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USGS1996

Geologic framework and hydrogeologic characteristics of the Edwards aquifer outcrop (Barton Springs segment), northeastern Hays and southwestern Travis Counties, Texas

The hydrogeologic subdivisions within the Barton Springs segment of the Edwards aquifer outcrop in northeastern Hays and southwestern Travis Counties generally are porous and permeable. The most porous and permeable appear to be hydrogeologic subdivision VI, the Kirschberg evaporite member of the Kainer Formation; and hydrogeologic subdivision III, the leached and collapsed members, undivided, of the Person Formation. Hydrogeologic subdivision II, the cyclic and marine members, undivided, of the Person Formation, also is quite porous and permeable in Hays County. The porosity of the rocks in the Edwards aquifer outcrop is related to depositional or diagenetic elements along specific stratigraphic horizons (fabric selective) and to dissolution and structural elements that can occur in any lithostratigraphic horizon (not fabric selective). Permeability depends on the physical properties of the rock such as pore size, shape, distribution, fissuring, dissolution, and interconnection of pores and vugs. The Edwards aquifer rocks that crop out in the Barton Springs segment of the Edwards aquifer generally have the same lithologic characteristics as the Edwards aquifer rocks that crop out in Comal and southwestern Hays Counties. However, in the northeastern part of the segment in Travis County, the rock unit that is apparently equivalent to the basal nodular member of the Kainer Formation is called the Walnut Formation. Because the units appear to be stratigraphically and lithologically equivalent, the basal nodular member is used instead of the Walnut Formation for this report. Essentially all of hydrogeologic subdivision II, which is about 70 feet thick in Hays County, is missing in Travis County. In the Barton Springs segment of the Edwards aquifer, the aquifer probably is most vulnerable to surface contamination in the rapidly urbanizing areas on the Edwards aquifer outcrop. Contamination can result from spills or leakage of hazardous materials; or runoff on the intensely faulted and fractured, karstic limestone outcrops characteristic of the recharge zone.

Texas↗

USGS1999

Water-resources-related information for the Oneida Reservation and vicinity, Wisconsin

Water-resources information has been compiled from 82 studies in which data were collected from the Oneida Reservation and vicinity. Forty-seven studies addressed surface-water issues, 33 studies addressed ground-water issues, and 23 studies addressed aquatic-biology issues. Some multidisciplinary studies are included in more than one category. Most of the surface-water studies summarized in this report included both water-quality and flow information. Several surface-water studies provided detailed short-term descriptions of surface- water quality and flow for parts of the Reservation and vicinity. Surface-water and stream-sediment quality data from several data bases have been compiled for this report. Most of the compiled data come from two sites on Duck Creek. Data from Duck Creek were analyzed for trends in concentrations of suspended sediment, dissolved nitrite plus nitrate, and dissolved atrazine. No trends were detected for any of these constituents. Trends in concentration of most constituents in surface-water samples were not calculated because of the short period of data collection at nearly all of the sites. Most of the ground-water reports that were identified included both quality and quantity and flow information. None of the ground-water studies provided a detailed description of ground-water quality for the Reservation as a whole. Several reports provide varied and detailed information for ground-water models that are useful for understanding hydrogeology and ground-water flow for the Reservation and vicinity. Ground-water quality data from 180 wells, compiled from several data bases, provided an incomplete summary of the condition of the drinking- water resources of the Reservation. Only 12 constituents, from a small number of wells, exceeded a USEPA drinking-water limit. Most of the exceedences were for trace metals and organics. No exceedences for pesticides or nitrate were reported; however, pesticide data were collected from only a small number of wells. Most of the aquatic biology studies described in this report include fish data, habitat data, or calculations of biotic index values, most of which comes from Duck Creek. Historical aquatic biology data for the Reservation and vicinity are limited. Most of the 23 studies described here were done since 1992. Most of the biota-quality data compiled for this report come from several sites on Duck Creek and represent a small number of samples. Results of the community survey regarding the water resources of the Oneida Reservation indicate that water usage by Tribal members today has declined when compared to the past. The most common reason given for the decline in usage was pollution. Most of those surveyed perceived Duck Creek as being "polluted," but about 50 percent thought that water quality in the Reservation was improving.

Wisconsin↗

USGS2005

Quality of nutrient data from streams and ground water sampled during water years 1992-2001

Proper interpretation of water-quality data requires consideration of the effects that bias and variability might have on measured constituent concentrations. In this report, methods are described to estimate the bias due to contamination of samples in the field or laboratory and the variability due to sample collection, processing, shipment, and analysis. Contamination can adversely affect interpretation of measured concentrations in comparison to standards or criteria. Variability can affect interpretation of small differences between individual measurements or mean concentrations. Contamination and variability are determined for nutrient data from quality-control samples (field blanks and replicates) collected as part of the National Water-Quality Assessment (NAWQA) Program during water years 1992-2001. Statistical methods are used to estimate the likelihood of contamination and variability in all samples. Results are presented for five nutrient analytes from stream samples and four nutrient analytes from ground-water samples. Ammonia contamination can add at least 0.04 milligram per liter in up to 5 percent of all samples. This could account for more than 22 percent of measured concentrations at the low range of aquatic-life criteria (0.18 milligram per liter). Orthophosphate contamination, at least 0.019 milligram per liter in up to 5 percent of all samples, could account for more than 38 percent of measured concentrations at the limit to avoid eutrophication (0.05 milligram per liter). Nitrite-plus-nitrate and Kjeldahl nitrogen contamination is less than 0.4 milligram per liter in 99 percent of all samples; thus there is no significant effect on measured concentrations of environmental significance. Sampling variability has little or no effect on reported concentrations of ammonia, nitrite-plus-nitrate, orthophosphate, or total phosphorus sampled after 1998. The potential errors due to sampling variability are greater for the Kjeldahl nitrogen analytes and for total phosphorus sampled before 1999. The uncertainty in a mean of 10 concentrations caused by sampling variability is within a small range (1 to 7 percent) for all nutrients. These results can be applied to interpretation of environmental data collected during water years 1992-2001 in 52 NAWQA study units.

