USGS Science⌕ Search

SEARCH · USGS Science

Results for “Carbon”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8Linked to original sources
USGS1993

Stable carbon and oxygen isotope studies of the sediments of Elk Lake, Minnesota

Variations in the ratios of 18 O: 16 O and 13 C: 12 C in calcite throughout the Holocene in Elk Lake, Minnesota, are recorded in three varve-calibrated carbonate cores. Marl in a varved deep-basin (29.6 m) core consists mainly of calcite precipitated from surface waters during the summer and probably provides the least complicated isotope record. Marl in a sublittoral (10 m) core consists of calcite contributed from several inorganic and organic sources and probably is the most complicated of the three isotope records. Calcite from shells of the ostracod Candona ohioensis in the sublittoral core provides a record of shallow-water conditions in Elk Lake for the period between 10,500 and 5500 varve yr. Variations in the 13 C: 12 C ratio of organic carbon deposited in Elk Lake during the Holocene are recorded in organic matter in the deep-basin core. All three oxygen isotope records show that, in general, the 18 O: 16 O ratio in carbonate was enriched in 18 O by several parts per mil during the mid-Holocene relative to the past few thousand years. This pattern of oxygen isotope variation is similar to that observed for carbonate materials from other lakes in the northeastern and north-central United States. Oxygen isotope records from these other lakes also show that the 18 O: 16 O ratio during the early Holocene was lower than during the mid-Holocene, and this pattern has been interpreted as representing a response to a generally warmer and drier climate during the mid-Holocene beginning about 8000 varve yr (the so-called hypsithermal). Ostracod and diatom assemblages from Elk Lake cores show, however, that the lake was colder and more saline than at present until at least 6700 varve yr, with conditions similar to those that exist today in cold prairie lakes of Canada. It may be more appropriate, therefore, to refer to the mid-Holocene in northwestern Minnesota as the “prairie period” rather than the hypsithermal, indicating that the climate was drier, but with no connotation regarding temperature. The oxygen isotope data from the three Elk Lake records for this period are somewhat equivocal. Values of δ 18 O in the marl from the sublittoral core and shells of Candona increase from 10,000 to about 6800 varve yr. However, values of δ 18 O in the marl that accumulated in the deepest part of the lake over the same interval (10,000–6800 varve yr) are more or less constant and enriched in 18 O; this probably reflects the cold, saline prairie-lake conditions predicted from the ostracod and diatom assemblage data. All three oxygen isotope records show decreases in 18 O: 16 O ratios after about 6800 varve yr in response to an increase in temperature and decrease in salinity of the lake. The 13 C: 12 C ratios in carbonates from all three Elk Lake records show a distinct pattern; the ratio increased gradually from 10,000 to 8000 varve yr going into the mid-Holocene prairie period and then decreased gradually coming out of the prairie period between about 5500 and 2500 varve yr. These changes in the 13 C: 12 C ratio could have been related to temperature through its effect on solubility of carbon dioxide; however, this interpretation is not supported by the oxygen isotope data. Another possibility is that changes in the 13 C: 12 C ratio are related to organic productivity that removes 13 C-depleted organic carbon and results in 13 C-enriched surface waters. This interpretation implies that organic productivity was higher in Elk Lake during the mid-Holocene prairie period. Support for the high-productivity, 13 C-enriched surface-water model for the mid-Holocene prairie period in Elk Lake is provided by changes in the 13 C: 12 C ratio of organic carbon in the deep-basin core. These changes parallel almost exactly those in the 13 C: 12 C ratio of carbonate carbon, but are about 2% larger (about 6% as opposed to about 4% for carbonate carbon). The difference of about 2% may represent 13 C depletion due to CO 2 limitation. The percentage of organic carbon in the sediment did not increase during the prairie period because it was diluted by an increased flux of detrital clastic material. The ultimate burial rate of organic carbon increased considerably, however, indicating that organic productivity was higher and/or the degree of preservation increased. Diatom assemblages and plant-pigment concentrations indicate that productivity was higher during the prairie period. Pyrolysis hydrogen and oxygen indices show that the 13 C-enriched organic matter that accumulated during the prairie period was hydrogen rich and oxygen poor relative to organic matter that accumulated before and after. These two indices demonstrate that the organic matter that accumulated during the prairie period was much better preserved.

