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Variable partitioning of lithium in rhyolitic melt during decompression and ascent

The partitioning behavior of Li in magmatic systems is increasingly being investigated due to the economic importance of Li in the transition to sustainable energy resources (e.g., batteries). However, at upper crustal pressures, it remains uncertain whether Li preferentially partitions into the vapor or liquid (brine) phase or remains in the silicate melt. This complicates our ability to determine where Li resides—silicate melt, minerals, or fluid phase—upon eruption, a crucial factor for understanding its postdepositional movement and concentration into a brine or volcano-sedimentary deposit. Here, we present a novel investigation into the behavior of Li within natural evolved melts during continuous magma decompression and ascent using melt embayments (open melt inclusions). Mineral-hosted melt embayments preserve records of the evolving composition of the exterior melt, including degassing pathways and ascent timescales, when paired with appropriate diffusion coefficients. Lithium concentration profiles were measured in quartz-hosted melt embayments from the rapidly quenched eruptive phases of five rhyolitic, caldera-forming eruptions to investigate the behavior of Li during magma decompression and ascent, where vapor partitioning and ascent dynamics were previously established by investigating H 2 O and CO 2 profiles. We find that in four systems, embayments contain lower interior Li concentrations than the coerupted melt inclusions; the fifth system contains the same Li concentrations in embayments and melt inclusions. However, many of these embayments contain gradients, with 84 % preserving Li enrichment near the melt-bubble interface, as compared to their interior concentration. We interpret these characteristics to represent two distinct stages of Li partitioning during magma decompression and ascent, in contrast to existing literature that proposes only one type of partitioning behavior. The first stage is interpreted as melt depletion of Li, likely driven by partitioning into an exsolved supercritical fluid phase, supported by the strong correlation between the extent of Li depletion and Cl concentration in the melt, as well as the decompression rate. This behavior then fundamentally shifts, where Li reenriches in the melt, postulated to be driven by the unmixing of the supercritical fluid phase at shallow pressures. For the one system that did not develop Li gradients through decompression, we attribute this to the lower values of Na and Cl in the melt, potentially inhibiting the partitioning of Li into a fluid phase. Importantly, the behavior of Li during decompression is not consistent within or between volcanic centers, highlighting the need for systematic experimental investigation in variable composition melts at pressures relevant to conduit dynamics. This knowledge would improve our ability to model Li profiles to understand magma decompression, and predict where Li resides (e.g., stored in volcanic glass, gas, or crystals) upon eruption prior to any later extraction.

Economic Geology

Utility of an instantaneous salt dilution method for measuring streamflow in headwater streams

Streamflow records are biased toward large streams and rivers, yet small headwater streams are often the focus of ecological research in response to climate change. Conventional flow measurement instruments such as acoustic Doppler velocimeters (ADVs) do not perform well during low-flow conditions in small streams, truncating the development of rating curves during critical baseflow conditions dominated by groundwater inflow. We revisited an instantaneous solute tracer injection method as an alternative to ADVs based on paired measurements to compare their precision, efficiency, and feasibility within headwater streams across a range of flow conditions. We show that the precision of discharge measurements using salt dilution by slug injection and ADV methods were comparable overall, but salt dilution was more precise during the lowest flows and required less time to implement. Often, headwater streams were at or below the depth threshold where ADV measurements could even be attempted and transects were complicated by coarse bed material and cobbles. We discuss the methodological benefits and limitations of salt dilution by slug injection and conclude that the method could facilitate a proliferation of streamflow observation across headwater stream networks that are highly undersampled compared to larger streams.