Scientific Investigations Report↗

USGS2007

Selenium and other elements in water and adjacent rock and sediment of Toll Gate Creek, Aurora, Arapahoe County, Colorado, December 2003 through March 2004

Streamwater and solid samples (rock, unconsolidated sediment, stream sediment, and efflorescent material) in the Toll Gate Creek watershed, Colorado, were collected and analyzed for major and trace elements to determine trace-element concentrations and stream loads from December 2003 through March 2004, a period of seasonally low flow. Special emphasis was given to selenium (Se) concentrations because historic Se concentrations exceeded current (2004) stream standards. The goal of the project was to assess the distribution of Se concentration and loads in Toll Gate Creek and to determine the potential for rock and unconsolidated sediment in the basin to be sources of Se to the streamwater. Streamwater samples and discharge measurements were collected during December 2003 and March 2004 along Toll Gate Creek and its two primary tributaries - West Toll Gate Creek and East Toll Gate Creek. During both sampling periods, discharge ranged from 2.5 liters per second to 138 liters per second in the watershed. Discharge was greater in March 2004 than December 2003, but both periods represent low flow in Toll Gate Creek, and results of this study should not be extended to periods of higher flow. Discharge decreased moving downstream in East Toll Gate Creek but increased moving downstream along West Toll Gate Creek and the main stem of Toll Gate Creek, indicating that these two streams gain flow from ground water. Se concentrations in streamwater samples ranged from 7 to 70 micrograms per liter, were elevated in the upstream-most samples, and were greater than the State stream standard of 4.6 micrograms per liter. Se loads ranged from 6 grams per day to 250 grams per day, decreased in a downstream direction along East Toll Gate Creek, and increased in a downstream direction along West Toll Gate Creek and Toll Gate Creek. The largest Se-load increases occurred between two sampling locations on West Toll Gate Creek during both sampling periods and between the two sampling locations on the main stem of Toll Gate Creek during the December 2003 sampling. These load increases may indicate that sources of Se exist between these two locations; however, Se loading along West Toll Gate Creek and Toll Gate Creek primarily was characterized by gradual downstream increases in load. Linear regressions between Se load and discharge for both sampling periods had large, significant values of r2 (r2 > 0.96, p < 0.0001) because increases in Se load (per unit of flow increase) were generally constant. This relation is evidence for a constant addition of water having a relatively constant Se concentration over much of the length of Toll Gate Creek, a result which is consistent with a ground-water source for the Se loads. Rock outcroppings along the stream were highly weathered, and Se concentrations in rock and other solid samples ranged from below detection (1 part per million) to 25 parts per million. One sample of efflorescence (a surface encrustation produced by evaporation) had the greatest selenium concentration of all solid samples, was composed of thenardite (sodium sulfate), gypsum (calcium sulfate) and minor halite (sodium chloride), and released all of its Se during a 30-minute water-leaching procedure. Calculations indicate there was an insufficient amount of this material present throughout the watershed to account for the observed Se load in the stream. However, this material likely indicates zones of ground-water discharge that contain Se. This report did not identify an unequivocal source of Se in Toll Gate Creek. However, multiple lines of evidence indicate that ground-water discharge supplies Se to Toll Gate Creek: (1) the occurrence of elevated Se concentrations in the stream throughout the watershed and in the headwater regions, upstream from industrial sources; (2) the progressive increase in Se loads moving downstream, which indicates a continuous input of Se along the stream rather than input from point sources; (3) the occurr

Colorado↗

USGS2010

Application of SEAWAT to select variable-density and viscosity problems

SEAWAT is a combined version of MODFLOW and MT3DMS, designed to simulate three-dimensional, variable-density, saturated groundwater flow. The most recent version of the SEAWAT program, SEAWAT Version 4 (or SEAWAT_V4), supports equations of state for fluid density and viscosity. In SEAWAT_V4, fluid density can be calculated as a function of one or more MT3DMS species, and optionally, fluid pressure. Fluid viscosity is calculated as a function of one or more MT3DMS species, and the program also includes additional functions for representing the dependence of fluid viscosity on temperature. This report documents testing of and experimentation with SEAWAT_V4 with six previously published problems that include various combinations of density-dependent flow due to temperature variations and/or concentration variations of one or more species. Some of the problems also include variations in viscosity that result from temperature differences in water and oil. Comparisons between the results of SEAWAT_V4 and other published results are generally consistent with one another, with minor differences considered acceptable.

