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A Reconnaissance for Emerging Contaminants in the South Branch Potomac River, Cacapon River, and Williams River Basins, West Virginia, April-October 2004

In 2003 a team of scientists from West Virginia Division of Natural Resources and the U. S. Geological Survey found a high incidence of an intersex condition, oocytes in the testes, among smallmouth bass (Micropterus dolomieu) in the South Branch Potomac River and the Cacapon River of West Virginia, indicating the possible presence of endocrine-disrupting compounds (EDCs). Possible sources of EDCs include municipal and domestic wastewater, and agricultural and industrial activities. Several sampling strategies were used to identify emerging contaminants, including potential EDCs, and their possible sources in these river basins and at an out-of-basin reference site. Passive water-sampling devices, which accumulate in-stream organic chemical compounds, were deployed for 40-41 days at 8 sampling sites. Sampler extracts were analyzed for a broad range of polar and non-polar organic compounds including pesticides, flame retardants, pharmaceuticals, and personal-care products. Analysis of passive-sampler extracts found 4 compounds; hexachloro-benzene; pentachloroanisole; 2,2',4,4',5-penta-bromo-diphenyl ether (BDE 47); and 2,2',4,4',6-penta-bromo-diphenyl ether (BDE 99) to be present at every sampled site, including the reference site, and several sites had detectable quantities of other compounds. No detectable quantity of any antibiotics was found in any passive-sampler extract. Effluent samples were analyzed for 39 antibiotics as tracers of human and agricultural waste. Additionally, poultry-processing plant effluent was sampled for roxarsone, an organoarsenic compound used as a poultry-feed additive, and other arsenic species as tracers of poultry waste. Antibiotics were detected in municipal wastewater, aquaculture, and poultry-processing effluent, with the highest number of antibiotics and the greatest concentrations found in municipal effluent. Arsenate was the only arsenic species detected in the poultry-processing plant effluent, at a concentration of 1.0 ?g/L. Water samples were collected from 7 stream sites and analyzed for arsenic species, including roxarsone. Arsenate was detected in samples from 6 of the 7 stream samples, in concentrations ranging from 0.3 to 0.5 ?g/L. Additionally, the analysis of smallmouth bass blood plasma for potential EDCs indicated the presence of several compounds including some found in the passive sampler extracts, specifically BDE 47 and BDE 99. Data from this reconnaissance will help to focus efforts for further studies of the occurrence of emerging contaminants, EDCs, and intersex in smallmouth bass in these Potomac River tributaries.

Open-File Report↗

Understanding the role of fog in forest hydrology: Stable isotopes as tools for determining input and partitioning of cloud water in montane forests

Understanding the hydrology of tropical montane cloud forests (TMCF) has become essential as deforestation of mountain areas proceeds at an increased rate worldwide. Passive and active cloud‐water collectors, throughfall and stemflow collectors, visibility or droplet size measurements, and micrometeorological sensors are typically used to measure the fog water inputs to ecosystems. In addition, stable isotopes may be used as a natural tracer for fog and rain. Previous studies have shown that the isotopic signature of fog tends to be more enriched in the heavier isotopes 2 H and 18 O than that of rain, due to differences in condensation temperature and history. Differences between fog and rain isotopes are largest when rain is from synoptic‐scale storms, and fog or orographic cloud water is generated locally. Smaller isotopic differences have been observed between rain and fog on mountains with orographic clouds, but only a few studies have been conducted. Quantifying fog deposition using isotope methods is more difficult in forests receiving mixed precipitation, because of limitations in the ability of sampling equipment to separate fog from rain, and because fog and rain may, under some conditions, have similar isotopic composition. This article describes the various types of fog most relevant to montane cloud forests and the importance of fog water deposition in the hydrologic budget. A brief overview of isotope hydrology provides the background needed to understand isotope applications in cloud forests. A summary of previous work explains isotopic differences between rain and fog in different environments, and how monitoring the isotopic signature of surface water, soil water and tree xylem water can yield estimates of the contribution of fog water to streamflow, groundwater recharge and transpiration. Next, instrumentation to measure fog and rain, and methods to determine isotopic concentrations in plant and soil water are discussed. The article concludes with the identification of some of the more pressing research questions in this field and offers various suggestions for future research.

Hydrological Processes↗

Lessons learned from wetlands research at the Cottonwood Lake Study Area, Stutsman County, North Dakota, 1967–2021

