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USGS2005

Net alkalinity and net acidity 1: Theoretical considerations

Net acidity and net alkalinity are widely used, poorly defined, and commonly misunderstood parameters for the characterization of mine drainage. The authors explain theoretical expressions of 3 types of alkalinity (caustic, phenolphthalein, and total) and acidity (mineral, CO2, and total). Except for rarely-invoked negative alkalinity, theoretically defined total alkalinity is closely analogous to measured alkalinity and presents few practical interpretation problems. Theoretically defined "CO 2-acidity" is closely related to most standard titration methods with an endpoint pH of 8.3 used for determining acidity in mine drainage, but it is unfortunately named because CO2 is intentionally driven off during titration of mine-drainage samples. Using the proton condition/mass- action approach and employing graphs to illustrate speciation with changes in pH, the authors explore the concept of principal components and how to assign acidity contributions to aqueous species commonly present in mine drainage. Acidity is defined in mine drainage based on aqueous speciation at the sample pH and on the capacity of these species to undergo hydrolysis to pH 8.3. Application of this definition shows that the computed acidity in mg L -1 as CaCO3 (based on pH and analytical concentrations of dissolved FeII, FeIII, Mn, and Al in mg L -1):aciditycalculated=50{1000(10-pH)+[2(FeII)+3(FeIII)]/56+2(Mn)/ 55+3(Al)/27}underestimates contributions from HSO4- and H+, but overestimates the acidity due to Fe3+ and Al3+. However, these errors tend to approximately cancel each other. It is demonstrated that "net alkalinity" is a valid mathematical construction based on theoretical definitions of alkalinity and acidity. Further, it is shown that, for most mine-drainage solutions, a useful net alkalinity value can be derived from: (1) alkalinity and acidity values based on aqueous speciation, (2) measured alkalinity minus calculated acidity, or (3) taking the negative of the value obtained in a standard method "hot peroxide" acidity titration, provided that labs report negative values. The authors recommend the third approach; i.e., net alkalinity = -Hot Acidity. ?? 2005 Elsevier Ltd. All rights reserved.

Applied Geochemistry↗

USGS2020

Spatially referenced models of streamflow and nitrogen, phosphorus, and suspended-sediment loads in streams of the midwestern United States

