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Derivation of solute-transport equations for a turbulent natural-channel flow

The continuity equation of water and the convection-diffusion equation for a solute are derived by use of an orthogonal curvilinear (natural) coordinate system, which follows the meandering and irregular pattern of natural channel geometry. The solute is assumed to be neutrally buoyant, conservative, and passive. The three-, two-, and one-dimensional equations derived herein represent one of the most satisfactory descriptions of solute transport by turbulent flow in a natural channel.

Journal of Research of the U.S. Geological Survey↗

Water levels through 1989 in bedrock aquifers in South Dakota

The U.S. Geological Survey, in cooperation with the South Dakota Department of Environmental and Natural Resources, has collected water-level data for 237 wells completed in bedrock aquifers throughout South Dakota. The water levels are presented in hydrographs in the main body of the report and in tables in a Supplemental Information section at the end of the report. The data are organized by county, in alphabetical order.

Open-File Report↗

Irrigation drainage studies of the Angostura Reclamation Unit and the Belle Fourche Reclamation Project, western South Dakota: Results of 1994 sampling and comparisons with 1988 data

The U.S. Department of the Interior started the National Irrigation Water Quality Program in 1985 to identify the nature and extent of irrigation-induced water-quality problems that might exist in the western U.S. The Angostura Reclamation Unit (ARU) and Belle Fourche Reclamation Project (BFRP) in western South Dakota were included as part of this program. The ARU and BFRP reconnaissance studies were initiated in 1988, during below-normal streamflow conditions in both study areas. Surface water, bottom sediment, and fish were resampled in 1994 at selected sites in both study areas during generally near-normal streamflow conditions to compare with 1988 study results. Concentrations of major ions in water for both the ARU and BFRP study areas are high relative to national baseline levels. Major-ion concentrations for both areas generally are lower for 1994 than for 1988, when low-flow conditions prevailed, but ionic proportions are similar between years. For ARU, dissolved-solids concentrations probably increase slightly downstream from Angostura Reservoir; however, the available data sets are insufficient to confidently discern effects of ARU operations on dissolved-solids loading. For BFRP, dissolved-solids concentrations are slightly higher at sites that are affected by irrigation drainage; again, however, the data are inconclusive to determine whether BFRP operations increase dissolved-solids loading. Most trace-element concentrations in water samples for both study areas are similar between 1988 and 1994, and do not show strong relations with discharge. ARU operations probably are not contributing discernible additional loads of trace elements to the Cheyenne River. For BFRP, concentrations of some trace elements are slightly higher at sites downstream from irrigation operations than at a site upstream from irrigation operations. BFRP operations might contribute to trace-element concentrations in the Belle Fourche River, but available data are insufficient to quantify increases. For both study areas, concentrations of several trace elements occasionally exceed National Irrigation Water Quality Program guidelines. Selenium routinely occurs in concentrations that could be problematic at sites upstream and downstream from both study areas. Elevated selenium concentrations at sites upstream from irrigation operations indicate that naturally occurring selenium concentrations are relatively high in and near the study areas. While ARU operations probably do not contribute discernible additional loads of selenium to the Cheyenne River, BFRP operations might contribute additional selenium loads to the Belle Fourche River. Concentrations of most trace elements in bottom sediment, except arsenic and selenium, are similar to typical concentrations for western U.S. soils for both study areas. Bottom-sediment arsenic and selenium (1988) concentrations in both study areas can reach levels that might be of concern; however, there is insufficient information to determine whether irrigation operations contribute to these elevated concentrations. Concentrations of most trace elements in fish in both study areas are less than values known to adversely affect fish or birds, although there are occasional exceedances of established criteria. However, selenium concentrations in fish samples routinely are within the National Irrigation Water Quality Program level of concern, and also commonly exceed the dietary guideline for avian consumers for both study areas. Selenium concentrations in fish samples generally are higher at sites downstream from irrigation operations. For BFRP, arsenic and mercury concentrations are elevated in fish samples from site B-18, which is influenced by mine tailings.

