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Compilation of Mineral Resource Data for Mississippi Valley-Type and Clastic-Dominated Sediment-Hosted Lead-Zinc Deposits

This report contains a global compilation of the mineral resource data for sediment-hosted lead-zinc (SH Pb-Zn) deposits. Sediment-hosted lead-zinc deposits are historically the most significant sources of lead and zinc, and are mined throughout the world. The most important SH Pb-Zn deposits are hosted in clastic-dominated sedimentary rock sequences (CD Pb-Zn) that are traditionally called sedimentary exhalative (SEDEX) deposits, and those in carbonate-dominated sequences that are known as Mississippi Valley-type (MVT) Pb-Zn deposits. In this report, we do not include sandstone-Pb, sandstone-hosted Pb, or Pb-Zn vein districts such as those in Freiberg, Germany, or Coeur d'Alene, Idaho, because these deposits probably represent different deposit types (Leach and others, 2005). We do not include fracture-controlled deposits in which fluorite is dominant and barite typically abundant (for example, Central Kentucky; Hansonburg, N. Mex.) or the stratabound fluorite-rich, but also lead- and zinc-bearing deposits, such as those in southern Illinois, which are considered a genetic variant of carbonate-hosted Pb-Zn deposits (Leach and Sangster, 1993). This report updates the Pb, Zn, copper (Cu), and silver (Ag) grade and tonnage data in Leach and others (2005), which itself was based on efforts in the Canadian Geological Survey World Minerals Geoscience Database Project (contributions of D.F. Sangster to Sinclair and others, 1999). New geological or geochronological data, classifications of the tectonic environment in which the deposits formed, and key references to the geology of the deposits are presented in our report. Data for 121 CD deposits, 113 MVT deposits, and 6 unclassified deposits that were previously classified as either SEDEX or MVT in the Leach and others (2005) compilation, are given in appendix table A1. In some cases, mineral resource data were available only for total district resources, but not for individual mines within the district. For these districts, the resource data are presented in appendix table A2. In addition, numerous figures (appendix figures B1-B9) displaying important grade-tonnage and geologic features are included. These mineral deposit resource data are important for exploration targeting and mineral resource assessments. There is significant variability in the resource data for these deposit types, and ore controls vary from one region to another. Therefore, grade-tonnage estimations are best evaluated as subsets of the data in appendix table A1 where local mineralization styles and ore controls characterize the region being evaluated for grade-tonnage relations. Furthermore, consideration should also be given to the tendency for MVT resources to occur in large mineralized regions.

Open-File Report↗

Assessment of undiscovered copper resources of the world, 2015

The U.S. Geological Survey completed the first-ever global assessment of undiscovered copper resources for the two most significant sources of global copper supply: porphyry copper deposits and sediment-hosted stratabound copper deposits. The geology-based study identified 236 areas for undiscovered copper in 11 regions of the world. Estimated amounts of undiscovered copper resources are reported at different levels of probability. The results of the assessment indicate that a mean of at least 3,500 million metric tons (Mt) of undiscovered copper associated with these deposit types may exist worldwide, exceeding the 2,100 Mt of identified copper resources tabulated for these deposit types. Porphyry copper deposits contain 1,800 Mt of identified copper resources and are estimated to contain a mean of at least 3,100 Mt of undiscovered copper resources. South America is the dominant source for both identified and undiscovered porphyry copper resources. However, several regions of Asia, including China, have significant potential for undiscovered porphyry copper resources. The amount of mean undiscovered porphyry copper resources that may be economic to extract varies as a function of likely depth to a deposit and quality of local infrastructure that could support mining. Sediment-hosted stratabound copper deposits contain 310 Mt of identified copper resources and are estimated to contain a mean of at least 420 Mt of undiscovered copper resources. The sedimentary basins that may contain significant undiscovered copper resources are the Katanga Basin in central Africa, the Southern Permian Basin of Poland and Germany, the Chu-Sarysu Basin of Kazakhstan, and the Kodar-Udokan area of Russia. Sedimentary basins in the Northwest Botswana Rift in Botswana and Namibia, the Benguela and Cuanza Basins of Angola, and the Cambrian rocks of Egypt, Israel, and Jordan are recognized as having significant potential for undiscovered copper resources in sediment-hosted stratabound copper deposits; however, these areas require additional research, analysis, and evaluation before quantitative resource estimates can be made. The estimate of at least 3,500 Mt of undiscovered copper in two deposit types provides a basis for long-range planning for this important commodity. U.S. copper consumption is 2 Mt per year, world consumption is about 20 Mt per year, and global production from these two deposit types is about 12 Mt per year. Total global copper production from all deposit types from 1879 to 2012 was about 600 Mt. The world’s use of mineral resources, such as copper, will continue to increase in the foreseeable future to support a growing world population and increasing standards of living. The world has sufficient copper to last for decades. However, increases in exploration and growth in mining capacity will be necessary to identify and develop undiscovered resources to supply projected demand.

