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A Holocene record of ocean productivity and upwelling from the northern California continental slope

The Holocene upwelling history of the northern California continental slope is examined using the high-resolution record of TN062-O550 (40.9°N, 124.6°W, 550 m water depth). This 7-m-long marine sediment core spans the last ∼7500 years, and we use it to test the hypothesis that marine productivity in the California Current System (CCS) driven by coastal upwelling has co-varied with Holocene millennial-scale warm intervals. A combination of biogenic sediment concentrations (opal, total organic C, and total N), stable isotopes (organic matter δ 13 C and bulk sedimentary δ 15 N), and key microfossil indicators of upwelling were used to test this hypothesis. The record of biogenic accumulation in TN062-O550 shows considerable Holocene variability despite being located within 50 km of the mouth of the Eel River, which is one of the largest sources of terrigenous sediment to the Northeast Pacific Ocean margin. A key time interval beginning at ∼2900 calibrated years before present (cal yr BP) indicates the onset of modern upwelling in the CCS, and this period also corresponds to the most intense period of upwelling in the last 7500 years. When these results are placed into a regional CCS context during the Holocene, it was found that the timing of upwelling intensification at TN062-O550 corresponds closely to that seen at nearby ODP Site 1019, as well as in the Santa Barbara Basin of southern California. Other CCS records with less refined age control show similar results, which suggest late Holocene upwelling intensification may be synchronous throughout the CCS. Based on the strong correspondence between the alkenone sea surface temperature record at ODP Site 1019 and the onset of late Holocene upwelling in northern California, we suggest that CCS warming may be conducive to upwelling intensification, though future changes are unclear as the mechanisms forcing SST variability may differ.

California↗

Map showing sediment isopachs in the deep-sea basins of the Pacific continental margin, Point Conception to Point Loma

The U.S. Geological Survey conducted a series of cruises, EEZSCAN 84 (EEZ-SCAN 84 Scientific Staff, 1986), to collect reconnaissance data on the newly proclaimed Exclusive Economic Zone (EEZ), the area out to 200 nautical miles from the coastline of the United States. The cruises systematically surveyed the entire conterminous United States west coast EEZ using the Geological Long-Range Inclined Asdic (GLORIA) side-scan sonar, a 160-in 3 airgun seismic-reflection profiler, a 3.5-kHz high-resolution seismic-reflection profiler, a 10-kHz echo sounder, and a proton-precession magnetometer. The nominal trackline spacing throughout the survey was 30 km. Derivative maps of sediment thickness (I-2089-A, I-2090-A, I-2091-A) and depth to basement (I-2089-B, I-2090-B, I-2091-B) in the basins of the west coast EEZ were compiled from both the sonar-image dala and the deep-penetration seismic data obtained on these cruises. Only EEZ-SCAN 84 data were used for the map compilations because available data from other cruises in this region are sparsely located, have poor navigational control, or were obtained with seismic systems that were not powerful enough to resolve oceanic basement. For this map series, sediment thickness and depth to basement were determined only in the deep-ocean basin regions because the seismic system used on the EEZ-SCAN 84 cruises could not resolve oceanic basement beneath the thick sediments of the continental slope. All the data used to compile the maps are presented in the "Atlas of the Exclusive Economic Zone, Western Conterminous United States" (EEZ-SCAN 84 Scientific Staff, 1986). Basement Outcrops GLORIA imagery was used to locate areas of basement outcrop throughout the region. Where possible, sediment thickness on and immediately adjacent to basement outcrops was measured from seismic data. Where there was no bathymetric or seismic control, a seamount peak was assumed to have no sediment cover. A pattern is used on the map to indicate all basement outcrops. Data Reduction Acoustic basement in the basins, invariably oceanic Layer 2, was observed on all of the seismic records. One-way traveltime was measured from the sea floor to acoustic basement. Because the trackline spacing of about 30 km is relatively large compared to the data density along track, we chose to measure the sediment thickness every 0.5 hour or at an interval of approximately 7.5 km. Water depth was measured with a 10-kHz profiler. Depth to basement was calculated using the sea surface as the zero datum and adding the corrected water depth (Carter, 1980) to the sediment thickness. Acoustic travel times were converted to depths by first calculating a regression equation from the interval velocity versus depth data of Connard and others (1984). Their data base comprises a compilation of all available Deep Sea Drilling Project data plus wide-angle refraction data, which were collected in Cascadia Basin west of Oregon and represents the best data set available for the United States west coast EEZ. The regression equation was integrated to determine sediment thickness as a function of one-way traveltime . The resulting equation is z = 1400t + 0 .5t 2 where z is sediment thickness in meters, and t is one-way traveltime in seconds. Sediment thicknesses calculated using this equation were compared to values calculated from the general equation of Carlson and others (1986). Values for sediment thickness calculated by the two equations differed by no greater than 10 percent throughout the range of travel times. Bathymetry The bathymetry is from Chase and others (1981). The bathymetric data were compiled from a variety of sources, and data quality is inconsistent. Because of differences in navigational precision and density of coverage, the bathymetric contours of a feature may be at a different location than the corresponding isopleths derived from the EEZ-SCAN 84 data, or a feature may not be indicated on the bathymetry at all. These situations occur because either the feature is poorly located in the bathymetric data set or, especially in the outer EEZ, the bathymetric data are too sparse to have defined the existence of a feature. Acknowledgments Topographic digital data bases were corrected and verified by Christina Lief. Gerald Evenden developed the computer software system MAPGEN, used to compose this map. Reviews, suggestions, and technical contributions from Edward C. Escowitz and Florence Wong and advice about cartographic design from Will Stettner substantially improved the quality of this map. References Cited Carlson, R.L., Gangi, A.F., and Snow, K.R., 1986, Empirical reflection-traveltime/ depth and velocity/depth functions for the deep-sea sediment column: Journal of Geophysical Research, v. 91, no. B8, p. 8249-8266. Carter, D.J.T., 1980, Echo-sounding correction tables: Taunton, United Kingdom, Hydrographic Department, Ministry of Defence, 150 p. Chase, T.E., Wilde, Pat, Normark, W.R, Miller, C.P., Seekins, B.A., and Young, J.D., 1981, Offshore topography of the Western United States between 32° and 49° North latitudes: U.S. Geological Survey Open-File Report 81-443, scale 1:864,518 at 38° latitude, 2 sheets. Connard, G., Couch, R., Keeling , K., Roy, J., and Troseth, S., 1984, Abyssal plain and continental net-objective sedimentary thicknesses, in Kulm, L.D., and others, eds., Western North America continental margin and adjacent ocean floor off Oregon and Washington, Atlas 1 of Regional Atlas Series, Ocean Margin Drilling Program: Woods Hole, Mass., Marine Science International, sheet 7. EEZ-SCAN 84 Scientific Staff, 1986, Atlas of the Exclusive Economic Zone, Western Conterminous United States: U.S. Geological Survey Miscellaneous Investigations Series I-1792, scale 1:500,000, 152 p. index map for I-2089-A See Also "U.S. Pacific West Coast Field Activities" (Paskevich and others, 2011; http://pubs.usgs.gov/of/2010/1332/htmldocs/pc/pc_overview.html). Paskevich, V.F., Wong, F.L., O?Malley, J.J., Stevenson, A.J., and Gutmacher, C.E., 2011, GLORIA sidescan-sonar imagery for parts of the U.S. Exclusive Economic Zone and adjacent areas: U.S. Geological Survey Open-File Report 2010?1332, available at http://pubs.usgs.gov/of/2010/1332/.