Depressional wetlands in the Prairie Pothole Region of North America have a long history of investigation owing to their importance in maintaining migratory-bird populations, especially waterfowl. One area of particularly intensive study is the Cottonwood Lake study area in Stutsman County, North Dakota. Studies at the Cottonwood Lake study area began in 1967 and continue through the present (2022). During this period of scientific discovery, meteorological conditions at the Cottonwood Lake study area varied greatly and included one of the most severe droughts of the 20th century and one of the wettest periods in the past 500 years. Persistent wet conditions that began in 1993 have contributed to state changes in many of the study area’s larger wetlands to lake-like conditions, whereas the smaller wetlands returned to seasonally ponded conditions during relatively dry years interspersed within the longer-term wet period. Additionally, some nonwetland areas of the study area developed wetland plant, hydrology, and soil characteristics during the 1993-to-present (2022) wet period. The persistently high stages of water in the larger wetlands since 1993 contributed to a buildup of dissolved solids and increases in salinity with time following an initial decrease in salinity caused by the dilution of dissolved solids within a larger volume of water. During 2021, drought conditions similar to the 1988 to 1992 period may develop if conditions persist. However, meteorological changes during the past 30 years have persisted long enough to be considered a change in climate conditions at the study area and, if such wet conditions continue, would represent a change from conditions that occurred in the past two millennia. During the period of study covered in this report (1967–2021), biotic communities responded in a variety of ways to subtle and marked changes in ponded-water depths, permanence, and salinity among the different wetland types in the study area. This report provides background information on the Cottonwood Lake study area and its context within the Prairie Pothole Region, documents techniques used to quantify environmental conditions and biotic communities, describes major trends that have been observed, presents significant findings as “lessons learned,” discusses recent modeling advances, and highlights key messages to managers. The Wetland Continuum concept was used as a framework to place research findings within an ecological context and to highlight the dynamic nature of prairie-pothole wetland ecosystems.

North Dakota↗

Water chemistry of the Redwood Creek and Mill Creek basins, Redwood National Park, Humboldt and Del Norte Counties, California

A 2-year study was made in the Redwood Creek and Mill Creek drainage basins of Redwood National Park to determine existing chemical water-quality conditions and to identify the effects of logging on water quality in the main stems and tributaries of the two basins. Overall, the chemical water quality of the main stems and the tributaries is excellent, suitable for most beneficial uses. Dissolved-solids concentrations range from 25 milligrams per liter in the Redwood Creek basin and 21 milligrams per liter in the Mill Creek basin during the rainy season to 139 and 49 during the dry season. Water shifts from a mixed calcium-sodium bicarbonate-chloride type toward a calcium bicarbonate type from the end of the wet season to the end of the dry season. It shifts back toward a mixed calcium-sodium bicarbonate-chloride type from the end of the dry season to the end of the wet season. The pH shifts with the water type from a median value of 6.80 in the rainy season to 7.37 in the dry season. Nitrogen and phosphorus concentrations are generally too low to support nuisance algae but are high enough, in some streams, to support modest populations, particularly in the main stem where light levels are high. Trace-metal concentrations are low, typical of clean streams. Evidence suggests that dissolved calcium and bicarbonate in stream water is produced by weathering of the Franciscan assemblage underlying the basins but that chlorides are transported inland from the ocean as dry fallout and spray and in rain. Exposure of the surface soils to the elements, either by logging or by natural causes such as sparse vegetation, seems to accelerate weathering, which leads to a calcium bicarbonate water type. Logging accelerates weathering most in the tributary watersheds with regoliths derived from sandstone and least in those with regoliths derived from schist; however, the data suggest that the rate of weathering in a schistose watershed can increase dramatically if soil disruption is extensive. Studies during storms indicated that specific conductance and alkalinity were two to three times as likely to decrease at the discharge peak in logged watersheds as in forested ones. This suggests that overland flow containing lower concentrations of soil-derived dissolved solids than flow from other sources is a larger component of peak flow in logged watersheds than in forested watersheds. Comparing a storm in November 1974 to one in February 1975, nitrate concentration increased significantly from November to February in a stream draining a logged watershed and decreased significantly in a stream draining a forested watershed. Then from the rainy season to the dry season, nitrate decreased in both logged and forested watersheds. This pattern suggests that soil nitrate produced by fixation and organic decomposition early in the rainy season tends to wash out of logged watersheds but be taken up in tree growth in forested watersheds. As the dry season progresses, base flow containing little nitrate enters the streams, causing a decrease in nitrate concentration. By contrast, the other plant nutrients--phosphorus, Kjeldahl nitrogen, ammonium, and dissolved organic carbon--all decreased in streams from the November 1974 storm to the February 1975 storm and changed little from the rainy season through the dry season. This pattern suggests that these materials tend to accumulate in the soil during the dry season and be washed out and diluted as the rainy season progresses. Very little reaches the water table due to soil absorption so that little appears in the base flow during the dry season.

California↗

Establishing an Agassiz’s Desert Tortoise monitoring program within the Coachella Valley multiple species habitat conservation plan area: Final report to the Coachella Valley conservation commission on work performed near the Orocopia Mountains

