 39 Ar and zircon U/Pb dates constrain porphyry systems to the Late Cretaceous-earliest Paleocene (ca. 71-63 Ma). Zircon Hf-isotope ratios and Ce and Eu concentrations indicate that Late Cretaceous-Paleocene intrusions emplaced into basement dominated by Triassic and Jurassic plutons are more isotopically juvenile, reflecting more oxidized conditions. In contrast, those emplaced into basement dominated by mid-Cretaceous plutons are more reduced crustal geochemical-affinity. Diversity in mineral assemblages in contrasting systems may reflect emplacement into crustal domains of varying compositions and oxidation states. Those formed within a domain containing more-oxidized Triassic and Jurassic plutons are molybdenite-rich and apparently lack gold. In contrast, systems formed within domains dominated by more reduced mid-Cretaceous plutons contain lower-sulfidation state mineral assemblages with reported gold.
Alaska, Yukon↗
The geology, mineralogy and paragenesis of the Castrovirreyna lead-zinc-silver deposits, Peru
The Castrovirreyna mining district lies in the Andean Cordillera of South Central Peru, and has been worked sporadically since its discovery in 1591. Supergene silver ores were first mined. Currently the district produces about 20,000 tons of lead-zinc ore and 5000 tons of silver ore annually. The district is underlain by Tertiary andesitic rocks interbedded with basalts and intruded by small bodies of quartz latite porphyry. The terrane reflects recent glaciation and is largely covered by glacial debris. The ore deposits are steeply dipping veins that strike N. 60? E. to S. 50? E., and average 60 centimeters wide and 300 meters long. The principal veins are grouped around three centers, lying 5 kilometers apart along a line striking N. 55? E. They are, from east to west: San Genaro, Caudalosa, and La Virreyna. A less important set of veins, similarly aligned, lies 2 kilometers to the north. Most of the veins were worked to depths of about 30 meters, the limit of supergene enrichment; but in the larger veins hypogene ores have been worked to depths of over 150 meters. Galena, sphalerite, chalcopyrite, and tetrahedrite are common to all veins, but are most abundant in the westernmost veins at La Virreyna. In the center of the district, around Caudalosa, land sulfantimonides are the commonest ore minerals, and at the eastern end, around San Genaro and Astohuaraca, silver sulfosalts predominate. Supergene enrichment of silver is found at shallow depths in all deposits. Silver at San Genaro, however, was concentrated towards the surface by migration along hypogene physico-chemical gradients in time and space, as vein material was reworked by mineralizing fluids. The pattern of wallrock alteration throughout the district grades from silicification and scricitization adjacent to the veins, through argillization and propylitization, to widespread chloritization farther away. Mineralization can be divided into three stages: 1) Preparatory stage, characterized by silicification and pyritization; 2) Depositional stage, characterized by the deposition of base-metal sulfides; and 3) Reworking stage, characterized by the formation of lead sulfantimonides from galena at Caudalosa, and the deposition of silver sulfide and sulfosalts at San Genaro. Maximum temperatures, indicated by the wurtzite-sphalerite, famatinite-energite and chalcopyrite-sphalerite assemblages, did not exceed 350? C. The low iron content of sphalerite suggests that most of the base-metal sulfides were deposited below 250? C. The colloidal habits of pyrite and quartz in the preparatory and reworking stages imply relatively low temperatures of deposition, probably between 50? C and 100? C. Mineralization was shallow and pressures ranged from 17 atmospheres in the silver deposits to over 45 atmospheres in the lead sulfantimonide deposits. Mineralization at Castrovirreyna represents an open chemical system in which mineralizing fluids constantly modified the depositional environment while they themselves underwent modification. The deposits formed under nonequilibrium conditions from fluids containing complex ions and colloids. Reworking and migration along persistent physico-chemical gradients in time and space, from a deep source to the west concentrated base-metal sulfides in the western half, lead-antimony minerals in the center, and silver-antimony minerals in the eastern part of the district. Silver, antimony, and bismuth were kept in solution as complex ions until low temperature and pressure prevailed. They document in situ reworking by reacting with existing minerals. Physico-chemical gradients controlled the type of minerals deposited, whereas vein structure controlled the quantity deposited. Vein fissures formed by the equivalent of from east-west compression during Andean orogenesis and mineralization probably came from the underlying Andean Batholith.
