USGS Science⌕ Search

SEARCH · USGS Science

Results for “Chemical Geology”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,423 records · Page 79Linked to original sources
USGS2009

The Effects of Urbanization and Other Environmental Gradients on Algal Assemblages in Nine Metropolitan Areas across the United States

The U.S. Geological Survey conducted studies from 2000 to 2004 to determine the effects of urbanization on stream ecosystems in nine major metropolitan study areas across the United States. Biological, chemical, and physical components of streams were assessed at 28 to 30 sites in each study area. Benthic algae were sampled to compare the degree to which algal assemblages correlated to urbanization, as characterized by an urban intensity index (UII), relative to other environmental gradients that function at either the watershed or reach scales. Ordination site scores were derived from principal components analyses of the environmental data to define environmental gradients at two spatial scales: (1) watershed-scale gradients that summarized (a) landscape modifications and (b) socioeconomic factors, and (2) reach-scale gradients that characterized (a) physical habitat and (b) water chemistry. Algal response was initially quantified by site scores derived from nonmetric multi-dimensional scaling ordinations of the algal assemblage data. The site scores were then correlated with a set of algal metrics of structure and function to help select specific indicators that would best represent changes in the algal assemblages and would infer ecological condition. The selected metrics were correlated to the UII and other environmental gradients. The results indicated that diatom-taxa in the assemblages were distinctly different across the nine study areas, likely due to physiographic differences across the country, but nevertheless, some algal metrics were applicable to all areas. Overall, the study results indicated that although the UII represented various landscape changes associated with urbanization across the country, the algal response was more strongly related to more specific factors generally associated with water quality measured within the stream reach.

Scientific Investigations Report↗
USGS2020

Discharge and dissolved-solids characteristics and trends of Snake River above Jackson Lake at Flagg Ranch, Wyoming, 1986–2018

The headwaters of the Snake River are in the mountains of northwestern Wyoming. Maintaining the recognized high quality of water in Grand Teton National Park is a National Park Service (NPS) priority. To characterize and understand the water resources of Grand Teton National Park, the NPS established a monitoring program to monitor the quality of area surface waters. Beginning in 2006, water was sampled by the NPS and analyzed for a range of chemical species at the Snake River above Jackson Lake at Flagg Ranch streamgage 13010065 (hereafter referred to as “Snake River at Flagg Ranch”), a site where the U.S. Geological Survey (USGS) previously sampled and analyzed water from 1986 through 2004. The USGS, in cooperation with the NPS, evaluated water-quality data collected by both entities to determine if discharge and total dissolved solids (referred to as dissolved solids) have changed in the Snake River at the Flagg Ranch. To understand potential changes with time in dissolved solids, discharge was analyzed between January 1986 and December 2018, which corresponds with the time period when water-quality data were collected. Mean annual discharge varied during this time, with high, low, mean, and median flows generally increasing from 1986 through 1998, decreasing through 2005, and then generally increasing through 2018. Combining water-quality data collected by the USGS and NPS provides a longer, more complete dataset for analyses. During the period of time when NPS was the sampling agency, specific conductance data were collected, but dissolved-solids data were not. The specific conductance data from both agencies were evaluated to determine if combining the data was justified. The interquartile ranges of data collected by both agencies are similar, and rapid, large changes in values during the period of transition between USGS and NPS sampling do not occur. The USGS and NPS datasets are not statistically different in the spring, summer, or fall, but are statistically different in the winter. The winter differences could be a function of the lack of wintertime NPS sampling, which excludes higher-concentration, lower-discharge data or a function of changes in the actual concentration in the stream. Although there is some difference in the winter datasets, the similarity in sampling methods and general overall data characteristics justifies combining the data for trend analyses. Because the dissolved-solids parameter is useful for managers, it is often calculated from specific conductance using a linear regression model when dissolved-solids data are absent. For this study, creating a modeled dataset of dissolved solids for the NPS data collection period of time provided a longer, more complete dataset of dissolved-solids concentrations. The concentrations of dissolved solids over time are identified by season and indicate that samples collected in the fall and winter have higher concentrations than samples collected in spring and summer. Specifically, the mean dissolved-solids concentrations in fall and winter are around 188 milligrams per liter (mg/L), whereas the mean concentrations are around 130 mg/L in spring and summer. This difference is generally attributed to the dilution of spring and summer samples by snowmelt generated runoff during the high-flow period of the year. Trend analyses of dissolved-solids concentrations and loads indicate that an upward trend in concentration from 1986 to 2018 is likely, and a downward trend in load is highly likely. Comparing 1986 to 2018, dissolved-solids concentration is estimated to have increased by 2.25 mg/L (1.4 percent). During that same period, the dissolved-solids load is estimated to have decreased 11.8 million kilograms per year (12-percent decrease). This decrease is consistent with the estimated decrease in annual mean of daily mean discharge. Because 10 percent of the total change in dissolved-solids load is related to a change in the concentration-discharge relationship and 2 percent is related to changes in discharge, the decreased load is related less to changes in discharge and more to landscape scale processes that are affecting the concentration-discharge relationship. As noted above, the data collected by the USGS and NPS are generally comparable with regards to sampling and analytical methods, and data collected by both agencies were used as one dataset for trend analyses. The current NPS sampling schedule, however, is creating a dataset biased towards lower concentration dissolved-solids data, which occurs during higher summer flows, by only sampling during April through November. From 1986 to 2018, the percentage of NPS samples is small enough that the effect on trends is expected to be minimal. Because of the importance of low flow (winter season) data, it is likely that an April through November sampling regime may affect the ability to detect trends or determine seasonality in the future. Collection of winter data in particular is important based on the findings that the changes in the modeled concentration-discharge relationship over time have been most pronounced during the winter (represented by February) months.