In this report, SPAtially Referenced Regression On Watershed attributes (SPARROW) models developed to describe long-term (2000–14) mean-annual streamflow, total nitrogen (TN), total phosphorus (TP), and suspended-sediment (SS) transport in streams of the Midwestern part of the United States (the Mississippi River, Great Lakes, and Red River of the North Basins) are described. The nutrient and suspended-sediment models have a base year of 2012, which means they were developed based on source inputs and management practices similar to those existing during or near 2012 and average hydrological conditions detrended to 2012 (2000–14), whereas the streamflow model has base years of 2000–14, which means it was developed based on the average input precipitation minus actual evapotranspiration from 2000 to 2014. In developing the models, several updates and improvements were made to the data inputs and statistical approaches used to calibrate/develop the models from those used in the previous 2002 SPARROW models. The 2012 SPARROW models were constructed using a higher resolution stream network, which resulted in a mean catchment size of 2.7 square kilometers compared to 480 square kilometers in the 2002 models; more detailed and updated wastewater treatment plant contribution estimates; inputs from background phosphorus sources that were not included in the 2002 model; and more accurate loads for calibration that were computed using a modified Beale ratio-estimator technique whenever no trend in load was determined. Statistical approaches were added to compensate for the unequal effect of each monitoring site during the calibration process by adjusting for the fraction of the basin included in other upstream monitored sites (nested share) and thinning the calibration sites if a negative statistical correlation between nearby sites was determined. Results from 2012 SPARROW models describe how much of each water, TN, TP, and SS source was delivered to the stream network, and the major landscape factors that affected their delivery. Atmospheric deposition and natural (background) sources of TN and TP, respectively, were the dominant sources in anthropogenically unaffected areas (especially in the Rocky Mountains and north-central areas of the Midwest), whereas fertilizers, manure, and fixation were dominant sources in agricultural areas, especially in the Corn Belt and near the Mississippi River. Urban sources of TN and TP were typically localized, but they were still important for some large areas, especially the Lake Erie Basin. All of the land-to-water delivery variables in the nutrient and sediment SPARROW models, such as runoff, soil erodibility, basin slope, and the amount of tile drains, are commonly included in process-driven models. In the SPARROW TN and TP models, best management practices (BMPs) reduced the delivery of these nutrients to streams. Long-term mean-annual flows and nutrient and sediment loads were simulated in streams throughout the Midwest. The simulated flows from the SPARROW flow model were used in the SPARROW TN, TP, and SS models to help describe nutrient and sediment transport from the watershed and through the stream network. Outputs from the TN, TP, and SS models describe loads and yields of these constituents throughout the Midwest, and from major drainage basins throughout the Midwest. Highest TN, TP, and SS yields and delivered yields were from the Lake Erie, Ohio River, Upper Mississippi River, and Lower Mississippi River Basins, whereas lowest yields were spread over most other areas. Losses during downstream delivery resulted in part of the TN, TP, and SS that reach the stream network not reaching the downstream receiving bodies: 14, 15, and 28 percent of the TN, TP, and SS, respectively, are lost during delivery to the Great Lakes and 19, 23, and 52 percent of the TN, TP, and SS, respectively, are lost during delivery to the Gulf of Mexico. The largest losses of nutrients and sediments during transport were in the Missouri and Arkansas River Basins. Information from these SPARROW models can help guide nutrient and sediment reduction strategies throughout the Midwest. Model results provide information on what may be the most appropriate general type of actions to reduce total loading by describing the relative importance of each source, and where to most efficiently place the efforts to reduce loading by describing the distribution of nutrient and sediment loading. By implementing management efforts addressing the major sources of the loads in areas contributing the highest loads, it may be possible to reduce nutrient loading throughout the Mississippi River Basin and thus reduce the size of the hypoxic zone in the Gulf of Mexico; reduce nutrient loading into lakes, and thus reduce the occurrence of harmful algal blooms; and reduce sediment losses, and thus improve the benthic habitat in streams and rivers throughout the Midwest.

Scientific Investigations Report↗

USGS2024

Role of tributary cyanobacterial and nutrient transport and sediment processes on cyanobacterial bloom initiation in Lake Superior nearshore

Watershed fluxes of suspended sediment (SS), nutrients, in particular phosphorus (P), and cyanobacteria may play a role in driving cyanobacterial blooms along the southwestern shore of oligotrophic Lake Superior. To understand how tributary loads contribute to nearshore blooms, we sampled two southwestern shore tributaries, Bois Brule and Siskiwit Rivers. We collected water-quality samples to compute nutrient and sediment loads and to assess cyanobacteria community composition from the tributaries to the nearshore. We collected suspended and streambed sediment to assess the capacity for sediment to store and transport bioavailable P and to assess cyanobacteria community composition. Storm flows drove export of SS, total P, and total nitrogen, with the majority of total P being particulate P. Equilibrium P concentrations revealed that SS sorbed P as it is moved through the stream network across sites and seasons and was a potential source of P to the nearshore. However, streambed sediment in the Bois Brule and Siskiwit River watersheds were P sinks during summer, which potentially delayed transport of dissolved P to the lake. The cyanobacteria community varied spatially and temporally relating to multiple environmental variables including nutrients (P, N, and C) and specific conductivity. Cyanobacteria capable of producing cyanotoxins were present in tributaries and found across multiple environmental compartments indicating a potential for fluvial flow to the nearshore. This study demonstrated that streamflow is a primary driver of total nutrient and sediment loading in both watersheds, which indicates the potential for algal loading to the nearshore via suspended sediment or water.

