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At least 145 records · Page 8Linked to original sources

Compositions of modern dust and surface sediments in the Desert Southwest, United States

Modern dusts across southwestern United States deserts are compositionally similar to dust-rich Av soil horizons (depths of 0-0.5 cm and 1-4 cm at 35 sites) for common crustal elements but distinctly different for some trace elements. Chemical compositions and magnetic properties of the soil samples are similar among sites relative to dust sources, geographic areas, and lithologic substrates. Exceptions are Li, U, and W, enriched in Owens Valley, California, and Mg and Sr, enriched in soils formed on calcareous fan gravel in southeast Nevada. The Av horizons are dominated by dust and reflect limited mixing with substrate sediments. Modern dust samples are also similar across the region, except that Owens Valley dusts are higher in Mg, Ba, and Li and dusts both there and at sites to the north on volcanic substrates are higher in Sb and W. Thus, dust and Av horizons consist of contributions from many different sources that are well mixed before deposition. Modern dusts contain significantly greater amounts of As, Cd, Cr, Cu, Ni, Pb, and Sb than do Av horizons, which record dust additions over hundreds to thousands of years. These results suggest that modern dust compositions are influenced by anthropogenic sources and emissions from Owens (dry) Lake after its artificial desiccation in 1926. Both modern dusts and Av horizons are enriched in As, Ba, Cu, Li, Sb, Th, U, and W relative to average crustal composition, which we interpret to indicate that the geologic sources of dust in the southwestern United States are geochemically distinctive.

Journal of Geophysical Research F: Earth Surface

Determining the spatial variability of wetland soil bulk density, organic matter, and the conversion factor between organic matter and organic carbon across coastal Louisiana, U.S.A.

Soil bulk density (BD), soil organic matter (SOM) content, and a conversion factor between SOM and soil organic carbon (SOC) are often used in estimating SOC sequestration and storage. Spatial variability in BD, SOM, and the SOM–SOC conversion factor affects the ability to accurately estimate SOC sequestration, storage, and the benefits ( e.g., land building area and vertical accretion) associated with wetland restoration efforts, such as marsh creation and sediment diversions. There are, however, only a few studies that have examined large-scale spatial variability in BD, SOM, and SOM–SOC conversion factors in coastal wetlands. In this study, soil cores, distributed across the entire coastal Louisiana (approximately 14,667 km 2 ) were used to examine the regional-scale spatial variability in BD, SOM, and the SOM–SOC conversion factor. Soil cores for BD and SOM analyses were collected during 2006–09 from 331 spatially well-distributed sites in the Coastwide Reference Monitoring System network. Soil cores for the SOM–SOC conversion factor analysis were collected from 15 sites across coastal Louisiana during 2006–07. Results of a split-plot analysis of variance with incomplete block design indicated that BD and SOM varied significantly at a landscape level, defined by both hydrologic basins and vegetation types. Vertically, BD and SOM varied significantly among different vegetation types. The SOM–SOC conversion factor also varied significantly at the landscape level. This study provides critical information for the assessment of the role of coastal wetlands in large regional carbon budgets and the estimation of carbon credits from coastal restoration.

Louisiana

Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: I. An introduction to the project

We investigated paleolimnological records from a series of river deltas around the northeastern rim of Lake Tanganyika, East Africa (Tanzania and Burundi) in order to understand the history of anthropogenic activity in the lake's catchment over the last several centuries, and to determine the impact of these activities on the biodiversity of littoral and sublittoral lake communities. Sediment pollution caused by increased rates of soil erosion in deforested watersheds has caused significant changes in aquatic communities along much of the lake's shoreline. We analyzed the effects of sediment discharge on biodiversity around six deltas or delta complexes on the east coast of Lake Tanganyika: the Lubulungu River delta, Kabesi River delta, Nyasanga/Kahama River deltas, and Mwamgongo River delta in Tanzania; and the Nyamuseni River delta and Karonge/Kirasa River deltas in Burundi. Collectively, these deltas and their associated rivers were chosen to represent a spectrum of drainage-basin sizes and disturbance levels. By comparing deltas that are similar in watershed attributes (other than disturbance levels), our goal was to explore a series of historical "experiments" at the watershed scale, with which we could more clearly evaluate hypotheses of land use or other effects on nearshore ecosystems. Here we discuss these deltas, their geologic and physiographic characteristics, and the field procedures used for coring and sampling the deltas, and various indicators of anthropogenic impact. ?? Springer 2005.

