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USGS1996

Environmental behavior and fate of methyl tert-butyl ether (MTBE)

When gasoline that has been oxygenated with methyl tert-butyl ether (MTBE) comes in contact with water, large amounts of MTBE can dissolve; at 25 degrees Celsius the water solubility of MTBE is about 5,000 milligrams per liter for a gasoline that is 10 percent MTBE by weight. In contrast, for a nonoxygenated gasoline, the total hydrocarbon solubility in water is typically about 120 milligrams per liter. MTBE sorbs only weakly to soil and aquifer materials; therefore, sorption will not significantly retard MTBE's transport by ground water. In addition, MTBE generally resists degradation in ground water. The half-life of MTBE in the atmosphere can be as short as 3 days in a regional airshed. MTBE in the air tends to partition into atmospheric water, including precipitation. However, washout of gas-phase MTBE by precipitation would not, by itself, greatly alter the gas-phase concentration of the compound in the air. The partitioning of MTBE to precipitation is nevertheless strong enough to allow for up to 3 micrograms per liter or more inputs of MTBE to surface and ground water.

Fact Sheet↗

USGS2025

PFAS sampling activities in the U.S. Geological Survey national networks

Per- and polyfluoroalkyl substances (PFAS), frequently called “forever chemicals,” are used for a wide variety of industrial purposes and are often found in common household and industrial items such as firefighting foams, non-stick cookware, and water-resistant materials. The contamination of water, air, and soil by PFAS is a national and global issue due to their widespread occurrence in multiple applications and resistance to biodegradation and other traditional treatment processes. Research indicates that many PFAS can be emitted to the atmosphere and transported and deposited long distances from the source. The U.S. Geological Survey (USGS) Water Resources Mission Area received funding to implement a national-scale sampling effort to assess PFAS occurrence. To follow agency directives, the National Water Quality Network (NWQN) added PFAS sample monitoring for both surface water and groundwater, and also added PFAS monitoring to selected sites in the National Atmospheric Deposition Program (NADP).

General Information Product↗

USGS2000

Assessment of Folsom Lake Watershed response to historical and potential future climate scenarios

An integrated forecast-control system was designed to allow the profitable use of ensemble forecasts for the operational management of multi-purpose reservoirs. The system ingests large-scale climate model monthly precipitation through the adjustment of the marginal distribution of reservoir-catchment precipitation to reflect occurrence of monthly climate precipitation amounts in the extreme terciles of their distribution. Generation of ensemble reservoir inflow forecasts is then accomplished with due account for atmospheric- forcing and hydrologic- model uncertainties. These ensemble forecasts are ingested by the decision component of the integrated system, which generates non- inferior trade-off surfaces and, given management preferences, estimates of reservoir- management benefits over given periods. In collaboration with the Bureau of Reclamation and the California Nevada River Forecast Center, the integrated system is applied to Folsom Lake in California to evaluate the benefits for flood control, hydroelectric energy production, and low flow augmentation. In addition to retrospective studies involving the historical period 1964-1993, system simulations were performed for the future period 2001-2030, under a control (constant future greenhouse-gas concentrations assumed at the present levels) and a greenhouse-gas- increase (1-% per annum increase assumed) scenario. The present paper presents and validates ensemble 30-day reservoir- inflow forecasts under a variety of situations. Corresponding reservoir management results are presented in Yao and Georgakakos, A., this issue. Principle conclusions of this paper are that the integrated system provides reliable ensemble inflow volume forecasts at the 5-% confidence level for the majority of the deciles of forecast frequency, and that the use of climate model simulations is beneficial mainly during high flow periods. It is also found that, for future periods with potential sharp climatic increases of precipitation amount and to maintain good reliability levels, operational ensemble inflow forecasting should involve atmospheric forcing from appropriate climatic periods.

Open-File Report↗

USGS2001

A guide to potential soil carbon sequestration: Land-use management for mitigation of greenhouse gas emissions

Terrestrial carbon sequestration has a potential role in reducing the recent increase in atmospheric carbon dioxide (CO2) that is, in part, contributing to global warming. Because the most stable long-term surface reservoir for carbon is the soil, changes in agriculture and forestry can potentially reduce atmospheric CO2 through increased soil-carbon storage. If local governments and regional planning agencies are to effect changes in land-use management that could mitigate the impacts of increased greenhouse gas (GHG) emissions, it is essential to know how carbon is cycled and distributed on the landscape. Only then can a cost/benefit analysis be applied to carbon sequestration as a potential land-use management tool for mitigation of GHG emissions. For the past several years, the U.S. Geological Survey (USGS) has been researching the role of terrestrial carbon in the global carbon cycle. Data from these investigations now allow the USGS to begin to (1) 'map' carbon at national, regional, and local scales; (2) calculate present carbon storage at land surface; and (3) identify those areas having the greatest potential to sequester carbon.