Wyoming↗
USGS1952

Present and past ground-water conditions in the Morrison Formation in southwestern Colorado and southeastern Utah

Field and laboratory studies of ground-water conditions in the carnotite-bearing Morrison formation in southwestern Colorado and southeastern Utah were undertaken to determine possible relations between ground waters and the carnotite deposits. The ore-bearing sandstone consists of lenticular sandstone strata, interbedded within discontinuous layers of mudstone; these strata were deposited in a stream environment. The porosity and permeability of the ore-bearing sandstone in one area are relatively low, porosity averaging about 15 percent and permeability ranging between 30 and 3300 millidarcys. Permeability studies in this same area show that sandstone classed as favorable for ore is slightly more permeable than and has nearly twice the transmissibility of sandstone classed as semifavorable; outcrop studies also suggest a lower transmissibility for sandstone that is unfavorable. Samples of water from the ore-bearing and associated strata show considerable variation in chemical charter. These water samples are generally low in uranium, vanadium, copper, and lead, most samples containing less than 1 part per million (ppm) of each metal. General geologic relations suggest that ground-water movement probably was active through the ore-bearing strata during their deposition and shortly afterward. Movement during this time probably occurred largely through the more permeable sand strata and in the general direction of initial dip and stream flow. During Cretaceous time, when several thousand feet of marine sediments accumulated over the Morrison, the water contained in the ore-bearing strata probably was immobile or nearly so and was protected from escape or contamination. Following Tertiary deformation and erosion, active ground-water circulation no doubt was restored, but because of the low permeability and the lenticular character and therefore low transmissibility of the ore-bearing sandstone, ground-water movement probably was slow. Faulting probably also influenced the direction and rate of ground-water movement during Tertiary time. Movement and localization of ground water would permit the concentration of metal-bearing solutions during Salt Wash and early Brushy Basin time in the beds that now contain ore deposits. It is more difficult to explain the formation of these deposits, which have a wide geographic distribution at a restricted stratigraphic position, from solutions circulating through the rocks at a later date. Whatever mode of origin is used to explain the deposits, geologists almost without exception, agree that the metals were transported by solutions that have migrated through the sediments for considerable distances. For this reason, a study of the horizontal and vertical transmissibility characteristics of all exposed sedimentary formations on the Colorado Plateau is planned.

