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Per- and polyfluoroalkyl substances (PFAS) mass flux and mass balance at an aqueous film-forming foam release site in semiarid eastern New Mexico, USA

Passive flux meters (PFMs) directly measure groundwater chemistry mass flux and Darcy flux, providing insight into contaminant source-zone architecture and transport properties. This study uses PFMs to characterize PFAS flux in groundwater at a semiarid site with a thick (greater than 90-m) unsaturated zone where groundwater has been contaminated with per - and polyfluoroalkyl substances (PFAS) related to the use of aqueous film-forming foam (AFFF) for fire training and fire suppression. PFAS mass discharge (PFAS mass flux integrated over a control plane) in groundwater downgradient from several PFAS release areas is calculated using PFM results. In groundwater downgradient from fire-training areas, total PFAS mass discharge (summed across 14 compounds) was estimated to be between 6.0 and 31 g per day in 2020 and between 5.9 and 23 g per day in 2021. Site-specific documentation, generic information on AFFF properties, and literature values of PFAS concentration in AFFF are used to estimate site-specific PFAS-application rates at fire-training areas. These PFAS-application rates are compared to groundwater PFAS-discharge rates. Results suggest that transformation processes (exact pathways unknown) have led to increased discharge of measured PFAS in groundwater relative to initial AFFF formulations. The mass balance approach has broad applicability as a high-level approach that can provide insight into PFAS transport at AFFF sites.

New Mexico

Perspectives and insights gained from applying landscape ecological approaches to the Upper Mississippi riverscape

Advances in remote sensing, spatial data collection, hydraulic and geospatial models, and the maturation of landscape ecology during the early 2000s spurred the concept of rivers as landscapes or ‘riverscapes’. Since that time, the Upper Mississippi River Restoration (UMRR) Program - one of the world’s longest running large-river ecosystem restoration and monitoring programs - has applied landscape ecological principles to the Upper Mississippi River System (UMRS). I examine spatial patterns of aquatic nutrient concentrations, submersed aquatic vegetation, and fish and mussel communities, finding that within-river patterns are often patchy in nature, likely resulting from how nutrient processes and community traits interact with spatial variability in hydraulic exchange patterns. Local-scale patchy spatial patterns in the UMRS are embedded in system-scale longitudinal gradients and a hierarchical view of the river has provided a foundation for strategic river restoration planning. Key Words: Aquatic Habitat, hydraulic connectivity, patch, restoration, riverscape

BioScience

The Long Island Sound and Watershed Metadata map application

The Long Island Sound and its watershed encompass an area of about 17,000 square miles and include the Connecticut, Housatonic, and Thames Rivers, which all drain to the sound. Dozens of organizations from government agencies, nonprofits, and Tribal Nations have developed projects and monitoring programs to analyze and protect the water resources of the watershed and sound. The abundance of data and lack of an existing searchable index require a centralized metadata repository to allow users to find water resources data more efficiently. The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the Long Island Sound Study, has created an interactive map application to visualize and search for metadata information across organizations working to monitor and protect the Long Island Sound.

Connecticut, Massachusetts, New Hampshire, New Yor

Statistical approaches for modeling correlated grade and tonnage distributions and applications for mineral resource assessments

Correlations between grade and tonnage exist in mineral resource data compiled from published reports, but they are not always addressed during quantitative assessment of undiscovered mineral resources. Failure to account for correlated grade and tonnage distributions can result in geologically unrealistic assessment results. Current software tools simulate univariate ore tonnage and multivariate resource grades of undiscovered deposits independently. As a result, analysts are forced to rely on ad-hoc solutions to minimize the correlation issues by: 1) creating subsets of data with restricted criteria; 2) truncating grade and tonnage distributions; and 3) testing model robustness using exploratory data analysis. While these methods represent pragmatic solutions, the statistical solutions presented here provide additional options to address real correlations in grade and tonnage data used for mineral resource assessments. We present a modified version of the MapMark4 package in R that introduces two alternatives for modeling grade and tonnage distributions, consisting of a multivariate solution that accounts for correlations between ore tonnage and metal grades and an empirical solution that utilizes simple random sampling with replacement to reproduce coupled grades and tonnages from the input data. We present simulations for contained ore and metal for three case studies representing tungsten skarn, komatiite-hosted nickel, and sediment-hosted carbonate amagmatic zinc-lead (Mississippi Valley-type) deposits. Employing the methods presented here yields quantitative mineral resource assessment results that more closely reflect the empirical distributions of grades and tonnages observed in nature and expands the applicability of these tools for ongoing critical mineral resource assessments.

