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At least 1,423 records · Page 79Linked to original sources

Priority-pollutant trace elements in streambed sediments of the Cook Inlet basin, Alaska, 1998-2000

Trace element concentrations in 48 streambed sediment samples collected at 47 sites in the Cook Inlet Basin, Alaska, were compared to concentrations from studies in the conterminous United States using identical methods and to Probable Effect Concentrations. Concentrations of arsenic, chromium, mercury, and nickel in the 0.063-mm size fraction of streambed sediments from the Cook Inlet Basin were elevated relative to reference sites in the conterminous United States. Concentrations of cadmium, lead, and zinc were highest at the most urbanized site in Anchorage and at two sites downstream from an ore body in Lake Clark National Park and Preserve. At least 35 percent of the 48 samples collected in the Cook Inlet Basin exceeded the Probable Effect Concentration for arsenic, chromium, or nickel. More than 50 percent of the samples were considered to have low potential toxicity for cadmium, lead, mercury, nickel, selenium, and zinc. A Probable Effect Concentration quotient that reflects the combined toxicity of arsenic, cadmium, chromium, copper, lead, mercury, nickel, and zinc was exceeded in 44 percent of the samples from the Cook Inlet Basin. The potential toxicity was high in the Denali and Lake Clark National Parks and Preserves where organic carbon concentrations in streambed sediments were low. However, potential toxicity results should be considered in context with the very small amounts of fine-grained sediment present in the streambed sediments of the Cook Inlet Basin.

Water-Resources Investigations Report↗

Assessing per- and polyfluoroalkyl substances (PFAS) in sediments and fishes in a large, urbanized estuary and the potential human health implications

The primary source of chronic exposures to per- and polyfluoroalkyl substances (PFASs) in humans is through the ingestion of contaminated foods and drinking water, with fish and other seafood being a major contributor. Nevertheless, there is scant literature on the dietary exposure to PFASs for the general United States (U.S.) population. The Tampa Bay (Florida, USA) region has the highest population density in the State and communities and their attendant support services are arrayed in an urban to semi-rural continuum from the head of the Bay to the ocean mouth. Tampa Bay supports productive recreational and commercial fisheries, providing a diverse community of species. A variety of potential PFAS sources surround Tampa Bay including airports, industry, wastewater treatment plants, fire-fighting training areas and military installations. The objective of this study is to quantify PFASs in sediment and fishes collected from Tampa Bay to further estimate human health risks from dietary exposures. Sediment ( n = 17) and fish (24 species, n = 140) were collected throughout Tampa Bay in 2020 and 2021 and analyzed for 25 PFAS compounds. Concentrations of PFASs in sediments and edible tissues of fish ranged from 36.8 to 2,990 ng kg -1 (dry weight) and 307 to 33,600 ng kg -1 (wet weight), respectively. Generally, levels were highest in Old Tampa Bay and decreased south towards the Gulf of Mexico. Profiles in both matrices were generally dominated by perfluorooctane sulfonic acid (PFOS) with variations by location. Estimated human health risks from the consumption of contaminated fish collected in Tampa Bay exceeded concentration thresholds for minimum risk levels (MRLs) and tolerable weekly intake (TWIs) values for adults and youths. Additionally, concentrations of PFOS in edible fish tissues of several recreationally important species collected in Tampa Bay exceeded consumption guideline levels established by several governmental agencies. In the current context, the elevated levels of PFAS in Tampa Bay and the exceedances of available thresholds for potential human health risks are a cause for concern and justify a more intensive examination especially for more heavily utilized species, particularly those used in subsistence-level fishing, which, as elsewhere may be significantly under documented.

Florida↗

Multi-gauge Calibration for modeling the Semi-Arid Santa Cruz Watershed in Arizona-Mexico Border Area Using SWAT

In most watershed-modeling studies, flow is calibrated at one monitoring site, usually at the watershed outlet. Like many arid and semi-arid watersheds, the main reach of the Santa Cruz watershed, located on the Arizona-Mexico border, is discontinuous for most of the year except during large flood events, and therefore the flow characteristics at the outlet do not represent the entire watershed. Calibration is required at multiple locations along the Santa Cruz River to improve model reliability. The objective of this study was to best portray surface water flow in this semiarid watershed and evaluate the effect of multi-gage calibration on flow predictions. In this study, the Soil and Water Assessment Tool (SWAT) was calibrated at seven monitoring stations, which improved model performance and increased the reliability of flow, in the Santa Cruz watershed. The most sensitive parameters to affect flow were found to be curve number (CN2), soil evaporation and compensation coefficient (ESCO), threshold water depth in shallow aquifer for return flow to occur (GWQMN), base flow alpha factor (Alpha_Bf), and effective hydraulic conductivity of the soil layer (Ch_K2). In comparison, when the model was established with a single calibration at the watershed outlet, flow predictions at other monitoring gages were inaccurate. This study emphasizes the importance of multi-gage calibration to develop a reliable watershed model in arid and semiarid environments. The developed model, with further calibration of water quality parameters will be an integral part of the Santa Cruz Watershed Ecosystem Portfolio Model (SCWEPM), an online decision support tool, to assess the impacts of climate change and urban growth in the Santa Cruz watershed.

