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U-Pb zircon ages and Pb isotope geochemistry of gold deposits in the Carolina slate belt of South Carolina

Volcanic rocks of the Persimmon Fork Formation host the largest known gold mines of the Carolina slate belt. U-Pb (SHRIMP) zircon ages have been obtained from rocks closely associated with pyrite-enargite-gold deposits at Brewer (quartz-topaz rhyolite breccia from the argillic alteration zone in the Brewer pit and felsic ash-flow tuff from the quartz sericite alteration zone), from the disseminated and semimassive pyrite-gold deposits at Haile (crystal lithic rhyolitic ash-flow tuffs from the Champion pit), and from the Ridgeway deposit (felsic ash-flow tuff from the stratigraphic host of the North pit gold deposit). Generally, the zircons are fine grained, fractured, and contain crystal imperfections (corrosion, inclusions, and pits). 206 Pb/ 238 U zircon spot ages for all deposits span a wide range, mostly from 400 to 760 Ma. Inclusions and cores indicative of inherited domains in the zircons were not found, and only a few analyses range from 1.1 to 1.8 Ga. A distinct xenocrystic zircon population was not identified. The 206 Pb/ 238 U weighted age averages of zircon indicate the following crystallization dates for the volcanic and volcaniclastic rocks closely associated with the gold deposits: 550 &plusmn; 3 Ma for Brewer, 553 &plusmn; 2 Ma for Haile, and 556 &plusmn; 2 Ma for the Ridgeway deposit. These zircon crystallization ages represent close estimates of the age of the original gold mineralizing events. Younger zircon spot ages can be attributed to the effects of Paleozoic regional metamorphism. Pb isotope compositions of sulfide minerals (galena, pyrite, enargite, sphalerite, chalcopyrite, and molybdenite) and silicate minerals (K-feldspar, and sericite) in the gold deposits help to constrain the sources of fluids and metals during the mineralizing events. The deposits are pyrite rich, containing multiple generations of pyrite, including early-crystallized pyrite that is closely associated with the original gold mineralizing event, as well as recrystallized pyrite formed in response to Paleozoic metamorphism. Pb isotope compositions of pyrite span a wide range, including the most radiogenic values for the sulfides. Galena and K-feldspar are not abundant but where present they are typically the least radiogenic minerals. Galena has a limited range of Pb isotope compositions that are representative of the gold deposits as a group ( 206 Pb/ 204 Pb = 18.020&ndash;18.326, 207 Pb/ 204 Pb = 15.550&ndash;15.639, 208 Pb/ 204 Pb = 37.605&ndash;38.286). Values of 207 Pb/ 204 Pb straddle the average crustal Pb growth curve, consistent with contributions involving the mantle and continental crust. Whole-rock Pb isotope compositions of volcanic and volcaniclastic rocks of the Persimmon Fork Formation nearly match the range for sulfides in the gold deposits. Subtle regional contrasts in Pb isotope compositions exist among the deposits. Sulfide minerals from Barite Hill (e.g., galena 206 Pb/ 204 Pb < 18.077) in southern South Carolina are generally less radiogenic than sulfides from Ridgeway ( 206 Pb/ 204 Pb > 18.169), Haile ( 206 Pb/ 204 Pb > 18.233), and Brewer ( 206 Pb/ 204 Pb > 18.311) in northern South Carolina. Because Pb isotope compositions of basement rocks from Grenville massifs in the southern Appalachians and sulfide minerals from the gold deposits do not match, a direct genetic connection cannot be established. Diversity in values of 206 Pb/ 204 Pb and the relatively high values of 207 Pb/ 204 Pb suggest that the deposits evolved adjacent to or closely related to continental blocks, perhaps linked to a back-arc tectonic setting. Among potential younger analogues of the slate belt gold deposits are the sulfide deposits of the Okinawa trough in the western Pacific. Mantle-derived isotopic contributions were more important at Barite Hill in southern South Carolina, the least radiogenic among the deposits where oceanic crust had developed, than at Brewer, Haile, and Ridgeway in northern South Carolina where rifting thinned the continental crust.

Georgia, North Carolina, South Carolina, Virginia

The magnitude and proximate cause of ice-sheet growth since 35,000 yr B.P.