Open-File Report↗
Mineral resources of the Minarets Wilderness and adjacent areas, Madera and Mono counties, California
A mineral survey of the Minarets Wilderness area and adjacent areas in the central Sierra Nevada, Calif., was conducted during 1973 through 1975. The total area covers about 620 km 2 (237 sq mi) in the Sierra and Inyo National Forests, of which about 440 km 2 (170 sq mi) are within the officially designated Minarets Wilderness. The mineral resource potential was evaluated by geological, geochemical, and geophysical studies by the U.S. Geological Survey, and by examination of mineralized rocks, prospects, and mining claims by the U.S. Bureau of Mines. The results of the survey indicate that the study area has small to moderate submarginal to paramarginal resources of copper, silver, zinc, lead, iron, and tungsten and an unevaluated potential for molybdenum resources. Limestone is present, but not of commercial quantity or quality. No other industrial minerals have been recognized in quantity. Granitic rocks have potential use as decorative stone and sand and gravel could be produced from either alluvial deposits or glacial drift. However, these commodities are more accessible elsewhere at localities closer to markets. The study area has no potential for fossil fuels, and, because of the general geologic environment, the potential for nuclear fuel minerals is considered to be low. The study area has low geothermal potential, even though it is on the western edge of the Mono-Long Valley "Known Geothermal Resource Area" (KGRA). The area is underlain by metavolcanic and metasedimentary rocks that have been intruded by granitic rocks of the Sierra Nevada batholith. Pliocene volcanic rocks are present locally. With few exceptions, the known occurrences of mineralized rock are confined to the metamorphic rocks, and the exceptions appear to be confined to plutonic rocks that are older than the Late Cretaceous granitic rocks that make up the bulk of the batholithic rocks in the study area. Although no mineral production has been recorded from prospects within the study area, mines adjacent to it have produced significant amounts of gold and tungsten. Production figures are incomplete, but mines in the Mammoth mining district (fig. 1) may have produced as much as $1 million worth of gold, silver, and other metals at the then-existing prices. The Monte Cristo mine in the Mammoth district was in production during 1978.
California↗
Preliminary report on geophysics ground follow-up of the 1977 airborne survey in the Wadi Bidah District, Kingdom of Saudi Arabia
Reconnaissance geologic and geochemical sampling was made during the 1978 field season at most of the 50 or so electromagnetic anomalies detected in the 1977 airborne electromagnetic (AEM) survey of the Wadi Bidah district. These Phase 1 studies also included reconnaissance geophysical traverses of nine of the AEM conductors. In addition the AEM anomalies were classified on the basis of this reconnaissance work into a list of priority targets for use in economic studies, and six AEM anomalies were selected for further studies. During Phase 2 conducted in the 1979 field season, ground geophysical work consisting of electromagnetic (EM), self-potential (SP), and selected magnetic surveys were carried out in the six targets selected in the Phase 1 studies. These target areas in aggregate cover about 30 km 2, and are approximately half of the Wadi Bidah Class 1 and Class 2 priority targets found during the 1977 airborne electromagnetic (AEM) survey of parts of the Arabian Shield. The results indicate possible extension of known reserves at the Rabathan area (AEM anomaly B-29), with possible potential for mineralization in the area extending 15-20 km north (anomaly B-13), where the geologic and geophysical environment is similar. An important observation is that mineralization in the B-29 (Rabathan) zone is coincident with narrow SP anomalies superimposed on the larger, broader, and more formational-type SP anomalies encountered in both areas B-29 and B-13. AEM anomaly B-25-26 areahas geophysical characteristics that show in the groundwork and that make it an attractive drill target. EM and SP anomalies are associated, in part, with magnetic anomalies and with exposures of significant limonitic gossan. Wadi al Khadra prospect, not included in the 1977 AEM survey, and the AEM anomaly B-25-26 area were also high-mineralization-potential products of the Phase 2 studies. Target area B-35 remains an unknown quantity, and AEM anomaly B-24 is almost certainly due to a carbonaceous schist. Geochemical results, along with detailed geologic mapping and the geophysical data, indicate several potential mineralized targets. Further detailed geophysics (EM and SP) will assist in understanding the geophysical data thus far collected. Further ground follow-up studies are recommended.