Arizona↗

Eutrophication study at the Panjiakou-Daheiting Reservoir system, northern Hebei Province, People's Republic of China: Chlorophyll-a model and sources of phosphorus and nitrogen

Concentrations, loads, and sources of nitrate and total phosphorus were investigated at the Panjiakou and Daheiting Reservoir system in northern Hebei Province, People's Republic of China. The Luan He River is the primary source of water to these reservoirs, and the upstream watershed has a mix of land uses including agriculture, forest, and one large urban center. The reservoirs have a primary use for storage of drinking water and partially supply Tianjin City with its annual needs. Secondary uses include flood control and aqua culture (fish cages). The response of the reservoir system from phosphorus input, with respect to chlorophyll- a production from algae, was fitted to a model of normalized phosphorus loading that regresses the average summer-time chlorophyll- a concentration to the average annual phosphorus concentration of the reservoir. Comparison of the normalized phosphorus loading and chlorophyll- a response of this system to other reservoirs throughout the world indicate a level of eutrophication that will require up to an approximate 5–10-fold decrease in annual phosphorus load to bring the system to a more acceptable level of algal productivity. Isotopes of nitrogen and oxygen in dissolved nitrate were measured from the headwater streams and at various locations along the major rivers that provide the majority of water to these reservoirs. Those isotopic measurements indicate that the sources of nitrate change from natural background in the rivers to animal manure and septic waste upstream of the reservoir. Although the isotopic measurements suggest that animal and septic wastes are a primary source of nutrients, measurements of the molar ratio of nitrogen to phosphorus are more indicative of row-cropping practices. Options for reduction of nutrient loads include changing the management practices of the aqua culture, installation of new sewage treatment systems in the large urbanized area of the upper watershed, and agricultural management practices that would reduce the loading of nutrients and soil erosion from that land use.

Agricultural Water Management↗

Geology of the continental margin beneath Santa Monica Bay, Southern California, from seismic-reflection data

We interpret seismic-reflection data, which were collected in Santa Monica Bay using a 70-in3 generator-injector air gun, to show the geologic structure of the continental shelf and slope and of the deep-water, Santa Monica and San Pedro Basins. The goal of this research is to investigate the earthquake hazard posed to urban areas by offshore faults. These data reveal that northwest of the Palos Verdes Peninsula, the Palos Verdes Fault neither offsets the seafloor nor cuts through an undeformed sediment apron that postdates the last sea level rise. Other evidence indicates that this fault extends northwest beneath the shelf in the deep subsurface. However, other major faults in the study area, such as the Dume and San Pedro Basin Faults, were active recently, as indicated by an arched seafloor and offset shallow sediment. Rocks under the lower continental slope are deformed to differing degrees on opposite sides of Santa Monica Canyon. Northwest of this canyon, the continental slope is underlain by a little-deformed sediment apron; the main structures that deform this apron are two lower-slope anticlines that extend toward Point Dume and are cored by faults showing reverse or thrust separation. Southeast of Santa Monica Canyon, lower-slope rocks are deformed by a complex arrangement of strike-slip, normal, and reverse faults. The San Pedro Escarpment rises abruptly along the southeast side of Santa Monica Canyon. Reverse faults and folds underpinning this escarpment steepen progressively southeastward. Locally they form flower structures and cut downward into basement rocks. These faults merge downward with the San Pedro Basin fault zone, which is nearly vertical and strike slip. The escarpment and its attendant structures diverge from this strike-slip fault zone and extend for 60 km along the margin, separating the continental shelf from the deep-water basins. The deep-water Santa Monica Basin has large extent but is filled with only a thin (less than 1.5-km) section of what are probably post-Miocene rocks and sediment. Extrapolating ages obtained from Ocean Drilling Program site 1015 indicates that this sedimentary cover is Quaternary, possibly no older than 600 ka. Folds and faults along the base of the San Pedro Escarpment began to form during 8-13 ka ago. Refraction-velocity data show that high-velocity rocks, probably the Catalina Schist or Miocene volcanic rocks, underlie the sedimentary section. The San Pedro Basin developed along a strike-slip fault, widens to the southeast, and is deformed by faults having apparent reverse separation and by folds near Redondo Canyon and the Palos Verdes Peninsula.

California↗

Understanding pesticides in California's Delta

The Sacramento-San Joaquin River Delta (Delta) is the hub of California’s water system and also an important habitat for imperiled fish and wildlife. Aquatic organisms are exposed to mixtures of pesticides that flow through the maze of Delta water channels from sources including agricultural, landscape, and urban pest-control applications. While we do not know all of the effects pesticides have on the ecosystem, there is evidence that they cause some damage to organisms in the Delta. Decades of USGS research have provided a good understanding of when, where, and how pesticides enter the Delta. However, pesticide use is continually changing. New field studies and methods are needed so that scientists can analyze which pesticides are present in the Delta, and at what concentrations, enabling them to estimate exposure and ultimate effects on organisms. Continuing research will provide resource managers and stakeholders with crucial information to manage the Delta wisely.