Wisconsin↗

USGS2009

Assigning land use to supply wells for the statistical characterization of regional groundwater quality: Correlating urban land use and VOC occurrence

Many national and regional groundwater studies have correlated land use "near" a well, often using a 500 m radius circle, with water quality. However, the use of a 500 m circle may seem counterintuitive given that contributing areas are expected to extend up-gradient from wells, and not be circular in shape. The objective of this study was to evaluate if a 500 m circle is adequate for assigning land use to a well for the statistical correlation between urban land use and the occurrence of volatile organic compounds (VOCs). Land use and VOC data came from 277 supply wells in four study areas in California. Land use was computed using ten different-sized circles and wedges (250 m to 10 km in radius), and three different-sized "searchlights" (1-2 km in length). We define these shapes as contributing area surrogates (CASs), recognizing that a simple shape is at best a surrogate for the actual contributing area. The presence or absence of correlation between land use and the occurrence of VOCs was evaluated using Kendall's tau (??). Values of ?? were within 10% of one another for wedges and circles ranging in size from 500 m to 2 km, with correlations remaining statistically significant (p < 0.05) for all CAS sizes and shapes, suggesting that a 500 m circular CAS is adequate for assigning land use to a well. Additional evaluation indicated that urban land use is autocorrelated at distances ranging from 8 to 36 km. Thus, urban land use in a 500 m CAS is likely to be predictive of urban land use in the actual contributing area.

Journal of Hydrology↗

USGS2012

Trimming the UCERF2 hazard logic tree

The Uniform California Earthquake Rupture Forecast 2 (UCERF2) is a fully time‐dependent earthquake rupture forecast developed with sponsorship of the California Earthquake Authority (Working Group on California Earthquake Probabilities [WGCEP], 2007; Field et al., 2009). UCERF2 contains 480 logic‐tree branches reflecting choices among nine modeling uncertainties in the earthquake rate model shown in Figure 1. For seismic hazard analysis, it is also necessary to choose a ground‐motion‐prediction equation (GMPE) and set its parameters. Choosing among four next‐generation attenuation (NGA) relationships results in a total of 1920 hazard calculations per site. The present work is motivated by a desire to reduce the computational effort involved in a hazard analysis without understating uncertainty. We set out to assess which branching points of the UCERF2 logic tree contribute most to overall uncertainty, and which might be safely ignored (set to only one branch) without significantly biasing results or affecting some useful measure of uncertainty. The trimmed logic tree will have all of the original choices from the branching points that contribute significantly to uncertainty, but only one arbitrarily selected choice from the branching points that do not.

Seismological Research Letters↗

USGS1983

Explosion-induced stress changes estimated from vibrating-wire stressmeter measurements near the Mighty Epic event, Nevada Test Site

Explosion-induced compressive stress increases near an underground nuclear explosion are believed to contribute significantly to the containment of high-pressure gases within the explosion-produced cavity. These induced compressive stresses are predicted by computer calculations, but have never been adequately confirmed by field measurements, owing primarily to the unique difficulties of obtaining such field data. Vibrating-wire stressmeter measurements made near the Mighty Epic nuclear detonation, however, qualitatively indicate that within 150 meters of the working point, permanent compressive stress increases of several megapascals were present 15 weeks after the event. Additionally, stress-change magnitudes interpreted from the stressmeter data between the 75- and 260-meter range from the working point compare favorably with calculational predictions of the stress changes believed to be present shortly after detonation of the event. The measurements and calculations differ, however, with regard to the pattern of stress change radial and transverse to the explosion source. For the range of the field measurements from the working point, computer models predict the largest compressive-stress increase to be radial to the explosion source, while the field data indicate the transverse component of. stress change to be the most compressive. The significance of time-dependent modification of the initial explosion-induced stress distribution is, however, uncertain with regard to the comparison of the field measurements and theoretical predictions.