Scientific Investigations Report↗

USGS2010

Groundwater-quality monitoring program in Chester County, Pennsylvania, 1980-2008

The U.S. Geological Survey in cooperation with the Chester County Water Resources Authority and the Chester County Health Department began a groundwater-quality monitoring program in 1980 in Chester County, Pa., where a large percentage of the population relies on wells for drinking-water supply. This report documents the program and serves as a reference for data collected through the program from 1980 through 2008. The initial focus of the program was to collect data on groundwater quality near suspected localized sources of contamination, such as uncontrolled landfills and suspected industrial wastes, to determine if contaminants were present that might pose a health risk to those using the groundwater. Subsequently, the program was expanded to address the effects of widely distributed contaminant sources associated with agricultural and residential land uses on groundwater quality and to document naturally occurring constituents, such as radium, radon, and arsenic, that are potential hazards in drinking water. Since 2000, base-flow stream samples have been collected in addition to well-water and spring samples in a few small drainage areas to investigate the relation between groundwater quality measured in well samples and streams. The program has primarily consisted of spatial assessment with limited temporal data collected on groundwater quality. Most data were collected through the monitoring program for reconnaissance purposes to identify and locate groundwater-quality problems and generally were not intended for rigorous statistical analyses that might determine land-use or geochemical factors affecting groundwater quality in space or through time. Results of the program found several contaminants associated with various land uses and human activities in groundwater in Chester County. Volatile organic compounds (such as trichloroethylene) were measured in groundwater near suspected localized contaminant sources in concentrations that exceeded drinking-water standards. Groundwater in some agricultural areas had concentrations of nitrate and some pesticides that exceeded drinking-water standards. Elevated concentrations of chloride were measured near salt storage areas and highways. Formaldehyde was detected in groundwater near cemeteries. In residential areas with on-site wastewater disposal, effects on groundwater quality included elevated nitrate concentrations and low concentrations of volatile organic compounds and wastewater compounds, such as antibiotics and detergents. Base-flow samples indicated that groundwater discharge to streams carried contaminants such as nitrate, pesticides, wastewater compounds, and other contaminants. Radionuclides, including radium-226, radium-228, radium-224, and radon-222, and gross alpha-particle activity were measured in groundwater at levels above established and proposed drinking-water standards in some geologic units, particularly in quartzite and quartzite schists. Arsenic concentrations above drinking-water standards were measured in a few samples and were most likely to occur in groundwater in the shales and sandstones in the northern part of the county. Other potential natural hazards, such as lead from aquifer materials or leached from plumbing because of pH, were present in concentrations above drinking-water standards infrequently (less than 10 percent of samples). Limited temporal sampling suggested that chloride concentrations in groundwater increased in the county since the program began in 1980 through 2008, reflecting increasing population and urbanization in that period.

Scientific Investigations Report↗

USGS2016

The source of groundwater and solutes to Many Devils Wash at a former uranium mill site in Shiprock, New Mexico

The Shiprock Disposal Site is the location of the former Navajo Mill (Mill), a uranium ore-processing facility, located on a terrace overlooking the San Juan River in the town of Shiprock, New Mexico. Following the closure of the Mill, all tailings and associated materials were encapsulated in a disposal cell built on top of the former Mill and tailings piles. The milling operations, conducted at the site from 1954 to 1968, created radioactive tailings and process-related wastes that are now found in the groundwater. Elevated concentrations of constituents of concern—ammonium, manganese, nitrate, selenium, strontium, sulfate, and uranium—have also been measured in groundwater seeps in the nearby Many Devils Wash arroyo, leading to the inference that these constituents originated from the Mill. These constituents have also been reported in groundwater that is associated with Mancos Shale, the bedrock that underlies the site. The objective of this report is to increase understanding of the source of water and solutes to the groundwater beneath Many Devils Wash and to establish the background concentrations for groundwater that is in contact with the Mancos Shale at the site. This report presents evidence on three working hypotheses: (1) the water and solutes in Many Devils Wash originated from the operations at the former Mill, (2) groundwater in deep aquifers is upwelling under artesian pressure to recharge the shallow groundwater beneath Many Devils Wash, and (3) the groundwater beneath Many Devils Wash originates as precipitation that infiltrates into the shallow aquifer system and discharges to Many Devils Wash in a series of springs on the east side of the wash. The solute concentrations in the shallow groundwater of Many Devils Wash would result from the interaction of the water and the Mancos Shale if the source of water was upwelling from deep aquifers or precipitation. In order to compare the groundwater from various wells to groundwater that has been affected by Mill activities, a classification system was developed to determine which wells were most likely to have been affected. Affects to groundwater by the Mill were determined by using the reported uranium alpha activity ratios measured in groundwater samples, along with the concentration of the uranium and the location of the wells relative to the Mill. Activity ratios of 1.2 or less were determined to be the most reliable indicator of Mill-affected groundwater. Wells with samples that had a reported activity ratio of 1.2 or less were classified as Mill affected. To compare groundwater with background water-quality, data from groundwater seeps and springs in the Upper Eagle Nest Arroyo and Salt Creek Wash, located north of the San Juan River, are also presented and analyzed. Based on groundwater elevations and tritium concentrations measured in wells located between the disposal cell and Many Devils Wash, Mill water is not likely to reach Many Devils Wash. The tritium concentrations also indicate that groundwater from the Mill has not substantially affected Many Devils Wash in the past. Upwelling from deep aquifers was also determined to be an unlikely source, primarily by comparing the composition of the stable isotopes of water in the shallow groundwater with those reported in groundwater samples from the deeper aquifers. The stable-isotope compositions of the shallow groundwater around the site are enriched relative to the San Juan River and local meteoric lines, which suggests that most of the shallow groundwater has been influenced by evaporation and therefore was recharged at the surface. Several observations indicate that focused recharge is the likely source of groundwater in the area of Many Devils Wash. The visible erosional features in Many Devils Wash provide evidence of piping and groundwater sapping, and the distribution and type of vegetation in Many Devils Wash suggest that the focused recharge of precipitation is occurring. The estimated recharge from precipitation was calculated to be 0.0008 inches per year (in/yr) by using the mass-balance approach from reported seep discharge and 0.0011 in/yr using the chloride mass-balance approach. A conceptual model of groundwater quality beneath Many Devils Wash is presented to explain the source of solutes in the groundwater beneath Many Devils Wash. The major-ion concentrations and geochemical evolution in the groundwater beneath Many Devils Wash and across the study area support the conceptual model that the underlying Mancos Shale is the source of solutes. Differences in the major-ion composition between groundwater samples collected around the site, result from the degree of weathering to the Mancos Shale. The cation distribution appears to be an indicator of effects from the Mill, with samples from the Mill-affected wells largely having a calcium/magnesium-sulfate composition that resembles the reported compositions of more weathered shale; however, that composition could change if the Mill-processed water flowed into areas where the Mancos Shale was less weathered. On the basis of the widespread presence of uranium in the Mancos Shale and the distribution of aqueous uranium in the analog sites and other sites in the region, it appears likely that uranium in the groundwater of Many Devils Wash is naturally sourced from the Mancos Shale.