The magnitude of late Wisconsinan (post-35,000 yr B.P.) ice-sheet growth in the Northern Hemisphere is not well known. Ice volume at ???35,000 yr B.P. may have been as little as 20% or as much as 70% of the volume present at the last glacial maximum (LGM). A conservative evaluation of glacial-geologic, sea level, and benthic ??18O data indicates that ice volume at ???35,000 yr B.P. was approximately 50% of that extant at the LGM (???20,000 yr B.P.); that is, it doubled in about 15,000 yr. On the basis of literature for the North Atlantic and a sea-surface temperature (SST) data compilation, it appears that this rapid growth may have been forced by low-to-mid-latitude SST warming in both the Atlantic and Pacific Oceans, with attendant increased moisture transport to high latitudes. The SST ice-sheet growth notion also explains the apparent synchroneity of late Wisconsinan mountain glaciation in both hemispheres.

Quaternary Research

East asian gold: Deciphering the anomaly of phanerozoic gold in precambrian cratons

Early Cretaceous orogenic gold deposits in eastern Asia are globally unique in that large Phanerozoic lode gold deposits occur in Archean-Paleoproterozoic cratons. In the northern Pacific region, ca. 125 Ma orogenic gold deposits in the North China, Yangzte, and Siberian craton margins, as well as in young terranes in California, may ultimately relate to the giant Cretaceous mantle plume in the southern Pacific basin and the relatively rapid tectonic consequences along both continental margins from resulting Pacific plate reconfigurations. In eastern Asia, such consequences include reactivation of and fluid flow along major fault systems, with fluid focusing into simultaneously forming, isolated core complexes of uncertain genesis. Deposition of gold ores in previously devolatilized high-grade Precambrian metamorphic rocks requires an exotic source of ore fluid, most likely subducted Mesozoic oceanic crust and/or overlying sediment. An implication is that Phanerozoic metamorphic core complexes in other destabilized craton margins could host large gold resources. ?? 2007 by Economic Geology.

Economic Geology

Fish kill from underwater explosions

The U.S. Geological Survey has used 23 different shotpoints during two seasons of field work in our seismic study of crustal structure in western United States. Without exception, it has been found that under-water shotpoints result in a more efficient conversion of explosive energy into seismic energy than do drilled-hole shotpoints. This experience, together with elimination of drilling costs, has led to the use of underwater shotpoints wherever possible. Three of the 23 shotpoints were in the Pacific Ocean, and for these we have no detailed information on the fish kill. Another six shotpoints were located in inland bodies of water. These are: * Soda Lake near Fallon, Nevada * Mono Lake near Lee Vining, California * Lake Mead near Boulder City, Nevada * Shasta Lake near Redding, California * C.J. Strike Reservoir near Bruneau, Idaho * Lucky Peak Reservoir near Boise, Idaho The 22 high-explosive charges, weighing a total of 95,100 pounds, that were fired in lakes containing fish life resulted in the known death of 2,413 game fish with a total weight of 759 pounds. The average mortality was 110 game fish or 34.5 pounds of game fish killed per average shot of 4,325 pounds of high-explosives.

California;Nevada;Idaho

Real-time forecasting of the April 11, 2012 Sumatra tsunami

The April 11, 2012, magnitude 8.6 earthquake off the northern coast of Sumatra generated a tsunami that was recorded at sea-level stations as far as 4800 km from the epicenter and at four ocean bottom pressure sensors (DARTs) in the Indian Ocean. The governments of India, Indonesia, Sri Lanka, Thailand, and Maldives issued tsunami warnings for their coastlines. The United States' Pacific Tsunami Warning Center (PTWC) issued an Indian Ocean-wide Tsunami Watch Bulletin in its role as an Interim Service Provider for the region. Using an experimental real-time tsunami forecast model (RIFT), PTWC produced a series of tsunami forecasts during the event that were based on rapidly derived earthquake parameters, including initial location and Mwp magnitude estimates and the W-phase centroid moment tensor solutions (W-phase CMTs) obtained at PTWC and at the U. S. Geological Survey (USGS). We discuss the real-time forecast methodology and how successive, real-time tsunami forecasts using the latest W-phase CMT solutions improved the accuracy of the forecast.