IMAP↗

Map showing depth to basement in the deep-sea basins of the Pacific continental margin, Point Conception to Point Loma

The U.S. Geological Survey conducted a series of cruises, EEZSCAN 84 (EEZ-SCAN 84 Scientific Staff, 1986), to collect reconnaissance data on the newly proclaimed Exclusive Economic Zone (EEZ), the area out to 200 nautical miles from the coastline of the United States. The cruises systematically surveyed the entire conterminous United States west coast EEZ using the Geological Long-Range Inclined Asdic (GLORIA) side-scan sonar, a 160-in 3 airgun seismic-reflection profiler, a 3.5-kHz high-resolution seismic-reflection profiler, a 10-kHz echo sounder, and a proton-precession magnetometer. The nominal trackline spacing throughout the survey was 30 km. Derivative maps of sediment thickness (I-2089-A, I-2090-A, I-2091-A) and depth to basement (I-2089-B, I-2090-B, I-2091-B) in the basins of the west coast EEZ were compiled from both the sonar-image dala and the deep-penetration seismic data obtained on these cruises. Only EEZ-SCAN 84 data were used for the map compilations because available data from other cruises in this region are sparsely located, have poor navigational control, or were obtained with seismic systems that were not powerful enough to resolve oceanic basement. For this map series, sediment thickness and depth to basement were determined only in the deep-ocean basin regions because the seismic system used on the EEZ-SCAN 84 cruises could not resolve oceanic basement beneath the thick sediments of the continental slope. All the data used to compile the maps are presented in the "Atlas of the Exclusive Economic Zone, Western Conterminous United States" (EEZ-SCAN 84 Scientific Staff, 1986). Basement Outcrops GLORIA imagery was used to locate areas of basement outcrop throughout the region. Where possible, sediment thickness on and immediately adjacent to basement outcrops was measured from seismic data. Where there was no bathymetric or seismic control, a seamount peak was assumed to have no sediment cover. A pattern is used on the map to indicate all basement outcrops. Data Reduction Acoustic basement in the basins, invariably oceanic Layer 2, was observed on all of the seismic records. One-way traveltime was measured from the sea floor to acoustic basement. Because the trackline spacing of about 30 km is relatively large compared to the data density along track, we chose to measure the sediment thickness every 0.5 hour or at an interval of approximately 7.5 km. Water depth was measured with a 10-kHz profiler. Depth to basement was calculated using the sea surface as the zero datum and adding the corrected water depth (Carter, 1980) to the sediment thickness. Acoustic travel times were converted to depths by first calculating a regression equation from the interval velocity versus depth data of Connard and others (1984). Their data base comprises a compilation of all available Deep Sea Drilling Project data plus wide-angle refraction data, which were collected in Cascadia Basin west of Oregon and represents the best data set available for the United States west coast EEZ. The regression equation was integrated to determine sediment thickness as a function of one-way traveltime . The resulting equation is z = 1400t + 0 .5t 2 where z is sediment thickness in meters, and t is one-way traveltime in seconds. Sediment thicknesses calculated using this equation were compared to values calculated from the general equation of Carlson and others (1986). Values for sediment thickness calculated by the two equations differed by no greater than 10 percent throughout the range of travel times. Bathymetry The bathymetry is from Chase and others (1981). The bathymetric data were compiled from a variety of sources, and data quality is inconsistent. Because of differences in navigational precision and density of coverage, the bathymetric contours of a feature may be at a different location than the corresponding isopleths derived from the EEZ-SCAN 84 data, or a feature may not be indicated on the bathymetry at all. These situations occur because either the feature is poorly located in the bathymetric data set or, especially in the outer EEZ, the bathymetric data are too sparse to have defined the existence of a feature. Acknowledgments Topographic digital data bases were corrected and verified by Christina Lief. Gerald Evenden developed the computer software system MAPGEN, used to compose this map. Reviews, suggestions, and technical contributions from Edward C. Escowitz and Florence Wong and advice about cartographic design from Will Stettner substantially improved the quality of this map. References Cited Carlson, R.L., Gangi, A.F., and Snow, K.R., 1986, Empirical reflection-traveltime/ depth and velocity/depth functions for the deep-sea sediment column: Journal of Geophysical Research, v. 91, no. B8, p. 8249-8266. Carter, D.J.T., 1980, Echo-sounding correction tables: Taunton, United Kingdom, Hydrographic Department, Ministry of Defence, 150 p. Chase, T.E., Wilde, Pat, Normark, W.R, Miller, C.P., Seekins, B.A., and Young, J.D., 1981, Offshore topography of the Western United States between 32° and 49° North latitudes: U.S. Geological Survey Open-File Report 81-443, scale 1:864,518 at 38° latitude, 2 sheets. Connard, G., Couch, R., Keeling , K., Roy, J., and Troseth, S., 1984, Abyssal plain and continental net-objective sedimentary thicknesses, in Kulm, L.D., and others, eds., Western North America continental margin and adjacent ocean floor off Oregon and Washington, Atlas 1 of Regional Atlas Series, Ocean Margin Drilling Program: Woods Hole, Mass., Marine Science International, sheet 7. EEZ-SCAN 84 Scientific Staff, 1986, Atlas of the Exclusive Economic Zone, Western Conterminous United States: U.S. Geological Survey Miscellaneous Investigations Series I-1792, scale 1:500,000, 152 p. index map for I-2089-A See Also "U.S. Pacific West Coast Field Activities" (Paskevich and others, 2011; http://pubs.usgs.gov/of/2010/1332/htmldocs/pc/pc_overview.html). Paskevich, V.F., Wong, F.L., O?Malley, J.J., Stevenson, A.J., and Gutmacher, C.E., 2011, GLORIA sidescan-sonar imagery for parts of the U.S. Exclusive Economic Zone and adjacent areas: U.S. Geological Survey Open-File Report 2010?1332, available at http://pubs.usgs.gov/of/2010/1332/.

IMAP↗

Map showing sediment isopachs in the deep-sea basins of the Pacific continental margin, Cape Mendocino to Point Conception

The U.S. Geological Survey conducted a series of cruises, EEZSCAN 84 (EEZ-SCAN 84 Scientific Staff, 1986), to collect reconnaissance data on the newly proclaimed Exclusive Economic Zone (EEZ), the area out to 200 nautical miles from the coastline of the United States. The cruises systematically surveyed the entire conterminous United States west coast EEZ using the Geological Long-Range Inclined Asdic (GLORIA) side-scan sonar, a 160-in 3 airgun seismic-reflection profiler, a 3.5-kHz high-resolution seismic-reflection profiler, a 10-kHz echo sounder, and a proton-precession magnetometer. The nominal trackline spacing throughout the survey was 30 km. Derivative maps of sediment thickness (I-2089-A, I-2090-A, I-2091-A) and depth to basement (I-2089-B, I-2090-B, I-2091-B) in the basins of the west coast EEZ were compiled from both the sonar-image dala and the deep-penetration seismic data obtained on these cruises. Only EEZ-SCAN 84 data were used for the map compilations because available data from other cruises in this region are sparsely located, have poor navigational control, or were obtained with seismic systems that were not powerful enough to resolve oceanic basement. For this map series, sediment thickness and depth to basement were determined only in the deep-ocean basin regions because the seismic system used on the EEZ-SCAN 84 cruises could not resolve oceanic basement beneath the thick sediments of the continental slope. All the data used to compile the maps are presented in the "Atlas of the Exclusive Economic Zone, Western Conterminous United States" (EEZ-SCAN 84 Scientific Staff, 1986). Basement Outcrops GLORIA imagery was used to locate areas of basement outcrop throughout the region. Where possible, sediment thickness on and immediately adjacent to basement outcrops was measured from seismic data. Where there was no bathymetric or seismic control, a seamount peak was assumed to have no sediment cover. A pattern is used on the map to indicate all basement outcrops. Data Reduction Acoustic basement in the basins, invariably oceanic Layer 2, was observed on all of the seismic records. One-way traveltime was measured from the sea floor to acoustic basement. Because the trackline spacing of about 30 km is relatively large compared to the data density along track, we chose to measure the sediment thickness every 0.5 hour or at an interval of approximately 7.5 km. Water depth was measured with a 10-kHz profiler. Depth to basement was calculated using the sea surface as the zero datum and adding the corrected water depth (Carter, 1980) to the sediment thickness. Acoustic travel times were converted to depths by first calculating a regression equation from the interval velocity versus depth data of Connard and others (1984). Their data base comprises a compilation of all available Deep Sea Drilling Project data plus wide-angle refraction data, which were collected in Cascadia Basin west of Oregon and represents the best data set available for the United States west coast EEZ. The regression equation was integrated to determine sediment thickness as a function of one-way traveltime . The resulting equation is z = 1400t + 0 .5t 2 where z is sediment thickness in meters, and t is one-way traveltime in seconds. Sediment thicknesses calculated using this equation were compared to values calculated from the general equation of Carlson and others (1986). Values for sediment thickness calculated by the two equations differed by no greater than 10 percent throughout the range of travel times. Bathymetry The bathymetry is from Chase and others (1981). The bathymetric data were compiled from a variety of sources, and data quality is inconsistent. Because of differences in navigational precision and density of coverage, the bathymetric contours of a feature may be at a different location than the corresponding isopleths derived from the EEZ-SCAN 84 data, or a feature may not be indicated on the bathymetry at all. These situations occur because either the feature is poorly located in the bathymetric data set or, especially in the outer EEZ, the bathymetric data are too sparse to have defined the existence of a feature. Acknowledgments Topographic digital data bases were corrected and verified by Christina Lief. Gerald Evenden developed the computer software system MAPGEN, used to compose this map. Reviews, suggestions, and technical contributions from Edward C. Escowitz and Florence Wong and advice about cartographic design from Will Stettner substantially improved the quality of this map. References Cited Carlson, R.L., Gangi, A.F., and Snow, K.R., 1986, Empirical reflection-traveltime/ depth and velocity/depth functions for the deep-sea sediment column: Journal of Geophysical Research, v. 91, no. B8, p. 8249-8266. Carter, D.J.T., 1980, Echo-sounding correction tables: Taunton, United Kingdom, Hydrographic Department, Ministry of Defence, 150 p. Chase, T.E., Wilde, Pat, Normark, W.R, Miller, C.P., Seekins, B.A., and Young, J.D., 1981, Offshore topography of the Western United States between 32° and 49° North latitudes: U.S. Geological Survey Open-File Report 81-443, scale 1:864,518 at 38° latitude, 2 sheets. Connard, G., Couch, R., Keeling , K., Roy, J., and Troseth, S., 1984, Abyssal plain and continental net-objective sedimentary thicknesses, in Kulm, L.D., and others, eds., Western North America continental margin and adjacent ocean floor off Oregon and Washington, Atlas 1 of Regional Atlas Series, Ocean Margin Drilling Program: Woods Hole, Mass., Marine Science International, sheet 7. EEZ-SCAN 84 Scientific Staff, 1986, Atlas of the Exclusive Economic Zone, Western Conterminous United States: U.S. Geological Survey Miscellaneous Investigations Series I-1792, scale 1:500,000, 152 p. See Also "U.S. Pacific West Coast Field Activities" (Paskevich and others, 2011; http://pubs.usgs.gov/of/2010/1332/htmldocs/pc/pc_overview.html). Paskevich, V.F., Wong, F.L., O?Malley, J.J., Stevenson, A.J., and Gutmacher, C.E., 2011, GLORIA sidescan-sonar imagery for parts of the U.S. Exclusive Economic Zone and adjacent areas: U.S. Geological Survey Open-File Report 2010?1332, available at http://pubs.usgs.gov/of/2010/1332/.

