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At least 1,387 records · Page 77Linked to original sources
USGS1994

Effects of ground-water chemistry and flow on quality of drainflow in the western San Joaquin Valley, California

Chemical and geohydrologic data were used to assess the effects of regional ground-water flow on the quality of on-farm drainflows in a part of the western San Joaquin Valley, California. Shallow ground water beneath farm fields has been enriched in stable isotopes and salts by partial evaporation from the shallow water table and is being displaced by irrigation, drainage, and regional ground-water flow. Ground-water flow is primarily downward in the study area but can flow upward in some down- slope areas. Transitional areas exist between the downward and upward flow zones, where ground water can move substantial horizontal distances (0.3 to 3.6 kilometers) and can require 10 to 90 years to reach the downslope drainage systems. Simulation of ground-water flow to drainage systems indicates that regional ground water contributes to about 11 percent of annual drainflow. Selenium concentrations in ground water and drainwater are affected by geologic source materials, partial evaporation from a shallow water table, drainage-system, and regional ground-water flow. Temporal variability in drainflow quality is affected in part by the distribution of chemical constituents in ground water and the flow paths to the drainage systems. The mass flux of selenium in drainflows, or load, generally is proportional to flow, and reductions in drainflow quantity should reduce selenium loads over the short-term. Uncertain changes in the distribution of ground-water quality make future changes in drainflow quality difficult to quantify.

Open-File Report↗
USGS1969

Hydrogeologic data for the southwestern coastal river basins, Connecticut

This report presents hydrologic and geologic data collected by the U.S. Geological Survey during an investigation of water resources in the southwestern coastal river basins of Connecticut in cooperation with the Connecticut Water Resources Commission. These basins occupy about 394 square miles in Connecticut and 46 square miles in New York, including the towns of Greenwich, Stamford, Darien, New Canaan, Norwalk, Wilton, Westport, Weston, Fairfield, Easton, and Bridgeport and parts of Danbury, Ridgefield, Redding, Bethel, Newtown, Trumbull, Monroe, Shelton, and Stratford. A companion interpretive report evaluating the water resources of the basins will be published as Connecticut Water Resources Bulletin No. 17. The data on the following pages serve to document and supplement that report and should be especially useful in planning the development of water resources at specific localities. Data were collected as part of this investigation during the period July 1963 through November 1966. Streamflow records from continuous-record gaging stations in the basins have been published annually along with data from other parts of the State in a series of U.S. Geological Survey reports entitled "Surface Water Records of Connecticut." Water-level measurements in wells throughout the State from 1960 through 1966, including most of those made as part of this investigation, are published in Connecticut Water Resources Bulletins No. 7 and No. 13. Most other data collected during this investigation are tabulated on the following pages. Included are some well records and chemical analyses of water samples collected prior to July 1963 and not previously published. The locations of sites at which data were collected are shown on plate A in the pocket at the back of the report. Data presented, unless otherwise noted, were collected by U.S. Geological Survey personnel.

Connecticut↗
USGS1980

Chemical analyses of coal and coal-associated shale samples from the lower part of the Fort Union Formation, Little Snake River coal field, Sweetwater and Carbon counties, Wyoming

As part of a continuing program by the U.S. Geological Survey to collect and analyze representative samples of U.S. coals, 26 coal and 5 coal-associated shale samples were collected from 13 core and rotary-drill holes in the lower part of the Paleocene Fort Union Formation in the Little Snake River coal field, Sweetwater and Carbon Counties, Wyoming (fig. 1). The samples are briefly described in table 1. Twenty-six of the samples were collected from eight core holes that were drilled in connection with the Red Rim EMRIA (Energy Mineral Rehabilitation Inventory and Analyses) study (U.S. Department of the Interior, 1976). The locations of these eight holes and five other drill holes are shown in figure 2. Detailed geologic mapping of part of the sample collection area was done by Sanders (1974) in his work on the Riner quadrangle. Seven of the core holes (index map locations 1-7) are located in this quadrangle. In his discussion, Sanders (1974) describes the coal beds in the lower part of the Fort Union Formation as being thin, discontinuous, and generally lenticular. Few beds attain a thickness of more than five feet. In the Riner quadrangle coal beds in the lower part of the Fort Union Formation dip 12° to 24° northwestward.

