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At least 1,423 records · Page 79Linked to original sources
USGS1993

A review of possible causes of nutrient enrichment and decline of endangered sucker populations in Upper Klamath Lake, Oregon

Upper Klamath Lake, and the connecting Agency Lake, is a large (140 square mile) lake in south-central Oregon. The lake has a recent history of long-duration, near-monoculture, blue-green algal blooms of Aphanizomenon flos-aquae . Typically, the algal bloom causes nuisance and detrimental conditions, including a deep-green "pea soup" appearance, from mid-May to late October. Accompanying the blooms are foul odors, extremely high pH, widely varied dissolved-oxygen concentrations of supersaturation or near depletion, occasional but extensive fish kills, and elevated levels of toxic ammonia. In 1988, the Lost River sucker ( Deltistes luxatus ) and shortnose sucker ( Chasmistes brevirostris ), long-term inhabitants of Upper Klamath Lake, were placed on the Federal endangered-species list. The endangering of the sucker species in recent years is hypothesized to be caused by degraded lake-water-quality conditions. Upper Klamath Lake has been eutrophic since it was first discovered. However, increases in algal abundance and changes in algal type over relatively recent years are evident, and can be correlated with agricultural development of the basin. The most common cause for an increased abundance of algae in lakes is increased enrichment of nitrogen and phosphorus compounds. Ten possible causes for this excessive enrichment in nutrients are described. Three of these hypotheses are suggested for immediate testing because of large-scale changes in nutrient loading that may have occurred as a result of man’s activities. These three hypotheses relate nutrient enrichment to (1) conversion of marshland to agricultural land, (2) agricultural drainage from the basin, and (3) reservoir regulation. Eleven possible hypothetical causes for the decline in sucker populations also are described. The decline in sucker population may be related to excessive nutrient enrichment (eutrophication) of the lake.

Oregon↗
USGS1995

Relation of land use to nitrogen concentration in ground water in the Patuxent River basin, Maryland

A decrease in nitrogen inputs could improve water quality in the Chesapeake Bay. In order to provide information about nitrogen transport to the bay, the U.S. Geological Survey examined historical land use associated with nonpoint sources of nitrogen and nitrogen concentrations in ground water in the Patuxent River Basin, Maryland; The Patuxent River is a major tributary to the bay. Most nitrogen in ground water was present as nitrate. In the Piedmont Physiographic Province part of the Patuxent River basin, nitrate concentrations in ground water were higher in agricultural areas than in forested and urban areas. Nitrate concentrations were related to land use at well sites because wells yielded water that infiltrated within the same contributing area where the wells are located. Agricultural activities possibly were a source for the transport of large amounts of nitrogen to ground water and probably also to base flow in nearby streams. The high nitrate concentrations were not attributed to sampling bias. In the Coastal Plain Physiographic Province, most nitrate concentrations were low and were unrelated to land use at the well site because the wells were screened in deep, regional aquifers. Ground water in a few shallow wells had high nitrate concentrations, possibly related to nearby agricultural and urban land use. Increased nitrate concentrations in shallow ground water could increase concentrations in stream base flow and eventually could increase concentrations in regional aquifers and ground water that discharges directly to the Chesapeake Bay.

Water-Resources Investigations Report↗
USGS1995

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma: Analysis of information on nutrients, suspended sediment, and suspended solids, 1970-92

Water-quality data collected during water years 1970-90 (October 1 to September 30) for 83 surface-water sites and during 1970-92 for 395 ground-water sites in the 48,000 square mile Ozark Plateaus study unit of the National Water Quality Assessment Program were analyzed using selected descriptive and statistical methods. The water- quality data include nutrient (nitrogen and phosphorus), suspended sediment, and suspended- solids data, and ancillary information such as fertilizer use, animal waste, sewage treatment plant, and land use. Statistically significant differences exist in surface-water quality that can be attributed to physiography, land use, and other effects. The sites that were considered to be substantially affected by sewage treatment plants had the largest concentrations of nutrients. Nutrient concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. Statistically significant differences existed in the quality of ground water that can be attributed to hydrogeologic and land-use effects. Nutrient concentrations generally were largest where the water source is indicated to be shallow in origin and where parts of the hydrogeologic units are in agricultural land-use areas. Water quality has changed at several surface-water sites since 1970. Nutrient concentrations appear to have increased at some sites and decreased at other sites. Causes of these apparent trends are not known, but many of the sites with apparent trends are in agricultural areas. Surface-water loads of nutrients and suspended sediment were affected by several factors including streamflow, climate, drainage area, reservoir operation, and inputs from point and nonpoint sources. Annual loads were largest in large basins, with large inputs of nutrients or sediment during periods of high streamflows at locations where reservoir operation effects are not substantial.

Arkansas, Kansas, Missouri, Oklahoma↗
USGS1996

Water-quality assessment of the Connecticut, Housatonic, and Thames River Basins study unit: Analysis of available data on nutrients, suspended sediments, and pesticides, 1972-92

This retrospective report examines available nutrient, suspended sediment, and pesticide data in surface and ground water in the Connecticut, Housatonic and Thames Rivers Study Unit of the National Water-Quality Assessment Program. The purpose of this study is to improve the understanding of natural and anthropogenic factors affecting water quality in the study unit. Waterquality data were acquired from various sources, primarily, the U.S. Geological Survey and the U.S. Environmental Protection Agency. The report examines data for water years 1972-92, focusing on 1980-92, although it also includes additional data from as early as 1905. The study unit lies within the New England Physiographic Province and altitudes range from sea level in coastal Connecticut to 6,288 feet above sea level at Mount Washington, New Hampshire. Two major aquifer types underlie the study unit unconsolidated glacial deposits and fractured bedrock. The climate generally is temperate and humid, with four distinct seasons. Average annual precipitation ranges from 34 to 65 inches. The study unit has a population of about 4.5 million, which is most highly concentrated in southwestern Connecticut and along the south-central region of the Connecticut River Valley. Surface-water-quality data were screened to provide information about sites with adequate numbers of analyses (50) over sufficiently long periods (1980-90) to enable valid statistical analyses. In order to compare effects of different types of land use on surface-water quality, examination of data required application of several statistical and graphical techniques, including mapping, histograms, boxplots, concentration-discharge plots, trend analysis, and load estimation. Spatial and temporal analysis of surface-water-quality data indicated that, with a single exception, only stations in the Connecticut water-quality network had sufficient data collected over adequately long time periods to use in detailed analyses. Ground-water nutrient and pesticide data were compiled from several Federal and State agencies, primarily the U.S. Geological Survey, U.S. Environmental Protection Agency, and Connecticut Department of Health Services. Nutrient data were available for several thousand wells; nitrite plus nitrate as nitrogen was the most commonly reported constituent. Most wells with nutrient data are in Massachusetts and Connecticut. Relative to nutrient data in ground and surface water, pesticide data are less common. Pesticide data were available for slightly more than 200 surface-water sites and less than 500 wells; about 95 percent of the wells are completed in stratified-drift or till aquifers. Data for 81 pesticide compounds were available in various data bases. 2,4-D and silvex were the most commonly detected herbicides in surface water and dieldrin and diazinon were the most commonly detected insecticides. Most surface-water pesticide samples and detections are from bed sediment, but much of the data are not recent. Ethylene dibromide (EDB), a soil fumigant used in tobacco farming was detected in 268 wells in a 50 square-mile area of north-central Connecticut; EDB contamination also was detected in wells in Massachusetts. Atrazine, an herbicide commonly used in corn farming, commonly was detected in wells installed in tilled agricultural fields. Corn herbicides were commonly detected in the northern part of the study unit, although the sampling has been less frequent than in the southern part of the study unit. Pesticides were seldom detected in public-supply wells in Connecticut. Urban sites with relatively high population densities and high concentrations of dischargers were characterized by having the highest nutrient concentrations and loads when adjusted for differences in drainage area or population. Particularly, the Pequabuck, Naugatuck, and Quinnipiac River Basins were characterized by high nutrient concentrations median total nitrogen concentrations ranged from 3.3 to 4.2 mg/L (milligrams per liter) and median total phosphorus concentrations ranged from 0.42 to 0.8 mg/L. In contrast, the predominantly forested and low density residential land-use sites, such as Saugatuck and Salmon River Basins, were characterized by low nutrient concentrations median total nitrogen ranged from 0.50 to 0.60 mg/L and median total phosphorus concentrations ranged from 0.01 to 0.02 mg/L. Estimated total nitrogen loadings in median discharge years ranged from 940 kilograms per square mile at the Salmon River near East Hampton, Conn., to 5,800 kilograms per square mile at the Naugatuck River at Beacon Falls, Conn. Water quality, in terms of nutrient concentrations and areally adjusted loadings, for sites with large drainage basins integrating a wide variety of land-use categories fell between the extremes of the urban and forested sites total nitrogen was 1,400 kilograms per square mile per year at the Connecticut River at Thompsonville, Conn. Nitrate concentrations in ground water occasionally exceeded the safe drinking-water standard of 10 mg/L as nitrogen. The greatest number of detections exceeding the standard, however, were not in public-water supplies but in shallow observation wells in agricultural settings (the most frequently sampled type of well). None of the public-supply wells in Massachusetts exceeded the standard. Although nitrate concentrations for Vermont and New Hampshire generally were low, few data were available and those were seldom reported on the basis of drainage basin, making analysis difficult. Trend analysis indicated that flow-adjusted concentrations of total and dissolved phosphorus generally decreased during the period of analysis, however, total nitrogen did not change substantially. Decreases in ammonia concentrations with time were usually accompanied by increases in nitrate, suggesting improvements in sewage treatment. The lack of adequate data from more or less exclusively agricultural areas points to the need for further study of the effects of fanning on surface-water quality in the study unit. Furthermore, additional information is needed on the rates, transformations, and movements of nutrients and other materials through and between the aquatic and terrestrial components of the study unit.