South Dakota↗

Hydrology of Salt Wells Creek — A plains stream in southwestern Wyoming

Development of energy minerals in plains areas of Wyoming is expanding rapidly. Such development may affect water resources and hydrologic relations of the plains; however, little information exists concerning hydrologic processes for these areas. This report summarizes results of a hydrologic study made during 1975-78 of Salt Wells creek, a drainage area of about 500 square miles located southeast of Rock Springs, Wyoming. The area is typical of arid and semiarid plains areas in southwestern Wyoming where mineral development is occurring. Salt Wells Creek is predominately an intermittent stream. Numerous springs in the headwaters cause small perennial flows in some upstream tributaries, but evaporation, freezeup, and seepage deplete these flows so that the middle and lower reaches of the main channel have only intermittent flows. The intermittent nature of streamflow affects water quality. It was observed that a flushing of dissolved solids and suspended sediment occurs during the first flows of a runoff event. A striking feature of the stream is its deeply incised channel. The downcutting is attributed to the cummulative effects of: (1) a change in the relative climate, amounts of annual precipitation occurring as rain and snow, (2) change in base level due to downstream channelization, and (3) changes in land use. Because of the incision, erosion is now expanding to include intervening tributaries.

Wyoming↗

Inputs of the Dormant-Spray Pesticide, Diazinon, to the San Joaquin River, California, February 1993

INTRODUCTION The objective of the National Water Quality Assessment (NAWQA) Program of the U.S. Geological Survey is to describe the status and trends of the Nation's water quality with respect to natural features of the environment and human activities or land-use. Pesticides are a major water-quality issue in the San Joaquin Valley of California (fig. 1), and pesticide residues may be transported to rivers and streams in agricultural runoff following winter storms. Three sites in the western San Joaquin Valley were monitored during and after two February 1993 storms. The storms occurred after extensive spraying of organophosphate insecticides, mostly diazinon, on almond and other stone-fruit orchards.

Fact Sheet↗

Water use in Wisconsin, 2000

As part of the National Water-Use Information Program, the U.S. Geological Survey (USGS) stores water-use data in standardized format for different catego ries of water use. Information about amounts of water withdrawn, sources of wa ter, how the water was used, and how much water was returned is available to those involved in establishing water-resource policy and to those managing water resources. In 1978, the USGS entered into a cooperative program with the Wisconsin De partment of Natural Resources (WDNR) to inventory water use in Wisconsin. Since that time, four reports summarizing water use have been published (Law rence and Ellefson, 1982; Ellefson and others, 1987; Ellefson and others, 1993; Ellefson and others, 1997). Ellefson and others (1997) present 1995 water-use data in a map and graph format. Because water use changes with time, an update report is periodically required. This report presents 2000 data in the same format as the 1997 report.