California↗

Hydrogeology of the Pictured Cliffs Sandstone in the San Juan structural basin, New Mexico, Colorado, Arizona, and Utah

This report is one in a series resulting from the U.S. Geological Survey's Regional Aquifer System Analysis (RASA) study of the San Juan structural basin that began in October 1984. The purposes of the study (Welder, 1986) are to: (1) Define and evaluate the aquifer system; (2) assess the effects of past, present, and potential ground-water use on aquifers and streams, and (3) determine the availability and quality of ground water. Previous reports in this series describe the hydrogeology of the Dakota Sandstone (Craigg and others, 1989), Gallup Sandstone (Kernodle and others, 1989), Morrison Formation (Dam and others, 1990), Point Lookout Sandstone (Craigg and others, 1990), Kirtland Shale and Fruitland Formation (Kernodle and others, 1990), Menefee Formation (Levings and others, 1990), Cliff House Sandstone (Thorn and others, 1990), and Ojo Alamo Sandstone (Thorn and others, 1990) in the San Juan structural basin. This report summarizes information on the geology and the occurrence and quality of water in the Pictured Cliffs Sandstone, one of the primary water-bearing units in the regional aquifer system. Data used in this report were collected during the RASA study or derived from existing records in the U.S. Geological Survey's computerized National Water Information System (NWIS) data base, the Petroleum Information Corporation's data base, and the Dwight's ENERGYDATA Inc. BRIN database. Although all data available for the Pictured Cliffs Sandstone were considered in formulating the discussions in the text, not all those data could be plotted on the illustrations. The San Juan structural basin in New Mexico, Colorado, Arizona, and Utah has an area of about 21,600 square miles (fig. 1). The structural basin is about 140 miles wide and about 200 miles long. The study area is that part of the structural basin that contains rocks of Triassic and younger age; therefore, the study area is less extensive than the structural basin. Triassic through Tertiary sedimentary rocks are emphasized in this study because these units are the major aquifers in the basin. The study area is about 140 miles wide (about the same as the structural basin), 180 miles long, and has an area of about 19,400 square miles. Altitudes in the study area range from about 4,500 feet in southeastern Utah, to about 11,000 feet in the southeastern part of the basin. The area-weighted mean altitude is about 6,700 feet. Annual precipitation in the high mountainous areas along the north and east margins of the basin is as much as 45 inches, whereas annual precipitation in the lower altitude, central basin is generally less than 8 inches. Mean annual precipitation is about 12 inches. Data obtained from documents published by the U.S. Bureau of the Census (1980 and 1985) were used to calculate the population of the study area. The population in 1970 was calculated to be about 134,000. The population increased to about 194,000 in 1980,212,000 in 1982,221,000 in 1984, and then declined to about 210,000 in 1985. The economy of the basin is supported by exploration and development of natural gas, petroleum, coal, and uranium resources; urban enterprise; farming and ranching tourism, and recreation. The rise and fall in population were related to changes in the economic strength of the minerals, oil, and gas industries, and support services. Uranium-mining and -milling activities underwent rapid growth until the late 1970's when most uranium-mining activity came to an abrupt end. Likewise, the oil and gas industry prospered until about 1983 and then declined rapidly.

Hydrologic Atlas↗

Low-flow frequency and flow duration of selected South Carolina streams in the Catawba-Wateree and Santee River Basins through March 2012

Part of the mission of both the South Carolina Department of Health and Environmental Control and the South Carolina Department of Natural Resources is to protect and preserve South Carolina’s water resources. Doing so requires an ongoing understanding of streamflow characteristics of the rivers and streams in South Carolina. A particular need is information concerning the low-flow characteristics of streams, which is especially important for effectively managing the State’s water resources during critical flow periods, such as during the historic droughts that South Carolina has experienced in the past few decades. In 2008, the U.S. Geological Survey, in cooperation with the South Carolina Department of Health and Environmental Control, initiated a study to update low-flow statistics at continuous-record streamgaging stations operated by the U.S. Geological Survey in South Carolina. This report presents the low-flow statistics for 11 selected streamgaging stations in the Catawba-Wateree and Santee River Basins in South Carolina and 2 in North Carolina. For five of the streamgaging stations, low-flow statistics include daily mean flow durations or the 5-, 10-, 25-, 50-, 75-, 90-, and 95-percent probability of exceedance and the annual minimum 1-, 3-, 7-, 14-, 30-, 60-, and 90-day mean flows with recurrence intervals of 2, 5, 10, 20, 30, and 50 years, depending on the length of record available at the streamgaging station. For the other eight streamgaging stations, only daily mean flow durations and (or) exceedance percentiles of annual minimum 7-day average flows are provided due to regulation. In either case, the low-flow statistics were computed from records available through March 31, 2012. Of the five streamgaging stations for which recurrence interval computations were made, three streamgaging stations in South Carolina were compared to low-flow statistics that were published in previous U.S. Geological Survey reports. A comparison of the low-flow statistics for the annual minimum 7-day average streamflow with a 10-year recurrence interval (7Q10) from this study with the most recently published values indicated that two of the streamgaging stations had values lower than the previous values and the 7Q10 for the third station remained unchanged at zero. Low-flow statistics are influenced by length of record, hydrologic regime under which the data were collected, analytical techniques used, and other factors, such as urbanization, diversions, and droughts that may have occurred in the basin.

