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Assessment of fresh groundwater discharge and saline surface-water intrusion at Operable Unit 2, North Chevalier Field Disposal Area (Site 11), Naval Air Station Pensacola, Florida, 2018–22

Site 11 is a former landfill at North Chevalier Field Disposal Area in Operable Unit 2 at Naval Air Station Pensacola, in northwest Florida. Site 11 is adjacent to Bayou Grande, a shallow, tidally influenced, saline estuary of the Pensacola Bay watershed. Federal and Florida regulators have expressed concern that contaminants detected in groundwater beneath the inland parts of Site 11 may discharge to Bayou Grande. In 2017, the Department of Defense, U.S. Navy, Naval Facilities Engineering Systems Command Southeast asked the U.S. Geological Survey to assess the occurrence of fresh groundwater discharge to Bayou Grande at Site 11 and to delineate to the extent practicable the location of groundwater discharge. Between 2018 and 2022, the U.S. Geological Survey used a multiple-lines-of-evidence approach that included a visual method and three physical methods based on the temperature difference between groundwater and surface water to assess groundwater discharge. One of the physically based methods also used the difference in specific conductance between fresh groundwater and brackish to saline surface water. Combined, the data indicate that fresh groundwater from across Site 11 discharges primarily along the shoreline of the northern and northeastern part of Site 11. The data also indicate that saline surface water from Bayou Grande intrudes tens of feet into the shallow aquifer beneath Site 11. The combined data indicate that the interface between fresh groundwater and saline surface water changes over space and time. Any new monitoring wells proposed for installation near the shoreline of Site 11 should include approaches to monitor the changes in the location of the freshwater/saltwater interface. Care would need to be taken to collect any groundwater samples at the correct season and tidal period to provide the highest probability of collecting a representative sample of Site 11 groundwater unaffected by saltwater.

Florida

Determination of baseline water-quality conditions using continuous specific conductance and discrete measurements of total dissolved solids and selected major ions, Arkansas River Basin, Colorado

From 2022 through 2024, the U.S. Geological Survey (USGS) in cooperation with the Regional Resources Planning Group (Southeastern Colorado Water Conservancy District, Colorado Springs Utilities, Pueblo Water, Lower Arkansas Valley Water Conservancy District, Aurora Water, and Upper Arkansas Water Conservancy District) established a basinwide water-quality monitoring network in the Arkansas River Basin in Colorado. The study leveraged ongoing continuous measurements of streamflow and specific conductance (SC) at 13 sites along the main stem Arkansas River and Fountain Creek from the USGS 07108600 Arkansas River at Granite, Colo., (Ark Granite) site to the USGS 07137500 Arkansas River near Coolidge, Kansas, (Ark Coolidge) site. Baseline water-quality conditions were established using data from October 1989 through September 2022 to help identify changes in water quality that could result from changes in land and water use. Total dissolved solids (TDS) concentration was the main indicator of general water quality in this study because it can be accurately estimated from SC and is sensitive to changes in streamflow, water operations, and source contributions. Median TDS concentrations in Arkansas River samples (October 1989 through December 2023) ranged from 75 milligrams per liter (mg/L) at Ark Granite near the headwaters to 3,660 mg/L at Ark Coolidge near the Colorado–Kansas State line. Distinct seasonal differences in median streamflow and TDS were apparent during the winter and summer months. Seasonal Kendall tests showed no significant trends in monthly mean streamflow (October 1995 through September 2022) at Arkansas River sites upstream from Pueblo Reservoir. Upward trends in TDS concentrations and loads occurred only at Ark Granite. Downward trends in streamflow, TDS concentrations, and TDS loads occurred at Arkansas River sites from USGS 07109500 Arkansas River near Avondale, Colo., to Ark Coolidge. Downward trends in streamflow and SC (surrogate for TDS) were more prevalent during winter base flow months and may indicate changes in groundwater quantity, and possibly groundwater quality, potentially affecting the river water-quality condition.

