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USGS2013

Software for analysis of chemical mixtures--composition, occurrence, distribution, and possible toxicity

The composition, occurrence, distribution, and possible toxicity of chemical mixtures in the environment are research concerns of the U.S. Geological Survey and others. The presence of specific chemical mixtures may serve as indicators of natural phenomena or human-caused events. Chemical mixtures may also have ecological, industrial, geochemical, or toxicological effects. Chemical-mixture occurrences vary by analyte composition and concentration. Four related computer programs have been developed by the National Water-Quality Assessment Program of the U.S. Geological Survey for research of chemical-mixture compositions, occurrences, distributions, and possible toxicities. The compositions and occurrences are identified for the user-supplied data, and therefore the resultant counts are constrained by the user’s choices for the selection of chemicals, reporting limits for the analytical methods, spatial coverage, and time span for the data supplied. The distribution of chemical mixtures may be spatial, temporal, and (or) related to some other variable, such as chemical usage. Possible toxicities optionally are estimated from user-supplied benchmark data. The software for the analysis of chemical mixtures described in this report is designed to work with chemical-analysis data files retrieved from the U.S. Geological Survey National Water Information System but can also be used with appropriately formatted data from other sources. Installation and usage of the mixture software are documented. This mixture software was designed to function with minimal changes on a variety of computer-operating systems. To obtain the software described herein and other U.S. Geological Survey software, visit http://water.usgs.gov/software/.

Scientific Investigations Report↗
USGS2017

An introduction to high-frequency nutrient and biogeochemical monitoring for the Sacramento–San Joaquin Delta, northern California

Executive Summary This report is the first in a series of three reports that provide information about high-frequency (HF) nutrient and biogeochemical monitoring in the Sacramento–San Joaquin Delta of northern California (Delta). This first report provides an introduction to the reasons for and fundamental concepts behind collecting HF measurements, and describes the benefits associated with a real-time, continuous, HF, multi-parameter water quality monitoring station network that is co-located with flow stations. It then provides examples of how HF nutrient measurements have improved our understating of nutrient sources and cycling in aquatic systems worldwide, followed by specific examples from the Delta. These examples describe the ways in which HF instrumentation may be used for both fixed-station and spatial assessments. The overall intent of this document is to describe how HF measurements currently (2017) are being used in the Delta to examine the relationship between nutrient concentrations, nutrient cycling, and aquatic habitat conditions. The second report in the series (Downing and others, 2017) summarizes information about HF nutrient and associated biogeochemical monitoring in the northern Delta. The report synthesizes data available from the nutrient and water quality monitoring network currently operated by the U.S. Geological Survey in this ecologically important region of the Delta. In the report, we present and discuss the available data at various timescales—first, at the monthly, seasonal, and inter-annual timescales; and, second, for comparison, at the tidal and event (for example, storms, reservoir releases, phytoplankton blooms) timescales. As expected, we determined that there is substantial variability in nitrate concentrations at short timescales within hours, but also significant variability at longer timescales such as months or years. This multi-scale, high variability affects calculation of fluxes and loads, indicating that HF monitoring is necessary for understanding and assessing flux-based processes and outcomes in tidal environments, such as the Delta. The third report in the series (Bergamaschi and others, 2017) provides information about how to design HF nutrient and biogeochemical monitoring for assessment of nutrient inputs and dynamics in the Delta. The report provides background, principles, and considerations for designing an HF nutrient-monitoring network for the Sacramento–San Joaquin Delta to address high-priority, nutrient-management questions. The report starts with high-priority management questions to be addressed, continues with questions and considerations that place demands and constraints on network design, discusses the principles applicable to network design, and concludes with the presentation of three example nutrient‑monitoring network designs for the Delta. For the three example networks, we assess how they would address high-priority questions identified by the Delta Regional Monitoring Program (Delta Regional Monitoring Program Technical Advisory Committee, 2015).