IMAP↗

Map showing depth to basement in the deep-sea basins of the Pacific continental margin, Cape Mendocino to Point Conception

The U.S. Geological Survey conducted a series of cruises, EEZSCAN 84 (EEZ-SCAN 84 Scientific Staff, 1986), to collect reconnaissance data on the newly proclaimed Exclusive Economic Zone (EEZ), the area out to 200 nautical miles from the coastline of the United States. The cruises systematically surveyed the entire conterminous United States west coast EEZ using the Geological Long-Range Inclined Asdic (GLORIA) side-scan sonar, a 160-in 3 airgun seismic-reflection profiler, a 3.5-kHz high-resolution seismic-reflection profiler, a 10-kHz echo sounder, and a proton-precession magnetometer. The nominal trackline spacing throughout the survey was 30 km. Derivative maps of sediment thickness (I-2089-A, I-2090-A, I-2091-A) and depth to basement (I-2089-B, I-2090-B, I-2091-B) in the basins of the west coast EEZ were compiled from both the sonar-image dala and the deep-penetration seismic data obtained on these cruises. Only EEZ-SCAN 84 data were used for the map compilations because available data from other cruises in this region are sparsely located, have poor navigational control, or were obtained with seismic systems that were not powerful enough to resolve oceanic basement. For this map series, sediment thickness and depth to basement were determined only in the deep-ocean basin regions because the seismic system used on the EEZ-SCAN 84 cruises could not resolve oceanic basement beneath the thick sediments of the continental slope. All the data used to compile the maps are presented in the "Atlas of the Exclusive Economic Zone, Western Conterminous United States" (EEZ-SCAN 84 Scientific Staff, 1986). Basement Outcrops GLORIA imagery was used to locate areas of basement outcrop throughout the region. Where possible, sediment thickness on and immediately adjacent to basement outcrops was measured from seismic data. Where there was no bathymetric or seismic control, a seamount peak was assumed to have no sediment cover. A pattern is used on the map to indicate all basement outcrops. Data Reduction Acoustic basement in the basins, invariably oceanic Layer 2, was observed on all of the seismic records. One-way traveltime was measured from the sea floor to acoustic basement. Because the trackline spacing of about 30 km is relatively large compared to the data density along track, we chose to measure the sediment thickness every 0.5 hour or at an interval of approximately 7.5 km. Water depth was measured with a 10-kHz profiler. Depth to basement was calculated using the sea surface as the zero datum and adding the corrected water depth (Carter, 1980) to the sediment thickness. Acoustic travel times were converted to depths by first calculating a regression equation from the interval velocity versus depth data of Connard and others (1984). Their data base comprises a compilation of all available Deep Sea Drilling Project data plus wide-angle refraction data, which were collected in Cascadia Basin west of Oregon and represents the best data set available for the United States west coast EEZ. The regression equation was integrated to determine sediment thickness as a function of one-way traveltime . The resulting equation is z = 1400t + 0 .5t 2 where z is sediment thickness in meters, and t is one-way traveltime in seconds. Sediment thicknesses calculated using this equation were compared to values calculated from the general equation of Carlson and others (1986). Values for sediment thickness calculated by the two equations differed by no greater than 10 percent throughout the range of travel times. Bathymetry The bathymetry is from Chase and others (1981). The bathymetric data were compiled from a variety of sources, and data quality is inconsistent. Because of differences in navigational precision and density of coverage, the bathymetric contours of a feature may be at a different location than the corresponding isopleths derived from the EEZ-SCAN 84 data, or a feature may not be indicated on the bathymetry at all. These situations occur because either the feature is poorly located in the bathymetric data set or, especially in the outer EEZ, the bathymetric data are too sparse to have defined the existence of a feature. Acknowledgments Topographic digital data bases were corrected and verified by Christina Lief. Gerald Evenden developed the computer software system MAPGEN, used to compose this map. Reviews, suggestions, and technical contributions from Edward C. Escowitz and Florence Wong and advice about cartographic design from Will Stettner substantially improved the quality of this map. References Cited Carlson, R.L., Gangi, A.F., and Snow, K.R., 1986, Empirical reflection-traveltime/ depth and velocity/depth functions for the deep-sea sediment column: Journal of Geophysical Research, v. 91, no. B8, p. 8249-8266. Carter, D.J.T., 1980, Echo-sounding correction tables: Taunton, United Kingdom, Hydrographic Department, Ministry of Defence, 150 p. Chase, T.E., Wilde, Pat, Normark, W.R, Miller, C.P., Seekins, B.A., and Young, J.D., 1981, Offshore topography of the Western United States between 32° and 49° North latitudes: U.S. Geological Survey Open-File Report 81-443, scale 1:864,518 at 38° latitude, 2 sheets. Connard, G., Couch, R., Keeling , K., Roy, J., and Troseth, S., 1984, Abyssal plain and continental net-objective sedimentary thicknesses, in Kulm, L.D., and others, eds., Western North America continental margin and adjacent ocean floor off Oregon and Washington, Atlas 1 of Regional Atlas Series, Ocean Margin Drilling Program: Woods Hole, Mass., Marine Science International, sheet 7. EEZ-SCAN 84 Scientific Staff, 1986, Atlas of the Exclusive Economic Zone, Western Conterminous United States: U.S. Geological Survey Miscellaneous Investigations Series I-1792, scale 1:500,000, 152 p. See Also "U.S. Pacific West Coast Field Activities" (Paskevich and others, 2011; http://pubs.usgs.gov/of/2010/1332/htmldocs/pc/pc_overview.html). Paskevich, V.F., Wong, F.L., O?Malley, J.J., Stevenson, A.J., and Gutmacher, C.E., 2011, GLORIA sidescan-sonar imagery for parts of the U.S. Exclusive Economic Zone and adjacent areas: U.S. Geological Survey Open-File Report 2010?1332, available at http://pubs.usgs.gov/of/2010/1332/.