Minnestoa↗
USGS2014

Sources and sinks of carbon in boreal ecosystems of interior Alaska: a review

Boreal regions store large quantities of carbon but are increasingly vulnerable to carbon loss due to disturbance and climate warming. The boreal region, underlain by discontinuous permafrost, presents a challenging landscape for itemizing current and potential carbon sources and sinks in the boreal soil and vegetation. The roles of fire, forest succession, and the presence (or absence) of permafrost on carbon cycle, vegetation, and hydrologic processes have been the focus of multidisciplinary research in this area for the past 20 years. However, projections of a warming future climate, an increase in fire severity and extent, and the potential degradation of permafrost could lead to major landscape process changes over the next 20 to 50 years. This provides a major challenge for predicting how the interplay between land management activities and impacts of climate warming will affect carbon sources and sinks in Interior Alaska. To assist land managers in adapting and managing for potential changes in the Interior Alaska carbon cycle we developed this review paper incorporating an overview of the climate, ecosystem processes, vegetation types, and soil regimes in Interior Alaska with a focus on ramifications for the carbon cycle. Our objective is to provide a synthesis of the most current carbon storage estimates and measurements to support policy and land management decisions on how to best manage carbon sources and sinks in Interior Alaska. To support this we have surveyed relevant peer reviewed estimates of carbon stocks in aboveground and belowground biomass for Interior Alaska boreal ecosystems. We have also summarized methane and carbon dioxide fluxes from the same ecosystems. These data have been converted into the same units to facilitate comparison across ecosystem compartments. We identify potential changes in the carbon cycle with climate change and human disturbance including how compounding disturbances can affect the boreal system. Finally, we provide recommendations to address the challenges facing land managers in efforts to manage carbon cycle processes. The results of this study can be used for carbon cycle management in other locations within the boreal biome which encompass a broad distribution from 45° to 83° north.

Alaska↗
USGS2012

Weathering, landscape equilibrium, and carbon in four watersheds in eastern Puerto Rico: Chapter H in Water quality and landscape processes of four watersheds in eastern Puerto Rico

The U.S. Geological Survey's Water, Energy, and Biogeochemical Budgets (WEBB) program research in eastern Puerto Rico involves a double pair-wise comparison of four montane river basins, two on granitic bedrock and two on fine-grained volcaniclastic bedrock; for each rock type, one is forested and the other is developed. A confounding factor in this comparison is that the developed watersheds are substantially drier than the forested (runoff of 900–1,600 millimeters per year compared with 2,800–3,700 millimeters per year). To reduce the effects of contrasting runoff, the relation between annual runoff and annual constituent yield were used to estimate mean-annual yields at a common, intermediate mean-annual runoff of 1,860 millimeters per year. Upon projection to this intermediate runoff, the ranges of mean-annual yields among all watersheds became more compact or did not substantially change for dissolved bedrock, sodium, silica, chloride, dissolved organic carbon, and calcium. These constituents are the primary indicators of chemical weathering, biological activity on the landscape, and atmospheric inputs; the narrow ranges indicate little preferential influence by either geology or land cover. The projected yields of biologically active constituents (potassium, nitrate, ammonium ion, phosphate), and particulate constituents (suspended bedrock and particulate organic carbon) were considerably greater for developed landscapes compared with forested watersheds, consistent with the known effects of land clearing and human waste inputs. Equilibrium rates of combined chemical and physical weathering were estimated by using a method based on concentrations of silicon and sodium in bedrock, river-borne solids, and river-borne solutes. The observed rates of landscape denudation greatly exceed rates expected for a dynamic equilibrium, except possibly for the forested watershed on volcaniclastic rock. Deforestation and agriculture can explain the accelerated physical erosion in the two developed watersheds. Because there has been no appreciable deforestation, something else, possibly climate or forest-quality change, must explain the accelerated erosion in the forested watersheds on granitic rocks. Particulate organic carbon yields are closely linked to sediment yields. This relation implies that much of the particulate organic carbon transport in the four rivers is being caused by this enhanced erosion aided by landslides and fast carbon recovery. The increase in particulate organic carbon yields over equilibrium is estimated to range from 300 kilomoles per square kilometer per year (6 metric tons carbon per square kilometer per year) to 1,700 kilomoles per square kilometer per year (22 metric tons carbon per square kilometer per year) and is consistent with human-accelerated particulate-organic-carbon erosion and burial observed globally. There is no strong evidence of human perturbation of silicate weathering in the four study watersheds, and differences in dissolved inorganic carbon are consistent with watershed geology. Although dissolved organic carbon is slightly elevated in the developed watersheds, that elevation is not enough to unambiguously demonstrate human causes; more work is needed. Accordingly, the dissolved organic carbon and dissolved inorganic carbon yields of tropical rivers, although large, are of secondary importance in the study of the anthropgenically perturbed carbon cycle.