California↗
USGS2021

The use of continuous water-quality time-series data to compute total phosphorus loadings for the Turkey River at Garber, Iowa, 2018–20

In support of nutrient reduction efforts, total phosphorus loads and yields were computed for the Turkey River at Garber, Iowa (U.S. Geological Survey station 05412500), for January 1, 2018, to April 30, 2020, based on continuously monitored turbidity sensor data. Sample data were used to create a total phosphorus turbidity-surrogate model. Streamflow-based total phosphorus models were used during periods of missing sensor data to obtain a more complete annual total phosphorus load. This report presents methods needed to accurately compute site-specific loads and track annual progress toward nutrient reduction goals within the State. Annual total phosphorus loads for the Turkey River at Garber, Iowa, were 1,740 and 1,490 U.S. short tons for 2018 and 2019, respectively, with annual yields ranging from 3.01 to 3.53 pounds per acre per year, compared to a mean statewide yield of 0.73 pound per acre per year needed to achieve the total phosphorus-reduction goal.

Iowa↗
USGS1984

Trace metals in Suisun Bay, California: A preliminary report

A 5-month partial study (February to July 1983) was completed in Suisun Bay, a shallow embayment of San Francisco Bay, Calif., to determine characteristic heavy metal concentrations present in sediments and organisms (Corbicula clams) prior to possible discharge of San Luis Drain irrigation tile return water. Preliminary results show sediments are typical of other San Francisco Bay study sites, ranging from coarse sands to fine silt-clays. The sediments are enriched in manganese and low in organic carbon; iron is moderately enriched, with acid-extractable iron concentrations of 162-3,521 micro-g/g. Sediment concentrations of silver, zinc, lead, and cadmium measured between April and July are reported. Previous area studies have shown increased concentrations during autumn and winter, a period not covered in the data set. Due to insufficient data, interpretations are incomplete. Clam-tissue burdens for silver and zinc are similar to those found in Corbicula from pristine areas. Lead concentrations are typically below the 2-micrograms/g detection level. Corbicula do show indications of more tissue enrichment for cadmium and copper at estuarine stations than at riverine stations.

California↗
USGS1988

Simulation of the regional geohydrology of the Tesuque aquifer system near Santa Fe, New Mexico

Declining groundwater levels resulting from groundwater withdrawals in the Santa Fe, New Mexico, area have caused concern about the future availability of water in the Tesuque aquifer system. This report describes the geohydrology of the Tesuque aquifer system in the Santa Fe area and presents a three-dimensional regional groundwater flow model which assesses the effects of existing and possible future groundwater withdrawals on the regional aquifer system. The model was calibrated using simulations of the predevelopment steady-state condition and the 1947-82 historical period. The response of the aquifer to two scenarios of future groundwater withdrawals from 1983 to 2020 was simulated. (USGS)

Water-Resources Investigations Report↗
USGS1985

Discharge and water quality of springs in Roan and Parachute Creek basins, northwestern Colorado, 1981-83

This report is a compilation and interpretation of discharge, water-quality, and radiochemical data collected at springs in the oil-shale regions of Roan and Parachute Creek basins, Colorado, from 1981 to 1983. Springs located on upland plateaus and ridges are mixed-cation bicarbonate water types with 216 to 713 milligrams per liter dissolved solids. Calcite and dolomite dissolution are dominant chemical reactions in upland springs. Springs located in the canyons contain greater concentrations of sodium and sulfate and have 388 to 3,970 milligrams per liter dissolved solids. Gypsum dissolution is an important chemical reaction in canyon spring water. The only trace constituents with mean concentration greater than 10 micrograms per liter in the study area were barium, boron, lithium and strontium. None of the canyon springs investigated represent discharge from the lower aquifer in the Green River Formation. Analysis of chemical and discharge data for streams in the Roan Creek drainage showed evidence of lower-aquifer discharge into the canyons. Springs located near an oil-shale mine or processing plant could be used for monitoring groundwater quality and quantity. Bicarbonate, fluoride, arsenic, boron, lithium, mercury, ammonia, and organic carbon may be chemical indicators of mine or process-water contamination of shallow aquifers near an oil-shale plant or mine.

