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At least 1,369 records · Page 76Linked to original sources
USGS1977

Further paleomagnetic results for the San Juan volcanic field of southern Colorado

Combining paleomagnetic data for 17 new sites from the northwest portion of the (Oligocene) San Juan volcanic field of southern Colorado with data for 29 sites previously published yields a paleomagnetic pole at 85°N, 114°E (with a 95% confidence circle of 7.5° radius). A further combination of the San Juan data with the results of other studies on rocks of Oligocene age from tectonically stable parts of North America gives a mid-Tertiary reference pole located at 81°N, 132.5°E, with a confidence circle of approximately 4°. Mid-Tertiary paleomagnetic poles for the western edge of the continent diverge markedly from this reference pole.

Colorado↗
USGS1978

Decomposition of hydroxy amino acids in foraminiferal tests; kinetics, mechanism and geochronological implications

The diagenesis of the hydroxy amino acids serine and threonine in foraminiferal tests has been investigated. The decomposition pathways of these amino acids are complex; the principal reactions appear to be dehydration, aldol cleavage and decarboxylation. Stereochemical studies indicate that the α-amino-n-butyric acid (ABA) detected in foraminiferal tests is the end product of threonine dehydration pathway. Decomposition of serine and threonine in foraminiferal tests from two well-dated Caribbean deep-sea cores, P6304-8 and -9, has been found to follow irreversible first-order kinetics. Three empirical equations were derived for the disappearance of serine and threonine and the appearance of ABA. These equations can be used as a new geochronological method for dating foraminiferal tests from other deep-sea sediments. Preliminary results suggest that ages deduced from the ABA kinetics equation are most reliable because “species effect” and contamination problems are not important for this nonbiological amino acid. Because of the variable serine and threonine contents of modern foraminiferal species, it is likely that the accurate age estimates can be obtained from the serine and threonine decomposition equations only if a homogeneous species assemblage or single species sample isolated from mixed natural assemblages is used.

Earth and Planetary Science Letters↗
USGS1978

The crystal structure and thermal history of orthopyroxene from lunar anorthosite 15415

A single crystal of untwinned orthopyroxene from lunar anorthosite sample 15415, with composition (Mg 1.14 Fe 0.80 Mn 0.02 Ca 0.04 )(Si 1.97 Al 0.03 )O 6 , has a unit cell in space group Pbca with a = 18.310(15)Å, b = 8.904(10)Å, c = 5.214(7)Å, containing 2 formula units. A set of 742 counter-measured intensity data made with MoK α radiation has been used to refine the crystal structure in isotropic thermal mode to R = 0.116. Anisotropic refinement led to R = 0.092, but thermal parameters are distorted by non-random errors resulting from poor crystal texture. The resulting structure is in close agreement with that obtained by Ghose [9] for a hypersthene from Greenland. A parameter q , which gives ( Mg q Fe 1−q ) for cation site M (1) and (Mg 1.14− q Fe q −0.18 Ca 0.04 ) for site M (2), was included in the least-squares analysis, yielding q = 0.90(1). This orthopyroxene has the high degree of cation order expected of pyroxenes subjected to Apollonian metamorphism at lower than 500–600°C. No evidence exists for a subsequent thermal event of sufficient intensity to disorder the pyroxene. On the basis of previous laboratory studies of argon-release patterns of lunar plagioclase and order-disorder kinetics of terrestrial pyroxenes, we attribute the reported isotopic age (3.9–4.1 AE) to cessation of metamorphism, perhaps caused by impact excavation.

Earth and Planetary Science Letters↗
USGS1978

Isotopic composition of lead in oceanic basalt and its implication to mantle evolution

New data are given in this report for (1) Pb isotopic compositions and U, Th, and Pb concentrations of basalts from the island of Hawaii; (2) redetermined Pb isotopic compositions of some abyssal tholeiites; and (3) U, Th, and Pb concentrations of altered and fresh abyssal basalts, and basalt genesis and mantle evolution are discussed. The Th/U ratios of abyssal and Japanese tholeiites are distinctly lower than those of tholeiites and alkali basalts from other areas. It is thought that these low values reflect a part of the mantle depleted in large ionic lithophile elements. Thus a mantle evolution model is presented, in which Th/U ratios of the depleted zone in the mantle have decreased to ∼2, and U/Pb ratios have increased, showing an apparent ∼1.5-b.y. isochron trend in the 207 Pb/ 204 Pb vs. 206 Pb/ 204 Pb plot. The Pb isotopic compositions of basalts from the island of Hawaii are distinct for each of the five volcanoes, and within each volcano, Pb's of tholeiites and alkali basalts are similar. An interaction between partially melted material (hot plume?) of the asthenosphere and the lithosphere is suggested to explain the trend in the Pb isotopic compositions of Hawaiian basalts.