IMAP↗

Map showing sediment isopachs in the deep-sea basins of the Pacific Continental Margin, Strait of Juan de Fuca to Cape Mendocino

The U.S. Geological Survey conducted a series of cruises, EEZSCAN 84 (EEZ-SCAN 84 Scientific Staff, 1986), to collect reconnaissance data on the newly proclaimed Exclusive Economic Zone (EEZ), the area out to 200 nautical miles from the coastline of the United States. The cruises systematically surveyed the entire conterminous United States west coast EEZ using the Geological Long-Range Inclined Asdic (GLORIA) side-scan sonar, a 160-in 3 airgun seismic-reflection profiler, a 3.5-kHz high-resolution seismic-reflection profiler, a 10-kHz echo sounder, and a proton-precession magnetometer. The nominal trackline spacing throughout the survey was 30 km. Derivative maps of sediment thickness (I-2089-A, I-2090-A, I-2091-A) and depth to basement (I-2089-B, I-2090-B, I-2091-B) in the basins of the west coast EEZ were compiled from both the sonar-image dala and the deep-penetration seismic data obtained on these cruises. Only EEZ-SCAN 84 data were used for the map compilations because available data from other cruises in this region are sparsely located, have poor navigational control, or were obtained with seismic systems that were not powerful enough to resolve oceanic basement. For this map series, sediment thickness and depth to basement were determined only in the deep-ocean basin regions because the seismic system used on the EEZ-SCAN 84 cruises could not resolve oceanic basement beneath the thick sediments of the continental slope. All the data used to compile the maps are presented in the "Atlas of the Exclusive Economic Zone, Western Conterminous United States" (EEZ-SCAN 84 Scientific Staff, 1986). Basement Outcrops GLORIA imagery was used to locate areas of basement outcrop throughout the region. Where possible, sediment thickness on and immediately adjacent to basement outcrops was measured from seismic data. Where there was no bathymetric or seismic control, a seamount peak was assumed to have no sediment cover. A pattern is used on the map to indicate all basement outcrops. Data Reduction Acoustic basement in the basins, invariably oceanic Layer 2, was observed on all of the seismic records. One-way traveltime was measured from the sea floor to acoustic basement. Because the trackline spacing of about 30 km is relatively large compared to the data density along track, we chose to measure the sediment thickness every 0.5 hour or at an interval of approximately 7.5 km. Water depth was measured with a 10-kHz profiler. Depth to basement was calculated using the sea surface as the zero datum and adding the corrected water depth (Carter, 1980) to the sediment thickness. Acoustic travel times were converted to depths by first calculating a regression equation from the interval velocity versus depth data of Connard and others (1984). Their data base comprises a compilation of all available Deep Sea Drilling Project data plus wide-angle refraction data, which were collected in Cascadia Basin west of Oregon and represents the best data set available for the United States west coast EEZ. The regression equation was integrated to determine sediment thickness as a function of one-way traveltime . The resulting equation is z = 1400t + 0 .5t 2 where z is sediment thickness in meters, and t is one-way traveltime in seconds. Sediment thicknesses calculated using this equation were compared to values calculated from the general equation of Carlson and others (1986). Values for sediment thickness calculated by the two equations differed by no greater than 10 percent throughout the range of travel times. Bathymetry The bathymetry is from Chase and others (1981). The bathymetric data were compiled from a variety of sources, and data quality is inconsistent. Because of differences in navigational precision and density of coverage, the bathymetric contours of a feature may be at a different location than the corresponding isopleths derived from the EEZ-SCAN 84 data, or a feature may not be indicated on the bathymetry at all. These situations occur because either the feature is poorly located in the bathymetric data set or, especially in the outer EEZ, the bathymetric data are too sparse to have defined the existence of a feature. Acknowledgments Topographic digital data bases were corrected and verified by Christina Lief. Gerald Evenden developed the computer software system MAPGEN, used to compose this map. Reviews, suggestions, and technical contributions from Edward C. Escowitz and Florence Wong and advice about cartographic design from Will Stettner substantially improved the quality of this map. References Cited Carlson, R.L., Gangi, A.F., and Snow, K.R., 1986, Empirical reflection-traveltime/ depth and velocity/depth functions for the deep-sea sediment column: Journal of Geophysical Research, v. 91, no. B8, p. 8249-8266. Carter, D.J.T., 1980, Echo-sounding correction tables: Taunton, United Kingdom, Hydrographic Department, Ministry of Defence, 150 p. Chase, T.E., Wilde, Pat, Normark, W.R, Miller, C.P., Seekins, B.A., and Young, J.D., 1981, Offshore topography of the Western United States between 32° and 49° North latitudes: U.S. Geological Survey Open-File Report 81-443, scale 1:864,518 at 38° latitude, 2 sheets. Connard, G., Couch, R., Keeling , K., Roy, J., and Troseth, S., 1984, Abyssal plain and continental net-objective sedimentary thicknesses, in Kulm, L.D., and others, eds., Western North America continental margin and adjacent ocean floor off Oregon and Washington, Atlas 1 of Regional Atlas Series, Ocean Margin Drilling Program: Woods Hole, Mass., Marine Science International, sheet 7. EEZ-SCAN 84 Scientific Staff, 1986, Atlas of the Exclusive Economic Zone, Western Conterminous United States: U.S. Geological Survey Miscellaneous Investigations Series I-1792, scale 1:500,000, 152 p. See Also "U.S. Pacific West Coast Field Activities" (Paskevich and others, 2011; http://pubs.usgs.gov/of/2010/1332/htmldocs/pc/pc_overview.html). Paskevich, V.F., Wong, F.L., O?Malley, J.J., Stevenson, A.J., and Gutmacher, C.E., 2011, GLORIA sidescan-sonar imagery for parts of the U.S. Exclusive Economic Zone and adjacent areas: U.S. Geological Survey Open-File Report 2010?1332, available at http://pubs.usgs.gov/of/2010/1332/.

IMAP↗

Map showing depth to basement in the deep-sea basins of the Pacific continental margin, Strait of Juan de Fuca to Cape Mendocino