Wyoming↗
USGS1993

Understanding our fragile environment; Lessons from geochemical studies

An understanding of our fragile environment can begin with a recognition of the importance of certain elements, commonly called "minerals substances" (such as iron and zinc), in the lives of humans and animals and in the soils that support plants. This recognition is well deserved because these elements are essential for the life or optimum health of an organism. Some elements such as carbon, hydrogen, oxygen, magnesium, potassium, and phosphorus are required in relatively large amounts by organisms. However, others are required in smaller quantities; these are referred to as trace elements. Diseases have been related to the deficiency of about 20 elements in animals and humans and to the deficiency of approximately 13 elements in plants. At the same time, if these and other elements occur in quantities great enough, toxicity can result. An element, or any substance, that occurs in the environment and contains concentrations above what are considered to be background levels may be considered a contaminant. When contaminants occur at levels that are potentially harmful to organisms, they are labeled as hazards. Often the quantitative difference between essential amounts and toxic concentrations of these elements is very small. For example, the trace element selenium is required at a level of no less than 0.4 ppm in the diet of cattle but can be toxic at levels greater than approximately 4ppm. Elements that are required for survival by animals and plants are termed essential, while those not required are nonessential. Trace essential elements such as fluorine, copper, selenium, molybdenum, and others listed in the table on page 1 can be hazardous to life forms if present at high levels. Nonessential heavy metals such as arsenic, lead, mercury, cadmium, and chromium are usually toxic to organisms at much lower levels than trace essential elements. Depending on the association that these nonessential elements may form with natural geologic materials such as organic matter, other elements or minerals, and adsorbers (such as clays), these elements can range from being safe to being extremely toxic. The elemental composition of plants, animals, and humans correlates with the geologic makeup of the Earth, and life has evolved reflecting these natural occurrences. The science of environmental geochemistry examines the interrelationship of life with the physical and chemical Earth.

Circular↗
USGS2000

U.S. talc; baby powder and much more

When most people think of talc, they probably envision talcum and baby powder. Since talc is very soft and easily carved, one might also think of sculptures in soapstone (massive talc). In fact, these uses of talc are quite minor compared to its wide variety of applications in manufacturing and agriculture. High-quality (pure) talc has many physical and chemical properties favorable for its use, such as its softness, purity, fragrance retention, whiteness, luster, moisture content, oil and grease adsorption, chemical inertness, low electrical conductivity, high dielectric strength, and high thermal conductivity (Virta, 1998).

Fact Sheet↗
USGS1997

USGS Blind Sample Project: monitoring and evaluating laboratory analytical quality

The U.S. Geological Survey (USGS) collects and disseminates information about the Nation's water resources. Surface- and ground-water samples are collected and sent to USGS laboratories for chemical analyses. The laboratories identify and quantify the constituents in the water samples. Random and systematic errors occur during sample handling, chemical analysis, and data processing. Although all errors cannot be eliminated from measurements, the magnitude of their uncertainty can be estimated and tracked over time. Since 1981, the USGS has operated an independent, external, quality-assurance project called the Blind Sample Project (BSP). The purpose of the BSP is to monitor and evaluate the quality of laboratory analytical results through the use of double-blind quality-control (QC) samples. The information provided by the BSP assists the laboratories in detecting and correcting problems in the analytical procedures. The information also can aid laboratory users in estimating the extent that laboratory errors contribute to the overall errors in their environmental data.

Fact Sheet↗
USGS1995

Volcanic investigations in the Commonwealth of the Northern Mariana Islands, April to May 1994