South Carolina↗

Map depicting susceptibility to landslides triggered by intense rainfall, Puerto Rico

Landslides in Puerto Rico range from nuisances to deadly events. Centuries of agricultural and urban modification of the landscape have perturbed many already unstable hillsides on the tropical island. One of the main triggers of mass wasting on the island is the high-intensity rainfall that is associated with tropical atmospheric systems. Puerto Rico’s geographic position and rugged topography render millions of residents vulnerable to widespread landslide events. In this study, a high-resolution (5 meters), high-intensity rainfall-induced landslide susceptibility model was produced using the frequency-ratio method. Datasets utilized in the model included a complete-island landslide inventory created from imagery obtained after Hurricanes Irma and María impacted the island during September 2017, slope inclination, land-surface curvature, soil type, geologic terrane, mean annual precipitation, land use, soil moisture, and distance to roadways and streams. The final data product (plate 1) is a statistically viable representation of where landslides are likely to initiate during or soon after intense rainfall, with a robust receiver operating characteristic area-under-curve value of 0.87. The model output raster pixel values were binned into 100 equal-area quantiles and then classified into Low, Moderate, High, Very High, and Extremely High classes of susceptibility. The Extremely High susceptibility classification represents the most vulnerable 1 percent of the island, whereas Very High, High, Moderate, and Low classifications cover 9, 20, 30, and 40 percent of the island, respectively. The susceptibility map is intended to assist in planning future development, mitigation measures, and post-event emergency response; however, it is not a substitute for site-specific, slope-stability assessments performed by licensed geologists and engineers. Additionally, the map does not portray locations where landslide material may travel after mobilization, and which may be at extreme risk; nor does it necessarily portray where landslides may occur during earthquakes or mass wasting triggered by prolonged, relatively low-intensity rainfall.

Puerto Rico↗

Water-resources activities in Florida, 1988-89

This report contains summary statements of water resources activities in Florida conducted by the Water Resources Division of the U.S. Geological Survey in cooperation with Federal, State , and local agencies during 1988. These activities are part of the Federal program of appraising the Nation 's water resources. Included are brief descriptions of the nature and scope of all active studies, summaries of significant results for 1988 and anticipated accomplishments during 1989. Water resources appraisals in Florida are highly diversified, ranging from hydrologic records networks to interpretive appraisals of water resources and applied research to develop investigative techniques. Thus, water-resources investigations range from basic descriptive water-availability studies for areas of low-intensity water development and management to sophisticated cause and effect studies in areas of high-intensity water development and management. The interpretive reports and records that are products of the investigations are a principal hydrologic foundation upon which the plans for development, management, and protection of Florida 's water resources may be used. Water data and information required to implement sound water-management programs in highly urbanized areas relate to the quantity and quality of storm runoff, sources of aquifer contamination, injection of wastes into deep strata, underground storage of freshwater, artificial recharge of aquifers, environmental effects of reuse of water, and effects of land development on changes in ground-and surface-water quality. In some parts of the State broad areas are largely rural. Future growth is anticipated in many of these. This report is intended to inform those agencies vitally interested in the water resources of Florida as to the current status and objectives of the U.S. Geological Survey cooperative program. The mission of this program is to collect, interpret, and publish information on water resources. Almost all of this work is done in cooperation with other public agencies. (USGS)

Open-File Report↗

Predatory bird populations in the east Mojave Desert, California

We surveyed 7 species of predatory birds weekly during a 12-month period (December 1992 through November 1993) in the east Mojave Desert, California. The Common Raven (Corvus corax) was the most frequently observed species with an average of 6.9 sightings per 100 km. Turkey Vultures (Cathartes aura), Red-tailed Hawks (Buteo jamaicensis), Loggerhead Shrikes (Lanius ludovicianus), American Kestrels (Falco sparverius), Golden Eagles (Aquila chrysaetos), and Prairie Falcons (Falco mexicanus) were seen in decreasing order of frequency of observation through the study period. Ravens, Red-tailed Hawks, Loggerhead Shrikes, American Kestrels, and Prairie Falcons were seen throughout the year. Turkey Vultures were not present during winter months, while Golden Eagles were seen only during November and December. Turkey Vultures, Red-tailed Hawks, and ravens were most numerous on agricultural lands, while Loggerhead Shrikes were most Common at urban areas. Raven numbers increased with increasing number of linear rights-of-way parallel to the survey route. Perching was the most common behavior type, although Turkey Vultures and ravens were often observed soaring, flying, or standing on the ground near highways. Transmission powerline towers and telephone poles were used as perch sites disproportionately to availability.