Earth and Planetary Science Letters↗
USGS1978

Cobalt and scandium partitioning versus iron content for crystalline phases in ultramafic nodules

Fractionation of Co and Sc between garnets, olivines, and clino- and orthopyroxenes, separated from a suite of Salt Lake Crater ultramafic nodules that equilibrated at the same T and P , is strongly dependent on Fe contents. This observation suggests that petrogenetic equilibrium models of partial melting and crystal fractionation must take into account effects of magma composition, if they are to describe quantitatively geochemical evolutionary trends.

Earth and Planetary Science Letters↗
USGS1978

Radioactive disequilibrium in altered mid-oceanic basalts

A young (<1 m.y.) tholeiitic basalt dredged from the Mid-Atlantic Ridge displays a 234 U excess and a 230 Th deficiency that have resulted from the addition of seawater uranium during weathering at seafloor temperatures. Two older samples, though they acquired substantial amounts of uranium from seawater, are depleted in 234 U, indicating preferential leaching of this isotope. Hydrothermally altered samples suggest that some uranium loss may have occurred. Possible isotopic effects of preferential 234 U leaching, however, are obscured by secondary addition of seawater uranium at lower temperatures.

Earth and Planetary Science Letters↗
USGS1979

D/H ratios in speleothem fluid inclusions: A guide to variations in the isotopic composition of meteoric precipitation?

D/H ratios of fluid inclusion waters extracted from 230 Th/ 234 U-dated speleothems that were originally deposited under conditions of isotopic equilibrium should provide a direct estimate of the hydrogen isotopic composition of ancient meteoric waters. We present here D/H ratios for 47 fluid inclusion samples from thirteen speleothems deposited over the past 250,000 years at cave sites in Iowa, West Virginia, Kentucky and Missouri. At each site glacial-age waters are depleted in deuterium relative to those of interglacial age. The average interglacial/glacial shift in the hydrogen isotopic composition of meteoric precipitation over ice-free areas of east-central North America is estimated to be −12‰. This shift is consistent with the present climatic models and can be explained in terms of the prevailing pattern of atmospheric circulation and an increased ocean-continent temperature gradient during glacial times which more than compensated for the increase in deuterium content of the world ocean.

Earth and Planetary Science Letters↗
USGS1979

Random crustal magnetization and its effect on coherence of short-wavelength marine magnetic anomalies

Recent studies of DSDP samples from layer 2A of oceanic basement have found complex magnetic stratigraphies that seem incompatible with the frequent existence of linear short-wavelength anomalies caused by palaeomagnetic field behavior. Statistical models are developed for the lateral variation of the average magnetization of layer 2A: a Poisson series for reversals of the earth's field and a stairstep random series for discrete magnetic units. It is shown with the power-density spectra of these statistical models that lateral inhomogeneities must average out over distances of less than a few hundred meters. Specifically, individual magnetic units of the type seen at DSDP Site 332 cannot extend uniformly for distances greater than a few hundred meters.

Earth and Planetary Science Letters↗
USGS1979

Correlation of lunar far-side magnetized regions with ringed impact basins

By the method of electron reflection, we have identified seven well-defined magnetized regions in the equatorial belt of the lunar far side sampled by the Apollo 16 Particles and Fields subsatellite. Most of these surface magnetic fields lie within one basin radius from the rim of a ringed impact basin, where thick deposits of basin ejecta are observed or inferred. The strongest of the seven magnetic features is linear, at least 250 km long, and radial to the Freundlich-Sharonov basin. The apparent correlation with basin ejecta suggests some form of impact origin for the observed permanently magnetized regions.

Earth and Planetary Science Letters↗
USGS1979

Temperature calibration of amino acid racemization: Age implications for the Yuha skeleton

D/L of aspartic acid ranged from 0.52 to 0.56 for femur samples of the Yuha skeleton. Subsurface temperature measurements made at the burial site indicate average annual temperature is 18°C and diagenetic temperature is 21.6°C. These data and a relation derived for the dependence of the aspartic acid rate constant on diagenetic temperature indicate an age of 23,600. The result is consistent with 14 C and 230 Th dating of calcrete found coating the bones.

Earth and Planetary Science Letters↗
USGS1979

Amino acid racemization dating of fossil bones, I. inter-laboratory comparison of racemization measurements

Enantiomeric measurements for aspartic acid, glutamic acid, and alanine in twenty-one different fossil bone samples have been carried out by three different laboratories using different analytical methods. These inter-laboratory comparisons demonstrate that D/L aspartic acid measurements are highly reproducible, whereas the enantiomeric measurements for the other amino acids show a wide variation between the three laboratories. At present, aspartic acid measurements are the most suitable for racemization dating of bone because of their superior analytical precision.