The U.S. Geological Survey conducted a series of cruises, EEZSCAN 84 (EEZ-SCAN 84 Scientific Staff, 1986), to collect reconnaissance data on the newly proclaimed Exclusive Economic Zone (EEZ), the area out to 200 nautical miles from the coastline of the United States. The cruises systematically surveyed the entire conterminous United States west coast EEZ using the Geological Long-Range Inclined Asdic (GLORIA) side-scan sonar, a 160-in 3 airgun seismic-reflection profiler, a 3.5-kHz high-resolution seismic-reflection profiler, a 10-kHz echo sounder, and a proton-precession magnetometer. The nominal trackline spacing throughout the survey was 30 km. Derivative maps of sediment thickness (I-2089-A, I-2090-A, I-2091-A) and depth to basement (I-2089-B, I-2090-B, I-2091-B) in the basins of the west coast EEZ were compiled from both the sonar-image dala and the deep-penetration seismic data obtained on these cruises. Only EEZ-SCAN 84 data were used for the map compilations because available data from other cruises in this region are sparsely located, have poor navigational control, or were obtained with seismic systems that were not powerful enough to resolve oceanic basement. For this map series, sediment thickness and depth to basement were determined only in the deep-ocean basin regions because the seismic system used on the EEZ-SCAN 84 cruises could not resolve oceanic basement beneath the thick sediments of the continental slope. All the data used to compile the maps are presented in the "Atlas of the Exclusive Economic Zone, Western Conterminous United States" (EEZ-SCAN 84 Scientific Staff, 1986). Basement Outcrops GLORIA imagery was used to locate areas of basement outcrop throughout the region. Where possible, sediment thickness on and immediately adjacent to basement outcrops was measured from seismic data. Where there was no bathymetric or seismic control, a seamount peak was assumed to have no sediment cover. A pattern is used on the map to indicate all basement outcrops. Data Reduction Acoustic basement in the basins, invariably oceanic Layer 2, was observed on all of the seismic records. One-way traveltime was measured from the sea floor to acoustic basement. Because the trackline spacing of about 30 km is relatively large compared to the data density along track, we chose to measure the sediment thickness every 0.5 hour or at an interval of approximately 7.5 km. Water depth was measured with a 10-kHz profiler. Depth to basement was calculated using the sea surface as the zero datum and adding the corrected water depth (Carter, 1980) to the sediment thickness. Acoustic travel times were converted to depths by first calculating a regression equation from the interval velocity versus depth data of Connard and others (1984). Their data base comprises a compilation of all available Deep Sea Drilling Project data plus wide-angle refraction data, which were collected in Cascadia Basin west of Oregon and represents the best data set available for the United States west coast EEZ. The regression equation was integrated to determine sediment thickness as a function of one-way traveltime . The resulting equation is z = 1400t + 0 .5t 2 where z is sediment thickness in meters, and t is one-way traveltime in seconds. Sediment thicknesses calculated using this equation were compared to values calculated from the general equation of Carlson and others (1986). Values for sediment thickness calculated by the two equations differed by no greater than 10 percent throughout the range of travel times. Bathymetry The bathymetry is from Chase and others (1981). The bathymetric data were compiled from a variety of sources, and data quality is inconsistent. Because of differences in navigational precision and density of coverage, the bathymetric contours of a feature may be at a different location than the corresponding isopleths derived from the EEZ-SCAN 84 data, or a feature may not be indicated on the bathymetry at all. These situations occur because either the feature is poorly located in the bathymetric data set or, especially in the outer EEZ, the bathymetric data are too sparse to have defined the existence of a feature. Acknowledgments Topographic digital data bases were corrected and verified by Christina Lief. Gerald Evenden developed the computer software system MAPGEN, used to compose this map. Reviews, suggestions, and technical contributions from Edward C. Escowitz and Florence Wong and advice about cartographic design from Will Stettner substantially improved the quality of this map. References Cited Carlson, R.L., Gangi, A.F., and Snow, K.R., 1986, Empirical reflection-traveltime/ depth and velocity/depth functions for the deep-sea sediment column: Journal of Geophysical Research, v. 91, no. B8, p. 8249-8266. Carter, D.J.T., 1980, Echo-sounding correction tables: Taunton, United Kingdom, Hydrographic Department, Ministry of Defence, 150 p. Chase, T.E., Wilde, Pat, Normark, W.R, Miller, C.P., Seekins, B.A., and Young, J.D., 1981, Offshore topography of the Western United States between 32° and 49° North latitudes: U.S. Geological Survey Open-File Report 81-443, scale 1:864,518 at 38° latitude, 2 sheets. Connard, G., Couch, R., Keeling , K., Roy, J., and Troseth, S., 1984, Abyssal plain and continental net-objective sedimentary thicknesses, in Kulm, L.D., and others, eds., Western North America continental margin and adjacent ocean floor off Oregon and Washington, Atlas 1 of Regional Atlas Series, Ocean Margin Drilling Program: Woods Hole, Mass., Marine Science International, sheet 7. EEZ-SCAN 84 Scientific Staff, 1986, Atlas of the Exclusive Economic Zone, Western Conterminous United States: U.S. Geological Survey Miscellaneous Investigations Series I-1792, scale 1:500,000, 152 p. See Also "U.S. Pacific West Coast Field Activities" (Paskevich and others, 2011; http://pubs.usgs.gov/of/2010/1332/htmldocs/pc/pc_overview.html). Paskevich, V.F., Wong, F.L., O?Malley, J.J., Stevenson, A.J., and Gutmacher, C.E., 2011, GLORIA sidescan-sonar imagery for parts of the U.S. Exclusive Economic Zone and adjacent areas: U.S. Geological Survey Open-File Report 2010?1332, available at http://pubs.usgs.gov/of/2010/1332/.

IMAP↗

User's Guide for Mixed-Size Sediment Transport Model for Networks of One-Dimensional Open Channels

This user's guide describes a mathematical model for predicting the transport of mixed sizes of sediment by flow in networks of one-dimensional open channels. The simulation package is useful for general sediment routing problems, prediction of erosion and deposition following dam removal, and scour in channels at road embankment crossings or other artificial structures. The model treats input hydrographs as stepwise steady-state, and the flow computation algorithm automatically switches between sub- and supercritical flow as dictated by channel geometry and discharge. A variety of boundary conditions including weirs and rating curves may be applied both external and internal to the flow network. The model may be used to compute flow around islands and through multiple openings in embankments, but the network must be 'simple' in the sense that the flow directions in all channels can be specified before simulation commences. The location and shape of channel banks are user specified, and all bedelevation changes take place between these banks and above a user-specified bedrock elevation. Computation of sediment-transport emphasizes the sand-size range (0.0625-2.0 millimeter) but the user may select any desired range of particle diameters including silt and finer (<0.0625 millimeter). As part of data input, the user may set the original bed-sediment composition of any number of layers of known thickness. The model computes the time evolution of total transport and the size composition of bed- and suspended-load sand through any cross section of interest. It also tracks bed -surface elevation and size composition. The model is written in the FORTRAN programming language for implementation on personal computers using the WINDOWS operating system and, along with certain graphical output display capability, is accessed from a graphical user interface (GUI). The GUI provides a framework for selecting input files and parameters of a number of components of the sediment-transport process. There are no restrictions in the use of the model as to numbers of channels, channel junctions, cross sections per channel, or points defining the cross sections. Following completion of the simulation computations, the GUI accommodates display of longitudinal plots of either bed elevation and size composition, or of transport rate and size composition of the various components, for individual channels and selected times during the simulation period. For individual cross sections, the GUI also allows display of time series of transport rate and size composition of the various components and of bed elevation and size composition.

Water-Resources Investigations Report↗

Characterization of coal-derived hydrocarbons and source-rock potential of coal beds, San Juan Basin, New Mexico and Colorado, U.S.A.

Coal beds are considered to be a major source of nonassociated gas in the Rocky Mountain basins of the United States. In the San Juan basin of northwestern New Mexico and southwestern Colorado, significant quantities of natural gas are being produced from coal beds of the Upper Cretaceous Fruitland Formation and from adjacent sandstone reservoirs. Analysis of gas samples from the various gas-producing intervals provided a means of determining their origin and of evaluating coal beds as source rocks. The rank of coal beds in the Fruitland Formation in the central part of the San Juan basin, where major gas production occurs, increases to the northeast and ranges from high-volatile B bituminous coal to medium-volatile bituminous coal ( R m values range from 0.70 to 1.45%). On the basis of chemical, isotopic and coal-rank data, the gases are interpreted to be thermogenic. Gases from the coal beds show little isotopic variation ( δ 13 C 1 values range −43.6 to −40.5 ppt), are chemically dry (C 1 /C 1–5 values are > 0.99), and contain significant amounts of CO 2 (as much as 6%). These gases are interpreted to have resulted from devolatilization of the humic-type bituminous coal that is composed mainly of vitrinite. The primary products of this process are CH 4 , CO 2 and H 2 O. The coal-generated, methane-rich gas is usually contained in the coal beds of the Fruitland Formation, and has not been expelled and has not migrated into the adjacent sandstone reservoirs. In addition, the coal-bed reservoirs produce a distinctive bicarbonate-type connate water and have higher reservoir pressures than adjacent sandstones. The combination of these factors indicates that coal beds are a closed reservoir system created by the gases, waters, and associated pressures in the micropore coal structure. In contrast, gases produced from overlying sandstones in the Fruitland Formation and underlying Pictured Cliffs Sandstone have a wider range of isotopic values ( δ 13 C 1 values range from −43.5 to −38.5 ppt), are chemically wetter (C 1 /C 1–5 values range from 0.85 to 0.95), and contain less CO 2 (< 2%). These gases are interpreted to have been derived from type III kerogen dispersed in marine shales of the underlying Lewis Shale and nonmarine shales of the Fruitland Formation. In the underlying Upper Cretaceous Dakota Sandstone and Tocito Sandstone Lentil of the Mancos Shale, another gas type is produced. This gas is associated with oil at intermediate stages of thermal maturity and is isotopically lighter and chemically wetter at the intermediate stage of thermal maturity as compared with gases derived from dispersed type III kerogen and coal; this gas type is interpreted to have been generated from type II kerogen. Organic matter contained in coal beds and carbonaceous shales of the Fruitland Formation has hydrogen indexes from Rock-Eval pyrolysis between 100 and 350, and atomic H:C ratios between 0.8 and 1.2. Oxygen indexes and atomic O:C values are less than 24 and 0.3, respectively. Extractable hydrocarbon yields are as high as 7,000 ppm. These values indicate that the coal beds and carbonaceous shales have good potential for the generation of liquid hydrocarbons. Voids in the coal filled with a fluorescent material that is probably bitumen is evidence that liquid hydrocarbon generation has taken place. Preliminary oil-source rock correlations based on gas chromatography and stable carbon isotope ratios of C 15+ hydrocarbons indicate that the coals and (or) carbonaceous shales in the Fruitland Formation may be the source of minor amounts of condensate produced from the coal beds at relatively low levelsof thermal maturity ( R m =0.7).