Colorado, Utah↗
USGS1956

The determination of uranium (IV) in apatite

Geologic and mineralogic evidence indicate that the uranium present in apatite may proxy for calcium in the mineral structure as U(IV). An experimental investigation was conducted and chemical evidence was obtained that establishes the presence of U(IV) in apatite. The following analytical procedure was developed for the determination of U(IV). Carbonate-fluorapatite is dissolved in cold 1.5M orthophosphoric acid and fluorapatite is dissolved in cold 1.2M hydrochloric acid containing 1.5 g of hydroxylamine hydrochloride per 100 ml. Uranium (IV) is precipitated by cupferron using titanium as a carrier. The uranium in the precipitate is separated by use of the ethyl acetate extraction procedure and determined fluorimetrically. The validity and the limitations of the method have been established by spike experiments.

Trace Elements Investigations↗
USGS1984

Water resources of Ponape, Caroline Islands

Ponape is the third largest island in the western Pacific, with a land area of 129 square miles. The island is volcanic, nearly circular in shape, and covered with lush tropical vegetation. The mountainous interior has the highest peaks in the western Pacific. Annual rainfall at Kolonia and other coastal areas is 191 inches. Inland at higher elevations, the rainfall is considerably higher. The upper Nanpil River basin averages about 340 inches annually. Runoff-to-rainfall ratios for Ponapean streams show that about two thirds of the rain falling on the island runs off. Flow-duration curves show the similarity of the geology, vegetation, and rainfall of the drainage basins and indicate little ground-water contribution to surface runoff. Surface-water quality is excellent as shown by 53 chemical anlyses of water from 19 streams. Water of the Nanpil River, the source of water for the central water system, is especially low in dissolved elements and solids. This report summarizes in one volume all the hydrologic data collected and provides analyses that may be used by planning and public works officials as a basis for making decisions on the development and management of their water resources. (USGS)

Water-Resources Investigations Report↗
USGS1989

Modification of a method-of-characteristics solute-transport model to incorporate decay and equilibrium-controlled sorption or ion exchange

The U.S. Geological Survey computer model of two-dimensional solute transport and dispersion in ground water (Konikow and Bredehoeft, 1978) has been modified to incorporate the following types of chemical reactions: (1) first-order irreversible rate-reaction, such as radioactive decay; (2) reversible equilibrium-controlled sorption with linear, Freundlich, or Langmuir isotherms; and (3) reversible equilibrium-controlled ion exchange for monovalent or divalent ions. Numerical procedures are developed to incorporate these processes in the general solution scheme that uses method-of- characteristics with particle tracking for advection and finite-difference methods for dispersion. The first type of reaction is accounted for by an exponential decay term applied directly to the particle concentration. The second and third types of reactions are incorporated through a retardation factor, which is a function of concentration for nonlinear cases. The model is evaluated and verified by comparison with analytical solutions for linear sorption and decay, and by comparison with other numerical solutions for nonlinear sorption and ion exchange.

Water-Resources Investigations Report↗
USGS1966

Hydrology of the Upper Capibaribe Basin, Pernambuco, Brazil - A reconnaissance in an Area of Crystalline Rocks