New Mexico↗

USGS2017

Methods for estimating annual exceedance-probability streamflows for streams in Kansas based on data through water year 2015

A study was done by the U.S. Geological Survey in cooperation with the Kansas Department of Transportation and the Federal Emergency Management Agency to develop regression models to estimate peak streamflows of annual exceedance probabilities of 50, 20, 10, 4, 2, 1, 0.5, and 0.2 percent at ungaged locations in Kansas. Peak streamflow frequency statistics from selected streamgages were related to contributing drainage area and average precipitation using generalized least-squares regression analysis. The peak streamflow statistics were derived from 151 streamgages with at least 25 years of streamflow data through 2015. The developed equations can be used to predict peak streamflow magnitude and frequency within two hydrologic regions that were defined based on the effects of irrigation. The equations developed in this report are applicable to streams in Kansas that are not substantially affected by regulation, surface-water diversions, or urbanization. The equations are intended for use for streams with contributing drainage areas ranging from 0.17 to 14,901 square miles in the nonirrigation effects region and, 1.02 to 3,555 square miles in the irrigation-affected region, corresponding to the range of drainage areas of the streamgages used in the development of the regional equations.

Colorado, Kansas, Missouri, Nebraska, Oklahoma↗

USGS2019

Geochemical and mineralogical maps, with interpretation, for soils of the conterminous United States

Between 2007 and 2013, the U.S. Geological Survey conducted a low-density (1 site per 1,600 square kilometers, 4,857 sites) geochemical and mineralogical survey of soils in the conterminous United States. The sampling protocol for the national-scale survey included, at each site, a sample from a depth of 0 to 5 centimeters, a composite of the soil A horizon, and a deeper sample from the soil C horizon or, if the top of the C horizon was at a depth greater than 1 meter, a sample from a depth of approximately 80–100 centimeters. The <2-millimeter fraction of each sample was analyzed for a suite of 45 major and trace elements by methods that yield the total or near-total elemental concentration. The major mineralogical components in the samples from the soil A and C horizons were determined by a quantitative X-ray diffraction method using Rietveld refinement. This report presents all the maps and statistical information for each determined element and mineral along with an interpretive section discussing the possible processes that caused the observed national-scale geochemical and mineralogical patterns. Most often, the geochemical and mineralogical patterns reflect the composition of the underlying soil parent material with some modifications caused by leaching of the more mobile elements (for example, calcium and sodium) in the humid areas of the country.