Colorado↗
USGS2022

Depth to water and water quality in groundwater wells in the Ogallala aquifer within the North Plains Groundwater Conservation District, Texas Panhandle, 2019–20, and comparison to 2012–13 conditions

The Ogallala aquifer is the primary source of water for agricultural and municipal purposes in the Texas Panhandle. Because most of the groundwater in the Texas Panhandle is withdrawn from the Ogallala aquifer, information on the quality of groundwater in the Ogallala aquifer in this part of Texas is useful for resource characterization. During 2012–13, the U.S. Geological Survey in cooperation with the North Plains Groundwater Conservation District (NPGCD), collected and analyzed water-quality samples from 30 groundwater monitoring wells in the Texas Panhandle. The results of the initial 2012–13 synoptic sampling were published in 2014 to help provide an initial characterization of the spatial and temporal variability of water quality in the NPGCD management area. This report documents the results of a followup synoptic sampling completed between March 2019 and July 2020 by the U.S. Geological Survey, in cooperation with the NPGCD, to further characterize the spatial and temporal characteristics of groundwater in the NPGCD management area; measurements of the depth to water, in feet below land surface, and water-quality samples were obtained from the same 30 monitoring wells that were sampled during 2012–13. The water-quality samples were analyzed for major ions, nutrients, trace elements, and selected organic compounds. Results from the 2019–20 synoptic sampling were compared to drinking-water standards and to the results from the 2012–13 synoptic sampling. Between the 2012–13 and 2019–20 sampling periods, the depth to water increased in 28 of the 30 wells, with a median difference of 18.17 feet. Results from major ion analyses indicate that most of the groundwater samples collected during 2019–20 were classified as magnesium-bicarbonate type, the same water type indicated for most samples during 2012–13. Dissolved-solids concentrations for the wells sampled during 2019–20 ranged from 260 to 774 milligrams per liter (mg/L) with a median dissolved-solids concentration of 316 mg/L, which was slightly higher than the median dissolved-solids concentration of 311 mg/L for the 2012–13 sampling period. Of the four nutrients analyzed, nitrate was the dominant nitrogen species, with a median nitrate concentration of 2.25 mg/L for the 2019–20 sampling period, which was a slight increase relative to the median nitrate concentration of 2.05 mg/L for the 2012–13 sampling period. Accounting for variability in analyses, median major ion concentrations and median concentrations for nutrient species were similar during the 2012–13 and 2019–20 sampling periods. None of the trace element concentrations exceeded any maximum contaminant level or secondary drinking-water standards. Median concentrations of trace elements from the 2012–13 sampling period were compared to those from the 2019–20 sampling period for constituents in cases where at least 50 percent of concentrations measured in the samples were detected at concentrations greater than the highest applicable laboratory reporting level, and variability in analyses was accounted for. Comparison results indicated that that median concentrations of two trace elements (lithium and uranium) increased, whereas median concentrations for two of the other trace elements measured (barium and molybdenum) decreased. Atrazine and deethylatrazine were the only organic compounds detected; both were detected in four of the six samples collected from different wells and analyzed for organic compounds. Concentrations of atrazine and deethylatrazine detections were all less than 0.05 micrograms per liter.

