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At least 145 records · Page 8Linked to original sources

Polycrystalline methane hydrate: Synthesis from superheated ice, and low-temperature mechanical properties

We describe a new and efficient technique to grow aggregates of pure methane hydrate in quantities suitable for physical and material properties testing. Test specimens were grown under static conditions by combining cold, pressurized CH 4 gas with granulated H 2 O ice, and then warming the reactants to promote the reaction CH 4 (g) + 6H 2 O(s→l) → CH 4 ·6H 2 O (methane hydrate). Hydrate formation evidently occurs at the nascent ice/liquid water interface on ice grain surfaces, and complete reaction was achieved by warming the system above the ice melting point and up to 290 K, at 25−30 MPa, for approximately 8 h. The resulting material is pure, cohesive, polycrystalline methane hydrate with controlled grain size and random orientation. Synthesis conditions placed the H 2 O ice well above its melting temperature while reaction progressed, yet samples and run records showed no evidence for bulk melting of the unreacted portions of ice grains. Control experiments using Ne, a non-hydrate-forming gas, showed that under otherwise identical conditions, the pressure reduction and latent heat associated with ice melting are easily detectable in our fabrication apparatus. These results suggest that under hydrate-forming conditions, H 2 O ice can persist metastably to temperatures well above its ordinary melting point while reacting to form hydrate. Direct observations of the hydrate growth process in a small, high-pressure optical cell verified these conclusions and revealed additional details of the hydrate growth process. Methane hydrate samples were then tested in constant-strain-rate deformation experiments at T = 140−200 K, P c = 50−100 MPa, and ε = 10 - 4 −10 - 6 s - 1 . Measurements in both the brittle and ductile fields showed that methane hydrate has measurably different strength than H 2 O ice, and work hardens to an unusually high degree compared to other ices as well as to most metals and ceramics at high homologous temperatures. This work hardening may be related to a changing stoichiometry under pressure during plastic deformation; X-ray analyses showed that methane hydrate undergoes a process of solid-state disproportionation or exsolution during deformation at conditions well within its conventional stability field.

Energy and Fuels↗

Post-Wildfire Sedimentation in Saguaro National Park, Rincon Mountain District, and Effects on Lowland Leopard Frog Habitat

The Rincon Mountain District of Saguaro National Park occupies about 272 square kilometers of mountains, canyons, and alluvial fans in southeastern Arizona just east of Tucson. The park contains some of the last remaining habitat in the Tucson Basin of the lowland leopard frog that lives in the bedrock pools called tinajas in canyons at elevations between 850 and 1,800 meters. Those tinajas that contain water year-round are critical winter habitat for tadpoles, and the breeding success of the leopard frogs depends on these features. In recent years, many tinajas that previously had provided habitat for the leopard frogs have been buried beneath large volumes of coarse sandy gravel that resulted from severe, stand-replacing wildfires in the watersheds above them. The U. S. Geological Survey in cooperation with the National Park Service, conducted a study in 2004-06 to determine critical sediment-source areas, and the mechanisms of sediment delivery from hillslopes to stream channels to areas of leopard frog habitat and to estimate the increase in rates of sedimentation resulting from wildfires. Spatial data of watershed characteristics, as well as historical data, including photographs, monitoring surveys, precipitation and stream discharge records, were used in conjunction with field observations conducted between spring 2004 and fall 2005. The Helens II fire in 2003, the fifth largest wildfire to burn in the Rincon Mountains since 1989, offered an opportunity to observe mechanisms of sediment erosion, transport, and deposition in the immediate post-fire environment. Reduction of the forest canopy, understory vegetation, and organic litter on the ground surface in severe burn areas caused increased surface runoff in the Joaquin Canyon watershed that led to intensified erosion of hillslopes. An initial flush of fine material, mostly ash, was transported to lower channel reaches with the first significant precipitation event following the fire. Subsequently, the main erosional mechanisms were rainsplash and sheetwash that delivered high sediment loads to headwater tributaries. The increased runoff also led to scouring of the headwater tributaries and the downstream transport of a sediment slug by a series of episodic debris flows or hyperconcentrated flows. The sediment slug, following intense summer precipitation, moved downstream several hundred meters at a time. Sediment was remobilized during subsequent periods of runoff. As of fall 2005, sediment had traveled 3.3 km downstream from the nearest burn area margin and had buried several tinajas in as much as a meter of sediment. Sediment continued to overwhelm the transport capacity of the channel even as the hillslopes in the burn area were showing evidence of recovery. The sedimentation history and effects on leopard frog habitat in other channels in the Rincon Mountains was evaluated by analyzing observations made by Saguaro National Park staff during monitoring surveys of leopard frog populations. The best record of post-wildfire sediment deposition was that of Loma Verde Wash in which the filling of all tinajas in the two years after the 1999 Box Canyon fire was recorded. Monitoring of leopard frog populations in Wildhorse Canyon appeared to reflect the lingering effects of heavy sedimentation related to the 1989 Chiva fire. Populations appear to be recovering in the upper tinajas, which were mainly free of sediment, but sightings of frogs were sparse in the lower tinajas that still contained high volumes of sediment. In Madrona Canyon, leopard frog sightings were sparse, possibly indicating that habitat had been detrimentally affected by the Rincon fire of 1994. Based on rates of filling of tinajas in Joaquin Canyon and Loma Verde Wash, minimum estimated rates of sediment yield from burn areas ranged from 425 to 1,960 kg ha-1. The residence time of sediment in tinajas was found to be highly variable. Tinajas in Loma Verde Wash that were buried following the

