USGS Science⌕ Search

SEARCH · USGS Science

Results for “Carbon”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,423 records · Page 79Linked to original sources
USGS2008

Littoral zones as sources of biodegradable dissolved organic carbon in lakes

A survey of 12 lakes in Minnesota, USA, was conducted to examine the factors controlling variability in biodegradable dissolved organic carbon (BDOC) concentration. The principal question addressed was whether BDOC concentration was more strongly related to lake trophic status or morphometric parameters. BDOC concentration was determined by incubating filtered lake water for a period of 15 months and fitting an exponential decay curve to measured DOC concentrations. BDOC concentrations varied from 73 to 427 mmol C.L-1 and composed 15%-63% of the total DOC pool. There were no significant correlations between BDOC and measures of lake trophic status. Instead, BDOC was most closely associated with the percentage of lake area covered by littoral zone, suggesting a significant source of BDOC from aquatic macrophytes and lake surface sediments. ?? 2008 NRC.

Canadian Journal of Fisheries and Aquatic Sciences↗
USGS2008

Four centuries of soil carbon and nitrogen change after stand-replacing fire in a forest landscape in the western Cascade Range of Oregon

Episodic stand-replacing wildfire is a significant disturbance in mesic and moist Douglas-fir (Pseudotsuga menziesii (Mirb.) Franco) forests of the Pacific Northwest. We studied 24 forest stands with known fire histories in the western Cascade Range in Oregon to evaluate long-term impacts of stand-replacing wildfire on carbon (C) and nitrogen (N) pools and dynamics within the forest floor (FF, Oe and Oa horizons) and the mineral soil (0-10 cm). Twelve of our stands burned approximately 150 years ago ('young'), and the other 12 burned approximately 550 years ago ('old'). Forest floor mean C and N pools were significantly greater in old stands than young stands (N pools: 1823 ?? 132 kg??ha-1 vs. 1450 ?? 98 kg??ha -1; C pools: 62 980 ?? 5403 kg??ha-1 vs. 49 032 ?? 2965 kg??ha-1, mean ?? SE) as a result of significant differences in FF mass. Forest floor C and N concentrations and C/N ratios did not differ by time since fire, yet potential N mineralization rates were significantly higher in FF of old sites. Old and young mineral soils did not differ significantly in pools, concentrations, C/N ratios, or cycling rates. Our results suggest that C and N are sequestered in FF of Pacific Northwest Douglas-fir forests over long (???400 year) intervals, but that shorter fire return intervals may prevent that accumulation. ?? 2008 NRC.

Canadian Journal of Forest Research↗
USGS2023

Carbonate sediment transport across coral reefs: A comparison of fringing vs. barrier reefs

Considerable uncertainty remains in the budgets of carbonate sediment on reef lined coasts, particularly with respect to the supply of sediment to a reef flat that is then transported throughout a reef system. In this study, we re-examine two recent studies, one on a barrier reef bounded by channels that incise the reef, and one on a fringing reef without channels. Results indicate that the presence of channels results in a circulation regime that promotes not only the onshore sediment flux across the reef flat, but also upslope transport of sediment from the fore reef onto the reef flat. Data from these experiments suggest that when channels are present in the reef flat, the hydrodynamics of these reef systems favor the transport the transport of sediment up the fore reef. This outcome has implications for the design of potential reef restoration efforts intended to protect shorelines.