Open-File Report↗
Petrographic differentiation of depositional environments of sandstones of the Pennsylvanian Breathitt Formation, northeastern Kentucky and southwestern West Virginia
Petrographic properties of sandstone samples from the lower and middle Pennsylvanian Breathitt Formation in northeastern Kentucky and southwestern West Virginia were utilized to classify their environments of deposition. Simultaneous consideration of mineral composition, grain size, and sorting of the sandstones by using stepwise multiple discriminant-function analysis has permitted differentiation between alluvial-plain and delta-plain sandstones. Stepwise multiple discriminant-function analysis of the sandstone samples- was performed in two parts. The first analysis assigned the sandstones of all grain-size classes to one of three environments of deposition: (1) alluvial plain, (2) upper delta plain, and (3) lower delta plain. The second analysis classed the sandstones by grain size and subdivided each grain-size class into these environmental groups. Discriminant analyses of sandstones of all grain-size classes led to correct assignment of depositional environment to 76 percent of the samples. Analyses of the sandstones classed by grain size led to correct classification of 67 percent of the medium-grained sandstones, 83 percent of the fine-grained sandstones, and 91 percent of the very fine grained sandstones. The discriminantfunction method was adopted to classify the depositional environment and stratigraphic position of test sandstone samples. Analyses of fine-grained and very fine grained sandstones resulted in correct classification of 84 percent of the test samples to their depositional setting and stratigraphic position. The best discrimination is offered by analyses of fine-grained sandstones, which resulted in correct classification of 88 percent of the samples. Thus, this statistical method can be adopted as a powerful tool for exploration programs that concern delineation of genetically similar sandstones.
Kentucky, Virginia↗
Ore mineralization in the Mofete and San Vito geothermal fields, Campi Flegrei volcanic complex, Naples, Italy
The Mofete and San Vito geothermal fields, located west of Naples, Italy, are part of the Campi Flegrei volcanic complex. In the 1970s, exploratory wells were drilled to a depth of ~3000 m in an attempt to locate high-enthalpy fluids for potential power production. Drill core samples from Mofete wells (MF1, MF2, and MF5) and from San Vito wells (SV1 and SV3) contain authigenic ore mineralization. Pyrite, pyrrhotite, and galena are abundant. Less common are chalcopyrite, sphalerite, arsenopyrite, and scheelite; rare are millerite, violarite, native bismuth, tellurobismuthite, cassiterite, molybdenite, and acanthite. Mineral chemistry was determined by electron microprobe wavelength dispersive spectroscopy aided by a scanning electron microscope equipped with energy-dispersive spectroscopy. The mineral assemblage suggests a low sulfidation environment and the absence of pyrrhotite in the MF1 well and upper part of the SV1 well indicates variable sulfur activity. Both molybdenite and scheelite were identified in samples SV1–2860 and SV3–2353 and scheelite in the SV3 well is zoned with variable Mo 6+ content; low Mo 6+ zones show blue cathodoluminescence, whereas, zones with high Mo 6+ content are yellow to brown. Zoned scheelite and the occurrence of both Mo-bearing minerals attest to the variability of ƒO 2 and ƒS 2 in the geothermal fluid.