The upper Capibaribe basin is the western three-fourths, approximately, of the valley of the river that empties into the Atlantic Ocean at Recife, the capital of the State of Pernambuco, Brazil. It is the part of the drainage basin that is within the Drought Polygon of northeast Brazil, and it totals about 5,400 square kilometers. It receives relatively abundant precipitation in terms of the annual average, yet is regarded as hot subhumid to semiarid because the precipitation is uneven from year to year and place to place. The dependable water supply, therefore, is small. The basin has water, which could be put to better use than at present, but the opportunities for augmenting the usable supply are not great. The streams are intermittent and therefore cannot be expected to fill surface reservoirs and to keep them filled. The ground-water reservoirs have small capacity--quickly filled and quickly drained. A rough estimate based on the records for 1964 suggests that, of 4,700 million cubic meters of precipitation in the upper Capibaribe basin, 2,700 million cubic meters (57 percent) left the basin as runoff and 2,000 million cubic meters {43 percent) went into underground storage or was evaporated or transpired. The bedrock of the upper Capibaribe basin is composed of granite, gneiss, schist, and other varieties of crystalline rocks, which have only insignificant primary permeability. They are permeable mainly where fractured. The principal fracture zones, fortunately, are in the valleys, where water accumulates and can feed into them, but the volume of fractured rock is small in relation to the basin as a whole. A well in a large water-filled fracture zone may yield up to 20,000 liters per hour, but the average well yields less than one-fourth this amount, and some wells yield none. The saprolite, or weathered rock, is many meters thick at some places especially in the eastern half of the upper Capibaribe basin. It contains water locally, but ordinarily will yield only small quantities to wells. The alluvium probably is the most productive aquifer in the basin, but is limited to narrow bands along the rivers that generally are no more than a few hundred meters wide and 5 meters thick. The alluvium contains variable amounts of silty sand capable of yielding small to moderate quantities of water to wells. Wells driven or dug into the alluvium could solve many small water problems. The chemical quality of the water in the upper Capibaribe basin ranges from good to bad and generally presents a major problem that cannot be solved solely by applying geological criteria. Mineralized water is widespread in the area, both in streams and underground, and .the choice of aquifers is small. All known aquifers contain, at one place or another, water that is mineralized, leaving no alternative for a natural supply of good-quality water. Although much of the available water is unsatisfactory for human consumption, it is generally acceptable for animals and therefore meets one of the principal water needs. Some of the ground water could be made potable by diluting it with rainwater, which could be collected during rainy seasons and temporarily stored in cisterns or reservoirs.

Water Supply Paper↗
USGS1988

Estimation of urban stormwater quality

Two data-based methods for estimating urban stormwater quality have recently been made available - a planning level method developed by the U.S. Environmental Protection Agency (EPA), and a nationwide regression method developed by the U.S. Geological Survey. Each method uses urban stormwater water-quality constituent data collected for the Nationwide Urban Runoff Program (NURP) during 1979-83. The constituents analyzed include 10 chemical constituents - chemical oxygen demand (COD), total suspended solids (TSS), dissolved solids (DS), total nitrogen (TN), total ammonia plus nitrogen (AN), total phosphorus (TP), dissolved phosphorous (DP), total copper (CU), total lead (PB), and total zinc (ZN). The purpose of this report is to briefly compare features of the two estimation methods.