Journal of Paleolimnology

Assessment of site-specific agricultural Best Management Practices in the Upper East River watershed, Wisconsin, using a field-scale SWAT model

The Great Lakes “Priority Watershed” effort targeted the Upper East River watershed, a 116.5 km2 tributary watershed to Green Bay in Wisconsin, to reduce sediment and nutrients entering Green Bay. A Soil and Water Assessment Tool (SWAT) model was created to determine the effectiveness of Best Management Practices (BMPs) derived from the U.S. Department of Agriculture-Natural Resources Conservation Service National Conservation Planning (NCP) Database. The model was calibrated at the monthly timestep for flow, sediment, dissolved reactive phosphorus (DRP), total phosphorus (TP), and total nitrogen (TN). Field- and watershed-scale sediment and nutrient reductions were calculated due to the implementation of 74 BMP combinations on dairy and cash grain rotations. Modeling results indicated that when multiple BMPs are placed on a field, especially those that included filter strips and grassed waterways, generally reduced sediment and nutrient loads more than a single BMP implementation. The most effective in-field practice at reducing DRP and TP on dairy fields was a combination of 5 different BMPs: cover crops, crop rotation, nutrient management plan, reduced tillage, and a filter strip. Conservation cover was the most effective practice at reducing sediment and nutrient yields. Sediment and nutrient loads decreased at the watershed scale as the quantity and coverage of BMPs increased. When all contracted NCP BMPs were simulated at the watershed scale, sediment loads were reduced 2%, while TP, DRP, TN and nitrate loads were reduced 20%, 9%, 24%, and 17%, respectively. Modeling scenarios indicated that as the number and area of BMPs were increased, sediment and nutrient load reductions were also increased.

Wisconsin

Radiocarbon age-offsets in an arctic lake reveal the long-term response of permafrost carbon to climate change

Continued warming of the Arctic may cause permafrost to thaw and speed the decomposition of large stores of soil organic carbon (OC), thereby accentuating global warming. However, it is unclear if recent warming has raised the current rates of permafrost OC release to anomalous levels or to what extent soil carbon release is sensitive to climate forcing. Here we use a time series of radiocarbon age-offsets ( 14 C) between the bulk lake sediment and plant macrofossils deposited in an arctic lake as an archive for soil and permafrost OC release over the last 14,500 years. The lake traps and archives OC imported from the watershed and allows us to test whether prior warming events stimulated old carbon release and heightened age-offsets. Today, the age-offset (2 ka; thousand of calibrated years before A.D. 1950) and the depositional rate of ancient OC from the watershed into the lake are relatively low and similar to those during the Younger Dryas cold interval (occurring 12.9–11.7 ka). In contrast, age-offsets were higher (3.0–5.0 ka) when summer air temperatures were warmer than present during the Holocene Thermal Maximum (11.7–9.0 ka) and Bølling-Allerød periods (14.5–12.9 ka). During these warm times, permafrost thaw contributed to ancient OC depositional rates that were ~10 times greater than today. Although permafrost OC was vulnerable to climate warming in the past, we suggest surface soil organic horizons and peat are presently limiting summer thaw and carbon release. As a result, the temperature threshold to trigger widespread permafrost OC release is higher than during previous warming events.

Alaska

Catchment disturbance and stream metabolism: Patterns in ecosystem respiration and gross primary production along a gradient of upland soil and vegetation disturbance

Catchment characteristics determine the inputs of sediments and nutrients to streams. As a result, natural or anthropogenic disturbance of upland soil and vegetation can affect instream processes. The Fort Benning Military Installation (near Columbus, Georgia) exhibits a wide range of upland disturbance levels because of spatial variability in the intensity of military training. This gradient of disturbance was used to investigate the effect of upland soil and vegetation disturbance on rates of stream metabolism (ecosystem respiration rate [ER] and gross primary production rate [GPP]). Stream metabolism was measured using an open-system, single-station approach. All streams were net heterotrophic during all seasons. ER was highest in winter and spring and lowest in summer and autumn. ER was negatively correlated with catchment disturbance level in winter, spring, and summer, but not in autumn. ER was positively correlated with abundance of coarse woody debris, but not significantly related to % benthic organic matter. GPP was low in all streams and generally not significantly correlated with disturbance level. Our results suggest that the generally intact riparian zones of these streams were not sufficient to protect them from the effect of upland disturbance, and they emphasize the role of the entire catchment in determining stream structure and function. ?? 2005 by The North American Benthological Society.