Open-File Report↗

USGS2002

Statistical methods in water resources

Preface This book began as class notes for a course we teach on applied statistical methods to hydrologists of the Water Resources Division, U. S. Geological Survey (USGS). It reflects our attempts to teach statistical methods which are appropriate for analysis of water resources data. As interest in this course has grown outside of the USGS, incentive grew to develop the material into a textbook. The topics covered are those we feel are of greatest usefulness to the practicing water resources scientist. Yet all topics can be directly applied to many other types of environmental data. This book is not a stand-alone text on statistics, or a text on statistical hydrology. For example, in addition to this material we use a textbook on introductory statistics in the USGS training course. As a consequence, discussions of topics such as probability theory required in a general statistics textbook will not be found here. Derivations of most equations are not presented. Important tables included in all general statistics texts, such as quantiles of the normal distribution, are not found here. Neither are details of how statistical distributions should be fitted to flood data -- these are adequately covered in numerous books on statistical hydrology. We have instead chosen to emphasize topics not always found in introductory statistics textbooks, and often not adequately covered in statistical textbooks for scientists and engineers. Tables included here, for example, are those found more often in books on nonparametric statistics than in books likely to have been used in college courses for engineers. This book points the environmental and water resources scientist to robust and nonparametric statistics, and to exploratory data analysis. We believe that the characteristics of environmental (and perhaps most other 'real') data drive analysis methods towards use of robust and nonparametric methods. Exercises are included at the end of chapters. In our course, students compute each type of analysis (t-test, regression, etc.) the first time by hand. We choose the smaller, simpler examples for hand computation. In this way the mechanics of the process are fully understood, and computer software is seen as less mysterious. We wish to acknowledge and thank several other scientists at the U. S. Geological Survey for contributing ideas to this book. In particular, we thank those who have served as the other instructors at the USGS training course. Ed Gilroy has critiqued and improved much of the material found in this book. Tim Cohn has contributed in several areas, particularly to the sections on bias correction in regression, and methods for data below the reporting limit. Richard Alexander has added to the trend analysis chapter, and Charles Crawford has contributed ideas for regression and ANOVA. Their work has undoubtedly made its way into this book without adequate recognition. Professor Ken Potter (University of Wisconsin) and Dr. Gary Tasker (USGS) reviewed the manuscript, spending long hours with no reward except the knowledge that they have improved the work of others. For that we are very grateful. We also thank Madeline Sabin, who carefully typed original drafts of the class notes on which the book is based. As always, the responsibility for all errors and slanted thinking are ours alone.

Techniques of Water-Resources Investigations↗

USGS1978

Evaluation and correlation of water-quality data for the North Fork Flathead River, northwestern Montana

This report is a compilation and evaluation of water-quality measurements that have been made by the U.S. Geological Survey at two stations on the North Fork Flathead River in Montana. Historical streamflow records show an annual mean daily discharge of 3,010 cubic feet per second near the mouth--a threefold increase compared to discharge at the international boundary. The chemical character of the water is dominated by calcium and magnesium cations and the bicarbonate anion. Base flow, in contrast to high flows from runoff, is characterized by higher dissolved constituents and lower concentrations of suspended sediment. The several lakes that contribute water throughout the middle and lower drainage have a dampening effect on both streamflow and constituent concentrations. Using the available data and computer techniques, regression equations were developed between certain water-quality variables. (Woodard-USGS)

Water-Resources Investigations Report↗

USGS1996

Hydrogeologic controls on the groundwater interactions with an acidic lake in karst terrain, Lake Barco, Florida

Transient groundwater interactions and lake stage were simulated for Lake Barco, an acidic seepage lake in the mantled karst of north central Florida. Karst subsidence features affected groundwater flow patterns in the basin and groundwater fluxes to and from the lake. Subsidence features peripheral to the lake intercepted potential groundwater inflow and increased leakage from the shallow perimeter of the lake bed. Simulated groundwater fluxes were checked against net groundwater flow derived from a detailed lake hydrologic budget with short-term lake evaporation computed by the energy budget method. Discrepancies between modeled and budget-derived net groundwater flows indicated that the model underestimated groundwater inflow, possibly contributed to by transient water table mounding near the lake. Recharge from rainfall reduced lake leakage by 10 to 15 times more than it increased groundwater inflow. As a result of the karst setting, the contributing groundwater basin to the lake was 2.4 ha for simulated average rainfall conditions, compared to the topographically derived drainage basin area of 81 ha. Short groundwater inflow path lines and rapid travel times limit the contribution of acid-neutralizing solutes from the basin, making Lake Barco susceptible to increased acidification by acid rain.