Sumatra

Sr87/Sr86 ratios of Quaternary lavas of the Cascade Range, northern California

Quaternary lavas from Mount Lassen, Mount Shasta, and Medicine Lake, which range in composition from olivine basalt to rhyolite, have Sr 87 /Sr 86 values that fall between 0.7030 and 0.7043, corrected to 0.7080 for the Eimcr and Amend (MIT) SrCO 3 standard. These values are very close to average (corrected) strontium isotopic values of some other circum-Pacific volcanic suites and of lavas of oceanic islands. The low ratios suggest a mantle origin. The notably high strontium content (1400 ppm) in the andesites from Mount Shasta also indicates a mantle origin at depths where plagioclase is absent as a stable phase in the residual material.

California

History of earthquakes and tsunamis along the eastern Aleutian-Alaska megathrust, with implications for tsunami hazards in the California Continental Borderland

During the past several years, devastating tsunamis were generated along subduction zones in Indonesia, Chile, and most recently Japan. Both the Chile and Japan tsunamis traveled across the Pacific Ocean and caused localized damage at several coastal areas in California. The question remains as to whether coastal California, in particular the California Continental Borderland, is vulnerable to more extensive damage from a far-field tsunami sourced along a Pacific subduction zone. Assuming that the coast of California is at risk from a far-field tsunami, its coastline is most exposed to a trans-Pacific tsunami generated along the eastern Aleutian-Alaska subduction zone. We present the background geologic constraints that could control a possible giant (M w ~9) earthquake sourced along the eastern Aleutian-Alaska megathrust. Previous great earthquakes (M w ~8) in 1788, 1938, and 1946 ruptured single segments of the eastern Aleutian-Alaska megathrust. However, in order to generate a giant earthquake, it is necessary to rupture through multiple segments of the megathrust. Potential barriers to a throughgoing rupture, such as high-relief fracture zones or ridges, are absent on the subducting Pacific Plate between the Fox and Semidi Islands. Possible asperities (areas on the megathrust that are locked and therefore subject to infrequent but large slip) are identified by patches of high moment release observed in the historical earthquake record, geodetic studies, and the location of forearc basin gravity lows. Global Positioning System (GPS) data indicate that some areas of the eastern Aleutian-Alaska megathrust, such as that beneath Sanak Island, are weakly coupled. We suggest that although these areas will have reduced slip during a giant earthquake, they are not really large enough to form a barrier to rupture. A key aspect in defining an earthquake source for tsunami generation is determining the possibility of significant slip on the updip end of the megathrust near the trench. Large slip on the updip part of the eastern Aleutian-Alaska megathrust is a viable possibility owing to the small frontal accretionary prism and the presence of arc basement relatively close to the trench along most of the megathrust.

Alaska

The 3D Elevation Program—Supporting Idaho’s economy

Introduction Due to Idaho’s inland location approximately 350 miles from the Pacific Ocean and its 80 recognized mountain ranges, the State’s climate varies widely, with maritime influence in the northern and western parts of Idaho and continental influence on the eastern side. The weather in the abundant mountains is unpredictable and often associated with natural hazards such as severe thunder and lightning storms leading to flooding, landslides, and wildfires. Issues important to Idaho’s economy include river, stream, and forest resource management, and infrastructure and construction management. Idaho participated in the U.S. Geological Survey 3D Elevation Program (3DEP) in 2016, the State’s first 3DEP project. The success of this project led to development of the Idaho Statewide Lidar Plan. Critical applications that meet the State’s management needs depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features.

Idaho

Glacier mass-balance fluctuations in the Pacific Northwest and Alaska, USA

The more than 40 year record of net and seasonal mass-balance records from measurements made by the United States Geological Survey on South Cascade Glacier, Washington, and Wolverine and Gulkana Glaciers, Alaska, shows annual and interannual fluctuations that reflect changes in the controlling climatic conditions at regional and global scales. As the mass-balance record grows in length, it is revealing significant changes in previously described glacier mass-balance behavior, and both inter-glacier and glacier-climate relationships. South Cascade and Wolverine Glaciers are strongly affected by the warm and wet maritime climate of the northeast Pacific Ocean. Their net balances have generally been controlled by winter accumulation, with fluctuations that are strongly related to the Pacific Decadal Oscillation (PDO). Recently, warm dry summers have begun to dominate the net balance of the two maritime glaciers, with a weakening of the correlation between the winter balance fluctuations and the PDO. Non-synchronous periods of positive and negative net balance for each glacier prior to 1989 were followed by a 1989-2004 period of synchronous and almost exclusively negative net balances that averaged -0.8 m for the three glaciers.