Journal of the North American Benthological Societ

Evidence for montmorillonite or its compositional equivalent in Columbia Hills, Mars

During its exploration of the Columbia Hills, the Mars Exploration Rover "Spirit" encountered several similar samples that are distinctly different from Martian meteorites and known Gusev crater soils, rocks, and sediments. Occurring in a variety of contexts and locations, these "Independence class" samples are rough-textured, iron-poor (equivalent FeO ??? 4 wt%), have high Al/Si ratios, and often contain unexpectedly high concentrations of one or more minor or trace elements (including Cr, Ni, Cu, Sr, and Y). Apart from accessory minerals, the major component common to these samples has a compositional profile of major and minor elements which is similar to the smectite montmorillonite, implicating this mineral, or its compositional equivalent. Infrared thermal emission spectra do not indicate the presence of crystalline smectite. One of these samples was found spatially associated with a ferric sulfate-enriched soil horizon, possibly indicating a genetic relationship between these disparate types of materials. Compared to the nearby Wishstone and Watchtower class rocks, major aqueous alteration involving mineral dissolution and mobilization with consequent depletions of certain elements is implied for this setting and may be undetectable by remote sensing from orbit because of the small scale of the occurrences and obscuration by mantling with soil and dust.

Journal of Geophysical Research E: Planets

Rocky 7 prototype Mars rover field geology experiments: 1. Lavic Lake and Sunshine volcanic field, California

Experiments with the Rocky 7 rover were performed in the Mojave Desert to better understand how to conduct rover-based, long-distance (kilometers) geological traverses on Mars. The rover was equipped with stereo imaging systems for remote sensing science and hazard avoidance and 57 Fe Mössbauer and nuclear magnetic resonance spectrometers for in situ determination of mineralogy of unprepared rock and soil surfaces. Laboratory data were also obtained using the spectrometers and an X ray diffraction (XRD)/XRF instrument for unprepared samples collected from the rover sites. Simulated orbital and descent image data assembled for the test sites were found to be critical for assessing the geologic setting, formulating hypotheses to be tested with rover observations, planning traverses, locating the rover, and providing a regional context for interpretation of rover-based observations. Analyses of remote sensing and in situ observations acquired by the rover confirmed inferences made from orbital and simulated descent images that the Sunshine Volcanic Field is composed of basalt flows. Rover data confirmed the idea that Lavic Lake is a recharge playa and that an alluvial fan composed of sediments with felsic compositions has prograded onto the playa. Rover-based discoveries include the inference that the basalt flows are mantled with aeolian sediment and covered with a dense pavement of varnished basalt cobbles. Results demonstrate that the combination of rover remote sensing and in situ analytical observations will significantly increase our understanding of Mars and provide key connecting links between orbital and descent data and analyses of returned samples.

Journal of Geophysical Research E: Planets

Hydro-bio-geomechanical properties of hydrate-bearing sediments from Nankai Trough