Scientific Investigations Report↗

Compositional analyses of small lunar pyroclastic deposits using Clementine multispectral data

Clementine ultraviolet-visible (UVVIS) data are used to examine the compositions of 18 pyroclastic deposits (15 small, three large) at 13 sites on the Moon. Compositional variations among pyroclastic deposits largely result from differing amounts of new basaltic (or juvenile) material and reworked local material entrained in their ejecta upon eruption. Characterization of pyroclastic deposit compositions allows us to understand the mechanisms of lunar explosive volcanism. Evidence for compositional differences between small pyroclastic deposits at a single site is observed at Atlas crater. At all sites, compositional variation among the small pyroclastic deposits is consistent with earlier classification based on Earth-based spectra: three compositional groups can be observed, and the trend of increasing mafic absorption band strength from Group 1 to Group 2 to Group 3 is noted. As redefined here, Group 1 deposits include those of Alphonsus West, Alphonsus Southeast, Alphonsus Northeast 2, Atlas South, Crüger, Franklin, Grimaldi, Lavoisier, Oppenheimer, Orientale, and Riccioli. Group 1 deposits resemble lunar highlands, with weak mafic bands and relatively high UV/VIS ratios. Group 2 deposits include those of Alphonsus Northeast 1, Atlas North, Eastern Frigoris East and West, and Aristarchus Plateau; Group 2 deposits are similar to mature lunar maria, with moderate mafic band depths and intermediate UV/VIS ratios. The single Group 3 deposit, J. Herschel, has a relatively strong mafic band and a low UV/VIS ratio, and olivine is a likely juvenile component. Two of the deposits in these groups, Orientale and Aristarchus, are large pyroclastic deposits. The third large pyroclastic deposit, Apollo 17/Taurus Littrow, has a very weak mafic band and a high UV/VIS ratio and it does not belong to any of the compositional groups for small pyroclastic deposits. The observed compositional variations indicate that highland and mare materials are also present in many large and small pyroclastic deposits, and they suggest that volcanic glasses or spheres may not be dominant juvenile components in all large pyroclastic deposits.

Journal of Geophysical Research E: Planets↗

Ridges and scarps in the equatorial belt of Mars

The morphology and distribution of ridges and scarps on Mars in the ± 30° latitude belt were investigated. Two distinct types of ridges were recognized. The first is long and linear, resembling mare ridges on the Moon; it occurs mostly in plains areas. The other is composed of short, anastomosing segments and occurs mostly in ancient cratered terrain and intervening plateaus. Where ridges are eroded, landscape configurations suggest that they are located along regional structures. The age of ridges is uncertain, but some are as young as the latest documented volcanic activity on Mars. The origins of ridges are probably diverse-they may result from wrinkling due to compression or from buckling due to settling over subsurface structures. The similar morphologic expressions of ridge types of various origins may be related to a similar deformation mechanism caused by two main factors: (1) most ridges are developed in thick layers of competent material and (2) ridges formed under stresses near a free surface.