Water Resources Research↗

USGS2009

Development and application of a mark-recapture model incorporating predicted sex and transitory behaviour

We developed an extension of Cormack-Jolly-Seber models to handle a complex mark-recapture problem in which (a) the sex of birds cannot be determined prior to first moult, but can be predicted on the basis of body measurements, and (b) a significant portion of captured birds appear to be transients (i.e. are captured once but leave the area or otherwise become ' untrappable'). We applied this methodology to a data set of 4184 serins (Serinus serinus) trapped in northeastern Spain during 1985-96, in order to investigate age-, sex-, and time-specific variation in survival rates. Using this approach, we were able to successfully incorporate the majority of ringings of serins. Had we eliminated birds not previously captured (as has been advocated to avoid the problem of transience) we would have reduced our sample sizes by >2000 releases. In addition, we were able to include 1610 releases of birds of unknown (but predicted) sex; these data contributed to the precision of our estimates and the power of statistical tests. We discuss problems with data structure, encoding of the algorithms to compute parameter estimates, model selection, identifiability of parameters, and goodness-of-fit, and make recommendations for the design and analysis of future studies facing similar problems.

Bird Study↗

USGS2000

Water-surface profile and flood boundaries for the computed 100-year flood, lower Salt River, Lincoln County, Wyoming

The water-surface profile and flood boundaries for the computed 100-year flood were determined for a part of the lower Salt River in Lincoln County, Wyoming. Channel cross-section data were provided by Lincoln County. Cross-section data for bridges and other structures were collected and compiled by the U.S. Geological Survey. Roughness coefficients ranged from 0.034 to 0.100. The 100-year flood was computed using standard methods, ranged from 5,170 to 4,120 cubic feet per second through the study reach, and was adjusted proportional to contributing drainage area. Water-surface elevations were determined by the standard step-backwater method. Flood boundaries were plotted on digital basemaps.

Open-File Report↗

USGS1982

Multi-event urban runoff quality model

A computer model is presented for simulating the quality of surface runoff from urban watersheds. The model can simulate impervious area, pervious area, and precipitation contributions to runoff quality as well as the effects of street sweeping and (or) detention storage. Within-storm variations of runoff quality are simulated for user-specified storm-runoff periods. Between these storms, a daily accounting of the accumulation and washoff of water-quality constituents on effective impervious areas is maintained. The time step of the within-storm simulations can range from 1 to 60 minutes. The model can be operated as a lumped-parameter model or as a distributed-parameter model. As a lumped-parameter model, no spatial variations in model parameters are accounted for, and input to the model requires flow hydrographs only at the outlet of the watershed. The outlet hydrographs can be either observed or simulated. As a distributed-parameter model, the model requires flow hydrographs at many points in the watershed, as defined by basin segmentation. These hydrographs will normally be simulated by the Distributed Routing Rainfall-Runoff Model. This report includes a presentation of the theory and limitations of the model, as well as a program listing, instructions for running the program, and example simulations.

