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Water quality in the Arthur R. Marshall Loxahatchee National Wildlife Refuge — Trends and spatial characteristics of selected constituents, 1974-2004

Water quality in the interior marsh of the Arthur R. Marshall Loxahatchee National Wildlife Refuge is characterized by low concentrations of major ions, principally sodium and chloride, and is affected primarily by natural seasonal processes, such as evapotranspiration, rainfall, and biological activity. During the dry season, evapotranspiration exceeds precipitation, and specific conductance and conservative ion concentrations at marsh background sites typically increase by 40-70 percent between the end of the rainy season in September and the end of the dry season in May. Water enters the Refuge mainly from rainfall and perimeter canals. Water is pumped into the perimeter canals from large pumping stations, such as S-5A and S-6. In recent years, much of the water pumped into the Refuge passes through Stormwater Treatment Areas (STAs) before being released into the perimeter canals that surround the Refuge. Since 2001, water at S-6 has been diverted south toward STA-2, away from the Refuge perimeter canals. Water from S-5A and S-6 flows through agricultural lands with intense agricultural activity and typically contains relatively high concentrations of major ions, nutrients, and pesticides. Specific conductance, major-ion concentrations, and nutrient concentrations are an order of magnitude higher at S-5A and S-6 canal sites than at interior marsh sites. Water quality in the marsh bordering the canals can be affected substantially by the canal water, and these effects can extend several miles or more into the marsh depending on location in the Refuge and on the water level in the canals. As canal water flows into the marsh, processes such as uptake by periphyton and rooted vegetation and settling of particulate matter reduce the concentrations of nutrients to a greater extent than conservative ions such as chloride. Long- and short-term trends for specific conductance, chloride ion, sulfate ion, total phosphorus, and total nitrogen at five sites were evaluated primarily using an uncensored seasonal Kendall test with a water-level adjustment to reduce the effects of long wet or dry periods. Significant long-term trends (1974-2003) for specific conductance, chloride, total phosphorus, and total nitrogen at canal sites S-5A and S-6 were generally downward. Of the five sites, S-5A had the most pronounced decline for specific conductance at about -340 microsiemens per centimeter (?S/cm), followed by S-6 with a decline of about -280 ?S/cm. The two internal marsh sites, LOX8 and LOX13, had significant long-term trends in specific conductance of about +37 and -36 ?S/cm, respectively. Long-term trends for other constituents at the two internal marsh sites were generally small in magnitude or not measurable between 1978 and 2003. Marsh site LOX15 near the Hillsboro Canal showed no long-term trends, although specific conductance and sulfate concentration increased about 560 ?S/cm and 30 milligrams per liter, respectively, from 1998 to 2002. Site LOX15 is influenced strongly by intrusions of canal water, and increases in specific conductance and sulfate at this site coincided with increased canal-water inflows from STA-1W between 2001 and 2003. Median concentrations at LOX13 and S-5A were used to represent background and canal concentrations, respectively. Based on these values, the median chloride concentration at LOX15 indicates that the water is typically about 31 percent canal water and 69 percent ?natural? background water. Using median sulfate concentrations, similarly to chloride, the fraction of water at LOX15 was estimated to be 17 percent from canals and 83 percent from ?natural? background water. This finding suggests that in the low sulfate environment of the Refuge, sulfate is not conservative and only about half of the sulfate from canal water typically reaches LOX15; the rest presumably is removed by marsh plants, algae, and bottom sediments. Concentrations of pesticides and other organic compounds were measured

Florida↗

Walleye in Lake Erie and Lake St. Clair

The history and current status of walleye (Stizostedion vitreum vitreum) stocks in Lake Erie and Lake St. Clair are reviewed in relation to their exploitation by commercial and recreational fishermen, environmental factors, rehabilitation efforts, and community dynamics. Management initiatives and stock recovery under these processes are outlined. After the collapse of the fishery in 1957, the highly productive walleye stock of western Lake Erie remained depressed through the 1960s, while the eastern basin stock remained stable. Closure of the fishery for walleye from 1970-73 because of mercury contamination provided an opportunity for the development of an international interagency management plan. With quota management, the walleye stock in western Lake Erie responded well to limited exploitation, steadily increased, and expanded its range. As population expanded, growth began to decline and was more apparent in the young-of-the-year (YOY) in the 1970s, and in older walleye in the late 1970s and 1980s. At the turn of the century, commercial harvest of walleye in Lake St. Clair ranged from 12-127 tonnes annually. A relatively stable period from 1910-59 was followed by significantly increased harvests (100-150 t) in 1959-65. This increase was a result of increased commercial exploitation as well as an increased abundance of walleye. After the mercury contamination problem of 1970, angling effort and harvest was reduced but then gradually increased in Ontario waters from 37 t in 1973 to 62 t in 1988. The increased mean age of the stock during the early 1970s was due to a few strong year-classes (1970, 1972, and 1974) as well as a period of stable or reduced catch per unit effort. With the current mean age not reduced significantly, the stocks of walleye should continue to provide good yields.