Colorado

Comparison of creek and bay influences on salt marsh sediment budget and deposition patterns

The resilience of salt marshes with low organic production depends on their effective capture and retention of mineral sediment from adjacent waters. Little prior work has directly compared mechanisms of sediment import from wave-influenced marsh boundaries against those of tidal creeks. We used simultaneous deployment of net-deposition tiles and oceanographic sensors to identify the timing and magnitude of sediment import/export to, and redistribution within, a marsh in south San Francisco Bay. As the marsh has both an eroding bay-exposed scarp and a prominent tidal creek, we investigated the mechanisms and magnitudes of sediment import from the marsh-bay versus the marsh-creek interface. The strong daily sea breezes of the summer season produced most of the wave-driven erosion of the marsh scarp and controlled suspended sediment concentrations; the winter season had weaker winds punctuated by a few storms. A large seasonal difference in suspended sediment concentrations influenced both flood and ebb sediment fluxes to the marsh and led to much higher rates of import in the summer. Both bay-side and creek-side processes were important to total marsh sediment budget. Bay-side sediment contributions were more variable in time due to the bay-influenced environment, and creek-side contributions were overall larger, reflecting the large proportion of the marsh fed by creek water. Sediment was redistributed throughout the system, with erosion near the bay-edge, accretion near the creek-edge and slow import to the marsh interior. The marsh was net importing sediment in the summer and exporting in the winter from different rates of these processes; on an annual scale, the marsh was net importing despite rapid lateral marsh loss. These findings emphasize that a positive sediment budget does not imply a stable marsh and that both creek- and edge-side dynamics are important for marsh sedimentation and geomorphic trajectories. Further, we expand understandings of non-storm and seasonal controls on marsh sedimentation.

California

Revisiting an enigma on California's north coast: The Mw6.5 Fickle Hill earthquake of 21 December 1954

Many earthquakes occur along the North Coast of California in the vicinity of the Mendocino Triple Junction (MTJ), where the Pacific, Gorda, and North American (NA) plates meet, and on the adjacent plate boundaries. The MTJ marks the nexus of the Mendocino and San Andreas faults with the Cascadia subduction zone (CSZ). Historically, most large earthquakes around the MTJ have been within the offshore Gorda plate and its subducted portion beneath the NA plate. North of the MTJ, active faults mapped in the NA plate are part of the CSZ fold‐and‐thrust belt. Although some events have been detected in the NA plate, no large historic events have been associated with mapped surface faults. The 21 December 1954 M w 6.5 earthquake in Humboldt County is one possible exception. Using published data from catalogs and articles, unpublished data from Berkeley’s archives, and S ‐ P times interpreted from two U.S. Coast and Geodetic Survey (USCGS) accelerometers, we determine a probability cloud for the earthquake’s hypocenter using NonLinLoc. The highest probability location lies beneath Fickle Hill just east of the city of Arcata, California, at 40.87° N, 124.03° W, and ∼11 km depth. Using P ‐wave polarities from Berkeley stations and the digitized waveforms from the accelerometers, we find that the focal mechanism most consistent with the data indicates thrust movement with strike, dip, and rake of 350°, 10°, and 90°, respectively, at a depth of 14 km. Given the depth uncertainties of both this event and the megathrust, this implies that the earthquake most likely took place on the subduction interface rather than on the mapped faults in the Mad River fault zone that trend 322° and dip to the northeast. The revisited intensity in the epicentral region also supports a location beneath Fickle Hill to the east of the city of Arcata, California.

California, Idaho, Nevada, Oregon, Washington

Geomorphic map of the Umatilla River corridor, Oregon

This map portrays the distribution of landforms along the Umatilla River in northeastern Oregon and covers a corridor 127 kilometers long from the confluence of the Umatilla River with the Columbia River upstream to Meacham Creek. The map encompasses the valley bottom and extends about 1 kilometer up the adjoining hillslopes. Map data are intended to support water quality and fisheries enhancement efforts pursuant to the First Foods, a resource-management approach that focuses on traditionally gathered foods including water, fish, big game, roots, and berries and calls attention to the reciprocity between people and the foods upon which humans depend. The Umatilla River drains about 6,300 square kilometers on the northwest slope of the Blue Mountains in northeast Oregon. Most of the drainage basin is underlain by Miocene basalt flows of the Columbia River Basalt Group. Younger, weakly lithified, late Miocene and early Pliocene gravel deposits of local origin (for example, McKay Formation) are mapped in a few places. Upland surfaces are mantled with windborne silt (loess) correlative with deposits elsewhere known as the Palouse Formation. Surfaces below an elevation of about 340 meters were inundated repeatedly by large Pleistocene glacial outburst floods, most emanating from glacial Lake Missoula in western Montana. In backflooded areas such as the lower Umatilla River valley, Missoula floods deposited extensive slack-water silt. Areas mapped as open water, active channel and tie channel, flood basin, valley bottom, and modified land constitute the geomorphic floodplain: the area subject to occasional inundation by the Umatilla River. Deposits and landforms within the floodplain are inset into Missoula flood deposits and hence postdate the 20–15-kilo-annum Missoula floods. Some floodplain deposits are no more than a few centuries old, as indicated by substantial erosion and deposition during the Umatilla River flood of February 2020, the largest since systematic measurements began in October 1903. Deposits and landforms of the floodplain are transient features within the longer-term incision of the Umatilla River into mid-Miocene flood basalts and younger gravel of the McKay Formation.