The Moon and the Planets↗

Origin of concretionary Mn-Fe-oxides in stream sediments of Maine, U.S.A.

Studies of stream and sediment-pore waters largely explain the genesis of concretionary Mn-Fe-oxides in Maine. Waters of two small streams near Jackman, Maine, were studied in terms of pH, Eh, dissolved oxygen, dissolved organic carbon, dissolved Mn, total dissolved Fe, and ferrous and ferric Fe. Pyrite Creek has profuse concretions and coatings of Mn-Fe-oxides, whereas West Pyrite Creek has only sparse Mn-Fe-oxide stains. Pyrite Creek drains boggy terrain and West Pyrite Creek drains well-drained terrain. In West Pyrite Creek, stream and subjacent pore waters have chemical characteristics that do not differ greatly. However, dissolved Mn, ferrous Fe, dissolved oxygen, and in situ Eh measurements show that a steep Eh gradient exists between stream and subjacent pore waters of Pyrite Creek. The steep Eh gradient is manifested by the common zonation of coatings and stains on rocks in stream sediment. The bottom zone has no deposition of oxides, the middle zone is red and consists mostly of Fe-oxides, and the upper zone is black or dark-brown and consists of Mn-oxides with varying amounts of Fe-oxides. The zonation agrees with theoretical predictions of oxide stability as one moves from a reducing to an oxidizing environment. At locations where concretionary Mn-Fe-oxides form, pore waters are depleted of oxygen because of abundant decaying organic material in the stream sediment. The pore waters are charged with dissolved Mn and Fe because mechanically deposited Mn-Fe-oxides are remobilized due to the low-Eh conditions. Groundwaters also contribute dissolved Mn and Fe. Stream waters, on the other hand, are oxygenated and the high-Eh conditions result in low concentrations of dissolved Mn and Fe in stream waters because of the insolubility of Mn-Fe-oxides in high-Eh environments. Therefore, concretionary Mn-Fe-oxides form at the interface between pore and stream waters because Mn- and Fe-rich pore waters, which are undersaturated with respect to Mn-Fe-oxides, mix with oxygen-rich stream waters, which are saturated with respect to Mn-Fe-oxides. ?? 1983.

Chemical Geology↗

Dome formation on Ceres by sold-state flow analogous to terrestrial salt tectonics

The dwarf planet Ceres’s outer crust is a complex, heterogeneous mixture of ice, clathrates, salts and silicates. Numerous large domes on Ceres’s surface indicate a degree of geological activity. These domes have been attributed to cryovolcanism, but that is difficult to reconcile with Ceres’s small size and lack of long-lived heat sources. Here we alternatively propose that Ceres’s domes form by solid-state flow within the compositionally heterogeneous crust, a mechanism directly analogous to salt tectonics on Earth. We use numerical simulations to illustrate that differential loading of a crust with compositional heterogeneity on a scale of tens of kilometres can produce dome-like features of scale similar to those observed. The mechanism requires the presence of low-viscosity and low-density, possibly ice-rich, material in the upper 1–10 km of the subsurface. Such substantial regional heterogeneity in Ceres’s crustal composition is consistent with observations from the National Aeronautics and Space Administration’s Dawn mission. We conclude that deformation analogous to that in terrestrial salt tectonics is a viable alternative explanation for the observed surface morphologies, and is consistent with Ceres being both cold and geologically active.

Nature Geoscience↗

Development of spatial data guidelines and standards: spatial data set documentation to support hydrologic analysis in the U.S. Geological Survey

