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At least 1,387 records · Page 77Linked to original sources

Geophysical expression of elements of the Rio Grande rift in the northeast Tusas Mountains - Preliminary interpretations

New interpretations of the nature of the Rio Grande rift and pre-existing rocks in the northeast Tusas Mountains region are derived from new and existing gravity and aeromagnetic data. 12-15 mGal amplitude gravity lows are interpreted to mainly reflect large thicknesses of the upper Oligocene to upper Miocene, syn-rift Los Pinos Formation and possibly significant amounts of the Eocene El Rito Formation. The Broke Off Mountain sub basin, named after the location of its greatest inferred depth, is interpreted to be a ~40 km long and ~13 km wide structure elongated in a northwest trend at the western margin of the San Luis Basin. The sub basin is interpreted to contain a maximum combined thickness of 900-2300 m of the Los Pinos Formation and El Rito Formation, with the Los Pinos Formation constituting the majority of the section. Sub basin age is constrained to be older than 21.6 ± 1.4 Ma, the age of a Hinsdale Formation basalt flow that caps the Los Pinos Formation section at Broke Off Mountain. This age constraint and surface geology indicate a pre- and early-rift age. The structural fabric of the northeast Tusas Mountains region is dominated by northwest-trending normal faults, as indicated by geologic mapping and interpretation of aeromagnetic data. Preliminary analysis of the aeromagnetic data suggests that lineaments, possibly reflecting faulting, trend through volcanic rocks as young as Pliocene in age. If correct, these interpretations challenge commonly held beliefs regarding two stages in the structural style of rifting, where early (Oligocene-Miocene) rifting was characterized by broad, shallow basins bounded by northwest-trending faults and later (Miocene-Pliocene) rifting was characterized by deep, narrow basins bounded by north-trending faults. The Broke Off Mountain sub basin is a counter example of a pre- and early-rift, deep and narrow basin. We hypothesize that the Broke Off Mountain sub basin may represent a southward extension of the Monte Vista graben in Colorado, based on similarities in geophysical expression, stratigraphy, and its position at the western portion of the San Luis Basin

Colorado, New Mexico↗

Element cycling in the Middle-Late Triassic Shublik Formation: Mineralization vs. recycling of biolimiting nutrients in an unconventional resource play

The Triassic Shublik Formation in northern Alaska is one of the major source rocks in North America, having generated much of the petroleum in Prudhoe Bay and associated fields. The middle Shublik Formation, the focus of this study, is a highly phosphatic, organic-rich carbonate mudstone interval. Apatite cements can occur as phosphatic peloids, steinkerns, elongate or angular nodules, and shells or shell fragments. We propose a model whereby phosphatization is favored in early diagenetic environments that have low concentrations of dissolved iron relative to reactive organic matter in the pore water sulfate reduction zone.

Alaska↗

Appendix D: Synthesis element 1 (revised): Water temperature effects on fisheries and stream health in nontidal waters

A limited review of relevant scientific literature related to temperature sensitivities of fish species, stream health indicators, and any related geospatial information was conducted. Based on this review, we provide a syntheses of information related to nontidal waters in the Chesapeake Bay Rising stream temperatures will have a range of impacts on nontidal aquatic ecosystems. Cold headwaters and associated species like brook trout and sculpin are especially vulnerable to higher stream temperatures. Efforts could be taken to identify and protect high quality resilient cold headwater brook trout (Salvelinus fontinalis) habitat. More information on groundwater impacts on stream temperatures and ecologically relevant temperature thresholds for species of concern could help resource managers identify temperature resilient habitats and populations. A vulnerability assessment could be valuable to better understand the drivers and stressors of rising stream temperatures, their effects on aquatic resources, and the risk to fish and other aquatic species. Further research could help in developing and fully vetting a complete list of cold/cool water benthic macroinvertebrate taxa and freshwater mussel taxa that are vulnerable to temperature change in the Chesapeake watershed.