Oregon

Near-surface material and topography generate anomalous high-frequency ground motion amplification in Chugiak, Alaska

An ∼3 km long nodal array oriented approximately east–west was deployed in Chugiak, Alaska, by the U.S. Geological Survey during 2021. The array intersects with the permanent NetQuakes station NP.ARTY, where peak ground acceleration (PGA) value of 1.98 g was recorded during the 2018 M w 7.1 Anchorage, Alaska, earthquake, in sharp contrast to the PGA of ∼0.3 g at a site just 4 km to the west. Seismic data for M w 1.8–4.3 aftershocks from the M w 7.1 event recorded by the nodal array confirm the anomalously large ground motions obtained at NP.ARTY as well as similar amplifications at nodes within ∼1 km to the east. Here, we performed 0–10 Hz 3D finite‐difference simulations, including high‐resolution surface topography, to explore the cause of the unexpectedly large amplification. As expected, the simulations computed with a regional 3D tomography velocity model severely underpredict the 0–10 Hz acceleration records at almost all sites. Adding a near‐surface low‐velocity taper to 300 m depth amplifies the accelerations by up to a factor of 5 and enables a reasonable match between the nodal data and simulations at sites to the west of NP.ARTY. However, this model still underpredicts the spectral energy in the area covered by glacial sediments by up to an order of magnitude. The addition of a till layer using a depth‐dependent shear‐wave velocity ( ⁠⁠ V s ) profile along with a homogeneous, 8 m thick low‐velocity layer with V s = 250 m/s representing the kame terraces improves the fit to data to within a factor of 2 at nodes located on top of the glacial sediments. Our study shows that the anomalously large high‐frequency amplification recorded at and near NP.ARTY can be explained by a combination of topographic effects and near‐surface low‐velocity material with amplification effects on the high‐frequency ground motion by up to about 40% and an order of magnitude, respectively.

Alaska

Pre-Acadian tectonics of the eastern Orange-Milford Belt, south-central Connecticut

This excursion presents a reinterpretation of mapping and new analytical data from the eastern Orange-Milford belt (OMB) in south-central Connecticut. The OMB is a fault-bound terrane of argillites and mafic rocks of anomalously low metamorphic grade—and of poorly constrained ages and tectonic affinity—wedged between kyanite/sillimanite-grade peri- Laurentian rocks to the west and anatectic peri-Gondwanan rocks to the east (Fig. 1A). Our data demonstrate that Ordovician(?) igneous and sedimentary rocks of the OMB were variably metamorphosed in the Ordovician and Silurian but escaped regionally pervasive, high-grade Devonian and later metamorphism. Previous interpretations (Fritts 1963a, 1965a, 1965b; Burger, 1967; Burger and others, 1968; Rodgers, 1985) described these rocks as a conformable sequence of low-grade, Ordovician to Devonian metasediments and metavolcanics. Our results reveal that the “metavolcanics” are not extrusive rocks but rather slivers of lower oceanic crust with complicated high- and low-grade metamorphic fabrics, intruded by a swarm of Silurian sheeted basalt dikes, and in fault contact with the surrounding metasediments. The purpose of this trip is to show evidence of early Paleozoic (Taconic) deformation and metamorphism preserved in rocks of the eastern OMB. These rocks remained shallow, cool, and sufficiently dry during the regionally dominant Acadian and Alleghanian orogenies to have avoided significant overprinting. As such, these rocks serve as windows into a geologic history otherwise unavailable between anatectic rocks of the peri-Gondwanan Bronson Hill, Avalon, and Gander terranes east of the Hartford basin and sillimanite-grade rocks of the peri-Laurentian Hartland and gneiss dome belts west of the OMB. We present major and trace element geochemistry including rare-earth element patterns for all mafic units in the eastern OMB as well as 40 Ar/ 39 Ar age spectra of amphibole, muscovite, and K-feldspar from rocks of the Maltby Lakes complex (of Deasy and others, 2017), Savin Schist, and Wepawaug Schist. Our evidence demonstrates that the units of the OMB have been assembled by faulting or intrusion, and that no stratigraphic relationships exist between the argillaceous schists and the metaigneous rocks.