Texas↗
USGS2023

Analysis of high-resolution single channel seismic data for use in sediment resource evaluation, eastern Texas and western Louisiana Continental Shelf, Gulf of Mexico

Shallow subsurface geologic data recorded as high-resolution seismic profiles are used to interpret the geology of coastal and marine systems. These data were originally recorded on paper rolls that are stored in geophysical archives. Data collection has since converted to entirely digital formats, yet the analog data are still useful for geologic interpretation. This report describes the process of recovering analog copies of seismic profiles from physical archives, electronically scanning, and converting them to industry-standard digital format. The recovered data are also reviewed and assessed for potential sediment resources. The data recovered in this study were collected from the Gulf of Mexico continental shelf offshore of East Texas and West Louisiana. The project is a collaborative study between the U.S. Geological Survey and the Bureau of Ocean Energy Management.

Louisiana, Texas↗
USGS2025

Characterization of suspended sediment flux and streamflow trends in the Fountain Creek watershed, Colorado, 1998 through 2022

The U.S. Geological Survey evaluated long-term suspended sediment flux and streamflow datasets for temporal trends (monotonic and step trends) at 10 streamgage sites within the Fountain Creek watershed in central Colorado using the Mann-Kendall test (monotonic trend) and the Wilcoxon signed-rank test (step trend). Data were collected in cooperation with Colorado Springs Stormwater Enterprise. In this study, 10 sites with long-term suspended sediment records were evaluated during their operational periods, which ranged from 1998 through 2022. To assess how stream behavior might relate to shifts in suspended sediment transport, the Richards-Baker flashiness index, a measure of flashiness, was evaluated for each site. The Richards-Baker flashiness index was calculated for the same months as streamflow and suspended sediment (April through September) using all available streamflow data for a given site. Additionally, cumulative double-mass curves were developed to define temporal variation in the relation between streamflow and suspended sediment loads. This was completed by assessing differences in slopes before and after an observed break in the double-mass curve plots. Five streamgage sites showed statistically significant ( p <0.05) negative trends for suspended sediment flux, and nonsignificant decreases were indicated at the other five sites. The statistically significant negative trends are distributed across the watershed and include smaller tributaries and the main stem of Fountain Creek closer to its confluence with the Arkansas River. Such a broad distribution of negative trends is most likely an indication of improved water quality in the watershed with regards to suspended sediment. Assessing causes for the decreases in suspended sediment loads is beyond the scope of this report; however, spatially distributed bank erosion control projects, stormflow retention projects in the watershed, and changes in climate and storm patterns could be some of the potential drivers of the suspended sediment load trends in this watershed. The flashiness of the streamflow was assessed and can be dismissed on the basis of this study as a potential driver of trends in suspended sediment flux because the magnitude of changes was found to be negligible at all sites.

Colorado↗
USGS2003

Estimated flood-inundation maps for Cowskin Creek in western Wichita, Kansas

The October 31, 1998, flood on Cowskin Creek in western Wichita, Kansas, caused millions of dollars in damages. Emergency management personnel and flood mitigation teams had difficulty in efficiently identifying areas affected by the flooding, and no warning was given to residents because flood-inundation information was not available. To provide detailed information about future flooding on Cowskin Creek, high-resolution estimated flood-inundation maps were developed using geographic information system technology and advanced hydraulic analysis. Two-foot-interval land-surface elevation data from a 1996 flood insurance study were used to create a three-dimensional topographic representation of the study area for hydraulic analysis. The data computed from the hydraulic analyses were converted into geographic information system format with software from the U.S. Army Corps of Engineers' Hydrologic Engineering Center. The results were overlaid on the three-dimensional topographic representation of the study area to produce maps of estimated flood-inundation areas and estimated depths of water in the inundated areas for 1-foot increments on the basis of stream stage at an index streamflow-gaging station. A Web site (http://ks.water.usgs.gov/Kansas/cowskin.floodwatch) was developed to provide the public with information pertaining to flooding in the study area. The Web site shows graphs of the real-time streamflow data for U.S. Geological Survey gaging stations in the area and monitors the National Weather Service Arkansas-Red Basin River Forecast Center for Cowskin Creek flood-forecast information. When a flood is forecast for the Cowskin Creek Basin, an estimated flood-inundation map is displayed for the stream stage closest to the National Weather Service's forecasted peak stage. Users of the Web site are able to view the estimated flood-inundation maps for selected stages at any time and to access information about this report and about flooding in general. Flood recovery teams also have the ability to view the estimated flood-inundation map pertaining to the most recent flood. The availability of these maps and the ability to monitor the real-time stream stage through the U.S. Geological Survey Web site provide emergency management personnel and residents with information that is critical for evacuation and rescue efforts in the event of a flood as well as for post-flood recovery efforts.