Applied Computing and Geosciences

U.S.-Mexico Borderland & vegetation community map

People on both sides of the United States-Mexico border need a high-resolution, binational vegetation community map that spans the entire United States-Mexico borderlands. Traditionally, mapping efforts in this region were impeded by complex logistics related to the international border, differing national needs and plans, and resource allocations and priorities. To address this need, scientists from the U.S. Geological Survey (USGS) Southwest Biological Science Center partnered with the Sonoran Joint Venture, the U.S. Fish and Wildlife Service (FWS) Migratory Bird Program, data engineers from the Department of Biosystems Engineering at the University of Arizona, and collaborators from the Wildlands Network, the Borderlands Program to produce the first prototype land cover map within the overlapping Mojave Desert, Sonoran Desert, and the North American Bird Conservation Initiative’s Bird Conservation Region 33 (BCR33) using Landsat satellite data . BCR33 is an area of high biodiversity, providing habitat for bird species of concern and other wildlife. The land cover map supports FWS recovery plan efforts related to conservation planning activities for many species, including Yellow-billed Cuckoo ( Coccyzus americanus ), Cactus Ferruginous Pygmy-Owl ( Glaucidium brasilianum cactorum ), Southwestern Willow Flycatcher ( Empidonax traillii extimus ), Yuma Ridgway’s Rail ( Rallus obsoletus yumanensis ), Bendire’s thrasher ( Toxostoma bendirei ), LeConte’s thrasher ( Toxostoma lecontei ), Masked Bobwhite ( Colinus virginianus ridgwayi ), jaguar ( Panthera onca ), and endangered plants such as Bartram’s stonecrop ( Graptopetalum bartramii ) and the Pima pineapple cactus ( Coryphantha robustispina ssp. robustispina ). In 2024, a Phase-II map for the full BCR33 region was completed, increasing the understanding of the binational nature of natural communities. The published map and associated paper can be found here .

Borderland

Airborne geophysical analysis to decipher salinization for coastal Louisiana

Coastal Louisiana is known for saltwater intrusion that threatens wetlands, aquifers, and rivers. However, the extent of saltwater intrusion is not well understood. This study develops an innovative framework with airborne electromagnetic (AEM) data to map chloride concentration distributions for wetlands in the Mississippi River deltaic plain and Chenier plain as well as for the Mississippi River Valley alluvial aquifer (MRVA) and Chicot aquifer. Moreover, the framework maps chloride concentrations along the Mississippi River and Atchafalaya River. Key components in the framework include the establishment of resistivity-to-chloride concentration transformation, 3D resistivity architecture building through geostatistics, and the employment of a lithologic model. The transformation functions correlate AEM resistivity data with porewater salinity measurements and groundwater and river chloride samples. The results show that AEM data reliably infers soil water chloride concentrations and correlates well with the distribution of various marsh types. AEM data reveals extensive saltwater presence at depth and near the coast, originating from salt domes and the Gulf of Mexico, respectively. The saltwater upconing pattern in the Chicot aquifer is likely due to excessive groundwater withdrawals. The AEM data also confirms a distinct tongue of saltwater intruding into the Atchafalaya Basin from the Gulf. The AEM data helps to identify faults that are obscured or eroded at the surface, which appear as leaky barriers in the subsurface where dramatic changes in chloride concentration are apparent. Finally, this study uses the AEM data to infer the presence of an extensive seawater wedge in the Mississippi River and Atchafalaya River.