Connecticut

Leveraging wildfire to augment forest management and amplify forest resilience

Successive catastrophic wildfire seasons in western North America have escalated the urgency around reducing fire risk to communities and ecosystems. In historically frequent-fire forests, fuel buildup as a result of fire exclusion is contributing to increased fire severity. The probability of high-severity fire can be reduced by active forest management that reduces fuels, prompting federal and state agencies to commit significant resources to increase the pace and scale of fuel reduction treatments. However, lower severity areas of wildfires also have the potential to act as “treatments,” and even catastrophic fires with large areas of high severity can still have substantial areas of lower severity fire that may be improving forest conditions locally. We quantified active management and wildfire severity across yellow pine and mixed conifer (YPMC) forests in the Sierra Nevada of California over a 22-year period (2001–2022). We did not detect increases in the area treated through time, but the area of beneficial wildfire (low to moderate severity) increased substantially, exceeding active treatment area in 8 of 22 years. Overall, beneficial wildfire treated ~17% more area than all treatments combined, and roughly four times more area than fire-related treatments alone. We then used disturbance history to evaluate resistance to high-severity wildfire and forest loss across the YPMC range. Of the 2.3 million ha YPMC of forests in 2001, 20% lost mature forests due to high-severity fire by 2022, which is nearly half of all YPMC area burned. Most of the landscape (47%) remains at risk of high-severity fire because it had no restorative disturbances, but 33% of the study area has some level of resistance to high-severity wildfire. In these areas, resistance will need to be enhanced and maintained over time via active management or managed wildfire, but these treatment needs will likely outpace capacity even under optimistic implementation scenarios. Given limited resources for implementing active management and the likelihood of a more fiery future, incorporating beneficial wildfire into landscape-level treatment planning has the potential to amplify the impact of active management treatments.

California, Nevada

Geochemistry and radiogenic isotopes constrain the mantle source region of the Mountain Pass Intrusive Suite, California

The Mountain Pass carbonatite stock is the largest rare earth element (REE) deposit and only active REE mine in the United States. The carbonatite intrusion and spatially associated alkaline silicate intrusions constitute the Mountain Pass Intrusive Suite, which is located within the Mojave Province in California. Both the carbonatite and the alkaline silicate rocks are enriched in large ion lithophile elements and light REEs, and less enriched to depleted in high field strength elements, indicating the mantle source region was metasomatically enriched in incompatible trace elements. The cause of this metasomatic mantle enrichment and the genetic relationship between the carbonatite and the alkaline silicate stocks are poorly understood. In this study, major and trace element geochemical data and isotopic (Rb-Sr, Sm-Nd, and Lu-Hf) data are presented to constrain genesis of the Mountain Pass Intrusive Suite, from mantle source region to the intrusion of the stocks. Our geochemical data are consistent with derivation of the alkaline silicate and carbonatite melts through partial melting from a shared mantle source region rather than through liquid immiscibility or fractional crystallization and separation of a carbothermal fluid. Although the Rb-Sr isotopic system in the Mountain Pass Intrusive Suite is disturbed at the whole-rock scale, the isotopic systems for whole-rock Sm-Nd (εNd i = ‐2.2 ± 0.8) and zircon Lu-Hf (εHf i = 0.1 ± 1.1) are robust and support mantle derivation of the magmas. Geochemical modeling using experimentally derived partition coefficients was used to identify possible causes of enrichment in incompatible elements through metasomatism in the mantle source region. Modeling of metasomatism by melts derived by partial melting of deeply subducted carbonated sediments approximates observed Mountain Pass Intrusive Suite trace element chemistry. Scattered εHf i in inherited zircon (2.8 ± 2.6) is consistent with derivation from an arc-related environment with substantial crustal contamination. Paleotectonic studies in the Mojave Province indicate that regional subduction preceded emplacement of the Mountain Pass Intrusive Suite by ∼300 Ma. Melting of the Mountain Pass source region may have been caused by post-collisional thermal relaxation and extension.