Spatial data analysis has become an integral component in many surface and sub-surface hydrologic investigations within the U.S. Geological Survey (USGS). Currently, one of the largest costs in applying spatial data analysis is the cost of developing the needed spatial data. Therefore, guidelines and standards are required for the development of spatial data in order to allow for data sharing and reuse; this eliminates costly redevelopment. In order to attain this goal, the USGS is expanding efforts to identify guidelines and standards for the development of spatial data for hydrologic analysis. Because of the variety of project and database needs, the USGS has concentrated on developing standards for documenting spatial sets to aid in the assessment of data set quality and compatibility of different data sets. An interim data set documentation standard (1990) has been developed that provides a mechanism for associating a wide variety of information with a data set, including data about source material, data automation and editing procedures used, projection parameters, data statistics, descriptions of features and feature attributes, information on organizational contacts lists of operations performed on the data, and free-form comments and notes about the data, made at various times in the evolution of the data set. The interim data set documentation standard has been automated using a commercial geographic information system (GIS) and data set documentation software developed by the USGS. Where possible, USGS developed software is used to enter data into the data set documentation file automatically. The GIS software closely associates a data set with its data set documentation file; the documentation file is retained with the data set whenever it is modified, copied, or transferred to another computer system. The Water Resources Division of the USGS is continuing to develop spatial data and data processing standards, with emphasis on standards needed to support hydrologic analysis, hydrologic data processing, and publication of hydrologic thermatic maps. There is a need for the GIS vendor community to develop data set documentation tools similar to those developed by the USGS, or to incorporate USGS developed tools in their software.

Conference Paper↗

Fault growth and acoustic emissions in confined granite

The failure process in a brittle granite was studied by using acoustic emission techniques to obtain three dimensional locations of the microfracturing events. During a creep experiment the nucleation of faulting coincided with the onset of tertiary creep, but the development of the fault could not be followed because the failure occurred catastrophically. A technique has been developed that enables the failure process to be stabilized by controlling the axial stress to maintain a constant acoustic emission rate. As a result the post-failure stress-strain curve has been followed quasi-statically, extending to hours the fault growth process that normally would occur violently in a fraction of a second. The results from the rate-controlled experiments show that the fault plane nucleated at a point on the sample surface after the stress-strain curve reached its peak. Before nucleation, the microcrack growth was distributed throughout the sample. The fault plane then grew outward from the nucleation site and was accompanied by a gradual drop in stress. Acoustic emission locations showed that the fault propagated as a fracture front (process zone) with dimensions of 1 to 3 cm. As the fracture front passed by a given fixed point on the fault plane, the subsequent acoustic emission would drop. When growth was allowed to progress until the fault bisected the sample, the stress dropped to the frictional strength. These observations are in accord with the behavior predicted by Rudnicki and Rice's bifurcation analysis but conflict with experiments used to infer that shear localization would occur in brittle rock while the material is still hardening.

Applied Mechanics Reviews↗

The release of dissolved actinium to the ocean: A global comparison of different end-members

The measurement of short-lived 223Ra often involves a second measurement for supported activities, which represents 227Ac in the sample. Here we exploit this fact, presenting a set of 284 values on the oceanic distribution of 227Ac, which was collected when analyzing water samples for short-lived radium isotopes by the radium delayed coincidence counting system. The present work compiles 227Ac data from coastal regions all over the northern hemisphere, including values from ground water, from estuaries and lagoons, and from marine end-members. Deep-sea samples from a continental slope off Puerto Rico and from an active vent site near Hawaii complete the overview of 227Ac near its potential sources. The average 227Ac activities of nearshore marine end-members range from 0.4??dpm m- 3 at the Gulf of Mexico to 3.0??dpm m- 3 in the coastal waters of the Korean Strait. In analogy to 228Ra, we find the extension of adjacent shelf regions to play a substantial role for 227Ac activities, although less pronounced than for radium, due to its weaker shelf source. Based on previously published values, we calculate an open ocean 227Ac inventory of 1.35 * 1018??dpm 227Acex in the ocean, which corresponds to 37??moles, or 8.4??kg. This implies a flux of 127??dpm m-2 y- 1 from the deep-sea floor. For the shelf regions, we obtain a global inventory of 227Ac of 4.5 * 1015??dpm, which cannot be converted directly into a flux value, as the regional loss term of 227Ac to the open ocean would have to be included. Ac has so far been considered to behave similarly to Ra in the marine environment, with the exception of a strong Ac source in the deep-sea due to 231Paex. Here, we present evidence of geochemical differences between Ac, which is retained in a warm vent system, and Ra, which is readily released [Moore, W.S., Ussler, W. and Paull, C.K., 2008-this issue. Short-lived radium isotopes in the Hawaiian margin: Evidence for large fluid fluxes through the Puna Ridge. Marine Chemistry]. Another potential mechanism of producing deviations in 227Ac/228Ra and daughter isotope ratios from the expected production value of lithogenic material is observed at reducing environments, where enrichment in uranium may occur. The presented data here may serve as a reference for including 227Ac in circulation models, and the overview provides values for some end-members that contribute to the global Ac distribution. ?? 2007 Elsevier B.V. All rights reserved.