A team of U.S. Geological Survey geologists, a seismologist, and technicians gathered new geologic, seismic, and deformation data in the Commonwealth of the Northern Mariana Islands (CNMI). Nine volcanic islands on the active East Mariana Ridge north of Saipan were examined between April 20 and May 3, 1994. In addition, a new radio-telemetry seismic station was installed on the island of Agrihan (also spelled Agrigan). This report describes our continuing efforts, that began in May 1981, to establish volcano monitors and to assess hazards in the CNMI. Our previous visits, from September 1990 to May 1992, are documented in Moore and others (1991, 1993). Regional seismicity of the Mariana Island region, as recorded by the USGS National Earthquake Information Center (NEIC), included at least 324 events between January 1, 1991, and February 4, 1994. The largest event was a M 8.1 Guam earthquake on August 8, 1993, which caused extensive damage to that island and was felt on Saipan. Intermittent seismic activity continues to occur in the Anatahan-Sarigan, Guguan-Alamagan-Pagan, and PaganAgrihan-Asuncion areas. Mount Pagan volcano was actively erupting ash during our 11 days on the island of Pagan. We were able to document seismicity and ground deformation associated with this volcanic activity. None of the other subaerial volcanoes in the chain showed signs of eruptive activity during our visit, but an overflight in a fixed-wing aircraft by geologist Richard Moore and CNMI Lieutenant Governor Jesus Borja detected an apparent submarine eruption between Farallon de Pajaros (also known as Uracas or Uracus) and Maug. The only surveillance of the three uninhabited islands of Farallon de Pajaros, Maug, and Sarigan was by aerial reconnaissance. Geologists studied the other six islands in greater detail by field mapping and aerial surveillance. Electronic distance measurement (EDM) permanent-glass monitor lines were measured on Agrihan, Pagan, and Anatahan. The majority of line-length changes on Agrihan were insignificant (<16 mm). Mount Pagan's south EDM monitor was reestablished, and 1994 results, compared with 1983 measurements, show large changes associated with renewed volcanic activity. Contractions of 59 mm (stations INS to REF) and 157 mm (stations INS to MID) were measured on the south monitor. The southwest Pagan EDM monitor showed a 56 mm contraction for the same period (stations PAGAN 1 to RIDGE 2). Line-length change of this sense and magnitude usually indicates that inflation has occurred in the volcano. Measurements during the 1994 visit to Pagan Island showed no significant changes (for all measurements made during April-May 1994). Anatahan also showed changes as large as -50 mm, accumulated over a time span of approximately two years. Temperatures and pH values of hot spring waters on Agrihan, Pagan, and Anatahan and fumaroles on Agrihan and Anatahan were measured. The temperature data indicated no significant change in the state of these volcanoes since 1992. We collected warm spring water from Lagoonam Sanhalom (Inland Lake) near Mount Pagan. In addition, we started geologic mapping on Asuncion and Guguan, collected charcoal to date three eruptions of Mount Pagan, and collected rocks on Asuncion, Guguan, Pagan, and Alamagan for petrographic and chemical studies. We conclude that the low and infrequent shallow seismicity, lack of significant deformation, and low fumarole temperatures suggest that no eruption is likely soon on Agrihan and Alamagan. Anatahan's deformation pattern continues to behave in an erratic manner. Because f the lack of seismicity, it seems unlikely that an eruption of Anatahan will occur soon. The persistent volcanic tremor and significant EDM changes on Mount Pagan mean that small explosive eruptions will continue to occur.

Mariana Islands↗
USGS2006

Reconnaissance-level assessment of water and bottom-sediment quality, including pesticides and mercury, in Yankton Sioux Tribe wetlands, Charles Mix County, South Dakota, June-July 2005