Earth and Planetary Science Letters↗
USGS1979

Trace element and strontium isotope characteristics of volcanic rocks from Isla Tortuga: A young seamount in the Gulf of California

Isla Tortuga is a small isolated central volcano which is located near an actively spreading trough in the Gulf of California. The basalt lavas from Tortuga which have the highest Mg/Fe and Ni contents have trace element abundances and ratios and 87 Sr/ 86 Sr which are similar to those of mid-ocean ridge tholeiite. The major element, rare earth element and Sr abundances of fractionated tholeiite (low Mg/Fe) and tholeiitic andesite of Tortuga are consistent with an origin by closed-system fractional crystallization. This hypothesis is not supported by K, Na, Rb and Ba abundances in the lavas nor by their variable 87 Sr/ 86 Sr (0.7024–0.7035). It is proposed that the apparent decoupling of light rare earth elements, other incompatible trace elements and 87 Sr/ 86 Sr is due to contamination of some Tortuga magmas while they are fractionated in a high-level crustal magma chamber. The mantle source of least-contaminated, high Mg/Fe basalt lavas of Tortuga is similar, although not identical to the source of normal mid-ocean ridge tholeiite; significant differences exist. The reasons for these differences are not yet known.

Earth and Planetary Science Letters↗
USGS1980

Growth rates of manganese nodules in Oneida Lake, New York

226 Ra is used to document the growth histories of six manganese nodules from Oneida Lake, New York. Detailed sectioning and analysis reveal that there are discontinuous gradients in 226 Ra content in these samples. These gradients result from periods of rapid growth (>1 mm/100 years) separated by periods of no growth of erosion. Although the 226 Ra “age” of the nodules approximates the age of Oneida Lake, the nodules are not sediment-covered because they occur only in areas of the lake where fine-grained sediments are not accumulating.

New York↗
USGS1980

U-Pb ages of uraniferous opals and implications for the history of beryllium, fluorine, and uranium mineralization at Spor Mountain, Utah

The U-Pb isotope systematics of uraniferous opals from Spor Mountain, Utah, were investigated to determine the suitability of such material for geochronologic purposes, and to estimate the timing of uranium and associated beryllium and fluorine mineralization. The results indicate that uraniferous opals can approximate a closed system for uranium and uranium daughters, so that dating samples as young as ∼1 m.y. should be possible. In addition, the expected lack of initial 230 Th and 231 Pa in opals permits valuable information on the initial 234 U/ 238 U to be obtained on suitable samples of ≲10 m.y. age. The oldest 207 Pb/ 235 U apparent age observed, 20.8 ± 1m.y., was that of the opal-fluorite core of a nodule from a beryllium deposit in the Spor Mountain Formation. This age is indistinguishable from that of fission-track and K-Ar ages from the host rhyolite, and links the mineralization to the first episode of alkali rhyolite magmatism and related hydrothermal activity at Spor Mountain. Successively younger ages of 13 m.y. and 8–9 m.y. on concentric outer zones of the same nodule indicate that opal formed either episodically or continuously for over 10 m.y. Several samples of both fracture-filling and massive-nodule opal associated with beryllium deposits gave 207 Pb/ 235 U apparent ages of 13–16 m.y., which may reflect a restricted period of mineralization or perhaps an averaging of 21−and<13−m.y. periods of opal growth. Several samples of fracture-filling opal in volcanic rocks as young as 6 m.y. gave 207 Pb/ 235 U ages of 3.4–4.8 m.y. These ages may reflect hot-spring activity after the last major eruption of alkali rhyolite.

Utah↗
USGS1980

A high-temperature hydrothermal deposit on the seabed at a Gulf of California spreading center ( Guaymas Basin).

A submersible dive on a turbidite-covered spreading axis in Guaymas Basin photographed and sampled extensive terraces and ledges of talc. The rock contains siliceous microfossils, smectite, and euhedral pyrrhotite as well as rather pure iron-rich talc. S and O isotopes indicate precipitation around a hydrothermal vent, at about 2800C. - Authors

Earth and Planetary Science Letters↗
USGS1980

Declination and inclination errors in experimentally deposited specularite-bearing sand

Naturally disaggregated specularite-bearing sandstone from the Triassic Moenkopi Formation, artificially deposited in controlled magnetic fields of ∼5 × 10 −2 mT, acquires a stable remanent magnetization that has systematic errors in inclination and declination. Inclinations about 12° shallower than the applied fields are produced by deposition on a horizontal surface in still water. Deposition from flowing water on a surface inclined 6–10° results in inclination errors of as much as 20°. Water flowing obliquely to the applied field results in declination errors of about 10°, with declinations systematically rotated toward the upstream direction of current flow. These experimental results indicate that specularite-bearing sediment responds to the earth's field in a manner similar to magnetite-bearing sediment, and support observational evidence for a primary magnetization of depositional origin in specularite in red beds of the Moenkopi Formation.

Earth and Planetary Science Letters↗
USGS1980

Circum-arctic plate accretion - Isolating part of a pacific plate to form the nucleus of the Arctic Basin

A mosaic of large lithospheric plates rims the Arctic Ocean Basin, and foldbelts between these plates contain numerous allochthonous microplates. A new model for continental drift and microplate accretion proposes that prior to the late Mesozoic the Kula plate extended from the Pacific into the Arctic. By a process of circumpolar drift and microplate accretion, fragments of the Pacific basin, including parts of the Kula plate, were cut off and isolated in the Arctic Ocean, the Yukon-Koyukuk basin in Alaska, and the Bering Sea.

Earth and Planetary Science Letters↗