International Journal of Coal Geology↗

Geologic history of natural coal-bed fires, Powder River basin, USA

Coal-bed fires ignited by natural processes have baked and fused overlying sediments to form clinker, a hard red or varicolored rock, through much of the northern Great Plains of the United States (USA). The gently dipping coal beds in the region burn when regional downwasting brings them above the local water table. The resulting clinker forms a rim along the exposed edge of the coal bed in an ongoing process through geologic time. The resistant clinker is left capping buttes and ridges after the softer unbaked strata erode away. Clinker outcrops cover more than 4100 km2 in the Powder River basin (PRB), which lies in Wyoming (WY) and Montana (MT). The clinker in place records tens of billions of tons of coal that have burned, releasing gases into the atmosphere. The amount of clinker that has eroded away was at least an order of magnitude greater than the clinker that remains in place. Fission-track and uranium-thorium/ helium ages of detrital zircon crystals in clinker, and paleomagnetic ages of clinker, show that coal beds have burned naturally during at least the past 4 million years (Ma). The oldest in-place clinker that has been dated, collected from a high, isolated, clinker-capped ridge, has a fission track age of 2.8??0.6 Ma. Evidence of erosion and downcutting is also preserved by clinker clasts in gravel terraces. One clinker boulder in a terrace 360 m above the Yellowstone River has a fission track age of 4.0??0.7 Ma. Coal-bed fires are caused by lightning, wildfires, spontaneous combustion, or human activity on coal outcrops and in mines. Miners, government agencies, and ranchers have extinguished thousands of coal bed fires, but natural ignition continues where fresh coal has access to air. At any given time, hundreds of fires, mostly small, are burning. In the Powder River basin, the total amount of coal burned by natural fires in the last 2 Ma is one to two orders of magnitude greater than the total amount of coal removed by mining in the past century. However, current annual rates of coal mining are three to four orders of magnitude greater than estimated prehistoric annual rates of coal consumption by natural fires. ?? 2004 Published by Elsevier B.V.

International Journal of Coal Geology↗

Holocene environmental and climatic change in the Northern Great Plains as recorded in the geochemistry of sediments in Pickerel Lake, South Dakota

The sediments in Pickerel Lake, northeastern South Dakota, provide a continuous record of climatic and environmental change for the last 12000 yr. Sediments deposited between 12 and 6 ka (radiocarbon) show extreme variations in composition, oxygen and carbon isotopic composition of bulk carbonate, carbon isotopic composition of organic matter, and magnetic susceptibility. These variations reflect changes in sources of moisture, regional vegetation types, precipitation-evaporation balance, ground- and surface-water influx, water residence time, erosion, lake productivity, water level, and water temperature. The total carbonate content of late Pleistocene sediments steadily increased from <20% at the base of the core to as much as 80% in sediments deposited between 11 and 9 ka. By about 8 ka, the total carbonate content of the sediments had declined to about 40% where it remained with little variation for the past 8 kyr, suggesting relatively stable conditions. There are marked increases in values of ??13C and ??18O in bulk carbonate, and ??13C of organic matter, in sediments deposited between 10 and 6 ka as evaporation increased, and the vegetation in the watershed changed from forest to prairie. This shift toward more 18O-enriched carbonate may also reflect a change in source or seasonality of precipitation. During this early Holocene interval the organic carbon (OC) content of the sediments remained relatively low (2-3%), but then increased rapidly to 4.5% between 7 and 6 ka, reflecting the rapid transition to a prairie lake. The OC content fluctuates slightly between 4 and 6% in sediments deposited over the past 6 kyr. Like OC and total carbonate, most variables measured show little variation in the 13 m of sediment deposited over the past 6 kyr, particularly when compared with early Holocene variations. Although the magnetic susceptibility of this upper 13 m of sediment is generally low (<10 SI units), the upper six meters of the section is marked by striking 1 m cycles (ca. 400-500 yr periodicity) in susceptibility. These cycles are interpreted as being due to variations in the influx of eolian detrital-clastic material. Century-scale cyclic variations in different proxy variables for aridity and eolian activity from sediments deposited over the past 2000 yr in other lakes in the northern Great Plains, as well as in sand dune activity, suggest that aridity cycles were the dominant feature of late Holocene climate of the northern Great Plains. (C) 2000 Elsevier Science Ltd and INQUA. All rights reserved.

Quaternary International↗

Contaminant trends in sport fish from Lake Roosevelt and the upper Columbia River, Washington, 1994-1998

Fish from Lake Roosevelt were first reported to contain elevated concentrations of contaminants in the early 1980?s, with mercury, dioxins and furans, and polychlorinated biphenyls (PCBs) identified as being of most concern to human health. Over the following years there were a series of studies by United States and Canadian agencies addressing contaminants in fish from both a human and environmental perspective. In the early 1990?s, industrial discharges to the Columbia River above the international boundary decreased. The dominant changes in industrial practices included a reduction in slag and effluent discharges from a lead-zinc smelter, and a reduction in dioxins and furans due to processing changes at a Canadian pulp mill. It is believed that these two alterations in industrial practices may have greatly reduced the loading of selected contaminants to the Columbia River system. In response to these recent changes, the U.S. Geological Survey initiated this present study for the purpose of determining the present concentrations of mercury, dioxins and furans, and PCBs in fish, and, if possible, to determine if concentrations have changed since the 1994 studies. All contaminant analysis was done on fish fillets in order to address human health concerns. Our study concluded that the concentrations of contaminants in fish that were identified as a potential threat to human health have either not changed since the 1994 studies, or have decreased. PCBs, as determined by Aroclor 1254, do not appear to have changed between 1994 and 1998; sources of PCBs are presently unknown. In contrast, dioxins and furans, as indicated by 2,3,7,8-TCDF, did show a significant decrease in rainbow trout fillets from 1994 to 1998. However, there was no apparent change in the average 2,3,7,8-TCDF concentrations in mountain whitefish, with the reason uncertain at this time. Average concentrations of 2,3,7,8-TCDF were higher in mountain whitefish than in rainbow trout. Toxicity equivalence concentrations (TEC) are determined by summing the relative toxicity of individual congeners of dioxins, furans, and toxic ?dioxin-like? PCB congeners in individual fish. Rainbow trout from the upper reach have higher TECs than rainbow trout from the lower reach, with trout from the upper reach having a higher percentage of the toxicity from toxic ?dioxin-like? PCBs than dioxin and furan compounds. In relation to mercury, the concentrations of total mercury in walleye have significantly decreased by about 50 percent from 1994 to 1998.

Water-Resources Investigations Report↗

Organic geochemistry applied to environmental assessments of Prince William Sound, Alaska, after the Exxon Valdez oil spill—a review