Conference Paper↗
USGS2013

Historical methane hydrate project review

In 1995, U.S. Geological Survey made the first systematic assessment of the volume of natural gas stored in the hydrate accumulations of the United States. That study, along with numerous other studies, has shown that the amount of gas stored as methane hydrates in the world greatly exceeds the volume of known conventional gas resources. However, gas hydrates represent both a scientific and technical challenge and much remains to be learned about their characteristics and occurrence in nature. Methane hydrate research in recent years has mostly focused on: (1) documenting the geologic parameters that control the occurrence and stability of gas hydrates in nature, (2) assessing the volume of natural gas stored within various gas hydrate accumulations, (3) analyzing the production response and characteristics of methane hydrates, (4) identifying and predicting natural and induced environmental and climate impacts of natural gas hydrates, and (5) analyzing the effects of methane hydrate on drilling safety. Methane hydrates are naturally occurring crystalline substances composed of water and gas, in which a solid water-­‐lattice holds gas molecules in a cage-­‐like structure. The gas and water becomes a solid under specific temperature and pressure conditions within the Earth, called the hydrate stability zone. Other factors that control the presence of methane hydrate in nature include the source of the gas included within the hydrates, the physical and chemical controls on the migration of gas with a sedimentary basin containing methane hydrates, the availability of the water also included in the hydrate structure, and the presence of a suitable host sediment or “reservoir”. The geologic controls on the occurrence of gas hydrates have become collectively known as the “methane hydrate petroleum system”, which has become the focus of numerous hydrate research programs. Recognizing the importance of methane hydrate research and the need for a coordinated effort, the U.S. Congress enacted Public Law 106-­‐193, the Methane Hydrate Research and Development Act of 2000. This Act called for the Secretary of Energy to begin a methane hydrate research and development program in consultation with other U.S. federal agencies. At the same time a new methane hydrate research program had been launched in Japan by the Ministry of International Trade and Industry to develop plans for a methane hydrate exploratory drilling project in the Nankai Trough. Since this early start we have seen other countries including India, China, Canada, and the Republic of Korea establish large gas hydrate research and development programs. These national led efforts have also included the investment in a long list of important scientific research drilling expeditions and production test studies that have provided a wealth of information on the occurrence of methane hydrate in nature. The most notable expeditions and projects have including the following: -­‐Ocean Drilling Program Leg 164 (1995) -­‐Japan Nankai Trough Project (1999-­‐2000) -­‐Ocean Drilling Program Leg 204 (2004) -­‐Japan Tokai-­‐oki to Kumano-­‐nada Project (2004) -­‐Gulf of Mexico JIP Leg I (2005) -­‐Integrated Ocean Drilling Program Expedition 311 (2005) -­‐Malaysia Gumusut-­‐Kakap Project (2006) -­‐India NGHP Expedition 01 (2006) -­‐China GMGS Expedition 01 (2007) -­‐Republic of Korea UBGH Expedition 01 (2007) -­‐Gulf of Mexico JIP Leg II (2009) -­‐Republic of Korea UBGH Expedition 02 (2010) -­‐MH-­‐21 Nankai Trough Pre-­‐Production Expedition (2012-­‐2013) -­‐Mallik Gas Hydrate Testing Projects (1998/2002/2007-­‐2008) -­‐Alaska Mount Elbert Stratigraphic Test Well (2007) -­‐Alaska Iġnik Sikumi Methane Hydrate Production Test Well (2011-­‐2012) Research coring and seismic programs carried out by the Ocean Drilling Program (ODP) and Integrated Ocean Drilling Program (IODP), starting with the ODP Leg 164 drilling of the Blake Ridge in the Atlantic Ocean in 1995, have also contributed greatly to our understanding of the geologic controls on the formation, occurrence, and stability of gas hydrates in marine environments. For the most part methane hydrate research expeditions carried out by the ODP and IODP provided the foundation for our scientific understanding of gas hydrates. The methane hydrate research efforts under ODP-­‐IODP have mostly dealt with the assessment of the geologic controls on the occurrence of gas hydrate, with a specific goal to study the role methane hydrates may play in the global carbon cycle. Over the last 10 years, national led methane hydrate research programs, along with industry interest have led to the development and execution of major methane hydrate production field test programs. Two of the most important production field testing programs have been conducted at the Mallik site in the Mackenzie River Delta of Canada and in the Eileen methane hydrate accumulation on the North Slope of Alaska. Most recently we have also seen the completion of the world’s first marine methane hydrate production test in the Nankai Trough in the offshore of Japan. Industry interest in gas hydrates has also included important projects that have dealt with the assessment of geologic hazards associated with the presence of hydrates. The scientific drilling and associated coring, logging, and borehole monitoring technologies developed in the long list of methane hydrate related field studies are one of the most important developments and contributions associated with methane hydrate research and development activities. Methane hydrate drilling has been conducted from advanced scientific drilling platforms like the JOIDES Resolution and the D/V Chikyu, which feature highly advanced integrated core laboratories and borehole logging capabilities. Hydrate research drilling has also included the use of a wide array of industry, geotechnical and multi-­‐service ships. All of which have been effectively used to collect invaluable geologic and engineering data on the occurrence of methane hydrates throughout the world. Technologies designed specifically for the collection and analysis of undisturbed methane hydrate samples have included the development of a host of pressure core systems and associated specialty laboratory apparatus. The study and use of both wireline conveyed and logging-­‐while-­‐drilling technologies have also contributed greatly to our understanding of the in-­‐situ nature of hydrate-­‐bearing sediments. Recent developments in borehole instrumentation specifically designed to monitor changes associated with hydrates in nature through time or to evaluate the response of hydrate accumulations to production have also contributed greatly to our understanding of the complex nature and evolution of methane hydrate systems. Our understanding of how methane hydrates occur and behave in nature is still growing and evolving – we do not yet know if methane hydrates can be economically produced, nor do we know fully the role of hydrates as an agent of climate change or as a geologic hazard. But it is known for certain that scientific drilling has contributed greatly to our understanding of hydrates in nature and will continue to be a critical source of the information to advance our understanding of methane hydrates.