Louisiana

Tapwater exposures, residential risk, and mitigation in a PFAS-impacted-groundwater community

Tapwater (TW) safety and sustainability are priorities in the United States. Per/polyfluoroalkyl substance(s) (PFAS) contamination is a growing public-health concern due to prolific use, widespread TW exposures, and mounting human-health concerns. Historically-rural, actively-urbanizing communities that rely on surficial-aquifer private wells incur elevated risks of unrecognized TW exposures, including PFAS, due to limited private-well monitoring and contaminant-source proliferation in urbanizing landscapes. Here, a broad-analytical-scope TW-assessment was conducted in a hydrologically-vulnerable, Mississippi River alluvial-island community, where PFAS contamination of the shallow-alluvial drinking-water aquifer has been documented, but more comprehensive contaminant characterization to inform decision-making is currently lacking. In 2021, we analyzed 510 organics, 34 inorganics, and 3 microbial groups in 11 residential and community locations to assess (1) TW risks beyond recognized PFAS issues, (2) day-to-day and year-to-year risk variability, and (3) suitability of the underlying sandstone aquifer as an alternative source to mitigate TW-PFAS exposures. Seventy-six organics and 25 inorganics were detected. Potential human-health risks of detected TW exposures were explored based on cumulative benchmark-based toxicity quotients ( ∑ TQ ). Elevated risks ( ∑ TQ ≥ 1) from organic and inorganic contaminants were observed in all alluvial-aquifer-sourced synoptic samples but not in sandstone-aquifer-sourced samples. Repeated sampling at 3 sites over 52–55 h indicated limited variability in risk over the short-term. Comparable PFAS-specific ∑ TQ for spatial-synoptic, short-term (3 days) temporal, and long-term (3 years quarterly) temporal samples indicated that synoptic results provided useful insight into the risks of TW-PFAS exposures at French Island over the long-term. No PFAS detections in sandstone-aquifer-sourced samples over a 3 year period indicated no PFAS-associated risk and supported the sandstone aquifer as an alternative drinking-water source to mitigate community TW-PFAS exposures. This study illustrated the importance of expanded contaminant monitoring of private-well TW, beyond known concerns (in this case, PFAS), to reduce the risks of a range of unrecognized contaminant exposures.

Wisconsin

Perspectives on transportable array Alaska background noise levels

Background seismic noise fundamentally sets a lower bound on our ability to record signals arising from earthquakes. The background noise spectrum at a station is a combination of cultural noise, ocean-generated microseism noise, intrinsic instrument self-noise, and the sensitivity of the instrument to nonseismic noise sources. The USArray-Transportable Array Alaska deployed 195 stations across Alaska and parts of Canada (Yukon, British Columbia, and Northwest Territories). These stations were all installed using similar techniques and made use of instruments with similar self-noise levels. As such, this network provides an opportunity to look at how geographic location influences seismic background. Using these broadband stations, we report background noise levels from 0.2 to 75 s period in six discrete bands. By constructing “noise maps,” we depict both spatial and temporal changes in the background noise field. Using these maps, combined with targeted analysis, we infer sources and contributing factors to noise levels in these different period bands. These include cultural noise, the formation of sea ice, seasonal changes in permafrost and wave activity in the Gulf of Alaska, and magnetic field variability. We use this study as an opportunity to review several previous studies examining seismic noise in Arctic regions.