Marine Chemistry↗

Shock-wave-induced fracturing of calcareous nannofossils from the Chesapeake Bay impact crater

Fractured calcareous nannofossils of the genus Discoaster from synimpact sediments within the Chesapeake Bay impact crater demonstrate that other petrographic shock indicators exist for the cratering process in addition to quartz minerals. Evidence for shock-induced taphonomy includes marginal fracturing of rosette-shaped Discoaster species into pentagonal shapes and pressure- and temperature-induced dissolution of ray tips and edges of discoasters. Rotational deformation of individual crystallites may be the mechanism that produces the fracture pattern. Shock-wave-fractured calcareous nannofossils were recovered from synimpact matrix material representing tsunami or resurge sedimentation that followed impact. Samples taken from cohesive clasts within the crater rubble show no evidence of shock-induced fracturing. The data presented here support growing evidence that microfossils can be used to determine the intensity and timing of wet-impact cratering.

Geology↗

Rare earth element contents and multiple mantle sources of the transform-related Mount Edgecumbe basalts, southeastern Alaska

Pleistocene basalt of the Mount Edgecumbe volcanic field (MEF) is subdivided into a plagioclase type and an olivine type. Olivine basalt crops out farther inboard from the nearby Fairweather transform than plagioclase basalt. Th/La ratios of plagioclase basalt are similar to those of mid-ocean-ridge basalt (MORB), whereas those of olivine basalt are of continental affinity. The olivine basalt has higher 87 Sr/ 86 Sr ratios than the plagioclase basalt.We model rare earth element (REE) contents of the olivine basalt, which resemble those of transitional MORB, by 10–15% partial melting of fertile spinel–plagioclase lherzolite followed by removal of 8–13% olivine. Normative mineralogy indicates melting in the spinel stability field. REE contents of an undersaturated basalt (sample 5L005) resemble those of Mauna Loa tholeiite and are modelled by 5–10% partial melting of fertile garnet lherzolite followed by 10% olivine removal. Plagioclase basalt resembles sample 5L005 in REE contents but is lower in other incompatible-element contents and 87 Sr/ 86 Sr ratios. Plagioclase basalt either originated in depleted garnet lherzolite or is a mixture of sample 5L005 and normal MORB; complex zoning of plagioclase and colinear Sc and Th contents are consistent with magma mixing.We conclude that olivine basalt originated in subcontinental spinel lherzolite and that plagioclase basalt may have originated in suboceanic lithosphere of the Pacific plate. Lithospheric melting seemingly requires vertical flow of mantle material, although there is no direct evidence at the MEF for crustal extension that might provide a mechanism for mantle advection. In any case, most MEF magmas are subalkaline because of moderately high degrees of partial melting at shallow depth.

Alaska↗

Enhancing marsh elevation using sediment augmentation: A case study from southern California, USA

Tidal marshes are an important component of estuaries that provide habitat for fish and wildlife, protection from flooding, recreation opportunities, and can improve water quality. Critical to maintaining these functions is vertical accretion, a key mechanism by which tidal marshes build elevation relative to local sea level. The beneficial use of dredged material to build marsh elevations in response to accelerating sea level rise has gained attention as a management action to prevent habitat loss over the coming decades. In January 2016, a sediment augmentation project using local dredged material was undertaken at Seal Beach National Wildlife Refuge in Anaheim Bay, California, USA, to benefit tidal marsh habitat and the listed species it supports. The application process added 12,900 cubic meters of sediment with an initial, average 22-cm gain in elevation over a 3.2-hectare site. Due to sediment characteristics and higher than anticipated elevations in some areas, vegetation colonization did not occur at the expected rate; therefore, adaptive management measures were undertaken to improve hydrology of the site and facilitate vegetation colonization. More case studies that test and monitor sea level adaptation actions are needed to assist in the planning and implementation of climate-resilient projects to prevent coastal habitat loss over the coming century.