Great Basin Naturalist↗

Chemical quality of water, sediment, and fish in Mountain Creek Lake, Dallas, Texas, 1994-97

The occurrence, trends, and sources of numerous inorganic and organic contaminants were evaluated in Mountain Creek Lake, a reservoir in Dallas, Texas. The study, done in cooperation with the Southern Division Naval Facilities Engineering Command, was prompted by the Navy’s concern for potential off-site migration of contaminants from two facilities on the shore of Mountain Creek Lake, the Naval Air Station Dallas and the Naval Weapons Industrial Reserve Plant. Sampling of stormwater (including suspended sediment), lake water, bottom sediment (including streambed sediment), and fish was primarily in Mountain Creek Lake but also was in stormwater outfalls from the Navy facilities, nearby urban streams, and small streams draining the Air Station. Volatile organic compounds, predominantly solvents from the Reserve Plant and fuel-related compounds from the Air Station, were detected in stormwater from both Navy facilities. Fuel-related compounds also were detected in Mountain Creek Lake at two locations, one near the Air Station inlet where stormwater from a part of the Air Station enters the lake and one at the center of the lake. Concentrations of volatile organic compounds at the two lake sites were small, all less than 5 micrograms per liter. Elevated concentrations of cadmium, chromium, copper, lead, mercury, nickel, silver, and zinc, from 2 to 4 times concentrations at background sites and urban reference sites, were detected in surficial bottom sediments in Cottonwood Bay, near stormwater outfalls from the Reserve Plant. Elevated concentrations of polycyclic aromatic hydrocarbons and polychlorinated biphenyls, compared to background and urban reference sites, were detected in surficial sediments in Cottonwood Bay. Elevated concentrations of polycyclic aromatic hydrocarbons, indicative of urban sources, also were detected in Cottonwood Creek, which drains an urbanized area apart from the Navy facilities. Elevated concentrations of polychlorinated biphenyls were detected in two inlets near the Air Station shoreline. Polycyclic aromatic hydrocarbon and heavy metal concentrations near the Air Station shoreline were not elevated compared to urban reference sites. Much larger concentrations of selected heavy metals, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls were detected in deeper, older sediments than in surficial sediments in Cottonwood Bay. The decreases in concentrations coincide with changes in wastewater discharge practices at the Reserve Plant. Elevated concentrations of polycyclic aromatic hydrocarbons and polychlorinated biphenyls also were detected in older sediments in the Air Station inlet. On the basis of dated sediment cores and contaminant discharge histories, contaminant accumulation rates in Cottonwood Bay were much greater historically than recently. Most heavy metals, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls that accumulated in the central and eastern parts of Cottonwood Bay appear to have come from the west lagoon on the Reserve Plant. Treated sewage and industrial-process wastewater were discharged to the west lagoon from about 1941 to 1974. Estimated annual contaminant accumulation rates in Cottonwood Bay decreased by from 1 to 2 orders of magnitude after 1974, when most point-source discharges to the west lagoon ceased. Polychlorinated biphenyls were detected in 61 of 62 individual fish-tissue samples. The largest average concentrations were in eviscerated channel catfish and the smallest were in largemouth bass fillets. Polychlorinated biphenyl and selenium concentrations from analyses of this study were large enough to prompt the Texas State Department of Health to issue a fish-possession ban for Mountain Creek Lake in 1996. Suspended sediments in stormwater at the lagoon outfalls and at sites on Cottonwood Creek were sampled and analyzed for major and trace elements, polycyclic aromatic hydrocarbons, organochlorine pesticides, and polychlorinated biphenyls. The suspended sediments from the outfalls contained about the same mixture of heavy metals and organic compounds, in elevated concentrations compared to reference sites, as bottom sediments from the lagoons and surficial bottom sediments in Cottonwood Bay. Diagnostic ratios of polycyclic aromatic hydrocarbons indicate that uncombusted fuel sources contribute to older sediments and that pyrogenic sources of polycyclic aromatic hydrocarbons dominate recently deposited sediments in Cottonwood Bay and along the Air Station shoreline.

Texas↗

Biological water-quality assessment of selected streams in the Milwaukee Metropolitan Sewerage District Planning Area of Wisconsin, 2007