In support of the goals of the Coachella Valley Multiple Species Habitat Conservation Plan and Natural Community Conservation Plan (CVMSHCP/NCCP), a population of Agassiz’s desert tortoises ( Gopherus agassizii ) was marked and studied to establish a desert tortoise monitoring program near the Orocopia Mountains beginning in early 2017 and ending in the summer of 2018, following the epic drought of 2012‒2016. This effort compliments a similar effort in the nearby mouth of Cottonwood Canyon in 2015‒2016. Surveys were performed to locate tortoises, tortoise burrows, and tortoise remains at the eastern end of the CVMSHCP area north of the Orocopia Mountains and south of Interstate 10 in Riverside County, California. Although the area is considered Critical Habitat for the recovery of tortoise populations, it was heavily impacted by military training activities in the early 1940s and continues to be impacted by off-highway vehicle use. Data were collected from all live and dead tortoise specimens encountered. Only 22 live tortoises were found during transects covering approximately 21 km 2 of habitat surveyed. The sex ratio of live adult tortoises was strongly biased toward males and the sex ratio of recently (4‒5 years) dead carcasses during the long drought was strongly biased toward females. High female mortality may have resulted from the interaction of drought (including increased predation) and the reproductive strategy of tortoises. We located only one new live tortoise in the drought year of 2018 when there was no germination of winter annual food plants. A subsample of nine tortoises was outfitted with radio transmitters, and females (n = 4) were X-radiographed at approximately 10-day intervals from April–July. Mean clutch size was about 4 eggs as is typical for tortoises in this region. Additional tortoises were located opportunistically in and around the Santa Rosa Mountains (located in the southern end of the CVMSHCP area), and these tortoises were also marked for future identification. Blood samples were taken from adult tortoises and scute clips were taken from a subset of juveniles for ongoing studies to determine genetic diversity and relationships of desert tortoises within the CVMSHCP/NCCP area and beyond. The low tortoise density and high adult female mortality observed by us and others in the area may compromise the long-term viability of the population, especially given published predictions of the negative effects of future droughts on tortoises in the region.

California↗

A cross-validation package driving Netica with python

Bayesian networks (BNs) are powerful tools for probabilistically simulating natural systems and emulating process models. Cross validation is a technique to avoid overfitting resulting from overly complex BNs. Overfitting reduces predictive skill. Cross-validation for BNs is known but rarely implemented due partly to a lack of software tools designed to work with available BN packages. CVNetica is open-source, written in Python, and extends the Netica software package to perform cross-validation and read, rebuild, and learn BNs from data. Insights gained from cross-validation and implications on prediction versus description are illustrated with: a data-driven oceanographic application; and a model-emulation application. These examples show that overfitting occurs when BNs become more complex than allowed by supporting data and overfitting incurs computational costs as well as causing a reduction in prediction skill. CVNetica evaluates overfitting using several complexity metrics (we used level of discretization) and its impact on performance metrics (we used skill).

Environmental Modelling and Software↗

Practical use of video imagery in nearshore oceanographic field studies

An approach was developed for using video imagery to quantify, in terms of both spatial and temporal dimensions, a number of naturally occurring (nearshore) physical processes. The complete method is presented, including the derivation of the geometrical relationships relating image and ground coordinates, principles to be considered when working with video imagery and the two-step strategy for calibration of the camera model. The techniques are founded on the principles of photogrammetry, account for difficulties inherent in the use of video signals, and have been adapted to allow for flexibility of use in field studies. Examples from field experiments indicate that this approach is both accurate and applicable under the conditions typically experienced when sampling in coastal regions. Several applications of the camera model are discussed, including the measurement of nearshore fluid processes, sand bar length scales, foreshore topography, and drifter motions. Although we have applied this method to the measurement of nearshore processes and morphologic features, these same techniques are transferable to studies in other geophysical settings.

IEEE Journal of Oceanic Engineering↗

Hydrology and water quality of Geneva Lake, Walworth County, Wisconsin

As part of continuing efforts to improve the water quality of Geneva Lake, a collaborative effort between the U.S. Geological Survey, the Wisconsin Department of Natural Resources, and the Geneva Lake Environmental Agency was initiated in 1997 to document the present quality of the lake and its sediments, compute detailed hydrologic and nutrient (primarily phosphorus) budgets for the lake, estimate how changes in nutrient loading may affect water quality, and describe changes in the lake over the past 170 years by comparing water quality measured in this study with historical measurements and sediment-core information. This report presents the results of this collaborative study. Measurements collected during this study (1997.2000) indicate that the trophic status of the lake ranges from mesotrophic to oligotrophic: the mean Secchi depth was 4.8 m (meters), mean surface phosphorus concentration was 9 ?g/L (micrograms per liter), mean surface nitrogen concentration was 550 ?g/L, and mean surface chlorophyll a concentration was 3 ?g/L. Surface nitrogen: phosphorus ratios indicated that, if just these nutrients are considered, phosphorus should be the limiting nutrient. Phosphorus budgets constructed for water years 1998 and 1999 indicate that recent annual phosphorus loads were about 2,000 kg (kilograms) less than that estimated in 1975 (total annual input was about 3,200 kg in 1998 and about 8,500 kg in 1999). The major source of phosphorus to the lake was from its tributaries, which contributed about 84 percent of the total load. The primary difference from the phosphorus load estimates for 1975 was the decrease in loading from the Fontana sewage-treatment plant. Direct measurements and indirect measurements based on sediment-core analyses indicate that the water quality of Geneva Lake has degraded in the last 170 years, the greatest effects resulting from urbanization. Sedimentation rates were highest between 1900 to 1930, and phosphorus concentrations were highest between the 1930s to early 1980s. As a result of the recent reduction in phosphorus loading, in-lake near-surface phosphorus concentrations decreased from 20.25 ?g/L to about 10.15 ?g/L and are similar to those estimated for the lake in the early 1900s. Concentrations of other chemical constituents associated with urban areas, however, have continually increased, especially in Williams Bay and Geneva Bay.