California

Indications of preferential groundwater seepage feeding northern peatland pools

Groundwater seepage from underlying permeable glacial sedimentary structures, such as eskers, has been hypothesized to directly feed pools in northern peat bogs. These hypotheses directly contradict classical peat bog models for ombrogenous systems, wherein meteoric water is the sole water input to these systems. Variations in the underlying mineral sediment in contact with the peat imply that unrecognized hydrogeologic connectivity may exist with pools in northern peat bogs, particularly where high permeability materials are in contact with the peat. Seepage dynamics originating from these structural variations were investigated using a suite of thermal and hydrogeophysical methods deployed around pools in a peat bog of northeastern Maine, USA. Thermal characterization methods mapped anomalies that were confirmed as matrix seepage or preferential flow pathways (PFPs). Geochemical methods were employed at identified thermal anomalies to confirm upwelling of solute-rich groundwater. Conduits around pools were associated with surficial terminations of suspected peat pipes, based on the inference of pathways extending down into the peat, that focus flow through PFPs in the peat matrix. Discharge also occurred through the peat matrix adjacent to suspected pipe structures and matrix seepage rates were quantified using analysis of diurnal temperature signals recorded at multiple depths. Seepage rates, with a maximum of nearly 0.4 m/d, were measured at localized points around pools. Periods of synchronized temperatures paired with highly muted diurnal temperature signals, recorded in diurnal temperature with depth data, were interpreted qualitatively as activation of strong upward discharge rates through suspected peat pipes. These time periods correlated strongly with local precipitation events around the peatland. Ground-penetrating radar surveys revealed discontinuities in the low permeability glacio-marine clay at the mineral sediment-peat interface, interpreted to be regional glacial esker deposits, which were located beneath and around pools. Heat tracing, specific conductance contrasts, seepage rates, and trace metal concentrations all imply groundwater seepage originating from underlying permeable glacial esker deposits and directly sourcing pools. Preferential groundwater inputs into northern peat bogs may play a key role in developing and maintaining pool systems, with enhanced solute transport impacting peatland ecology, water resources, and carbon cycling.

Maine

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 5 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 5, the subject of this scientific investigations map, has an area of 211 km 2 and has water depths that range from 23 meters (m) on the Stellwagen Bank crest to 105 m in the Stellwagen Basin. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates on the crest and western flank of the south-central part of Stellwagen Bank and in Stellwagen Basin to the west. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 729 stations were analyzed, including 620 sediment samples. The geologic substrate maps of quadrangle 5 show the distribution of 20 substrates that represent a wide range of textures, such as mobile and rippled sand, immobile sand, sand that partially veneers gravel, boulder ridges, and mud. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 5. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that utilize the various substrates, and to support seabed management in the region.

Massachusetts

Characterization of the hydrogeologic framework, groundwater-flow system, geochemistry, and aquifer hydraulic properties of the shallow groundwater system in the Wilcox and Lorraine process areas of the Wilcox Oil Company Superfund site near Bristow, Oklahoma, 2022

The Wilcox Oil Company Superfund site (hereinafter referred to as “the site”) was formerly an oil refinery northeast of Bristow in Creek County, Oklahoma. Historical refinery operations contaminated the soil, surface water, streambed sediments, alluvium, and groundwater with refined and stored products at the site. The Wilcox and Lorraine process areas are where the highest concentrations of volatile organic compounds, semivolatile organic compounds, polycyclic aromatic hydrocarbons, and trace elements (including metals) (collectively hereinafter referred to as “contaminants”) were measured in a local shallow perched groundwater system within the alluvium (hereinafter referred to as the “alluvial aquifer”) at the site during previous site assessments. In order to understand the potential migration of contaminants through the soil and groundwater in these areas, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, investigated aquifer characteristics of the alluvial aquifer in the Wilcox and Lorraine process areas of the site to (1) document hydraulic conductivity and other aquifer characteristics of the alluvial aquifer that govern contaminant fate and transport, (2) describe the geospatial extent and concentration of the contaminants in the alluvial aquifer in the Wilcox and Lorraine process areas, and (3) describe the geochemical controls pertaining to oxidation and reduction governing the fate and transport and the degradation potential of contaminants in the groundwater. Various data were compiled and collected to evaluate the aquifer characteristics at the site including the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer. A total of 20 new (2022) groundwater monitoring wells were installed at the site to collect data used to supplement groundwater-level altitude and groundwater-quality data collected from older, existing groundwater monitoring wells and piezometers. Data compiled and collected for the study were used to evaluate the characteristics of the alluvial aquifer at the site. These aquifer characteristics are defined by the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer.