North Carolina↗

USGS2002

Rocky Mountain snowpack chemistry network: History, methods, and the importance of monitoring mountain ecosystems

Because regional-scale atmospheric deposition data in the Rocky Mountains are sparse, a program was designed by the U.S. Geological Survey to more thoroughly determine the quality of precipitation and to identify sources of atmospherically deposited pollution in a network of high-elevation sites. Depth-integrated samples of seasonal snowpacks at 52 sampling sites, in a network from New Mexico to Montana, were collected and analyzed each year since 1993. The results of the first 5 years (1993–97) of the program are discussed in this report. Spatial patterns in regional data have emerged from the geographically distributed chemical concentrations of ammonium, nitrate, and sulfate that clearly indicate that concentrations of these acid precursors in less developed areas of the region are lower than concentrations in the heavily developed areas. Snowpacks in northern Colorado that lie adjacent to both the highly developed Denver metropolitan area to the east and coal-fired powerplants to the west had the highest overall concentrations of nitrate and sulfate in the network. Ammonium concentrations were highest in northwestern Wyoming and southern Montana.

Rocky Mountains↗

USGS2002

AVIRIS data calibration information: Oquirrh and East Tintic mountains, Utah

The information contained herein pertains to the original reflectance calibration derived solely from the Saltair beach site on the shores of Great Salt Lake. The reflectance data derived from this calibration becomes markedly affected by residual absorptions due to atmospheric water vapor and carbon dioxide within short horizontal and vertical distances from the calibration site due to the presence of what is believed to be a distinct microclimate by the lake. Subsequent to the development of this web site, a new reflectance calibration was derived which mitigated these effects. Reflectance spectra of bright areas of known composition in the East Tintic Mountains, far from Great Salt Lake, were sampled from the calibrated high altitude AVIRIS data cubes and edited, or "polished," to identify artifacts related to residual absorptions of atmospheric gases, particulates, and sensor noise. The subtle artifacts identified in this way were incorporated into the multiplier spectra derived from the original calibration site, generating new multiplier spectra that were used to re-calibrate the ATREM- and path radiance-corrected cubes to reflectance. This process generated a reflectance calibration customized for the Oquirrh/East Tintic Mountain region.

Utah↗

USGS2003

Preliminary Mineralogic and Stable Isotope Studies of Altered Summit and Flank Rocks and Osceola Mudflow Deposits on Mount Rainier, Washington

About 5600 years ago part of Mount Rainier?s edifice collapsed with the resultant Osceola Mudflow traveling more than 120 km and covering an area of at least 505 km2. Mineralogic and stable isotope studies were conducted on altered rocks from outcrops near the summit and east flank of the volcano and samples of clasts and matrix from the Osceola Mudflow. Results of these analyses are used to constrain processes responsible for pre-collapse alteration and provide insight into the role of alteration in edifice instability prior to the Osceola collapse event. Jarosite, pyrite, alunite, and kaolinite occur in hydrothermally altered rock exposed in summit scarps formed by edifice collapse events and in altered rock within the east-west structural zone (EWSZ) of the volcano?s east flank. Deposits of the Osceola Mudflow contain clasts of variably altered and unaltered andesite within a clay-rich matrix. Minerals detected in samples from the edifice are also present in many of the clasts. The matrix includes abundant smectite, kaolinite and variably abundant jarosite. Hydrothermal fluid compositions calculated from hydrogen and oxygen isotope data of alunite, and smectite on Mount Rainier reflect mixing of magmatic and meteoric waters. The range in the dD values of modern meteoric water on the volcano (-85 to 155?) reflect the influence of elevation on the dD of precipitation. The d34S and d18OSO4 values of alunite, gypsum and jarosite are distinct but together range from 1.7 to 17.6? and -12.3 to 15.0?, respectively; both parameters increase from jarosite to gypsum to alunite. The variations in sulfur isotope composition are attributed to the varying contributions of disproportionation of magmatic SO2, the supergene oxidation of hydrothermal pyrite and possible oxidation of H2S to the parent aqueous sulfate. The 18OSO4 values of jarosite are the lowest recorded for the mineral, consistent with a supergene origin. The mineralogy and isotope composition of alteration minerals define two and possibly three environments of alteration. At deeper levels magmatic vapor, H2S, SO2 and other gases from venting magmas migrated upward and condensed into the meteoric water. Disproportionation of SO2 into aqueous sulfate and H2S resulted in acid-sulfate (alunite + kaolinite + pyrite) and related argillic and propylitic alteration envelopes in a magmatic hydrothermal environment. At shallow levels H2S reacted with andesite to form pyrite that is associated with smectite along fractures on both the flanks and upper edifice. It is not clear to what extent H2S was oxidized by atmospheric O2 to form aqueous sulfate in a steam-heated environment. Near the ground surface, pyrite is oxidized by atmospheric oxygen resulting in soluble iron-and aluminum-hydroxysulfates. These supergene hydroxysulfates, which may also form around fumaroles from the oxidation of H2S, are subject to continuous solution and redeposition.