Naples↗
Clay mineral formation and transformation in rocks and soils
Three mechanisms for clay mineral formation (inheritance, neoformation, and transformation) operating in three geological environments (weathering, sedimentary, and diagenetic-hydrothermal) yield nine possibilities for the origin of clay minerals in nature. Several of these possibilities are discussed in terms of the rock cycle. The mineralogy of clays neoformed in the weathering environment is a function of solution chemistry, with the most dilute solutions favoring formation of the least soluble clays. After erosion and transportation, these clays may be deposited on the ocean floor in a lateral sequence that depends on floccule size. Clays undergo little reaction in the ocean, except for ion exchange and the neoformation of smectite; therefore, most clays found on the ocean floor are inherited from adjacent continents. Upon burial and heating, however, dioctahedral smectite reacts in the diagenetic environment to yield mixed-layer illite-smectite, and finally illite. With uplift and weathering, the cycle begins again. Refs.
Philosophical Transactions of the Royal Society A:↗
Spontaneous combustion of metal sulfide minerals and implications for seafloor massive sulfide mining
Metal sulfide minerals are abundant phases in many environments on earth, including seafloor massive sulfide (SMS) deposits, which occur at hydrothermal vents throughout the global ocean. These deep-sea settings are currently undergoing exploration for potential future mining. Here, we describe rocks from Escanaba Trough on the southern Gorda Ridge that underwent spontaneous combustion during laboratory processing. We compared the mineralogy, composition, and thermogravimetric behavior of the combusting samples to rocks from the same location that did not combust. We then used thermodynamic analyses to evaluate the exothermic nature of different metal sulfide oxidation reactions. The combusting rocks are primarily composed of nanocrystalline marcasite pseudomorphing blades of primary pyrrhotite. These altered, nanocrystalline rocks are less stable than their primary predecessors. Typically, recrystallization decreases reactivity as minerals trend towards steady state; however, both of the combusting samples we characterized are secondary, and demonstrate the instability of this metastable intermediate phase. Further, thermodynamic calculations indicate that metal sulfide oxidation is more exothermic when oxygen serves as the oxidant, as occurs in seawater or air. The distinct mineralogy, texture, and setting of SMS deposits in the modern oceans thus suggests a greater potential for self-heating in comparison to their ancient analogues.
Scientific Reports↗
Experimental and simulation studies of iron oxides for geochemical fixation of CO2-SO2 gas mixtures
Iron-bearing minerals are reactive phases of the subsurface environment and could potentially trap CO 2 –SO 2 gas mixtures derived from fossil fuel combustion processes by their conversion to siderite (FeCO 3 ) and dissolved sulfate. Changes in fluid and mineral compositions resulting from reactions, involving the co-injection of SO 2 with CO 2 were observed both theoretically and experimentally. Experiments were conducted with a natural hematite (α-Fe 2 O 3 ) sample. A high pressure-high temperature apparatus was used to simulate conditions in geologic formations deeper than 800 m, where CO 2 is in the supercritical state. Solid samples were allowed to react with a NaCl–NaOH brine and SO 2 -bearing CO 2 -dominated gas mixtures. The predicted equilibrium mineral assemblage at 100 °C and 250 bar became hematite, dawsonite (NaAl(OH) 2 CO 3 ), siderite (FeCO 3 ) and quartz (SiO 2 ). Experimentally, siderite and dawsonite, derived from the presence of kaolinite (Al 2 Si 2 O 5 (OH) 4 ) in the parent material, were present in residual solids at longer reaction time intervals, which agreed well with results from the modelling work.