Connecticut, Massachusetts, New Hampshire, Quebec,↗
USGS1997

Stream habitat characteristics of fixed sites in the western Lake Michigan drainages, Wisconsin and Michigan, 1993-95

Habitat characteristics of 11 fixed sites in the Western Lake Michigan Drainages were examined by the U.S. Geological Survey from 1993 through 1995 as part of the ecological assessment of the National Water-Quality Assessment Program. Evaluation of habitat consisted of more than 75 measurements at three spatial levels: drainage basin, stream segment between major tributaries (length from 1 to 14 kilometers), and stream reach (approximately 150 meters). The 11 fixed sites consisted of 8 "indicator" sites with drainage basins that differ in bedrock type, surficial deposits, and land use; and 3 "integrator" sites with drainage basins that contain a mixture of bedrock type, surficial deposits, and land use. Spatial and temporal variations in habitat characteristics are described and compared. Comparisons are limited to indicator sites except for comparisons amongbasin characteristics, which include all fixed sites. Two habitat classification schemes used in Wisconsin and Michigan were used to rank the quality of habitat in indicator streams. Reach-level data were collected at two additional reaches at three of the indicator sites to assess the representativeness of the reach for overall stream conditions. Although the number of sites is small, statistical analyses indicate that spatial distribution of several characteristics can be related to land use, geology, topography, and width of the riparian zone. Land use and geology, in combination, appeared to be important factors in controlling flood magnitudes. Annual mean flow was correlated with basin shape and drainage density and low flow was correlated with permeability of soils in the basin. At the reach level, a wide variety of characteristics were observed at the eight indicator sites, with many of the characteristics significantly different between sites. Spatial differences in some reach characteristics can be attributed to the percentage of agriculture in the drainage basin, type of surficial deposits, and width of the riparian zone. Temporal variability in width, depth, and velocity can be attributed to variable flow conditions; whereas temporal variability in streambank measurements are attributed to problematic identification of the boundary between the flood plain and streambanks. Data from multiple-reach sites indicate that the primary reach adequately represented the variability found within the stream segment for depth, streambank stability index, and canopy angle. However, velocity, dominant substrate type, embeddedness, streambank height, streambank angle, and streambank vegetative stability differed among the multiple reaches at one or more of the three sites. Correlation analyses of habitat characteristics with median concentrations of four nutrients, pH, and specific conductance indicates that dissolved nitrate plus nitrite concentrations are related to percentage of agriculture in the basin and fine-grained sediment deposition in the reach. Geology and land use appear to be major influences on pH, but their influence on specific conductance, although expected, was not confirmed in this study. Habitat evaluation scores at the eight indicator sites ranged from poor to good. Scores were correlated to the percentage of agricultural or urban land in the drainage basins, width of the riparian zone, and streambank stability index. Results from this study illustrate the need for collection of habitat data at multiple scales along with water-chemistry data for determining major influences on distribution of aquatic communities. These results also indicate the importance of collecting land use, geological, and geomorphic information at the drainage-basin level to adequately describe how natural and human factors influence local aquatic habitat conditions.

Michigan, Wisconsin↗
USGS1996

Detailed study of water quality, bottom sediment, and biota associated with irrigation drainage in the Klamath Basin, California and Oregon, 1990-92

The effect of irrigation drainage on the water quality and wildlife of the Klamath Basin in California and Oregon was evaluated during 1990-92 as part of the National Irrigation Water Quality Program of the U.S. Department of the Interior. The study focused on land serviced by the Bureau of Reclamation Klamath Project, which supplies irrigation water to agricultural land in the Klamath Basin and the Lost River Basin. The Tule Lake and Lower Klamath National Wildlife Refuges, managed by the U.S. Fish and Wildlife Service, are in the study area. These refuges provide critical resting and breeding habitat for waterfowl on the Pacific flyway and are dependent on irrigation drainwater from upstream agriculture for most of their water supply. Water-quality characteristics throughout the study area were typical of highly eutrophic systems during the summer months of 1991 and 1992. Dissolved-oxygen concentrations and pH tended to fluctuate each day in response to diurnal patterns of photosynthesis, and frequently exceeded criteria for protection of aquatic organisms. Nitrogen and phosphorus concentrations were generally at or above threshold levels characteristic of eutrophic lakes and streams. At most sites the bulk of dissolved nitrogen was organically bound. Elevated ammonia concentrations were common in the study area, especially downstream of drain inputs. High pH of water increased the toxicity of ammonia, and concentrations exceeded criteria at sites upstream and downstream of irrigated land. Concentrations of ammonia in samples from small drains on the Tule Lake refuge leaseland were higher than those measured in the larger, integrating drains at primary monitoring sites. The mean ammonia concentration in leaseland drains [1.21 milligrams per liter (mg/L)] was significantly higher than the mean concentration in canals delivering water to the leaseland fields (0.065 mg/L) and higher than concentrations reported to be lethal to Daphnia magna (median lethal concentration of 0.66 mg/L). Dissolved-oxygen concentrations also were lower, and Daphnia survivability measured during in situ bioassays was correspondingly lower in the leaseland drains than in water delivery canals. In static laboratory bioassays, water samples collected at the primary monitoring sites caused toxicity in up to 78 percent of Lemna minor tests, in up to 49 percent of Xenopus laevis tests, in 17 percent and 8 percent of Hyalella azteca and Pimephales promelas tests, respectively, and 0 percent in Daphnia magna tests. In situ exposure at the sites caused mortality in more than 83 percent of Pimephales tests and in more than 41 percent of Daphnia and Hyalella tests. Much of the observed toxicity appears to have been caused by low dissolved oxygen, high pH, and ammonia. Although water in the study area was toxic to a variety of organisms, no statistically significant differences in the degree of toxicity between sites were observed above or below irrigated agricultural land in any of the bioassays. Pesticides were frequently detected in water samples collected at the monitoring sites during the 1991 and 1992 irrigation seasons. Among the most frequently detected compounds were the herbicides simazine, metribuzin, EPTC, and metolachlor and the insecticide terbufos. All the insecticides detected were at concentrations substantially below acute toxicity values reported for aquatic organisms. The herbicide acrolein has been used extensively in the basin to manage aquatic plant growth in irrigation canals and drains. The concentration of acrolein was monitored in a canal near Tule Lake after an application in order to evaluate the potential for the pesticide to be transported to refuge waters. Although acrolein concentrations were toxic to fish in the channels adjacent to Tule Lake, very little of the canal water entered the refuge during the monitoring period. Organochlorine pesticide concentrations in 25 surficial sediment samples collected in 1990 were below baseline levels commonly found in soils and sediment. Seventeen sediment samples were analyzed for chlorophenoxy acid herbicides and two samples were analyzed for organophosphorus and carbamate insecticides in 1992. No pesticides were detected in any of these samples. Residues of the trace elements selenium, mercury, and arsenic in algae, invertebrates, fish, and avian eggs revealed no bioaccumulation problems. Concentrations of organochlorine compounds, especially of p,p' DDE, were associated with a mean 11-percent eggshell thinning in white-faced ibis. However, ibis populations appear to be increasing, and some eggs of ibis were relatively low in DDE concentration. DDE concentrations in eggs of western grebes were not as high as in the eggs of ibis. Concentrations and types of organochlorine compounds detected in grebe and ibis eggs were highly variable, indicating that the birds were exposed to these compounds outside the basin. Fish and invertebrates inhabiting drainwater were representative of pollution-tolerant species assemblages. The aquatic communities retained little of their historic ecological structure. Extensive hydrologic modifications and hypereutrophic conditions in Klamath Basin waterways have degraded the quality of aquatic habitat and altered aquatic communities.