Report↗
USGS1990

Palynological assessment of organic tissues and metallic minerals in the Jerritt Canyon gold deposit, Nevada (U.S.A.)

Organic tissues and metallic minerals were studied in acid residues and thin section of the Jerritt Canyon (Bell Mine) gold deposit. The purpose was to compare gold-bearing and gold-free rocks, characterize their differences, and assess a possible relationship between the invisible gold and the organic tissues in these early Paleozoic, carbonaceous limestones, dolomites, and claystones. The most visually abundant acid-resistant component in the sooty, unoxidized, gold-bearing rocks is a black, rectangular, carbon-bearing mineraloid. In X-ray diffraction, it is poorly crystalline; in nuclear magnetic resonance, it is a highly aromatized structure. The increase in gold content that accompanies the increase in content of this protographite suggests that it may be the major gold-bearing compound. Less abundant among the acid-resistant residues are uncarbonized organic tissues that are typical of marine settings. The tissues not in the vicinity of silicified veins are medium to dark brown. The dominant tissues are the amorphous remains of algae and their zooplankton predators. These uncarbonized indigenous tissues indicate that temperatures were lower than those determined by geochemical and fluid inclusion methods. The presence of different kinds of carbon-bearing compounds could account for the discrepancy between the palynological and geochemical data. The uncarbonized organic tissues comprise such a small percentage of these rocks that they could be easily missed by bulk analytical methods. The presence of uncarbonized tissues helps to constrain the duration of the high heat flow that is shown by the fluid inclusion data. The presence of mixed signals suggests that the protographite may be the product of chemical rather than thermal reactions.

Nevada↗
USGS1968

Experimental evidence that fluid inclusions do not leak

The possibility of leakage of fluids into or out of fluid inclusions subjected to large pressure gradients has always been considered a serious problem in the interpretation of inclusion data. As previous experimental evidence on leakage was contradictory, new experiments were performed. Inclusion vapor bubble diameters in twelve quartz crystals (≤ 3 mm; 8 localities), not sawn, ground or polished, were measured. The samples were run at Pa-.o,-4,000 bars, at T u 100°-410° C, for ≤ 17 days total, and remeasured after each run. Similar experiments at ≤ 155° C were made on sphalerite and calcite. Most inclusions in most samples (even those only 5am under the surface in quartz) showed no change in bubble diameter, hence no leakage. A few exceptions, mainly among inclusions homogenizing at T « Tru, had P internal » P internal , hence they ruptured and lost liquid during the 410° C run. From this work and a review of the literature, we conclude that most inclusions have not suffered major leakage. Some previous experiments indicating leakage may be explained by microfractures introduced during sample preparation. The present work does not , however, preclude the possibility of diffusion of small but chemically significant amounts of substances such as hydrogen in or out of inclusions .

Economic Geology↗
USGS1973

Spectrophotometric determination of tungsten in rocks by an isotope dilution procedure

Samples are decomposed with hydrofluoric acid and perchloric acid in the presence of W 181 tracer. Molybdenum is extracted from a hydrochloric acid solution with tributyl phosphate. Tungsten is separated from most other elements by extraction of the a-benzoinoximate into chloroform. Stannous chloride in concentrated hydrochloric acid is used to strip tungsten and reduce it to W +5 . The amount of tungsten is determined spectrophotometrically after extraction as the thiocyanate complex into amyl alcohol. The correction for chemical losses is determined by counting W 181 .

Journal of Research of the U.S. Geological Survey↗
USGS1974

Regional flow system and ground-water quality in western Ohio

Most relatively deep wells drilled in the carbonate aquifers in western Ohio tap a recognizable regional flow system encompassing all or parts of several major basins. The principal recharge area includes the higher, central part of the region, where much of the terrane is hummocky to hilly glacial moraine. The principal discharge areas are the valleys of the major streams and lowlands along Lake Erie. Ground water moving through this system undergoes a progressive change in chemical quality, from a calcium bicarbonate type in recharge areas to a calcium sulfate type in discharge areas. Changes in selected chemical constituents are orderly and, within the observed parameters, predictable.