Virginia

Water resources of Mellette and Todd counties, South Dakota

Mellette and Todd Counties are located in south-central South Dakota and have a combined area of 2,694 square miles. The White River and its tributaries, which include the Little White River, drain Mellette County and about one-half of Todd County. Tributaries to the Niobrara River, which include the Keya Paha River, drain the other one-half of Todd County. The average discharge of the Little White River is about 56 cubic feet per second as the river enters Todd County and is about 131 cubic feet per second as it discharges to the White River in northern Mellette County. The average discharge of the Keya Paha River just outside Todd County is about 39 cubic feet per second. The average annual runoff for Mellette and Todd Counties ranges from 0.94 to 2.36 inches based on records from nine streamflow-gaging stations in and near the counties. The average annual runoff is 1.62 inches, which compares with the average annual precipitation of about 19 inches. In Todd County, shallow wells completed in the alluvial, Ogallala, Arikaree, and White River aquifers generally can supply water that has low concentrations of dissolved solids, is fresh, and is soft to moderately hard. Ground water from shallow aquifers is limited in Mellette County; therefore, deep wells, often greater than 1,000 feet, are sometimes installed. The Pierre Shale often is used to supply rural domestic and stock wells in Mellette County even though well yields are low and the water has high dissolved solids, is moderately saline, and is very hard. Alluvial aquifers are present in both counties and store an estimated 1.6 million acre-feet of water. The water quality of the alluvial aquifers is dependent on the underlying deposits, and generally the water has low concentrations of dissolved solids, is fresh, and is soft to moderately hard where underlain by the Ogallala and Arikaree Formations; has moderate concentrations of dissolved solids, is slightly saline, and is hard where underlain by the White River Group; and has high concentrations of dissolved solids, is saline, and is very hard where underlain by the Pierre Shale. Also, yields often are lower where the alluvial aquifers are underlain by the Pierre Shale. The Ogallala aquifer is present in only Todd County, and the Arikaree aquifer is present throughout most of Todd County and southwestern and south-central Mellette County. The Ogallala aquifer contains an estimated 17 million acre-feet of water in storage, and the Arikaree aquifer contains an estimated 50 million acre-feet of water in storage. Both aquifers generally are suitable for irrigation, and yields from these aquifers are sometimes greater than 1,000 gallons per minute. Nitrate concentrations in 13 out of 92 water samples collected from the Ogallala aquifer exceeded the Primary Drinking Water Maximum Contaminant Level (MCL) of 10 milligrams per liter. In 11 out of 46 samples collected from the Arikaree aquifer, arsenic concentrations exceeded the MCL of 50 micrograms per liter. The White River aquifer, where present, is usually the shallowest source of ground water in Mellette County. The White River aquifer also is used in northern Todd County where the Ogallala and Arikaree aquifers are not present. The White River aquifer contains an estimated 50 million acre-feet of water in storage. Reported yields from the aquifer range from 1 to 30 gallons per minute, which generally is insufficient to support irrigation in most areas. However, yields are sufficient for livestock-watering and rural-domestic purposes. In both counties, the Pierre Shale is the shallowest bedrock aquifer and is exposed at the land surface throughout most of Mellette County. This aquifer is used primarily in Mellette County. Although the aquifer contains an estimated maximum of 1.5 million acre-feet of water in storage, it is not a viable source of ground water because the aquifer is relatively impermeable, yields are low, and water usually can be obtained from shallower sources, especially in Todd County. Reported yields from the Pierre Shale aquifer range from 1 to 8 gallons per minute. Because few test holes and wells penetrate below the Pierre Shale, little is known about the extent of the deeper bedrock aquifers. All wells completed in the Dakota Sandstone, Inyan Kara, and Minnelusa and Madison aquifers in the counties are used for stock-watering purposes. High concentrations of dissolved solids and hard water are characteristic of the water quality in the bedrock aquifers. Depths to the top of the deeper bedrock aquifers range from 1,270 feet to greater than 2,000 feet below land surface.