California, Oregon↗
USGS1996

Environmental setting and factors that affect water quality in the Georgia-Florida Coastal Plain study unit

The Georgia-Florida Coastal Plain study unit covers an area of nearly 62,000 square miles in the southeastern United States, mostly in the Coastal Plain physiographic province. Land resource provinces have been designated based on generalized soil classifications. Land resource provinces in the study area include: the Coastal Flatwoods, the Southern Coastal Plain, the Central Florida Ridge, the Sand Hills, and the Southern Piedmont. The study area includes all or parts of seven hydrologic subregions: the Ogeechee-Savannah, the Altamaha- St.Marys, the Suwannee, the Ochlockonee, the St. Johns, the Peace-Tampa Bay, and the Southern Florida. The primary source of water for public supply in the study area is ground water from the Upper Floridan aquifer. In 1990, more than 90 percent of the 2,888 million gallons per day of ground water used came from this aquifer. The population of the study area was 9.3 million in 1990. The cities of Jacksonville, Orlando, St. Petersburg, Tallahassee, and Tampa, Florida, and parts of Atlanta and Savannah, Georgia, are located in the study area. Forest and agricultural areas are the most common land uses in the study area, accounting for 48 percent and 25 percent of the study area, respectively. Climatic conditions range from temperate in Atlanta, Georgia, where mean annual temperature is about 61.3 degrees Fahrenheit, to subtropical in Tampa, Florida, where mean annual temperature is about 72.4 degrees Fahrenheit. Long-term average precipitation (1961-90) ranges from 43.9 inches per year in Tampa, Florida, and 44.6 in Macon, Georgia, to 65.7 inches per year in Tallahassee, Florida. Floods in the study area result from frontal systems, hurricanes, tropical storms, or severe thunderstorms. Droughts are not common in the study area,especially in the Florida part of the study area due to extensive maritime exposure. The primary physical and cultural characteristics in the study area include physiography, soils and land resource provinces, geologic setting, ground-water systems, surface- water systems, climate, floods, droughts, population, land use, and water use. Factors affecting water quality in the study area are land use (primarily urban and agricultural land uses), water use in coastal areas, hydrogeology, ground-water/surface-water interaction, geology, and climate. Surface-water quality problems in urban areas have occurred in the Ogeechee, Canoochee, Ocmulgee, St. Marys, Alapaha, Withlacoochee (north), Santa Fe, Ochlockonee, St. Johns, and Oklawaha Rivers and include nitrogen and phosphorus loading, low dissolved oxygen, elevated bacteria, sediment, and turbidity, and increased concentrations of metals. In agricultural areas, surface-water quality problems include elevated nitrogen and phosphorus concentrations, erosion, and sedimentation and have occurred in the Ocmulgee, St. Marys, Santa Fe, Ochlockonee, St. Johns, Oklawaha, Withlacoochee (South), Hillsborough, and Alafia Rivers. Ground water-quality problems such as saltwater intrusion have occurred mostly in coastal areas and were caused by excessive withdrawals.

Florida, Georgia↗
USGS1996

Influences of environmental settings on aquatic ecosystems in the Apalachicola-Chattahoochee-Flint River basin

The watershed boundary of the Apalachicola-Chattahoochee-Flint (ACF) River basin defines an aquatic ecosystem whose water quality is the result of complex interactions of natural and human influences on land and water resources. Topics relating to the basin's environmental setting-its physical, biological, and cultural characteristics-are summarized to provide an understanding of factors that influence water quality and the health of aquatic ecosystems. The ACF River basin lies partly in southwestern Georgia, southeastern Alabama, and northwestern Florida and covers 19,800 square miles in the Blue Ridge, the Piedmont, and the Coastal Plain Provinces. The basin includes the drainages of the Chattahoochee River and the Flint River, which meet to form the Apalachicola River. The Apalachicola River flows into the Gulf of Mexico at Apalachicola Bay. Basin hydrology and water quality are influenced by 16 mainstem reservoirs, 13 of which are on the Chattahoochee River. Ground water in the basin is contained in six aquifers-the surficial aquifer system, the Floridan aquifer system, the Claiborne aquifer, the Clayton aquifer, the Providence aquifer, and the crystalline-rock aquifer. Physiography, climate, and hydrology of the ACF River basin provide natural conditions that support a rich and abundant diversity of plants and animals. Although most of the ACF River basin has been altered by human activities, the basin's environment is noteworthy for its remaining biological diversity and the role it plays in sustaining biological productivity in Apalachicola Bay. The Bay produces 90 percent of Florida's and 13 percent of the Nation's oyster harvest; and functions as a nursery for penaeid shrimp, blue crabs, and a variety of fin fish. The diversity of the basin's aquatic fauna is noteworthy because the basin is home to (1) the largest number of fish species among Gulf Coast drainages east of the Mississippi River, (2) the largest assemblage of freshwater fish in Florida, (3) the largest number of mollusc species among western Florida drainages, and (4) the highest species density of amphibians and reptiles on the continent north of Mexico. Population of the ACF River basin in 1990 was estimated at 2.6 million. Nearly 90 percent of the total population lived in Georgia, and nearly 60 percent lived in the Metropolitan Atlanta area. The 1990 basin population is projected to increase by 15 percent to 3.0 million by the year 2000, and by 30 percent to 3.4 million by 2010. The largest increases in populations are projected for the Metropolitan Atlanta area. In 1972-76, approximately 59 percent of the basin was covered by forest, 29 percent was agricultural, 5 percent was wetland, 4 percent was urban, and 3 percent was water or barren land. Most of the original land cover of the basin has been transformed by human activity. Timber is the basin's largest cash crop and most forests consist of second-growth stands or large acreages of planted pine. The dominant agricultural land use in the Piedmont Province is pasture and confined feeding for dairy, livestock, and poultry production. Row-crop agriculture, orchards, and silviculture are most common in the Coastal Plain Province. The top five crops in order from most to least acres harvested in 1990 were peanuts, corn, soybeans, wheat, and cotton. The water in the basin is used for public and industrial supply, irrigation, power generation, navigation, and recreation. Although most public-supply withdrawals in the Blue Ridge and Piedmont Provinces are from surface-water sources, with the exception of counties near or immediately below the Fall Line, all publicly supplied water in the Coastal Plain is withdrawn from ground-water sources. Ground water supplied 18 percent of the basin's population served by public supply. Total water withdrawn in the ACF River basin in 1990 was 2,098 million gallons per day (Mgal/d), of which Georgia withdrew 82 percent and Florida and Alabama each withdrew 9 percent. Power generation is the single largest water use. Sixteen of the basin's 22 power generating plants are located along the mainstem of the Chattahoochee River. The U.S. Army Corps of Engineers maintains a navigation channel from the mouth of the Apalachicola River to Columbus, Ga., on the Chattahoochee River and to Bainbridge, Ga., on the Flint River. Water quality in the basin is influenced by the operation of 137 municipal wastewater-treatment facilities. In 1990, 354 Mgal/d of municipal wastewater was discharged within the ACF River basin. Eighty-eight percent of the wastewater was discharged into the Chattahoochee River basin, 10.6 percent into the Flint River basin, and 1.4 percent into the Apalachicola River basin. Two-thirds of the 938 stream miles in the Georgia portion of the ACF River basin having water quality that does not meet or only partially meets the designated-use criteria in the Chattahoochee River basin. The Chattahoochee River is the most heavily-used water resource both in the ACF River basin and in Georgia. Urban runoff or unknown nonpoint sources are cited as the causes of water-quality regulations in 72 percent of violations. The remaining causes primarily are combined sewer overflows in the Atlanta area, and discharges from municipal or industrial treatment facilities with inadequate treatment capabilities or operational deficiencies.