Open-File Report↗

USGS2003

Rocky Mountain snowpack chemistry at selected sites for 2001

Because regional-scale atmospheric deposition data in the Rocky Mountains are sparse, a program was designed by the U.S. Geological Survey, in cooperation with the National Park Service, U.S. Department of Agriculture Forest Service, and other agencies, to more thoroughly determine the chemical composition of precipitation and to identify sources of atmospherically deposited contaminants in a network of high-elevation sites. Samples of seasonal snowpacks at 57 geographically distributed sites, in a regional network from New Mexico to Montana, were collected and analyzed for major ions (including ammonium, nitrate, and sulfate), alkalinity, and dissolved organic carbon during 2001. Sites selected in this report have been sampled annually since 1993, enabling identification of increases or decreases in chemical concentrations from year to year. Spatial patterns in snowpack-chemical data for concentrations of ammonium, nitrate, and sulfate indicate that concentrations of these acid precursors in less developed areas of the region are lower than concentrations in the heavily developed areas. Results for the 2001 snowpack-chemistry analyses, however, indicate increases in concentrations of ammonium and nitrate in particular at sites where past concentrations typically were lower. Since 1993, concentrations of nitrate and sulfate were highest from snowpack samples in northern Colorado that were collected from sites adjacent to the Denver metropolitan area to the east and the coal-fired powerplants to the west. In 2001, relatively high concentrations of nitrate (12.3 to 23.0 microequivalents per liter (?eq/L) and sulfate (7.7 to 12.5 ?eq/L) were detected in Montana and Wyoming. Ammonium concentrations were highest in north-central Colorado (14.5 to 16.9 ?eq/L) and southwestern Montana (12.8 to 14.2 ?eq/L).

Open-File Report↗

USGS2004

Mineral commodity profiles: nitrogen

Overview -- Nitrogen (N) is an essential element of life and a part of all animal and plant proteins. As a part of the DNA and RNA molecules, nitrogen is an essential constituent of each individual's genetic blueprint. As an essential element in the chlorophyll molecule, nitrogen is vital to a plant's ability to photosynthesize. Some crop plants, such as alfalfa, peas, peanuts, and soybeans, can convert atmospheric nitrogen into a usable form by a process referred to as 'fixation.' Most of the nitrogen that is available for crop production, however, comes from decomposing animal and plant waste or from commercially produced fertilizers. Commercial fertilizers contain nitrogen in the form of ammonium and/or nitrate or in a form that is quickly converted to the ammonium or nitrate form once the fertilizer is applied to the soil. Ammonia is generally the source of nitrogen in fertilizers. Anhydrous ammonia is commercially produced by reacting nitrogen with hydrogen under high temperatures and pressures. The source of nitrogen is the atmosphere, which is almost 80 percent nitrogen. Hydrogen is derived from a variety of raw materials, which include water, and crude oil, coal, and natural gas hydrocarbons. Nitrogen-based fertilizers are produced from ammonia feedstocks through a variety of chemical processes. Small quantities of nitrates are produced from mineral resources principally in Chile. In 2002, anhydrous ammonia and other nitrogen materials were produced in more than 70 countries. Global ammonia production was 108 million metric tons (Mt) of contained nitrogen. With 28 percent of this total, China was the largest producer of ammonia. Asia contributed 46 percent of total world ammonia production, and countries of the former U.S.S.R. represented 13 percent. North America also produced 13 percent of the total; Western Europe, 9 percent; the Middle East, 7 percent; Central America and South America, 5 percent; Eastern Europe, 3 percent; and Africa and Oceania contributed the remaining 4 percent (International Fertilizer Industry Association, 2003b, p. 1-4). In 2002, world ammonia exports were 13.1 Mt of contained nitrogen. Trinidad and Tobago (22 percent), Russia (18 percent), Ukraine (10 percent), and Indonesia (7 percent) accounted for 57 percent of the world total. The largest importing regions were North America with 36 percent of the total followed by Western Europe with 23 percent and Asia with 22 percent (International Fertilizer Industry Association, 2003b, p. 5L-11). In 2002, world urea production was 51.4 Mt of contained nitrogen, and exports were 12.0 Mt of contained nitrogen. China and India, which were the two largest producing countries, accounted for 48 percent of world production. The United States and Canada produced about 10 percent of the total. Russia and Ukraine together accounted for 28 percent of total urea exports; Central America and South America, 27 percent; and Asia, North America, and Western Europe, 10 percent each. North America accounted for 36 percent of the total urea imports; Western Europe, 23 percent; and Asia, 22 percent (International Fertilizer Industry Association, 2003f, p. 1-15). Ammonia production capacity in North America and Western Europe is projected to decline through 2004, and capacity in other world regions is projected to increase. Fluctuating natural gas prices are mainly responsible for the capacity decline in North America. Ammonia production capacity is continuing to shift to world regions that have abundant sources of natural gas, and away from those where costs (raw material, labor, environmental compliance) are higher.