South Dakota

A comprehensive fault system inversion approach: Methods and application to NSHM23

We present updated inversion‐based fault‐system solutions for the 2023 update to the National Seismic Hazard Model (NSHM23), standardizing earthquake rate model calculations on crustal faults across the western United States. We build upon the inversion methodology used in the Third Uniform California Earthquake Rupture Forecast (UCERF3) to solve for time‐independent rates of earthquakes in an interconnected fault system. The updated model explicitly maps out a wide range of fault recurrence and segmentation behavior (epistemic uncertainty), more completely exploring the solution space of viable models beyond those of UCERF3. We also improve the simulated annealing implementation, greatly increasing computational efficiency (and thus inversion convergence), and introduce an adaptive constraint weight calculation algorithm that helps to mediate between competing constraints. Hazard calculations show that ingredient changes (especially fault and deformation models) are the primary driver of hazard changes between NSHM23 and UCERF3. Updates to the inversion methodology are also consequential near faults in which the slip rate in UCERF3 was poorly fit or was satisfied primarily using large multifault ruptures that are now restricted by explicit b ‐value and segmentation constraints.

Bulletin of the Seismological Society of America

Quantitative evaluations of earthquake early warning performance using “Did You Feel It?” and post-alert surveys

We examine responses to the U.S. Geological Survey’s “Did You Feel It?” (DYFI) survey and its companion earthquake early warning (EEW) questionnaire to assess the performance of the U.S. ShakeAlert EEW system directly from the alert recipients’ perspectives. ShakeAlert rapidly detects earthquakes and develops alert information, but as official alert delivery partners issue these alerts, it is thus difficult to determine how many people were alerted and when. We investigate DYFI reports for six California earthquakes that had EEW alerts and substantial responses to the DYFI EEW questionnaire. Comparisons of ShakeAlert predictions to reported intensities demonstrate that magnitude estimation accuracy is not necessarily indicative of ground-motion prediction accuracy. Perceived warning time distributions indicate that estimating maximum-expected warning times using the S-wave arrival is a reasonable assumption when discussing public EEW performance. However, we also find many reports of shorter warning times, late alerts, and missed alerts than expected based on ShakeAlert publication times, suggesting alert delivery latencies are substantial and highly variable. The novelty of our analysis is that we demonstrate that the DYFI EEW survey provides useful EEW efficacy information—independent of the specific alerting pathway—that can be used to inform our choices for conveying EEW performance.

California

Testing rate‐and‐state predictions of aftershock decay with distance

We analyze aftershocks of the 2019 M 7.1 Ridgecrest mainshock and isolated M 5–6 mainshocks in southern California to test predictions made by the rate‐and‐state friction model of Dieterich (1994) . Rate‐and‐state friction predicts that the seismicity rate after a stress step follows Omori decay, where the Omori c ‐value, which is the saturation in aftershock rate observed at small times, is larger for smaller stress steps. Put in the context of an aftershock sequence, this predicts that the Omori c ‐value will be systematically larger at greater distances from the mainshock. To our knowledge, this predicted effect has not been observed. In part this may be because the Omori c ‐value is difficult to measure because it often reflects short‐term catalog incompleteness rather than a true saturation in aftershock rate. We explore the dependence of the Omori c ‐value on the distance to the mainshock by applying the “ a ‐positive” method ( van der Elst and Page, 2023 ). This method is insensitive to short‐term aftershock incompleteness and allows resolution of the true aftershock rate deep into the mainshock coda. For aftershocks of the Ridgecrest mainshock and stacked M 5–6 mainshocks, we observe systematic differences in early aftershock rates, relative to mainshock distance, consistent with the predictions of rate‐and‐state friction. Furthermore, for the larger Ridgecrest dataset, we observe that aftershocks nearer to the mainshock start earlier, and we resolve a flattening of the Omori curve consistent with a larger Omori c ‐value for the farthest aftershocks, as predicted by Dieterich (1994) .