Book chapter

Groundwater structures fish growth and production across a riverscape

Landscapes are composed of habitat patches and conditions that vary across space and time. While habitat variability and complexity can support important ecological processes and ecosystem services, the dynamic nature of habitats can also constrain organismal growth and production as optimal conditions are fleeting. In riverine ecosystems, groundwater discharge to streams stabilises water temperature and flow regimes, thus mediating how habitat complexity is expressed. Yet, how stable habitats structure growth and production within the broader landscape matrix is not well understood. In this study, we explored the effects of groundwater on spatiotemporal variation in growth and production for juvenile Yellowstone cutthroat trout ( Oncorhynchus virginalis bouvieri ) across the upper Snake River catchment, Wyoming, USA. We combined machine learning techniques and remotely sensed landscape data to estimate groundwater availability across the river network, which we linked to stream temperature regimes and conspecific density. We then used Bayesian hierarchical models to quantify the effects of temperature, density and groundwater on spatiotemporal variation in fish growth and production in 52 focal reaches. Finally, we predicted body size trajectories and trends in total production continuously over both space and time to understand the effect of groundwater at the riverscape scale. Groundwater discharged to streams where topography changes abruptly in valley-bottom areas underlain by coarse glacial deposits. Groundwater stabilised temperature regimes and was associated with high trout densities. Temperature and density, in turn, interacted to influence growth rates: growth increased strongly with temperature, but this effect was reduced when density was high. Accordingly, variation in groundwater availability among stream reaches diversified growth and production regimes. In reaches with low groundwater availability, growth and production declined over time from summer maxima. In contrast, in reaches with high groundwater availability, temporal trends in growth and production were hump-shaped—peaking in autumn—and mean production was greater. At the riverscape scale, temporal asynchrony in growth rates generated convergent spatial variation in growth capacity, but—when combined with density—led to the formation of distinct hotspots of production. Our results demonstrate how groundwater, an important driver of aquatic ecosystem heterogeneity, structures trout growth and production across space and time. Importantly, rare, but stable habitats may disproportionately affect ecological processes and serve as key sources of population diversity at larger spatial scales.

Wyoming

An unexplained tsunami: Was there megathrust slip during the 2020 Mw7.6 Sand Point, Alaska, earthquake?

On October 19, 2020, the M w 7.6 Sand Point earthquake struck south of the Shumagin Islands in Alaska. Moment tensors indicate the earthquake was primarily strike-slip, yet the event produced an enigmatic tsunami that was larger and more widespread than expected for an earthquake of that magnitude and mechanism. Using a suite of hydrodynamic, seismic, and geodetic modeling techniques, we explore plausible causes of the tsunami. We find that strike-slip models consistent with the moment tensor orientation cannot produce the observed tsunami. Hydrodynamic inversion of sea surface deformation from deep ocean and tide gauge data suggest seafloor deformation more closely matches a megathrust, rather than a strike-slip, source. Static slip inversions, using sea level and Global Navigation Satellite System data, allow for a portion of co-seismic megathrust slip that can explain tsunamigenesis. Combining all available geophysical datasets to model the kinematic rupture, we show that considerable, relatively slow, megathrust slip is allowable in the Shumagin segment, concurrent with strike-slip faulting. We hypothesize that the slow megathrust rupture does not contribute much seismic radiation allowing it to previously go unnoticed with traditional seismic monitoring.

Alaska

Hydrogeology and groundwater quality in the Snake River alluvial aquifer at Jackson Hole Airport, Wyoming, 2011–20

The Snake River alluvial aquifer underlying the Jackson Hole Airport (JHA) in northwest Wyoming is an important source of water used for domestic, commercial, and irrigation purposes by the airport and nearby residents. The U.S. Geological Survey, in response to previously identified water-quality concerns in the area, monitored and evaluated changes in hydrogeologic characteristics and groundwater-quality conditions of the alluvial aquifer during 2011–20. During that period, the Jackson Hole Airport made several changes that potentially improved water quality at and downgradient from the airport. Well, water level, and hydrogeologic data were collected from the alluvial aquifer to identify hydrogeologic characteristic and groundwater quality changes. Additionally, results of statistical tests were applied to water-quality results to evaluate trends in selected physical properties and constituent concentrations with time. The trends of those data show that water quality did improve overall during the study period compared to previously collected data. Presumably, these trends are in response to the changes in the aircraft deicing/anti-icing fluid (ADAF) formulation used by the JHA, the many JHA infrastructure improvements made during 2011–20, the degradation of existing ADAFs in subsurface soils and groundwater, or some combination of these possibilities.