Open-File Report↗

USGS2005

Determination of total mercury in biological and geological samples

The analytical chemist is faced with several challenges when determining mercury in biological and geological materials. These challenges include widespread mercury contamination, both in the laboratory and the environment, possible losses of mercury during sample preparation and digestion, the wide range of mercury values commonly observed, ranging from the low nanogram per gram or per liter for background areas to hundreds of milligrams per kilogram in contaminated or ore-bearing areas, great matrix diversity, and sample heterogeneity1. These factors can be naturally occurring or anthropogenic, but must be addressed to provide a precise and accurate analysis. Although there are many instrumental methods available for the successful determination of mercury, no one technique will address all problems or all samples all of the time. The approach for the determination of mercury used at the U.S. Geological Survey, Crustal Imaging and Characterization Team, Denver Laboratories, utilizes a suite of complementary instrumental methods when approaching a study requiring mercury analyses. Typically, a study could require the analysis of waters, leachates or selective digestions of solids, vegetation, and biological materials such as tissue, bone, or shell, soils, rocks, sediments, coals, sludges, and(or) ashes. No one digestion or sample preparation method will be suitable for all of these matrices. The digestions typically employed at our laboratories include: (i) a closed-vessel microwave method using nitric acid and hydrogen peroxide, followed by digestion/dilution with a nitric acid/sodium dichromate solution, (ii) a robotic open test-tube digestion with nitric acid and sodium dichromate, (iii) a sealed Teflon? vessel with nitric acid and sodium dichromate, (iv) a sealed glass bottle with nitric acid and sodium dichromate, or (v) open test tube digestion with nitric and sulfuric acids and vanadium pentoxide. The common factor in all these digestions is that they are very oxidative to ensure the conversion of all mercury forms into Hg (II). Each method of digestion has its advantages and limitations. The method of detection used in our laboratories involves a combination of an in-house, custom, classic continuous-flow cold-vapor atomic absorption spectrometry (CVAAS), a commercially available, automated, flow-injection and a continuous flow cold-vapor atomic fluorescence spectrometry (CV-AFS) systems, and a relatively new, automated and integrated approach where solid or liquid samples are thermally decomposed under an oxygen atmosphere (a nitrogen atmosphere is used for coals) and the released mercury vapor trapped onto a gold gauze and then thermally released into an AAS system. Other less frequently used instrumental methods available for the determination of mercury include inductively coupled plasma ? optical emission spectrometry (ICP-OES), inductively couple plasma ? mass spectrometry (ICP-MS) (both solution nebulization and laser ablation), and instrumental neutron activation analysis (INAA). Results from two case studies involving the determination of mercury in the challenging matrices of biological materials will be presented. These will include fillet, liver and stomach-content samples from grayling for a baseline/background study in Alaska, and samples of meat tissue and shell material from Tanner crabs from Glacier Bay, Alaska. These studies show that the method of digestion is more important than a very sensitive detection limit for mercury.