Report↗

Understanding our fragile environment; Lessons from geochemical studies

An understanding of our fragile environment can begin with a recognition of the importance of certain elements, commonly called "minerals substances" (such as iron and zinc), in the lives of humans and animals and in the soils that support plants. This recognition is well deserved because these elements are essential for the life or optimum health of an organism. Some elements such as carbon, hydrogen, oxygen, magnesium, potassium, and phosphorus are required in relatively large amounts by organisms. However, others are required in smaller quantities; these are referred to as trace elements. Diseases have been related to the deficiency of about 20 elements in animals and humans and to the deficiency of approximately 13 elements in plants. At the same time, if these and other elements occur in quantities great enough, toxicity can result. An element, or any substance, that occurs in the environment and contains concentrations above what are considered to be background levels may be considered a contaminant. When contaminants occur at levels that are potentially harmful to organisms, they are labeled as hazards. Often the quantitative difference between essential amounts and toxic concentrations of these elements is very small. For example, the trace element selenium is required at a level of no less than 0.4 ppm in the diet of cattle but can be toxic at levels greater than approximately 4ppm. Elements that are required for survival by animals and plants are termed essential, while those not required are nonessential. Trace essential elements such as fluorine, copper, selenium, molybdenum, and others listed in the table on page 1 can be hazardous to life forms if present at high levels. Nonessential heavy metals such as arsenic, lead, mercury, cadmium, and chromium are usually toxic to organisms at much lower levels than trace essential elements. Depending on the association that these nonessential elements may form with natural geologic materials such as organic matter, other elements or minerals, and adsorbers (such as clays), these elements can range from being safe to being extremely toxic. The elemental composition of plants, animals, and humans correlates with the geologic makeup of the Earth, and life has evolved reflecting these natural occurrences. The science of environmental geochemistry examines the interrelationship of life with the physical and chemical Earth.

Circular↗

Geochemical and mineralogical study of the Red Mountain porphyry copper-molybdenum deposit and vicinity, Santa Cruz County, Arizona