Wyoming

Using surficial geologic maps, vegetation, and monitoring to address erosion impacts from grazing in Channel Islands National Park, California

Employing a map-unit classification scheme based on geomorphic process and age, the U.S. Geological Survey (USGS) mapped Quaternary surficial deposits of the five islands comprising Channel Islands National Park (CHIS), California, as no such maps previously existed. Mapping was motivated through an agreement with the National Park Service (NPS) to aid natural resource assessments, including post-grazing disturbance recovery and identification of mass wasting and tectonic hazards. The resulting detailed (1:12,000 scale) maps portray areas of upland erosional transport processes and alluvial, fluvial, eolian, beach, marine terrace, mass wasting, and mixed depositional processes at a scale commensurate with the process signal on the landscape. Detailed, GPS-located observations of sedimentology, pedogenic development, landscape position, and geomorphology constrain map unit identification. In addition, map-unit boundary delineation was determined in a GIS using a variety of high-resolution (sub-meter) aerial imagery and lidar-based DEMs complemented by derivative raster products. The GIS geodatabase schema used is GeMS compliant. Resolvable map-unit widths are as small as 10-15 meter. Locational accuracy of unit boundaries is estimated to be as low as 10 m or better. Detailed mapping is at a scale allowing determination of geomorphic transport processes operating on the landscape and conveys geologic information to land managers at a resolution commensurate with park resources. Map unit ages are constrained by relative soil chronostratigraphy, vertebrate and invertebrate fossils, and materials collected for dating control using radiogenic, luminescence, and cosmogenic radionuclide techniques. Associated topical studies examined connections between geology, surface water, and vegetation distribution and restoration.

California

U.S. Geological Survey National Groundwater Climate Response Network

What is the U.S. Geological Survey National Groundwater Climate Response Network? The U.S. Geological Survey’s (USGS) National Water Monitoring Network is a network of networks that includes the Climate Response Network (CRN). The CRN is a network of wells selected to monitor the effects of climate variability, including droughts, on groundwater systems within the United States, Puerto Rico, and the U.S. Virgin Islands. The primary purpose of the CRN is to monitor these effects on groundwater levels in unconfined or near-surface confined aquifers that are minimally affected by pumping or other human-induced stresses.

Fact Sheet

Stream nitrate dynamics driven primarily by discharge and watershed physical and soil characteristics at intensively monitored sites: Insights from deep learning

We developed a suite of models using deep learning to make hindcast predictions of the 7‐day average backward‐looking nitrate concentration at 46 predominantly agricultural sites across the midwestern and eastern United States. The models used daily observations of discharge and meteorological variables and watershed attributes describing anthropogenic modification to hydrology, nitrogen application, climate, groundwater, land use, watershed physiographic attributes, and soils. Across all sites, discharge and watershed soil and physiographic attributes showed a strong influence on model performance. Analysis of drivers across sites revealed considerable regional differences related to controlling processes such as groundwater contributions. We tested several ways to pool data across sites to develop accurate models and make the most effective use of available data. Single‐site models, in which models are trained and tested at a single location, showed generally strong predictive performance (median Kling‐Gupta Efficiency = 0.66), and accuracy at poorly performing sites could be improved by grouping sites with similar characteristics. Developing a single model for all sites reduced performance at several locations with distinct characteristics, suggesting that there is a threshold of dissimilarity beyond which more data does not improve the model. While many deep learning studies have shown that national or even global models can outperform local models, it is not clear that this is true for water quality constituents. This study demonstrates how data can be combined effectively, using deep learning to develop accurate and interpretable models of instream nitrate at sites where varying processes are responsible for changes in nitrate concentration.