Open-File Report↗

USGS1973

Water resources data for Wyoming, water year 1972; part 1, surface water records

Surface-water records for the 1972 water year for Wyoming, including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, are given in this report. The locations of the gaging stations and partial-record stations are shown in figures 1 and 2. Records for a few pertinent gaging stations in bordering States also are included. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in Wyoming. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Robert L. Cushman, district chief. Wyoming district personnel who contributed significantly to the collection and preparation of data included in this report were: S.A. Druse, D. J. O'Connell, G. S. Craig, Jr., G. W. Armentrout, Jr., H. W. Lowham, B. H. Ringen, P. B. McCollam, C. F. Obert, W. R. Glass, T.W. Custis, R. L. Muench, J. 0. Ragsdale, M. D. Stevens, J. M. Johnson, and J. L. Lynch. Through September 30, 1960, the records of discharge and stage of streams and canals, and contents and stage of lakes or reservoirs, were published in an annual series of U.S. Geological Survey water-supply papers entitled "Surface Water Supply of the United States." Beginning with the 1961 water year, surface-water records have been released by the Geological Survey in annual reports on a State-boundary basis. Distribution of these reports is limited; they are designed primarily for rapid release of data shortly after the end of the water year to meet local needs. Records of discharge and reservoir storage for 1961-65 have been published in a Geological Survey water-supply paper series entitled "Surface Water Supply of the United States 1961-65." Records of discharge and reservoir storage for 1966-70 also will be published in a Geological Survey water-supply paper series entitled "Surface Water Supply of the United States 1966-70."

Wyoming↗

USGS1973

Water resources data for Wyoming, water year 1972; part 2, water quality records

Water-resources data for the 1972 water year for Wyoming include records of data for the chemical and physical characteristics of surface and ground water. Data on the quality of surface water (chemical, temperature, and sediment) were collected from designated sampling sites at predetermined intervals such as once daily, weekly, monthly or less frequently. At some sites water-temperature data were recorded on charts by recorders. Data are given for 138 sampling stations of which 112 are continuous-record stations and 26 are miscellaneous sites. Chemical analyses also are given for 127 ground-water sites. Locations of surface water-quality stations are shown in figure 1 and locations of ground-water sites are shown in figure 2. These data represent that portion of the National Water Data System collected by the U.S. Geological Suryey and cooperating State and Federal agencies in Wyoming. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Robert L. Cushman, district chief. Wyoming district personnel who contributed significantly to the collection and preparation of data included in this report were: E. R. Cox, S. A. Druse, W. G. Hodson, M. E. Lowry, D. J. O'Connell, G. W. Armentrout, Jr., M.A. Crist, B. H. Ringen, W. B. Borchert, W.R. Glass, G. C. Lines, H.B. Fabricius, P. B. McCollam, C. E. Obert, K. G. Polinoski, T. W. Custis, R. L. Muench, J. O. Ragsdale, M. D. Stevens, R .. C. Baumann, D. W. Brownell, R. V. Foresman, J.M. Johnson, J. L. Lynch, M. L. Smalley, and J. P. Kyner. The Geological Survey has published records of chemical quality, water temperatures, and sediment since 1941 in an annual series of water-supply papers entitled, "Quality of Surface Water of the United States." Beginning with the 1964 water year, water-quality records have been released by the Geological Survey in annual reports on a State-boundary basis. These reports are for limited distribution and are designed primarily for rapid release of data shortly after the end of the water year. These records will be published later in Geological Survey water-supply papers.

Wyoming↗

USGS1974

Water resources data for Wyoming, water year 1973; part 1, surface water records

Surface-water records for the 1973 water year for Wyoming, including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, are given in this report. The locations of the gaging stations and partial-record stations are shown in figures 1 and 2. Records for a few pertinent gaging stations in bordering States also are included. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in Wyoming. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Robert L. Cushman, district chief. Wyoming district personnel who contributed significantly to the collection and preparation of data included in this report were: S.A. Druse, D. J. O'Connell, G. S. Craig, Jr., G. W. Armentrout, Jr., H. W. Lowham, J. G. Rankl, P. B. McCollam, C. F. Obert, W. R. Glass, T.W. Custis, R. L. Muench, J. O. Ragsdale, M. D. Stevens, R. C. Bauman, J. L. Lynch, and S. L. Green. Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. These reports are for limited distribution and are designed primarily for rapid release of data shortly after the end of the water year. Records of discharge and stage of streams and canals, and contents and stage of lakes or reservoirs, are published in a series of U.S. Geological Survey water-supply papers entitled "Surface Water Supply of the United States." Through September 30, 1960, these water-supply papers were in an annual series and since then are in a 5-year series. More information is given under the heading "Publications" on page 9.