Oklahoma

Layered intrusions in the Precambrian: Observations and perspectives

Layered intrusions are plutonic bodies of cumulates that form by the crystallization of mantle-derived melts. These intrusions are characterized by igneous layering distinguishable by shifts in mineralogy, texture, or composition. Layered intrusions have been fundamental to our understanding of igneous petrology; however, it is their status as important repositories of critical metals – such as platinum-group elements, chromium, and vanadium – that has predominantly driven associated research in recent decades. Many layered intrusions were emplaced during the Precambrian, predominantly at the margins of ancient cratons during intervals of supercontinent accretion and destruction. It appears that large, layered intrusions require rigid crust to ensure their preservation, and their geometry and layering is primarily controlled by the nature of melt emplacement. Layered intrusions are best investigated by integrating observations from various length-scales. At the macroscale, intrusion geometries can be discerned, and their presence understood in the context of the regional geology. At the mesoscale, the layering of an intrusion may be characterized, intrusion-host rock contact relationships studied, and the nature of stratiform mineral occurrences described. At the microscale, the mineralogy and texture of cumulate rocks and any mineralization are elucidated, particularly when novel microtextural and mineral chemical datasets are integrated. For example, here we demonstrate how mesoscale observations and microscale datasets can be combined to understand the petrogenesis of the perplexing snowball oiks outcrop located in the Upper Banded Series of the Stillwater Complex. Our data suggest that the orthopyroxene oikocrysts did not form in their present location, but rather formed in a dynamic magma chamber where crystals were transported either by convective currents or within crystal-rich slurries. Critical metals may be transported to the level of a nascent intrusion as dissolved components in the melt. Alternatively, ore minerals are entrained from elsewhere in a plumbing system, potentially facilitated by volatile-rich phases. There are many ore-forming processes propounded by researchers to occur at the level of emplacement; however, each must address the arrival of the ore mineral, its concentration of metals, and its accumulation into orebodies. In this contribution, several of these processes are described as well as our perspectives on the future of layered intrusion research.

Precambrian Research

Assessment of long-term changes in surface-water extent within Klamath Marsh, south-central Oregon, 1985–2021

The annual maximum extent of surface water in Klamath Marsh has naturally fluctuated in response to periods of wet and dry conditions in the surrounding basin. Field observations during the 2010s indicate that the annual maximum extent of surface water has been declining and the marsh is not responding to hydrologic inputs as it had historically. This report describes the results of a hydrologic evaluation of Klamath Marsh to characterize and understand multi-year declines in the surface-water extent and increased intermittency of streamflow exiting the marsh. Landsat imagery collected during 1985–2021 was processed to create a time series of annual maximum surface-water extent to assess changes in surface-water inundation within the marsh. A 50-percent decrease in the mean surface area of annual total open-water extent (TOWE) during the latter half of the study period (2003–21) compared to the first half (1985–2003) was observed in this 37-year time-series dataset. The change in open-water extent was offset by a corresponding increase in dry land in the marsh. Time series of streamflow, groundwater level, total annual precipitation, annual mean temperature, and anthropogenic water use and water management were compiled and evaluated to improve understanding of the factors affecting TOWE. Statistically significant downward trends in the regional groundwater table and streamflow into and out of the marsh were identified as well as statistically significant upward trends in annual mean temperature. Statistically significant correlations among TOWE, streamflow, and groundwater level also were identified. The decreasing trends could not be attributed to changes in total annual precipitation or changing anthropogenic groundwater use within the study area. Declines in the open-water extent of Klamath Marsh since 2000 principally are due to a decoupling of the groundwater and surface-water system beneath the marsh because of regional declines in groundwater level. Regional increases in air temperature and the reestablishment of more than 55,000 acres of forested land within the study area have likely contributed to increasing evapotranspiration, leaving less water available for groundwater recharge and stream base flow and resulting in basin-wide declines in streamflow and groundwater levels.