Scientific Investigations Report↗

USGS Mineral Resources Program; national maps and datasets for research and land planning

The U.S. Geological Survey, the Nation’s leader in producing and maintaining earth science data, serves as an advisor to Congress, the Department of the Interior, and many other Federal and State agencies. Nationwide datasets that are easily available and of high quality are critical for addressing a wide range of land-planning, resource, and environmental issues. Four types of digital databases (geological, geophysical, geochemical, and mineral occurrence) are being compiled and upgraded by the Mineral Resources Program on regional and national scales to meet these needs. Where existing data are incomplete, new data are being collected to ensure national coverage. Maps and analyses produced from these databases provide basic information essential for mineral resource assessments and environmental studies, as well as fundamental information for regional and national land-use studies. Maps and analyses produced from the databases are instrumental to ongoing basic research, such as the identification of mineral deposit origins, determination of regional background values of chemical elements with known environmental impact, and study of the relationships between toxic elements or mining practices to human health. As datasets are completed or revised, the information is made available through a variety of media, including the Internet. Much of the available information is the result of cooperative activities with State and other Federal agencies. The upgraded Mineral Resources Program datasets make geologic, geophysical, geochemical, and mineral occurrence information at the state, regional, and national scales available to members of Congress, State and Federal government agencies, researchers in academia, and the general public. The status of the Mineral Resources Program datasets is outlined below.

Fact Sheet↗

A GIS and statistical approach to identify variables that control water quality in hydrothermally altered and mineralized watersheds, Silverton, Colorado, USA

Hydrothermally altered bedrock in the Silverton mining area, southwest Colorado, USA, contains sulfide minerals that weather to produce acidic and metal-rich leachate that is toxic to aquatic life. This study utilized a geographic information system (GIS) and statistical approach to identify watershed-scale geologic variables in the Silverton area that influence water quality. GIS analysis of mineral maps produced using remote sensing datasets including Landsat Thematic Mapper, advanced spaceborne thermal emission and reflection radiometer, and a hybrid airborne visible infrared imaging spectrometer and field-based product enabled areas of alteration to be quantified. Correlations between water quality signatures determined at watershed outlets, and alteration types intersecting both total watershed areas and GIS-buffered areas along streams were tested using linear regression analysis. Despite remote sensing datasets having varying watershed area coverage due to vegetation cover and differing mineral mapping capabilities, each dataset was useful for delineating acid-generating bedrock. Areas of quartz–sericite–pyrite mapped by AVIRIS have the highest correlations with acidic surface water and elevated iron and aluminum concentrations. Alkalinity was only correlated with area of acid neutralizing, propylitically altered bedrock containing calcite and chlorite mapped by AVIRIS. Total watershed area of acid-generating bedrock is more significantly correlated with acidic and metal-rich surface water when compared with acid-generating bedrock intersected by GIS-buffered areas along streams. This methodology could be useful in assessing the possible effects that alteration type area has in either generating or neutralizing acidity in unmined watersheds and in areas where new mining is planned.