Special Publication↗

An objective replacement method for censored geochemical data

Geochemical data are commonly censored, that is, concentrations for some samples are reported as "less than" or "greater than" some value. Censored data hampers statistical analysis because certain computational techniques used in statistical analysis require a complete set of uncensored data. We show that the simple substitution method for creating an uncensored dataset, e.g., replacement by 3/4 times the detection limit, has serious flaws, and we present an objective method to determine the replacement value. Our basic premise is that the replacement value should equal the mean of the actual values represented by the qualified data. We adapt the maximum likelihood approach (Cohen, 1961) to estimate this mean. This method reproduces the mean and skewness as well or better than a simple substitution method using 3/4 of the lower detection limit or 3/4 of the upper detection limit. For a small proportion of "less than" substitutions, a simple-substitution replacement factor of 0.55 is preferable to 3/4; for a small proportion of "greater than" substitutions, a simple-substitution replacement factor of 1.7 is preferable to 4/3, provided the resulting replacement value does not exceed 100%. For more than 10% replacement, a mean empirical factor may be used. However, empirically determined simple-substitution replacement factors usually vary among different data sets and are less reliable with more replacements. Therefore, a maximum likelihood method is superior in general. Theoretical and empirical analyses show that true replacement factors for "less thans" decrease in magnitude with more replacements and larger standard deviation; those for "greater thans" increase in magnitude with more replacements and larger standard deviation. In contrast to any simple substitution method, the maximum likelihood method reproduces these variations. Using the maximum likelihood method for replacing "less thans" in our sample data set, correlation coefficients were reasonably accurately estimated in 90% of the cases for as much as 40% replacement and in 60% of the cases for 80% replacement. These results suggest that censored data can be utilized more than is commonly realized. ?? 1993 International Association for Mathematical Geology.

Mathematical Geology↗

Historical patterns of wildfire ignition sources in California ecosystems

State and federal agencies have reported fire causes since the early 1900s, explicitly for the purpose of helping land managers design fire-prevention programs. We document fire-ignition patterns in five homogenous climate divisions in California over the past 98 years on state Cal Fire protected lands and 107 years on federal United States Forest Service lands. Throughout the state, fire frequency increased steadily until a peak c. 1980, followed by a marked drop to 2016. There was not a tight link between frequency of ignition sources and area burned by those sources and the relationships have changed over time. Natural lightning-ignited fires were consistently fewer from north to south and from high to low elevation. Throughout most of the state, human-caused fires dominated the record and were positively correlated with population density for the first two-thirds of the record, but this relationship reversed in recent decades. We propose a mechanistic multi-variate model of factors driving fire frequency, where the importance of different factors has changed over time. Although ignition sources have declined markedly in recent decades, one notable exception is powerline ignitions. One important avenue for future fire-hazard reduction will be consideration of solutions to reduce this source of dangerous fires.

California↗

Hydrology, water quality, and nutrient loads to Lake Catherine and Channel Lake, near Antioch, Lake County, Illinois

From April 21, 1998, through April 30, 1999, the U.S. Geological Survey, in cooperation with the Fox Waterway Agency, conducted an investigation designed to characterize the hydrology, water quality, hydrologic budget, sediment budget, and nutrient budget of Lake Catherine and Channel Lake, Lake County, Illinois. These lakes are the northernmost lakes of the Fox Chain of Lakes. Lake Catherine and Channel Lake are divided into two basins by a submerged ridge but are continuous at the surface. The lakes are marginally to moderately eutrophic. Lake Catherine and Channel Lake have a combined volume of 7,098 acre-feet at a stage of about 736.5 feet above sea level. Lake Catherine and Channel Lake are subject to thermal stratification. Although most of the water in the lakes is well oxidized, nearly anoxic conditions were present at the bottom of Lake Catherine and Channel Lake during part of the summer in 1998. Water enters Lake Catherine and Channel Lake as inflow from surface water in the watershed (61.9 percent), inflow through the State Highway 173 bridge openings (20.7 percent), direct precipitation (8.2 percent), inflow from storm drains (7.2 percent), and inflow of ground water (2.0 percent). Water exits Lake Catherine and Channel Lake as outflow through the State Highway 173 bridge openings (87.8 percent), evaporation (7.2 percent), and as outflow to ground water (5.0 percent). About 5,200 pounds of phosphorus and 107,200 pounds of nitrogen compounds were added to the lakes during the period of investigation. Phosphorus compounds were derived from primarily internal regeneration (40.2 percent), inflow from surface water in the watershed (30.9 percent), inflow from storm drains (12.5 percent), and inflow through the State Highway 173 bridge openings (9.8 percent). Inflowing ground water, waterfowl excrement, precipitation, and atmospheric deposition of particulate matter account for 6.6 percent of the phosphorus load. Nitrogen was derived from inflow of surface water from within the watershed (52.9 percent), internal regeneration (19.5 percent), inflow through the State Highway 173 bridge openings (10.7 percent), precipitation (7 percent), and inflow from storm drains (6.5 percent). Inflowing ground water, waterfowl excrement, and atmospheric deposition of particulate matter account for about 3.4 percent of the nitrogen load. About 2,220 pounds of phosphorus and 52,300 pounds of nitrogen compounds are removed from the lakes, primarily through the openings at State Highway 173. Nitrate, nitrite, ammonia, and dissolved phosphorus are utilized by algae and aquatic macrophytes. Uptake of these nutrients by aquatic macrophytes and algae temporarily removes them from the water column but not from the lake basin. Because the amount of nutrients entering the lake greatly exceeds the amount leaving, the nutrients are concentrated in the sediments at the lake bottom, where the nutrients can be used by the rooted aquatic macrophytes (rooted aquatic plant large enough to be visible to the unaided eye) and released to the water column during reducing conditions. The buildup of nitrogen and phosphorus compounds in the lakes has the potential over time to stimulate algal and plant growth to nuisance levels that have the potential to affect the fishery and detract from the aesthetic quality of these lakes.