Water-Resources Investigations Report↗
USGS2003

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Evaluation of alkaline persulfate digestion as an alternative to Kjeldahl digestion for determination of total and dissolved nitrogen and phosphorus in water

Alkaline persulfate digestion was evaluated and validated as a more sensitive, accurate, and less toxic alternative to Kjeldahl digestion for routine determination of nitrogen and phosphorus in surface- and ground-water samples in a large-scale and geographically diverse study conducted by U.S. Geological Survey (USGS) between October 1, 2001, and September 30, 2002. Data for this study were obtained from about 2,100 surface- and ground-water samples that were analyzed for Kjeldahl nitrogen and Kjeldahl phosphorus in the course of routine operations at the USGS National Water Quality Laboratory (NWQL). These samples were analyzed independently for total nitrogen and total phosphorus using an alkaline persulfate digestion method developed by the NWQL Methods Research and Development Program. About half of these samples were collected during nominally high-flow (April-June) conditions and the other half were collected during nominally low-flow (August-September) conditions. The number of filtered and whole-water samples analyzed from each flow regime was about equal.By operational definition, Kjeldahl nitrogen (ammonium + organic nitrogen) and alkaline persulfate digestion total nitrogen (ammonium + nitrite + nitrate + organic nitrogen) are not equivalent. It was necessary, therefore, to reconcile this operational difference by subtracting nitrate + nitrite concentra-tions from alkaline persulfate dissolved and total nitrogen concentrations prior to graphical and statistical comparisons with dissolved and total Kjeldahl nitrogen concentrations. On the basis of two-population paired t-test statistics, the means of all nitrate-corrected alkaline persulfate nitrogen and Kjeldahl nitrogen concentrations (2,066 paired results) were significantly different from zero at the p = 0.05 level. Statistically, the means of Kjeldahl nitrogen concentrations were greater than those of nitrate-corrected alkaline persulfate nitrogen concentrations. Experimental evidence strongly suggests, however, that this apparent low bias resulted from nitrate interference in the Kjeldahl digestion method rather than low nitrogen recovery by the alkaline persulfate digestion method. Typically, differences between means of Kjeldahl nitrogen and nitrate-corrected alkaline persulfate nitrogen in low-nitrate concentration (< 0.1 milligram nitrate nitrogen per liter) subsets of filtered surface- and ground-water samples were statistically equivalent to zero at the p =level.Paired analytical results for dissolved and total phosphorus in Kjeldahl and alkaline persulfate digests were directly comparable because both digestion methods convert all forms of phosphorus in water samples to orthophosphate. On the basis of two-population paired t-test statistics, the means of all Kjeldahl phosphorus and alkaline persulfate phosphorus concentrations (2,093 paired results) were not significantly different from zero at the p = 0.05 level. For some subsets of these data, which were grouped according to water type and flow conditions at the time of sample collection, differences between means of Kjeldahl phosphorus and alkaline persulfate phosphorus concentrations were not equivalent to zero at the p = 0.05 level. Differences between means of these subsets, however, were less than the method detection limit for phosphorus (0.007 milligram phosphorus per liter) by the alkaline persulfate digestion method, and were therefore analytically insignificant.This report provides details of the alkaline persulfate digestion procedure, interference studies, recovery of various nitrogen- and phosphorus-containing compounds, and other analytical figures of merit. The automated air-segmented continuous flow methods developed to determine nitrate and orthophosphate in the alkaline persulfate digests also are described. About 125 microliters of digested sample are required to determine nitrogen and phosphorus in parallel at a rate of about 100 samples per hour with less than 1-percent sample in