Energy Procedia↗
Blood mineral concentrations in manatees ( Trichechus manatus latirostris and Trichechus manatus manatus )
Limited information is available regarding the role of minerals and heavy metals in the morbidity and mortality of manatees. Whole-blood and serum mineral concentrations were evaluated in apparently healthy, free-ranging Florida ( Trichechus manatus latirostris , n = 31) and Belize ( Trichechus manatus manatus , n = 14) manatees. Toxicologic statuses of the animals and of their environment had not been previously determined. Mean mineral whole-blood (WB) and serum values in Florida (FL) and Belize (BZ) manatees were determined, and evaluated for differences with respect to geographic location, relative age, and sex. Mean WB and serum silver, boron, cobalt, magnesium, molybdenum, and WB cadmium concentrations were significantly higher in BZ versus FL manatees ( P ≤ 0.05). Mean WB aluminum, calcium, manganese, sodium, phosphorus, vanadium, and serum zinc concentrations were significantly lower in BZ versus FL manatees. Adult manatees had significant and higher mean WB aluminum, manganese, sodium, antimony, vanadium, and serum manganese and zinc concentrations compared to juvenile animals. Significant and lower mean WB and serum silver, boron, cobalt, and serum copper and strontium concentrations were present in adults compared to juveniles ( P ≤ 0.05). Females had significant and higher mean WB nickel and serum barium compared to males ( P ≤ 0.05). Mean WB arsenic and zinc, and mean serum iron, magnesium, and zinc concentrations fell within toxic ranges reported for domestic species. Results reveal manatee blood mineral concentrations differ with location, age, and sex. Influence from diet, sediment, water, and anthropogenic sources on manatee mineral concentration warrant further investigation.
Journal of Zoo and Wildlife Medicine↗
Geochemistry of rare earth elements in Permian coals from the Huaibei Coalfield, China
The rare earth elements (REEs) in coals are important because of: (a) REE patterns can be an indicator of the nature of source rocks of the mineral matter as well as sedimentary environments; (b) REEs abundance in coal may have industrial-significance. In this study, a total of thirty-four samples of Permian coal, partings, roof, and floor were collected from the Huaibei Coalfield, Anhui Province, China. Abundances of rare earth elements (REEs) and other elements in the samples were determined by inductively coupled-plasma mass spectrometry (ICP-MS) and inductively coupled-plasma atomic emission spectrometry (ICP-AES). The results show that the REEs are enriched in coals in the Huaibei Coalfield as compared with Chinese and U.S. coals and the world coal average. Coals in the Lower Shihezi Formation (No. 7, 5, and 4 Coals) and Upper Shihezi Formation (No. 3) have higher REE abundances than the coals in Shanxi Formation (No. 10). Magmatic intrusion resulted in high enrichment of REEs concentrations in No. 5 and 7 Coals. The REE abundances are positively correlated with the ash content. The mineral matter in these coals is mainly made up of clay minerals and carbonates. The REEs are positively correlated with lithophile elements including Si, Al, Ti, Fe, and Na, which are mainly distributed in clay minerals, indicating that REEs are contained mainly in clay minerals. The REE abundances in coals normalized by the ash are higher than that in partings. REEs abundances of coals cannot be accounted for by the REE content in the mineral matter, and some REEs associated with organic matter in coals. ?? 2007 Elsevier Ltd. All rights reserved.
Journal of Asian Earth Sciences↗
Diverging mineral chemistry of iron and nickel throughout Earth’s changing redox conditions reveals foundation for their evolution as protein cofactors
Iron (Fe) and nickel (Ni) were both foundational to early metabolism, yet their biological trajectories diverged as Earth’s surface redox state changed. Here, we integrate mineral chemistry network analysis, protein metal-site coordination-sphere analysis, and curated redox comparisons to test how geochemistry and metalloprotein architecture co-evolved. Mineral network analyses show broader electronegativity variation and network diversity for Fe-bearing minerals through time relative to Ni-bearing minerals. In structural analyses of protein metal centers in a combined Fe/Ni protein structure set, it is shown that Fe- and Ni-associated environments differ in amino-acid composition, hydropathy structure, and cysteine representation. The greater chemical diversity and electronegativity variation in Fe minerals mirror the higher redox and structural versatility of Fe-binding proteins. The presence of Fe in a broader range of mineral and protein environments demonstrates the chemical adaptability of the metal, from the anoxic Archean to oxidative Earth surface conditions following the Great Oxidation Event. Iron, with its broad redox potential range in Fe-oxidoreductases, has a central role in both anaerobic and aerobic metabolisms. Nickel, by contrast, is less widespread in biology. Today, Ni is predominantly employed in deeply branching anaerobic pathways and by proteins with narrower redox potential ranges. Our results show that evolutionary processes, constrained by metal chemistry, habitually utilize Fe as a redox generalist while retaining Ni in specialized roles. The divergent paths of Ni and Fe, from rocks to proteins, demonstrate the intimate relationship between planetary geochemistry and metabolic origins on Earth and suggest that Fe/Ni geochemistry may inform habitability assessments in extraterrestrial environments when interpreted within specific planetary environmental contexts.