Conference Paper↗
USGS2017

Archaeal diversity and CO2 fixers in carbonate-/siliciclastic-rock groundwater ecosystems

Groundwater environments provide habitats for diverse microbial communities, and although Archaea usually represent a minor fraction of communities, they are involved in key biogeochemical cycles. We analysed the archaeal diversity within a mixed carbonate-rock/siliciclastic-rock aquifer system, vertically from surface soils to subsurface groundwater including aquifer and aquitard rocks. Archaeal diversity was also characterized along a monitoring well transect that spanned surface land uses from forest/woodland to grassland and cropland. Sequencing of 16S rRNA genes showed that only a few surface soil-inhabiting Archaea were present in the groundwater suggesting a restricted input from the surface. Dominant groups in the groundwater belonged to the marine group I (MG-I) Thaumarchaeota and the Woesearchaeota. Most of the groups detected in the aquitard and aquifer rock samples belonged to either cultured or predicted lithoautotrophs (e.g., Thaumarchaeota or Hadesarchaea). Furthermore, to target autotrophs, a series of 13 CO 2 stable isotope-probing experiments were conducted using filter pieces obtained after filtration of 10,000 L of groundwater to concentrate cells. These incubations identified the SAGMCG Thaumarchaeota and Bathyarchaeota as groundwater autotrophs. Overall, the results suggest that the majority of Archaea on rocks are fixing CO 2 , while archaeal autotrophy seems to be limited in the groundwater.

Archaea↗
USGS2018

Diagenetic palaeotemperatures from aqueous fluid inclusions: re-equilibration of inclusions in carbonate cements by burial heating

Diagenetic palaeotemperatures determined from aqueous fluid inclusions can be affected by re-equilibration during burial heating. Calculations based on the observed behaviour of inclusions in fluorite under external confining pressure allows prediction of the temperatures and depths of burial necessary to initiate re-equilibration of aqueous inclusions in the common size range 40 to 4 µm. Heating of 20° to 60°C over the initial trapping temperature may cause errors of 10° to 20°C in the homogenization temperature. This suggests re-equilibration may cause aqueous inclusions in carbonates to yield a poor record of their low-temperature history, but a useful record of the maximum temperature experienced by the host rock. Previous work suggests inclusions containing petroleum fluids will be less susceptible to re-equilibration.

Mineralogical Magazine↗
USGS2009

Characterisation of carbon nanotubes in the context of toxicity studies

Nanotechnology has the potential to revolutionise our futures, but has also prompted concerns about the possibility that nanomaterials may harm humans or the biosphere. The unique properties of nanoparticles, that give them novel size dependent functionalities, may also have the potential to cause harm. Discrepancies in existing human health and environmental studies have shown the importance of good quality, well-characterized reference nanomaterials for toxicological studies. Here we make a case for the importance of the detailed characterization of nanoparticles, using several methods, particularly to allow the recognition of impurities and the presence of chemically identical but structurally distinct phases. Methods to characterise fully, commercially available multi-wall carbon nanotubes at different scales, are presented.

Environmental Health↗
USGS2005

4D seismic to image a thin carbonate reservoir during a miscible CO2 flood: Hall-Gurney Field, Kansas, USA

Time-lapse (TL) seismic monitoring has proven a valuable tool for reservoir management. If available in a timely and cost-effective manner, it can be incorporated into a dynamic reservoir management approach, spec-ifically in terms of assessing sweep efficiency through constraining reservoir simulations, quantifying compartmentalization, and enhancing the placement of infill wells. Thus, cost-effectiveness, rapid turnaround time, and sensitivity of the seismic response to subtle changes in reservoir properties evident in production data are critical assets of a robust and economic TL application. Successful applications of TL monitoring have been predominantly offshore—Gulf of Mexico and North Sea—in thick clastic reservoirs characterized as low technical risk. Changes in TL seismic images as a direct result of enhanced oil recovery operations in low compressibility, “stiff” carbonate reservoirs are so small that distinguishing reservoir fluid changes from background noise on seismic attribute maps is challenging at best and many times impossible. Consequently, reservoirs predicted to produce weak TL anomalies associated with enhanced oil recovery (EOR) operations are classified as high-risk cases and languish in what has been designated the “stretch portfolio” of time-lapse application in reservoir management.