Wisconsin↗

Ground-Water Hydrology of the Upper Deschutes Basin, Oregon

The upper Deschutes Basin is among the fastest growing regions in Oregon. The rapid population growth has been accompanied by increased demand for water. Surface streams, however, have been administratively closed to additional appropriation for many years, and surface water is not generally available to support new development. Consequently, ground water is being relied upon to satisfy the growth in water demand. Oregon water law requires that the potential effects of ground-water development on streamflow be evaluated when considering applications for new ground-water rights. Prior to this study, hydrologic understanding has been insufficient to quantitatively evaluate the connection between ground water and streamflow, and the behavior of the regional ground-water flow system in general. This report describes the results of a hydrologic investigation undertaken to provide that understanding. The investigation encompasses about 4,500 square miles of the upper Deschutes River drainage basin.A large proportion of the precipitation in the upper Deschutes Basin falls in the Cascade Range, making it the principal ground-water recharge area for the basin. Water-balance calculations indicate that the average annual rate of ground- water recharge from precipitation is about 3,500 ft3/s (cubic feet per second). Water-budget calculations indicate that in addition to recharge from precipitation, water enters the ground-water system through interbasin flow. Approximately 800 ft3/s flows into the Metolius River drainage from the west and about 50 ft3/s flows into the southeastern part of the study area from the Fort Rock Basin. East of the Cascade Range, there is little or no ground-water recharge from precipitation, but leaking irrigation canals are a significant source of artificial recharge north of Bend. The average annual rate of canal leakage during 1994 was estimated to be about 490 ft3/s. Ground water flows from the Cascade Range through permeable volcanic rocks eastward out into the basin and then generally northward. About one-half the ground water flowing from the Cascade Range discharges to spring-fed streams along the margins of the range, including the upper Metolius River and its tributaries. The remaining ground water flows through the subsurface, primarily through rocks of the Deschutes Formation, and eventually discharges to streams near the confluence of the Deschutes, Crooked, and Metolius Rivers. Substantial ground-water discharge occurs along the lower 2 miles of Squaw Creek, the Deschutes River between Lower Bridge and Pelton Dam, the lower Crooked River between Osborne Canyon and the mouth, and in Lake Billy Chinook (a reservoir that inundates the confluence of the Deschutes, Crooked, and Metolius Rivers).The large amount of ground-water discharge in the confluence area is primarily caused by geologic factors. North (downstream) of the confluence area, the upper Deschutes Basin is transected by a broad region of low-permeability rock of the John Day Formation. The Deschutes River flows north across the low-permeability region, but the permeable Deschutes Formation, through which most of the regional ground water flows, ends against this rampart of low-permeability rock. The northward-flowing ground water discharges to the streams in this area because the permeable strata through which it flows terminate, forcing the water to discharge to the surface. Virtually all of the regional ground water in the upper Deschutes Basin discharges to surface streams south of the area where the Deschutes River enters this low-permeability terrane, at roughly the location of Pelton Dam.The effects of ground-water withdrawal on streamflow cannot presently be measured because of measurement error and the large amount of natural variability in ground-water discharge. The summer streamflow near Madras, which is made up largely of ground-water discharge, is approximately 4,000 ft3/s. Estimated consumptive ground-water use in the basin i

Water-Resources Investigations Report↗

Estimating late 19th century hydrology in the Greater Everglades Ecosystem: An integration of paleoecologic data and models

Determining hydrologic conditions prior to instrumental records is a challenge for restoration of freshwater ecosystems worldwide. Paleoecologic data provide this information on past conditions and when these data are used to adjust hydrologic models, allow conditions to be hindcast that may not be directly estimated from the paleo-data alone. In this context, the paleo-data provide real-world estimates as input to the models. Restoration of the Greater Everglades Ecosystem requires this understanding of the hydrology of the natural system prior to significant alterations due to water management and land use. Large scale models such as the Natural Systems Model (NSM 4.6.2) have been used by the South Florida Water Management District and other agencies responsible for restoration to estimate past hydrologic conditions; however, these models typically portray a drier natural system for the beginning of the 20th century than what is indicated by paleoecologic analyses and historical data. The purpose of this study is to estimate pre-20th century water levels, hydroperiods and flow in the freshwater wetlands of the Everglades by using pollen assemblage data in three sediment cores to adjust the Natural Systems Model. This study is designed to further test estimates of flow through the Everglades derived from analysis of sediment cores collected in Florida Bay. The results demonstrate that the NSM 4.6.2 underestimates water levels and hydroperiods in the Everglades compared to the paleo-adjusted NSM 4.6.2 model outputs. Flow models that use the paleo-adjusted water levels as input indicate flow through Shark River Slough in the late 19th century was approximately two times flow between 1990 and 2000, and flow through Taylor Slough was approximately three times flow between 1990 and 2000. The flow estimates derived from this study agree with the estimates derived from earlier studies using estuarine cores. This integration of paleoecologic information and hydrologic models provides resource managers with the best available estimates of past conditions and allows them to set realistic targets for restoration of freshwater ecosystems.