Scientific Investigations Report↗

USGS1954

Monazite in Atlantic shore-line features

This report is a survey of present and potential production of monazite from part of the Maryland-Florida section of the Atlantic Coastal Plain. The part of the Coastal Plain covered here is the outer (shore-ward) half. In this area, all the large heavy-mineral placers so far discovered occur in sand bodies that, by their shape, size, orientation, and lithology, appear to be ancient beaches, spits, bars, or dunes. Smaller placers have produced from recent shore-line features. The inner part of the Coastal Plain, to be treated in another report, is underlain generally by older rocks, ranging in age from Cretaceous to older Pleistocene. Only two large heavy-mineral placers are now in production at Trail Ridge, and near Jacksonville, both in Florida. Production is planned for the near future near Yulee, Fla.: in Folkston, Ga.: and at one or two localities in eastern North Carolina. Each of these three will produce monazite as a byproduct; the total new reserve for the three placers is about 33,000 tons of monazite. In large heavy-mineral placers of this type, monazite has not been found to run more than about 1 percent of total heavy minerals. In some large placers, notably Trail Ridge, it is almost or completely lacking. No reason for its sporadic occurrence has been found in this investigation. Two placers of potential economic value have been found by this project in Virginia, one west and one east of Chesapeake Bay. Neither is of promise for monazite production, but if they serve to open up exploration or production in the area, there is a chance for monazite as a byproduct from other placers. A discovery of considerable scientific interest has to do with the occurrence of two different suites of heavy minerals in the Coastal Plain, at least south of Virginia. One, an “older” suite, lacks epidote, hornblende, and garnet; this suite occurs in all older formations and in Pleistocene deposits lying above about 50 or 60 feet above sea level. The other, “younger” suite contains these three minerals: it is restricted to recent beaches and streams, and to Pleistocene deposits at low altitudes. Monazite may occur with either of these suites. The percentage of titania (TiO 2 ) in illmenite is of both scientific and economic interest. Illmenite is by far the most sought-for mineral in present exploration, and whether it contains the “normal” 53 percent of titania or, as it commonly does in Florida, 60 percent, is often of decisive importance in its exploitation. The nature, time, and place of this “enrichment” in titania has not been worked out. The heavy-mineral industry of the area seems to give promise of considerable expansion in the near future, and a greater monazite production seems assured.

Florida;Maryl;North Carolina;South Carolina;Virgin↗

USGS1978

Areas subject to inundation by the 100-year flood in Avra Valley, Pima County, Arizona

Avra Valley in Pima County, Arizona, is sparsely populated and is used mainly for agriculture and cattle grazing; however, its proximity to Tucson makes it desirable for urban development. Administrators and planners concerned with future land development may use the map report to determine the approximate areas that are subject to inundation by the 100-year flood. Avra Valley is drained mainly by Brawley Wash; Blanco Wash drains the west side of the valley. Most of the natural drainage system consists of small braided channels bordered by narrow bands of dense vegetation, which cause floodwater to spread over wide areas of shallow depths. During the 100-year flood, the areas inundated by Brawley and Blanco Washes may join in several places. (Woodard-USGS)

Arizona↗

USGS1985

A preliminary evaluation of hydrology and water quality near the Tacoma landfill, Pierce County, Washington

The Tacoma landfill, located in western Pierce County, Washington, has been used for the disposal of waste since about 1960. Disposal operations are planned to continue at this site until at least 1990. Data were compiled and interpreted to help understand the possible effects of the landfill on water quality in the surrounding area. Data were collected from published and unpublished reports of the U.S. Geological Survey, and from predominantly unpublished data in the files of other government agencies. The Tacoma landfill is underlain by unconsolidated, glacially derived deposits that consist of a wide variety of mixtures of clay to boulder-sized materials. Ground water is mostly the result of rainfall on the land surface, and moves through artesian aquifers (under the landfill) that are tapped for both domestic and municipal use. Hazardous liquid and dissolved wastes are probably present in the landfill, and potential flow paths for waste migration exist. An undetermined number of single-family domestic wells and 18 public-supply wells are within 3 miles of the landfill, three as close as 0.2 miles. There is only limited evidence indicating ground- and surface-water contamination. Further investigations of the geology, hydrology and water quality are needed to characterize the impact the landfill has on ground- and surface-water of the surrounding area.

Washington↗

USGS2004

Evaluation of Methods Used for Estimating Selected Streamflow Statistics, and Flood Frequency and Magnitude, for Small Basins in North Coastal California

Accurate streamflow statistics are essential to water resource agencies involved in both science and decision-making. When long-term streamflow data are lacking at a site, estimation techniques are often employed to generate streamflow statistics. However, procedures for accurately estimating streamflow statistics often are lacking. When estimation procedures are developed, they often are not evaluated properly before being applied. Use of unevaluated or underevaluated flow-statistic estimation techniques can result in improper water-resources decision-making. The California State Water Resources Control Board (SWRCB) uses two key techniques, a modified rational equation and drainage basin area-ratio transfer, to estimate streamflow statistics at ungaged locations. These techniques have been implemented to varying degrees, but have not been formally evaluated. For estimating peak flows at the 2-, 5-, 10-, 25-, 50-, and 100-year recurrence intervals, the SWRCB uses the U.S. Geological Surveys (USGS) regional peak-flow equations. In this study, done cooperatively by the USGS and SWRCB, the SWRCB estimated several flow statistics at 40 USGS streamflow gaging stations in the north coast region of California. The SWRCB estimates were made without reference to USGS flow data. The USGS used the streamflow data provided by the 40 stations to generate flow statistics that could be compared with SWRCB estimates for accuracy. While some SWRCB estimates compared favorably with USGS statistics, results were subject to varying degrees of error over the region. Flow-based estimation techniques generally performed better than rain-based methods, especially for estimation of December 15 to March 31 mean daily flows. The USGS peak-flow equations also performed well, but tended to underestimate peak flows. The USGS equations performed within reported error bounds, but will require updating in the future as peak-flow data sets grow larger. Little correlation was discovered between estimation errors and geographic locations or various basin characteristics. However, for 25-percentile year mean-daily-flow estimates for December 15 to March 31, the greatest estimation errors were at east San Francisco Bay area stations with mean annual precipitation less than or equal to 30 inches, and estimated 2-year/24-hour rainfall intensity less than 3 inches.