Open-File Report↗

USGS2006

Ground-Water Levels in Huron County, Michigan, 2004-05

In 1990, the U.S. Geological Survey (USGS) completed a study of the hydrogeology of Huron County, Michigan (Sweat, 1991). In 1993, Huron County and the USGS entered into a continuing agreement to measure water levels at selected wells throughout Huron County. As part of the agreement, USGS has operated four continuous water-level recorders, installed from 1988 to 1991 on wells in Bingham, Fairhaven, Grant, and Lake Townships (fig. 1) and summarized the data collected in an annual or bi-annual report. The agreement was altered in 2003, and beginning January 1, 2004, only the wells in Fairhaven and Lake Townships retained continuous waterlevel recorders, while the wells in Grant and Bingham Townships reverted primarily to periodic or quarterly measurement status. USGS also has provided training for County or Huron Conservation District personnel to measure the water level, on a quarterly basis, in 25 wells. USGS personnel regularly accompany County or Huron Conservation District personnel to provide a quality assurance/quality control check of all measurements being made. Water-level data collected from the 25 periodically or quarterly-measured wells is summarized in an annual or bi-annual report. In 1998, the USGS also completed a temporal and spatial analysis of the monitoring well network in Huron County (Holtschlag and Sweat, 1998). The altitude of Lake Huron and precipitation are good indicators of general climatic conditions and, therefore, provide an environmental context for ground-water levels in Huron County. Figure 2 shows the mean-monthly water-level altitude of Lake Huron, averaged from measurements made by the U.S. Army Corps of Engineers at sites near Essexville or Harbor Beach, or both (National Oceanic and Atmospheric Administration, 2003-05), and monthly precipitation measured in Bad Axe (National Oceanic and Atmospheric Administration, 2003-05). In March 2003, a new low-water level for the period from 1991 through 2005 was measured in Lake Huron. There was almost no net change in the water level of Lake Huron from January 2004 through December 2005. In 2004, annual precipitation measured in Port Hope was about 3.7 inches above normal, but precipitation measured in Bad Axe was about 1.4 inches below normal. About 14.5 inches of precipitation was measured in Bad Axe during the 2004 summer growing season (May through August), which is about the same as was measured in Port Hope during the same period. Provisional precipitation totals for 2005 were 30.7 inches for January through November in Port Hope, and about 31.7 inches for the year in Bad Axe. About 10.6 inches of precipitation was measured in Bad Axe during the 2005 summer growing season, which is about 0.2 inches more than was recorded at Port Hope during the same period. Two wells equipped with continuous-data recorders are completed in the Saginaw and Marshall aquifers in Fairhaven and Lake Townships, respectively. From January 2004 through December 2005, the net rise in the water level in the Fairhaven Township well was 0.71 ft, and the net rise in the Lake Township well was 0.98 ft. The Fairhaven Township well is drilled adjacent to Saginaw Bay (Lake Huron), and, as previously noted, there was almost no net change in the water level in Saginaw Bay over the same period. Hydrographs showing water levels are presented for the two wells equipped with continuous-data recorders. Continuous-data recorders were discontinued in the Grant and Bingham Township wells at the end of 2003 due to budget constraints. The decision of which two wells to discontinue was based on an analysis of the intrinsic value to Huron County of data from each well. The Grant Township well was selected for periodic or quarterly measurement at that time because it is completed in the glacial aquifer, which is little used for drinking water purposes or absent in much of Huron County. The Bingham Township well, which is completed in the Marshall aquifer, was selected for periodic or quarterly measurement because water levels in the well are often perturbed as a result of pumpage from nearby production wells and do not reflect baseline conditions within the aquifer. Twenty five wells were measured on a periodic or quarterly basis in 2004-05. These wells are completed in the glacial, Saginaw, and Marshall aquifers, and the Coldwater confining unit. Although each quarterly measurement only provides a “snapshot” water level (measured in feet below land surface), the data adequately define the generalized water-level trend in the aquifer near the well. Water levels in 15 quarterlymeasured wells had a net rise ranging from 0.20 to 1.31 ft for the period from January 2004 to December 2005, while water levels in 10 of the wells had a net decline ranging from 0.07 to 0.99 ft over the same period (fig. 3; table 1). Period-of-record (the time period when water levels have been measured by U.S. Geological Survey or their cooperators) minimum depths to water (high-water levels) were measured in March 2004 in two quarterly-measured wells completed in the Marshall aquifer in Lake and Hume Townships. Period-of-record maximum depths to water were measured in September 2005 in three wells completed in the Marshall aquifer near Bad Axe. Water levels in those three wells recovered about 3 to 5 ft between September and December 2005. No period-of-record minimum or maximum depths to water were measured for the period from January 2004 through December 2005 in wells completed in either the glacial and Saginaw aquifers, or the Coldwater confining unit. Hydrographs showing water levels measured in each well are presented for the 25 wells measured on a quarterly basis. Water-level trends measured for the period from January 2004 through December 2005 in other wells in Lower Michigan have similarities to those measured in Huron County wells. Several external factors influence water-level trends including proximity to nearby production wells, amount and timing of precipitation events, evapotranspiration and type of prevalent ground cover, proximity of aquifer to the surface, and hydraulic characteristics of overlying geologic materials.