Professional Paper↗
USGS2023

The blue carbon reservoirs from Maine to Long Island, NY

In response to the New England Governor and Eastern Canadian Premier 2017 Climate Change Action Plan recommendation to “manage blue carbon resources to preserve and enhance their existing carbon reservoirs,” the U.S. Environmental Protection Agency (EPA) convened a New England Blue Carbon Inventory Workgroup, comprised of a variety of federal, state, academic, and non-profit organizations to develop an inventory of blue carbon stocks from Maine to Long Island, New York. The Workgroup focused its inventory efforts on salt marshes and eelgrass meadows, leveraging existing habitat maps for geographic data. Existing data for soil organic carbon stocks were then used to calculate blue carbon stock estimates. For visual display purposes, sediment carbon heat maps were developed to highlight areas of greatest carbon accumulation. The habitat distribution and sediment carbon heat maps can be accessed on the Northeast Ocean Data Portal (www.northeastoceandata.org/eelgrass) which is a public source of expert-reviewed, interactive maps and data on the ocean ecosystem, economy, and culture of the northeastern United States and can be used to facilitate decision making by government agencies, tribal nations, businesses, non-governmental organizations (NGOs), academic institutions, and individuals. Based on available data and Workgroup calculations, the target geographic area has an estimated 218,222 acres of eelgrass meadows, salt marsh and saline Phragmites, which are estimated to provide a reservoir of 7,523,568 megagrams of blue carbon, or the equivalent to the annual carbon emissions from over 5,944,024 passenger vehicles. Due to data limitations, the carbon stock estimate represents a mere fraction of the actual quantity of accumulated carbon in these habitats. The findings from the Workgroup’s efforts and the resulting map products can help inform land and coastal management policies, fisheries management, and climate change mitigation practices. Further refinements and expansion of data are needed, including more detailed habitat maps, deeper soil core data for soil organic carbon content, and inclusion of more marine flora into calculations.

Connecticut, Maine, Massachusetts, New Hampshire, ↗
USGS2017

Contributions of wildland fire to terrestrial ecosystem carbon dynamics in North America from 1990 to 2012

Burn area and the frequency of extreme fire events have been increasing during recent decades in North America, and this trend is expected to continue over the 21st century. While many aspects of the North American carbon budget have been intensively studied, the net contribution of fire disturbance to the overall net carbon flux at the continental scale remains uncertain. Based on national scale, spatially explicit and long-term fire data, along with the improved model parameterization in a process-based ecosystem model, we simulated the impact of fire disturbance on both direct carbon emissions and net terrestrial ecosystem carbon balance in North America. Fire-caused direct carbon emissions were 106.55 ± 15.98 Tg C/yr during 1990–2012; however, the net ecosystem carbon balance associated with fire was −26.09 ± 5.22 Tg C/yr, indicating that most of the emitted carbon was resequestered by the terrestrial ecosystem. Direct carbon emissions showed an increase in Alaska and Canada during 1990–2012 as compared to prior periods due to more extreme fire events, resulting in a large carbon source from these two regions. Among biomes, the largest carbon source was found to be from the boreal forest, primarily due to large reductions in soil organic matter during, and with slower recovery after, fire events. The interactions between fire and environmental factors reduced the fire-caused ecosystem carbon source. Fire disturbance only caused a weak carbon source as compared to the best estimate terrestrial carbon sink in North America owing to the long-term legacy effects of historical burn area coupled with fast ecosystem recovery during 1990–2012.

Global Biogeochemical Cycles↗
USGS2026

Tidal forested wetlands can be incorporated into blue carbon conservation and restoration strategies

Purpose of Review Blue carbon is an important concept for environmental policy. Blue carbon strategies (conservation and restoration for carbon gain) have been primarily implemented with mangroves, though are likely to be suitable for other tidal forested wetlands. Here, we discuss the expanding definition of blue carbon encompassing all tidal forested wetlands, synthesize ecological and carbon sink knowledge of tidal forested wetlands, and reflect on key actions in mangrove blue carbon research and implementation that could be applied to other tidal forested wetlands. Recent Findings Conceptually, the blue carbon concept has now expanded beyond traditional coastal vegetated ecosystems to include all tidal wetlands, including tidal forested wetlands. Emerging data on carbon sequestration, emissions, and budgets from around the world now show that many tidal forested wetland ecosystems are carbon sinks at a magnitude similar to mangroves. At the global scale, mangroves have become incorporated into blue carbon strategies rapidly compared to other tidal forested wetlands, facilitated by agenda-setting papers, adequate data addressing concerns on emissions and permanence, the availability of global maps, a clear ecosystem definition, clear accounting and policy frameworks, and international stakeholders who acted as high profile ecosystem advocates, alongside long-term capacity building efforts. This provides a roadmap for implementation in other tidal forested wetlands. Summary Tidal forested wetlands other than mangroves have high potential for blue carbon management. Many tidal forested wetlands share biophysical similarities with mangroves, carbon stocks can be similar, and methane emissions are often no higher. An increasing evidence base, challenging assumptions around greenhouse gas fluxes, and robust engagement with policy actors and frameworks, could increase the use of blue carbon for tidal forested wetland conservation and restoration.

Current Forestry Reports↗
USGS2015

Normalization of stable isotope data for carbonate minerals: implementation of IUPAC guideline