Natural hydrate-bearing sediments from the Nankai Trough, offshore Japan, were studied using the Pressure Core Characterization Tools (PCCTs) to obtain geomechanical, hydrological, electrical, and biological properties under in situ pressure, temperature, and restored effective stress conditions. Measurement results, combined with index-property data and analytical physics-based models, provide unique insight into hydrate-bearing sediments in situ. Tested cores contain some silty-sands, but are predominantly sandy- and clayey-silts. Hydrate saturations S h range from 0.15 to 0.74, with significant concentrations in the silty-sands. Wave velocity and flexible-wall permeameter measurements on never-depressurized pressure-core sediments suggest hydrates in the coarser-grained zones, the silty-sands where S h exceeds 0.4, contribute to soil-skeletal stability and are load-bearing. In the sandy- and clayey-silts, where S h < 0.4, the state of effective stress and stress history are significant factors determining sediment stiffness. Controlled depressurization tests show that hydrate dissociation occurs too quickly to maintain thermodynamic equilibrium, and pressure–temperature conditions track the hydrate stability boundary in pure-water, rather than that in seawater, in spite of both the in situ pore water and the water used to maintain specimen pore pressure prior to dissociation being saline. Hydrate dissociation accompanied with fines migration caused up to 2.4% vertical strain contraction. The first-ever direct shear measurements on never-depressurized pressure-core specimens show hydrate-bearing sediments have higher sediment strength and peak friction angle than post-dissociation sediments, but the residual friction angle remains the same in both cases. Permeability measurements made before and after hydrate dissociation demonstrate that water permeability increases after dissociation, but the gain is limited by the transition from hydrate saturation before dissociation to gas saturation after dissociation. In a proof-of-concept study, sediment microbial communities were successfully extracted and stored under high-pressure, anoxic conditions. Depressurized samples of these extractions were incubated in air, where microbes exhibited temperature-dependent growth rates.

Journal of Marine and Petroleum Geology

Nitrogen fluxes through unsaturated zones in five agricultural settings across the United States

The main physical and chemical controls on nitrogen (N) fluxes between the root zone and the water table were determined for agricultural sites in California, Indiana, Maryland, Nebraska, and Washington from 2004 to 2005. Sites included irrigated and nonirrigated fields; soil textures ranging from clay to sand; crops including corn, soybeans, almonds, and pasture; and unsaturated zone thicknesses ranging from 1 to 22 m. Chemical analyses of water from lysimeters and shallow wells indicate that advective transport of nitrate is the dominant process affecting the flux of N below the root zone. Vertical profiles of (i) nitrogen species, (ii) stable isotopes of nitrogen and oxygen, and (iii) oxygen, N, and argon in unsaturated zone air and correlations between N and other agricultural chemicals indicate that reactions do not greatly affect N concentrations between the root zone and the capillary fringe. As a result, physical factors, such as N application rate, water inputs, and evapotranspiration, control the differences in concentrations among the sites. Concentrations of N in shallow lysimeters exhibit seasonal variation, whereas concentrations in lysimeters deeper than a few meters are relatively stable. Based on concentration and recharge estimates, fluxes of N through the deep unsaturated zone range from 7 to 99 kg ha −1 yr −1 Vertical fluxes of N in ground water are lower due to spatial and historical changes in N inputs. High N fluxes are associated with coarse sediments and high N application rates.

Journal of Environmental Quality

Hydrochemical evolution of sodium-sulfate and sodium-chloride groundwater beneath the Northern Chihuahuan Desert, Trans-Pecos, Texas, USA

Groundwater beneath the northern Chihuahuan Desert, Trans-Pecos, Texas, USA, occurs in both carbonate and siliciclastic aquifers beneath a thick unsaturated zone in shallow Rio Grande alluvium. Groundwater hydrochemical evolution was investigated by analyzing soils, soils leachates, bolson-fill sediments, water from the unsaturated zone, and groundwater from three major aquifers. Ionic relations, mineral saturation states, and geochemical modeling show that groundwater compositions are controlled by reactions in the unsaturated zone, mineralogy of unsaturated sediments and aquifers, position in the groundwater flow system, and extensive irrigation. Recharge to aquifers unaffected by irrigation is initially a Ca-HCO 3 type as a result of dissolving carbonate surficial salts. With continued flow and mineral-water interaction, saturation with calcite and dolomite is maintained, gypsum is dissolved, and aqueous Ca and Mg are exchanged for adsorbed Na to produce a Na-SO 4 water. Groundwater in Rio Grande alluvium is a Na-Cl type, reflecting river-water composition and the effects of irrigation, evapotranspiration, and surficial salt recycling. These results document two hydrochemical evolution paths for groundwater in arid lands. If recharge is dilute precipitation, significant changes in water chemistry can occur in unsaturated media, ion exchange can be as important as dissolution-precipitation reactions in determining groundwater composition, and mineral-water reactions ultimately control groundwater composition. If recharge is return flow of irrigation water that already contains appreciable solutes, mineral-water reactions are less important than irrigation-water composition in determining groundwater chemistry.