Changes in the water quality of stream ecosystems in an urban area may manifest in conspicuous ways, such as in murky or smelly streamwater, or in less conspicuous ways, such as fewer native or pollution-sensitive organisms. In 2004, and again in 2007, the U.S. Geological Survey sampled stream organisms—algae, invertebrates, and fish—in 14 Milwaukee area streams to assess water quality as part of the ongoing Milwaukee Metropolitan Sewerage District (MMSD) Corridor Study. In addition, passive-sampling devices (SPMDs, “semipermeable membrane devices”) were deployed at a subset of sites in order to evaluate the potential exposure of stream organisms to certain toxic chemicals. Results of the 2007 sampling effort are the focus of this report. Results of sampling from 2007 are compared with results from 2004. The water quality of sampled streams was assessed by evaluating biological-assemblage data, metrics computed from assemblage data, and an aggregate bioassessment ranking method that combined data for algae, invertebrates, and fish. These data contain information about the abundance (number) of different species in each group of stream organisms and the balance between species that can or cannot tolerate polluted or disturbed conditions. In 2007, the highest numbers of algal, invertebrate, and fish species were found at the Milwaukee River at Milwaukee, the largest sampled site. Algal results indicated water quality concerns at 10 of the 14 sampled sites due to the occurrence of nuisance algae or low percentages of pollution-sensitive algae. When compared to 2004, total algal biovolume was higher in 2007 at 12 of 14 sites, due mostly to more nuisance green algae from unknown causes. Results of several metrics, including the Hilsenhoff Biotic Index (HBI-10), suggest that invertebrate assemblages in the Little Menomonee River, Underwood Creek, and Honey Creek were poorer quality in 2007 compared to 2004. Six sites received “very poor” quality ratings for fish in 2007, mostly because inadequate numbers of fish were collected at five sites to allow computation of an Index of Biotic Integrity (IBI); this resulted in three additional sites receiving “very poor” ratings compared to 2004. Some signs of potential improvement in the fish assemblage were evident at Lincoln Creek, possibly reflecting delayed effects of the restoration of stream habitat, completed in 2002; however, algae and invertebrates did not show signs of improvement. Aggregate bioassessment rankings across all groups of organisms for 2004 and 2007 indicated that water quality at the two Milwaukee River main stem sites (at Milwaukee and near Cedarburg), Jewel Creek, and the Menomonee River at Menomonee Falls was the least-degraded among all sampled sites. Rankings for Oak Creek and Little Menomonee suggested water quality was worse in 2007 compared to 2004 and placed these two sites together with Kinnickinnic River and Underwood Creek, two concrete-line sites, indicating the most-degraded water quality among all sampled sites. The aggregate ranking for Lincoln Creek in 2007 would have placed it in the most-degraded category but for the positive influence of the fish ranking when compared to poor algal and invertebrate rankings. Potential toxicity due to certain manmade chemicals, such as polycyclic aromatic hydrocarbons (PAHs), was found at all six sites where SPMDs were deployed. As was found in 2004, the highest potential toxicity in 2007 was observed at Lincoln Creek where chemical screening in 2007 also showed the highest total PAHs of all six sites; however, potential toxicity at Little Menomonee River, Honey Creek, and Kinnickinnic River was relatively high compared to Milwaukee River near Cedarburg. Although toxicity and chemical results in 2007 did not agree with aggregate rankings for Lincoln Creek because of fish, nor for Honey Creek, the results did agree with aggregate rankings at four of the six sites. In addition to toxicological and chemical influences, the more urbanized sites have high percentages of impervious surface area, resulting in frequent high stream flows that can adversely affect algal, invertebrate, and fish assemblages. Assessments of the ecological status of different groups of organisms and of potential chemical and physical stressors to organisms are important tools in evaluating streamwater quality.

Wisconsin↗

Mercury in fish, bed sediment, and water from streams across the United States, 1998-2005

Mercury (Hg) was examined in top-predator fish, bed sediment, and water from streams that spanned regional and national gradients of Hg source strength and other factors thought to influence methylmercury (MeHg) bioaccumulation. Sampled settings include stream basins that were agricultural, urbanized, undeveloped (forested, grassland, shrubland, and wetland land cover), and mined (for gold and Hg). Each site was sampled one time during seasonal low flow. Predator fish were targeted for collection, and composited samples of fish (primarily skin-off fillets) were analyzed for total Hg (THg), as most of the Hg found in fish tissue (95-99 percent) is MeHg. Samples of bed sediment and stream water were analyzed for THg, MeHg, and characteristics thought to affect Hg methylation, such as loss-on-ignition (LOI, a measure of organic matter content) and acid-volatile sulfide in bed sediment, and pH, dissolved organic carbon (DOC), and dissolved sulfate in water. Fish-Hg concentrations at 27 percent of sampled sites exceeded the U.S. Environmental Protection Agency human-health criterion of 0.3 micrograms per gram wet weight. Exceedances were geographically widespread, although the study design targeted specific sites and fish species and sizes, so results do not represent a true nationwide percentage of exceedances. The highest THg concentrations in fish were from blackwater coastal-plain streams draining forests or wetlands in the eastern and southeastern United States, as well as from streams draining gold- or Hg-mined basins in the western United States (1.80 and 1.95 micrograms THg per gram wet weight, respectively). For unmined basins, length-normalized Hg concentrations in largemouth bass were significantly higher in fish from predominantly undeveloped or mixed-land-use basins compared to urban basins. Hg concentrations in largemouth bass from unmined basins were correlated positively with basin percentages of evergreen forest and also woody wetland, especially with increasing proximity of these two land-cover types to the sampling site; this underscores the greater likelihood for Hg bioaccumulation to occur in these types of settings. Increasing concentrations of MeHg in unfiltered stream water, and of bed-sediment MeHg normalized by LOI, and decreasing pH and dissolved sulfate were also important in explaining increasing Hg concentrations in largemouth bass. MeHg concentrations in bed sediment correlated positively with THg, LOI, and acid-volatile sulfide. Concentrations of MeHg in water correlated positively with DOC, ultraviolet absorbance, and THg in water, the percentage of MeHg in bed sediment, and the percentage of wetland in the basin.