Carbonate minerals provide a rich source of geochemical information because their δ 13 C and δ 18 O values provide information about surface and subsurface Earth processes. However, a significant problem is that the same δ 18 O value is not reported for the identical carbonate sample when analyzed in different isotope laboratories in spite of the fact that the International Union of Pure and Applied Chemistry (IUPAC) has provided reporting guidelines for two decades. This issue arises because (1) the δ 18 O measurements are performed on CO 2 evolved by reaction of carbonates with phosphoric acid, (2) the acid-liberated CO 2 is isotopically fractionated (enriched in 18 O) because it contains only two-thirds of the oxygen from the solid carbonate, (3) this oxygen isotopic fractionation factor is a function of mineralogy, temperature, concentration of the phosphoric acid, and δ 18 O value of water in the phosphoric acid, (4) researchers may use any one of an assortment of oxygen isotopic fractionation factors that have been published for various minerals at various reaction temperatures, and (5) it sometimes is not clear how one should calculate δ 18 O VPDB values on a scale normalized such that the δ 18 O value of SLAP reference water is −55.5 ‰ relative to VSMOW reference water. To enable researchers worldwide to publish the same δ 18 O value (within experimental uncertainty) for the same carbonate sample, we have re-evaluated reported acid fractionation factors for calcite at 25, 50, and 75 °C and propose a revised relation for the temperature dependence of oxygen isotopic acid fractionation factor, α CO 2 ( ACID ) -calcite αCO2(ACID)-calcite , of 1000ln α CO 2 ( ACID ) -calcite=3.48(10 3 /T)-1.47 1000lnαCO2(ACID)-calcite=3.48(103/T)-1.47 Turn MathJax on where T is temperature in kelvin. At 25 °C, α CO 2 ( ACID ) -calcite=1.01025 αCO2(ACID)-calcite=1.01025 , the most commonly accepted value for this quantity. We propose a normalization protocol in which (1) the internationally distributed carbonate isotopic reference materials NBS 18 and NBS 19 are interspersed among carbonate samples analyzed by treatment with phosphoric acid, (2) the δ 18 O values of the calcite reference materials and the carbonate samples are calculated, respectively, by using the α CO 2 ( ACID ) -calcite αCO2(ACID)-calcite relation above and oxygen-isotope acid fractionation factors appropriate for the sample mineralogy and reaction temperature, (3) the δ 18 O values of solid carbonate samples are determined on the VPDB scale ( δ 18 O VPDB ) with IUPAC-recommended scale expansion such that the δ 18 O of SLAP reference water is −55.5 ‰ relative to VSMOW reference water by normalizing δ 18 O values of carbonate samples with 2014-IUPAC-recommended δ 18 O values of NBS 18 and NBS 19, and (4) δ 18 O values on the VPDB scale are converted to δ 18 O values on the VSMOW-SLAP scale by using IUPAC recommendations. To ease calculations in the protocol, a software application titled “Carbon and Oxygen Isotopic Normalization Tool for Carbonates” is available that relies upon IUPAC-recommended δ 13 C and δ 18 O values of carbonate isotopic reference materials ( http://isotopes.usgs.gov/research/topics/carbonatesnormalizationtool.html ).

Geochimica et Cosmochimica Acta↗
USGS2015

Storage and release of organic carbon from glaciers and ice sheets

Polar ice sheets and mountain glaciers, which cover roughly 11% of the Earth's land surface, store organic carbon from local and distant sources and then release it to downstream environments. Climate-driven changes to glacier runoff are expected to be larger than climate impacts on other components of the hydrological cycle, and may represent an important flux of organic carbon. A compilation of published data on dissolved organic carbon from glaciers across five continents reveals that mountain and polar glaciers represent a quantitatively important store of organic carbon. The Antarctic Ice Sheet is the repository of most of the roughly 6 petagrams (Pg) of organic carbon stored in glacier ice, but the annual release of glacier organic carbon is dominated by mountain glaciers in the case of dissolved organic carbon and the Greenland Ice Sheet in the case of particulate organic carbon. Climate change contributes to these fluxes: approximately 13% of the annual flux of glacier dissolved organic carbon is a result of glacier mass loss. These losses are expected to accelerate, leading to a cumulative loss of roughly 15 teragrams (Tg) of glacial dissolved organic carbon by 2050 due to climate change — equivalent to about half of the annual flux of dissolved organic carbon from the Amazon River. Thus, glaciers constitute a key link between terrestrial and aquatic carbon fluxes, and will be of increasing importance in land-to-ocean fluxes of organic carbon in glacierized regions.

Nature Geoscience↗
USGS2012

11 things a geologist thinks an engineer should know about carbonate beaches

This is a review of the geological aspects of carbonate beaches that a geologist thinks may be useful for an engineer. Classical geologic problems of carbonate beaches, for example how ancient examples are recognized in rock sequences, are of little interest to engineers. Geologists not involved in engineering problems may find it difficult to know what an engineer should understand about carbonate beaches. Nevertheless, there are at least eleven topics that are potentially very useful for engineers to keep in mind. These eleven are chosen with as much thought going into what has been omitted as has been given to the eleven included topics. Some qualifications are in order: First, this paper does not discuss certain kinds of carbonate shorelines that are beyond the scope of engineering issues. For example, this review does not discuss very high-energy carbonate boulder beaches. These beaches are comprised of pieces of carbonate material ganging in size from ten centimeters to meters. Typically, these are high-energy storm deposits formed from pieces of either eroded carbonate rock or other large carbonate pieces such as pieces of large corals. This paper focuses on sand-sized (0.0625–2.0 mm) coastal carbonate deposits. Second, offshore beaches will not be discussed. There are many carbonate beaches that form on banks or shoals exposed at low tide, but our discussion is confined to what most people think of when they go to some tropical island and/or resort and walk out to lay on the beach. Third, this paper does not consider mixed carbonate/quartz sand beaches. While mixed beaches are common, only the end member of purely carbonate sand beaches is considered. Fourth, there will be no order of preference of the eleven topics. And lastly, these eleven topics are not consensus items. These are simply one geologist s thoughts about the aspects of carbonate beaches that would be useful for engineering colleagues to keep in mind. Where possible, general reference is made to textbooks that will lead the reader to extensive literature on carbonate sediments. Several of the topics are not so broad as to have had a large general treatment in texts, and in those cases some original literature is cited.