Alabama, Florida, Georgia↗
USGS1996

Analysis of nutrients in the surface waters of the Georgia–Florida Coastal Plain study unit, 1970–91

During the early phase of the Georgia-Florida National Water Quality Assessment study, existing information on nutrients was compiled and analyzed in order to evaluate the nutrient concentrations within the 61,545 square mile study unit. Evaluation of the nutrient concentrations collected at surface-water sites between October 1, 1970, and September 30, 1991, utilized the environmental characteristics of land resource provinces, land use, and nonpoint and point-source discharges within the study unit. Long-term trends were investigated to determine the temporal distribution of nutrient concentrations. In order to determine a level of concern for nutrient concentrations, the U.S. Environmental Protection Agency (USEPA) guidelines were used: (1) for nitrate concentrations, the maximum contaminant level in public-drinking water supplies (10 mg/L); (2) for ammonia concentrations, the chronic exposure of aquatic organisms to un-ionized ammonia (2.1 mg/L); (3) for total-phosphorus concentrations, the recommended concentration in flowing water to discourage excessive growth of aquatic plants (0.1 mg/L); and (4) for kjeldahl concentrations, however, no guidelines were available. For sites within the 10 major river basins, median nutrient concentrations were enerally below USEPA guidelines, except for total-phosphorus concentrations where 45 percent of the medians exceeded the guideline. The only median ammonia concentration that exceeded the guideline occurred at the Swift Creek site (3.4 mg/L), in the Suwannee River basin, perhaps due to wastewater discharges. For all sites within the Withlacoochee, Aucilla, and St. Marys River basins, median concentrations of nitrate, ammonia, and total phosphorus were below the USEPA guidelines. Nutrient data at each monitoring site within each major basin were aggregated for comparisons of median nutrient concentrations among major basins. The Ochlockonee and Hillsborough River basins had the highest median nutrient concentrations, the Aucilla River basin had the lowest. Median concentrations of nitrate and ammonia among all major basins were below USEPA guidelines. The median total-phosphorus concentrations for the following river basins exceeded the USEPA guideline: Hillsborough, St. Johns, Suwannee, Ochlockonee, Satilla, Altamaha, and Ogeechee. Although nutrient concentrations within the study unit were low, long-term increasing trends were found in all four nutrients. All 18 study-unit wide nitrate trends had increasing slopes ranging from less than 0.01 to 0.07 (mg/L)/yr. The range in slope for the 13 ammonia trends was -0.03 to 0.01 (mg/L)/yr with 6 increasing trends in the northern part of the study unit. Of the 17 total-phosphorus trends found in the study unit, 10 were found at sites where the median concentration exceeded the USEPA guideline. At these 10 sites, 4 sites had increasing trends with slopes ranging from less than 0.01 to 0.07 (mg/L)/yr, 5 sites had decreasing trends with slopes ranging from -0.01 to -0.24 (mg/L)/yr, and one site showed a seasonal concentration trend. Median nutrient concentrations were significantly different among the four land resource provinces: Southern Piedmont, Southern Coastal Plain, Coastal Flatwoods, and Central Florida Ridge. As a result, nutrient concentrations among basins with similar nutrient inputs but located within different land resource provinces are not expected to be the same due to differences in the combination of factors such as soil permeability, runoff rates, and stream channel slopes. This concept is an important consideration in designing a surface-water quality network within the study area. For the most part, the Coastal Flatwoods showed the lowest median nutrient concentrations and the Southern Coastal Plain had the highest median nutrient concentrations. Lower median nitrate concentrations in surface-water basins were associated with the forest/wetland land-use category and higher median concentrations of nitrate and ammonia with the urban category when land-use percentages were classified into four land-use categories (agriculture, forest/wetland, mixed, and urban). These results were reasonable based on expected high nutrient inputs from urban areas and low inputs from forested and wetland areas. However, the lack of association between high nutrient concentrations and the agricultural land-use category was not expected since high nutrient inputs are generally needed for agriculture production.

Florida, Georgia↗
USGS1996

Nutrient sources and analysis of nutrient water-quality data, Apalachicola-Chattahoochee-Flint River basin, Georgia, Alabama, and Florida, 1972-90