California↗

Rhodamine-WT dye losses in a mountain stream environment

A significant fraction of rhodamine WT dye was lost during a short term multitracer injection experiment in a mountain stream environment. The conservative anion chloride and the sorbing cation lithium were concurrently injected. In-stream rhodamine WT concentrations were as low as 45 percent of that expected, based on chloride data. Concentration data were available from shallow‘wells’dug near the stream course and from a seep of suspected return flow. Both rhodamine WT dye and lithium were nonconservative with respect to the conservative chloride, with rhodamine WT dye closely following the behavior of the sorbing lithium. Nonsorption and sorption mechanisms for rhodamine WT loss in a mountain stream were evaluated in laboratory experiments. Experiments evaluating nonsorption losses indicated minimal losses by such mechanisms. Laboratory experiments using sand and gravel size streambed sediments show an appreciable capacity for rhodamine WT sorption. The detection of tracers in the shallow wells and seep indicates interaction between the stream and the flow in the surrounding subsurface, intergravel water, system. The injected tracers had ample opportunity for intimate contact with materials shown in the laboratory experiments to be potentially sorptive. It is suggested that in the study stream system, interaction with streambed gravel was a significant mechanism for the attenuation of rhodamine WT dye (relative to chloride).

Journal of the American Water Resources Associatio↗

Use of an airborne Fraunhofer line discriminator for the detection of solar stimulated luminescence

Luminescence is the property of some materials to emit light when excited by external stimuli such as ultraviolet or visible light or by chemical or mechanical action. The Fraunhofer line discriminator (FLO) is an airborne electro-optical device which operates as a non-imaging radiometer and permits detection of solar stimulated luminescence several orders of magnitude below the intensity detectable with the human eye. A prototype FLO, used in 1969 to monitor the dynamic of water currents in the San Francisco area, was than 5 parts per Airborne tests o a redesigned FLO, featuring an order of magnitude improvement in sensitivity, permitted measurement of differences in the luminescence of trees containing geochemically anomalous concentrations of Colorado) and molybdenum (near Gardnerville, Nevada) trees growing in background areas nearby. In the tests near Denver, luminescence-contrast between stressed and non-stressed trees tended to be greater during periods when cloud cover was 10 percent or less; in most cases, contrast insignificant when cloud cover exceeded 10 percent. In other airborne test the FLO distinguished luminescing phosphate rock and gypsum from sands one and siltstone near Pine Mountain, California; dispersal of oil in a natural seep from uncontaminated sea water in the Santa Barbara Channel; cattle feed lot and municiple sewage effluents near Denver; and paper and phosphate processing effluents in eastern and central Florida. Procedures employing a laboratory fluorescence spectrometer permit prediction of the detectivity with an FLO prior to monitoring an airborne test. Luminescence spectra of the material are corrected for wavelength variation in spectrometer source, detector sensitivity, and solar illumination. By comparing these results with the luminescence of a rhodamine WT dye standard, the luminescence .of the material may be expressed in terms of rhodamine dye equivalency at the wavelength of several Fraunhofer lines. The FLO detectivity may be assessed at each Fraunhofer line, and the optimum line for field observation of the material may be selected. Future work will include the integration of the FLO with a line scan imaging system in order to assess the contribution of two-dimensional spatial resolution to the interpretability and usefulness of luminescence data. It should also include 1) investigation of luminescence polarization of some materials, particularly metal stressed plants, 2) an assessment of the use of pulsed lasers to stimulate phosphorescence decay time in the nanosecond and microsecond ranges; and 3) a study to determine the feasibility of conducting an FLO experiment from the Space Shuttle or other spacecraft.