Water-Resources Investigations Report↗

Simplification of polylines by segment collapse: Minimizing areal displacement while preserving area

This paper reports on a new Area Preserving Segment Collapse (APSC) algorithm for simplifying polygonal boundaries while preserving polygonal area at simplified target scales and minimizing areal displacement. A general segment collapse algorithm is defined by iteratively collapsing segments to Steiner points in priority order, guided by placement and displacement functions. The algorithm is specified by defining functions that minimize areal displacement under the constraint that the areas of adjoining polygons are preserved exactly. Self-intersections can be avoided by testing for intersections with two new line segments associated with each segment collapse operation. The paper demonstrates simplification results for a sample of 10 lakes formed from alpine, Karst, glacial and arid desert processes as well as artificial dams. APSC results are compared with three other simplification routines and evaluated for area preservation, linear and areal displacement, complexity and introduction of boundary self-intersections. Results confirm that the APSC algorithm preserves area exactly and indicate that it outperforms the other tested algorithms for minimizing areal displacement while producing reasonably low measures of linear displacement. Self-intersections can occur more commonly with APSC than other algorithms but are avoided with the proposed topology check. The APSC algorithm additionally preserves polygon complexity better than other tested algorithms.

International Journal of Cartography↗

Hawai‘i and U.S.-Affiliated Pacific Islands

The U.S. Pacific Islands are culturally and environmentally diverse, treasured by the 1.9 million people who call them home. Pacific islands are particularly vulnerable to climate change impacts due to their exposure and isolation, small size, low elevation (in the case of atolls), and concentration of infrastructure and economy along the coasts. A prevalent cause of year-to-year changes in climate patterns around the globe and in the Pacific Islands region is the El Niño –Southern Oscillation (ENSO). The El Niño and La Niña phases of ENSO can dramatically affect precipitation, air and ocean temperature, sea surface height, storminess, wave size, and trade winds. It is unknown exactly how the timing and intensity of ENSO will continue to change in the coming decades, but recent climate model results suggest a doubling in frequency of both El Niño and La Niña extremes in this century as compared to the 20th century under scenarios with more warming, including the higher scenario (RCP8.5). On islands, all natural sources of freshwater come from rainfall received within their limited land areas. Severe droughts are common, making water shortage one of the most important climate-related risks in the region. As temperature continues to rise and cloud cover decreases in some areas, evaporation is expected to increase, causing both reduced water supply and higher water demand. Streamflow in Hawai‘i has declined over approximately the past 100 years, consistent with observed decreases in rainfall. The impacts of sea level rise in the Pacific include coastal erosion, episodic flooding, permanent inundation, heightened exposure to marine hazards, and saltwater intrusion to surface water and groundwater systems. Sea level rise will disproportionately affect the tropical Pacific and potentially exceed the global average. Invasive species , landscape change, habitat alteration, and reduced resilience have resulted in extinctions and diminished ecosystem function. Inundation of atolls in the coming decades is projected to impact existing on-island ecosystems. Wildlife that relies on coastal habitats will likely also be severely impacted. In Hawaiʻi, coral reefs contribute an estimated $477 million to the local economy every year. Under projected warming of approximately 0.5°F per decade, all nearshore coral reefs in the Hawai‘i and Pacific Islands region will experience annual bleaching before 2050. An ecosystem -based approach to international management of open ocean fisheries in the Pacific that incorporates climate-informed catch limits is expected to produce more realistic future harvest levels and enhance ecosystem resilience. Indigenous communities of the Pacific derive their sense of identity from the islands. Emerging issues for Indigenous communities of the Pacific include the resilience of marine-managed areas and climate-induced human migration from their traditional lands. The rich body of traditional knowledge is place-based and localized and is useful in adaptation planning because it builds on intergenerational sharing of observations. Documenting the kinds of governance structures or decision-making hierarchies created for management of these lands and waters is also important as a learning tool that can be shared with other island communities. Across the region, groups are coming together to minimize damage and disruption from coastal flooding and inundation as well as other climate-related impacts. Social cohesion is already strong in many communities, making it possible to work together to take action. Early intervention can lower economic, environmental, social, and cultural costs and reduce or prevent conflict and displacement from ancestral land and resources.

Report↗

The U.S. Geological Survey Land Remote Sensing Program

In 2002, the U. S. Geological Survey (USGS) launched a program to enhance the acquisition, preservation, and use of remotely sensed data for USGS science programs, as well as for those of cooperators and customers. Remotely sensed data are fundamental tools for studying the Earth's land surface, including coastal and near-shore environments. For many decades, the USGS has been a leader in providing remotely sensed data to the national and international communities. Acting on its historical topographic mapping mission, the USGS has archived and distributed aerial photographs of the United States for more than half a century. Since 1972, the USGS has acquired, processed, archived, and distributed Landsat and other satellite and airborne remotely sensed data products to users worldwide. Today, the USGS operates and manages the Landsats 5 and 7 missions and cooperates with the National Aeronautics and Space Administration (NASA) to define and implement future satellite missions that will continue and expand the collection of moderate-resolution remotely sensed data. In addition to being a provider of remotely sensed data, the USGS is a user of these data and related remote sensing technology. These data are used in natural resource evaluations for energy and minerals, coastal environmental surveys, assessments of natural hazards (earthquakes, volcanoes, and landslides), biological surveys and investigations, water resources status and trends analyses and studies, and geographic and cartographic applications, such as wildfire detection and tracking and as a source of information for The National Map. The program furthers these distinct but related roles by leading the USGS activities in providing remotely sensed data while advancing applications of such data for USGS programs and a wider user community.