Oregon

Groundwater-storage change in the north Phoenix aquifer, Arizona, 2020–23

The city of Phoenix, Arizona, relies primarily on surface water for municipal water supply. The city also maintains wells to withdraw groundwater, particularly in times of drought and reduced surface-water supply, and to recharge groundwater when excess surface water is available. As of 2023, withdrawals from the aquifer in the northeastern part of the city are a small volume of water, less than 3,000 acre-feet in most years. Each year a similar volume of water is recharged through injection wells. The withdrawal wells are permitted to produce in total more than 20,000 acre-feet per year; increased pumping could lead to future groundwater-storage declines. To better understand groundwater-storage change in the north Phoenix aquifer, a repeat microgravity monitoring network was established in 2020. Measurements of changes in Earth’s gravity provide a direct, non-invasive measurement of subsurface mass change. Groundwater-storage changes were small during the 2020–23 study period, consistent with the relatively small volumes of pumping and recharge. Groundwater levels measured in monitoring wells were stable or increased slightly during this period, although the number of monitoring wells within the area of the gravity monitoring network is sparse. In total, about 15,000 acre-feet of water were pumped and 31,000 acre-feet recharged through injection in the north Phoenix aquifer during the 2020–22 period. Within the monitored area, groundwater storage increased by a small amount, about 1,000 acre-feet, in 2020, and decreased by a larger amount, about 6,000 acre-feet, each year in 2021 and 2022. Storage decreased at 89 of 102 stations from 2020 to 2023. Groundwater-storage decreases greater than the volume of net pumping indicate down-gradient subflow from the aquifer is greater than recharge plus incoming subflow, drying of the unsaturated zone resulting from decreased land-surface recharge, or both. At present (2023), the aquifer appears able to store and supply the relatively small amounts of water needed without excessive drawdown or harmful effects, such as land subsidence and surface inundation. If pumping or recharge increases in the future, the established repeat microgravity network is well suited to capture the spatial extent and magnitude of groundwater-storage changes in the aquifer.

Arizona

Rare earth element-mineralized carbonatite in the Bear Lodge Alkaline Complex, USA—Ore genesis implications from fluid inclusion characterization

Rare earth element (REE) resources of the Bear Lodge Alkaline Complex, Wyoming, are hosted in variably leached carbonatite spatially related to diatreme breccia pipes. We investigated the genesis of REE and lesser-known gold resources through fluid inclusion analysis of carbonatite, fluorite breccia, and smoky quartz vein samples. Physicochemical characteristics of inclusion-trapped fluids were evaluated using petrography, microthermometry, Raman spectroscopy, decrepitate mound analysis, energy-dispersive spectroscopy, laser ablation inductively coupled plasma mass spectrometry, and noble gas isotope analysis. Microthermometry results reveal three fluid types that affected carbonatite dikes within deeper zones that escaped near-surface, ore-grade REE enrichment: (1) high-temperature (330–432°C) magmatic fluid captured in fine-grained calcite; (2) REE-enriched alkali bicarbonate-sulfate brine; and (3) low-temperature (117–182°C) diluted magmatic or meteoric water. Multiphase brine-like inclusions contain burbankite, nahcolite, strontianite, celestine and alkali sulfate daughter crystals, linking them to early burbankite mineralization. Peripheral smoky quartz and fluorite occurrences at Smith Ridge, 1.5 km from the central carbonatite dike swarm, contain primary inclusions that are Cl-poor and rich in Na-HCO 3 -SO 4 , similar to secondary and pseudosecondary inclusions in carbonatites. Helium isotopes reveal a MORB-like source for carbonatite samples and an older crust signature at Smith Ridge, consistent with the proximal ridge-top exposures of Archean granite. Results from this fluid inclusion study coupled with previous studies of carbonatite mineral paragenesis, show that light REEs (LREEs) were not mobilized great distances. Instead, burbankite crystallized within carbonatite from alkali bicarbonate fluids. With sodium retained in early burbankite, outward-emanating fluids enriched in potassium relative to sodium (higher K:Na) resulted in potassium–ferric iron metasomatism of silicate host rocks. This alkali fractionation was accompanied by fractionation of LREEs and heavy REEs (HREEs), with LREEs dominating the central carbonatite resources. In contrast, areas of peripheral REE mineralization at Bear Lodge are commonly characterized by higher HREE:LREE ratios. The K:Na ratio of associated fenites or alteration assemblages could be indicative of early crystallized burbankite in carbonatites and REE fractionation processes potentially leading to areas of concentrated HREEs with greater supply vulnerabilities.