Conference Paper

Paleoceanographic implications of Miocene deep-sea hiatuses

Miocene paleoceanographic evolution exhibits major changes resulting from the opening and closing of passages, the subsequent changes in oceanic circulation, and development of major Antarctic glaciation. The consequences and timing of these events can be observed in variations in the distribution of deep-sea hiatuses, sedimentation patterns, and biogeographic distribution of planktic organisms. The opening of the Drake Passage in the latest Oligocene to early Miocene (25–20 Ma) resulted in the establishment of the deep circumpolar current, which led to thermal isolation of Antarctica and increased global cooling. This development was associated with a major turnover in planktic organisms, resulting in the evolution of Neogene assemblages and the eventual extinction of Paleogene assemblages. The erosive patterns of two widespread hiatuses (PH, 23.0–22.5 Ma; and NH 1, 20–18 Ma) indicate that a deep circumequatorial circulation existed at this time, characterized by a broad band of carbonate-ooze deposition. Siliceous sedimentation was restricted to the North Atlantic and a narrow band around Antarctica. A major reorganization in deep-sea sedimentation and hiatus distribution patterns occurred near the early/middle Miocene boundary, apparently resulting from changes in oceanic circulation. Beginning at this time, deep-sea erosion occurred throughout the Caribbean (hiatus NH 2, 16–15 Ma), suggesting disruption of the deep circumequatorial circulation and northward deflection of deep currents, and/or intensification of the Gulf Stream. Sediment distribution patterns changed dramatically with the sudden appearance of siliceous-ooze deposition in the marginal and east equatorial North Pacific by 16.0 to 15.5 Ma, coincident with the decline of siliceous sedimentation in the North Atlantic. This silica switch may have been caused by the introduction of Norwegian Overflow Water into the North Atlantic acting as a barrier to outcropping of silica-rich Antarctic Bottom Water. The main aspects of the present oceanic circulation system and sediment distribution pattern were established by 13.5 to 12.5 Ma (hiatus NH 3), coincident with the establishment of a major East Antarctic ice cap. Antarctic glaciation resulted in a broadening belt of siliceous-ooze deposition around Antarctica, increased siliceous sedimentation in the marginal and east equatorial North Pacific and Indian Oceans, and further northward restriction of siliceous sediments in the North Atlantic. Periodic cool climatic events were accompanied by lower eustatic sea levels and widespread deep-sea erosion at 12 to 11 Ma (NH 4), 10 to 9 Ma (NH 5), 7.5 to 6.2 Ma (NH 6), and 5.2 to 4.7 Ma (NH 7).

Geological Society of America Bulletin

Inventory of Anchialine Pools in Hawaii's National Parks

BACKGROUND Anchialine (?near the sea?) pools are rare and localized brackish waters along coastal lava flows that exhibit tidal fluctuations without a surface connection with the ocean (Fig. 1). In Hawai`i, these pools were frequently excavated or otherwise modified by Hawaiians to serve as sources of drinking water, baths and fish ponds. National Parks in Hawai`i possess the full spectrum of pool types, from walled fish ponds to undisturbed pools in collapsed lava tubes, cracks and caves. Pools contain relatively rare and unique fauna threatened primarily by invasive species and habitat loss. In collaboration with the National Park Service?s Inventory and Monitoring Program, the U.S. Geological Survey?s Pacific Island Ecosystems Research Center undertook inventories of these unique ecosystems in two National Parks on the island of Hawai`i: Hawai`i Volcanoes National Park and Kaloko-Honokohau National Historical Park.