Seismological Research Letters

Ground-water flow in the surficial aquifer system and potential movement of contaminants from selected waste-disposal sites at Naval Station Mayport, Florida

Ground-water flow through the surficial aquifer system at Naval Station Mayport near Jacksonville, Florida, was simulated with a two-layer finite-difference model as part of an investigation conducted by the U.S. Geological Survey. The model was calibrated to 229 water-level measurements from 181 wells during three synoptic surveys (July 17, 1995; July 31, 1996; and October 24, 1996). A quantifiable understanding of ground-water flow through the surficial aquifer was needed to evaluate remedial-action alternatives under consideration by the Naval Station Mayport to control the possible movement of contaminants from sites on the station. Multi-well aquifer tests, single-well tests, and slug tests were conducted to estimate the hydraulic properties of the surficial aquifer system, which was divided into three geohydrologic units�an S-zone and an I-zone separated by a marsh-muck confining unit. The recharge rate was estimated to range from 4 to 15 inches per year (95 percent confidence limits), based on a chloride-ratio method. Most of the simulations following model calibration were based on a recharge rate of 8 inches per year to unirrigated pervious areas. The advective displacement of saline pore water during the last 200 years was simulated using a particle-tracking routine, MODPATH, applied to calibrated steady-state and transient models of the Mayport peninsula. The surficial aquifer system at Naval Station Mayport has been modified greatly by natural and anthropogenic forces so that the freshwater flow system is expanding and saltwater is being flushed from the system. A new MODFLOW package (VAR1) was written to simulate the temporal variation of hydraulic properties caused by construction activities at Naval Station Mayport. The transiently simulated saltwater distribution after 200 years of displacement described the chloride distribution in the I-zone (determined from measurements made during 1993 and 1996) better than the steady-state simulation. The advective movement of contaminants from selected sites within the solid waste management units to discharge points was simulated using MODPATH. Most of the particles were discharged to the nearest surface-water feature after traveling less than 1,000 feet in the ground-water system. Most areas within 1,000 feet of a surface-water feature or storm sewer had traveltimes of less than 50 years, based on an effective porosity of 40 percent. Contributing areas, traveltimes, and pathlines were identified for 224 wells at Naval Station Mayport under steady-state and transient conditions by back-tracking a particle from the midpoint of the wetted screen of each well. Traveltimes to contributing areas that ranged between 15 and 50 years, estimated by the steady-state model, differed most from the transient traveltime estimates. Estimates of traveltimes and pathlines based on steady-state model results typically were 10 to 20 years more and about twice as long as corresponding estimates from the transient model. The models differed because the steady-state model simulated 1996 conditions when Naval Station Mayport had more impervious surfaces than at any earlier time. The expansion of the impervious surfaces increased the average distance between contributing areas and observation wells.

Florida

Critical mineral inventory of select IOA-IOCG deposits, southwestern USA

Critical minerals are necessary for modern technology and strategic purposes. Their increasing importance requires finding new and nontraditional resources. Samples of ore, altered, and unaltered host rock were collected from 26 iron mines and prospects in California, Nevada, and Utah to assess the potential of these deposits to host economic quantities of different critical minerals. Geochemical analyses were conducted by 61 element ICP-OES-MS sodium peroxide fusion and major elements determined by WDXRF. These deposits concentrated many critical minerals beyond what is found in average upper crustal abundances, such as Sb, As, Bi, Co, Ga, Mg, Mn, Ni, Nb, Pd, REE, Sc, Te, Sn, Ti, W, V, and Zn. However, most of these are not concentrated enough in the ore to be considered as economic resources. Those critical minerals that are enriched enough in some of these deposits to possibly be considered as by-product commodities are Ni, REE, V, and potentially Co and Ga. These enrichments were not uniform, with REE more likely to be enriched in IOA deposits, whereas Co, Ga, Ni, and V could be found enriched in either IOA or IOCG deposits.

California, Nevada, Utah

Geophysical characterization of an alkaline‑carbonatite complex using gravity and magnetic methods at Magnet Cove, Arkansas, USA