Michigan↗

USGS2008

Ground-water levels in Huron County, Michigan, 2002-03

In 1990, the U.S. Geological Survey (USGS) completed a study of the hydrogeology of Huron County, Michigan (Sweat, 1991). In 1993, Huron County and the USGS entered into a continuing agreement to collect water-level altitudes (hereafter referred to as water levels) at selected wells throughout Huron County. As part of the agreement, USGS has operated four continuous water-level recorders, installed from 1988 to 1991 on wells in Bingham, Fairhaven, Grant, and Lake Townships (fig. 1) and summarized the data collected in an annual or bi-annual report. The agreement was altered in 2003, and beginning January 1, 2004, only the wells in Fairhaven and Lake Townships will have continuous water-level recorders, while the wells in Grant and Bingham Townships will revert to quarterly measurement status. USGS has also provided training for County or Huron Conservation District personnel to measure the water level, on a quarterly basis, in 23 wells. USGS personnel regularly accompany County or Huron Conservation District personnel to provide a quality assurance/quality control check of all measurements being made. Water-level data collected from the 23 quarterly-measured wells is also summarized in the annual or bi-annual report. In 1998, the USGS also completed a temporal and spatial analysis of the monitoring well network in Huron County (Holtschlag and Sweat, 1998). The altitude of Lake Huron and precipitation are good indicators of general climatic conditions and, therefore, provide an environmental context for groundwater levels in Huron County. Figure 2 shows the mean-monthly water-level altitude of Lake Huron, averaged from measurements made by the U.S. Army Corps of Engineers at sites near Essexville and Harbor Beach, and monthly precipitation measured in Bad Axe (National Oceanic and Atmospheric Administration [NOAA], 2002-04; Danny Costello, NOAA hydrologist, written commun., 2003-04). In March 2003, a new low-water level for the period of this study was measured in Lake Huron (National Oceanic and Atmospheric Administration, 2003; 2004). The net decline in the water level of Lake Huron from January 1, 2002 to December 31, 2003 was about 0.3 ft. Annual precipitation in 2002 was about 0.3 inches above normal, with much of it occurring during summer months. The provisional precipitation total for 2003 is about an inch below normal (NOAA, 2003, 2004; Danny Costello, NOAA hydrologist, written commun., 2003, 2004). Four wells equipped with continuous-data recorders are completed in the glacial, Saginaw, and Marshall aquifers. Water levels in three of the four wells equipped with continuous-data recorders experienced a net decline over the period from January 2002 to December 2003, while the level in well H9r, completed in the Saginaw aquifer in Fairhaven Township adjacent to Saginaw Bay (Lake Huron), rose about 1.3 ft over the same period. Interestingly, the water level in Saginaw Bay declined about 0.3 ft over the same period. A period-ofrecord maximum depth to water was recorded in September 2003 in well H25Ar, completed in the Marshall aquifer in Lake Township. Hydrographs showing altitude of the water surface are presented for each of four wells equipped with continuous-data recorders. Twenty three wells were measured on a quarterly basis in 2002-03. These wells are completed in the Saginaw and Marshall aquifers, and Coldwater confining unit. Although each quarterly measurement only provides a “snapshot” water level, the data adequately define the “generalized” water-level trend in the aquifer near the well. The water level in one quarterly-measured well completed in the Saginaw aquifer near Saginaw Bay, had a net rise for the period from January 2002 to December 2003, while levels in the other 22 quarterly-measured wells declined about 0.5 to 2.0 ft during the same period. A period-of-record minimum depth to water (high) was measured in 2002 in two quarterly-measured wells completed in the Saginaw aquifer, although the level in one of those wells had a net decline over the period from January 2002 through December 2003. Conversely, period-of-record maximum depths to water (low) were measured in 2002 in one well completed in the Saginaw aquifer and two wells completed in the Marshall aquifer; and in 2003, in 6 of 16 wells completed in the Marshall aquifer. Near period-ofrecord maximum depths to water were measured in 2003 in two additional wells completed in the Marshall aquifer. No period-of-record minimum or maximum depths to water were measured in 2002-03 in wells completed in the Coldwater confining unit. Hydrographs showing water levels measured in each well are presented for the 23 wells measured on a quarterly basis. Water-level trends measured in 2002-03 in other wells in Lower Michigan have similarities to those measured in Huron County wells. Several external factors appear to influence water-level trends including proximity to nearby production wells, amount and timing of precipitation events, evapotranspiration and type of prevalent ground cover, proximity of aquifer to the surface, and hydraulic characteristics of overlying geologic materials.