Fact Sheet

CDP seismic sections of the western Beaufort continental margin

The continental rise, slope, and shelf in the Beaufort Sea off northern Alaska were surveyed with 5600 km of common-depth-point (CDP) seismic data by the U.S. Geological Survey in 1977. The lower continental rise consists of a wedge of at least 4.5 km of low-velocity, generally flat-lying, parallel-bedded sediments. Slump-related diapiric folds, probably cored by shale, occur on the upper rise and lower slope. The observed minimum depth to oceanic basement in the Canada Basin requires an age for this basin of at least 120 m.y., assuming it to be floored by oceanic crust with a subsidence history similar to that of the Atlantic and Pacific oceans.

Alaska

Crustal processes of the Mid-Ocean Ridge

Independent geological and geophysical investigations of the Mid-Ocean Ridge system have begun to focus on the nature of the magma chamber system underlying its central axis. Thermal models predict the existence of a steady-state chamber beneath a thin crustal lid ranging in thickness from 2 to 13 kilometers. The only aspect of the system that these models fail to account for is the extremely slow spreading rates. Seismological studies reveal the existence of a low-velocity zone beneath segments of the East Pacific Rise, which is thought to correspond to a chamber system having a half-width of approximately 5 to 10 kilometers. These estimates compare favorably with those derived separately through petrological investigations of deep-sea drilling results, various sampling programs, and field and laboratory studies of ophiolites. The chamber is thought to be wing-shaped and to remain continuously open; it is thought to be fed from the center while simultaneously solidifying at the sides as spreading carries the two halves apart. Progressive fractionation occurs by crystal settling coupled with repeated replenishment and magma mixing in an open steady-state system. Near-bottom studies reveal that the zone of extrusion above the chamber is narrow, but its eruptive history is cyclic in nature, in conflict with the predictions of a steady-state model. On-bottom gravity data at 21°N on the East Pacific Rise reveal a negative gravity anomaly that may be related to the uppermost part of the chamber. The anomaly is only 2 kilometers wide and 1 kilometer below the sea floor. This feature may be associated with a short-term upper magma reservoir. The cyclic volcanic activity is directly related to the active phase of hydrothermal circulation responsible for the observed negative thermal anomaly. The volume of water associated with this circulation is equal to the entire ocean volume passing through the accretion zone approximately every 8 million years. This is about 0.5 percent of the world's rivers, but the effective transport rates of elements are comparable to those of rivers in that anomalies for individual elements are frequently between 100 and 1000 times the average river composition. The degree of subsurface dilution determines the final exit temperature and composition of the hydrothermal fluids, ranging from manganese domination at extreme dilution to iron at intermediate levels to sulfide deposition when low dilution occurs. The discovery of massive sulfide deposits on the East Pacific Rise is destined to have a profound impact on our understanding of ore-forming processes. Whether it will have any economic significance remains to be seen.

Science

Data on water wells, Naval Air Missile Test Center Area, Point Mugu, California

The entire water supply for the U. S. Naval Air Missile Test Center at Point Mugu, Calif., is pumped from wells located .within 2 miles of the Pacific Ocean. A large irrigation development inland from the Test Center has created a landward hydraulic gradient beneath the Test Center, causing sea-water encroachment into the water-yielding deposits. The encroaching sea water has not yet reached the Test Center well field; however, the encroachment poses a serious threat to the Test Center supply. To evaluate the adequacy of the water supply for the Naval Air Missile Test Center under these conditions and to suggest additional sources for future development, the U. S. Geological Survey has canvassed all wells and collected all available hydrologic dataat the Test Center and in the immediate vicinity. The data tabulated in this report include measurements of water levels in wells, well logs, and chemical analyses for all wells south of Hueneme Road collected through February 1959. This study was made by the Geological Survey, U. S. Department of the Interior, under the general supervision of H. L. Wilson, Jr., district engineer for California, and under the immediate supervision of Fred Kunkel, geologist in charge of the Long Beach subdistrict office.