In 1991, the U.S. Geological Survey began full-scale implementation of the National Water-Quality Assessment (NAWQA) program. One of the initial tasks of the NAWQA program is to compile and evaluate existing data from individual study units. Available nutrient data from 1972 through 1990 water years were used to estimate nutrient sources to the Apalachicola–Chattahoochee–Flint (ACF) River basin and describe the presence, distribution, and transport of nutrients in surface and ground waters. In 1990, about 2,500 tons of nitrogen and 1,100 tons of phosphorus were discharged as point-source loads by 127 municipal wastewater-treatment facilities (WWTF). Nonpoint-source inputs, an unknown percentage of which entered the hydrologic system, included about 120,000 tons of nitrogen and 28,000 tons of phosphorus from animal manure; 82,000 tons of nitrogen and 20,000 tons of phosphorus applied as fertilizer; and 24,000 tons of nitrogen from atmospheric deposition. Estimates of nutrient input to the ACF River basin were not made for natural sources and for the following anthropogenic sources: industrial-wastewater effluent; storm drains; sanitary and combined sewer outflows; and runoff from agricultural, urban, and suburban areas. Nutrient outflow from the Apalachicola River into Apalachicola Bay, Fla., was about 13 percent of estimated nitrogen sources and about 3 percent of estimated total-phosphorus sources in the ACF River basin. For 1972–90, nutrient concentrations in surface water were high enough to warrant concerns about accelerated eutrophication based on total-phosphorus concentrations and to warrant concerns intermittently about toxicity to fish based on dissolved-ammonia concentrations downstream of wastewater-treatment outfalls from Metropolitan Atlanta and LaGrange, Ga. Many improvements to the water quality of the Chattahoochee and Flint Rivers in the 1980’s and early 1990’s can be directly attributed to improvements in WWTF, legislation directed at decreasing point-source loads of phosphorus, and changes in locations of wastewater-treatment outfalls. However, limited data indicate that nonpoint-source inputs increased upstream of Atlanta and in the Chipola River watershed. Significant increases in nutrient concentrations, loads, and yields occurred from upstream to downstream of the metropolitan areas of Atlanta, Ga.; Columbus, Ga., and Phenix City, Ala.; and Albany, Ga. The highest mean-annual yields estimated in the ACF River basin for total nitrogen (2.9 tons per square mile (tons/mi 2 )), total-inorganic nitrogen (2.0 tons/mi 2 ), dissolved ammonia (1.1 tons/mi 2 ), and total phosphorus (0.75 tons/mi 2 ) were downstream of Atlanta. Most significant trends in nutrient-concentration data from 1980–90 in the Chattahoochee River and the Middle and Lower Flint River basins were increasing, except dissolved ammonia which decreased at several sampling sites in reaches downstream of Atlanta, Columbus and Phenix City, and Albany. At sampling sites on the Chattahoochee and Flint Rivers downstream of Atlanta and Albany, decreasing trends in dissolved-ammonia concentration and increasing trends in dissolved-nitrate concentration were the result of improved wastewater treatment at WWTF. Dissolved-ammonia concentrations decreased and dissolved-nitrate concentrations increased along river reaches downstream of wastewater-treatment facility outfalls for Atlanta and Albany because of nitrification of ammonia to nitrate. Increasing trends in total-phosphorus concentrations are an accurate representation of data for the period 1980–90. However, legislated restrictions on the use of phosphate detergents and improvements to WWTF in the late 1980’s and early 1990’s, resulted in substantial reductions of phosphorus concentrations in wastewater effluent and in rivers at many locations in the 1990’s. Reservoirs affect nutrient transport because of uptake by phytoplankton and aquatic plants, denitrification,and accumulation of phosphorus associated with sediment in reservoirs. Yields of total-inorganic nitrogen, dissolved ammonia, dissolved nitrate, and total phosphorus decreased between sampling sites upstream and downstream of four reservoirs on the Chattahoochee River. The only exception was the yield of dissolved ammonia increased slightly from upstream to downstream of Lake Sidney Lanier. Much of the nutrient load in the Chattahoochee River downstream of Atlanta is utilized by algae or settles out primarily in West Point Lake, and to a lesser extent, in Lake Harding and Walter F. George Reservoir. In general, the Flint River arm of Lake Seminole had significantly higher concentrations of nutrients than the Chattahoochee River arm of Lake Seminole, which may be the result of the large percentage of the Middle and Lower Chattahoochee River in backwater from reservoirs, the absence of reservoirs on the Flint River downstream of Albany until Lake Seminole, and nonpoint-source inputs of nutrients from intensively farmed areas in the Lower Flint River basin. Decreases in dissolved-ammonia, dissolved-nitrate, and total-phosphorus concentrations in reservoirs and backwater along the Chattahoochee River from West Point Lake to Lake Seminole during summer months are related to the seasonality of phytoplankton production. The Chipola River had the highest yields of dissolved nitrate (1.2 tons/mi 2 ) estimated in the ACF River basin. Estimated loads of dissolved nitrate increased fairly steadily from 500 to 1,500 tons per year from 1972–90. These factors strongly suggest an agricultural nonpoint source of elevated dissolved-nitrate concentrations from increased irrigated agriculture and fertilizer applications in the Chipola River watershed. Analyses of nutrients in ground water within the ACF River basin for 1972–90 water years were restricted because of limited available data. The distribution of nitrate concentrations in the ACF River basin for 1972–90 water years included 10 percent of wells and 6 percent of springs with concentrations that probably have elevated nitrate concentrations (3.1 to 10 milligrams per liter (mg/L)), and 1 percent of wells with median nitrate concentrations exceeding the maximum contaminant level of 10 mg/L. Dissolved-nitrate concentrations were significantly lower in the Providence aquifer than in the Floridan aquifer system and the crystalline-rock aquifers. Dissolved-nitrate concentrations in wells used for public supply were significantly lower than in wells used for domestic use or unused wells.

Alabama, Florida, Georgia↗
USGS1996

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico, and Texas: Shallow ground-water quality of a land-use area in the San Luis Valley, south-central Colorado, 1993

This report describes the quality of shallow ground water in an agricultural area in the San Luis Valley, Colorado, and discusses how natural and human factors affect the quality of shallow ground water. Thirty-five wells were installed, and water samples were collected from these wells and analyzed for selected dissolved common constituents, nutrients, trace elements, radionuclides, and synthetic organic compounds. The San Luis Valley is a high intermontane valley that is partially drained by the Rio Grande. The San Luis Valley land-use study area was limited to a part of the valley where the depth to water is generally less than 25 feet. The area where the 35 monitor wells were installed was further limited to the part of the study area where center-pivot overhead sprinklers are used to irrigate crops. Precipitation, runoff from adjacent mountainous areas, and ground-water inflow from the adjacent mountainous areas are the main sources of water to the aquifers in the San Luis Valley. Discharge of water from the shallow, unconfined aquifer in the valley is mainly from evapotranspiration. The dominant land use in the San Luis Valley is agriculture, although nonirrigated land and residential land are interspersed with agricultural land. Alfalfa, native hay, barley, wheat, potatoes, and other vegetables are the main crops. Dissolved-solids concentrations in shallow ground water sampled ranged from 75 to 1,960 milligrams per liter. The largest median concentration of cations was for calcium, and the largest median concentration of anions was for bicarbonate in shallow ground water in the San Luis Valley. Calcium concentrations ranged from 7.5 to 300 milligrams per liter, and bicarbonate concentrations ranged from 28 to 451 milligrams per liter. Nitrite plus nitrate concentrations ranged from less than 0.1 to 58 milligrams per liter as N; water from 11 wells had nitrite plus nitrate concentrations greater than 10 milligrams per liter as N. With the exception of the following trace elements--aluminum, barium, iron, manganese, molybdenum, and uranium--the concentrations of trace elements were less than 10 micrograms per liter in 90 percent of the samples. All trace-element concentrations measured were below the maximum contaminant levels set by the U.S. Environmental Protection Agency. Five samples exceeded the proposed maximum contaminant level of 0.02 milligram per liter for uranium. All samples collected exceeded the proposed maximum contaminant level for radon-222. The volatile organic compound methyltertbutylether was detected in one sample at a concentration of 0.6 microgram per liter. Of the pesticides analyzed for, one or more were detected in water from 5 of the 35 wells sampled. Metribuzin was the most commonly detected pesticide and was detected in water from three wells at concentrations ranging from an estimated 0.005 to 0.017 microgram per liter. Metolachlor (detected in one sample at a concentration of 0.072 microgram per liter), prometon (detected in one sample at a concentration of 0.01 microgram per liter), and p,p'-DDE (detected in one sample at an estimated concentration of 0.002 microgram per liter) were the other pesticides detected. The U.S. Environmental Protection Agency lifetime health advisory for metolachlor, metribuzin, and prometon is 100 micrograms per liter, which is much larger than the concentrations measured in the shallow ground water sampled for this study. The elevated nitrite plus nitrate concentrations in shallow ground water are indicative of leaching of fertilizers from the land surface. This conclusion is consistent with conclusions made in other investigations of the San Luis Valley.