The Magnet Cove alkaline‑carbonatite complex (MCC), located in the Ouachita Mountains of south-central Arkansas in the United States, hosts an extensive variety of rare rock types and critical mineral resources with physical properties (density and magnetization) that contrast significantly with the sedimentary rocks into which they have intruded. Newly acquired ground-based gravity and magnetic data were used to develop two-dimensional and three-dimensional geophysical models of the Cretaceous-aged Magnet Cove intrusive complex. The models reveal that the MCC: (1) widens out at middle crustal depths to as much 22 km across, and may reach a depth of 20 km; (2) has a total volume (exposed and subsurface) that may be over 800 km 3 ; (3) is likely connected at depth to other intrusions in the Arkansas alkaline province; and (4) has a geometry that is aligned with pre-existing structures such as the Reelfoot rift and the Ouachita orogenic belt, some of which were likely structurally controlled by the Precambrian crystalline basement and the continent-ocean transition zone buried beneath the Ouachita orogen. For the first time, the magnetic models of the MCC account for the presence of strong remanent magnetization. This results in a geophysical workflow necessary to accurately interpret magnetic anomalies over the much larger Arkansas alkaline province, its geologic and structural framework, and critical mineral potential.

Arkansas

From critical minerals to food security, the benefits of data collaboration

The volume of data in the public geoscience sphere is rapidly and continually expanding. At Geoscience Australia (GA) we saw an over 500% increase in data points within our relational databases between 2018 and 2024, over the life of the Exploring for the Future (EFTF) program. With the Resourcing Australia’s Prosperity initiative, a continued increase in data quantity will be seen for the next 10 to 35 years. At the same time, a broadening audience for geoscience data is increasing the desire to enhance the diversity of delivery streams. This ranges from data-dense highly technical outputs for geoscience specialists to curated interpretive products for people who are non-geoscientists. Development of these curated outputs has contributed to our awareness of the need for data to be collected and compiled in a way that ensures its reuse, with a focus on quality metadata and data provenance.

Conference Paper

Chemostratigraphy of the Cretaceous Hue Shale in Arctic Alaska: Exploring paleoceanographic controls on trace element enrichment, organic matter accumulation, and source-rock evolution

We document chemostratigraphy in an outcrop of late Albian to early Campanian (∼103–82 Ma) marine source rocks to better understand paleoenvironmental controls on trace element (TE) enrichment and organic matter accumulation in the distal Colville foreland basin of Arctic Alaska and how those drivers are linked to arc volcanism and successions of Cretaceous oceanographic and climatic biogeochemical events. This unique, 113-m-thick section of Cretaceous Hue Shale deposited during a series of previously undocumented Arctic Cretaceous oceanic anoxic events (Lease et al., 2024) is the only known exposure of thermally immature (0.48–0.52% R o , random vitrinite reflectance) Hue Shale in Arctic Alaska. Strata comprise mainly clay-rich mudstone with elevated total organic carbon (TOC) and hydrogen index values reaching 26.3 wt% (mean = 7.5 wt%) and 689 mg hydrocarbon (HC)/g TOC (mean = 385 mg HC/g TOC), respectively. Maceral composition consists predominantly of fluorescent amorphous organic matter, with abundant brightly fluorescent alginite, including Tasmanites , acritarchs, and Leiosphaeridia . Discrete layers of volcanic ash (preserved as bentonite) are present throughout the section and provide quantitative age control based on U–Pb dates. Chemostratigraphic trends are investigated to advance our understanding of local oceanographic conditions and controls on stratigraphic and temporal heterogeneity of Brookian source rocks. Concurrent sedimentary enrichment in Mo, U, V, Pb, and Cu across the Albian–Cenomanian boundary of the exposed basal gamma-ray zone, may reflect anoxic to euxinic benthic redox conditions favoring organic matter accumulation and preservation. Fluctuating degrees of anoxia-euxinia are inferred throughout the overlying Hue Shale succession, reflected by varying patterns of TE enrichment and TE–TOC covariation. Elevated C org /P molar ratios (>250) across most of the section, with several values exceeding 690, signify that enhanced biological productivity is sustained throughout deposition. Enhanced productivity, recorded by both C org /P and excess Ba, also parallels increases in source rock richness (elevated TOC and S 2 values) during the late Albian–early Cenomanian and late Cenomanian – Turonian. Enhanced productivity and variations in oceanic circulation/stratification likely both drove changes in benthic redox conditions that favored organic carbon accumulation and preservation. Increased continental arc volcanism (e.g., Okhotsk–Chukotka volcanic belt) and High Arctic Large Igneous Province magmatic eruptions throughout the Cretaceous, inferred to have influenced nutrient cycling and local aqueous nutrient availability, also have been invoked as potential drivers of organic carbon burial and source-rock development across the sedimentary sequence. Results presented here document the organic-rich and oil-prone source-rock quality of the Hue Shale in the distal part of the Colville foreland basin and bolster the potential for a Cretaceous petroleum system beneath the eastern North Slope.