Michigan↗

USGS2006

Ground-water levels in Huron County, Michigan, 2004-05

Michigan↗

USGS2007

Analysis of continuous GPS measurements from southern Victoria Land, Antarctica

Several years of continuous data have been collected at remote bedrock Global Positioning System (GPS) sites in southern Victoria Land, Antarctica. Annual to sub-annual variations are observed in the position time-series. An atmospheric pressure loading (APL) effect is calculated from pressure field anomalies supplied by the European Centre for Medium-Range Weather Forecasts (ECMWF) model loading an elastic Earth model. The predicted APL signal has a moderate correlation with the vertical position time-series at McMurdo, Ross Island (International Global Navigation Satellite System Service (IGS) station MCM4), produced using a global solution. In contrast, a local solution in which MCM4 is the fiducial site generates a vertical time series for a remote site in Victoria Land (Cape Roberts, ROB4) which exhibits a low, inverse correlation with the predicted atmospheric pressure loading signal. If, in the future, known and well modeled geophysical loads can be separated from the time-series, then local hydrological loading, of interest for glaciological and climate applications, can potentially be extracted from the GPS time-series.

Open-File Report↗

USGS2007

Debris flows and record floods from extreme mesoscale convective thunderstorms over the Santa Catalina Mountains, Arizona

Ample geologic evidence indicates early Holocene and Pleistocene debris flows from the south side of the Santa Catalina Mountains north of Tucson, Arizona, but few records document historical events. On July 31, 2006, an unusual set of atmospheric conditions aligned to produce record floods and an unprecedented number of debris flows in the Santa Catalinas. During the week prior to the event, an upper-level area of low pressure centered near Albuquerque, New Mexico generated widespread heavy rainfall in southern Arizona. After midnight on July 31, a strong complex of thunderstorms developed over central Arizona in a deformation zone that formed on the back side of the upper-level low. High atmospheric moisture (2.00' of precipitable water) coupled with cooling aloft spawned a mesoscale thunderstorm complex that moved southeast into the Tucson basin. A 15-20 knot low-level southwesterly wind developed with a significant upslope component over the south face of the Santa Catalina Mountains advecting moist and unstable air into the merging storms. National Weather Service radar indicated that a swath of 3-6' of rainfall occurred over the lower and middle elevations of the southern Santa Catalina Mountains. This intense rain falling on saturated soil triggered over 250 hillslope failures and debris flows throughout the mountain range. Sabino Canyon, a heavily used recreation area administered by the U.S. Forest Service, was the epicenter of mass wasting, where at least 18 debris flows removed structures, destroyed the roadway in multiple locations, and closed public access for months. The debris flows were followed by streamflow floods which eclipsed the record discharge in the 75-year gaging record of Sabino Creek. In five canyons adjacent to Sabino Canyon, debris flows approached or excited the mountain front, compromising floow conveyance structures and flooding some homes.