During June and July 2005, water and bottom-sediment samples were collected from selected Yankton Sioux Tribe wetlands within the historic Reservation area of eastern Charles Mix County as part of a reconnaissance-level assessment by the U.S. Geological Survey and Yankton Sioux Tribe. The water samples were analyzed for pesticides and mercury species. In addition, the water samples were analyzed for physical properties and chemical constituents that might help further characterize the water quality of the wetlands. The bottom-sediment samples were analyzed for mercury species. During June 2005, water samples were collected from 19 wetlands and were analyzed for 61 widely used pesticide compounds. Many pesticides were not detected in any of the water samples and many others were detected only at low concentrations in a few of the samples. Thirteen pesticides were detected in water samples from at least one of the wetlands. Atrazine and de-ethyl atrazine were detected at each of the 19 wetlands. The minimum, maximum, and median dissolved atrazine concentrations were 0.056, 0.567, and 0.151 microgram per liter (?g/L), respectively. Four pesticides (alachlor, carbaryl, chlorpyrifos, and dicamba) were detected in only one wetland each. The number of pesticides detected in any of the 19 wetlands ranged from 3 to 8, with a median of 6. In addition to the results for this study, recent previous studies have frequently found atrazine in Lake Andes and the Missouri River, but none of the atrazine concentrations have been greater than 3 ?g/L, the U.S. Environmental Protection Agency's Maximum Contaminant Level for atrazine in drinking water. During June and July 2005, water and bottom-sediment samples were collected from 10 wetlands. Water samples from each of the wetlands were analyzed for major ions, organic carbon, and mercury species, and bottom-sediment samples were analyzed for mercury species. For the whole-water samples, the total mercury concentrations ranged from 1.11 to 29.65 nanograms per liter (ng/L), with a median of 10.56 ng/L. The methylmercury concentrations ranged from 0.45 to 14.03 ng/L, with a median of 2.28 ng/L. For the bottom-sediment samples, the total mercury concentration ranged from 21.3 to 74.6 nanograms per gram (ng/g), with a median of 54.2 ng/g. The methylmercury concentrations ranged from <0.11 to 2.04 ng/g, with a median of 0.78 ng/g. The total mercury concentrations in the water samples were all much less than 2 ?g/L (2,000 ng/L), the U.S. Environmental Protection Agency's Maximum Contaminant Level for mercury in drinking water. However, water samples from four of the wetlands had concentrations larger than 0.012 ?g/L (12 ng/L), the State of South Dakota's chronic standard for surface waters, including wetlands. Maximum methylmercury concentrations for this study are larger than reported concentrations for wetlands in North Dakota and concentrations reported for the Cheyenne River Indian Reservation in South Dakota.

South Dakota↗
USGS2005

Methods for synthesis of some jarosites

Experimental procedures in this report summarize attempts to synthesize potassium-, hydronium-, sodium-, and mixed-composition (hydronium-bearing) jarosites. After experimentation, some acceptable combinations of chemical and physical factors were found to routinely synthesize chemically different jarosites, which were used as part of a characterization study of some natural and synthetic jarosites. Jarosite is a sulfate mineral that is common in geologic settings where iron sulfide minerals such as pyrite or marcasite are subject to oxidative weathering. The presence of jarosite is a hallmark of acidic conditions. Jarosite forms as a secondary mineral in weathered sulfidic ores, coal mine wastes, on oxidizing mine wastes, and in streams affected by acid mine drainage. Jarosite also forms in acid-sulfate soils, as an alteration product of sulfidic shales, and in hydrothermal environments. Because of its important role in earth surface processes, the USGS is conducting mineralogical, geochemical, and remote sensing studies to characterize natural jarosites and to elucidate its stability range and conditions of formation. The presence of jarosite is not limited to the Earth. The recent identification of jarosite in the rocks at the Meridiani Planum on Mars has given planetary geologists reason to think that jarosite may be evidence of relict lacustrine (lake systems) or hydrothermal (water enriched magma emanations) systems on the Martian surface. USGS scientists are currently developing jarosite detection systems that can be placed on orbiting spectrometers. One day these systems may guide Mars landers to sites abundant in jarosite, sites most likely to have sheltered ancient Martian life.

Techniques and Methods↗
USGS1979

Hydrologic data from urban watersheds in the Tampa Bay area, Florida

Hydrologic data are being collected in 10 urbanized watersheds located in the Tampa Bay area, Florida. The gaged watersheds have impervious areas that range from 19 percent for a residential watershed in north Tampa to nearly 100 percent for a downtown Tampa watershed. Land-use types, including roads, residential, commercial, industrial, institutional, recreational , and open space, have been determined for each watershed. Rainfall and storm runoff data collected since 1971 for one site and since 1975 for six other sites through September 1976, have been processed. These data are recorded at 5-minute intervals and are stored in the U. S. Geological Survey WATSTORE unit values file. Daily rainfall at 12 sites and daily pan evaporation at one site have been stored in the WATSTORE daily values file. Chemical and biological analyses of storm runoff for six sites, base flow for seven sites, and analyses of bottom material for seven sites are also stored in the WATSTORE water-quality files. Rainfall and storm runoff for selected storms, daily rainfall, and daily pan-evaporation data are summarized in this report. Water-quality analyses of all water-quality samples also are listed. (Woodard-USGS).