Colorado↗

U. S. Geological Survey programs in Pennsylvania

The U.S. Geological Survey (USGS) is involved in mapping and studying land, mineral, biological, and water resources and determining the risk from earthquakes and other natural hazards, which are of importance to the citizens of Pennsylvania. This Fact Sheet describes how the USGS is addressing some of the major environmental issues in Pennsylvania, which include availability of mineral resources; contamination of the environment by hazardous wastes; effects of coal mining, oil and gas production, and agriculture on the environment; nutrient input to streams and estuaries; and adequacy of good-quality water supplies. Information on acquiring the thousands of map, book, and aerial photographic products of the USGS also is given.

Fact Sheet↗

Questa baseline and premining ground-water quality investigation 18. Characterization of brittle structures in the Questa Caldera and their potential influence on bedrock ground-water flow, Red River Valley, New Mexico

This report presents a field-based characterization of fractured and faulted crystalline bedrock in the southern portion of the Questa caldera and its margin. The focus is (1) the identification and description of brittle geological structures and (2) speculation on the potential effects and controls that these structures might have on the potential fluxes of paleo to present-day ground water in relation to natural or mining-related metal and acid loads to surface and ground water. The entire study area is pervasively jointed with a few distinctive patterns such as orthogonal, oblique orthogonal, and conjugate joint sets. Joint intensity, the number of joints measured per unit line length, is high to extreme. Three types of fault zones are present that include partially silicified, low- and high-angle faults with well-developed damage zones and clay-rich cores and high-angle, unsilicified open faults. Conceptually, the joint networks can be thought of as providing the background porosity and permeability structure of the bedrock aquifer system. This background is cut by discrete entities such as the faults with clay-rich cores and open faults that may act as important hydrologic heterogeneities. The southern caldera margin runs parallel to the course of the Red River Valley, whose incision has left an extreme topographic gradient at high angles to the river. Many of the faults and fault intersections run parallel to this assumed hydraulic gradient; thus, these structures have great potential to provide paleo and present-day, discrete and anisotropic pathways for solute transport within the otherwise relatively low porosity and permeability bedrock background aquifer system. Although brittle fracture networks and faults are pervasive and complex, simple Darcy calculations are used to estimate the hydraulic conductivity and potential ground-water discharges of the bedrock aquifer, caldera margin, and other faults in order to gain insight into the potential contributions of these features to the ground-water and surface-water flow systems. These calculations show that, because all of these features are found along the Red River in the Cabin Springs-Columbine Park-Goat Hill fan area, their combined effect increases the probability that the bedrock aquifer ground-water flow system provides discharge to the Red River along this reach.

New Mexico↗

Flooding and sedimentation in Wheeling Creek basin, Belmont County, Ohio

The Wheeling Creek basin, which is located primarily in Belmont County, Ohio, experienced three damaging floods and four less severe floods during the 29-month period from February 1979 through June 1981. Residents of the basin became concerned about factors that could have affected the severity and frequency of out-of-bank floods. In response to those concerns, the U.S. Geological Survey, in cooperation with the Ohio Department of Natural Resources, undertook a study to estimate peak discharges and recurrence intervals for the seven floods of interest, provide information on current and historical mining-related stream-channel fill or scour, and examine storm-period subbasin contributions to the sediment load in Wheeling Creek. Streamflow data for adjacent basins, rainfall data, and, in two cases, flood-profile data were used in conjunction with streamflow data subsequently collected on Wheeling Creek to provide estimates of peak discharge for the seven floods that occurred from February 1979 through June 1981. Estimates of recurrence intervals were assigned to the Peak discharges on the basin of regional regression equations that relate selected basin characteristics to peak discharge with fixed recurrence intervals. These estimates indicate that a statistically unusual number of floods with recurrence intervals of 2 years or more occurred within that time period. Three cross sections located on Wheeling Creek and four located on tributaries were established and surveyed quarterly for approximately 2 years. No evidence of appreciable stream-channel fill or scour was observed at any of the cross sections, although minor profile changes were apparent at some locations. Attempts were made to obtain historical cross-section profile data for comparison with current cross-section profiles; however, no usable data were found. Excavations of stream-bottom materials were made near the three main-stem cross-section locations and near the mouth of Jug Run. The bottom materials were examined for evidence of recently deposited sediments of mining-related origin. The only evidence of appreciable mining-related sediment deposition was found at Jug Run, and, to a lesser extent, at one main-stem site.