Arizona↗

USGS2008

Ground-water levels in Huron County, Michigan, 2006-07

In 1990, the U.S. Geological Survey (USGS) completed a study of the hydrogeology of Huron County, Michigan (Sweat, 1991). In 1993, Huron County and the USGS entered into a continuing agreement to measure water levels at selected wells throughout Huron County. As part of the agreement, USGS initially operated four continuous water-level recorders, installed from 1988 to 1991 on wells in Bingham (H5r), Fairhaven (H9r), Grant (H2r), and Lake Townships (H25Ar) and summarized the data collected in an annual or bi-annual report (fig. 1). The agreement was altered in 2003, and beginning January 1, 2004, only wells H9r and H25Ar retained continuous water-level recorders, while wells H2r and H5r reverted to quarterly or periodic measurement status due to budget constraints. The decision of which two wells to discontinue was based on an analysis of the intrinsic value to Huron County of data from each well. Well H2r was selected for periodic measurement at that time because it is completed in the glacial aquifer, which is absent in much of Huron County and well H5r, which is completed in the Marshall aquifer, was selected because the water level in the well is often perturbed as a result of pumpage from nearby production wells and does not always reflect baseline conditions within the aquifer. USGS also has provided training for County or Huron Conservation District personnel to measure the water level in 24 of the wells on a quarterly basis. USGS personnel accompany County or Huron Conservation District personnel on a semi-annual basis to provide a quality assurance/quality control check of all measurements being made. Water-level data collected from the wells is summarized in an annual or bi-annual report. The altitude of Lake Huron and precipitation are good indicators of general climatic conditions and, therefore, provide an environmental context for groundwater levels in Huron County. Figure 2 shows the meanmonthly water-level altitude of Lake Huron, averaged from measurements made at Essexville and Harbor Beach (National Oceanic and Atmospheric Administration, 2008), and monthly precipitation measured in Harbor Beach, Sebewaing, and Bad Axe (National Oceanic and Atmospheric Administration, Danny Costello, written commun., 2007-08). In December 2007, the water level in Lake Huron dropped to a new monthly mean low of 576.38 ft for the period from 1988 through 2007 (the previous lowwater level of 576.57 ft was measured in March 2003). The net decline in the water level of Lake Huron from January 2006 through December 2007 was 0.68 ft. In 2006, annual precipitation measured at Harbor Beach was 3.2 in. above the long-term average of 31.1 in., with 10.6 in. measured during the 2006 growing season (May through August). In 2007, annual precipitation measured at Harbor Beach was 1.4 in. below normal, with 9.7 in. measured during the growing season. In the two wells equipped with continuous waterlevel recorders, the water level rose 0.32 ft from January 1, 2006 to December 31, 2007 in well H9r, but declined 1.11 ft in well H25Ar. Curiously, well H9r is drilled adjacent to Saginaw Bay (Lake Huron), and, as previously noted, there was a 0.68 ft decline in the water level in Saginaw Bay during that period. Twenty four wells were measured on a quarterly or periodic basis from December 2005 through December 2007 (well H26 was destroyed during summer 2007 reducing the total number of wells from 25). These wells are completed in the glacial, Saginaw and Marshall aquifers, and the Coldwater confining unit. Although each quarterly or periodic measurement only provides a “snapshot” water level (measured in ft below land surface, and altitude, in ft above sea level), the data adequately define the generalized water-level trend in the aquifer near the well. Water levels in 6 quarterly-measured wells had net rises ranging from 0.09 to 1.45 ft for the period, while water levels in 18 of the wells had net declines ranging from 0.26 to 2.19 ft (tables 1 and 2; fig. 3). Period-of-record (the time period during which water levels have been measured by U.S. Geological Survey or their cooperators) minimum depths to water (high-water levels) were measured in March and December 2006 in two quarterly-measured wells completed in the Saginaw aquifer in Oliver and Sebewaing Townships, respectively. A period-of-record minimum depth to water was also recorded June 5, 2007 in well H9r, completed in the Michigan Formation/Marshall aquifer in Fairhaven Township. Period-of-record maximum depths to water were measured in September 2007 in two wells completed in the Marshall aquifer in Oliver and Dwight Townships. Notably, water levels in those two wells recovered about 1 to 3 ft between September and December 2007. No period-of-record minimum or maximum depths to water were measured in wells completed in either the glacial aquifer or the Coldwater confining unit from December 2005 through December 2007. Several external factors influence water-level trends including proximity to nearby production wells, amount and timing of precipitation events, evapotranspiration and type of prevalent ground cover, proximity of aquifer to the surface, and hydraulic characteristics of overlying geologic materials.

Michigan↗

USGS2008

Mercury Deposition Network Site Operator Training for the System Blank and Blind Audit Programs

The U.S. Geological Survey operates the external quality assurance project for the National Atmospheric Deposition Program/Mercury Deposition Network. The project includes the system blank and blind audit programs for assessment of total mercury concentration data quality for wet-deposition samples. This presentation was prepared to train new site operators and to refresh experienced site operators to successfully process and submit system blank and blind audit samples for chemical analysis. Analytical results are used to estimate chemical stability and contamination levels of National Atmospheric Deposition Program/Mercury Deposition Network samples and to evaluate laboratory variability and bias.

Open-File Report↗

USGS2011

Loch Vale watershed long-term ecological research and monitoring program quality assurance report, 2003-09

The Loch Vale watershed project is a long-term research and monitoring program located in Rocky Mountain National Park that addresses watershed-scale ecosystem processes, particularly as they respond to atmospheric deposition and climate variability. Measurements of precipitation depth, precipitation chemistry, discharge, and surface-water quality are made within the watershed and elsewhere in Rocky Mountain National Park. As data collected for the program are used by resource managers, scientists, policy makers, and students, it is important that all data collected in Loch Vale watershed meet high standards of quality. In this report, data quality was evaluated for precipitation, discharge, and surface-water chemistry measurements collected during 2003-09. Equipment upgrades were made at the Loch Vale National Atmospheric Deposition Program monitoring site to improve precipitation measurements and evaluate variability in precipitation depth and chemistry. Additional solar panels and batteries have been installed to improve the power supply, and data completeness, at the NADP site. As a result of equipment malfunction, discharge data for the Loch Outlet were estimated from October 18, 2005, to August 17, 2006. Quality-assurance results indicate that more than 98 percent of all surface-water chemistry measurements were accurate and precise. Records that did not meet quality criteria were removed from the database. Measurements of precipitation depth, precipitation chemistry, discharge, and surface-water quality were all sufficiently complete and consistent to support project data needs.

Colorado↗