Fact Sheet↗

Geologic Map of the Sheep Hole Mountains 30' x 60' Quadrangle, San Bernardino and Riverside Counties, California

This data set describes and maps the geology of the Sheep Hole Mountains 30' x 60' quadrangle in southern California. The quadrangle covers an area of the Mojave Desert characterized by desert ranges separated by broad basins. Ranges include parts of the Old Woman, Ship, Iron, Coxcomb, Pinto, Bullion, and Calumet mountains as well as Lead Mountain and the Kilbeck Hills. Basins include part of Ward Valley, part of Cadiz Valley including Cadiz Lake playa, and broad valleys occupied by the Bristol Lake and Dale Lake playas. Bedrock geologic units in the ranges range in age from Proterozoic to Quaternary. The valleys expose Neogene and Quaternary deposits. Proterozoic granitoids in the quadrangle include the Early Proterozoic Fenner Gneiss, Kilbeck Gneiss, Dog Wash Gneiss, granite of Joshua Tree, the (highly peraluminous granite) gneiss of Dry Lakes valley, and a Middle Proterozoic granite. Proterozoic supracrustal rocks include the Pinto Gneiss of Miller (1938) and the quartzite of Pinto Mountain. Early Proterozoic orogeny left an imprint of metamorphic mineral assemblages and fabrics in the older rocks. A Cambrian to Triassic sequence deposited on the continental shelf lies above a profound nonconformity developed on the Proterozoic rocks. Small metamorphosed remnants of this sequence in the quadrangle include rocks correlated to the Tapeats, Bright Angel, Bonanza King, Redwall, Bird Spring, Hermit, Coconino, Kaibab, and Moenkopi formations. The Dale Lake Volcanics (Jurassic), and the McCoy Mountains Formation of Miller (1944)(Cretaceous and Jurassic?) are younger Mesozoic synorogenic supracrustal rocks in the quadrangle. Mesozoic intrusions form much of the bedrock in the quadrangle, and represent a succession of magmatic arcs. The oldest rock is the Early Triassic quartz monzonite of Twentynine Palms. Extensive Jurassic magmatism is represented by large expanses of granitoids that range in composition from gabbro to syenogranite. They include the Virginia May Quartz Monzonite and other members of the Bullion Intrusive Suite, the Chubbock Porphyry, and rocks that form the Goat Basin pluton, Music Valley pluton, and Ship Mountains pluton. The Jurassic plutons range in emplacement depths from mid-crustal to hypabysasal. Mafic and felsic dikes that probably are part of the Late Jurassic Independence dike swarm intrude the Jurassic batholithic rocks. A Mesozoic ductile fault (tectonic slide), the Scanlon thrust, places an inverted sequence of lower Paleozoic rocks and their Proterozoic basement over a lower plate of younger Paleozoic and Triassic rocks. The lower- plate rocks are internally sliced and folded. They in turn are superposed along an attenuation tectonic slide, the Kilbeck fault, over highly strained tectonic schist. The major tectonic slides and associated fabrics are cut by Late Cretaceous batholithic rocks. Widespread Late Cretaceous granitoids assigned to the Cadiz Valley batholith and the Old-Woman Piute Range batholith together form a contiguous super-unit of granite and granodiorite compositions. The Old- Woman Piute Range batholith includes the granite of Sweetwater Wash in the Painted Rock pluton and the Old Woman Mountains Granodiorite forming the Old Woman pluton. The large Cadiz Valley batholith is divided into the Iron Mountains Intrusive Suite and the Coxcomb Intrusive Suite. The Iron Mountains Intrusive Suite includes the Granite Pass Granite (which forms the Granite Pass pluton), the Danby Lake Granite Gneiss, and the Iron Granodiorite Gneiss. The Coxcomb Intrusive Suite consists of many units including the Clarks Pass Granodiorite, the Sheep Hole Mountains Granodiorite (forms the Sheep Hole Mountains pluton), and the Sheep Hole Pass Granite (forms the Sheep Hole Pass pluton). The Cretaceous rocks were emplaced at a range of deep to shallow depths, and their intrusion resulted in an aureole 2-3 km wide in older rocks. Mylonitic fabrics developed through a thickness of >1.3 km, together

Miscellaneous Field Studies Map↗

Connecticut and Landsat

Connecticut, the third-smallest State by land area, is the fourth most densely populated in the United States. Connecticut’s tightly packed cities serve as international hubs for the finance and insurance industries. These same urban enclaves host highly regarded institutions of higher learning, such as Yale, the University of Connecticut, and Quinnipiac and Wesleyan Universities. Yet Connecticut has surprisingly varied natural features. Its residents are never far from pristine environments that teem with wildlife and convey the sounds, scents, and scenery of the natural world. The Connecticut River, the longest in New England at 407 miles, cuts through the State’s center and drains into Long Island Sound, as do the Thames and Housatonic Rivers. Together, these rivers form an estuary spawning ground for hundreds of freshwater and saltwater aquatic species. North and east of the coastal lowlands that hug the estuary are the highlands of the Southern Taconic Range and the Berkshires. North and west of the coastline, smaller rivers and valleys weave through densely forested landscapes dotted with State parks and scenic lakes. Imagery from the U.S. Geological Survey Landsat archive, a trusted public resource with more than 50 years of worldwide Earth observations, provides a powerful tool for analyzing the interplay of human habitation and natural landscapes in Connecticut. Landsat data also offer land managers a critical information source for managing damage from invasive species and monitoring the local landscape effects of changing environmental conditions .

Connecticut↗

Groundwater quality in the Antelope Valley, California

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. Antelope Valley is one of the study areas being evaluated. The Antelope study area is approximately 1,600 square miles (4,144 square kilometers) and includes the Antelope Valley groundwater basin (California Department of Water Resources, 2003). Antelope Valley has an arid climate and is part of the Mojave Desert. Average annual rainfall is about 6 inches (15 centimeters). The study area has internal drainage, with runoff from the surrounding mountains draining towards dry lakebeds in the lower parts of the valley. Land use in the study area is approximately 68 percent (%) natural (mostly shrubland and grassland), 24% agricultural, and 8% urban. The primary crops are pasture and hay. The largest urban areas are the cities of Palmdale and Lancaster (2010 populations of 152,000 and 156,000, respectively). Groundwater in this basin is used for public and domestic water supply and for irrigation. The main water-bearing units are gravel, sand, silt, and clay derived from surrounding mountains. The primary aquifers in Antelope Valley are defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health database. Public-supply wells in Antelope Valley are completed to depths between 360 and 700 feet (110 to 213 meters), consist of solid casing from the land surface to a depth of 180 to 350 feet (55 to 107 meters), and are screened or perforated below the solid casing. Recharge to the groundwater system is primarily runoff from the surrounding mountains, and by direct infiltration of irrigation and sewer and septic systems. The primary sources of discharge are pumping wells and evapotranspiration near the dry lakebeds.