Florida↗
USGS1986

Theoretical technique for predicting the cumulative impact of iron and manganese oxidation in streams receiving discharge from coal mines

Two U.S. Geological Survey computer programs are modified and linked to predict the cumulative impact of iron and manganese oxidation in coal-mine discharge water on the dissolved chemical quality of a receiving stream. The coupled programs calculate the changes in dissolved iron, dissolved manganese, and dissolved oxygen concentrations; alkalinity; and, pH of surface water downstream from the point of discharge. First, the one-dimensional, stead-state stream, water quality program uses a dissolved oxygen model to calculate the changes in concentration of elements as a function of the chemical reaction rates and time-of-travel. Second, a program (PHREEQE) combining pH, reduction-oxidation potential, and equilibrium equations uses an aqueous-ion association model to determine the saturation indices and to calculate pH; it then mixes the discharge with a receiving stream. The kinetic processes of the first program dominate the system, whereas the equilibrium thermodynamics of the second define the limits of the reactions. A comprehensive test of the technique was not possible because a complete set of data was unavailable. However, the cumulative impact of representative discharges from several coal mines on stream quality in a small watershed in southwestern Indiana was simulated to illustrate the operation of the technique and to determine its sensitivity to changes in physical, chemical, and kinetic parameters. Mine discharges averaged 2 cu ft/sec, with a pH of 6.0, and concentrations of 7.0 mg/L dissolved iron, 4.0 mg/L dissolved manganese, and 8.08 mg/L dissolved oxygen. The receiving stream discharge was 2 cu ft/sec, with a pH of 7.0, and concentrations of 0.1 mg/L dissolved iron, 0.1 mg/L dissolved manganese, and 8.70 mg/L dissolved oxygen. Results of the simulations indicated the following cumulative impact on the receiving stream from five discharges as compared with the effect from one discharge: 0.30 unit decrease in pH, 1.82 mg/L increase in dissolved iron, 1.50 mg/L increase in dissolved manganese, and 0.24 mg/L decrease in dissolved oxygen concentration.