Alaska

Don’t Let Negatives Hold You Back: Accounting for Underlying Physics and Natural Distributions of Hydrothermal Systems When Selecting Negative Training Sites Leads to Better Machine Learning Predictions

Selecting negative training sites is an important challenge to resolve when utilizing machine learning (ML) for predicting hydrothermal resource favorability because ideal models would discriminate between hydrothermal systems (positives) and all types of locations without hydrothermal systems (negatives). The Nevada Machine Learning project (NVML) fit an artificial neural network to identify areas favorable for hydrothermal systems by selecting 62 negative sites where the research team had confidence that no hydrothermal resource exists. Herein, we compare the implications of the expert selection of negatives (i.e., the NVML strategy) with a random sample strategy, where it is assumed that areas outside the favorable structural ellipses defined by NVML are negative. Because hydrothermal systems are sparse, it is highly probable that, in the absence of a favorable geological structure, hydrothermal favorability is low. We compare three training strategies: 1) the positive and negative labeled examples from NVML; 2) the positive examples from NVML with randomly selected negatives in equal frequency as NVML; and 3) the positive examples from NVML with randomly selected negatives reflecting the expected natural distribution of hydrothermal systems relative to the total area. We apply these training strategies to the NVML feature data (input data) using two ML algorithms (XGBoost and logistic regression) to create six favorability maps for hydrothermal resources. When accounting for the expected natural distribution of hydrothermal systems, we find that XGBoost performs better than the NVML neural network and its negatives. Model validation was less reliable using F1 scores, a common performance metric, than comparing probability estimates at known positives, likely because of the extreme natural class imbalance and the lack of negatively labeled sites. This work demonstrates that expert selection of negatives for training in NVML likely imparted modeling bias. Accounting for the sparsity of hydrothermal systems and all the types of locations without hydrothermal systems allows us to create better models for predicting hydrothermal resource favorability.

Geothermal Resources Council Transactions

Sediment thickness map of United States Atlantic and Gulf Coastal Plain Strata, and their influence on earthquake ground motions

With the recent successful accounting of basin depth ground-motion adjustments in seismic hazard analyses for select areas of the western United States, we move toward implementing similar adjustments in the Atlantic and Gulf Coastal Plains by constructing a sediment thickness model and evaluating multiple relevant site amplification models for central and eastern United States seismic hazard analyses. We digitize and combine existing sediment thickness data sets into a composite surface that delineates the base of Cretaceous sediments under the Atlantic Coastal Plain and the base of Mesozoic sediments under the Gulf Coastal Plain. Amplification models dependent on sediment thickness, site natural period, and source-to-site path length are compared with data sets of observed ground motions to evaluate the ability of the new models to improve ground motion estimates. We find that the amplification models can account for observed trends in sediment-thickness and period-dependent residuals, but some tuning is required. For example, the model of Chapman and Guo requires a reference V S 30 , the time-averaged shear-wave velocity within 30 m of the Earth’s surface, for non-Coastal Plain sites, which we estimate to be between about 1 and 2 km/s. Along with our sediment thickness model, we estimate a velocity profile for application to the Harmon et al. site-natural-period-based model in order to best match the Chapman and Guo period dependence for a broad range of sediment thicknesses. The Next Generation of Attenuation models for the eastern United States Gulf Coast path-based adjustment models can also account for seismic attenuation in the Coastal Plain sediments and reduce the standard deviation of total residuals. If enacted in the U.S. Geological Survey National Seismic Hazard Model, these amplification models will reduce predicted short-period (<1 s) and increase predicted long-period (>1 s) ground motions in the Coastal Plains appreciably.