California↗

Major, trace element and isotope geochemistry (Sr-Nd-Pb) of interplinian magmas from Mt. Somma-Vesuvius (Southern Italy)

Major, trace element and isotopic (Sr, Nd, Pb) data are reported for representative samples of interplinian (Protohistoric, Ancient Historic and Medieval Formations) activity of Mt. Somma-Vesuvius volcano during the last 3500 years. Tephra and lavas exhibit significant major, trace element and isotopic variations. Integration of these data with those obtained by previous studies on the older Somma suites and on the latest activity, allows to better trace a complete petrological and geochemical evolution of the Mt. Somma-Vesuvius magmatism. Three main groups of rocks are recognized. A first group is older than 12.000 yrs, and includes effusive-explosive activity of Mt. Somma. The second group (8000-2700 yrs B.P.) includes the products emitted by the Ottaviano (8000 yrs. B.P.) and Avellino (3550 yrs B.P.) plinian eruptions and the interplinian activity associated with the Protohistoric Formation. Ancient Historic Formation (79-472 A.D.), Medieval Formation (472-1139 A.D.) and Recent interplinian activity (1631-1944 A.D.) belong to the third group of activity (79-1944 A.D.). The three groups of rocks display distinct positive trends of alkalis vs. silica, which become increasingly steeper with age. In the first group there is an increase in silica and alkalis with time, whereas an opposite tendency is observed in the two younger groups. Systematic variations are also evident among the incompatible (Pb, Zr, Hf, Ta, Th, U, Nb, Rb, Cs, Ba) and compatible elements (Sr, Co, Cr). REE document variable degrees of fractionation, with recent activity displaying higher La/Yb ratios than Medieval and Ancient Historic products with the same degree of evolution. N-MORB normalized multi-element diagrams for interplinian rocks show enrichment in Rb, Th, Nb, Zr and Sm (> *10 N-MORB). Sr isotope ratios are variable, with Protohistoric rocks displaying 87Sr/86Sr= 0.70711-0.70810, Ancient Historic 87Sr/86Sr=0.70665-0.70729, and Medieval 87Sr/86Sr=0.70685-0.70803. Neodymium isotopic compositions in the interplinian rocks show a tendency to become slightly more radiogenic with age, from the Protohistoric (143Nd/144Nd=0.51240-0.51247) to Ancient Historic (143Nd/144Nd=0.51245-0.51251). Medieval interplinian activity (143Nd/144Nd: 0.51250-0.51241) lacks meaningful internal trends. All the interplinian rocks have virtually homogeneous compositions of 207Pb/204Pb and 208Pb/204Pb in acid-leached residues (207Pb/204Pb ???15.633 to 15.687, 208Pb/204Pb ???38.947 to 39.181). Values of 206Pb/204Pb are very distinctive, however, and discriminate among the three interplinian cycles of activity (Protohistoric: 18.929-18.971, Ancient Historic: 19.018-19.088, Medieval: 18.964-19.053). Compositional trends of major, trace element and isotopic compositions clearly demonstrate strong temporal variations of the magma types feeding the Somma-Vesuvius activity. These different trends are unlikely to be related only to low pressure evolutionary processes, and reveal variations of parental melt composition. Geochemical data suggest a three component mixing scheme for the interplinian activity. These involve HIMU-type and DMM-type mantle and Calabrian-type lower crust. Interaction between these components has taken place in the source; however, additional quantitative constraints must be acquired in order to better discriminate between magma characteristics inherited from the sources and those acquired during shallow level evolution.

Mineralogy and Petrology↗

Field note--Successful establishment of a phytoremediation system at a petroleum-hydrocarbon contaminated shallow aquifer--Trends, trials, and tribulations

We report the establishment of a mixed hybrid poplar ( Populus spp .) and willow ( Salix spp .) phytoremediation system at a fuel-contaminated site. Several approaches were used to balance competing goals of cost-effectiveness yet successful tree establishment without artificial irrigation or trenching. Bare root and unrooted cuttings were installed using either: (1) 1.2 m deep holes excavated with an 8 cm diameter auger using a direct-push rig and backfilled with the excavated, in situ soil; (2) 1.2 m deep holes created with a 23 cm diameter auger attached to a Bobcat rig and backfilled with clean topsoil from offsite; and (3) shallow holes between 15–30 cm deep that were created with a 1.3 cm diameter rod and no backfill. Tree mortality from initial plantings indicated contaminated zones not quantified in prior site investigations and remedial actions. Aquifer heterogeneity, underground utilities, and prior remediation infrastructure hampered the ability of the site to support a traditional experimental design. Total stem length and mortality were measured for all planted trees and were incorporated into a geographic information system. Planting early in the growing season, augering a larger diameter hole, and backfilling with clean, uncontaminated topsoil was cost effective and allowed for greater tree cutting growth and survival.