Open-File Report↗

A temporal look at the influence of topographic amplification on earthquake-triggered landslides in 3D seismic simulations

Earthquakes are a primary trigger for landslides, often leading to catastrophic consequences. While numerous studies have explored the spatial distribution of earthquake-triggered landslides, understanding the interaction between seismic waves and topography remains a critical challenge. Topographic irregularities can cause seismic wave amplification, altering ground shaking, and can trigger landslides that are challenging for predictive models to anticipate. This study investigates the spatial and temporal evolution of topographically amplified landslides, focusing on coseismic landslides triggered by the Mw 7.5 mainshock of the 2018 Papua New Guinea earthquake and post-seismic landslides associated with its four aftershocks, each exceeding Mw 6.0. We employ low-frequency, three-dimensional numerical ground shaking simulations and data-driven multivariate analyses to examine how landslides evolved from the coseismic to post-seismic periods. Our findings reveal a spatial shift in landslide distribution, in which the mainshock triggered slope failures predominantly on steep hillslopes, and the aftershocks triggered landslides on gentler slopes, often near geologic boundaries. We attribute this transition partly to the earthquake legacy effect of the mainshock, where the mainshock caused weakening of these hillslopes, making them more prone to failure when aftershocks occur. Additionally, the concentration of failures along geologic contacts in the post-seismic phase suggests that site amplification, stemming from contrasts in subsurface materials, exerts a key influence on landslide occurrence. Although not explicitly captured in our current numerical simulations, this mechanism warrants further investigation for more accurate hazard modeling.

JGR Solid Earth↗

Slope basins, headless canyons, and submarine palaeoseismology of the Cascadia accretionary complex

A combination of geomorphological, seismic reflection and geotechnical data constrains this study of sediment erosion and deposition at the toe of the Cascadia accretionary prism. We conducted a series of ALVIN dives in a region south of Astoria Canyon to examine the interrelationship of fluid flow and slope failure in a series of headless submarine canyons. Elevated head gradients at the inflection point of canyons have been inferred to assist in localized failures that feed sediment into a closed slope basin. Measured head gradients are an order of magnitude too low to cause seepage-induced slope failure alone; we therefore propose transient slope failure mechanisms. Intercanyon slopes are uniformly unscarred and smooth, although consolidation tests indicate that up to several metres of material may have been removed. A sheet-like failure would remove sediment uniformly, preserving the observed smooth intercanyon slope. Earthquake-induced liquefaction is a likely trigger for this type of sheet failure as the slope is too steep and short for sediment flow to organize itself into channels. Bathymetric and seismic reflection data suggest sediment in a trench slope basin between the second and third ridges from the prism’s deformation is derived locally. A comparison of the amounts of material removed from the slopes and that in the basin shows that the amount of material removed from the slopes may slightly exceed the amount of material in the basin, implying that a small amount of sediment has escaped the basin, perhaps when the second ridge was too low to form a sufficient dam, or through a gap in the second ridge to the south. Regardless, almost 80% of the material shed off the slopes around the basin is deposited locally, whereas the remaining 20% is redeposited on the incoming section and will be re-accreted.

Oregon↗

Coeur d'Alene Lake, Idaho: Insights gained From limnological studies of 1991-92 and 2004-06