Scientific Investigations Report↗

USGS2013

Metal prices in the United States through 2010

This report, which updates and revises the U.S. Geological Survey (USGS) (1999) publication, “Metal Prices in the United States Through 1998,” presents an extended price history for a wide range of metals available in a single document. Such information can be useful for the analysis of mineral commodity issues, as well as for other purposes. The chapter for each mineral commodity includes a graph of annual current and constant dollar prices for 1970 through 2010, where available; a list of significant events that affected prices; a brief discussion of the metal and its history; and one or more tables that list current dollar prices. In some cases, the metal prices presented herein are for some alternative form of an element or, instead of a price, a value, such as the value for an import as appraised by the U.S. Customs Service. Also included are the prices for steel, steel scrap, and iron ore—steel because of its importance to the elements used to alloy with it, and steel scrap and iron ore because of their use in steelmaking. A few minor metals, such as calcium, potassium, sodium, strontium, and thorium, for which price histories were insufficient, were excluded. The annual prices given may be averages for the year, yearend prices, or some other price as appropriate for a particular commodity. Certain trade journals have been the source of much of this price information—American Metal Market, ICIS Chemical Business, Engineering and Mining Journal, Industrial Minerals, Metal Bulletin, Mining Journal, Platts Metals Week, Roskill Information Services Ltd. commodity reports, and Ryan’s Notes. Price information also is available in minerals information publications of the USGS (1880–1925, 1996–present) and the U.S. Bureau of Mines (1926–95), such as Mineral Commodity Summaries, Mineral Facts and Problems, Mineral Industry Surveys, and Minerals Yearbook. In addition to prices themselves, these journals and publications contain information relevant to prices, which has been helpful in the preparation of this publication. Prices in this report have been graphed in 1992 constant dollars to show the effects of inflation as measured by the U.S. Bureau of Labor Statistics Consumer Price Index for All Urban Consumers, a widely used measure of overall inflation in the United States. These prices are not tabulated, but a table of the deflators used is given in an appendix. Constant dollar prices can be used to show how prices that producers receive would have less purchasing power.

Scientific Investigations Report↗

USGS2000

Environmental setting and its relations to water quality in the Kanawha River basin

The Kanawha River and its major tributary, the New River, drain 12,233 mi2 in West Virginia, Virginia, and North Carolina. Altitude ranges from about 550 ft to more than 4,700 ft. The Kanawha River Basin is mountainous, and includes parts of three physiographic provinces, the Blue Ridge (17 percent), Valley and Ridge (23 percent), and Appalachian Plateaus (60 percent). In the Appalachian Plateaus Province, little of the land is flat, and most of the flat land is in the flood plains and terraces of streams; this has caused most development in this part of the basin to be near streams. The Blue Ridge Province is composed of crystalline rocks, and the Valley and Ridge and Appalachian Plateaus Provinces contain both carbonate and clastic rocks. Annual precipitation ranges from about 36 in. to more than 60 in., and is orographically affected, both locally and regionally. Average annual air temperature ranges from about 43ºF to about 55ºF, and varies with altitude but not physiographic province. Precipitation is greatest in the summer and least in the winter, and has the least seasonal variation in the Blue Ridge Province. In 1990, the population of the basin was about 870,000, of whom about 25 percent lived in the Charleston, W. Va. metropolitan area. About 75 million tons of coal were mined in the Kanawha River Basin in 1998. This figure represents about 45 percent of the coal mined in West Virginia, and about seven percent of the coal mined in the United States. Dominant forest types in the basin are Northern Hardwood, Oak-Pine, and Mixed Mesophytic. Agricultural land use is more common in the Valley and Ridge and Blue Ridge Provinces than in the Appalachian Plateaus Province. Cattle are the principal agricultural products of the basin. Streams in the Blue Ridge Province and Allegheny Highlands have the most runoff in the basin, and streams in the Valley and Ridge Province and the southwestern Appalachian Plateaus have the least runoff. Streamflow is greatest in the spring and least in the autumn. About 61 percent of the basin's population use surface water from public supply for their domestic needs; about 30 percent use self-supplied ground water, and about nine percent use ground water from public supply. In 1995, total withdrawal of water in the basin was about 1,130 Mgal/d. Total consumptive use was about 118 Mgal/d. Surface water in the Blue Ridge Province is usually dilute (less than 100 mg/L dissolved solids) and well aerated. Dissolved- solids concentrations in streams of the Valley and Ridge Province at low flow are typically greater (150-180 mg/L) than those in the Blue Ridge Province. The Appalachian Plateaus Province contains streams with the most dilute (less than 30 mg/L dissolved solids) and least dilute (more than 500 mg/L dissolved solids) water in the basin. Coal mining has degraded more miles of streams in the basin than any other land use. Streams that receive coal-mine drainage may be affected by sedimentation, and typically contain high concentrations of sulfate, iron, and manganese. Other major water-quality issues include inadequate domestic sewage treatment, present and historic disposal of industrial wastes, and logging, which results in the addition of sediment, nutrients, and other constituents to the water. One hundred eighteen fish species are reported from the Kanawha River system downstream from Kanawha Falls. Of these, 15 are listed as possible, probable, or known introductions. None of these fish species is endemic to the Kanawha River Basin. The New River system has only 46 native fishes, the lowest ratio of native fishes to drainage area of any river system in the eastern United States, and the second-highest proportion of endemic fish species (eight of 46) of any river system in the eastern United States.