Water-Resources Investigations Report↗
USGS1973

Index to water-quality data available from the U.S. Geological Survey in machine-readable form to December 31, 1972; Northeastern region

This report lists water quality stations operated by the U.S. Geological Survey for which data are available in machine-readable form. The data are the results of analyses of water samples and indicate the chemical and physical characteristics of surface and ground water. Samples of surface water were collected at designated sites at predetermined intervals such as once daily, weekly, monthly, or less frequently. Samples of ground water were collected from wells infrequently and on an irregular basis.

Water-Resources Investigations Report↗
USGS1976

Availability of ground water in the Middle Connecticut River basin, west-central New Hampshire

This report provides a guide for ground-water exploration and for water- and land-use planning and management. Sufficient amounts of water to supply single family homes are available from the bedrock aquifer nearly everywhere in the middle Connecticut River basin. Relatively thin and narrow, unconsolidated aquifers of sand or sand and gravel commonly capable of yielding more than 200 gallons per minute (12.6 litres per second) to properly located and constructed wells are found only in major stream valley.

New Hampshire↗
USGS1976

Availability of ground water in the middle Merrimack River basin, central and southern New Hampshire

This report provides a guide for ground-water exploration and for water- and land-use planning and management. Sufficient amounts of water to supply single family homes are available from the bedrock aquifer nearly everywhere in the middle Merrimack River basin. Relatively thin and narrow, unconsolidated aquifers of sand or sand and gravel commonly capable of yielding more than 200 gallons per minute (12.6 litres per second) to properly located and constructed wells are found only in major stream valleys.

New Hampshire↗
USGS1984

Relationship of suspended sediment to streamflow in the Green River Basin, Wyoming

The relation of suspended-sediment concentration to water discharge was computed using regression analysis for 33 stations and 2 miscellaneous sites in the Green River basin, Wyoming. These relations show that suspended-sediment concentrations vary in direct proportion to streamflow. The number of coincident instantaneous suspended-sediment concentration and water-discharge values available for each regression analysis ranged from 6 to 98. Standard error of estimates for 35 relationships were usually large and correlation were relatively small. Large standard errors and small correlations are expected because of the complexity of the fluvial system. The effects of other factors, such as geology, topography, climate, soils, vegetation, and land use were not evaluated. Daily suspended-sediment discharges for four stations were computed by the ' sediment-transport-curve ' method described in this report , and compared with values computed by the traditional ' temporal-concentration-graph ' method. Annual sediment yields in tons per square mile drainage area, were compared in like manner. For those stations examined, values computed by the ' sediment-transport-curve ' method were within 58 percent of those computed by the temporal-concentration-graph ' method when only one year of record was used, but were within 12 to 21 percent when 2 to 4 years of record were averaged. (USGS)

Water-Resources Investigations Report↗
USGS1984

Cost-effectiveness of the stream-gaging program in New Jersey

The results of a study of the cost-effectiveness of the stream-gaging program in New Jersey are documented. This study is part of a 5-year nationwide analysis undertaken by the U.S. Geological Survey to define and document the most cost-effective means of furnishing streamflow information. This report identifies the principal uses of the data and relates those uses to funding sources, applies, at selected stations, alternative less costly methods (that is flow routing, regression analysis) for furnishing the data, and defines a strategy for operating the program which minimizes uncertainty in the streamflow data for specific operating budgets. Uncertainty in streamflow data is primarily a function of the percentage of missing record and the frequency of discharge measurements. In this report, 101 continuous stream gages and 73 crest-stage or stage-only gages are analyzed. A minimum budget of $548,000 is required to operate the present stream-gaging program in New Jersey with an average standard error of 27.6 percent. The maximum budget analyzed was $650,000, which resulted in an average standard error of 17.8 percent. The 1983 budget of $569,000 resulted in a standard error of 24.9 percent under present operating policy. (USGS)