Conference Paper↗
USGS2018

Dependence of the evolution of carbon dynamics in the northern permafrost region on the trajectory of climate change

We conducted a model-based assessment of changes in permafrost area and carbon storage for simulations driven by RCP4.5 and RCP8.5 projections between 2010 and 2299 for the northern permafrost region. All models simulating carbon represented soil with depth, a critical structural feature needed to represent the permafrost carbon–climate feedback, but that is not a universal feature of all climate models. Between 2010 and 2299, simulations indicated losses of permafrost between 3 and 5 million km 2 for the RCP4.5 climate and between 6 and 16 million km 2 for the RCP8.5 climate. For the RCP4.5 projection, cumulative change in soil carbon varied between 66-Pg C (10 15 -g carbon) loss to 70-Pg C gain. For the RCP8.5 projection, losses in soil carbon varied between 74 and 652 Pg C (mean loss, 341 Pg C). For the RCP4.5 projection, gains in vegetation carbon were largely responsible for the overall projected net gains in ecosystem carbon by 2299 (8- to 244-Pg C gains). In contrast, for the RCP8.5 projection, gains in vegetation carbon were not great enough to compensate for the losses of carbon projected by four of the five models; changes in ecosystem carbon ranged from a 641-Pg C loss to a 167-Pg C gain (mean, 208-Pg C loss). The models indicate that substantial net losses of ecosystem carbon would not occur until after 2100. This assessment suggests that effective mitigation efforts during the remainder of this century could attenuate the negative consequences of the permafrost carbon–climate feedback.

Proceedings of the National Academy of Sciences of↗
USGS2020

Increased burning in a warming climate reduces carbon uptake in the Greater Yellowstone Ecosystem despite productivity gains

1. The effects of changing climate and disturbance on mountain forest carbon stocks vary with tree species distributions and over elevational gradients. Warming can increase carbon uptake by stimulating productivity at high elevations but also enhance carbon release by increasing respiration and the frequency, intensity, and size of wildfires. 2. To understand the consequences of climate change for temperate mountain forests, we simulated interactions among climate, wildfire, tree species, and their combined effects on regional carbon stocks in forests of the Greater Yellowstone Ecosystem, USA with the LANDIS‐II landscape change model. Simulations used historical climate and future potential climate represented by downscaled projections from five general circulation models (GCMs) that bracket the range of variability under the representative concentration pathway (RCP) 8.5 emissions scenario. 3. Total ecosystem carbon increased by 67% through 2100 in simulations with historical climate, and by 38 – 69% with GCM climate. Differences in carbon uptake among GCMs resulted primarily from variation in area burned, not productivity. Warming increased productivity by extending the growing season, especially near upper treeline, but did not offset biomass losses to fire. By 2100, simulated area burned increased by 27 – 215% under GCM climate, with the largest increases after 2050. With warming >3 °C in mean annual temperature, the increased frequency of large fires reduced live carbon stocks by 4 – 36% relative to the control, historical climate scenario. However, relative losses in total carbon were delayed under GCMs with large increases in summer precipitation and buffered by carbon retained in soils and the wood of fire‐killed trees. Increasing fire size limited seed dispersal, and reductions in soil moisture limited seedling establishment; both effects will likely constrain long‐term forest regeneration and carbon uptake. 4. Synthesis. Forests in the GYE can maintain a carbon sink through the mid‐century in a warming climate but continued warming may cause the loss of forest area, live aboveground biomass, and ultimately, ecosystem carbon. Future changes in carbon stocks in similar forests throughout western North America will depend on regional thresholds for extensive wildfire and forest regeneration and therefore, changes may occur earlier in drier regions.

Idaho, Montana, Wyoming↗
USGS2025

Land change, fire, and climate weaken carbon sink in the conterminous U.S.