Life↗
Extraction of in situ cosmogenic 14C from olivine
Chemical pretreatment and extraction techniques have been developed previously to extract in situ cosmogenic radiocarbon (in situ 14C) from quartz and carbonate. These minerals can be found in most environments on Earth, but are usually absent from mafic terrains. To fill this gap, we conducted numerous experiments aimed at extracting in situ 14C from olivine ((Fe,Mg)2SiO4). We were able to extract a stable and reproducible in situ 14C component from olivine using stepped heating and a lithium metaborate (LiBO2) flux, following treatment with dilute HNO3 over a variety of experimental conditions. However, measured concentrations for samples from the Tabernacle Hill basalt flow (17.3 ?? 0.3 ka4) in central Utah and the McCarty's basalt flow (3.0 ?? 0.2 ka) in western New Mexico were significantly lower than expected based on exposure of olivine in our samples to cosmic rays at each site. The source of the discrepancy is not clear. We speculate that in situ 14C atoms may not have been released from Mg-rich crystal lattices (the olivine composition at both sites was ~Fo65Fa35). Alternatively, a portion of the 14C atoms released from the olivine grains may have become trapped in synthetic spinel-like minerals that were created in the olivine-flux mixture during the extraction process, or were simply retained in the mixture itself. Regardless, the magnitude of the discrepancy appears to be inversely proportional to the Fe/(Fe+Mg) ratio of the olivine separates. If we apply a simple correction factor based on the chemical composition of the separates, then corrected in situ 14C concentrations are similar to theoretical values at both sites. At this time, we do not know if this agreement is fortuitous or real. Future research should include measurement of in situ 14C concentrations in olivine from known-age basalt flows with different chemical compositions (i.e. more Fe-rich) to determine if this correction is robust for all olivine-bearing rocks. ?? 2010 by the Arizona Board of Regents on behalf of the University of Arizona.
Radiocarbon↗
Environment of ore deposition in the creede mining district, San Juan Mountains, Colorado: Part V. Epithermal mineralization from fluid mixing in the OH vein
Detailed fluid inclusion studies on coarse-grained sphalerite from the OH vein, Creede, Colorado, have shown that the abrupt color changes between growth zones correspond to abrupt changes in the nature of the ore fluids. Within each growth zone, however, the composition of the fluids remained constant. The base of a distinctive orange-brown growth zone marks a sharp increase in both temperature and salinity relative to the preceding yellow-white zone. The orange-brown growth zone can be correlated along much of the vein and is believed to represent a time-stratigraphic interval. Along the vein, temperatures and salinities of fluid inclusions within this interval show a systematic decrease from about 285??C and 11.5 wt percent NaCl equiv near the base of the vein to about 250??C and 8 wt percent NaCl equiv, respectively, near the top of the vein. The iron concentration of this sphalerite growth zone shows a similar pattern, decreasing from about 2.8 to 1.2 mole percent FeS. When plotted on an enthalpy-salinity diagram, the fluid inclusion data define a spatial trend indicating the progressive mixing of deeply circulating hydrothermal brines with overlying, dilute ground waters. The hydrothermal brines entered the OH vein from below at a temperature, salinity, and density of approximately 285??C, 11.5 wt percent NaCl equiv, and 860 kg/m3, respectively, whereas the overlying ground waters appear to have been preheated to roughly 150??C and had an assumed salinity of 0 wt percent and a density of 920 kg/m3. The greater density of the heated ground water promoted mixing with the hydrothermal brine within the open fractures, causing sphalerite deposition. Although there were also episodes of boiling during vein mineralization, boiling appears unimportant for this sphalerite. Isotopic evidence and geochemical modeling studies also indicate that mixing was the depositional mechanism for sphalerite. An important aspect of the mixing hydrology of the Creede system involves an aquitard overlying the OH vein. This low permeability zone restricted the flow of ground water into the vein from above and forced the upwelling hydrothermal fluids to flow laterally along the vein. The mixing environment thus occurred along the interface between a deeply circulating hydrothermal convection cell and a topographically driven shallow ground-water system.