Florida↗

Sustaining salmonid populations: A caring understanding of naturalness of taxa

Species of the family of Salmonidae occur naturally in Northern Hemisphere waters that remain clear and cool to cold in summer. For purposes of reproduction, salmonids generally behaviorally respond to the currents of streams and lakes in recently glaciated areas. For feeding and maturation, many larger species migrate into existing systems of large lakes, seas, and oceans. The subfamilies include Salmoninae, Coregoninae, and Thymallinae. In many locales and regions of the hemisphere, numerous species of these subfamilies evolved and self-organized into species flocks or taxocenes of bewildering complexity. For example, any individual species may play different or unique ecological roles in different taxocenes. The northern Pacific and Atlantic Ocean ecosystems, with their seas and tributaries, each contained a metacomplex of such taxocenes that, in their natural state some centuries ago, resembled each other but differed in many ways. Humans have valued all species of this family for subsistence, ceremonial, naturalist, gustatory, angling, and commercial reasons for centuries. Modern progressive humans (MPHs), whose industrial and commercial enterprises have gradually spread over this hemisphere in recent time, now affect aquatic ecosystems at all scales from local to global. These human effects mingle in complex ways that together induce uniquely natural salmonid taxocenes to disintegrate with the loss of species, including those groups least tolerant to human manipulations, but extending more recently to those taxa more adapted to anthropogenic change. As we leave the modern era, dominated by MPHs, will we find ways to live sustainably with salmonid taxocenes that still exhibit self-organizational integrity, or will only individual, isolated populations of salmonid species, derived from those most tolerant of MPHs, survive? To achieve future sustainability of salmonids, we suggest implementation of a search for intuitive knowledge based on faith in the wisdom of nature and a caring-sharing, behavioral structure based on "survival of the wisest" for both humans and salmonids.

Conference Paper↗

Hydrogeologic settings and ground-water flow simulations for regional studies of the Transport of Anthropogenic and Natural Contaminants to public-supply wells - Studies begun in 2001

This study of the Transport of Anthropogenic and Natural Contaminants to public-supply wells (TANC study) is being conducted as part of the U.S. Geological Survey National Water Quality Assessment (NAWQA) Program and was designed to increase understanding of the most important factors to consider in ground-water vulnerability assessments. The seven TANC studies that began in 2001 used retrospective data and ground-water flow models to evaluate hydrogeologic variables that affect aquifer susceptibility and vulnerability at a regional scale. Ground-water flow characteristics, regional water budgets, pumping-well information, and water-quality data were compiled from existing data and used to develop conceptual models of ground-water conditions for each study area. Steady-state regional ground-water flow models were used to represent the conceptual models, and advective particle-tracking simulations were used to compute areas contributing recharge and traveltimes from recharge to selected public-supply wells. Retrospective data and modeling results were tabulated into a relational database for future analysis. Seven study areas were selected to evaluate a range of hydrogeologic settings and management practices across the Nation: the Salt Lake Valley, Utah; the Eagle Valley and Spanish Springs Valley, Nevada; the San Joaquin Valley, California; the Northern Tampa Bay region, Florida; the Pomperaug River Basin, Connecticut; the Great Miami River Basin, Ohio; and the Eastern High Plains, Nebraska. This Professional Paper Chapter presents the hydrogeologic settings and documents the ground-water flow models for each of the NAWQA TANC regional study areas that began work in 2001. Methods used to compile retrospective data, determine contributing areas of public-supply wells, and characterize oxidation-reduction (redox) conditions also are presented. This Professional Paper Chapter provides the foundation for future susceptibility and vulnerability analyses in the TANC study areas and comparisons among regional aquifer systems. The report is organized in sections. In addition to the introductory section (Section 1) are seven sections that present the hydrogeologic characterization and ground-water flow model documentation for each TANC regional study area (Sections 2 through 8). Abstracts in Sections 2 through 8 provide summaries and major findings for each regional study area.