The land carbon sink of the conterminous United States was evaluated using a bottom-up modeling framework and 30-meter land change data from 1985 to 2020. This cross-scale, cross-landscape, and cross-system approach tracked fractional land cover changes and applied regional model calibration. Results show average terrestrial and aquatic carbon sinks of +110 ± 37 and +19 ± 0.5 teragrams of carbon per year, respectively. The terrestrial carbon sink, showing no clear trend, peaked in the 1990s, with more years as a carbon source since 2000, contradicting recent national and global studies. Land change had the largest impact (−70 ± 5.5 teragrams of carbon per year), exceeding impacts of climate (−33 ± 48 teragrams of carbon per year), wildfire (−7.7 ± 2.4 teragrams of carbon per year), and erosion transport (−1.9 ± 0.13 teragrams of carbon per year). The positive CO2 fertilization effect (+69 ± 12 teragrams of carbon per year) was insufficient to maintain the carbon sink strength. Our framework reveals key paths of carbon loss, with implications for carbon budget and energy policies in the United States and beyond.

conterminous United States↗
USGS2021

Hydraulic characterization of carbonate-rock and basin-fill aquifers near Long Canyon, Goshute Valley, northeastern Nevada

Understanding groundwater flow and pumping effects near pending mining operations requires accurate subsurface hydraulic characterization. To improve conceptual models of groundwater flow and development in the complex hydrogeologic system near Long Canyon Mine, in northwestern Goshute Valley, northeastern Nevada, the U.S. Geological Survey characterized the hydraulic properties of carbonate rocks and basin-fill aquifers using an integrated analysis of steady-state and stressed aquifer conditions informed by water chemistry and aquifer-test data. Hydraulic gradients and groundwater-age data in northern Goshute Valley indicate carbonate rocks in the Pequop Mountains just west and south of the Long Canyon Mine project area constitute a more permeable and active flow system than saturated rocks in the northern Pequop Mountains, western Toano Range, and basin fill. Permeable carbonate rocks in the northern Pequop Mountains, in part, discharge to the Johnson Springs wetland complex (JSWC), where mean groundwater ages range from 500 to 2,400 years and samples all contain a small fraction of modern waters, relative to mean ages of 8,600 to more than 22,000 years for most groundwater sampled to the north and east. Recharge to the JSWC occurs from a roughly 27-square-mile area in the upgradient Pequop Mountains to the west, composed mostly of permeable carbonate rock and fractured quartzite, and bounded by low-permeability shales and marbleized and siliclastic rocks. Single-well aquifer-test analyses provided transmissivity estimates at pumped wells. Transmissivity estimates ranged from 7,000 to 400,000 feet squared per day (ft 2 /d) in carbonate rocks and from 2,000 to 80,000 ft 2 /d in basin fill near the Long Canyon Mine. Water-level drawdown from multiple-well aquifer testing and rise from unintentional leakage into the overlying basin-fill aquifer were estimated and distinguished from natural fluctuations in 93 pumping and monitoring sites using analytical water-level models. Leakage of disposed aquifer-test pumpage occurred south of the aquifer test area through an unlined irrigation ditch. Drawdown was detected at distances of as much as 3 miles (mi) from pumping wells at all but one carbonate-rock site, at basin-fill sites on the alluvial fan immediately downgradient from pumping wells, and in Big Spring and spring NS-05. Similar drawdowns in carbonate rocks within the drawdown detection area suggest all wells penetrate a highly transmissive zone (HTZ) that is bounded by low-permeability rocks. Drawdown was not detected in carbonate rocks to the west of Canyon fault, in any basin-fill sites on the valley floor east of the Hardy fault, or at volcanic sites to the north, indicating that these major fault structures and (or) permeability contrasts between hydrogeologic units impeded groundwater flow or obscured pumping signals. Alternatively, unintentional leakage might have obscured drawdown at basin-fill sites on the valley floor, where water-level rise was detected at nine sites over 3 mi. Consistent hydraulic properties were estimated by simultaneously interpreting steady-state flow during predevelopment conditions and changes in groundwater levels and springflows from the 2016 carbonate-rock aquifer test with an integrated groundwater-flow model. Hydraulic properties were distributed across carbonate rocks, basin fill, volcanic rocks, and siliciclastic rocks with a hydrogeologic framework developed from geologic mapping and hydraulic testing. Estimated transmissivity distributions spanned at least three orders of magnitude in each rock unit. In the HTZ, simulated transmissivities ranged from 10,000 to 23,000,000 ft 2 /d, with the most transmissive areas occurring around Big Spring. Comparatively low carbonate-rock transmissivities of less than 10,000 ft 2 /d were estimated in the northern Pequop Mountains and poorly defined values of less than 1,000 ft 2 /d were estimated in the western Toano Range. Transmissivities in basin fill ranged from less than 10 to 80,000 ft 2 /d and were minimally constrained by the 2016 carbonate-rock aquifer test because poorly quantified leakage affected water levels more so than pumping. The most transmissive areas were informed by single-well aquifer tests along the eastern edge of the Pequop Mountains near Long Canyon Mine and could be indicative of a hydraulic connection between basin fill and more transmissive underlying carbonate rocks. Simulated transmissivities of volcanic and low-permeability rocks mostly are less than 1,000 ft 2 /d. The estimated hydraulic-property distributions and informed interpretation of hydraulic connections among hydrogeologic units improved the characterization and representation of groundwater flow near the Long Canyon Mine.