International Journal of Phytoremediation↗

Temporal trends and stationarity in annual peak flow and peak-flow timing for selected long-term streamflow-gaging stations in or near Montana through water year 2011: Chapter B in Montana StreamStats

A large-scale study by the U.S. Geological Survey, in cooperation with the Montana Department of Transportation and the Montana Department of Natural Resources and Conservation, was done to investigate general patterns in peak-flow temporal trends and stationarity through water year 2011 for 24 long-term streamflow-gaging stations (hereinafter referred to as gaging stations) in Montana. Hereinafter, all years refer to water years; a water year is the 12-month period from October 1 through September 30 and is designated by the year in which it ends. The primary focus of the study was to identify general patterns in peak-flow temporal trends and stationarity that are relevant to application of peak-flow frequency analyses within a statewide gaging-station network. Temporal trends were analyzed for two hydrologic variables: annual peak flow and peak-flow timing. Annual peak flow is the maximum instantaneous discharge, in cubic feet per second, recorded each year a gaging station was operated. Peak-flow timing is the day of the annual peak flow (hereinafter referred to as day of peak), recorded each year a gaging station was operated. Study results provide evidence that annual peak flow for most of the long-term gaging stations can be reasonably considered as stationary for application of peak-flow frequency analyses within a statewide gaging station network. Upward trends in annual peak flow during 1930–76 generally were stronger than downward trends during 1967–2011 for most long-term gaging stations. Statistical distributions of annual peak flow generally were similar among three summary time periods (1930–78, 1979–2011, and the entire period of record). However, for two low-elevation gaging stations in eastern Montana (Poplar River at international boundary [gaging station 06178000] and Powder River at Moorhead, Montana [gaging station 06324500]), substantial downward trends in annual peak flow during 1967–2011 were of similar or stronger magnitude than the upward trends during 1930–76, and the annual-peak-flow medians for 1979–2011 were substantially lower than the medians for the entire period of record. For peak-flow timing for most long-term gaging stations, differences in trends between 1930–76 and 1967–2011 are variable and not particularly strong. Statistical distributions generally are similar among the summary time periods. However, for two high-elevation gaging stations on a Missouri River headwater tributary (Gallatin River near Gallatin Gateway, Montana [gaging station 06043500] and Gallatin River at Logan, Montana [gaging station 06052500]) and for five high-elevation gaging stations in the Yellowstone River Basin (Yellowstone River at Corwin Springs, Montana [gaging station 06191500], Yellowstone River near Livingston, Montana [gaging station 06192500], Clarks Fork Yellowstone River near Belfry, Montana [gaging station 06207500], Clarks Fork Yellowstone River at Edgar, Montana [gaging station 06208500], and Yellowstone River at Billings, Montana [gaging station 06214500]) downward trends in peak-flow timing during 1967–2011 generally were stronger than upward trends during 1930–1976, and day-of-peak medians for 1979–2011 were considerably less than medians for 1930–78. The downward trends in peak-flow timing for 1967–2011 indicate that the timing of annual peak flows changed from later in the year to earlier in the year. For the seven high-elevation gaging stations, the mean change during 1967–2011 was about 13 days (range of 8 to 22 days). For most of the high-elevation gaging stations in the Missouri River headwaters, Yellowstone River Basin, and Columbia River Basin, there was general correspondence between trend patterns for annual peak flow and trend patterns for peak-flow timing; that is, during periods when there were upward trends in annual peak flow, there generally also were upward trends in peak-flow timing. Conversely, during periods when there were downward trends in annual peak flow, there generally also were downward trends in peak-flow timing. The two low-elevation gaging stations in eastern Montana (Poplar River at international boundary [gaging station 06178000] and Powder River at Moorhead, Montana [gaging station 06324500]) had considerable changes in annual-peakflow characteristics after the mid-1970s, which might provide evidence of potential nonstationarity in the peak-flow records. The two low-elevation gaging stations that have potential nonstationarity are located in drainage basins that are strongly affected by agricultural activities that potentially affect the hydrologic regimes. Primary agricultural activities that might alter natural hydrologic conditions include construction of small impoundments (primarily for stock-watering purposes) and irrigation diversions. Temporal variability in these activities might contribute to the potential nonstationarity issues. Changes in climatic characteristics after the mid-1970s also possibly contribute to the potential nonstationarity issues. Lack of considerable indication of potential nonstationarity in annual peak flow for the other long-term gaging stations in this study might indicate that climatic changes have been more pronounced with respect to effects on peak flows in low elevation areas in eastern Montana than in areas represented by the other long-term gaging stations. Another possibility is that climatic changes after the mid-1970s are exacerbated in low-elevation areas where small-impoundment development and potential effects of irrigation diversions might be more extensive.

Montana↗

Summary of ground-water hydrology of the Cambrian-Ordovician aquifer system in the northern Midwest, United States