The Red Mountain porphyry copper-molybdenum deposit (Cu-Mo deposit or PCD) is located in the northern part of the Patagonia Mountains, Santa Cruz County, Arizona. Extensive core drilling has delineated a large, deep-seated, structurally intact mineral system that extends from the present surface to depths of more than 1,765 meters. This system is hosted in a thick complex of predominantly felsic to andesitic volcanic rocks of the Cretaceous Period. This complex was intruded by scattered bodies of the Tertiary Period that are predominantly quartz monzonite porphyry; no major associated source intrusion has yet been found at depth. A total of 818 samples of core were analyzed for as many as 44 elements. The abundances and distributions at depth of at least 17 of these elements (silver [Ag], arsenic [As], gold [Au], boron [B], bismuth [Bi], copper [Cu], mercury [Hg], potassium [K], molybdenum [Mo], lead [Pb], sulfur [S], antimony [Sb], tin [Sn], tellurium [Te], thallium [Tl], tungsten [W], and zinc [Zn]) are related mostly to events that generated the Red Mountain system. Many of these same samples were also analyzed by X-ray diffraction for a suite of minerals. The multielement and mineralogical analyses of the core samples provide important information about the concentrations, associations, and distributions of select elements and minerals, including zoning patterns that may not be apparent from visual examination of core samples. The distributions of selected elements and minerals in these samples reveal an unusually complete mineral system that extends from a typical PCD with potassic alteration at depth to peripheral zones of phyllic and advanced argillic alteration as well as a copper-rich supergene enriched zone and the remnants of a leached cap. R-mode factor analysis was run with 34 elements for a set of samples from the deep part of the hypogene Cu-Mo deposit and another set from the part of the supergene zone with the highest copper enrichment. For the hypogene zone dataset, five factors are related to the PCD: (1) Ag, Cu, Mo, S, and Te; (2) As, B, Hg, and Sb; (3) Au and sodium (Na); (4) manganese (Mn), Pb, and Zn; and (5) K and Tl. For the supergene dataset, the deposit-related factors include (1) Cu, Mo, S, and Te; (2) Ag, As, Hg, Pb, Sb, and Tl; (3) Au and Na; and (4) K and rubidium (Rb). The changes in element associations between the two datasets indicate that some of these new associations are a result of formation of several suites of hypogene minerals in the deep part of the deposit and different hypogene mineral suites in the peripheral part of the deposit. Some changes may be because of the effects of supergene processes. Zones containing deposit-related elements and minerals common to many PCDs are present at Red Mountain. These zones include a crude, inverted cup-shaped shell containing anomalous copper accompanied by high concentrations of Ag, Au, K, Mo, total S, sulfate S, Sb, Te, and Tl, as well as local concentrations of As, B, Hg, Pb, and Zn. Hydrothermal minerals spatially associated with the deep hypogene Cu-Mo deposit include chalcopyrite, molybdenite, pyrite, plagioclase, orthoclase, biotite, magnetite, calcite, quartz, and anhydrite. Many of the hydrothermally deposited elements that are spatially related to the deposit are also concentrated in zones above the deep part of the deposit, including Ag, As, K, Pb, Sb, Te, Tl, and Zn. These elements are concentrated either (1) in generally wide, flat zones present in the upper part of the system or (2) in crudely arcuate peripheral zones found mainly in the middle part of the system and surrounding the deep part of the deposit. Near-surface, restricted hypogene anomalies are present for bismuth, mercury, tin, and tungsten. The upper part of the deposit has been subjected to supergene enrichment and weathering. Deposit-related elements that remain anomalous in this area include Ag, As, Au, B, Bi, cobalt (Co), Cu, Hg, Mo, Pb, S, Sb, Sn, Te, Tl, uranium (U), and W. These positive concentrations indicate that, with the exception of copper and possibly mercury and uranium, these elements had relatively low chemical mobilities in the supergene enrichment and later weathering environments at Red Mountain. Most may have been deposited during one or more hypogene events and then redistributed locally during later events. Zinc is the only deposit-related element that has clearly been depleted as a result of supergene and (or) weathering events. Minerals that are common in the unweathered upper part of the system include chalcocite, pyrite, quartz, sericite, alunite, and pyrophyllite, as well as less common covellite, enargite, tennantite, tourmaline, barite, anglesite, and other sulfide or sulfate minerals. Subsequent to formation of the Red Mountain Cu-Mo deposit and supergene enrichment, chemical weathering produced an area of pervasive hematite and other iron oxides in the near-surface part of the deposit to form a leached cap. These iron-rich minerals formed primarily as a result of the oxidation of pyrite. This event was accompanied by losses of cobalt, mercury, magnesium, and zinc, as well as destruction of sericite, plagioclase, pyrite, clay minerals, and pyrophyllite. A total of 122 rock samples, 119 soil samples, and samples of three plant species (57 mesquite, 108 oak, and 68 juniper) were collected over and around Red Mountain. For the rock and soil samples, the distributions of anomalous Ag, As, Bi, Cu, Fe, Mo, Pb, Sb, Te, and Tl best delineated the exposed part of the deposit. The highest concentrations of many of these elements are centered on one or both of two main areas with exposures of quartz monzonite porphyry. The high concentrations of arsenic in the deposit area (as much as 390 parts per million (ppm) in rock and 1,500 ppm in soil) and of lead (as much as 2,370 ppm in rock and 1,490 ppm in soil) are particularly noteworthy. The concentrations of various elements in the plant ash vary widely among the three species and are species dependent. Many of the deposit-related elements are either nonessential for plant growth or are considered toxic at certain concentration ranges. In spite of this, the distributions of potentially toxic Ag, As, Bi, Cd, Cu, Mo, Pb, Sb, selenium (Se), and Zn produce deposit-related anomalies for one or more of the three species. Vegetation sampling offered no advantage over rock or soil sampling as an exploration tool. From an environmental standpoint, however, the plant analyses provide baseline data for both essential and nonessential elements that might be useful, for example, for selecting native plant species for revegetating mine waste areas. The exposed part of the Red Mountain deposit has not been greatly disturbed as a result of mining and other activities. However, some of the rock, soil, and plant samples that were collected near the Harshaw Creek and Alum Gulch drainages, which are peripheral to Red Mountain, are also anomalous for various deposit-related elements. These anomalies are probably the result of dispersion of stream sediments contaminated with material from past mining.

Arizona↗