Kansas↗
USGS2018

Status of tidal marsh mapping for blue carbon inventories

Remote-sensing-based maps of tidal marshes, both of their extents and carbon stocks, will play a key role in conducting greenhouse gas (GHG) inventories. The U.N. Environment Programme World Conservation Monitoring Centre has produced a new Global Distribution of Salt Marsh dataset that estimates global salt marsh area at 5.5 Mha. A Tier 1–2 GHG Inventory of U.S. Coastal Wetlands has been developed using the NOAA Coastal-Change Analysis Program Landsat-based land cover maps as a primary dataset. 180Successful mapping of tidal marsh biomass with optical satellite images provides opportunity to improve GHG Inventories. Further work is needed to map tidal marsh salinity gradients, the extent of tidal vs. non-tidal marshes, methane emissions, and high-resolution elevation.

Book chapter↗
USGS2006

Evolution of fracture and fault-controlled fluid pathways in carbonates of the Albanides fold-thrust belt

The process of fracture and fault formation in carbonates of the Albanides fold-thrust belt has been systematically documented using hierarchical development of structural elements from hand sample, outcrop, and geologic-map scales. The function of fractures and faults in fluid migration was elucidated using calcite cement and bitumen in these structures as a paleoflow indicator. Two prefolding pressure-solution and vein assemblages were identified: an overburden assemblage and a remote tectonic stress assemblage. Sheared layer-parallel pressure-solution surfaces of the overburden assemblage define mechanical layers. Shearing of mechanical layers associated with folding resulted in the formation of a series of folding assemblage fractures at different orientations, depending on the slip direction of individual mechanical layers. Prefolding- and folding-related fracture assemblages together formed fragmentation zones in mechanical layers and are the sites of incipient fault localization. Further deformation along these sites was accommodated by rotation and translation of fragmented rock, which formed breccia and facilitated fault offset across multiple mechanical layers. Strike-slip faults formed by this process are organized in two sets in an apparent conjugate pattern. Calcite cement and bitumen that accumulated along fractures and faults are evidence of localized fluid flow along fault zones. By systematic identification of fractures and faults, their evolution, and their fluid and bitumen contents, along with subsurface core and well-log data, we identify northeast-southwest-trending strike-slip faults and the associated structures as dominant fluid pathways in the Albanides fold-thrust belt. Copyright ?? 2006. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle↗
USGS2011

Geochemical analysis of Atlantic rim water, Carbon County, Wyoming: New applications for characterizing coalbed natural gas reservoirs

Coalbed natural gas (CBNG) production typically requires the extraction of large volumes of water from target formations, thereby influencing any associated reservoir systems. We describe isotopic tracers that provide immediate data on the presence or absence of biogenic natural gas and the identify methane-containing reservoirs are hydrologically confined. Isotopes of dissolved inorganic carbon and strontium, along with water quality data, were used to characterize the CBNG reservoirs and hydrogeologic systems of Wyoming’s Atlantic Rim. Water was analyzed from a stream, springs, and CBNG wells. Strontium isotopic composition and major ion geochemistry identify two groups of surface water samples. Muddy Creek and Mesaverde Group spring samples are Ca-Mg-SO4–type water with higher 87Sr/86Sr, reflecting relatively young groundwater recharged from precipitation in the Sierra Madre. Groundwaters emitted from the Lewis Shale springs are Na-HCO3–type waters with lower 87Sr/86Sr, reflecting sulfate reduction and more extensive water-rock interaction. To distinguish coalbed waters, methanogenically enriched d13CDIC was used from other natural waters. Enriched d13CDIC, between −3.6 and +13.3‰, identified spring water that likely originates from Mesaverde coalbed reservoirs. Strongly positive d13CDIC, between +12.6 and +22.8‰, identified those coalbed reservoirs that are confined, whereas lower d13CDIC, between +0.0 and +9.9‰, identified wells within unconfined reservoir systems

Wyoming↗
USGS2001

Sedimentary Carbon, Sulfur, and Iron Relationships in Modern and Ancient Diagenetic Environments of the Eel River Basin (U.S.A.)