Wisconsin↗

Map showing outcrop of the coal-bearing units and land use in the Gulf Coast region

This map is a preliminary compilation of the outcrop geology of the known coal-bearing units in the Gulf Coast Coal region. The map has been compiled for use in the National Coal Resource Assessment Project currently being conducted by the U.S. Geological Survey, and will be updated as the assessment progresses. The purpose of the map is to show the distribution of coal-bearing rocks in the Gulf Coastal Plain Region and to show stratigraphic correlations, transportation network, fossil-fuel burning power plants, and federally managed lands in the region. It is hoped that this map may aid coal exploration and development in the region. Geologic contacts were digitized from paper copies of the maps listed in the reference section below. The primary source of information was the 1:500,000-scale state geology map series, but larger scale maps were use to better define certain areas, notably the Jackson-Claiborne contact in western Kentucky and Tennessee for example (Olive, 1980). Contacts along state boundaries were modified to best-fit information available from the border areas. Note that coal distribution in the mapped units is not uniform. For example, the Jackson Group contains coal in Texas, but in Mississippi is not presently known to contain significant coal deposits. The unit is widespread and in part non-marine and thus of potential future interest. In contrast, the Jackson Group is not shown in Georgia where it is mostly marine and residuum (weathered material) at the surface. Tertiary age coal has also been noted in the Vicksburg Group (Oligocene) of Louisiana and Mississippi, but is not shown on this map. Contacts with mapped surficial units are not always shown. The locations of coal mine permit boundaries are based on information available at the time of publication and were obtained from the Division of Surface Mining and Reclamation, Railroad Commission of Texas, Austin, and the Injection and Mining Division, Department of Natural Resources, Baton Rouge, Louisiana. The correlation of map units and formation names generally follow Galloway and others (1991). We have placed the Paleocene-Eocene boundary in the middle of the Calvert Bluff Formation in Texas based on unpublished pollen biostratigraphy reports (N.O. Fredericksen, unpublished data, 1993; D.J. Nichols, unpublished data, 1996).

Alabama, Arkansas, Georgia, Florida, Kansas, Kentu↗

Detections, concentrations, and distributional patterns of compounds of emerging concern in the San Antonio River Basin, Texas, 2011-12

During 2011–12, the U.S. Geological Survey, in cooperation with the San Antonio River Authority, evaluated detections, concentrations, and distributional patterns of selected compounds of emerging concern (hereinafter referred to as “CECs”) from water-quality samples (hereinafter referred to as “samples”) collected at a total of 20 sampling sites distributed throughout the San Antonio River Basin, Texas. Of the 54 wastewater compounds analyzed, 32 were detected in at least one sample collected from the San Antonio River Basin, and 22 of those compounds were not detected in any samples. The flame retardants tris (2-chloroethyl) phosphate and tris (dichloroisopropyl) phosphate, both possible endocrine disruptors, were the most frequently detected wastewater compounds with 28 of the 33 samples analyzed for wastewater compounds having measureable concentrations of those compounds. Of the 13 analyzed pharmaceuticals, 4 compounds were detected in a least one sample. Carbamazepine, an anticonvulsant, was the most frequently detected prescription pharmaceutical with 24 detections in 34 samples analyzed for pharmaceuticals. Of the 17 steroidal hormones, 4 were detected in at least one sample from the San Antonio River Basin. Estrone was detected in 9 of 34 samples analyzed for steroidal hormones, making it the most frequently detected steroidal hormone. Of the 4 sterols, all 4 were detected in at least one sample from the San Antonio River Basin. Cholesterol, detected in 19 of 34 samples analyzed for sterols, was the most frequently detected sterol. Three synoptic sampling events were completed as part of this study. The first and second synoptic sampling events included samples collected at the same 12 sampling sites. During the first and second synoptic sampling events, the lowest number of detections (2 and 0, respectively) and the lowest total concentrations of all measured compounds (0.62 and not measureable, respectively) occurred in samples collected at the Macdona site (Medina River near Macdona, Tex.). The highest number of detections (21 and 23, respectively) and highest total concentrations of all measured compounds (7.75 and 3.97 micrograms per liter [µg/L], respectively) occurred in samples collected at the SAR Elmendorf site (San Antonio River near Elmendorf, Tex.). The third synoptic sampling event included samples collected at seven sites that were added to the study after the first two synoptic sampling events were completed. During the third synoptic sampling event, the lowest number of detections (two) and the lowest total concentration (0.14 µg/L) of compounds were measured in samples collected at the North Prong site (North Prong Medina River above confluence Wallace Creek near Medina, Tex.). The highest number of detections (21) occurred at the SAR Mitchell site (San Antonio River at Mitchell Street, San Antonio, Tex.). The Dos Rios site (the Dos Rios wastewater treatment plant outfall at San Antonio, Tex.) had the highest total concentration of all measured compounds (4.37 µg/L) in the third synoptic sampling event. Because Ecleto Creek flows only intermittently at the Ecleto site (Ecleto Creek near Runge, Tex.), samples from the Ecleto site were collected at different times than were samples from the other sites and were not included in a synoptic sampling event. The presence of wastewater compounds at the Ecleto site indicates that at least some wastewater compounds can be introduced into surface waters in rural parts of the San Antonio River Basin during runoff or because of onsite wastewater system seepage. The steroidal hormone and sterols detected at the Ecleto site, including estrone, cholesterol, beta -sitosterol, and beta -stigmastanol, likely were derived from cattle waste rather than from wastewater effluent. The distributional patterns of detections and concentrations of individual compounds and compound classes show the influence of wastewater-treatment plant (WWTP) outfalls on the quality of water in the San Antonio River Basin. In the Medina River Subbasin, the minimal influence of wastewater is evident as far downstream as the Macdona site. Downstream from the Macdona site, the Medina River receives treated municipal wastewater from both the Medio Creek Water Recycling Center site from an unnamed tributary at the plant and the Leon Creek Water Recycling Center site from Comanche Creek at the plant, and corresponding increases in both the number of detections and the total concentrations of all measured compounds at all downstream sampling sites were evident. Similarly, the San Antonio River receives treated municipal wastewater as far upstream as the SAR Witte site (San Antonio River at Witte Museum, San Antonio, Tex.) and additional WWTP outfalls along the Medina River upstream from the confluence of the Medina and San Antonio Rivers. Consequently, all samples collected along the main stem of the San Antonio River had higher concentrations of CECs in comparison to sites without upstream WWTPs. Sites in urbanized areas without upstream WWTPs include the Leon 35 site (Leon Creek at Interstate Highway 35, San Antonio, Tex.), the Alazan site (Alazan Creek at Tampico Street, San Antonio, Tex.), and the San Pedro site (San Pedro Creek at Probandt Street, at San Antonio, Tex.). The large number of detections at sites with no upstream wastewater source demonstrated that CECs can be detected in streams flowing through urbanized areas without a large upstream source of treated municipal wastewater. A general lack of detection of pharmaceuticals in streams without upstream outfalls of treated wastewater appears to be typical for streams throughout the San Antonio River Basin and may be a useful indicator of point-source versus nonpoint-source contributions of these compounds in urban streams. Observations of lower concentrations of compounds at the furthest downstream sampling sites in the basin indicate some natural attenuation of these compounds during transport; however, a more focused assessment is needed to make this determination.