Water-Resources Investigations Report↗
USGS1949

Ground-water supplies of the Ypsilanti area, Michigan

As of the date of this report (August 1945), the major water users in the Ypsilanti area are: (1) the city of Ypsilanti, (2) the Willow Run bomber plant, built by the Federal Government and operated by the Ford Motor Co., and (3) the war housing project of the Federal Public Housing Authority, designated in this report the Willow Run Townsite. The city, bomber plant, and townsite have required large quantities of water for domestic and industrial uses, and the necessary water supplies have been developed from wells. The Federal Works Agency had the responsibility of deciding whether the existing water facilities were adequate to meet the expected demands and determining the character of any additional public water-supply facilities that might be constructed with Federal assistance. In order to appraise the ground-water resources of the area the Federal Works Agency requested the Geological Survey to investigate the adequacy of the existing supplies and the availability of additional water. The present report is the result of the investigation, which was made in cooperation with the Michigan Geological Survey Division. The water supplies of the three major users are obtained from wells penetrating glacial and associated sands and gravels. Supplies for the city of Ypsilanti and the Willow Run bomber plant are obtained from wells in the valley of the Huron River; the supply for the Willow Run Townsite is obtained from wells penetrating glacial gravels underlying the upland northeast of the valley. The bedrock formations of the area either yield little water to wells or yield water that is too highly mineralized for most uses. The water supply for the bomber plant is obtained from three closely spaced, highly productive wells at the northern edge of the Huron River, a little more than 3 miles southeast of Ypsilanti. The water receives complete treatment in a modern treatment plant. River water also can be treated and has been used occasionally in the winter and spring. The average daily pumpage during periods of maximum production at the bomber plant has been 4.5 to 4.75 million gallons. On June 30, 1945, production of bombers was suspended, and the plant went on a. maintenance basis. The water supply of the bomber-plant well field is replenished by recharge from precipitation and from the Huron River. The evidence shows that recharge from the river is one of the principal sources of water and gives assurance both of the adequacy of the present supply and of the availability of additional water if needed. The safe yield of the three existing wells is estimated to be not less than 6 million gallons per day. The Ypsilanti public water supply is obtained from three tubular wells drilled in 1943, which replaced a number of suction-pumped tubular wells and one large dug well. All the wells penetrate sand and gravel in the bend of the Huron River in the southeastern part of Ypsilanti. The water is treated in a modern treatment plant completed in 1939. The average daily pumpage in million gallons was about 1.68 in 1942, 1.70 in 1943, and 1.66 in 1944. Considerable water was furnished to the Willow Run bomber plant from the Ypsilanti public-supply system during the period from August 1941 through March 1943. The available information indicates that the water pumped from the Ypsilanti well field is replenished by ground-water flow from adjacent stretches of the Huron Valley and from the upland areas outside the valley, from precipitation on the valley in the vicinity of the well field, and possibly from the Huron River. It is believed that sufficient water can be obtained from the well field to meet the expected demand for a considerable time. The safe yield of the present wells is estimated to be not less than 3 million gallons per day, and detailed pumping tests might show that still larger supplies could be safely developed. The water supply of the Willow Run Townsite is obtained from four wells in two well fields about 2 miles apart, one well in the northwest or Prospect and Geddes Road field, and three wells in the southeast or Wiard Road field. The pumpage was originally expected to be 2 to 3 million gallons per day, but it averaged only about 450,000 gallons per day from March 1943 through June 1945. The evidence afforded by logs of wells and by pumping tests indicates that the water-bearing gravels at the townsite are covered by relatively impermeable materials and thus that the rate of recharge is low. However, only relatively small declines in water level have occurred during more than 2 years' operation of the wells, indicating that recharge may occur nearby. The safe yield of the present wells is estimated to be 1.0 to 1.5 million gallons per day, and detailed pumping tests might show it to be somewhat greater. The water supply of the Willow Run Townsite has the smallest potential capacity of the three major ground-water supplies in the area; however, the demand has been relatively small, and no difficulty should arise unless this demand increases greatly. The investigation involved the drilling of 13 test wells to locate additional ground-water supplies, on the assumption that the wartime demand for water in the Ypsilanti area might increase beyond the capacity of the present sources. All 13 wells were drilled at sites selected by the Geological Survey. Two wells on the Willow Run Townsite were drilled by the Federal Public Housing Authority and 11 at other sites by the Federal Works Agency. Records of the wells are given in the report and discussed with respect to the availability of water at the different sites; similarly, the results of the controlled pumping tests made on four of the test wells drilled by the Federal Works Agency are analyzed and discussed with respect to the availability of additional water. The combined results of the test drilling and the pumping tests show that emergency supplies of several million gallons per day can be developed at the sites of the test wells. The best site shown by the test drilling is on the south bank of the Huron River opposite the bomber-plant well field, where a Well with a capacity of several thousand gallons per minute could be constructed if necessary. Three wells in the outwash-filled valley now occupied by Fleming Creek, on two of which pumping tests were made, show that emergency supplies ranging from a few hundred thousand to a million gallons per day could be developed at these test-well sites if necessary. Smaller Supplies ranging from a gallon or two per minute to perhaps 100,000 or 200,000 gallons per day could be developed at the sites of the remaining test Wells. Pumping tests made on the supply wells of the three major water users by the consulting-engineering firms who designed the systems are analyzed and discussed briefly by the authors. The report includes maps and graphs showing the surficial geology of the area, the location of wells, and fluctuations of water level in selected wells. Alsp included are tables giving data on water levels and pumpage, chemical analyses of representative ground waters, and records of wells.

Michigan↗
USGS1985

THEORETICAL TECHNIQUE FOR DETERMINING THE CUMULATIVE IMPACT OF IRON AND MANGANESE OXIDATION IN STREAMS RECEIVING COAL-MINE DISCHARGE.