Hydrogeology Journal

Quantifying wetland–aquifer interactions in a humid subtropical climate region: An integrated approach

Wetlands are widely recognized as sentinels of global climate change. Long-term monitoring data combined with process-based modeling has the potential to shed light on key processes and how they change over time. This paper reports the development and application of a simple water balance model based on long-term climate, soil, vegetation and hydrological dynamics to quantify groundwater–surface water (GW–SW) interactions at the Norman landfill research site in Oklahoma, USA. Our integrated approach involved model evaluation by means of the following independent measurements: (a) groundwater inflow calculation using stable isotopes of oxygen and hydrogen ( 16 O, 18 O, 1 H, 2 H); (b) seepage flux measurements in the wetland hyporheic sediment; and (c) pan evaporation measurements on land and in the wetland. The integrated approach was useful for identifying the dominant hydrological processes at the site, including recharge and subsurface flows. Simulated recharge compared well with estimates obtained using isotope methods from previous studies and allowed us to identify specific annual signatures of this important process during the period of study (1997–2007). Similarly, observations of groundwater inflow and outflow rates to and from the wetland using seepage meters and isotope methods were found to be in good agreement with simulation results. Results indicate that subsurface flow components in the system are seasonal and readily respond to rainfall events. The wetland water balance is dominated by local groundwater inputs and regional groundwater flow contributes little to the overall water balance.

Oklahoma

Sources of salinity near a coal mine spoil pile, north-central Colorado

A small (1 km 2 ) salt-affected stream drainage on the High Plains north of Denver, Colorado was sampled to determine the near-surface dispersion of soluble salts and metals from low-sulfur coal mining waste (spoil). Surface waters collected along the 0.8-km stream reach, and aqueous leachates of spoil and naturally saline local soil, were analyzed for chemical constituents and sulfur isotopes. In this semiarid setting with abundant carbonate-bearing surficial sediments, the limited, mildly acidic drainage from the spoil pile is quickly neutralized, restricting the mobility of many elements. However, some spoil-derived constituents were clearly traceable within the upper 0.4 km of the stream reach. Spoil leachates and surface water near the spoil pile have distinctive compositions of major anions and cations, and elevated levels of dissolved nitrate compared with downstream waters. Spoil-derived sulfate was traceable because it has generally positive values of δ 34 S that contrasted with generally negative values of δ 34 S in soil leachates and evaporite salts from the surrounding area. Spatial–chemical sampling of surface water showed an abrupt increase in dissolved U, Se, B, Li, and Mn in the lower 0.4 km of the stream reach where shallow ground water from surrounding irrigated fields contributed to surface flow. The downstream evolution of surface water chemistry and sulfur isotopic composition is consistent with mixing between spoil-affected upstream water and irrigation-return water. The methods described should be applicable at other sites in similar settings where the environmental effect of low-sulfur coal mining waste must be assessed and where access to samples of shallow ground water is limited.

Colorado

A method to quantify and value floodplain sediment and nutrient retention ecosystem services