Nevada↗
USGS1956

Water requirements of the carbon-black industry

Carbon blacks include an important group of industrial carbons used chiefly as a reinforcing agent in rubber tires. In 1953 more than 1,610 million pounds of carbon black was produced, of which approximately 1,134 million pounds was consumed by the rubber industry. The carbon-black industry uses small quantities of water as compared to some industries; however, the water requirements of the industry are important because of the dependence of the rubber-tire industry on carbon black. Two methods are used in the manufacture of carbon black - contact and furnace. The only process use of water in the contact method is that used in pelleting. Water is used also in the plant washhouse and for cleaning, and sometimes the company camp may be supplied by the plant. A survey made during the last quarter of 1953 showed that the average values of unit water use at contact plants for process use, all plant uses, and all uses including company camps are 0.08, 0.14, and 0.98 gallon of water per pound of carbon black respectively. In addition to use in wet pelleting, large quantities of water are required in continuous and cyclic furnace methods to reduce the temperature of the gases of decomposition in order to separate and collect the entrained carbon black. The 22 furnace plants in operation in 1953 used a total of 12.4 million gallons per day for process use. Four furnace plants generate electric power for plant use; condenser-cooling water for one such plant may nearly equal the requirements of the entire industry for process use. The average values of unit water use at furnace plants for process use, all plant uses and all uses including company camps but excluding power generation are 3.26, 3.34, and 3.45 gallons of water per pound of carbon black respectively. Carbon-black plants in remote, sparsely settled areas often must maintain company camps for employees. Twenty-one of twenty-seven contact plants surveyed in 1953 had company camps. These camps used large quantities of water: 0.84 gallon per pound of carbon black as compared to 0.14 gallon per pound used in the plants. Furnace plants can generally be located near a labor supply and, therefore, do not require company camps. Ten of the twenty-two furnace plants surveyed in 1953 had company camps. Because water used for pelleting and gas quenching is evaporated, leaving the dissolved minerals in the product as objectionable impurities, particular attention was paid to the quality of water available for use at the plants visited during the 1953 survey. Reports of chemical analyses of water samples were obtained at 23 plants. A study of these reports does not develop a pattern of the limits of tolerance of dissolved solids in water used in process or of the need for water treatment based on geographical location of the plant. However these analyses show that water used for quenching contains less dissolved solids than water used by the industry for any other purpose. Based on trends in the industry it is expected that the quantity of water used by the carbon-black industry will increase more rapidly than will the quantity of carbon black produced because of the increasing percentage produced in furnace plants, and that selection of sites for modern furnace plants will be influenced more by quantity and quality of the available water supply than was the case in selecting sites for contact plants for which low-cost natural gas was the primary consideration.

Water Supply Paper↗
USGS2013

Simulating boreal forest carbon dynamics after stand-replacing fire disturbance: insights from a global process-based vegetation model

Stand-replacing fires are the dominant fire type in North American boreal forests. They leave a historical legacy of a mosaic landscape of different aged forest cohorts. This forest age dynamics must be included in vegetation models to accurately quantify the role of fire in the historical and current regional forest carbon balance. The present study adapted the global process-based vegetation model ORCHIDEE to simulate the CO 2 emissions from boreal forest fire and the subsequent recovery after a stand-replacing fire; the model represents postfire new cohort establishment, forest stand structure and the self-thinning process. Simulation results are evaluated against observations of three clusters of postfire forest chronosequences in Canada and Alaska. The variables evaluated include: fire carbon emissions, CO 2 fluxes (gross primary production, total ecosystem respiration and net ecosystem exchange), leaf area index, and biometric measurements (aboveground biomass carbon, forest floor carbon, woody debris carbon, stand individual density, stand basal area, and mean diameter at breast height). When forced by local climate and the atmospheric CO 2 history at each chronosequence site, the model simulations generally match the observed CO 2 fluxes and carbon stock data well, with model-measurement mean square root of deviation comparable with the measurement accuracy (for CO 2 flux ~100 g C m −2 yr −1 , for biomass carbon ~1000 g C m −2 and for soil carbon ~2000 g C m −2 ). We find that the current postfire forest carbon sink at the evaluation sites, as observed by chronosequence methods, is mainly due to a combination of historical CO 2 increase and forest succession. Climate change and variability during this period offsets some of these expected carbon gains. The negative impacts of climate were a likely consequence of increasing water stress caused by significant temperature increases that were not matched by concurrent increases in precipitation. Our simulation results demonstrate that a global vegetation model such as ORCHIDEE is able to capture the essential ecosystem processes in fire-disturbed boreal forests and produces satisfactory results in terms of both carbon fluxes and carbon-stock evolution after fire. This makes the model suitable for regional simulations in boreal regions where fire regimes play a key role in the ecosystem carbon balance.