Scientific Investigations Report↗

Black bear movement and food conditioning in an exurban landscape

Conflicts between humans and wildlife have become increasingly important challenges for resource managers along the urban‐wildland interface. Food conditioning (i.e., reliance by an animal on anthropogenic foods) of American black bears (Ursus americanus ) is related to conflict behavior (i.e., being bold or aggressive toward humans, consuming human food or garbage, causing property damage) and often occurs in communities adjacent to Great Smoky Mountains National Park (GRSM or Park), USA. The goal of our study was to evaluate black bear space use in GRSM and in exurban areas on surrounding private lands and to identify factors associated with food conditioning and conflict behavior. We radio‐collared 53 bears (29 males, 24 females) from 2015 to 2017 to compare space use characteristics and used carbon isotopic signatures (δ13C) from bear hair to assess food conditioning. We then performed an integrated step selection function (iSSF) analysis to characterize and compare movement and resource use as related to food conditioning. Based on the stable isotope analyses, 24 bears were classified as food conditioned (FC; 16 males and 8 females) and 37 were not food conditioned (NFC; 14 males and 23 females). Annual 95% kernel density estimate (KDE) home ranges and 50% KDE core area estimates of female and male bears did not differ by level of food conditioning (i.e., mean δ13C), but 95% and 50% home ranges of FC females were smaller than NFC females when data from 2015, a year of food scarcity and abnormally large home ranges, were excluded. The mean proportion of exurban development (e.g., roads, buildings, openings) within 95% KDE and 50% KDE home ranges of females increased with mean δ13C (i.e., greater food conditioning). The iSSF models indicated that FC bears were more likely to use forest openings associated with higher levels of development than NFC bears. We used those models to demonstrate how landscape modifications can reduce bear use of exurban areas, particularly for NFC bears. Our stable isotope, movement, and resource use data indicate that conflict behaviors displayed by many bears within GRSM were learned in areas outside Park boundaries. © 2020 The Wildlife Society.

Tennessee, North Carolina↗

Deformity, erosion, lesion, tumor, and parasite (DELT) anomalies in fish communities of the Chesapeake Bay watershed, USA: A regional assessment and potential landscape drivers

Fish diseases in freshwater ecosystems pose significant ecological and socioeconomic challenges, yet monitoring them in wild populations is complex due to interactions between pathogens, hosts, and environmental conditions. We examine the prevalence and watershed-scale landscape drivers of external deformity, erosion, lesion, tumor, and parasite (DELT) anomalies in 57 riverine fish species using a large dataset (577,266 individuals collected 2008–2019) from the Chesapeake Bay watershed that originated from state and federal agencies. Overall, DELT prevalence was low (1.4%), but was higher in larger, longer-lived species, including Channel Catfish ( Ictalurus punctatus ) (18.9%), Rock Bass ( Ambloplites rupestris ) (7.6%), Smallmouth Bass ( Micropterus dolomieu ) (7.3%), Brown Bullhead ( Ameiurus nebulosus ) (5.6%), and Yellow Bullhead ( Ameiurus natalis ) (5.1%), signifying their potential as regional environmental health indicators. Spatial analysis indicated warmer temperatures increased the estimated probability of DELT occurrence, whereas higher precipitation often mitigated the probability of DELT occurrence. Conservation strategies (e.g., best management practices) had mixed effectiveness in reducing DELT occurrence probability across agricultural and urban landscapes. Across the landscape, various drivers, including harvested forest, impervious land, and pesticide use, influenced DELT occurrence probability differently across species. However, uncertainty remains partly due to low prevalence and variability in sampling methods across agencies. Despite low overall prevalence, DELT occurrence is a rapid fish health indicator. Future research could emphasize species-specific responses and longitudinal studies that incorporate life stages and health indicators. Understanding these intricate, multi-scale interactions is vital for effective monitoring, conservation, and adaptive management of freshwater ecosystems.