Floodplains provide critical ecosystem services to local and downstream communities by retaining floodwaters, sediments, and nutrients. The dynamic nature of floodplains is such that these areas can both accumulate sediment and nutrients through deposition, and export material downstream through erosion. Therefore, estimating floodplain sediment and nutrient retention should consider the net flux of both depositional and erosive processes. An ecosystem services framework was used to quantify and value the sediment and nutrient ecosystem service provided by floodplains in the Difficult Run watershed, a small (151 km 2 ) suburban watershed located in the Piedmont of Virginia (USA). A sediment balance was developed for Difficult Run and two nested watersheds. The balance included upland sediment delivery to streams, stream bank flux, floodplain flux, and stream load. Upland sediment delivery was estimated using geospatial datasets and a modified Revised Universal Soil Loss Equation. Predictive models were developed to extrapolate field measurements of the flux of sediment, sediment-bound nitrogen (N), and sediment-bound phosphorus (P) from stream banks and floodplains to 3232 delineated stream segments in the study area. A replacement cost approach was used to estimate the economic value of the sediment and nutrient retention ecosystem service based on estimated net stream bank and floodplain flux of sediment-bound N for all streams in the study area. Results indicated the net fluvial fluxes of sediment, sediment-bound N, and sediment-bound P were −10,439 Mg yr −1 (net export), 57,300 kg-N yr −1 (net trapping), and 98 kg-P yr −1 (net trapping), respectively. For sediment, floodplain retention was offset by substantial losses from stream bank erosion, particularly in headwater catchments, resulting in a net export of sediment. Nutrient retention in the floodplain exceeded that lost through stream bank erosion resulting in net retention of nutrients (TN and TP). Using a conservative cost estimate of \$12.69 (USD) per kilogram of nitrogen, derived from wastewater treatment costs, the estimated annual value for sediment and nutrient retention on Difficult Run floodplains was \$727,226 ± 194,220 USD/yr. Values and differences in floodplain nitrogen retention among stream reaches can be used to target areas for floodplain conservation and stream restoration. The methods presented are scalable and transferable to other areas if appropriate datasets are available for validation.

Virginia

The geochemistry of loess: Asian and North American deposits compared

Loess is widely distributed over Asia and North America and constitutes one of the most important surficial deposits that serve as terrestrial records of the Quaternary. The oldest Pleistocene loess in China is likely ∼2.6 Ma, thus spanning much or all of the Pleistocene. In North America, most loess is no older than the penultimate glacial period, with the exception of Alaska, where the record may go back to ∼3.0 Ma. On both continents, loess deposits date primarily to glacial periods, and interglacial or interstadial periods are represented by paleosols. Both glacial and non-glacial sources of silts that comprise the bulk of loess deposits are found on both continents. Although loess has been considered to be representative of the average upper continental crust, there are regionally distinctive compositions of loess in both Asia and North America. Loess deposits in Asia from Yakutia, Tajikistan, and China have compositionally distinct major element compositions, due to varying abundances of silicate minerals, carbonate minerals, and clay minerals. In North America, loess in the Mississippi River valley, the Great Plains, and Alaska are also distinguishable with regard to major element composition that reflects highly diverse source sediments. Trace element geochemistry (Sc-Th-Zr and the rare earth elements) also shows regional diversity of loess bodies, in both Asia and North America. On both continents, most loess bodies show significant contributions from later-cycle, altered sedimentary rocks, as opposed to direct derivation from igneous rocks. Further, some loess bodies have detectable contributions from mafic igneous rocks as well as major contributions from average, upper-crustal, felsic rocks. Intercalated paleosols in loess sections show geochemical compositions that differ significantly from the underlying loess parent materials. Ratios of soluble-to-insoluble elements show depletions in paleosols due to chemical weathering losses of calcite, dolomite, plagioclase, mica, apatite, and smectite. In Asia and North America, the last interglacial paleosol is more weathered than equivalent modern soils, which could be due either to a climate that was warmer and more humid, a longer period of pedogenesis, or both. In Asia, early Pleistocene loess and paleosols are both more weathered than those from the middle and late Pleistocene, forming prior to a mid-Pleistocene aridification of Asia from uplift of the Tibetan Plateau. Understanding the geochemistry of loess and paleosols can tell us much about past atmospheric circulation, past temperature and moisture regimes, and even tectonic processes.

Journal of Asian Earth Sciences

Evaluating the factors responsible for post-fire water quality response in forests of the western USA

Wildfires commonly increase nutrient, carbon, sediment, and metal inputs to streams yet the factors responsible for the type, magnitude and duration of water quality effects are poorly understood. Prior work by the current authors found increased nitrogen, phosphorus and cation exports were common the first five post-fire years from a synthesis of 159 wildfires across the western United States. In the current study, an analysis is undertaken to determine factors that best explain post-fire streamwater responses observed in those watersheds. Increased post-fire total nitrogen and phosphorus loading were proportional to the catchment extent of moderate and high burn severity. Post-fire dissolved metal concentrations increased in catchments with < 2% pre-fire soil organic matter. In contrast, in catchments with > 2% soil organic matter, post-fire dissolved metal concentrations decreased compared to pre-fire conditions. Where post-fire normalized difference vegetation index (NDVI), a remote sensing indicator of live green vegetation, was low, total metal concentrations increased by 25% on average and by > 100% in some cases. When pre-fire soil field capacity exceeded 17%, there was a 750% median increase in total metals export to streams. Overall, the current analysis identified burn severity, post-fire vegetation cover, and several soil properties as the key variables explaining extended post-fire water quality response across a broad range of conditions found in the western US.