Professional Paper↗

Introduction to emergent wetlands: Chapter A in Emergent wetlands status and trends in the northern Gulf of Mexico: 1950-2010

Throughout the past century, emergent wetlands have been declining across the Gulf of Mexico. Emergent wetland ecosystems provide a plethora of resources including plant and wildlife habitat, commercial and recreational economic activity, water quality improvement, and natural barriers against storms. As emergent wetland losses increase, so does the need for information on the causes and effects of these losses, for emergent wetland mapping, for monitoring and restoration efforts, and for increased education. The U.S. Geological Survey (USGS) and the U.S. Environmental Protection Agency’s Gulf of Mexico Program Office (EPA GMPO) are committed to providing the best science to restore, enhance, and protect these important ecosystems. The Emergent Wetlands Status and Trends Report is a continuation of the completed Seagrass Status and Trends in the Northern Gulf of Mexico Report (Handley and others, 2007), both of which serve to update the EPA GMPO Status and Trends of Emergent and Submerged Vegetated Habitats of Gulf of Mexico Coastal Waters, USA Report (Duke and Kruczynski, 1992). The Emergent Wetlands Status and Trends Report is also part of the Gulf of Mexico Alliance Ecosystems Integration and Assessment Priority Issue Team’s work plan to provide resources that will aid in the ecological and economic enhancement of the Gulf of Mexico region. The purpose of this report is to provide scientists, managers, and citizens with valuable baseline information on the status and trends of emergent wetlands along the coast of the Gulf of Mexico. The study upon which this report is based examines the emergent wetlands of eight individual estuarine areas within the northern Gulf of Mexico region and presents statewide summaries for Texas, Louisiana, Mississippi, Alabama, and Florida. Each estuarine area is detailed in vignettes that address current status and historical trends of estuarine and palustrine emergent wetlands, emergent wetlands mapping and monitoring, causes of status change, restoration and enhancement activities, background information for the study area, and the methodology employed to analyze and document the historical trends and current status of emergent wetlands. The eight individual estuarine areas examined in this report are:  Corpus Christi/ Nueces/Aransas Bays, Tex.  Galveston Bay, Tex.  Barataria/Terrebonne Bay, La.  Mississippi Delta, La.  Mississippi Sound, Miss.  Mobile Bay, Ala.  Florida Panhandle, Fla.  Tampa Bay, Fla.

Report↗

Estimating the sources and transport of nutrients in the Waikato River Basin, New Zealand

We calibrated SPARROW (Spatially Referenced Regression on Watershed Attributes) surface water‐quality models using measurements of total nitrogen and total phosphorus from 37 sites in the 13,900‐km 2 Waikato River Basin, the largest watershed on the North Island of New Zealand. This first application of SPARROW outside of the United States included watersheds representative of a wide range of natural and cultural conditions and water‐resources data that were well suited for calibrating and validating the models. We applied the spatially distributed model to a drainage network of nearly 5000 stream reaches and 75 lakes and reservoirs to empirically estimate the rates of nutrient delivery (and their levels of uncertainty) from point and diffuse sources to streams, lakes, and watershed outlets. The resulting models displayed relatively small errors; predictions of stream yield (kg ha −1 yr −1 ) were typically within 30% or less of the observed values at the monitoring sites. There was strong evidence of the accuracy of the model estimates of nutrient sources and the natural rates of nutrient attenuation in surface waters. Estimated loss rates for streams, lakes, and reservoirs agreed closely with experimental measurements and empirical models from New Zealand, North America, and Europe as well as with previous U.S. SPARROW models. The results indicate that the SPARROW modeling technique provides a reliable method for relating experimental data and observations from small catchments to the transport of nutrients in the surface waters of large river basins.