Organic geochemistry played a major role in the environmental assessments conducted following the Exxon Valdez oil spill, which occurred on March 24, 1989, and released about 258,000 bbls (41 million liters) of Alaska North Slope crude oil into Prince William Sound. Geochemical analyses of more than 15,000 sediment, tar, and biological samples and about 5000 water samples provide the largest database yet collected on oil-spill chemistry, and we review the results here. The marine environment of the Sound has a complex background of petrogenic, pyrogenic, and biogenic hydrocarbons from natural and anthropogenic sources. Geochemical evaluation of the fate and effects of the spilled oil required that this oil and its residues be distinguished from the background. A variety of molecular and isotopic techniques were employed to identify various hydrocarbon sources and to distinguish quantitatively among mixed sources in the samples. Although the specific criteria used to distinguish multiple sources in the region affected by the Exxon Valdez spill are not necessarily applicable to all spill situations, the principles that governed their selection are. Distributions of polycyclic aromatic hydrocarbons (PAH) and dibenzothiophenes distinguish Exxon Valdez oil and its weathered residues from background hydrocarbons in benthic sediments. Ratios of C 2 -dibenzothiophene C 2 -phenanthrene "> C 2 -dibenzothiopheneC 2 -phenanthrene and C 3 -dibenzothiophene C 3 -phenanthrene "> C 3 -dibenzothiopheneC 3 -phenanthrene were particularly useful. Carbon isotopes and terpane distributions distinguished Exxon Valdez residues found on shorelines from tars from other sources. Diesel and diesel soot were identified by the absence of alkylated chrysenes and a narrow distribution of n -alkanes, whereas pyrogenic products were distinguished by the dominance of 4- to 6-ring PAH over 2- to 3-ring PAH and by the dominance of non-alkylated over alkylated homologues of each PAH series. The presence of 18α(H)-oleanane in benthic sediments, coupled with its absence in Exxon Valdez oil and its residues, confirm another petrogenic source. Results of geochemical studies suggest that the petrogenic component in the background of benthic sediments is derived from oil seeps in the eastern Gulf of Alaska. In 1990 and 1991, Exxon Valdez residues, generally forming a small increment to the pre-spill background, were found to be only sporadically distributed in some shallow, near shore sediments adjacent to shorelines that had been heavily oiled in 1989. In 1994, occurrences of Exxon Valdez tars on shoreline surfaces were rare, although residues could be found buried in shoreline sediments at some isolated locations along the spill path where they were protected from wave action. Spilled oil residues collected 16 months after the spill were degraded, on average, by nearly 50%. Shoreline residues from sources other than the spill were also identified and are widespread throughout the Sound. These residues include (1) geochemically distinct tars and oils imported from California oil fields to Alaska for fuel and construction purposes prior to the discovery of the Cook Inlet and North Slope oil fields, (2) diesel and diesel soot, and (3) more highly refined products. Of the more than 2700 chemical analyses of biological samples of higher life forms (fish, birds, and mammals) about 150 (6%) indicate recognizable residues of Exxon Valdez oil, which were identified by their distribution of polycyclic aromatic hydrocarbons (PAH). Most of these samples (138) were collected in 1989 and most were associated with external surfaces or the gastrointestinal tract. Rarely do internal tissues or fluids contain recognizable fingerprints of spilled oil. This observation includes samples from marine mammals that were visibly oiled externally. Other hydrocarbon sources, including diesel and a non-petroleum artifact that occurs when concentrations of individual PAH are at or near their method detection limit, are also identified in biological samples.

Alaska↗

Pressure calibrants in the hydrothermal diamond-anvil cell

Based on the equation of state of water (EOSW), experimental pressure in the hydrothermal diamond-anvil cell (HDAC) using pure water or dilute aqueous solutions as a pressure medium can be accurately determined at each measured temperature. Consequently, meaningful interpretations can be obtained for observations in the HDAC, which has been widely accepted as a versatile, modern apparatus for hydrothermal experiments. However, this is not true when other pressure media were used because there is no reliable way to determine experimental pressure other than the use of in situ pressure sensors. Most of the available pressure sensors are difficult to apply because they either require expensive facilities to perform the measurements or are unable to provide the accuracy needed for the interpretation of hydrothermal experiments. The only exception is to use the interferometric method to detect the ??-?? quartz transition, although such applications are limited to temperatures above 573??C. In this study, three pressure calibrants were calibrated for applications at lower temperatures, and they were based on visual observation of the ferroelastic phase transitions in BaTiO3 (tetragonal/cubic), Pb3(PO4)2 (monoclinic/trigonal), and PbTiO3 (tetragonal/cubic). For the phase transitions in BaTiO3 and Pb3(PO4)2, the temperature at which twinning disappears during heating was taken as the transition temperature (Ttr); the phase transition pressures (Ptr) can be calculated, respectively, from Ptr (MPa; ??3%) = 0.17 - 21.25 [(Ttr) - 115.3], and Ptr (MPa; ??2%) = 1.00 - 10.62 [(Ttr) - 180.2], where Ttr is in ??C. For the phase transition in PbTiO3, the temperature at which the movement of phase front begins (or ends) on heating (or cooling) was taken as the transition temperature (Ttr,h or Ttr,c), and the phase transition pressures on heating (Ptr,h) and cooling (Ptr,c) can be calculated from Ptr,h (MPa; ??4%) = 7021.7 - 14.235 (Ttr,h), and Ptr,c (MPa; ??4%) = 6831.3 - 14.001 (Ttr,c). Phase transitions for these three pressure calibrants are easy to detect visually, and their P-T phase boundaries have negative slopes and intersect isochors of most of the geologic fluids at high angles and, therefore, are easy to apply. Copyright ?? 2007 by V. H. Winston & Son, Inc. All rights reserved.

International Geology Review↗

Gulf of Mexico summary report 2, August 1981: A revision of Outer Continental Shelf oil and gas activities in the Gulf of Mexico and their onshore impacts: A summary report, September 1980

The Gulf of Mexico Outer Continental Shelf (OCS) continues to be the most intensively developed offshore oil- and gas-producing region in the world. With the development of technology, exploration, development, and production are being extended to include areas off the coast of southwest Florida and deep-water areas near the Mississippi River Delta. Development in both areas requires careful analyses of local considerations. The hydrocarbon potential of the region, while not well established in the frontier portions, generally remains favorable. A total of 482 fields have been discovered to date in the federally regulated part of the Gulf of Mexico. Reserve estimates have been made for the 435 producing fields in the region. Through December 31, 1980, those fields have produced 5.0 billion barrels of oil and condensate, and 48.7 trillion cubic feet of gas. Remaining recoverable reserves are 3.1 billion barrels of oil and 40.2 trillion cubic feet of gas. Estimates of undiscovered recoverable resources for the Gulf of Mexico are 6.6 billion barrels of oil and 71.9 trillion cubic feet of gas. Since enactment of the Outer Continental Shelf Lands Act in 1953, there have been 42 oil and gas lease sales in the Gulf of Mexico. An average of three lease sales per year are scheduled through 1986. Since 1953, the Bureau of Land Management (BLM) has leased 3,119 tracts in the Gulf of Mexico; 1,825 leases are currently active. The distribution of leased tracts exhibits a regionwide pattern as shown by Lease Sales A62, 62, A66, and 66. Proposed Lease Sales 67, 69, 72, and 74 will probably continue that pattern. Tracts off the coast of southwest Florida in the Charlotte Harbor, Howell Hook, and Pulley Ridge Areas will be offered in upcoming sales. Operations on tracts in deepwater areas slated for future sales may require additional technology. Exploration, development, and production in the Gulf of Mexico Region are continuing at a rapid pace throughout the Gulf of Mexico. Between January 1, 1980, and April 15, 1981, 197 initial plans of exploration and 165 supplemental plans of exploration were submitted to the U.S. Geological Survey (USGS). During the same period, 107 initial and 131 supplemental plans of development/production were submitted to the USGS. As of May 1981, there were 121 offshore mobile drilling units operating in the Gulf of Mexico. Pipelines continue to be the preferred mode of transport for Gulf of Mexico OCS oil and gas production. Pipeline additions to the existing network average 69 miles (111 km) per month. At any given time, numerous pipeline projects are under way in the Gulf of Mexico. To supplement OCS oil and gas production several deepwater port projects, designed to handle imported crude oil, are being planned or constructed in the region. The process of transportation planning in the Gulf of Mexico is done by industry and government through BLM's Intergovernmental Planning Program and its Regional Technical Working Group (RTWG). The RTWG has completed the First Edition Gulf of Mexico Regional Transportation Management Plan. The nearshore and onshore facilities in the Gulf of Mexico service both the domestic onshore and offshore oil and gas industry as well as the global market. Most of the major centers along the Gulf Coast, including Houston, Corpus Christi, Galveston, Beaumont, Port Arthur, and Freeport, Texas; New Orleans, Lake Charles, Lafayette, Baton Rouge, Morgan City, and Houma, Louisiana; Pascagoula, Mississippi; Mobile, Alabama; and Port Manatee, Florida, have ties to the offshore industry. A wide array of services and support industries, ranging from small independent vendors to major international manufacturing contractors, can be found within the region. Profiles of selected centers reveal typical industries and patterns of activity that are characteristic throughout the Gulf Coast region.