Economic Geology↗
Mineralogy and environmental geochemistry of historical iron slag, Hopewell Furnace National Historic Site, Pennsylvania, USA
The Hopewell Furnace National Historic Site in southeastern Pennsylvania, which features an Fe smelter that was operational in the 18th and 19th centuries, is dominated by three slag piles. Pile 1 slag, from the Hopewell Furnace, and pile 2 slag, likely from the nearby Cornwall Furnace, were both produced in cold-blast charcoal-fired smelters. In contrast, pile 3 slag was produced in an anthracite furnace. Ore samples from the nearby Jones and Hopewell mines that fed the smelter are mainly magnetite-rich with some sulfides (pyrite, chalcopyrite, sphalerite) and accessory silicates (quartz, garnet, feldspar, and clay minerals). Slag piles 1 and 2 are similar mineralogically containing predominantly skeletal and dendritic aluminian diopside and augite, skeletal forsteritic olivine, glass, rounded blebs of metallic Fe, and exotic quartz. Olivine is a major phase in all samples from pile 2, whereas it occurs in only a few samples from pile 1. Samples of the <2 mm-size fraction of surface composite slag material or crushed slag from at depth in piles 1 and 2 are mineralogically similar to the large surface slag fragments from those piles with the addition of phases such as feldspars, Fe oxides, and clay minerals that are either secondary weathering products or entrained from the underlying bedrock. Pile 3 slag contains mostly skeletal forsteritic olivine and Ti-bearing aluminian diopside, dendritic or fine-grained subhedral melilite, glass, euhedral spinel, metallic Fe, alabandite–oldhamite solid solution, as well as a sparse Ti carbonitride phase. The bulk chemistry of the slag is dominated by Al 2 O 3 (8.5–16.2 wt.%), CaO (8.2–26.2 wt.%), MgO (4.2–24.7 wt.%), and SiO 2 (36.4–59.8 wt.%), constituting between 81% and 97% of the mass of the samples. Piles 1 and 2 are chemically similar; pile 1 slag overall contains the highest Fe 2 O 3 , K 2 O and MnO, and the lowest MgO concentrations. Pile 3 slag is high in Al 2 O 3 , CaO and S, and low in Fe 2 O 3 , K 2 O and SiO 2 compared to the other piles. In general, piles 1 and 2 are chemically similar to each other, whereas pile 3 is distinct – a conclusion that reflects their mineralogy. The similarities and differences among piles in terms of mineralogy and major element chemistry result from the different smelting conditions under which the slag formed and include the fuel source, the composition of the ore and flux, the type of blast (cold versus hot), which affects the furnace temperature, and other beneficiation methods. The three distinct slag piles at Hopewell are enriched in numerous trace elements, such as As (up to 12 mg/kg), Cd (up to 0.4 mg/kg), Co (up to 31.8 mg/kg), Cu (up to 647 mg/kg), Mn (up to 0.69 wt.%), Pb (up to 172 mg/kg) and Zn (up to 393 mg/kg), together with Fe (13.9 wt.%), when compared to the average for the continental crust, with the <2 mm-size fraction commonly containing the highest concentrations. Enrichments in various elements (e.g., Cd, Co, Cu, Pb, Zn) were also found in the ore samples. Despite these enrichments, comparison of bulk chemistry trace-element concentrations to the environmental guidelines suggests most elements are likely not problematic with the exception of As, Co, Fe and Mn. Leachate tests that simulate weathering indicate Fe (up to 973 μg/L) and Mn (up to 133 μg/L) are readily released in potentially harmful concentrations compared to secondary drinking water and some aquatic ecosystem toxicity criteria. Aluminum and Cu, although not high in the solid compared to environmental guidelines, also exceed relevant criteria in leachate extracts with maximum concentrations of 2700 μg/L and 17.7 μg/L, respectively. In contrast, As and Co, which are significant in the solids, are not leached in concentrations that exceed guidelines (i.e., 3 μg/L or less for both elements). The weathering rates of the Fe metal and Fe oxides, which host Cu and some Fe, are likely higher than the silicate glass, which hosts the majority of Al, Mn and some Fe, and the crystalline silicates and spinels affecting which elements and how much are released into the environment and surrounding aquatic ecosystem. The mineral assemblages and their chemical composition, the bulk sample chemistry, and leachability of trace elements are all important components in understanding the potential environmental impacts of the slag piles.