Depositional and diagenetic controls on the distributions of carbon, sulfur, and iron (C-S-Fe) in modern sediments and upper Pleistocene mudrocks of the Eel River Basin (ERB), northern California continental margin, were investigated using a combination of geochemical, radioisotopic, and sedimentological methods. A mass balance based on down-core profiles of porewater and solid-phase constituents and diagenetic modeling suggests that only 12-30% of the pyrite-S produced via SO 4 -2 reduction during burial is retained in modern shelf and upper slope deposits of the ERB. Bioturbational reoxidation of initially reduced S is inferred to be the major control on S preservation, on the basis of an observed inverse relationship between pyrite-S retention and biological mixing intensity, estimated from profiles of excess 234 Th. Importantly, these findings argue that massive depositional episodes on the shelf following floods of the Eel River have a negligible long-term impact on bioturbating macrofauna and the potential to affect geochemical properties of the sediments. Down-core profiles of reactive Fe 3+ and Py-Fe(II) for the modern deposits suggest that highly reactive Fe phases are sulfidized well within ∼ 500-2000 years of burial, thereby limiting later pyritization, which could occur through sulfidation of less reactive phases. This result explains the low (≤ 0.4) degree of pyritization (DOP) values exhibited by both modern and ancient deposits of the ERB and lends support to the notion that pyritization in aerobic continental-margin sediments is largely associated with highly reactive detrital Fe oxides. Comparable mean C/S weight ratios for modern sediments (5.4 ± 3.3, 1σ) and mudrocks (6.9 ± 4.5) of the ERB suggest that the upper Pleistocene strata reflect a geochemical environment analogous to that of the modern margin. Specifically, the C-S-Fe signatures shared by the modern and ancient deposits are a consequence of similar detrital Fe mineralogies, initial organic-matter content (C org ≤ 1%) and composition (C/N = 13 to 17, δ 13 C org = -22 to -25‰), burial rate, and importantly, bioturbation intensity. The findings of this study have important implications for the use of C-S-Fe signatures as indicators of diagenetic processes in dynamic, continental-margin environments.

California↗
USGS1970

Foraminiferal zonation and carbonate facies of Carboniferous (Mississippian and Pennsylvanian) Lisburne group, central and eastern Brooks range, Arctic Alaska

The Lisburne Group carbonate rocks of the central and eastern Brooks Range contain foraminiferal assemblages assigned to zones of late Tournaisian (Osage) to early Moscovian (Atoka) age. Representatives of both Eurasiatic and American cratonic microfaunas permit correlation with the original Carboniferous type sections in western Europe as well as with the standard Mississippian and Pennsylvanian sequences in the Mid-Continent region of North America. Correlation anomalies in the lower part of the sequence are discussed.

Alaska↗
USGS2009

Unraveling the stratigraphy of the Oriskany Sandstone: A necessity in assessing its site-specific carbon sequestration potential

The widespread distribution, favorable reservoir characteristics, and depth make the Lower Devonian Oriskany Sandstone a viable sequestration target in the Appalachian Basin. The Oriskany Sandstone is thickest in the structurally complex Ridge and Valley Province, thins toward the northern and western basin margins, and is even absent in other parts of the basin (i.e., the no-sand area of northwestern Pennsylvania). We evaluated four regions using petrographic data, core analyses, and geophysical log analyses. Throughout the entire study area, average porosities range from 1.35 to 14%. The most notable porosity types are primary intergranular, secondary dissolution, and fracture porosity. Intergranular primary porosity dominates at stratigraphic pinch-out zones near the Oriskany no-sand area and at the western limit of the Oriskany Sandstone. Secondary porosity occurs from dissolution of carbonate constituents primarily in the combination-traps natural gas play extending through western Pennsylvania, western West Virginia, and eastern Ohio. Fracture porosity dominates in the central Appalachian Plateau Province and Valley and Ridge Province. Based on average porosity, the most likely regions for successful sequestration in the Oriskany interval are (1) updip from Oriskany Sandstone pinch-outs in eastern Ohio, and (2) western Pennsylvania, western West Virginia, and eastern Ohio where production occurs from a combination of stratigraphic and structural traps. Permeability data, where available, were used to further evaluate the potential of these regions. Permeability ranges from 0.2 to 42.7 md. Stratigraphic pinch-outs at the northern and western limits of the basin have the highest permeabilities. We recommend detailed site assessments when evaluating the sequestration potential of a given injection site based on the variability observed in the Oriskany structure, lithology, and reservoir characteristics. ?? 2009. The American Association of Petroleum Geologists/Division of Environmental Ceosciences. All rights reserved.