Texas↗

Phytoforensics: Trees as bioindicators of potential indoor exposure via vapor intrusion

Human exposure to volatile organic compounds (VOCs) via vapor intrusion (VI) is an emerging public health concern with notable detrimental impacts on public health. Phytoforensics, plant sampling to semi-quantitatively delineate subsurface contamination, provides a potential non-invasive screening approach to detect VI potential, and plant sampling is effective and also time- and cost-efficient. Existing VI assessment methods are time- and resource-intensive, invasive, and require access into residential and commercial buildings to drill holes through basement slabs to install sampling ports or require substantial equipment to install groundwater or soil vapor sampling outside the home. Tree-core samples collected in 2 days at the PCE Southeast Contamination Site in York, Nebraska were analyzed for tetrachloroethene (PCE) and results demonstrated positive correlations with groundwater, soil, soil-gas, sub-slab, and indoor-air samples collected over a 2-year period. Because tree-core samples were not collocated with other samples, interpolated surfaces of PCE concentrations were estimated so that comparisons could be made between pairs of data. Results indicate moderate to high correlation with average indoor-air and sub-slab PCE concentrations over long periods of time (months to years) to an interpolated tree-core PCE concentration surface, with Spearman’s correlation coefficients (ρ) ranging from 0.31 to 0.53 that are comparable to the pairwise correlation between sub-slab and indoor-air PCE concentrations (ρ = 0.55, n = 89). Strong correlations between soil-gas, sub-slab, and indoor-air PCE concentrations and an interpolated tree-core PCE concentration surface indicate that trees are valid indicators of potential VI and human exposure to subsurface environment pollutants. The rapid and non-invasive nature of tree sampling are notable advantages: even with less than 60 trees in the vicinity of the source area, roughly 12 hours of tree-core sampling with minimal equipment at the PCE Southeast Contamination Site was sufficient to delineate vapor intrusion potential in the study area and offered comparable delineation to traditional sub-slab sampling performed at 140 properties over a period of approximately 2 years.

Nebraska↗

Ground-water potentialities in the Crescent Valley, Eureka and Lander Counties, Nevada