The Cambrian-Ordovician aquifer system contains very productive aquifers throughout an area of about 161,000 square miles in the northern Midwest. The aquifer system is used extensively for industrial and rural water supplies and is the primary source of water for many municipalities in most of its area of occurrence, except in Indiana, central and southern Illinois, and western Iowa, where the aquifer system contains saline water. About 680 million gallons per day was withdrawn from drilled wells in the aquifer system in 1980. Rocks of Cambrian and Ordovician age, mainly marine sandstones and carbonate rocks, constitute most of the bedrock and subcrop beneath glacial drift in southeastern Minnesota, northeastern Iowa, Wisconsin, northern Illinois, and extreme northwestern Indiana. These strata dip generally to the south and east off the Transcontinental arch in Minnesota and the Wisconsin arch, which are structurally high areas of the Precambrian basement, into the structural lows of the Forest City basin of southwestern Iowa, the Illinois basin, and the Michigan basin. The Cambrian and Ordovician rocks are buried by younger rocks in the remainder of Iowa, Illinois, and Indiana and in most of northern Missouri. Silurian and Devonian carbonate rocks immediately overlie the Cambrian and Ordovician rocks in those areas and are termed the "Silurian-Devonian aquifer" in this study. The balance of the Devonian rocks and the overlying Mississippian and Pennsylvanian rocks generally are fine-grained sediment or dense carbonate rocks and collectively are considered to be a regional confining unit. Most of the area is covered by a veneer of glacial drift, which, along with Cretaceous sandstone in northwestern Iowa, is treated as a regional water-table aquifer. The Cambrian-Ordovician aquifer system is composed of six hydrogeologic units, which are, in descending order, the Maquoketa confining unit, St. Peter-Prairie du Chien-Jordan aquifer, St. Lawrence- Franconia confining unit, Ironton-Galesville aquifer, Eau Claire confining unit, and Mount Simon aquifer. The uppermost confining unit is the least permeable; it consists primarily of the Maquoketa Shale but includes the dense carbonate rocks of the Galena Dolomite and the Decorah, Platteville, and Glenwood Formations where they are overlain by the Maquoketa Shale. The presence of the Maquoketa in Iowa, eastern Wisconsin, northeastern Illinois, and Indiana effectively confines the entire aquifer system below. The aquifer system is a leaky-artesian system in which movement of ground water is controlled partly by the internal confining units. In the northern outcrop area, unconfined conditions prevail in shallow parts of the aquifer system and where the system is thin. Much of the recharge in upland areas discharges to streams through local flow systems, which are no more than a few miles in length. The remainder of the recharge moves slowly downward to deeper formations and downgradient to form or join the regional flow system. Computer simulations of regional ground-water flow improve understanding of the regional character of the Cambrian-Ordovician aquifer system. Ground-water flow in the confined part of the aquifer system is mainly horizontal, away from the structural highs in the north, toward the structural basins in the south and east. The rate of ground-water movement is very slow, and the flux along flow paths into the basins decreases because of a progressive loss of head and small but widespread upward leakage. Saline water in the basins restricts movement of freshwater into the deeper parts of the basins, thereby forcing flow upward through confining units. Principal regional discharge areas are the Mississippi and Missouri Rivers, the Illinois and Michigan structural basins, and Lake Michigan. However, the lake is not in direct hydraulic connection with the Cambrian-Ordovician aquifer system and receives flow primarily from the Silurian-Devonian aquifer, which it directly overlies. The longest regional flow paths originate in recharge areas in northwestern Iowa and extend southeastward as much as 400 miles toward the Illinois basin. Simulated predevelopment recharge and discharge for the Cambrian- Ordovician aquifer system balance at 351 million gallons per day. Development of the aquifer system began in various parts of the northern Midwest in the 1860's and 1870's with the drilling of deep, generally flowing artesian wells near Lake Michigan in eastern Wisconsin and northeastern Illinois and along the valleys of the Mississippi River and its tributaries. Initial heads of 186 and 130 feet above Lake Michigan at Milwaukee and Chicago, respectively, have been reported. Large-scale pumping has produced cones of depression in these two areas, with respective head declines of as much as 375 and 900 feet. Other major pumping centers generally have had much smaller declines. The largest withdrawals from the aquifer system were about 180 million gallons per day in each of the major metropolitan areas of Chicago and Minneapolis-St. Paul (Twin Cities). However, the total decline in head in the St. Peter-Prairie du Chien-Jordan aquifer in the Twin Cities by 1980 was only 90 feet because the aquifer is unconfined. Most of the eastern two-thirds of Iowa, where the aquifer system is tightly confined, is characterized by more than 50 feet of head decline, with 200 feet or more at Mason City and the Quad Cities. Pumpage from the Cambrian-Ordovician aquifer system throughout the study area averaged 683 million gallons per day for the period 1976-80. Results of a transient-model simulation show that recharge increased over predevelopment recharge by 447 million gallons per day. Natural discharge decreased by 99 million gallons per day, and 137 million gallons per day was released from aquifer storage. Mineralization of ground water in the aquifer system increases from slightly mineralized calcium magnesium bicarbonate water in the northern recharge areas, through more mineralized, mixed water types with increased sodium and sulfate, to highly mineralized sodium chloride brines in the deeper parts of the structural basins.

Iowa, Illinois, Indiana, Michigan, Minnesota, Miss↗

Petrographic Descriptions of Selected Rock Specimens From the Meade Peak Phosphatic Shale Member, Phosphoria Formation (Permian), Southeastern Idaho

Based on petrographic observations of 135 thin sections, rocks in the Meade Peak Phosphatic Shale Member of the Permian Phosphoria Formation in southeastern Idaho can be placed into one of four major lithofacies: organic claystone, muddy siltstone, peloidal phosphorite, and dolomitized calclithite-in order of decreasing abundance. Organic claystones are the most common lithofacies in the Meade Peak. Many of these rocks contain sufficient amounts of silt to make silty, organic claystones a common subtype. Organic claystones commonly contain crystals of muscovite and bioclasts as accessory components, and they are typically parallel laminated. Muddy siltstones are composed primarily of quartz silt, but some feldspar and rare carbonate silt are also present; some rocks are parallel laminated. Phosphate peloids are composed of varying amounts of opaque, complex, and translucent material, and observed internal structures are classified as simple, banded, cored, zoned, oolitic, nucleated, and polynucleated. Opaque, complex, and translucent peloids form the framework grains of three peloidal phosphorite rocks: wackestone phosphorite, packstone phosphorite, and grainstone phosphorite. Wackestone phosphorite is phosphatic-mud supported and contains more than 10 percent peloids; it is the most common type of phosphorite. Packstone phosphorite is peloid supported and contains interstitial phosphatic mud; it is also a common type. Grainstone phosphorite is peloid supported but lacks phosphatic mud; it is the least common type. Dolomitized calclithites contain three types of carbonate grains: macrocrystalline, microcrystalline, and crystalline with a microcrystalline nuclei-in order of decreasing abundance. Based on chemical staining and X-ray diffraction analyses, most of the carbonate is dolomite. Sufficient amounts of quartz silt or muddy material allow some rocks to be called silty dolomitized calclithite or muddy dolomitized calclithite, respectively. Sedimentary structures are absent except in some muddy dolomitized calclithites. Organic claystones, muddy siltstones, and dolomitized calclithites are detrital deposits. Many rocks in the Meade Peak contain calcite and apatite as fracture fillings and vug linings. As expected, peloidal phosphorites are most common in ore zones, and detrital rocks are most common in waste zones. Mine-specific marker beds are mostly composed of dolomitized calclithite.