Environmental Geosciences↗
USGS2009

Reservoir uncertainty, Precambrian topography, and carbon sequestration in the Mt. Simon Sandstone, Illinois Basin

Sequestration sites are evaluated by studying the local geological structure and confirming the presence of both a reservoir facies and an impermeable seal not breached by significant faulting. The Cambrian Mt. Simon Sandstone is a blanket sandstone that underlies large parts of Midwest United States and is this region's most significant carbon sequestration reservoir. An assessment of the geological structure of any Mt. Simon sequestration site must also include knowledge of the paleotopography prior to deposition. Understanding Precambrian paleotopography is critical in estimating reservoir thickness and quality. Regional outcrop and borehole mapping of the Mt. Simon in conjunction with mapping seismic reflection data can facilitate the prediction of basement highs. Any potential site must, at the minimum, have seismic reflection data, calibrated with drill-hole information, to evaluate the presence of Precambrian topography and alleviate some of the uncertainty surrounding the thickness or possible absence of the Mt. Simon at a particular sequestration site. The Mt. Simon is thought to commonly overlie Precambrian basement granitic or rhyolitic rocks. In places, at least about 549 m (1800 ft) of topographic relief on the top of the basement surface prior to Mt. Simon deposition was observed. The Mt. Simon reservoir sandstone is thin or not present where basement is topographically high, whereas the low areas can have thick Mt. Simon. The paleotopography on the basement and its correlation to Mt. Simon thickness have been observed at both outcrops and in the subsurface from the states of Illinois, Ohio, Wisconsin, and Missouri. ?? 2009. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

Environmental Geosciences↗
USGS2011

Depositional and diagenetic variability within the Cambrian Mount Simon Sandstone: Implications for carbon dioxide sequestration

The Cambrian Mount Simon Sandstone is the major target reservoir for ongoing geologic carbon dioxide (CO 2 ) sequestration demonstrations throughout the midwest United States. The potential CO 2 reservoir capacity, reactivity, and ultimate fate of injected CO 2 depend on textural and compositional properties determined by depositional and diagenetic histories that vary vertically and laterally across the formation. Effective and efficient prediction and use of the available pore space requires detailed knowledge of the depositional and diagenetic textures and mineralogy, how these variables control the petrophysical character of the reservoir, and how they vary spatially. Here, we summarize the reservoir characteristics of the Mount Simon Sandstone based on examination of geophysical logs, cores, cuttings, and analysis of more than 150 thin sections. These samples represent different parts of the formation and depth ranges of more than 9000 ft ( 2743 m) across the Illinois Basin and surrounding areas. This work demonstrates that overall reservoir quality and, specifically, porosity do not exhibit a simple relationship with depth, but vary both laterally and with depth because of changes in the primary depositional facies, framework composition (i.e., feldspar concentration), and diverse diagenetic modifications. Diagenetic processes that have been significant in modifying the reservoir include formation of iron oxide grain coatings, chemical compaction, feldspar precipitation and dissolution, multiple generations of quartz overgrowth cementation, clay mineral precipitation, and iron oxide cementation. These variables provide important inputs for calculating CO 2 capacity potential, modeling reactivity, and are also an important baseline for comparisons after CO 2 injection.