Colorado↗
USGS1997

Shallow ground-water quality beneath cropland in the Red River of the North Basin, Minnesota and North Dakota, 1993-95

During 1993-95, the agriculture on two sandy, surficial aquifers in the Red River of the North Basin affected the quality of shallow ground water in each aquifer differently. The Sheyenne Delta aquifer, in the western part of the basin, had land-use, hydrogeological, and rainfall characteristics that allowed few agricultural chemicals to reach or remain in the shallow ground water. The Otter Tail outwash aquifer, in the eastern part of the basin, had characteristics that caused significant amounts of nutrients and pesticides to reach and remain in the shallow ground water. Shallow ground water from both aquifers is dominated by calcium, magnesium, and bicarbonate ions. During the respective sampling periods, water from the Sheyenne Delta aquifer was mostly anoxic and water from the Otter Tail outwash aquifer had a median dissolved oxygen concentration of 3.6 mg/L (milligrams per liter). The median nitrate concentration was 0.03 mg/L as nitrogen (mg/L-N) in shallow ground water from the Sheyenne Delta aquifer and 6.1 mg/L-N in that from the Otter Tail outwash aquifer. Of 18 herbicides and 4 insecticides commonly used in the aquifer areas and for which analyses were done, 5 herbicides and 1 herbicide metabolite were detected in the shallow ground water from the Sheyenne Delta aquifer and 8 herbicides and 2 metabolites were detected in that from the Otter Tail outwash aquifer. The total herbicide concentration median was less than the detection limit in shallow ground water from the Sheyenne Delta aquifer and 0.023 μ g/L (micorgrams per liter) in that from the Otter Tail outwash aquifer. Triazine herbicides were the most commonly detected herbicides and were detected at the highest concentrations in the shallow ground water from both study areas. One sample from the Sheyenne Delta aquifer contained a high concentration of picloram. Agricultural chemicals in both aquifers were stratified vertically and their concentration correlated inversely with ground-water age. The highest concentrations of these chemicals and the youngest ground-water ages were at the water table. Concentrations decreased and age increased with water-table depth. Nitrate concentration varied seasonally over one-half an order of magnitude, though concentrations only repeated seasonally in some shallow ground water. Land-use factors that increased nitrate and herbicide concentrations were greater tilled area, chemical application, irrigation, and cropland contiguity. Hydrogeological factors that increased these concentrations were a deeper watertable (higher oxygen concentration and less organic carbon), larger grain-size and degree of sorting of aquifer material (shorter time in the soil zone and aquifer), and fewer sulfur-containing minerals (lignite and pyrite) composing the aquifer. High rainfall, just before sampling of the Sheyenne Delta aquifer, contributed to the relatively low nitrate and pesticide concentrations in the shallow ground water of this aquifer by raising the water table higher into the soil zone, increasing ponded water (increasing biodegradation), preventing some chemical application (flooded fields), and leaching and then displacing nitrate-rich water downward, beneath new recharge. The shallow ground-water quality measured beneath cropland in these land-use study areas covers a large range. The land-use, hydrogeological, and rainfall factors controlling this quality also control shallow ground-water quality in other surficial aquifers in the Red River of the North Basin. Although not used for drinking water, 43% of the shallow ground water from the Otter Tail outwash aquifer was above the U.S. Environmental Protection Agency's nitrate maximum contaminant level of 10 mg/L-N, reducing its potential uses. These high nitrate concentrations do not threaten the Otter Tail outwash aquifer's surface-water bodies with eutrophication however, because significant denitrification occurs beneath riparian wetlands before ground water discharges to surface waters.

Minnesota, North Dakota, South Dakota↗
USGS1997

Nitrate and selected pesticides in ground water of the Mid-Atlantic region

Data from more than 850 sites were compiled and analyzed to document the occurrence of nitrate and pesticides in ground water of the Mid-Atlantic region as part of the Mid-Atlantic Integrated Assessment program of the U.S. Environmental Protection Agency. Only those data collected by the U.S. Geological Survey as part of regional networks between October 1985 and September 1996 (inclusive) were used in the analyses, and the data were examined to ensure analytical results are not biased toward sites at the same location or sites sampled multiple times during this period. Regional data are available for most of the Mid-Atlantic region but large spatial gaps in available data do exist. Nitrate was detected in nearly three-quarters of the samples for which it was analyzed, commonly at levels that suggest anthropogenic sources. Ten percent of samples contained nitrate at concentrations exceeding the Federal Maximum Contaminant Level (MCL) of 10 milligrams per liter as nitrogen. Pesticide compounds (including atrazine, metolachlor, prometon, simazine, and desethylatrazine, an atrazine degradate) were detected in about half of the samples for which they were analyzed, but rarely at concentrations exceeding established MCL?s. The most commonly detected pesticide compounds were desethylatrazine and atrazine. The occurrence of nitrate and pesticides in ground water of the Mid-Atlantic region is related to land cover and rock type. Likely sources of nitrate and pesticides to ground water include agricultural and urban land-use practices; rock type affects the movement of these compounds into and through the ground-water system. Nitrate concentrations in the compiled data set are significantly higher in ground water in agricultural areas than in urban or forested areas, but concentrations in areas of row crops are statistically indistinguishable from those in areas of pastures. Detection frequencies of atrazine, desethylatrazine, and simazine are indistinguishable among urban areas, row crops, and pastures. Prometon was most commonly detected in ground water in urban areas. Ground-water samples from forested areas typically contained the lowest concentrations of nitrate and detection frequencies of pesticides. Concentrations of nitrate and detection frequencies of pesticides were significantly higher in samples from carbonate rocks than in those from any other rock type. Most areas of the Mid-Atlantic region that are underlain by carbonate rocks have been developed for agricultural or urban use and the solution channels that are typical of carbonate rocks allow for relatively rapid transport of surficial contaminants throughout the ground-water system. Nitrate concentrations in unconsolidated aquifers were among the lowest for all rock types, possibly because of denitrification in organic-rich subsoils and shallow sediments.

Water-Resources Investigations Report↗
USGS1997

Water-quality assessment of part of the upper Mississippi River Basin, Minnesota and Wisconsin — Pesticides in streams, streambed sediment, and ground water, 1974-94