South Dakota, Wyoming

Tapwater exposures, residential risk, and mitigation in a PFAS-impacted-groundwater community

Tapwater (TW) safety and sustainability are priorities in the United States. Per/polyfluoroalkyl substance(s) (PFAS) contamination is a growing public-health concern due to prolific use, widespread TW exposures, and mounting human-health concerns. Historically-rural, actively-urbanizing communities that rely on surficial-aquifer private wells incur elevated risks of unrecognized TW exposures, including PFAS, due to limited private-well monitoring and contaminant-source proliferation in urbanizing landscapes. Here, a broad-analytical-scope TW-assessment was conducted in a hydrologically-vulnerable, Mississippi River alluvial-island community, where PFAS contamination of the shallow-alluvial drinking-water aquifer has been documented, but more comprehensive contaminant characterization to inform decision-making is currently lacking. In 2021, we analyzed 510 organics, 34 inorganics, and 3 microbial groups in 11 residential and community locations to assess (1) TW risks beyond recognized PFAS issues, (2) day-to-day and year-to-year risk variability, and (3) suitability of the underlying sandstone aquifer as an alternative source to mitigate TW-PFAS exposures. Seventy-six organics and 25 inorganics were detected. Potential human-health risks of detected TW exposures were explored based on cumulative benchmark-based toxicity quotients ( ∑ TQ ). Elevated risks ( ∑ TQ ≥ 1) from organic and inorganic contaminants were observed in all alluvial-aquifer-sourced synoptic samples but not in sandstone-aquifer-sourced samples. Repeated sampling at 3 sites over 52–55 h indicated limited variability in risk over the short-term. Comparable PFAS-specific ∑ TQ for spatial-synoptic, short-term (3 days) temporal, and long-term (3 years quarterly) temporal samples indicated that synoptic results provided useful insight into the risks of TW-PFAS exposures at French Island over the long-term. No PFAS detections in sandstone-aquifer-sourced samples over a 3 year period indicated no PFAS-associated risk and supported the sandstone aquifer as an alternative drinking-water source to mitigate community TW-PFAS exposures. This study illustrated the importance of expanded contaminant monitoring of private-well TW, beyond known concerns (in this case, PFAS), to reduce the risks of a range of unrecognized contaminant exposures.

Wisconsin

Fluid inclusion constraints on the geometry of the magmatic plumbing system beneath Mauna Loa – Part 2: Xenoliths

Mauna Loa volcano erupts crystal-poor material at its summit and more crystal-rich material on its rift zones. Some of the more olivine-rich lava flows contain xenoliths with diverse mineralogy, including cumulate harzburgites with high-Mg# orthopyroxenes and high-Fo olivines (both > 84). Previous experimental work and thermodynamic modelling has proposed that high-Mg# orthopyroxenes only crystallize from Mauna Loa melts at high pressures (> 6 kbar, > 20 km), leading to suggestions that there is a region of sub-Moho magma storage at Mauna Loa in addition to the geophysically imaged magma reservoir at 2–5 km depth below the summit. We use melt and fluid inclusion barometry combined with thermodynamic models to further investigate this suggestion. Fluid inclusion data from harzburgites and dunitic xenoliths yield storage depths remarkably similar to those found in non-xenolithic crystals from lavas and tephras, with a clear peak at ~ 2–3 km (below the summit). Depths from melt inclusions in these xenoliths overlap with fluid inclusion pressures, ruling out the possibility of fluid inclusion re-equilibration during a period of stalling in a shallower reservoir. We examine five different thermodynamic models and find that the minimum pressure of olivine-orthopyroxene co-saturation varies by ~ 4 kbar (~ 12 km). These models also fail to predict that orthopyroxene is stable in ~ 15–80% of compositionally relevant experimental charges which grew orthopyroxene. Overall, this shows that phase stability modelling is an unreliable method of determining magma storage depth at Mauna Loa. We suggest that model discrepancies reflect a lack of experimental constraints on orthopyroxene stability at > 1200 ℃ and 0.01–5 kbar. Based on the presence of large oikocrystic orthopyroxenes completely enclosing rounded olivine chadacrysts, we suggest that these harzburgitic xenoliths formed through the reaction of intruding melts with olivine mush piles within the Mauna Loa edifice at ~ 3 km depth below the summit, with no need for a deeper storage reservoir. The predominance of pre-eruptive shallow storage means that there is more chance of detecting reservoir destabilization with geophysical monitoring techniques compared to a scenario where melts are supplied from sub-Moho reservoirs.

Hawaii