Water-Resources Investigations Report↗

Application of the precipitation-runoff model in the Warrior coal field, Alabama

A deterministic precipitation-runoff model, the Precipitation-Runoff Modeling System, was applied in two small basins located in the Warrior coal field, Alabama. Each basin has distinct geologic, hydrologic, and land-use characteristics. Bear Creek basin (15.03 square miles) is undisturbed, is underlain almost entirely by consolidated coal-bearing rocks of Pennsylvanian age (Pottsville Formation), and is drained by an intermittent stream. Turkey Creek basin (6.08 square miles) contains a surface coal mine and is underlain by both the Pottsville Formation and unconsolidated clay, sand, and gravel deposits of Cretaceous age (Coker Formation). Aquifers in the Coker Formation sustain flow through extended rainless periods. Preliminary daily and storm calibrations were developed for each basin. Initial parameter and variable values were determined according to techniques recommended in the user's manual for the modeling system and through field reconnaissance. Parameters with meaningful sensitivity were identified and adjusted to match hydrograph shapes and to compute realistic water year budgets. When the developed calibrations were applied to data exclusive of the calibration period as a verification exercise, results were comparable to those for the calibration period. The model calibrations included preliminary parameter values for the various categories of geology and land use in each basin. The parameter values for areas underlain by the Pottsville Formation in the Bear Creek basin were transferred directly to similar areas in the Turkey Creek basin, and these parameter values were held constant throughout the model calibration. Parameter values for all geologic and land-use categories addressed in the two calibrations can probably be used in ungaged basins where similar conditions exist. The parameter transfer worked well, as a good calibration was obtained for Turkey Creek basin.

Water Supply Paper↗

Geochemical, aeromagnetic, and generalized geologic maps showing distribution and abundance of lead and silver, Golconda and Iron Point quadrangles, Humboldt County, Nevada

Detailed geologic and geochemical studies of the four 7 1/2-minute quadrangles that make up the Edna Mountain 15-minute quadrangle in Humboldt County, Nevada, were begun during the 1969 summer field season. The objectives of the project are to map the geology of this struct urally complex area at 1:24·,000 scale and to determine the regional distribution and abundance of metals in rocks of the are\3. and the factors that control the distribution and abundance of those metals. Tungstenbearing hot-spring tufa, metalliferous black shale in Ordovician rocks, base-metal and barite deposits in Paleozoic sedimentary rocks, and copper-molybdenum in granodiorite plutons of Cretaceous age occur in the Edna Mountain area. None of these deposits have been of much economic significance, although tungsten was mined from the hot-spring deposits during World War II. The numerous occurrences of mineralized ground, however, along with the broad spectrum of types of mineralization, intensity of alteration, structural complexity, and abundance of intermediate to silicic igneous intrusive rocks suggest that concealed or heretofore unrecognized mineral deposits may exist in the area. Integrated geologic, geochemical, and geophysical studies on a district- wide scale might improve our un~erstanding of the factors that control the distribution, methods of emplacement, and spatial and genetic relationships (if any) of these different types of deposits. We hope that broad target areas or guidelines for mineral exploration in th.is area may be identified. This series of maps shows the distribu t ion and abundance of mercury, arsenic, antimony, tungsten, gold, copper, l ead, and s ilver related to a geologic and aeromagnetic base in the Golconda and Iron Point 7 1/2-minute quadrangles. All samples are rock samples; most are f rom shear or f ault zones, fractures, jasperoid, breccia reefs, and altered rocks . All the samples were prepared and analyzed in truck-mounted laboratories at Wi nnemucca, Nevada. Arsenic , tungs t en, copper, lead, and si lver were determined by semiquantitative spectrogr aph i c methods by D. F. Siems and E. F. Cooley . Mercury and gold were determined by atomi c absorption methods and antimony was determined by a colorimetric method by R. M. O'Leary, M. S. Erickson, and others.