Chesapeake Bay watershed↗

Low-Level Volatile Organic Compounds in Active Public Supply Wells as Ground-Water Tracers in the Los Angeles Physiographic Basin, California, 2000

Data were collected to evaluate the use of low-level volatile organic compounds (VOC) to assess the vulnerability of public supply wells in the Los Angeles physiographic basin. Samples of untreated ground water from 178 active public supply wells in the Los Angeles physiographic basin show that VOCs were detected in 61 percent of the ground-water samples; most of these detections were low, with only 29 percent above 1 mg/L (microgram per liter). Thirty-nine of the 86 VOCs analyzed were detected in at least one sample, and 11 VOCs were detected in 7 percent or more of the samples. The six most frequently detected VOCs were trichloromethane (chloroform) (46 percent); trichloroethene (TCE) (28 percent); tetrachloro-ethene (PCE) (19 percent); methyl tert-butyl ether (MTBE) (14 percent); 1,1-dichloroethane (11 percent); and 1,1,1-trichloroethane (TCA) (11 percent). These VOCs were also the most frequently detected VOCs in ground water representative of a wide range of hydrologically conditions in urban areas nationwide. Only two VOCs (TCE and PCE) exceeded state and federal primary maximum contaminant levels (MCL) for drinking water in a total of seven samples. Because samples were collected prior to water treatment, sample concentrations do not represent the concentrations entering the drinking-water system.Ground water containing VOCs may be considered to be a tracer of postindustrial-aged water-water that was recharged after the onset of intense urban development. The overall distribution of VOC detections is related to the hydrological and the engineered recharge facilities in the Coastal Los Angeles Basin and the Coastal Santa Ana Basin that comprise the Los Angeles physiographic basin. Most of the ground-water recharge occurs at engineered recharge facilities in the generally coarse-grained northeastern parts of the study area (forebay areas). Ground-water recharge from the land surface is minimal in the southwestern part of the basins, distal from the recharge facilities, where clay layers impede the vertical migration of ground water (pressure areas).VOCs are not uniformly distributed over the study area. Most of the wells with multiple VOC detections, which also have the highest concentrations, are in the forebay areas and are clustered proximal to the recharge facilities. In addition, the number of VOC detections and VOC concentrations decrease beyond about 10-15 kilometers from the recharge facilities. The distribution of individual VOCs is also related to their history of use. MTBE traces ground water recharged during about the last decade and is detected almost exclusively in the forebay areas. Chloroform, which has been used since the 1920s, is more widely distributed and is detected at the greatest distances from the recharge facilities.Downward migration of VOCs from the land surface may be a viable process for VOCs to reach aquifers in parts of the forebay areas, but there is little indication that the same process is active in the pressure area. The lack of contrast in the number of VOC detections between wells of different depths over most of the study area suggests that the downward migration from the land surface is not a dominant pathway for VOCs to travel to the capture zones of public supply wells. Isolated occurrences of multiple VOC detections and high concentrations of VOCs in individual wells may indicate rapid vertical transport from a localized source. Stable isotope data indicate that ground water containing VOCs is a mixture of local precipitation and runoff with water that is isotopically lighter (more negative) than the local sources. The isotopically lighter water could either be Colorado River water or State Water Project water, both of which are imported to the basin and used as a source of recharge to the ground-water flow system. The stable isotope data support the interpretation that VOCs in ground water are associated with the engineered recharge facilities.Two of the most frequently detecte

Water-Resources Investigations Report↗

Regional Curves of Bankfull Channel Geometry for Non-Urban Streams in the Piedmont Physiographic Province, Virginia

Natural-channel design involves constructing a stream channel with the dimensions, slope, and plan-view pattern that would be expected to transport water and sediment and yet maintain habitat and aesthetics consistent with unimpaired stream segments, or reaches. Regression relations for bankfull stream characteristics based on drainage area, referred to as 'regional curves,' are used in natural stream channel design to verify field determinations of bankfull discharge and stream channel characteristics. One-variable, ordinary least-squares regressions relating bankfull discharge, bankfull cross-sectional area, bankfull width, bankfull mean depth, and bankfull slope to drainage area were developed on the basis of data collected at 17 streamflow-gaging stations in rural areas with less than 20 percent urban land cover within the basin area (non-urban areas) of the Piedmont Physiographic Province in Virginia. These regional curves can be used to estimate the bankfull discharge and bankfull channel geometry when the drainage area of a watershed is known. Data collected included bankfull cross-sectional geometry, flood-plain geometry, and longitudinal profile data. In addition, particle-size distributions of streambed material were determined, and data on basin characteristics were compiled for each reach. Field data were analyzed to determine bankfull cross-sectional area, bankfull width, bankfull mean depth, bankfull discharge, bankfull channel slope, and D50 and D84 particle sizes at each site. The bankfull geometry from the 17 sites surveyed during this study represents the average of two riffle cross sections for each site. Regional curves developed for the 17 sites had coefficient of determination (R2) values of 0.950 for bankfull cross-sectional area, 0.913 for bankfull width, 0.915 for bankfull mean depth, 0.949 for bankfull discharge, and 0.497 for bankfull channel slope. The regional curves represent conditions for streams with defined channels and bankfull features in the Piedmont Physiographic Province in Virginia with drainage areas ranging from 0.29 to 111 square miles. All sites included in the development of the regional curves were located on streams with current or historical U.S. Geological Survey streamflow-gaging stations. These curves can be used to verify bankfull features identified in the field and bankfull stage for ungaged streams in non-urban areas.

Scientific Investigations Report↗