Scientific Investigations Report↗

Water quality of lakes and streams in Voyageurs National Park, northern Minnesota, 1977-84

Water-quality investigations in six interconnected lakes that comprise most of the surface area of Voyageurs National Park in northern Minnesota revealed substantial differences in water-quality. Three large lakes; Sand Point, Namakan, and Rainy, near the eastern and northern boundaries of the Park; are oligotrophic to mesotrophic, having low dissolved solids and alkalinity, and dimictic circulation. In contrast, Kabetogama Lake, Black Bay, and Sullivan Bay, near the western and southern boundaries of the Park, were eutrophic, having higher dissolved solids and alkalinity, and polymictic circulation. Chemical characteristics of the three lakes along the eastern and northern boundary were similar to those of the Namakan River--a major source of inflow that drains an extensive area of exposed bedrock and thin noncalcareous drift east of the Park. The lake and embayments along the western and southern boundary receive inflow from two streams that drain an area west and south of the Park that is overlain by calcareous drift. Samples from one of these streams contained dissolved-solids concentrations about five times, and total alkalinity concentrations about eight times concentrations measured in the Namakan River. The nutrient-enriched lakes and embayments had high algal productivity that produced blooms of blue-green algae in some years. Annual patterns in the levels of trophic-state indicators revealed that the shallow, polymictic lakes experienced seasonal increases in totalphosphorus concentrations in their euphotic zones that did not occur in the deeper, dimictic lakes; this indicates a link between the frequent recirculation of these lakes and internal cycling of phosphorus. Secchi-disk transparency was limited by organic color in Sand Point, Namakan, and Rainy Lakes, and resuspended bottom material reduced transparency in Black Bay. Waters in the large lakes and embayments met nearly all U.S. Environmental Protection Agency criteria for protection of freshwater aquatic life, recreation, and drinking water. Some sites exceeded criteria because of oil and grease, phenols, sulfide, and ammonia. Reconnaissance sampling of 19 small lakes in remote areas of the Park indicated that most of them are sharply stratified and had very low dissolved solids and alkalinity concentrations (4.0-29 milligrams per liter total alkalinity). Thirteen of the lakes could be classified as moderately sensitive to acid precipitation, and two could be classified extremely sensitive. About half of the interior lakes had low nutrient concentrations (10-30 micrograms per liter total phosphorus) and low algal productivity (0.1- 2.0 micrograms per liter chlorophyll a). Five of the lakes had a marked reduction in trophic state from spring to summer. The Namakan River is the largest source of inflow to the Park and was found to have better quality than its receiving waters based on dissolved solids and nutrient concentrations, algal productivity, and transparency. The Ash River was found to deliver water that generally was poorer in quality than its receiving waters.

Minnesota↗

The potential for water-quality degradation of interconnected aquifers in west-central Florida

Thousands of deep artesian wells were drilled into the Upper Floridan aquifer in west-central Florida prior to well-drilling regulations adopted in the 1970's. The wells were usually completed with a short length of casing through the unconsolidated sediments and were left open to multiple aquifers containing water of varying quality. These open boreholes serve as a potential source of water-quality degradation within the aquifers when vertical internal borehole flow is induced by hydraulic-head differences. This potential for water-quality degradation exists in west-central Florida where both the intermediate aquifer system and Upper Floridan aquifer exist. Measurements of caliper, temperature, gamma, fluid conductivity, and flow were obtained in 87 wells throughout west-central Florida to determine the occurrence of interaquifer borehole flow between the intermediate aquifer system and the Upper Floridan aquifer. Flow measurements were made using an impeller flowmeter, a heat-pulse flowmeter, and a video camera with an impeller flowmeter attachment. Of the 87 wells measured with the impeller flowmeter, 17 had internal flow which ranged from 10 to 300 gallons per minute. A heat-pulse flowmeter was used in 19 wells in which flow was not detected using the impeller flowmeter. Of these 19 wells, 18 had internal flow which ranged from 0.3 to 10 gallons per minute. Additionally, water-quality samples were collected from specific contributing zones in wells that had internal flow. Analysis of geophysical and water-quality data indicates degradation of water quality has occurred from mineralized ground water flowing upward from the Upper Floridan aquifer into the intermediate aquifer system through both uncased boreholes and corroded black-iron well casings. In areas where there is a downward component of flow, data indicate that potable water from the intermediate aquifer system is artificially recharging the Upper Floridan aquifer through open boreholes. A geographical area was defined where there is a potential for water-quality degradation due to improperly cased wells. This area was delineated based on where there is an upward component of ground-water flow and where there is an occurrence of poor-quality water. The delineated area includes parts of Hillsborough, Manatee, Sarasota, Charlotte, De Soto, and Hardee Counties. To prevent further contamination of the aquifers, the Southwest Florida Water Management District began the Quality of Water Improvement Program in 1974 to restore hydrologic conditions altered by improperly constructed wells or deteriorating casings. As of May 1994, more than 3,000 wells have been inspected and approximately 1,350 have been plugged. To minimize interaquifer contamination, existing wells, especially ones with black-iron casing, should be inspected and, if necessary, repaired with new casing or plugged.

Florida↗