The Crescent Valley is an intermontane basin in Eureka and Lander Counties, just south of the Humboldt River in north-central Nevada. The valley floor, with an area of about 150 square miles, has a shape that more nearly resembles a Y than a crescent, although the valley apparently was named after the arc described by its southern part and northeastern arm. The northwestern arm of the Y extends northward to the small railroad town of Beowawe on the Humboldt River; the northeastern arm lies east of the low Dry Hills. The leg of the Y extends southwestward toward a narrow gap which separates the Crescent Valley from the Carico Lake Valley. The total drainage area of the Crescent Valley-about 700 square miles--includes also the slopes of the bordering mountain ranges: the Shoshone Range to the west, the Cortez Mountains to the east, and the Toiyabe Range to the south. The early history of the Crescent Valley was dominated by mining of silver and gold, centered at Lander in the Shoshone Range and at Cortez and Mill Canyon in the Cortez Mountains, but in recent years the only major mining activity has been at Gold Acres; there open-pit mining of low-grade gold ore has supported a community of about 200. For many years the only agricultural enterprises in the valley were two cattle ranches, but recently addition lands have been developed for the raising of crops in the west-central part of the valley. The average annual precipitation upon the floor of the Crescent Valley is probably less than 7 inches, of which only a little more than 1 inch formally falls during the growing season (from June through September). This is far less than the requirement of any plants of economic value, and irrigation is essential to agricultural development. Small perennial streams rising in the mountains have long been utilized for domestic supply, mining and milling activities of the past, and irrigation, and recently some large wells have been developed for irrigation. In 1956 the total pumpage from wells in the valley was 2,300 acre-feet. The Crescent Valley is a basin in which has accumulated a large volume of sediments that had been eroded and transported by streams from the surrounding mountains. The deepest wells have penetrated only the upper 350 feet of these sediments, which on the basis of the known thickness of sediments in other intermontane basins in central Nevada may be as much as several thousand feet thick. Because this valley fill is saturated practically to the level of the valley floor, the total volume of ground water in storage amounts to millions of acre-feet. In practically all wells drilled to date, the water has been of a quality satisfactory for irrigation and domestic use. The amount of water that can be developed and used perennially is far smaller than the total in storage and is dependent upon the average annual recharge to the ground-water reservoir. This recharge comes principally from streams, fed largely by snowmelt, that drain the higher mountains. The average annum recharge to the valley fill is estimated to be about 13,000 acre-feet. This natural supply, which is largely consumed by native vegetation on the valley floor, constitutes a perennial supply for beneficial use only to the extent that the natural discharge can be reduced. In time, much of the natural discharge, can probably be salvaged, if it is economically feasible to pump ground water after water levels have been lowered as much as 100 feet in the areas that now appear to be favorable for the development of irrigation supplies. In 5 wells in the phreatophyte area, where the water table is within 3-8 feet of the land surface, the trends in water level have paralleled those, in precipitation-downward during the dry years 1952-55, upward in wetter 1956 and 1957, and as high in 1957 as at any time since 1948. In most wells there is also a seasonal fluctuation of 1-3 feet, from a high in the spring to a low in the fall. There is no evi

Water Supply Paper↗

Zinc isotope investigation of surface and pore waters in a mountain watershed impacted by acid rock drainage

The pollution of natural waters with metals derived from the oxidation of sulfide minerals like pyrite is a global environmental problem. However, the metal loading pathways and transport mechanisms associated with acid rock drainage reactions are often difficult to characterize using bulk chemical data alone. In this study, we evaluated the use of zinc (Zn) isotopes to complement traditional geochemical tools in the investigation of contaminated waters at the former Waldorf mining site in the Rocky Mountains, Colorado, U.S.A. Geochemical signatures and statistical analysis helped in identifying two primary metal loading pathways at the Waldorf site. The first was characterized by a circumneutral pH, high alkalinity, and high Zn/Cd ratios. The second was characterized by acidic pHs and low Zn/Cd ratios. Zinc isotope signatures in surface water samples collected across the site were remarkably similar (the δ 66 Zn, relative to JMC 3-0749-L, for most samples ranged from 0.20 to 0.30‰ ± 0.09‰ 2σ). This probably suggests that the ultimate source of Zn is consistent across the Waldorf site, regardless of the metal loading pathway. The δ 66 Zn of pore water samples collected within a nearby metal-impacted wetland area, however, were more variable, ranging from 0.20 to 0.80‰ ± 0.09‰ 2σ. Here the Zn isotopes seemed to reflect differences in groundwater flow pathways. However, a host of secondary processes might also have impacted Zn isotopes, including adsorption of Zn onto soil components, complexation of Zn with dissolved organic matter, uptake of Zn into plants, and the precipitation of Zn during the formation of reduced sulfur species. Zinc isotope analysis proved useful in this study; however, the utility of this isotopic tool would improve considerably with the addition of a comprehensive experimental foundation for interpreting the complex isotopic relationships found in soil pore waters.

Colorado↗

Pollen evidence for late pleistocene bering land bridge environments from Norton Sound, Northeastern Bering Sea, Alaska

After more than half a century of paleoenvironmental investigations, disagreements persist as to the nature of vegetation type and climate of the Bering land bridge (BLB) during the late Wisconsin (Sartan) glacial interval. Few data exist from sites on the former land bridge, now submerged under the Bering and Chukchi Seas. Two hypotheses have emerged during the past decade. The first, based on pollen data from Bering Sea islands and adjacent mainlands of western Alaska and Northeast Siberia, represents the likely predominant vegetation on the Bering land bridge during full-glacial conditions: graminoid-herb-willow tundra vegetation associated with cold, dry winters and cool, dry summer climate. The second hypothesis suggests that dwarf birch-shrub-herb tundra formed a broad belt across the BLB, and that mesic vegetation was associated with cold, snowier winters and moist, cool summers. As a step towards resolving this controversy, a sediment core from Norton Sound, northeastern Bering Sea was radiocarbon dated and analyzed for pollen content. Two pollen zones were identified. The older, bracketed by radiocarbon ages of 29,500 and 11,515 14 C yr BP, contains pollen assemblages composed of grass, sedge, wormwood, willow, and a variety of herb (forb) taxa. These assemblages are interpreted to represent graminoid-herb-willow tundra vegetation that developed under an arid, cool climate regime. The younger pollen zone sediments were deposited about 11,515 14 C yr BP, when rising sea level had begun to flood the BLB. This younger pollen zone contains pollen of birch, willow, heaths, aquatic plants, and spores of sphagnum moss. This is interpreted to represent a Lateglacial dwarf birch-heath-willow-herb tundra vegetation, likely associated with a wetter climate with deeper winter snows, and moist, cool summers. This record supports the first hypothesis, that graminoid-herb-willow tundra vegetation extended into the lowlands of the BLB during full glacial conditions of the late Wisconsin.