Arizona, California, Colorado, Idaho, Montana, New

Effects of land disposal of municipal sewage sludge on fate of nitrates in soil, streambed sediment, and water quality

This study was undertaken to determine the effects of sewage-sludge disposal at the Lowry sewage-sludge-disposal area, near Denver, Colorado, on ground- and surface-water quality, to determine the fate of nitrates from sludge leachate, and to determine the source areas of leachate and the potential for additional leaching from the disposal area. Sewage-sludge disposal began in 1969. Two methods were used to apply the sludge: burial and plowing. Also, the sludge was applied both in liquid and cake forms. Data in this report represent the chemical composition of soil and streambed sediment from seven soil- and four streambed-sampling sites in 1986, chemical and bacterial composition of ground water from 28 wells from 1981 to 1987, and surface-water runoff from seven water-sampling sites from 1984 to 1987. Ground water samples were obtained from alluvial and bedrock aquifers. Samples of soil, streambed sediment, ground water and surface water were obtained for onsite measurement and chemical analysis. Measurements included determination of nitrogen compounds and major cations and anions, fecal-coliform and -streptococcus bacteria, specific conductance, and pH. Thirteen wells in the alluvial aquifer in Region 3 of the study area contain water that was probably affected by sewage-sludge leachate. The plots of concentration of nitrate with time show seasonal trends and trends caused by precipitation. In addition to yearly fluctuation, there were noticeable increases in ground-water concentrations of nitrate that coincided with increased precipitation. After 3 years of annual ground-water-quality monitoring and 4 years of a quarterly sampling program, it has been determined that leachate from the sewage-sludge-disposal area caused increased nitrite plus nitrate (as nitrogen) concentration in the alluvial ground water at the site. Soil analyses from the disposal area indicate that organic nitrogen was the dominant form of nitrogen in the soil. As a result of investigations at the research site, it has been determined that a potentially large source of contamination exists in the soils of the study area owing to increased concentrations of nitrogen, sodium, calcium, magnesium, sulfate, bicarbonate, and chloride because of sewage disposal. Continued monitoring of surface and ground water for nitrogen and the other ions previously mentioned is required to assess long-term effects of municipal sludge disposal on water quality.

Journal of Hydrology

Temporal variability of carbon and nutrient burial, sediment accretion, and mass accumulation over the past century in a carbonate platform mangrove forest of the Florida Everglades.

The objective of this research was to measure temporal variability in accretion and mass sedimentation rates (including organic carbon (OC), total nitrogen (TN), and total phosphorous (TP)) from the past century in a mangrove forest on the Shark River in Everglades National Park, USA. The 210 Pb Constant Rate of Supply model was applied to six soil cores to calculate annual rates over the most recent 10, 50, and 100 year time spans. Our results show that rates integrated over longer timeframes are lower than those for shorter, recent periods of observation. Additionally, the substantial spatial variability between cores over the 10 year period is diminished over the 100 year record, raising two important implications. First, a multiple-decade assessment of soil accretion and OC burial provides a more conservative estimate and is likely to be most relevant for forecasting these rates relative to long-term processes of sea level rise and climate change mitigation. Second, a small number of sampling locations are better able to account for spatial variability over the longer periods than for the shorter periods. The site average 100 year OC burial rate, 123&thinsp;&plusmn;&thinsp;19 (standard deviation) g m -2 yr -1 , is low compared with global mangrove values. High TN and TP burial rates in recent decades may lead to increased soil carbon remineralization, contributing to the low carbon burial rates. Finally, the strong correlation between OC burial and accretion across this site signals the substantial contribution of OC to soil building in addition to the ecosystem service of CO 2 sequestration.

Florida