Wyoming↗

USGS1975

Water resources data for Wyoming, water year 1974

Surface-water records for the 1974 water year for Wyoming, including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, are given in this report. The locations of the gaging stations and partial-record stations are shown in figures 1 and 2. Records for a few pertinent gaging stations in bordering States also are included. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in Wyoming. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Sam W. West, district chief. Wyoming district personnel who contributed significantly to the collection and preparation of data included in this report were: S. A. Druse, D. J. O'Connell, G. S. Craig, Jr., G. W. Armentrout, Jr., H. W. Lowham, J. G. Rankl, P. B. McCollam, C. F. Obert, W. R. Glass, D. J. Pangburn, T. W. Custis, R. L. Muench, J. O. Ragsdale, M. D. Stevens, R. C. Bauman, D. J. Wangsness, L. W. Lenfest, B. C. Pedersen, M. T. O'Grady, and S. L. Green. Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. These reports are for limited distribution and are designed primarily for rapid release of data shortly after the end of the water year. Records of discharge and stage of streams and canals, and contents and stage of lakes or reservoirs, are published in a series of U.S. Geological Survey water-supply papers entitled "Surface Water Supply of the United States." Through September 30, 1960, these water-supply papers were in an annual series and since then are in a 5-year series. More information is given under the heading "Publications" on page 9.

Wyoming↗

USGS2009

Discussion on remote sensing for aquatic monitoring

The special session on Remote Sensing for Aquatic Resource Monitoring concluded with an expert panel discussion. Panel members were Jennifer Bountry (hydraulic engineer, Bureau of Reclamation), Mimi D’Iorio (GIS analyst and database manager, National Oceanic and Atmospheric Administration), Russ Faux (president, Watershed Sciences, Inc.), Steve Lanigan (team leader, Aquatic and Riparian Effectiveness Monitoring Program, U.S. Forest Service), and Amar Nayegandhi (computer scientist, Jacobs Technology, contracted to U.S. Geological Survey). The panel was moderated by Ralph Haugerud (geologist, U.S. Geological Survey) and there were significant contributions from the audience. The dialogue is summarized below in question and answer format. This summary is followed by discussion of what we learned in the course of the special session and identification of some next steps for the Pacific Northwest aquatic monitoring community.

PNAMP Special Publication↗

USGS2011

Modeling sulfate reduction in methane hydrate-bearing continental margin sediments: Does a sulfate-methane transition require anaerobic oxidation of methane?

The sulfate‐methane transition (SMT), a biogeochemical zone where sulfate and methane are metabolized, is commonly observed at shallow depths (1–30 mbsf) in methane‐bearing marine sediments. Two processes consume sulfate at and above the SMT, anaerobic oxidation of methane (AOM) and organoclastic sulfate reduction (OSR). Differentiating the relative contribution of each process is critical to estimate methane flux into the SMT, which, in turn, is necessary to predict deeper occurrences of gas hydrates in continental margin sediments. To evaluate the relative importance of these two sulfate reduction pathways, we developed a diagenetic model to compute the pore water concentrations of sulfate, methane, and dissolved inorganic carbon (DIC). By separately tracking DIC containing 12 C and 13 C, the model also computes δ 13 C‐DIC values. The model reproduces common observations from methane‐rich sediments: a well‐defined SMT with no methane above and no sulfate below and a δ 13 C‐DIC minimum at the SMT. The model also highlights the role of upward diffusing 13 C‐enriched DIC in contributing to the carbon isotope mass balance of DIC. A combination of OSR and AOM, each consuming similar amounts of sulfate, matches observations from Site U1325 (Integrated Ocean Drilling Program Expedition 311, northern Cascadia margin). Without AOM, methane diffuses above the SMT, which contradicts existing field data. The modeling results are generalized with a dimensional analysis to the range of SMT depths and sedimentation rates typical of continental margins. The modeling shows that AOM must be active to establish an SMT wherein methane is quantitatively consumed and the δ 13 C‐DIC minimum occurs. The presence of an SMT generally requires active AOM.

Geochemistry, Geophysics, Geosystems↗