More than 100 years of mining and processing of metal-rich ores in northern Idaho’s Coeur d’Alene River basin have resulted in widespread metal contamination of the basin’s soil, sediment, water, and biota, including Coeur d’Alene Lake. Previous studies reported that about 85 percent of the bottom of Coeur d’Alene Lake is substantially enriched in antimony, arsenic, cadmium, copper, lead, mercury, silver, and zinc. Nutrients in the lake also are a major concern because they can change the lake’s trophic status—or level of biological productivity—which could result in secondary releases of metals from contaminated lakebed sediments. This report presents insights into the limnological functioning of Coeur d’Alene Lake based on information gathered during two large-scale limnological studies conducted during calendar years 1991–92 and water years 2004–06. Both limnological studies reported that longitudinal gradients exist from north to south for decreasing water column transparency, loss of dissolved oxygen, and increasing total phosphorus concentrations. Gradients also exist for total lead, total zinc, and hypolimnetic dissolved oxygen concentrations, ranging from high concentrations in the central part of the lake to lower concentrations at the northern and southern ends of the lake. In the southern end of the lake, seasonal anoxia serves as a mechanism to release dissolved constituents such as phosphorus, nitrogen, iron, and manganese from lakebed sediments and from detrital material within the water column. Nonparametric statistical hypothesis tests at a significance level of α=0.05 were used to compare analyte concentrations among stations, between lake zones, and between study periods. The highest dissolved oxygen concentrations were measured in winter in association with minimum water temperatures, and the lowest concentrations were measured in the Coeur d’Alene Lake hypolimnion during late summer or autumn as prolonged thermal stratification restricted mixing of the oxygenated upper water column and the hypolimnion, where oxygen was consumed. Large differences in median concentrations of dissolved inorganic nitrogen were measured between the euphotic zone and hypolimnion in the deep areas of the lake. These differences in nitrogen concentrations were attributable to several limnological processes, including seasonal inflow plume routing, isolation from wind-driven circulation and associated hypolimnetic enrichment, phytoplanktonic assimilation during summer months, and benthic flux. Increased chlorophyll- a and total phosphorus concentrations were measured throughout the lake in the 2004–06 study compared with results from the 1991–92 study. No significant change in hypolimnetic dissolved inorganic nitrogen concentration throughout the lake was noted even though total nitrogen loads into the lake decreased between study periods. Total zinc and total lead decreased throughout the lake from the 1991-92 study to the 2004-06 study except in the southern part of the lake, where concentrations were typically low. Median detected nitrogen-to-phosphorus ratios decreased from the 1991–92 study to the 2004–06 study. Whereas the lake was clearly phosphorus-limited in 1991–92, in 2004–06 the lake may have been much closer to the boundary value of 7.2 that separates nitrogen from phosphorus limitation. However, due to changes in analytical reporting limits in the period between the two studies, the data are insufficiently certain to draw reliable conclusions with regard to limiting nutrients. For both studies, the trophic state of the lake was classified as oligotrophic (less productive) or mesotrophic (moderately productive), depending on the constituent used for classification. Internal circulation from wind-generated waves and changes in the lake’s thermocline are important processes for distribution of water-quality constituents throughout Coeur d’Alene Lake. Surficial distribution of trace metals throughout most of the lake, including bays, is relatively uniform. Even south of the Coeur d’Alene River mouth, lakebed sediments are contaminated with trace metals. Inflow plume routing of the two primary inflow sources, the Coeur d’Alene and St. Joe Rivers, also significantly affects the fate and transport of contaminants. Most riverine inflows appear to move through the lake as overflow during summer, interflow during spring and autumn, and underflow during winter. Benthic flux is another key transport process for contaminants in Coeur d’Alene Lake. The results of in situ benthic flux chamber experiments indicated movement of dissolved metals, nutrients, and dissolved organic carbon out of the lakebed sediments. However, the lake is an overall sink for these constituents when they are associated with particulate material.

Idaho↗

Cyclic shear zone cataclasis and sintering during lava dome extrusion: Insights from Chaos Crags, Lassen Volcanic Center (USA)

The ascent and extrusion of crystal-rich magma is commonly facilitated by deformation partitioned within annular, conduit-parallel shear zones. The physical properties and textures of the shear zone materials, where exposed at surface, provide a record of ascent and eruption dynamics. We describe the shear zone developed in Dome C, part of Chaos Crags in the Lassen Volcanic Center (California, USA). The extruded shear zone comprises volcanic fault gouge and variably densified cataclasites. The competent cataclasites evidence deep-seated gouge production followed by gouge densification within the conduit on the timescale of lava dome ascent. Textural, geochemical and mineralogical data identify solid-state sintering as the densification mechanism. At the temperatures and pressures in the volcanic conduit, solid-state sintering causes rapid porosity and permeability loss within the gouge and concomitant material strengthening. Longer dwell times (i.e., slower ascent) allow for more sintering, producing stronger, denser and less permeable cataclasites. At Chaos Crags, we use the extent of sintering, quantified by residual porosity, to recover minimum in-conduit dwell times necessary to produce the observed cataclasites. Our analysis of the Dome C cataclasites suggests a maximum linear ascent rate of 10 m/day and a minimum ascent time of 100 days. We evaluate the consequences of shear zone lithification by solid-state sintering for the eruption of other crystal-rich, glass-poor magmas. Chaos Crags cataclasites preserve evidence of multiple cycles of fracturing, cataclasis and (re-)sintering suggesting a mechanism for transitions between effusive and explosive phases of dome-building eruptions.

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