Two U. S. Geological Survey computer programs are modified and linked to predict the cumulative impact of iron and manganese oxidation in coal-mine discharge on the dissolved-chemical quality of a receiving stream. The coupled programs calculate the changes in dissolved-iron, dissolved-manganese, and dissolved-oxygen concentrations, and the pH of surface water downstream from the discharge. The cumulative impact of representative discharges from several coal mines on stream quality in a small watershed in southwestern Indiana was simulated to determine the effectiveness and sensitivity of the coupled programs.

Conference Paper↗
USGS1978

Models for calculating density and vapor pressure of geothermal brines

In a model for estimating density of a brine, the density of a natural brine at a known temperature, pressure, and composition can be calculated from the densities of the component salt solutions in the complex brine. A model for estimating vapor pressure requires two direct or indirect estimates of the vapor pressure and uses a published "reference-substance principle" to extrapolate,; these data 200° to 300° above the temperature of the highest observation. The methods can be used to estimate the partial molal volume and partial molal enthalpy of H 2 O in the natural brine and the partial molal volume change and partial molal heat change for the H2O component in the vaporization process. The equations for density and vapor pressure and the derived thermochemical properties will help in designing turbines for operation with geothermal and geopressured brines, in optimizing production conditions, and in physical and chemical modeling of a geothermal reservoir.

Journal of Research of the U.S. Geological Survey↗
USGS2006

Effects of urbanization on stream ecosystems in the South Platte River basin, Colorado and Wyoming

This report describes the effects of urbanization on physical, chemical, and biological characteristics of stream ecosystems in 28 basins along an urban land-use gradient in the South Platte River Basin, Colorado and Wyoming, from 2002 through 2003. Study basins were chosen to minimize natural variability among basins due to factors such as geology, elevation, and climate and to maximize coverage of different stages of urban development among basins. Because land use or population density alone often are not a complete measure of urbanization, land use, land cover, infrastructure, and socioeconomic variables were integrated in a multimetric urban intensity index to represent the degree of urban development in each study basin. Physical characteristics studied included stream hydrology, stream temperature, and habitat; chemical characteristics studied included nutrients, pesticides, suspended sediment, sulfate, chloride, and fecal bacteria concentrations; and biological characteristics studied included algae, fish, and invertebrate communities. Semipermeable membrane devices (SPMDs), passive samplers that concentrate trace levels of hydrophobic organic contaminants like polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), also were used. The objectives of the study were to (1) examine physical, chemical, and biological responses along the gradient of urbanization; (2) determine the major physical, chemical, and landscape variables affecting the structure of aquatic communities; and (3) evaluate the relevance of the results to the management of water resources in the South Platte River Basin. Commonly observed effects of urbanization on instream physical, chemical, and biological characteristics, such as increased flashiness, higher magnitude and more frequent peak flows, increased concentrations of chemicals, and changes in aquatic community structure, generally were not observed in this study. None of the hydrologic, temperature, habitat, or chemical variables were correlated strongly (Spearman's rho greater than or equal to 0.7) with urban intensity, with the exception of some of the SPMD-based toxicity and chemical variables. SPMD-based measures of potential toxicity and PAH concentrations were positively correlated with urban intensity. The PAH concentrations also were positively correlated with measures of road density and negatively correlated with distance to the nearest road, indicating that automobile exhaust is a major source of these compounds in the study area. This source may be localized enough that the transport of PAHs would be minimally affected by water-management practices such as diversion or storage upstream. In contrast, the predominant sources of nutrients, bacteria, suspended sediment, sulfate, chloride, and pesticides may be more dispersed throughout the drainage area and, therefore, their transport to downstream sites may be subject to greater disruption by water regulation. Although no direct link was found between most water-chemistry characteristics and urbanization, invertebrate, algae, and fish-community characteristics were strongly associated with nutrients, pesticides, sulfate, chloride, and suspended sediment. None of the biological community variables were strongly correlated with the urban intensity index. Algal biomass predominantly was associated with total nitrogen concentrations, nitrite-plus-nitrate concentrations, and the duration of high flows. Fish communities predominantly were associated with housing age, the percentage of suspended sediment finer than 0.063 millimeters and chloride concentrations. Invertebrate communities predominantly were associated with the frequency of rising and falling flow events, the duration of high flows, total nitrogen concentrations, nitrite-plus-nitrate concentrations, and total herbicide concentrations. Historical records indicate that aquatic communities in the region may have been altered prior to any substantial urban development by early agricultural and water-management practices. Present-day aquatic communities are composed primarily of tolerant species even in areas of minimal urban development; when development does occur, the communities already may be resistant to disturbance. In addition to the effects of historical stressors on aquatic community structure, it is possible that current water-management practices in the study basins are having an effect. In the absence of natural, unaltered hydrologic conditions, more sensitive taxa may be unable to recolonize urban streams. The movement and storage of water also may lead to a disconnect between the land surface and streams, resulting in instream physical, chemical, and biological characteristics that, to some degree, are independent of land-cover characteristics.