Alabama, Florida, Louisiana, Mississippi, Texas↗

Varve calibrated records of carbonate and organic carbon accumulation over the last 2000 years in the Black Sea

Sedimentologic and geochemical studies of box and gravity cores recovered from the Black Sea during the first leg of a multileg international Black Sea expedition in 1988 allow reconstruction of the basinwide Holocene environmental history of the Black Sea. In the deeper parts of the basin, box cores typically recovered a flocculent surface layer (“fluff”), laminated coccolith marls of Unit I (25–45 cm thick), and the upper 5–10 cm of finely laminated, dark‐colored sapropels of Unit II. Fine‐grained, homogeneous mud turbidites are interbedded with Units I and II over much of the basin, but the stratigraphie position of these turbidites differs, from site to site. The deposition of individual turbidites up to 15 cm thick does not appear to have significantly disturbed underlying laminae. Sediment trap deployments in the Black Sea suggest that light and dark laminae couplets represent annual increments of sedimentation (i.e., varves); we have therefore constructed a varve chronology for the sequence in order to correlate and date distinctive sedimentation and paleoenvironmental events. Distinctive groups of laminae in Unit I can be correlated across the entire deeper basin (a distance of more than 1000 km). This implies a remarkable homogeneity in production, accumulation, and preservation of biogenic material over much of the Black Sea during deposition of Unit I. The change from deposition of finely laminated, organic carbon‐rich sapropels (Unit II) to laminated, more calcareous, coccolith‐rich marls (Unit I) is thought to represent the crossing of a salinity threshold for Emiliania huxleyi. The varve chronology sets this change at about 1.63 ka (1633±100 yr B.P.), but the record of magnetic secular variation measured in several cores produces an age estimate of about 2.0 ka for the base of Unit I, or about 1.2 times the varve age. The average of six calibrated accelerator mass spectrometry radiocarbon ages for the base of Unit I is 2.7 ka, or about 1.7 times the varve age. Following the initial change to coccolith‐dominated sedimentation, deposition of sapropel resumed for at least one significant period, 1.56–1.25 ka. Since 1.25 ka, cycles of carbonate deposition with quasi‐decadal periodicities have produced characteristic darker and lighter assemblages of laminae. These cycles may have been climatically driven. Geochemical analyses coupled with the varve ages adopted herein indicate that accumulation rates of carbonate are nearly an order of magnitude higher in Unit I (averaging 35–45 g m −2 yr −1 ) than in sapropelic Unit II. which contains primarily detrital carbonate. The accumulation of lithogenic components in parts of Unit I is only 1.5 times the rate in Unit II. Deepwater organic carbon accumulation rates are somewhat higher in Unit I (3.5–4.5 g m −2 yr −1 ) than in the upper part of Unit II. Organic carbon accumulation rates in Unit I are somewhat antithetic to those of carbonate, and on the basis of this and additional constraints placed by pyrolysis and carbon isotopic analyses of organic material, it appears that terrestrial organic matter is an important component (perhaps >25%) of total organic carbon burial in the basin. Unit I in the western part of the Black Sea has a higher terrestrial organic component and higher accumulation rates of terrigenous clastic material than Unit I in the eastern part. This difference between eastern and western Black Sea is to be expected because of the major rivers that empty into the western Black Sea from eastern Europe, Ukraine, and Russia. Shallow slope sites, but still within euxinic bottom waters, have lower organic carbon accumulation rates and lower pyrolysis hydrogen indices than deepwater basinal sites, suggesting selective resuspension and oxidation of organic matter at basin margins and focusing of organic matter deposition toward the basin center. A comparison of the Black Sea data with those from several open ocean sites with similar water depths showed no significant difference between organic carbon accumulation rates under oxic and anoxic conditions. For a given bulk accumulation rate the organic carbon accumulation rates, normalized to primary productivity, are about the same in both settings.

Global Biogeochemical Cycles↗

Spectral matching techniques (SMTs) and automated cropland classification algorithms (ACCAs) for mapping croplands of Australia using MODIS 250-m time-series (2000–2015) data

Mapping croplands, including fallow areas, are an important measure to determine the quantity of food that is produced, where they are produced, and when they are produced (e.g. seasonality). Furthermore, croplands are known as water guzzlers by consuming anywhere between 70% and 90% of all human water use globally. Given these facts and the increase in global population to nearly 10 billion by the year 2050, the need for routine, rapid, and automated cropland mapping year-after-year and/or season-after-season is of great importance. The overarching goal of this study was to generate standard and routine cropland products, year-after-year, over very large areas through the use of two novel methods: (a) quantitative spectral matching techniques (QSMTs) applied at continental level and (b) rule-based Automated Cropland Classification Algorithm (ACCA) with the ability to hind-cast, now-cast, and future-cast. Australia was chosen for the study given its extensive croplands, rich history of agriculture, and yet nonexistent routine yearly generated cropland products using multi-temporal remote sensing. This research produced three distinct cropland products using Moderate Resolution Imaging Spectroradiometer (MODIS) 250-m normalized difference vegetation index 16-day composite time-series data for 16 years: 2000 through 2015. The products consisted of: (1) cropland extent/areas versus cropland fallow areas, (2) irrigated versus rainfed croplands, and (3) cropping intensities: single, double, and continuous cropping. An accurate reference cropland product (RCP) for the year 2014 (RCP2014) produced using QSMT was used as a knowledge base to train and develop the ACCA algorithm that was then applied to the MODIS time-series data for the years 2000–2015. A comparison between the ACCA-derived cropland products (ACPs) for the year 2014 (ACP2014) versus RCP2014 provided an overall agreement of 89.4% (kappa = 0.814) with six classes: (a) producer’s accuracies varying between 72% and 90% and (b) user’s accuracies varying between 79% and 90%. ACPs for the individual years 2000–2013 and 2015 (ACP2000–ACP2013, ACP2015) showed very strong similarities with several other studies. The extent and vigor of the Australian croplands versus cropland fallows were accurately captured by the ACCA algorithm for the years 2000–2015, thus highlighting the value of the study in food security analysis. The ACCA algorithm and the cropland products are released through http://croplands.org/app/map and http://geography.wr.usgs.gov/science/croplands/algorithms/australia_250m.html

International Journal of Digital Earth↗

Depositional history of the Fire Clay coal bed (Late Duckmantian), Eastern Kentucky, USA

More than 3800 coal thickness measurements, proximate analyses from 97 localities, and stratigraphic and sedimentological analyses from more than 300 outcrops and cores were used in conjunction with previously reported palynological and petrographic studies to map individual benches of the coal and document bench-scale variability in the Fire Clay (Hazard No. 4) coal bed across a 1860 km2 area of the Eastern Kentucky Coal Field. The bench architecture of the Fire Clay coal bed consists of uncommon leader benches, a persistent but variable lower bench, a widespread, and generally thick upper bench, and local, variable rider benches. Rheotrophic conditions are inferred for the leader benches and lower bench based on sedimentological associations, mixed palynomorph assemblages, locally common cannel coal layers, and generally high ash yields. The lower bench consistently exhibits vertical variability in petrography and palynology that reflects changing trophic conditions as topographic depressions infilled. Infilling also led to unconfined flooding and ultimately the drowning of the lower bench mire. The drowned mire was covered by an air-fall volcanic-ash deposit, which produced the characteristic flint clay parting. The extent and uniform thickness of the parting suggests that the ash layer was deposited in water on a relatively flat surface without a thick canopy or extensive standing vegetation across most of the study area. Ash deposits led to regional ponding and establishment of a second planar mire. Because the topography had become a broadly uniform, nutrient-rich surface, upper-bench peats became widespread with large areas of the mire distant to clastic sources. Vertical sections of thick (> 70 cm), low-ash yield, upper coal bench show a common palynomorph change from arborescent lycopod dominance upward to fern and densospore-producing, small lycopod dominance, inferred as a shift from planar to ombrotrophic mire phases. Domed mires appear to have been surrounded by wide areas of planar mires, where the coal was thinner (< 70 cm), higher in ash yield, and dominated by arborescent lycopods. Rectangular thickness trends suggest that syndepositional faulting influenced peat accumulation, and possibly the position of the domed mire phase. Faulting also influenced post-depositional clastic environments of deposition, resulting in sandstone channels with angular changes in orientation. Channels and lateral facies were locally draped by high-ash-yield rider coal benches, which sometimes merged with the upper coal bench. These arborescent-lycopod dominant rider coal benches were profoundly controlled by palcotopography, much like the leader coal benches. Each of the benches of coal documented here represent distinctly different mires that came together to form the Fire Clay coal bed, rather than a single mire periodically split by clastic influx. This is significant as each bench of the coal has its own characteristics, which contribute to the total coal characteristics. The large data set allows interpretation of both vertical and lateral limits to postulated domed phases in the upper coal bench, and to the delineation of subtle tectonic structures that allow for meaningful thickness projections beyond the limits of present mining.A study was conducted to analyze the depositional history of the Fire Clay coal bed in the eastern Kentucky coal field. The study involved over 3800 coal thickness measurements, proximate analyses from 97 localities, and stratigraphic and sedimentological analyses from more than 300 outcrops and cores in conjunction with previously reported palynological and petrographic studies to map individual benches of the coal and document bench-scale variability.

International Journal of Coal Geology↗