Water-Resources Investigations Report↗
USGS1994

Surface-water-quality assessment of the Kentucky River Basin, Kentucky: Fixed-station network and selected water-quality data, April 1987 through August 1991

This report describes selected data-collection activities and the associated data collected during the Kentucky River Basin pilot study of the U.S. Geological Survey's National Water-Quality Assessment Program. The data are intended to provide a nationally consistent description and improved understanding of current water quality in the basin. The data were collected at seven fixed stations that represent stream cross sections where constituent transport and water-quality trends can be evaluated. The report includes descriptions of (1) the basin; (2) the design of the fixed-station network; (3) the fixed-station sites; (4) the physical and chemical measurements; (5) the methods of sample collection, processing, and analysis; and (6) the quality-assurance and quality-control procedures. Water-quality data collected at the fixed stations during routine periodic sampling and supplemental high-flow sampling from April 1987 to August 1991 are presented.

Kentucky↗
USGS1996

Variations in land use and nonpoint-source contamination on the Fort Berthold Indian Reservation, west-central North Dakota, 1990-93

The effects of land-use activities on the water quality of five streams on the Fort Berthold Indian Reservation were evaluated. The five basinsevaluated were East Fork Shell Creek, Deepwater Creek, Bear Den Creek, Moccasin Creek, and Squaw Creek. East Fork Shell Creek and DeepwaterCreek Basins are located east of Lake Sakakawea and Bear Den Creek, Moccasin Creek, and Squaw Creek Basins are located west of the lake. Land-use data for the five selected basins on and adjacent to the Fort Berthold Indian Reservation were obtained for 1990-92. Discharge measurements were made and water-quality samples were collected at stations and sites on each of the five streams during October 1991 through September 1993. Analysis of land-use data indicated that prairie was the largest land-use category in the study area. More prairie acreage was found in the basins located west of Lake Sakakawea than in the basins located east of the lake. Wheat was the predominant crop in the study area. More wheat acreage was found in the basins located east of Lake Sakakawea than in the basins located west of the lake. Discharge data for the five selected streams indicated that all of thestreams were ephemeral and had many days of no flow during the study period. High flows were usually the result of spring runoff or intense storms over the basins. East Fork Shell Creek and Deepwater Creek with larger basins and flatter stream slopes had high flows characterized by rapidly rising flows and gradually receding flows. In contrast, Bear DenCreek, Moccasin Creek, and Squaw Creek with smaller basins and steeper stream slopes had high flows characterized by rapidly rising flows and receding flows of shorter duration. Analysis of water-quality samples indicated concentrations of nitrogen, phosphorus, and total organic carbon varied throughout the study area. Nitrogen concentrations were larger in the streams located east of LakeSakakawea than in the streams located west of the lake. The largest nitrogen concentrations in all of the streams occurred during the nongrowing periods.Phosphorus (orthophosphate and total phosphorus)concentrations were larger in the streams located east of Lake Sakakawea than in the streams located west of the lake. The larger orthophosphateconcentrations in the eastern streams may be indicative of insecticide application in the eastern streams' basins. Total organic carbon concentrations were fairly consistent in all five streams. Water-quality samples were analyzed for the pesticides atrazine, carbofuran, cyanazine, and 2,4-D by using immunoassay testing. Pesticide concentrations above the minimum reporting levels were more prevalent insamples from streams located east of Lake Sakakawea than in the streams located west of the lake. The eastern streams drain areas where herbicides were applied to crops. Fecal-bacteria concentrations were larger in the streams located west of Lake Sakakawea, where prairie is more dominant, than in the streams located east of the lake. The larger concentrations and loads were associated with intense storm events and the presence of livestock.

Water-Resources Investigations Report↗