Nevada↗

United States Geological Survey, programs in Nevada

The U.S. Geological Survey (USGS) has been collecting and interpreting natural-resources data in Nevada for more than 100 years. This long-term commitment enables planners to manage better the resources of a State noted for paradoxes. Although Nevada is one of the most sparsely populated States in the Nation, it has the fastest growing population (fig. 1). Although 90 percent of the land is rural, it is the fourth most urban State. Nevada is the most arid State and relies heavily on water resources. Historically, mining and agriculture have formed the basis of the economy; now tourism and urban development also have become important. The USGS works with more than 40 local, State, and other Federal agencies in Nevada to provide natural-resources information for immediate and long-term decisions. Subjects included in this fact sheet: Low-Level Radioactive-Waste Disposal Mining and Water in the Humboldt Basin Aquifer Systems in the Great Basin Water Allocation in Truckee and Carson Basins National Water-Quality Assessment Program Minerals Assessment for Land Management Irrigation Drainage Ground-Water Movement at Nevada Test Site Oil and Gas Resources National Mapping Program Digital Mapping and Aerial Photography Collection of Hydrologlc Data Geologic Mapping Earthquake Hazards Assessing Mineral Resources of the Subsurface Earth Observation Data Cooperative Programs

Nevada↗

Solid-phase data from cores at the proposed Dewey Burdock uranium in-situ recovery mine, near Edgemont, South Dakota

This report releases solid-phase data from cores at the proposed Dewey Burdock uranium in-situ recovery site near Edgemont, South Dakota. These cores were collected by Powertech Uranium Corporation, and material not used for their analyses were given to the U.S. Geological Survey for additional sampling and analyses. These additional analyses included total carbon and sulfur, whole rock acid digestion for major and trace elements, 234 U/ 238 U activity ratios, X-ray diffraction, thin sections, scanning electron microscopy analyses, and cathodoluminescence. This report provides the methods and data results from these analyses along with a short summary of observations.

South Dakota↗

Abandoned mine drainage in the Swatara Creek Basin, southern anthracite coalfield, Pennsylvania, USA: 2. performance of treatment systems

A variety of passive and semi-passive treatment systems were constructed by state and local agencies to neutralize acidic mine drainage (AMD) and reduce the transport of dissolved metals in the upper Swatara Creek Basin in the Southern Anthracite Coalfield in eastern Pennsylvania. To evaluate the effectiveness of selected treatment systems installed during 1995–2001, the US Geological Survey collected water-quality data at upstream and downstream locations relative to each system eight or more times annually for a minimum of 3 years at each site during 1996–2007. Performance was normalized among treatment types by dividing the acid load removed by the size of the treatment system. For the limestone sand, open limestone channel, oxic limestone drain, anoxic limestone drain (ALD), and limestone diversion well treatment systems, the size was indicated by the total mass of limestone; for the aerobic wetland systems, the size was indicated by the total surface area of ponds and wetlands. Additionally, the approximate cost per tonne of acid treated over an assumed service life of 20 years was computed. On the basis of these performance metrics, the limestone sand, ALD, oxic limestone drain, and limestone diversion wells had similar ranges of acid-removal efficiency and cost efficiency. However, the open limestone channel had lower removal efficiency and higher cost per ton of acid treated. The wetlands effectively attenuated metals transport but were relatively expensive considering metrics that evaluated acid removal and cost efficiency. Although the water-quality data indicated that all treatments reduced the acidity load from AMD, the ALD was most effective at producing near-neutral pH and attenuating acidity and dissolved metals. The diversion wells were effective at removing acidity and increasing pH of downstream water and exhibited unique potential to treat moderate to high flows associated with storm flow conditions.