Pennsylvania↗
Platinum and associated elements at the New Rambler mine and vicinity, Albany and Carbon Counties, Wyoming
Platinum-group metals in the Medicine Bow Mountains were first identified by W. C. Knight in 1901. In the Medicine Bow Mountains, these metals are commonly associated with copper, silver, or gold in shear zones that cut a series of mafic igneous and metamorphic rocks. At the New Rambler mine, where the initial discovery was made, about 50,000 tons of mine and mill waste contain an average of 0.3 percent copper, 7 ppm (parts per million) silver, 1 ppm platinum plus palladium, and 0.7 ppm gold. This material is believed to be from a low-grade envelope around the high-grade pod of complex ore that was mined selectively in the old workings. Soil samples in the vicinity of the New Rambler mine exhibit a wide range of content of several elements associated with the ore. Most of the variation can be attributed to contamination, from the mine workings. Even though soil samples identify a low-level copper anomaly that persists to the limit of the area sampled, soils do not offer a promising medium for tracing mineralization owing to the blanket of transported overburden. Stream sediments, if preconcentrated for analysis, do reveal anomalies not only in the contaminated stream below the New Rambler mine, but in adjacent drainage and on Dave Creek. Examination of a spectrum of elements in heavy-mineral concentrates from stream sediment may contribute to knowledge of the nature of the mineralization and of the basic geology of the environment. The sampling of bedrock exposures is not particularly fruitful because outcrops are sparse and the exposed rocks are the least altered and mineralized. Bedrock sampling does, however, provide information on the large size and provincial nature of the platinum-rich area. We feel that a properly integrated program of geological, geophysical, and geochemical exploration in the Medicine Bow Mountains and probably in the Sierra Madre to the west has a reasonable probability of successfully locating a complex ore body.
Circular↗
Regional investigations of soil and overburden analysis and plant uptake of metals
Regional studies on the bioavailability of metals at native and disturbed sites were conducted over the past seven years by the USGS. The work was concentrated in the Fort Union, Powder River, and Green River coal resource regions where measures of extractable metals in soils were found to have limited use in predicting metal levels in plants. Correlations between Cu, Fe, and Zn in plants and extractable (DTPA, EDTA, and oxalate) or total levels in native A- and C-horizons of soil were occasionally significant. A simple linear model is generally not adequate, however, in estimating element uptake by plants. Prediction capabilities were improved when a number of soil chemical and physical parameters were included as independent variables in a stepwise linear multiple regression analysis; however, never more than 54% of the total variability in the data was explained by the equations for these metals. Soil pH was the most important variable relating soil chemistry to plant chemistry. This relation was always positive and apparently a response to soil levels of metal carbonates and not Fe and Mn oxides. Studies that compared the metal uptake by rehabilitation species to extractable (DTPA) metal levels in mice soils produced similar results. ?? 1984 Science and Technology Letters.
Minerals and the Environment↗