California

Offshore shallow structure and sediment distribution, Punta Gorda to Point Arena, Northern California

This publication consists of two map sheets that display shallow geologic structure, along with sediment distribution and thickness, for an approximately 150-km-long offshore section of the northern California coast between Punta Gorda and Point Arena. Each map sheet includes three maps at scales of either 1:100,000 or 1:200,000, and together the sheets include 30 figures that contain representative high-resolution seismic-reflection profiles. The maps and seismic-reflection surveys cover most of the continental shelf in this region. In addition, the maps show the locations of the shelf break and the 3-nautical-mile limit of California’s State Waters. The seismic-reflection data, which are the primary dataset used to develop the maps, were collected to support the California Seafloor Mapping Program, U.S. Geological Survey Offshore Geologic Hazards projects, and National Oceanic and Atmospheric Administration’s (NOAA’s) Ocean Explorer program. In addition to the two map sheets, this publication includes geographic information system data files of faults, sediment thicknesses, and depths-to-base of sediment The map area includes the northernmost section of the right-lateral San Andreas Fault, which extends offshore from Point Arena in the south to Point Delgada in the north. The San Andreas Fault is the primary structure in the widely distributed plate boundary between the Pacific Plate and the Sierra Nevada–Great Valley Microplate, with estimates of cumulative right slip of as much as up to 450 km. South of Point Delgada, fault-related transtension has resulted in development of the Noyo Basin. North of Point Delgada, the San Andreas Fault transitions into a complex contractional zone in and (or) south of the King Range, including a possible nearshore fault that may connect with the Mattole Canyon Fault. Quaternary sediments and bedrock underlie the shelf. On the seismic-reflection profiles, we digitally traced the thickness and depth of the uppermost seismic-stratigraphic unit, which is a focus of this publication. The upper contact of this unit is the seafloor; the lower contact is a transgressive surface of erosion, a commonly angular, wave-cut unconformity characterized by an upward change to lower amplitude, more diffuse reflections. On the basis of this lower contact, this stratigraphic unit is inferred to have been deposited on the shelf in the last about 21,000 years during the sea-level rise that followed the last major lowstand and the Last Glacial Maximum (LGM). Maps in this publication show both the thickness of this upper sediment unit and the depth to the base of the sediment unit. Within the map region, five different “domains” of post-LGM shelf sediment are delineated on the basis of sediment thickness and coastal geomorphology. Maximum sediment thickness (as much as 67 m) is found in the northern part of the region, along the steep south flank of the King Range. Minimum sediment thickness (areas of exposed bedrock) is found on fault-bounded uplifts, which include Tolo bank and Punta Gorda bank. Mean sediment thickness for the entire shelf in the map area between Punta Gorda and Point Arena is 8.9 m, and total sediment volume is 12,824×10 6 m 3 .

California

Chemical variations across the Alaska-Aleutian Range batholith

A study of 79 chemical analyses of plutonic rocks in the northern part of the Alaska-Aleutian Range batholith shows that K 2 O and SiO 2 in Late Cretaceous and Tertiary rocks decrease toward the Pacific margin and that Al 2 O 3 and CaO increase. Plots for Fe 2 O 3 , FeO, MgO, and TiO 2 suggest a possible increase toward the Pacific margin; Na 2 O, H 2 O+, and MnO show no significant trends across the batholith. Oxide trends for groups of plutons in the western and eastern parts of the batholith in general are opposite that of the groups combined. For the Jurassic plutonic rocks, K 2 O may decrease toward the Pacific margin; other oxides show considerable scatter, and meaningful trends are not readily apparent. The oxide trends across the batholith are similar to trends across the central Sierra Nevada batholith of California, with the exception of SiO 2 and A1 2 O 3 , which show no significant changes. In the Coast Range batholith of British Columbia, potassium also increases away from the Pacific margin. The increase in K 2 O toward the continent in the Alaska-Aleutian Range batholith is similar to that found across Quaternary volcanic island arcs, where K 2 O content increases directly with increasing depth to inclined seismic zones. This increase suggests that generation of magma may have taken place along, or above, a paleoseismic zone. Geologic evidence supports such a model for the Jurassic plutonic rocks, which represent the roots of an early Mesozoic magmatic arc that probably formed above a descending oceanic plate. However, the hypothesis that magma for Late Cretaceous and Tertiary plutonic rocks was generated along seismic zones does not fit available geologic evidence, and an anatectic model cannot be ruled out.