Pennsylvania↗

Development of the Wink Sink in west Texas, U.S.A., due to salt dissolution and collapse

The Wink Sink, in Winkler County, Texas, is a collapse feature that formed in June 1980 when an underground dissolution cavity migrated upward by successive roof failures until it breached the land surface. The original cavity developed in the Permian Salado Formation salt beds more than 400 m (1,300 ft) below ground level. Natural dissolution of salt occurred in the vicinity of the Wink Sink in several episodes that began as early as Salado time and recurred in later Permian, Triassic, and Cenozoic times. Although natural dissolution occurred in the past below the Wink Sink, it appears likely that the dissolution cavity and resultant collapse described in this report were influenced by petroleum-production activity in the immediate area. Drilling, completion, and plugging procedures used on an abandoned oil well at the site of the sink appear to have created a conduit that enabled water to circulate down the borehole and dissolve the salt. When the dissolution cavity became large enough, the roof failed and the overlying rocks collapsed into the cavity. Similar collapse features exist where underground salt beds have been intentionally dissolved during solution mining or accidentally dissolved as a result of petroleum-production activity. ?? 1989 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences↗

Reactive solute-transport simulation of pre-mining metal concentrations in mine-impacted catchments: Redwell Basin, Colorado, USA

With the increased importance of water resources in the western United States and many areas worldwide, the remediation of impacts from historical mining becomes ever more important. A possible process of making decisions about remediation for a catchment might include identification of principal sources of metals in the catchment, classification of the sources as natural or anthropogenic, and simulations to evaluate different options for removal of anthropogenic sources. The application of this process is based on understanding the pre-mining conditions in the catchment, so that remediation goals appropriately correct for the impacts of mining. A field experiment in Redwell Basin, Colorado, provided a setting to demonstrate this process and to evaluate pre-mining concentrations through reactive solute-transport modeling. The field experiment provided spatially detailed stream and inflow samples that were the basis for model calibration. Only two inflows along the study reach were affected by mining or mine exploration. To simulate pre-mining conditions, these inflows were removed from the model calibration; the result was a simulation of the stream with all the non-mining inputs. At a point downstream from the two mining inflows, the simulated pre-mining pH would have been 5.1, up from the measured 3.8. At the higher pH, the streambed likely would have been coated with Al precipitate. Simulated pre-mining Zn and Cu would have been 1300 µg/L and 18 µg/L, lower than the measured concentrations of 3340 and 93 µg/L. Despite these changes, the pre-mining conditions would not have met aquatic-life standards.

Colorado↗

Minor epigenetic, diagenetic, and syngenetic sulfide, fluorite, and barite occurrences in the central United States

Metallic sulfides, fluorite , barite , and celestite are widespread in the sedimentary rocks of the central United States . Many occurrences are epigenetic concentrations either in known major mineral districts or in clusters of deposits that warrant further exploration for potential ore. Evaluation of trace-element composition, of fluid inclusions, of depositional temperature, and of isotopic composition of sulfur may help discriminate potentially economic deposits from even more widespread, probably noneconomic, syngeneic occurrences . Known major mineral districts and many promising sulfide occurrences are located along complex major fault systems and particularly over structural domes at intersections of fault systems. Economically promising sulfide deposits occur along a west-trending fault system crossing Kentucky and Missouri near the 38th parallel, particularly at associated cryptoexplosion structures along it, at the intersection of the fault system with the Cincinnati arch. Elsewhere in the central United States , promising sulfide occurrences are located along the crest of the Findlay arch, near Serpent Mound, Ohio, along the northwest-trending Mount Carmel fault in southwestern Indiana, and buried at depth in oil fields of west- central Kansas.Other types of deposits that are productive or may have some future economic interest are locally economic and possibly syngenetic red-bed copper occurrences in Oklahoma, Texas, Kansas, and Pennsylvania. Most widespread are the black shale and pyritic sandstone beds, some of which have been a source of pyrite for sulfur and sulfuric acid in conjunction with coal mining. Bedded barite deposits of possibly diagenetic origin have been mined in Arkansas. Diagenetic siderite concretions containing sulfides and barite were widespread sources of iron in the 19th century.