Waikato River↗

Geomorphic change caused by outburst floods and debris flows at Mount Rainier, Washington, with emphasis on Tahoma Creek valley

Debris flows have caused rapid geomorphic change in several glacierized drainages on Mount Rainier, Washington. Nearly all of these flows began as glacial outburst floods, then transformed to debris flows by incorporating large masses of sediment in channel reaches where streams have incised proglacial sediments and stagnant glacier ice. This stagnant ice is a relic of advanced glacier positions achieved during the mid-nineteenth century Little Ice Age maximum and the readvance of the 1960's and 1970's. Debris flows have been especially important agents of geomorphic change along Tahoma Creek, which drains South Tahoma Glacier. Debris flows in Tahoma Creek valley have transported downstream about 107 m3 Of sediment since 1967, causing substantial aggradation and damage to roads and facilities in Mount Rainier National Park. The average denudation rate in the upper part of the Tahoma Creek drainage basin in the same period has been extraordinarily high: more than 20 millimeters per year, a value exceeded only rarely in basins affected by debris flows. However, little or none of this sediment has yet passed out of the Tahoma Creek drainage basin. Outburst floods from South Tahoma Glacier form by release of subglacially stored water. The volume of stored water discharged during a typical outburst flood would form a layer several tens of millimeters thick over the bed of the entire glacier, though it is more likely that large linked cavities account for most of the storage. Statistical analysis shows that outburst floods usually occur during periods of atypically hot or rainy weather in summer or early autumn, and that the probability of an outburst increases with temperature (a proxy measure of ablation rate) or rainfall rate. On the basis of these results, we suggest that outburst floods are triggered when rapid input of water to the glacier bed causes transient increase in water pressure, thereby destabilizing the linked-cavity system. The probabilistic nature of the relation between water-input rate and outburst-flood occurrence suggests that the connections between englacial conduits, basal cavities and main meltwater channels may vary temporally. The correlation between outburst floods and meteorological factors casts doubt on an earlier hypothesis that melting around geothermal vents triggers outburst floods from South Tahoma Glacier. The likelihood that outburst floods from South Tahoma Glacier will trigger debris flows should decrease with time, as the deeply incised reach of Tahoma Creek widens by normal slope processes and stagnant ice decays. Drawing analogies to the geomorphic evolution of a reach of Tahoma Creek first incised by an outburst flood in 1967, we suggest the present period of debris-flow activity along Tahoma Creek will last about 25 years, that is, until about the year 2010. Comparison of geomorphic change at Tahoma Creek to that in two other glacierized alphine basins indicates that debris-rich stagnant ice can be an importantsource of sediment to debris flows as long as floods are frequent or channel slope is great.

Washington↗

South Fork Iowa River watershed selected for a national water-quality study

The U.S. Geological Survey (USGS) is studying seven watersheds across the Nation to better understand how natural factors and agricultural management practices (AMPs) affect the transport of water and chemicals. Natural factors include climate and landscape (soil type, topography, geology), and AMPs include practices related to tillage, irrigation, and chemical application. The study approach is similar in each watershed so that we can compare and contrast the results and more accurately predict conditions in other agricultural settings. Study objectives Understand the links between the sources of water and agricultural chemicals (nutrients and pesticides) and their behavior and transport through the environment Predict the behavior and transport of water and agricultural chemicals in other agricultural areas not being studied Evaluate what the study results mean for management of water and water quality in a variety of agricultural settings We appreciate your help We are working with local growers and land owners to gain access to study sites. We also need information about the watershed and about current as well as historical agricultural management practices—past practices also affect concentrations of agricultural chemicals in ground and surface water. We will report the findings of the study in public meetings and in publications. These findings will provide information that will be useful for improving agricultural management locally and nationally, and will guide future studies in other watersheds. Why study the South Fork Iowa River watershed? The South Fork Iowa River and the other watersheds represent nationally important agricultural settings (chemical use, crops, and AMPs) and natural settings (climate, soils, topography, and geology). South Fork Iowa River, which is part of the Iowa River watershed, is representative of corn and soybean row cropping in the Midwest. Other features of the watershed that are relevant to this study: Use of agricultural chemicals: Commonly used chemicals include herbicides such as atrazine, acetochlor, metolachlor, and glyphosate; and fertilizers, both manure and chemical. Distinct natural setting: Low relief topography with common depressions that formerly formed ponds and wetlands and that are now drained by an extensive network of drainage tiles and ditches. Variety of agricultural management practices: AMPs include both tillage and no-tillage of fields used for corn and soybean production; production of large numbers of hogs in concentrated animal feeding facilities; small grassy riparian buffer zones commonly used to reduce overland runoff. Water-quality issues: Herbicides and nutrients have been frequently detected in Iowa surface and ground water, including in drinking-water wells (findings of USGS studies since the 1990s).