Alaska

Variation of Nb-Ta, Zr-Hf, Th-U and K-Cs in two diabase-granophyre suites

Concentrations of Nb, Ta, Zr, Hf, Th, U and Cs have been determined in samples of igneous rocks representing the diabase-granophyre suites from Dillsburg, Pennsylvania, and Great Lake, Tasmania. Niobium and tantalum have a three to fourfold increase with differentiation in each of the suites. The chilled margin of the Great Lake intrusion contains half the niobium and tantalum content (5.3 ppm and 0.4 ppm, respectively) of the chilled basalt from Dillsburg (10 ppm and 0.9 ppm, respectively). The twofold difference between the suites is correlated with differences in their titanium content. The average Nb Ta "> NbTa ratios for each suite are similar: 13.5 for the Great Lake suite, and 14.4 for the Dillsburg suite. The zirconium content of the two suites is essentially the same and increases from 50 to 60 ppm in the chilled margins to 240–300 ppm in the granophyres. Hafnium is low in the early formed rocks (0.5 –1.5 ppm and achieves a maximum in the granophyres (5–8 ppm). The Zr Hf "> ZrHf ratio decreases from 68 to 33 with progressive differentiation. In the Dillsburg suite thorium and uranium increase from 2.6 ppm and 0.6 ppm, respectively, in the chilled samples to 11.8 ppm and 3.1 ppm in the granophyres. The chilled margin of the Great Lake suite contains 3.2 ppm thorium and 9.8 ppm uranium; the granophyre contains 11.2 ppm thorium and 2.8 ppm uranium. The average Th U "> ThU ratios of the Dillsburg and Great Lake suites are nearly the same—4.1 and 4.4, respectively. Within each suite the Th U "> ThU ratio remains quite constant. Cesium and the K Cs "> KCs ratio do not vary systematically in the Dillsburg suite possibly because of redistribution or loss of cesium by complex geologic processes. Except for the chilled margin of the Great Lake suite, the variation of Cs and the K Cs "> KCs ratio are in accord with theoretical considerations. Cesium increases from about 0.6 ppm in the lower zone to 3.5 ppm in the granophyre; the K Cs "> KCs ratio varies from 10 × 10 3 in the lower zone to 6 × 10 3 in the granophyre. A comparison of the abundance of some of these elements is made with those reported on oceanic tholeiites from the Atlantic and Pacific oceans. Trace elements with large ionic radii (Th, U, Cs) are present in significantly greater concentrations in the two continental tholeiitic series than in the oceanic tholeiites. However, this does not seem to be true for lithophilic elements of smaller ionic radii (Zr and Nb). These trace element distribution patterns, when considered with other minor element and isotopic studies, indicate that 1. crustal contamination does not entirely account for differences between continental and oceanic tholeiites, and 2. the oceanic tholeiites do not necessarily delimit the geochemical characteristics of the mantle.

Geochimica et Cosmochimica Acta

Hydrologic Resources of Guam

Introduction The U.S. Territory of Guam, which lies in the western Pacific Ocean near latitude 13?28'N and longitude 144?45'E, is the largest (211 mi2) and southernmost of the islands in the Mariana chain. Ground water supplies about 80 percent of the drinking water for the island's 150,000 residents and nearly one million visitors per year. In northern Guam, water is obtained from wells that tap the upper part of a fresh ground-water lens in an aquifer composed mainly of limestone. About 180 wells, nearly all in the north, withdraw about 35 Mgal/d of water with chloride concentrations ranging from 6 to 585 mg/L. In southern Guam, the main source of freshwater is from surface water that runs off the weathered volcanic rocks that are exposed over much of the area. About 9.9 Mgal/d of freshwater is obtained using surface reservoirs. The island's freshwater resources are adequate to meet current (2003) needs, but future demands will eventually be higher. To better understand the hydrology of the island, the U.S. Geological Survey (USGS) entered into a cooperative study with the Water and Environmental Research Institute of the Western Pacific (WERI) at the University of Guam. The objective of the study was to provide a better understanding of the water resources of the island through analysis of data collected by the USGS on Guam. This report provides a description of the general hydrologic principles of the island's ground-water systems, as well as of the rainfall and geology of Guam. Hydrologic data described in the report include water levels, chloride concentrations, and pumpage from ground-water wells and streamflow data from southern Guam.

Water-Resources Investigations Report