Available data on pesticides in streams, streambed sediment, and ground water from Federal, state, and local agencies are reviewed for part of the Upper Mississippi River Basin study unit of the National Water-Quality Assessment Program. The analysis focuses on a smaller study area encompassing 19,500 square miles that includes the Upper Mississippi River Basin from Lake Pepin upstream to sampling stations on the Mississippi River near Royalton, Minnesota, and the Minnesota River near Jordan, Minnesota, and the entire drainage basins of the St. Croix, Vermillion, and Cannon Rivers. Assessment is generally restricted to two groups of pesticides the most frequently detected herbicides and organochlorine insecticides although pesticides rarely or never detected are noted. Herbicides, including alachlor, atrazine, cyanazine, or metolachlor, were detected in every stream sampled except the Kettle River. Streams draining row-crop areas had the most herbicide detections. Atrazine was the most widely detected herbicide, with detections in all streams sampled except the Kettle River. Concentrations of atrazine, metolachlor, and cyanazine were greatest in July and detectable most of the year at very low (parts-per-trillion) concentrations. The herbicides EPTC and trifluralin were never detected, although they were used in amounts equal to or greater than those detected, reflecting the fact that some herbicides are less persistent than others. A small urban stream draining part of the Lake Harriet Watershed in Minneapolis, Minnesota, contained substantial concentrations of pesticides as well. Eighty-five percent of runoff events sampled in this entirely urbanized watershed had detections of herbicides commonly used for residential purposes, and 43 percent of the events had detections of alachlor, atrazine, cyanazine, or metolachlor herbicides used predominantly for agriculture. Pesticide concentrations in urban runoff remained well above detection limits throughout the summer, indicating repeated applications of pesticides. Selected organochlorine insecticides, banned since the 1970's, still were detected in recent streambed-sediment samples. Three insecticides, 4,4'-DDT, heptachlor, and lindane, and their metabolites account for almost two-thirds of the organochlorine insecticides detected. Organochlorine insecticides were detected more frequently in streambed sediment than in streamwater. Detections in both phases were most frequent within or downstream of the Twin Cities metropolitan area, indicating that most of these insecticides originated from the Twin Cities metropolitan area. The most frequently detected herbicides in ground water were the same as those frequently detected in streams. Most detections were found in the sand and gravel aquifers underlying agricultural areas, including the Anoka Sand Plain and Bonanza Valley. Atrazine, deethylatrazine, and deisopropylatrazine were detected most frequently. Detection frequencies of atrazine were extremely variable among the various agencies, ranging from 0 to 66.7 percent, probably as a result of different sampling purposes, well locations, and detection levels. Atrazine and atrazine metabolites were the only pesticides detected in bedrock aquifers, with detections found mainly in the agriculture-dominated southeastern part of the study area where bedrock commonly outcrops near the surface. Thus, most detections of herbicides in ground water were found in environmental settings where ground water is vulnerable to contamination. Atrazine was the only pesticide that equaled or exceeded a maximum contaminant level (of 3.0 micrograms per liter) for drinking water. Two stream samples from a small urban watershed in Minneapolis had atrazine concentrations of 3.6 and 3.8 micrograms per liter, and one ground-water sample had a concentration of 3.0 micrograms per liter. Trace concentrations (less than 0.06 micrograms per liter) of the organochlorine insecticides chlordane, dieldrin, endrin, and heptachlor exceeded chronic freshwater-quality criteria in stream samples from the Mississippi, Minnesota, St. Croix, and Vemillion Rivers in 1981 and 1990.

Minnesota, Wisconsin↗
USGS1997

Occurrence of nitrate, pesticides, and volatile organic compounds in the Kirkwood-Cohansey aquifer system, southern New Jersey

Water samples were collected from a network of 72 shallow monitoring wells to assess the chemical quality of recently recharged ground water in the surficial Kirkwood- Cohansey aquifer system of southern New Jersey. The wells are randomly distributed among agricultural, urban, and undeveloped areas to provide data representative of chemical conditions of ground water underlying each of these land-use settings. Samples were analyzed for nutrients, pesticides, and volatile organic compounds (VOC's). Concentrations of nitrate were highest in agricultural areas, where the U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Level (MCL) of 10 mg/L (milligrams per liter) as nitrogen was exceeded in 60 percent of the samples. Concentrations of nitrate were intermediate in urban areas, where the 10-mg/L concentration was exceeded in only 1 of 44 samples. All concentrations in samples from undeveloped areas were less than 1.0 mg/L. Pesticides and VOC's were frequently detected; however, concentrations were low and rarely exceeded established or proposed USEPA or N.J. Department of Environmental Protection (NJDEP) drinking-water regulations. With the exception of the agricultural pesticide dinoseb, established regulations are at least 2.9 times the maximum concentration for pesticides and at least 5 times the maximum concentration for VOC's reported in the samples from the 72-well network. Investigations by the U.S. Geological Survey (USGS) are ongoing in southern New Jersey to evaluate the (1) presence and concentration of pesticide-degradation byproducts in shallow ground water; (2) presence and movement of nitrate, pesticides, and VOC's in the atmosphere, streams, unsaturated zone, and aquifers; (3) transport and fate of these compounds as they migrate deeper into the aquifer system; and (4) implications of these findings for the integrity of the regional water supply.

New Jersey↗
USGS1998

Water-quality assessment of part of the upper Mississippi River basin, Minnesota and Wisconsin— Ground-water quality in an urban part of the Twin Cities Metropolitan area, Minnesota, 1996

In the spring of 1996, the Upper Mississippi River Basin Study Unit of the National Water-Quality Assessment Program drilled 30 shallow monitoring wells in a study area characterized by urban residential and commercial land uses. The monitoring wells were installed in sandy river-terrace deposits adjacent to the Mississippi River in Anoka and Hennepin Counties, Minnesota, in areas where urban development primarily occurred during the past 30 years. Analyses of sediments collected during well drilling indicated that at most well sites the aquifer materials had relatively high hydraulic conductivities (ranging from 0.01 to 238 feet per day), and relatively low organic carbon contents (0.10 to 41 grams per kilogram), indicating a high susceptibility to leaching of fertilizers and organic substances used on the land surface. Sediment pH values, which can affect leaching of pesticides, were generally alkaline, ranging from 5.1 to 9.6. Ground-water levels ranged from 2.39 to 23.14 feet below land surface, and indicated that shallow ground water flows primarily toward the Mississippi River. Dissolved-oxygen concentrations in water samples from the wells were generally less than 3 milligrams per liter (mg/L) and specific conductances were generally greater than 600 microsiemens per centimeter. Calcium, magnesium, sodium, bicarbonate, chloride, and sulfate were the primary dissolved constituents in the water samples. Sodium and chloride concentrations were generally greater than commonly reported in the region, probably due to leaching of sodium chloride applied to roads during the winter. Most tracemetal concentrations in ground-water samples were less than 10 micrograms per liter (μg/L), but concentrations of iron and manganese commonly exceeded Secondary Maximum Contaminant Levels set by the U.S. Environmental Protection Agency of 300 and 50 μg/L, respectively. Mineral saturation indices indicated that calcite, dolomite, and gypsum were slightly undersaturated in most water samples, and that quartz, and many oxides and hydroxides of iron and manganese were oversaturated in all of the water samples. Concentrations of nitrate nitrogen, the primary nutrient of concern in ground water, ranged from less than 0.05 to 16 mg/L, with a median concentration of 1.4 mg/L. Dissolved phosphorus concentrations ranged from less than 0.01 to 1.5 mg/L in the water samples, with a median concentration of 0.02 mg/L. Water from one well was oversaturated with respect to hydroxyapatite, a phosphatic mineral used as a fertilizer. Pesticide compounds were detected in water samples from 16 wells, but concentrations of those compounds were less than 1.0 μg/L. Prometon, an herbicide commonly used for right-of-way weed control, was detected in water samples from 10 of the wells. Atrazine, and its metabolite deethylatrazine, were detectable in water samples from 6 and 8 wells, respectively. Atrazine is commonly applied to land planted with corn and is detectable in rainfall and air samples in concentrations of less than 1 ng/L in the urban land use study area. Other detected pesticide compounds, which are used in agriculture, right-of-way weed control, or lawn care included: tebuthiuron, EPTC, p , p '-DDE, metolachlor, simazine, bentazon, and bromacil. Volatile organic compounds were detected in water samples from 26 wells, but the concentrations of most of those compounds were less than 1 μg/L. Carbon disulfide, which may be produced by bacteria in soils, was the most commonly detected volatile organic compound in water samples from the wells. Other detected volatile organic compounds included: methyl chloride, acetone, dichlorofluoromethane, tetrahydrofuran, trichlorofluoromethane, methyl iodide, 1,1-dichloroethane, chloroform, toluene, trichloroethane, trichloroethene, cis -1,2-dichloroethene, methylene chloride, bromodichloromethane, benzene, methylisobutylketone, ethyl ether, and tetrachloroethene. Tritium concentrations, analyzed in water samples from 15 of the 30 wells, indicated that shallow ground water has been recharged since the mid-1950's, and that shallow ground water should be affected by urban development that has taken place over the past 40 years. Land uses in the urban land use study area affected the concentrations of some water-quality constituents. Concentrations of nitrate and chloride, and frequencies of detection of pesticides and of volatile organic compounds, were greater in water samples from the surficial sand and gravel aquifer underlying the urban land use study area than in water samples from similar aquifers from part of the Upper Mississippi River Basin National Water-Quality Assessment study unit. Land uses within 500-meter radii of each well were quantified by digitizing overlays of aerial photographs that were verified and updated in the field. Concentrations of magnesium and sulfate were greater in ground water beneath areas of denser residential development, which may be a natural artifact of better drainage and a deeper water table in those areas. Frequencies of detection of some pesticides and volatile organic compounds were greater in water from wells with greater proportions of industrial and transportation land uses. Ground water in areas with less dense residential development, mostly the more recently-developed areas, tended to have greater concentrations of agricultural herbicides and some nutrients probably a relict of previous agricultural land use.