Iowa, Minnesota↗

Aquifer systems in the Great Basin region of Nevada, Utah, and adjacent states: A study plan

The Great Basin Regional Aquifer Study includes about 140,000 square miles in parts of Nevada, Utah, California, Idaho, Oregon, and Arizona. Within that area, 240 hydrographic areas occupy structural depressions formed primarily by basin-and-range faulting. The principal aquifers are in basin- fill deposits; however, permeable carbonate rocks underlie valleys in much of eastern Nevada and western Utah and are significant regional aquifers. Anticipated future water needs require a better understanding of the resource so that wise management will be possible. In October 1980, the U.S Geological Survey started a 4-year study to (1) describe the ground-water systems as they existed under natural conditions and as they exist today, (2) analyze the changes that have led to the systems' present condition, (3) tie the results of this and previous studies together in a regional analysis, and (4) provide means by which effects of future ground-water development can be estimated. A plan of work is presented that describes the general approach to be taken in this study. It defines (1) the major task necessary to meet objectives and (2) constraints on the scope of work. The approach has been strongly influenced by the diverse nature of ground-water flow systems and the large number of basins. A detailed appraisal of 240 individual areas would require more resources than are available. Consequently, the general approach is to study selected "typical" areas and key hydrologic processes. Effort during the first 3 years will be directed toward describing the regional hydrology, conducting detailed studies of "type" areas, and studying selected hydrologic processes. Effort during the final year will be directed toward developing a regional analyses of results. Special studies that will address hydrologic processes, key components of the ground-water system, and improved use of technology include evaluations of regional geochemistry, regional hydrogeology, recharge, ground-water discharge, and the use of remote sensing. Areas selected for study using ground-water flow models include the regional carbonate-rock province in eastern Nevada and western Utah, six valleys Las Vegas, Carson, Paradise, Dixie, Smith Creek, and Stagecoach in Nevada, plus Jordan Valley, the Milford area, and Tule Valley in Utah.

Nevada, Utah↗

Baseline and premining geochemical characterization of mined sites

A rational goal for environmental restoration of new, active, or inactive mine sites would be ‘natural background’ or the environmental conditions that existed before any mining activities or other related anthropogenic activities. In a strictly technical sense, there is no such thing as natural background (or entirely non-anthropogenic) existing today because there is no part of the planet earth that has not had at least some chemical disturbance from anthropogenic activities. Hence, the terms ‘baseline’ and ‘pre-mining’ are preferred to describe these conditions. Baseline conditions are those that existed at the time of the characterization which could be pre-mining, during mining, or post-mining. Protocols for geochemically characterizing pre-mining conditions are not well-documented for sites already mined but there are two approaches that seem most direct and least ambiguous. One is characterization of analog sites along with judicious application of geochemical modeling. The other is reactive-transport modeling (based on careful synoptic sampling with tracer-injection) and subtracting inputs from known mining and mineral processing. Several examples of acidic drainage are described from around the world documenting the range of water compositions produced from pyrite oxidation in the absence of mining. These analog sites provide insight to the processes forming mineralized waters in areas untouched by mining. Natural analog water-chemistry data is compared with the higher metal concentrations, metal fluxes, and weathering rates found in mined areas in the few places where comparisons are possible. The differences are generally 1–3 orders of magnitude higher for acid mine drainage.