Water Resources Research

Induced earthquakes are generally not tidally triggered in Oklahoma and Kansas

Human-induced earthquakes occur along critically stressed faults as injected wastewater simultaneously heightens fluid pressure and pushes faults to failure. We investigate the possibility that small stresses imposed by Earth tides could trigger earthquakes in the induced seismicity region of Oklahoma and Kansas from 2011 to 2018. We decluster a catalog consisting of ∼110,000 earthquakes using three methods (Reasenberg, nearest-neighbor distance, and phase-bin). We find no significant tidal earthquake triggering using Schuster's p -value test for the declustered catalogs as a whole. We search for localized triggering using discretized space-time cells and find ∼0–6% of cells have significant tidal triggering which is close to what is randomly expected (5%) and indicates there is an insignificant amount of tidal triggering for the full study region. One area that has significant p -values across multiple time windows, ∼2014–2016 is ∼15 km from a region of large wastewater injection volume. It is possible that localized tidal triggering occurs for this time and area because faults remain critically stressed and are particularly susceptible to slip under the small stress load from the semidiurnal tide. Possible explanations for the lack of tidal triggering in our broader study are that the pre-seismic stressing rate in the earthquake nucleation area is faster than the tidal stressing rate (∼3 kPa/day), faults are not close enough to critically stressed to be affected by tidal forcing, and that nucleation occurs over longer periods than the tides considered in this study (∼1, ∼14 days). Fluid injection could be the source of a higher pre-seismic stress rate.

Kansas, Oklahoma

Seismicity and anisotropic imaging reveal an active detachment beneath the northern Alaska Range foothills

North of the Denali Fault, the collision between the Yakutat block with North America is accommodated by a fold-thrust belt giving rise to the northern Alaska Range foothills. At the western end, the Kantishna Hills anticline hosts prominent microseismicity and surface deformation, interpreted as active folding of the Kantishna Hills anticline above a midcrustal detachment. We test for this detachment by using anisotropy-aware receiver functions to image fabric contrasts within the crust in context with seismicity. Seismic stations near the crest of the Kantishna Hills anticline and near its southern flank show a single strong contrast in dipping fabric at depths of 12–13 km near microseismicity clustering depths, consistent with a detachment plane beneath the fold. A minimum b -value at 10–13 km depth is consistent with seismicity on the detachment, compatible with the imaged anisotropic contrast, while off-fault seismicity is shallower and deeper with smaller magnitudes. South-dipping imbricate thrusts in schist characterize the northern Alaska Range foothills structure. This supports our interpretation of the observed anisotropy as reflecting SSW–SSE-dipping foliation above a detachment at ∼10–13 km depth that exploits existing crustal weaknesses along subtle fabric contrasts observed in the seismically quiescent region north of the actively deforming belt.

Alaska

Subducting plate structure and megathrust morphology from deep seismic imaging linked to earthquake rupture segmentation at Cascadia

The origin of rupture segmentation along subduction zone megathrusts and linkages to the structural evolution of the subduction zone are poorly understood. Here, regional-scale seismic imaging of the Cascadia margin is used to characterize the megathrust spanning ~900 km from Vancouver Island to the California border, across the seismogenic zone to a few tens of kilometers from the coast. Discrete domains in lower plate geometry and sediment underthrusting are identified, not evident in prior regional plate models, which align with changes in lithology and structure of the upper plate and interpreted paleo-rupture patches. Strike-slip faults in the lower plate associated with oblique subduction mark boundaries between regions of distinct lower plate geometry. Their formation may be linked to changes in upper plate structure across long-lived upper plate faults. The Juan de Fuca plate is fragmenting within the seismogenic zone at Cascadia as the young plate bends beneath the heterogeneous upper plate resulting in structural domains that coincide with paleo-rupture segmentation.

Oregon, Washington

The U.S. Geological Survey Ohio Water Microbiology Laboratory

The U.S. Geological Survey Ohio Water Microbiology Laboratory is a part of the Ohio-Kentucky-Indiana Water Science Center. The mission of the laboratory is to provide microbiological data of public health significance from surface waters, groundwaters, and sediments for a variety of study objectives. The laboratory conducts internal projects, works with external cooperators, and assists U.S. Geological Survey offices and National programs. The laboratory offers guidance, study design, and data interpretation expertise to collaborators, all following rigorous quality control and quality assurance procedures.

Fact Sheet