Alaska↗

Ecological effects of pinyon-juniper removal in the Western United States—A synthesis of scientific research, January 2014–March 2021

Executive Summary Increasing density of pinyon ( Pinus spp. ) and juniper ( Juniperus spp. ) woodlands (hereinafter “pinyon-juniper”), as well as expansion of these woodlands into adjacent shrublands and grasslands, has altered ecosystem function and wildlife habitat across large areas of the interior western United States. Although there are many natural and human-caused drivers of woodland infilling and expansion, restoration of sagebrush ( Artemisia spp. ) habitat through removal of pinyon-juniper is considered an urgent management objective in many locations, particularly in support of sagebrush-dependent wildlife species of conservation concern. In December 2020, the Bureau of Land Management (BLM) established the Pinyon-Juniper Management Categorical Exclusion (PJCX) to expedite the regulatory process for pinyon-juniper removal projects on public lands, largely intended to benefit mule deer ( Odocoileus hemionus ) and greater sage-grouse ( Centrocercus urophasianus ) habitats. During final preparation of this report, the BLM discontinued use of the PJCX (as of November, 2022), but the pinyon-juniper tree removal techniques assessed in this report are commonly used and understanding their effects remains relevant to land use planning. To address areas of uncertainty relative to potential ecological effects of the PJCX, we conducted a review of the peer-reviewed science literature to better understand the likely responses of vegetation, environmental (for example, soils), and wildlife variables to specific tree removal techniques permitted by the PJCX. In brief, the PJCX permitted removal of trees by either manual cutting, mechanical cutting, or mastication; allowed certain methods to redistribute or remove resulting tree biomass after treatment; and prohibited broadcast burning, roadbuilding, removal of old-growth, and seeding of non-native species. Specifically, we conducted our review to address the following questions: How will PJCX removal techniques affect plant communities, soils, and abiotic resources? How do these pinyon-juniper removal techniques affect wildlife communities, including both woodland- and sagebrush-dependent species? What are the potential ecological implications of different pinyon-juniper removal treatment types and implementation strategies (for example, treatment sizes) over time? What are the most important gaps in our scientific understanding of how treatments might affect targeted ecosystems over space and time (for example, potential effects of climate change)? To answer these questions, we considered studies related to pinyon-juniper ecosystems, focusing on research that occurred over a large portion of the interior western United States that is the primary focus of the PJCX. We also focused on papers published from 2014 onward, to avoid excessive overlap with other recent reviews on pinyon-juniper management effects. Using strict criteria, including only considering research that tested responses for statistical significance, we identified 48 papers that primarily examined treatment effects on vegetation and other environmental variables (1,709 responses), and 11 papers that addressed effects on wildlife (132 responses). Responses to the PJCX-permitted treatments were summarized as either positive (that is, a significant increase), negative (that is, a significant decrease), or non-significant (that is, no significant difference). Responses were assigned to categories (for example, Native Annual Grass/Forb Abundance) and hierarchical treatment levels. We found that there were large proportions of non-significant responses among all categories combined, with roughly half or more of all responses non-significant (48 percent for wildlife, 60 percent for vegetation-environmental), comparable to other recent systematic reviews of pinyon-juniper treatment effects. However, we also found that when there were significant responses, some important trends potentially emerged. Important undesirable outcomes included far more positive than negative responses of exotic grass and forb abundance among nearly all treatment types. Cutting treatments were also more likely to decrease biocrust cover and microbial activity. Potentially beneficial outcomes included mostly positive responses among sagebrush obligate species, including more positive than negative responses for mule deer and sage-grouse. Some treatment types (for example, mastication) also resulted in more positive than negative responses for native grasses and forbs (although, non-significant responses were the majority). We also highlighted many limitations of this review, including how responses often come from few studies, and how some response-treatment category combinations lack adequate response data. Moreover, the existing research is often insufficient to address many key questions about treatment effects, largely owing to short time-scales and limited spatial extents of observations, which do not match the size of treatments being implemented by land managers, nor capture long-term, post-treatment ecological dynamics. We also identify a lack of research that addresses key interactions that could undermine restoration objectives, including potential effects of climate change and grazing on post-treatment environments. Thus, we emphasize the importance of integrating these factors into future pinyon-juniper treatment research, and we stress the need for use of monitoring programs and research studies that partake in data collection and analysis over long durations and broad spatial scales.