Minnesota↗
USGS1998

National water-quality assessment of the Lake Erie-Lake St. Clair Basin, Michigan, Indiana, Ohio, Pennsylvania, and New York — Environmental and hydrologic setting

The Lake Erie-Lake St. Clair Basin covers approximately 22,300 mi 2 (square miles) in parts of Indiana, Michigan, Ohio, Pennsylvania, and New York. Situated in two major physiographic provinces, the Appalachian Plateaus and the Central Lowland, the basin includes varied topographic and geomorphic features that affect the hydrology. As of 1990, the basin was inhabited by approximately 10.4 million people. Lake effect has a large influence on the temperature and precipitation of the basin, especially along the leeward southeast shore of Lake Erie. Mean annual precipitation generally increases from west to east, ranging from 31.8 inches at Detroit, Mich., to 43.8 inches at Erie, Pa. The rocks that underlie the Lake Erie-Lake St. Clair Basin range in age from Cambrian through Pennsylvanian, but only Silurian through Pennsylvanian rocks are part of the shallow ground-water flow system. The position of the basin on the edge of the Michigan and Appalachian Basins is responsible for the large range in geologic time of the exposed rocks. Rock types range from shales, siltstones, and mudstones to coarse-grained sandstones and conglomerates. Carbonate rocks consisting of limestones, dolomites, and calcareous shales also underlie the basin. All the basin is overlain by Pleistocene deposits- till, fine-grained stratified sediments, and coarse-grained stratified sediments-most of Wisconsinan age. A system of buried river valleys filled with various lacustrine, alluvial, and coarse glacial deposits is present in the basin. The soils of the Lake Erie-Lake St. Clair Basin consist of two dominant soil orders: Alfisols and Inceptisols. Four other soil orders in the basin (Mollisols, Histisols, Entisols, and Spodosols) are of minor significance, making up less than 8 percent of the total area. The estimated water use for the Lake Erie-Lake St. Clair Basin for 1990 was 10,649 Mgal/d (million gallons per day). Power generation accounted for about 77 percent of total water withdrawals for the basin, whereas agriculture accounted for the least water-use withdrawals, at an estimated 38 Mgal/d. About 98 percent of the total water used in the basin was drawn from surface water; the remaining 2 percent was from ground water. Agricultural and urban land are the predominant land covers in the basin. Agriculture makes up approximately 74.7 percent of the total basin area; urban land use accounts for 11.2 percent; forested areas constitute 10.5 percent; and water, wetlands, rangeland, and barren land constitute less than 4.0 percent. The eight principal streams in the basin are the Clinton, Huron, and Raisin Rivers in Michigan, the Maumee, Sandusky, Cuyahoga, and Grand Rivers in Ohio, and Cattaraugus Creek in New York. The Maumee River, the largest stream in the basin, drains 6,609 mi 2 and discharges just under 24 percent of the streamflow from the basin into Lake Erie. Combined, the eight principal streams discharge approximately 54 percent of the surface water from the basin to the Lake Erie system per year. Average runoff increases from west to east in the basin. The glacial and recent deposits comprise the unconsolidated aquifers and confining units within the basin. Yields of wells completed in tills range from 0 to 20 gal/min (gallon per minute), but yields generally are near the lower part of this range. Fine-grained stratified deposits can be expected to yield from 0 to 3 gal/ min, and coarse-grained stratified deposits can yield 0.3 to 2,050 gal/min. Pennsylvanian sandstones can yield more than 25 gal/min, but they generally yield 10 to 25 gal/min. Mississippian sandstones in the basin generally yield 2 to 100 gal/min. The Mississippian and Devonian shales are considered to be confining units; in places, they produce small quantities of water from fractures at or near the bedrock surface. Wells completed in the Devonian and Silurian carbonates yield 25 to 500 gal/min, but higher yields have been reported in several zones.

Indiana, Michigan, New York , Ohio, Pennsylvania↗
USGS1999

Environmental setting and natural factors and human influences affecting water quality in the White River Basin, Indiana

The White River Basin drains 11,349 square miles of central and southern Indiana and is one of 59 Study Units selected for water-quality assessment as part of the U.S. Geological Survey's National WaterQuality Assessment Program. Defining the environmental setting of the basin and identifying the natural factors and human influences that affect water quality are important parts of the assessment. Interrelated natural factors help determine the quality of surface and ground water in a river basin. The White River Basin has a humid continental climate, characterized by well-defined winter and summer seasons. Geologic features in the basin include glaciated and nonglaciated areas; a region of karst geomorphology that is characterized by caves and sinkholes; and a thick, sedimentary bedrock sequence underlying the entire basin. Unconsolidated glacial deposits of clay, silt, sand and gravel cover more than 60 percent of the basin. Soils developed in unconsolidated glacial deposits are typically fertile, naturally or artificially well drained, and farmed. Soils in the unglaciated south-central part of the basin are thin, have low fertility, and are best suited for forest or pasture. Agriculture is the principal land use in the White River Basin. Approximately 70 percent of the basin is used for agriculture, and about 50 percent of the basin is cropland. Corn and soybeans are the major crops. Other significant land uses are forest (22 percent) and urban and residential (7 percent). The population of the basin was 2.1 million in 1990. Water use in the White River Basin totaled 1,284 million gallons per day in 1995, of which 84.5 percent was surface water and 15.5 percent was ground water. Despite the predominant use of surface water, ground water was the primary source of drinking water for approximately 56 percent of the population. The general water chemistry in the White River Basin is determined by natural factors such as soils and geologic materials that water contacts as it moves through the hydrologic system. In the southern part of the basin, bedrock upland areas are dominated by non-carbonate bedrock, thin soils, and high runoff-rainfall ratios. These areas have small chemical concentrations in streamwater. Conversely, in the northern part of the basin where glacial deposits are thick and in the southwestern part of the basin where loess deposits are thick, water has longer periods of time to react with soils and aquifers and to acquire substantial quantities of dissolved constituents. As a result, streams in the till plain and glacial lowland have higher concentrations of most constituents than streams in the unglaciated parts of the basin. Water quality is significantly modified by human influences. Water quality is affected locally by point sources of contamination that include combined-sewer overflows, power-generation-plant cooling stations, and wastewater-treatment-plant effluents that are generally associated with densely populated areas. Water quality is additionally affected by non-point sources of contamination related to agriculture, urban runoff, and mining. Six hydrogeomorphic regions of the White River Basin are delineated on the basis of distinct and relatively homogeneous natural characteristics. These six regions are used in the White River Basin study as a framework for examining the effects of natural factors on water quality in the basin. Bedrock is exposed or near the surface in three hydrogeomorphic regions the bedrock uplands, bedrock lowland and plain, and karst plain; streams and shallow aquifers in these regions are susceptible to contamination, especially in the karst plain, and show rapid response to rainfall. The other three hydrogeomorphic regions the fluvial deposits, till plain, and glacial lowland are in the glaciated part of the basin. Where thick fine-grained unconsolidated sediments are present, primarily in the till plain, ground-water supplies are protected from contamination, and extreme high and low streamflows are moderated.

Indiana↗