Colorado, Wyoming↗
USGS2017

Water quality, sources of nitrate, and chemical loadings in the Geronimo Creek and Plum Creek watersheds, south-central Texas, April 2015–March 2016

Located in south-central Texas, the Geronimo Creek and Plum Creek watersheds have long been characterized by elevated nitrate concentrations. From April 2015 through March 2016, an assessment was done by the U.S. Geological Survey, in cooperation with the Guadalupe-Blanco River Authority and the Texas State Soil and Water Conservation Board, to characterize nitrate concentrations and to document possible sources of elevated nitrate in these two watersheds. Water-quality samples were collected from stream, spring, and groundwater sites distributed across the two watersheds, along with precipitation samples and wastewater treatment plant (WWTP) effluent samples from the Plum Creek watershed, to characterize endmember concentrations and isotopic compositions from April 2015 through March 2016. Stream, spring, and groundwater samples from both watersheds were collected during four synoptic sampling events to characterize spatial and temporal variations in water quality and chemical loadings. Water-quality and -quantity data from the WWTPs and stream discharge data also were considered. Samples were analyzed for major ions, selected trace elements, nutrients, and stable isotopes of water and nitrate. The dominant land use in both watersheds is agriculture (cultivated crops, rangeland, and grassland and pasture). The upper part of the Plum Creek watershed is more highly urbanized and has five major WWTPs; numerous smaller permitted wastewater outfalls are concentrated in the upper and central parts of the Plum Creek watershed. The Geronimo Creek watershed, in contrast, has no WWTPs upstream from or near the sampling sites. Results indicate that water quality in the Geronimo Creek watershed, which was evaluated only during base-flow conditions, is dominated by groundwater, which discharges to the stream by numerous springs at various locations. Nitrate isotope values for most Geronimo Creek samples were similar, which indicates that they likely have a common source (or sources) of nitrate. Nitrate sources in the Geronimo Creek watershed include a predominance of nitrate from fertilizer applications, as well as a contribution from septic systems. Additional nitrate loading from these sources is ongoing. Chemical loadings of dissolved solids, chloride, and sulfate varied little among sampling events and were low at most sites because of low streamflow. In contrast to the Geronimo Creek watershed, nitrate sources in the Plum Creek watershed are dominated by effluent discharge from the major WWTPs in the upper and central parts of the watershed. Results indicate that discharge from these WWTPs accounts for the majority of base flow in the watershed. Nitrate concentrations in Plum Creek were dependent on flow conditions, with the highest concentrations measured at lower flows, when flow is dominated by WWTP effluent discharge. In addition to WWTP effluent discharge, the Plum Creek watershed, similar to the Geronimo Creek watershed, also is affected by historical and current loading of nitrate from fertilizer applications and from septic systems in the watershed. Chemical loadings of dissolved solids, chloride, sulfate, and nitrate in Plum Creek at lower flow conditions are highest at the upstream sites and decrease downstream as distance from the WWTPs increases, which is consistent with WWTP effluent as an important control on water quality. Under higher flow conditions, however, nitrate loads to Plum Creek increased by about a factor of three. These higher nitrate loads cannot be accounted for by WWTP effluent discharge from the five major WWTPs in the watershed. This additional loading indicates that nitrate is exported from the northeastern part of the watershed. In the lower part of the Plum Creek watershed, higher concentrations of dissolved solids, chloride, and sulfate occur, which might be affected by produced water associated with oil and gas exploration, or mixing with saline groundwater.

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