North Carolina, Virginia, West Virginia↗

USGS2000

Climatology, hydrology, and simulation of an emergency outlet, Devils Lake basin, North Dakota

Devils Lake is a natural lake in northeastern North Dakota that is the terminus of a nearly 4,000-square-mile subbasin in the Red River of the North Basin. The lake has not reached its natural spill elevation to the Sheyenne River (a tributary of the Red River of the North) in recorded history. However, geologic evidence indicates a spill occurred sometime within the last 1,800 years. From 1993 to 1999, Devils Lake rose 24.5 feet and, at the present (August 2000), is about 13 feet below the natural spill elevation. The recent lake-level rise has caused flood damages exceeding $300 million and triggered development of future flood-control options to prevent further infrastructure damage and reduce the risk of a potentially catastrophic uncontrolled spill. Construction of an emergency outlet from the west end of Devils Lake to the Sheyenne River is one flood-control option being considered. This report describes the climatologic and hydrologic causes of the recent lake level rise, provides information on the potential for continued lake-level rises during the next 15 years, and describes the potential effectiveness of an emergency outlet in reducing future lake levels and in reducing the risk of an uncontrolled spill. The potential effects of an outlet on downstream water quantity and quality in the upper Sheyenne River also are described.

South Dakota↗

USGS2008

Documentation of Computer Program INFIL3.0 - A Distributed-Parameter Watershed Model to Estimate Net Infiltration Below the Root Zone

This report documents the computer program INFIL3.0, which is a grid-based, distributed-parameter, deterministic water-balance watershed model that calculates the temporal and spatial distribution of daily net infiltration of water across the lower boundary of the root zone. The bottom of the root zone is the estimated maximum depth below ground surface affected by evapotranspiration. In many field applications, net infiltration below the bottom of the root zone can be assumed to equal net recharge to an underlying water-table aquifer. The daily water balance simulated by INFIL3.0 includes precipitation as either rain or snow; snowfall accumulation, sublimation, and snowmelt; infiltration into the root zone; evapotranspiration from the root zone; drainage and water-content redistribution within the root-zone profile; surface-water runoff from, and run-on to, adjacent grid cells; and net infiltration across the bottom of the root zone. The water-balance model uses daily climate records of precipitation and air temperature and a spatially distributed representation of drainage-basin characteristics defined by topography, geology, soils, and vegetation to simulate daily net infiltration at all locations, including stream channels with intermittent streamflow in response to runoff from rain and snowmelt. The model does not simulate streamflow originating as ground-water discharge. Drainage-basin characteristics are represented in the model by a set of spatially distributed input variables uniquely assigned to each grid cell of a model grid. The report provides a description of the conceptual model of net infiltration on which the INFIL3.0 computer code is based and a detailed discussion of the methods by which INFIL3.0 simulates the net-infiltration process. The report also includes instructions for preparing input files necessary for an INFIL3.0 simulation, a description of the output files that are created as part of an INFIL3.0 simulation, and a sample problem that illustrates application of the code to a field setting. Brief descriptions of the main program routine and of each of the modules and subroutines of the INFIL3.0 code, as well as definitions of the variables used in each subroutine, are provided in an appendix.

Scientific Investigations Report↗

USGS2023

Selenium hazards in the Salton Sea environment—Summary of current knowledge to inform future wetland management