Indiana↗
USGS2024

Quantifying and evaluating strategies to decrease carbon dioxide emissions generated from tourism to Yellowstone National Park

The tourism industry needs strategies to reduce emissions and hasten the achievement of global carbon dioxide (CO 2 ) emission reduction targets. Using a case study approach, we estimated CO 2 emissions related to park tourism in Yellowstone National Park (USA) generated from transit to and from the park, transit within the park, accommodations, and park operations. Results indicate tourism to Yellowstone National Park produces an estimated 1.03 megaton (1.03 billion kg) of CO 2 -equivalent emissions annually, with an average of 479 kg CO 2 per visitor. Almost 90% of these emissions were attributable to transit to and from the destination, while 5% were from transit within the park, 4% from overnight accommodations, and about 1% from other park operations (e.g., visitor centers, museums, shops, restaurants, etc.). Visitors who fly only made up about 35% of all visitors, but produced 72% of the emissions related to transit to and from the park. Future scenarios that alter transit to and from the park can reduce emissions the most; this includes a greater proportion of local or regional visitors, fewer visitors flying, and increased fuel efficiency of vehicles. The method developed in this work, and applied specifically to Yellowstone National Park, can be adopted elsewhere and used to help decision makers evaluate the effectiveness of potential emission reduction strategies.

Wyoming↗
USGS2022

Variation in carbon and nitrogen concentrations among peatland categories at the global scale

Peatlands account for 15 to 30% of the world’s soil carbon (C) stock and are important controls over global nitrogen (N) cycles. However, C and N concentrations are known to vary among peatlands contributing to the uncertainty of global C inventories, but there are few global studies that relate peatland classification to peat chemistry. We analyzed 436 peat cores sampled in 24 countries across six continents and measured C, N, and organic matter (OM) content at three depths down to 70 cm. Sites were distinguished between northern (387) and tropical (49) peatlands and assigned to one of six distinct broadly recognized peatland categories that vary primarily along a pH gradient. Peat C and N concentrations, OM content, and C:N ratios differed significantly among peatland categories, but few differences in chemistry with depth were found within each category. Across all peatlands C and N concentrations in the 10–20 cm layer, were 440 ± 85.1 g kg -1 and 13.9 ± 7.4 g kg -1 , with an average C:N ratio of 30.1 ± 20.8. Among peatland categories, median C concentrations were highest in bogs, poor fens and tropical swamps (446–532 g kg -1 ) and lowest in intermediate and extremely rich fens (375–414 g kg -1 ). The C:OM ratio in peat was similar across most peatland categories, except in deeper samples from ombrotrophic tropical peat swamps that were higher than other peatlands categories. Peat N concentrations and C:N ratios varied approximately two-fold among peatland categories and N concentrations tended to be higher (and C:N lower) in intermediate fens compared with other peatland types. This study reports on a unique data set and demonstrates that differences in peat C and OM concentrations among broadly classified peatland categories are predictable, which can aid future studies that use land cover assessments to refine global peatland C and N stocks.

PLoS ONE↗
USGS2022

Minimum requirements for publishing hydrogen, carbon, nitrogen, oxygen and sulfur stable-isotope delta results (IUPAC Technical Report)

Stable hydrogen, carbon, nitrogen, oxygen and sulfur (HCNOS) isotope compositions expressed as isotope-delta values are typically reported relative to international standards such as Vienna Standard Mean Ocean Water (VSMOW), Vienna Peedee belemnite (VPDB) or Vienna Cañon Diablo Troilite (VCDT). These international standards are chosen by convention and the calibration methods used to realise them in practice undergo occasional changes. To ensure longevity and reusability of published data, a comprehensive description of (1) analytical procedure, (2) traceability, (3) data processing, and (4) uncertainty evaluation is required. Following earlier International Union of Pure and Applied Chemistry documents on terminology and notations, this paper proposes minimum requirements for publishing HCNOS stable-isotope delta results. Each of the requirements are presented with illustrative examples.

Pure and Applied Chemistry↗