Earthquake Spectra

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts

Classification of lakebed geologic substrate in autonomously collected benthic imagery using machine learning

Mapping benthic habitats with bathymetric, acoustic, and spectral data requires georeferenced ground-truth information about habitat types and characteristics. New technologies like autonomous underwater vehicles (AUVs) collect tens of thousands of images per mission making image-based ground truthing particularly attractive. Two types of machine learning (ML) models, random forest (RF) and deep neural network (DNN), were tested to determine whether ML models could serve as an accurate substitute for manual classification of AUV images for substrate type interpretation. RF models were trained to predict substrate class as a function of texture, edge, and intensity metrics (i.e., features) calculated for each image. Models were tested using a manually classified image dataset with 9-, 6-, and 2-class schemes based on the Coastal and Marine Ecological Classification Standard (CMECS). Results suggest that both RF and DNN models achieve comparable accuracies, with the 9-class models being least accurate (~73–78%) and the 2-class models being the most accurate (~95–96%). However, the DNN models were more efficient to train and apply because they did not require feature estimation before training or classification. Integrating ML models into benthic habitat mapping process can improve our ability to efficiently and accurately ground-truth large areas of benthic habitat using AUV or similar images.

Michigan, Wisconsin

System characterization report on the Environmental Mapping and Analysis Program (EnMAP)

This report addresses system characterization of the Environmental Mapping and Analysis Program hyperspectral sensor by the DLR (German Aerospace Center, ground segment project management), GFZ (Deutsches Geoforschungszentrum, science lead) and is part of a series of system characterization reports produced and delivered by the U.S. Geological Survey Earth Resources Observation and Science Cal/Val Center of Excellence. These reports present and detail the methodology and procedures for characterization; present technical and operational information about the EnMAP hyperspectral sensor; and provide a summary of test measurements, data retention practices, data analysis results, and conclusions. The Earth Resources Observation and Science Cal/Val Center of Excellence system characterization team completed data analyses to characterize the geometric (interior and exterior), and radiometric performances of the EnMAP hyperspectral sensor. Results of these analyses indicate that the Environmental Mapping and Analysis Program has a band-to-band geometric performance in the range of −0.135 to 0.15 pixel, geometric performance relative to the Operational Land Imager in the range of −27.716 meters (−0.92 pixel) to 32.892 meters (1.09 pixels) offset in comparison to Landsat 8 Operational Land Imager, offset of a radiometric comparison in the range of −0.012 to 0.020, slope of a radiometric comparison in the range of 0.947 to 1.031.

Open-File Report

Measurement of in situ-produced cosmogenic nuclides in fine-grained quartz from shale

In situ -produced 10 Be in quartz is widely used to constrain exposure ages and denudation rates, traditionally measured in sand-sized grains. Here we report a new method for isolating fine-grained quartz from shale and demonstrate its reliability for grain sizes down to single microns. Sequential dissolution tests and analyses of grain size separates show that meteoric 10 Be is eliminated and that recoil losses during cosmogenic nuclide production are balanced by implantation from other mineral grains. High-temperature combustion leads to diffusion of meteoric 10 Be into fine-grained quartz and must be used with caution.

Nuclear Instruments and Methods in Physics Researc

Groundwater surveillance of swine pathogens from private wells supplying swine farms in Iowa

Biosecurity practices are essential for maintaining pig health and productivity. Despite these measures, pathogen spread still occurs. Water is one of the largest daily inputs on swine farms by volume and is not routinely tested or disinfected before it is consumed by the animals [1-3], making it a poorly understood biosecurity risk. Groundwater from privately-owned wells is a common water source for swine farms. Pathogens in the landscape, such as bacteria, viruses, and protozoa, can reach groundwater more rapidly through soil macropores, maintaining viability and facilitating transmission of pathogens into aquifers [3-13].

Iowa