Ohio↗
USGS2020

Evaluating the potential role of bioactive chemicals on the distribution of invasive Asian carp upstream and downstream from river mile 278 in the Illinois waterway

Two non-native carp species have invaded the Illinois Waterway and are a threat to Great Lakes ecosystems. Poor water quality in the upper Illinois Waterway, may be a factor contributing to the stalling of the carp population front near river mile 278. In 2015, the U.S. Geological Survey collected 4 sets of water samples from two sites upstream and 4 sites downstream from river mile 278, and one tributary. Each sample was analyzed for up to 649 unique parameters of which 287 were detected including 96 pesticides, 62 pharmaceuticals, 39 wastewater indicator compounds, 29 metals, 19 volatile organic compounds (VOCs), six disinfection by-products (DBPs), five hormones, and five carboxylic acids. Potential for bioactivity was estimated by comparing chemical concentrations to aquatic life or human health criteria and to in-vitro bioactivity screening results in the U.S EPA ToxCast™ database. The resulting hazard quotients and exposure-activity ratios (EARs) are toxicity indexes, that can be used to rank potential bioactivity of individual chemicals and chemical mixtures. This analysis indicates that several bioactive chemicals (BCs) including: carbendazim, 2,4-D, metolachlor, terbuthylazine, and acetochlor (pesticides); 1,4-dioxane (VOC); metformin, diphenhydramine, sulfamethoxazole, tramadol, fexofenadine, and the anti-depressants (pharmaceuticals); bisphenol A, 4-nonylphenol, galaxolide, 4-tert-octylphenol (wastewater indicator chemical); lead and boron (metals); and estrone (hormone) all occur in the upper Illinois Waterway at concentrations that produce elevated EARs values and may be adversely affecting carp reproduction and health. The clear differences in water quality upstream and downstream from river mile 278 with higher contaminant concentrations and potential bioactivity upstream could represent a barrier to carp range expansion.

Illinois↗
USGS1999

Surface-Water Data, Georgia, Water Year 1999

Water resources data for the 1999 water year for Georgia consists of records of stage, discharge, and water quality of streams; and the stage and contents of lakes and reservoirs published in one volume in a digital format on a CD-ROM. This volume contains discharge records of 121 gaging stations; stage for 13 gaging stations; stage and contents for 18 lakes and reservoirs; continuous water quality records for 10 stations; and the annual peak stage and annual peak discharge for 75 crest-stage partial-record stations. These data represent that part of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in Georgia. Records of discharge and stage of streams, and contents or stage of lakes and reservoirs were first published in a series of U.S. Geological water-supply papers entitled, 'Surface-Water Supply of the United States.' Through September 30, 1960, these water-supply papers were in an annual series and then in a 5-year series for 1961-65 and 1966-70. Records of chemical quality, water temperature, and suspended sediment were published from 1941 to 1970 in an annual series of water-supply papers entitled, 'Quality of Surface Waters of the United States.' Records of ground-water levels were published from 1935 to 1974 in a series of water-supply papers entitled, 'Ground-Water Levels in the United States.' Water-supply papers may be consulted in the libraries of the principal cities in the United States or may be purchased from the U.S. Geological Survey, Branch of Information Services, Federal Center, Box 25286, Denver, CO 80225. For water years 1961 through 1970, streamflow data were released by the U.S. Geological Survey in annual reports on a State-boundary basis prior to the two 5-year series water-supply papers, which cover this period. The data contained in the water-supply papers are considered the official record. Water-quality records for water years 1964 through 1970 were similarly released either in separate reports or in conjunction with streamflow records. Beginning with the 1971 water year, water data for streamflow, water quality, and ground water are published in official Survey reports on a State-boundary basis. These official Survey reports carry an identification number consisting of the two-letter State abbreviation, the last two digits of the water year, and the volume number. For example, this volume is identified as 'U.S. Geological Survey Water-Data Report GA-99-1.' These water-data reports are for sale in various formats, by the National Technical Information Service, U.S. Department of Commerce, Springfield, VA 22161.