Applied Geochemistry↗

Estrogen and androgen receptor activities of hydraulic fracturing chemicals and surface and ground water in a drilling-dense region

The rapid rise in natural gas extraction using hydraulic fracturing increases the potential for contamination of surface and ground water from chemicals used throughout the process. Hundreds of products containing more than 750 chemicals and components are potentially used throughout the extraction process, including more than 100 known or suspected endocrine-disrupting chemicals. We hypothesized thataselected subset of chemicalsusedin natural gas drilling operationsandalso surface and ground water samples collected in a drilling-dense region of Garfield County, Colorado, would exhibit estrogen and androgen receptor activities. Water samples were collected, solid-phase extracted, and measured for estrogen and androgen receptor activities using reporter gene assays in human cell lines. Of the 39 unique water samples, 89%, 41%, 12%, and 46% exhibited estrogenic, antiestrogenic, androgenic, and antiandrogenic activities, respectively. Testing of a subset of natural gas drilling chemicals revealed novel antiestrogenic, novel antiandrogenic, and limited estrogenic activities. The Colorado River, the drainage basin for this region, exhibited moderate levels of estrogenic, antiestrogenic, and antiandrogenic activities, suggesting that higher localized activity at sites with known natural gas–related spills surrounding the river might be contributing to the multiple receptor activities observed in this water source. The majority of water samples collected from sites in a drilling-dense region of Colorado exhibited more estrogenic, antiestrogenic, or antiandrogenic activities than reference sites with limited nearby drilling operations. Our data suggest that natural gas drilling operationsmayresult in elevated endocrine-disrupting chemical activity in surface and ground water.

Colorado↗

Water-quality assessment of the Delmarva Peninsula, Delaware, Maryland, and Virginia--Effects of agricultural activities on, and distribution of, nitrate and other inorganic constituents in the surficial aquifer

Agricultural applications of inorganic fertilizers and manure have changed the natural chemical com- position of water in the surficial aquifer through- out the Delmarva Peninsula. Nitrate, derived from nitrification of ammonia in inorganic fertilizers and manure, is the dominant anion in agricultural areas. Concentrations of nitrate in 185 water samples collected in agricultural areas ranged from 0.4 to 48 mg/L as nitrogen, with a median concen- tration of 8.2 mg/L as nitrogen. Nitrate concen- trations exceeded the U.S. Environmental Protection Agency's maximum contaminant level for drinking water of 10 mg/L as nitrogen in about 33% of the 185 water samples. Groundwater affected by agricultural activities contains significantly higher concentrations of dissolved constituents than does natural groundwater. Concentrations of calcium and magnesium are higher because of liming of soils, and concentrations of potassium and chloride are higher because of applications of potash, a supple- ment to the nitrogen-based fertilizers. Alkalinity concentrations commonly are decreased because the bicarbonate ion is consumed in buffering reactions with acid that is produced during nitrification. Effects of agricultural activities on groundwater quality are not limited to the near-surface parts of the aquifer underlying farm fields. Elevated concentrations are common in aerobic water at or near the base of the aquifer, 80 to 100 ft below land surface. The median concentration of nitrate in water beneath agricultural areas collected from 24 wells deeper than 80 ft below land surface was 8.5 mg/L as nitrogen, and concentrations in 9 of these water samples exceeded the maximum contaminant level. Regional variations in concentrations of nitrate and other agriculture related constituents in the surficial aquifer in the Delmarva Peninsula depend on a number of factors that include geomorphology, geology, soils, land use, and groundwater-flow patterns. (USGS)

Delaware, Maryland, Virginia↗