Quaternary marine and continental shales in the western United States are sources of selenium that can be loaded into the aquatic environment through mining, agricultural, and energy production processes. The mobilization of selenium from shales through agricultural irrigation has been recognized since the 1930s; however, discovery of deformities in birds and other wildlife using agricultural habitats during the 1980s spurred studies to determine the extent and effects of the contamination. Through these early studies, researchers determined that biota in the Salton Sea drainage basin was at risk from legacy selenium contamination in the Colorado River watershed. The Salton Sea and its surrounding managed and unmanaged wetlands provide vital inland habitat and trophic support for diverse assemblages of resident and migratory wildlife, and understanding regional selenium hazards for these trust species is a priority for many Federal and State agencies. The modern Salton Sea is a shallow, landlocked saline lake in Riverside and Imperial Counties (not shown) of California that is sustained by irrigation return and perennial river inflow. Changes in water transfer agreements under the 2003 Quantification Settlement Agreement (QSA) have resulted in reduced irrigation flow, declining lake levels, and the evolution of unmanaged wetlands in areas where drains and rivers no longer reach the Salton Sea. These wetlands provide additional habitat for some species of concern, but their potential to increase selenium hazards for trust species is largely unknown. From the 1980s to 2020, efforts to document selenium contamination and effects throughout the region have resulted in a considerable amount of selenium data from the Salton Sea and its surrounding drainage basin; however, no long-term (greater than 20 years), consistent sampling program has been established, and all data have been collected by different entities using a variety of protocols and analytical techniques. This lack of coordination has been previously documented in regional management plans and has led to difficulty in reliably assessing selenium hazards in the Salton Sea environment. This report provides a summary of the available disparate selenium information collected from water, sediment, and biota in the Salton Sea region since the 1980s and to identify data gaps that need to be filled to understand the potential effects of selenium on species of concern, including federally endangered desert pupfish ( Cyprinodon macularius ) and Yuma Ridgway’s Rail ( Rallus obsoletus yumanensis; formerly Yuma Clapper Rail, Rallus longirostris yumanensis ). Available data from the Salton Sea drainage basin show that water from the Colorado River has the lowest selenium concentration of all surface water sources. All other surface water flowing into the Salton Sea has elevated selenium concentrations due to evaporation and evapotranspiration that occurs in agricultural fields and associated water delivery infrastructure or leaching of selenium from irrigated farmland soils. The Salton Sea has lower selenium concentrations because of various biogeochemical processes that recycle selenium into the sediment or volatilize it to the atmosphere; however, these mechanisms are not well defined, and it is not clear if selenium cycling will change in response to possible changes in the oxidation state of the Salton Sea bottom waters as water levels decline. Agricultural drains have the highest average selenium concentrations, but few drains have been sampled since changes in irrigation practices have occurred (due to the 2003 QSA). Groundwater selenium concentrations are variable; some wells south of the Salton Sea have selenium concentrations as high as 300 micrograms per liter (µg/L), whereas selenium concentrations are below detection in other wells. Groundwater and surface-water geothermal discharge zones around the margins of the Salton Sea and in unmanaged wetlands have not been studied in detail, and published selenium measurements are not available for these surface features. Selenium concentrations in the sediment of the Salton Sea drainage basin are highest in wetland particulate organic matter and the Salton Sea lakebed, indicating that removal of selenium from the water to the sediment has been a primary mechanism for keeping selenium concentrations low in the water column. Sediment selenium concentrations in wetlands are lower than in the Salton Sea but higher than inflowing drains and rivers, indicating the lentic wetland sites also may be important sinks for selenium because of biogeochemical processes. Sediment selenium data have not been collected in agricultural drains since changes in irrigation practices occurred (due to the 2003 QSA), and it is unknown if selenium sequestration from the water column has changed in these systems. We divided biological data into broad taxonomic categories, including primary producers, invertebrates, herpetofauna, mammals, fishes, and birds to facilitate evaluation of selenium concentrations and spatiotemporal trends observed in the Salton Sea. Overall, selenium concentrations were substantially greater in algae samples compared to all vascular plant samples combined. Median selenium concentrations in several invertebrate taxa (Chironomidae, Formicidae, Corixidae, Corbiculidae and Nereididae, and Decapoda) exceeded the maximum suggested dietary threshold of 3.0–4.0 micrograms per gram (µg/g) dry weight (dw) for predators consuming invertebrates in aquatic food webs. The greatest number of samples were collected from fish, and selenium distributions among species and locations showed that the range for most samples was lower than the U.S. Environmental Protection Agency selenium criterion for aquatic life (8.5 µg/g dw whole body, 11.3 µg/g dw fillets). The median selenium concentrations for whole body fish were below the selenium criterion in most locations, except for bairdiella ( Bairdiella icistia ) from the Salton Sea and irrigation drains, a few individual tilapia spp. (family Cichlidae, including genera Tilapia, Oreochromis , and their hybrids) from the river and river outlets, and several western mosquitofish ( Gambusia affinis ) and sailfin molly ( Poecilia latipinna ) from irrigation drain outlets. For avian samples combined among years and locations, median selenium concentrations in livers from all families except waders and Ibis (family Threskiornithidae) were higher than levels expected to cause selenium toxicosis (10–20 µg/g dw), and all median egg concentrations were above or near 6.0 μg/g dw, which is a conservative threshold value for reproductive impairment. Most knowledge gaps we identified for water, sediment, and biota were interrelated, and the use of integrated approaches to address knowledge gaps can provide greater insight into the drivers behind selenium hazards. Integrated water, sediment, and biota studies could help identify cost-effective management solutions that serve multiple purposes. A comprehensive analysis of the hydrology, biogeochemistry, and food-web processes in wetlands and other habitats can inform predictive models to identify drivers of selenium bioavailability, uptake from the environment and subsequent trophic transfer, ultimately forming the basis for experimental habitat management manipulations to minimize selenium hazards to wildlife. Furthermore, a comprehensive, long-term sampling and analytical laboratory plan would enable comparison of data among different entities that are sampling at the Salton Sea. Such efforts are well suited to help fill knowledge gaps that preclude understanding of selenium hazards and future management options for biota using Salton Sea habitats, including newly formed wetlands throughout the region. All data compiled for this report are available in two U.S. Geological Survey data releases: Groover and others (2022) for water and sediment samples and De La Cruz and others (2022) for biological samples. The data releases include all publicly available data for selenium concentrations in water, sediment, and biological samples collected in and around the Salton Sea, including the Coachella and Imperial Valleys. The data releases also include previously unpublished data.

California↗