Open-File Report↗

Analysis of vegetation changes in Rock Creek Park, 1991-2007

Vegetation data collected at Rock Creek Park every 4 years during 1991-2007 were analyzed for differences among 3 regions within the park and among years. The variables measured and analyzed were percentage of twigs browsed, percentage of canopy cover, species richness of herbaceous plants, number of tree seedlings in each of 7 height classes, tree seedling stocking rate for low deer density and high deer density areas, percentage of tree and shrub cover < 2 m in height, mean diameter at breast height (DBH) of trees > 1 cm DBH, number of tree stems > 1 cm DBH, species richness of trees and shrubs, and mean height of the 5 tallest trees in each plot quadrant. Repeated measures analysis of variance (ANOVA) was used to test for differences and, except for some differences in tree species composition among the 3 regions, no differences (P > 0.01) were found among the 3 regions in the variables discussed above. Many of the variables showed very significant differences (P < 0.01) among years, and causative factors should be investigated further. In addition, importance values were calculated for the 10 most important tree species in each region and changes over time were reported. Future sampling recommendations are also discussed.

Natural Resource Technical Report↗

Influence of the Houma Navigation Canal on Salinity Patterns and Landscape Configuration in Coastal Louisiana

Coastal Louisiana is a dynamic and ever changing landscape. From 1956 to 2004, over 297,000 ha of Louisiana's coastal wetlands were lost because of the effects of natural and human-induced activities. Studies show that, in 2005, Hurricanes Katrina and Rita transformed over 56,200 ha of wetlands to open water in various parts of coastal Louisiana. Besides the catastrophic hurricanes, factors such as subsidence, sea-level rise, freshwater and sediment deprivation, saltwater intrusion, the dredging of oil and gas canals, navigation canals, shoreline erosion, and herbivory are all contributors to wetland loss in Louisiana. Various scientific literatures have well described the direct impacts associated with an immediate physical conversion of habitat in coastal Louisiana; however, the indirect impacts that are subtle and operate over longer time horizons (such as salinity intrusion) have been difficult to discern. In this report, long-term influences on salinity patterns and landscape configuration are evaluated for pre- and postconstruction periods of the Houma Navigation Canal (HNC), which is located in the coastal region of southeastern Louisiana. Analysis of daily and hourly salinity data from long-term data collection stations within the areas surrounding the HNC indicated that there were no obvious patterns in increasing salinity levels following the completion of the canal, except for the immediate increase in salinity spikes that occurred toward the completion of its construction in 1961. Increases in salinity spikes were also observed during a severe drought in 1999-2000. Data from Bayou Grand Caillou at Dulac, however, show a longer term trend of increasing salinity levels, which is similar to the pattern observed at the Houma Water Treatment Plant. A potential explanation for these patterns is based on the dredging history of the HNC, where dates of maintenance dredging correspond fairly closely to the salinity peaks in Bayou Grand Caillou and the canal. It appears that the dredging events opened up a deeper route from the canal to Crozier and into Grand Bayou Caillou, but it also may be a result of the general breakup of the marsh in the adjacent area, which resulted in greater exchange of bay water and subsequently higher salinity levels. Although the available salinity data were insufficient to conduct statistical correlations, there was close agreement between salinity changes and specific dredging events of the HNC. A procedure for analyzing marsh landscapes, which utilizes the FRAGSTATS landscape statistical application and a two-part marsh classification system, was developed as a means of determining the connectivity and configuration of marsh and water patches within the study area. Individual landscape metrics were used to determine the percentage and rate of land change and the shifts in density, shape, and cohesiveness of water within the marsh. Wetland loss rates for coastal Louisiana and Terrebonne basin were compared to the long- and short-term loss rates of the Houma Navigation Canal study area that were quantified by using the FRAGSTATS landscape analysis method. These results suggest that the canal study area was losing land at a significantly faster rate than both the marshes of coastal Louisiana (over all periods) and the other highly degraded neighboring marshes within Terrebonne basin. Overall, 37 percent (17,625 ha) of the project area marsh was lost between 1958 and 1998. As a means of quantifying the distance and degree of influence that the HNC had on marsh degradation, a 3-km interval buffer array and comparable years of vegetation data were used to describe the changes in primary metric values across the three project dates (1958, 1968/69, and 1998). The patterns across landscape metrics varied, and it was difficult to discern direct relationships based on proximity to the canal. Even though the canal may have an influence on marsh degradation, these analyses show that the degree and d

Open-File Report↗

A decade of insights into grassland ecosystem responses to global environmental change

Earth’s biodiversity and carbon uptake by plants, or primary productivity, are intricately interlinked, underlie many essential ecosystem processes, and depend on the interplay among environmental factors, many of which are being changed by human activities. While ecological theory generalizes across taxa and environments, most empirical tests of factors controlling diversity and productivity have been observational, single-site experiments, or meta-analyses, limiting our understanding of variation among site-level responses and tests of general mechanisms. A synthesis of results from ten years of a globally distributed, coordinated experiment, the Nutrient Network (NutNet), demonstrates that species diversity promotes ecosystem productivity and stability, and that nutrient supply and herbivory control diversity via changes in composition, including invasions of non-native species and extinction of native species. Distributed experimental networks are a powerful tool for tests and integration of multiple theories and for generating multivariate predictions about the effects of global changes on future ecosystems.

Nature Ecology & Evolution↗