Biogeosciences↗
USGS2008

Co-precipitation of dissolved organic matter by calcium carbonate in Pyramid Lake, Nevada

Our previous research has demonstrated that dissolved organic matter (DOM) influences calcium carbonate mineral formation in surface and ground water. To better understand DOM mediation of carbonate precipitation and DOM co-precipitation and/or incorporation with carbonate minerals, we characterized the content and speciation of DOM in carbonate minerals and in the lake water of Pyramid Lake, Nevada, USA. A 400-gram block of precipitated calcium carbonate from the Pyramid Lake shore was dissolved in 8 liters of 10% acetic acid. Particulate matter not dissolved by acetic acid was removed by centrifugation. DOM from the carbonate rock was fractionated into nine portions using evaporation, dialysis, resin adsorption, and selective precipitations to remove acetic acid and inorganic constituents. The calcium carbonate rock contained 0.23% DOM by weight. This DOM was enriched in polycarboxylic proteinaceous acids and hydroxy-acids in comparison with the present lake water. DOM in lake water was composed of aliphatic, alicyclic polycarboxylic acids. These compound classes were found in previous studies to inhibit calcium carbonate precipitation. DOM fractions from the carbonate rock were 14 C-age dated at about 3,100 to 3,500 years before present. The mechanism of DOM co-precipitation and/or physical incorporation in the calcium carbonate is believed to be due to formation of insoluble calcium complexes with polycarboxylic proteinaceous acids and hydroxy-acids that have moderately large stability constants at the alkaline pH of the lake. DOM co-precipitation with calcium carbonate and incorporation in precipitated carbonate minerals removes proteinaceous DOM, but nearly equivalent concentrations of neutral and acidic forms of organic nitrogen in DOM remain in solution. Calcium carbonate precipitation during lime softening pretreatment of drinking water may have practical applications for removal of proteinaceous disinfection by-product precursors.

Nevada↗
USGS2017

A carbon balance model for the great dismal swamp ecosystem

Background Carbon storage potential has become an important consideration for land management and planning in the United States. The ability to assess ecosystem carbon balance can help land managers understand the benefits and tradeoffs between different management strategies. This paper demonstrates an application of the Land Use and Carbon Scenario Simulator (LUCAS) model developed for local-scale land management at the Great Dismal Swamp National Wildlife Refuge. We estimate the net ecosystem carbon balance by considering past ecosystem disturbances resulting from storm damage, fire, and land management actions including hydrologic inundation, vegetation clearing, and replanting. Results We modeled the annual ecosystem carbon stock and flow rates for the 30-year historic time period of 1985–2015, using age-structured forest growth curves and known data for disturbance events and management activities. The 30-year total net ecosystem production was estimated to be a net sink of 0.97 Tg C. When a hurricane and six historic fire events were considered in the simulation, the Great Dismal Swamp became a net source of 0.89 Tg C. The cumulative above and below-ground carbon loss estimated from the South One and Lateral West fire events totaled 1.70 Tg C, while management activities removed an additional 0.01 Tg C. The carbon loss in below-ground biomass alone totaled 1.38 Tg C, with the balance (0.31 Tg C) coming from above-ground biomass and detritus. Conclusions Natural disturbances substantially impact net ecosystem carbon balance in the Great Dismal Swamp. Through alternative management actions such as re-wetting, below-ground biomass loss may have been avoided, resulting in the added carbon storage capacity of 1.38 Tg. Based on two model assumptions used to simulate the peat system, (a burn scar totaling 70 cm in depth, and the soil carbon accumulation rate of 0.36 t C/ha −1 /year −1 for Atlantic white cedar), the total soil carbon loss from the South One and Lateral West fires would take approximately 1740 years to re-amass. Due to the impractical time horizon this presents for land managers, this particular loss is considered permanent. Going forward, the baseline carbon stock and flow parameters presented here will be used as reference conditions to model future scenarios of land management and disturbance.

North Carolina, Virginia↗
USGS2017

Disrupted carbon cycling in restored and unrestored urban streams: Critical timescales and controls

Carbon fixation and respiration in flowing waterways play significant roles in global and regional carbon budgets, yet how land use and watershed management interact with temporal disturbances (storms) to influence metabolism remains poorly understood. Here, we combine long-term with synoptic sampling of metabolism and its variable controls in neighboring watersheds of the Chesapeake Bay to resolve limiting factors and critical timescales associated with recovery from disturbance. We found that, relative to predictions of the river continuum concept, focal streams have “disrupted” carbon cycles, with carbon balances closer to zero, and, in some cases, tighter coupling between gross primary production (GPP) and ecosystem respiration (ER), attributable to carbon limitation. Carbon became limiting to ER where flashy storm hydrographs and simplified channel geomorphology inhibited accumulation of fine sediment. Shannon entropy analysis of timescales revealed that fine sediment served as a time-release capsule for nutrients and carbon over 4–6 months, fueling biogeochemical transformations. Loss of fines through hydraulic disturbance had up to 30-d impacts on GPP and 50-d impacts on ER in the stream with carbon limitation. In contrast, where GPP and ER were not tightly coupled, recovery occurred within 1 d. Results suggest that a complex interplay between nutrient and carbon limitation and mechanical and chemical disturbance governs patterns and consequences of disrupted carbon cycling in urban streams. Carbon limitation and tight GPP/ER coupling enhance the vulnerability of stream ecosystem functions, but best management practices that target stormflow reduction and channel geomorphic diversity can break that coupling and minimize carbon cycle disruptions.

Limnology and Oceanography↗