Economic Geology↗

Tin, copper, and uranium at Majuba Hill, Nevada

Uranium minerals occur with ores of copper, tin, and silver at Majuba Hill, Nevada. During World War I, the Majuba Hill mine produced about 4,000 tons of 12 percent copper ore, and during World War II about 23,000 tons of ore containing 2 to 4 percent copper and enough tin ore to furnish from 10 to 15 tons of metallic tin. No uranium has been produced. The bedrock geology of Majuba Hill consists of a complex; volcanic neck or plug composed of rhyolite porphyry, porphyritic rhyolite, quartz feldspar porphyry, breccia dikes, and irregular breccia masses. This plug intruded Triassic (?) sedimentary rocks, chiefly shale. The principal loci of ore deposition were (l) parts of the breccia bodies, particularly where they were porous and where they were silicified and tourmalinized, and (2) a few small pre-mineral fractures adjacent to the breccia masses, Intense hydrothermal alteration resulted in the formation of sericite, quartz, and tourmaline in the wall rocks. This was accompanied or followed by deposition of arsenopyrite, pyrite, cassiterite, fluorite, and several primary sulfide minerals of copper. All of the ore bodies exposed in the mine are highly oxidized, and a profusion of secondary minerals of copper and iron have been found. The only uranium minerals detected are the phosphates torbernite and matatorbernite and the arsenate zeunerite. These are widely disseminated throughout the mine in small amounts associated with the secondary minerals of copper and iron along minor fault surfaces, bedding planes in the shale, and in porous parts of the breccia. A primary uranium mineral has not been found. The secondary uranium minerals appear to be most abundant where copper ore is highest grade. Although unoxidized uranium ore has not been found, it is inferred from this relation that the deposition of the original uranium minerals favored those areas where primary copper mineralization was most intense. There may have been an intimate association of uranium with silver in the ore, but this has not been established. The U 3 O 8 content of samples of copper ore ranges from .0.002 to 0.30 percent. Because the bottom of the oxidized ore has not been reached in mining or exploration, the downward extensions of the known ore bodies of secondary minerals would appear to be worthy of investigation to determine the grade and extent of the primary ore.

Nevada↗

Mercury in the Walker River Basin, Nevada and California: Sources, distribution, and potential effects on the ecosystem