Georgia↗
USGS1978

Reconnaissance of chemical quality of surface water and fluvial sediment in the Dirty Devil River basin, Utah

The water-quality reconnaissance in the Dirty Devil River basin, Utah, covered an area of about 4,300 square miles (11,100 square kilo-meters). Data were obtained by the U.S. Geological Survey one or more times at 104 sites during the period July 1975 to September 1976; and during visits to 34 other sites during the same period, the streams were dry. Precipitation was below normal in both 1975 and 1976 at weather stations at Emery and Capitol Reef National Park and was above normal in 1975 and below normal in 1976 at Hanksville. Streamflow was near normal in the Dirty Devil River basin in 1975 and was much below normal in 1976. Rocks that crop out in the basin range in age from Permian to Quaternary. The Carmel Formation of Jurassic age and various members of the Mancos Shale of Cretaceous age are major contributors of dissolved solids to streams in the basin. Major diversions are made from Muddy Creek for irrigation in the Emery area. Downstream reaches of Muddy Creek commonly receive only seepage and irrigation return flow. Three major irrigation diversions near Fremont commonly remove nearly all the flow from the upper Fremont River. Major flow accretions to the Fremont River in Bicknell Bottoms furnish water for additional diversions along the remaining length of the Fremont River. The most pronounced change in chemical characteristics of water in streams in the Dirty Devil River basin occurs in a 15-mile (24-kilometer) reach of Muddy Creek between the major diversions 5 miles (8 kilometers) north of Emery and the point at which Highway 1-70 crosses Muddy Creek. Dissolved-solids concentrations at the diversions are generally less than 300 milligrams per liter and at the lower end of the reach are commonly greater than 2,000 milligrams per liter. Factors that contribute to the deterioration in the chemical quality of water in the Emery area are the soluble minerals in the rocks of Cretaceous age that crop out in the area, the major or total diversion of flow of Muddy Creek, and the irrigation of and return flow from soils that have commonly developed on material derived from gypsum-bearing marine shale. Dissolved-solids concentrations remain high to the mouth of Muddy Creek near Hanksville. Only one perennial stream--Salt Wash--enters Muddy Creek between Highway 1-70 and the mouth. The discharge of Salt Wash is usually 2.0 to 2.5 cubic feet per second (0.057 to 0.071 cubic meter per second), and the dissolved-solids concentration ranges from about 5,400 to 5,900 milligrams per liter.

Utah↗
USGS1987

Water resources data for Arkansas, water year 1986

Water resources data for the 1986 water year for Arkansas consist of records of gage height, discharge, and water quality of streams; water quality of lakes; and water levels and water quality of wells. This report contains discharge records for 48 gaging stations; water quality for 154 stations, 73 partial-record stations, 5 observation wells, and 1 precipitation station, and water levels for 96 observation wells. Also included are data for 85 crest-stage partial record stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating State and Federal agencies in Arkansas. Records of discharge or gage height of streams, and contents or elevation of lakes were first published in a series of U.S. Geological Survey water-supply papers entitled "Surface Water Supply of the United States." Through September 30, 1960, these water-supply papers were in an annual series and for 1961-65 and 1966-70 were in a 5 -year series. Records of chemical quality, water temperatures, and suspended sediment were published from 1941 to 1970 in an annual series of water-supply papers entitled "Quality of Surface Waters of the United States." Records of ground-water levels were published from 1935 to 1974 in a series of water-supply papers entitled "Ground Water Levels in the United States." Water-supply papers may be consulted in the libraries of the principal cities in the United States or may be purchased from Branch of Distribution, U.S. Geological Survey, 1200 South Eads Street, Arlington, VA 22202. For water years 1961 through 1974, streamflow data were released by the Geological Survey in annual reports on a State-boundary basis. Water-quality records for water years 1964 through 1974 were similarly released, either in separate reports or in conjuction with streamflow records. Beginning with the 1975 water year, water data for streamflow, water quality, and ground water are published as an official Survey report on a State-boundary basis. These official Survey reports carry an identification number consisting of the two-letter State abbreviation, the last two digits of the water year, and the volume number. For example, this report is identified as "U.S. Geological Survey Water Data Report AR-86-1."

Arkansas↗