Mercury is one of the most serious contaminants of water, sediment, and biota in Nevada because of its use during 19th century mining activities to recover gold and silver from ores. In 1998, mercury problems were discovered in the Walker River Basin of California and Nevada when blood drawn from three common loons from Walker Lake was analyzed and found to have severely elevated mercury levels. From 1999 to 2001, the U.S. Geological Survey and the U.S. Fish and Wildlife Service collected water, sediment, and biological samples to determine mercury sources, distribution, and potential effects on the Walker River Basin ecosystem. Total-mercury concentrations ranged from 0.62 to 57.11 ng/L in streams from the Walker River system and ranged from 1.02 to 26.8 ng/L in lakes and reservoirs. Total-mercury concentrations in streambed sediment ranged from 1 to 13,600 ng/g, and methylmercury concentrations ranged from 0.07 to 32.1 ng/g. The sediment-effects threshold for mercury for fresh-water invertebrates is 200 ng/g, which was exceeded at nine stream sites in the Walker River Basin. The highest mercury concentrations were in streams with historic mines and milling operations in the watershed. The highest mercury concentration in sediment, 13,600 ng/g, was found in Bodie Creek near Bodie, Calif., a site of extensive gold mining and milling activities during the 19th century. Sediment cores taken from Walker Lake show total-mercury concentrations exceeding 1,000 ng/g at depths greater than 15 cm below lake bottom. The presence of 137Cs above 8 cm in one core indicates that the upper 8 cm was deposited sometime after 1963. The mercury peak at 46 cm in that core, 2,660 ng/g, likely represents the peak of mining and gold extraction in the Bodie and Aurora mining districts between 1870 and 1880. Mercury concentrations in aquatic invertebrates at all sites downstream from mining activities in the Rough Creek watershed, which drains the Bodie and Aurora mining districts, were elevated (range 0.263 to 0.863 ?g/g, dry weight). Mercury concentrations in the Walker Lake tui chub, the most abundant and likely prey for common loons, ranged from approximately 0.09 ?g/g to approximately 0.9 ?g/g (wet weight). Larger tui chub in the lake, which are most likely older, had the highest mercury concentrations. Blood samples from 94 common loons collected at Walker Lake between 1998 and 2001 contained a mean mercury concentration of 2.96 ?g/g (standard deviation 1.72 ?g/g). These levels were substantially higher than those found in more than 1,600 common loons tested across North America. Among the 1,600 common loons, the greatest blood mercury concentration, 9.46 ?g/g, was from a loon at Walker Lake. According to risk assessments for northeastern North America, blood mercury concentrations exceeding 3.0 ?g/g cause behavioral, reproductive, and physiological effects. At least 52 percent of the loons at Walker Lake are at risk for adverse effects from mercury on the basis of their blood-mercury concentrations. The larger loons staging in the spring are the most at risk group. The elevated mercury levels found in tui chub and common loons indicate that there is a potential threat to the well being and reproduction of fish and wildlife that use Walker Lake. Wildlife that use Weber Reservoir may also be at risk because it is the first reservoir downstream from mining activities in the Bodie and Aurora areas and mercury concentrations in sediment were elevated. Additional data on mercury concentrations in top level predators, such as piscivorous fish and birds, are needed to assess public health and other environmental risks.

California, Nevada↗

Geochemical data for core and bottom-sediment samples collected in 2007 from Grand Lake O' the Cherokees, northeast Oklahoma

Grand Lake O' the Cherokees is a large reservoir in northeast Oklahoma, below the confluence of the Neosho and Spring Rivers, both of which drain the Tri-State Mining District to the north. The Tri-State district covers an area of 1,200 mi 2 (3,100 km 2 ) and comprises Mississippi Valley-type lead-zinc deposits. A result of 120 years of mining activity is an estimated 75 million tons of processed mine tailings (chat) remaining in the district. Concerns of sediment quality and the possibility of human exposure to cadmium and lead through eating fish have led to several studies of the sediments in the Tri-State district. In order to record the transport and deposition of metals from the Tri-State district by the Spring and Neosho Rivers into Grand Lake O' the Cherokees, the U.S. Geological Survey collected 11 sediment cores and 15 bottom-sediment samples in September 2007. Subsamples from five selected cores and the bottom-sediment samples were analyzed for major and trace elements and forms of carbon. The sediment samples collected from the sediment-water interface had larger average concentrations of zinc, cadmium, and lead than local background. The core collected from the Spring River had the largest concentrations of mining-related elements. A core collected just south of Twin Bridges State Park, at the confluence of the Spring and Neosho Rivers, showed a mixing zone with more mining-related elements coming from the Spring River side. The element zinc showed the most definitive patterns in graphs depicting concentration-versus-depth profiles. A core collected from the main body of the reservoir showed affected sediment down to a depth of 85 cm (33 in). This core and two others appear to have penetrated to below mining-affected sediment.

Open-File Report↗