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Water-Quality Characterization of Surface Water in the Onondaga Lake Basin, Onondaga County, New York, 2005-08

Water-resources managers in Onondaga County, N.Y., have been faced with the challenge of improving the water-quality of Onondaga Lake. To assist in this endeavor, the U.S. Geological Survey undertook a 3-year basinwide study to assess the water quality of surface water in the Onondaga Lake Basin. The study quantified the relative contributions of nonpoint sources associated with the major land uses in the basin and also focused on known sources (streams with large sediment loads) and presumed sinks (Onondaga Reservoir and Otisco Lake) of sediment and nutrient loads, which previously had not been evaluated. Water samples were collected and analyzed for nutrients and suspended sediment at 26 surface-water sites and 4 springs in the 285-square-mile Onondaga Lake Basin from October 2005 through December 2008. More than 1,060 base-flow, stormflow, snowmelt, spring-water, and quality-assurance samples collected during the study were analyzed for ammonia, nitrite, nitrate-plus-nitrite, ammonia-plus-organic nitrogen, orthophosphate, phosphorus, and suspended sediment. The concentration of total suspended solids was measured in selected samples. Ninety-one additional samples were collected, including 80 samples from 4 county-operated sites, which were analyzed for suspended sediment or total suspended solids, and 8 precipitation and 3 snowpack samples, which were analyzed for nutrients. Specific conductance, salinity, dissolved oxygen, and water temperature were periodically measured in the field. The mean concentrations of selected constituents in base-flow, stormflow, and snowmelt samples were related to the land use or land cover that either dominated the basin or had a substantial effect on the water quality of the basin. Almost 40 percent of the Onondaga Lake Basin is forested, 30 percent is in agricultural uses, and almost 21 percent, including the city of Syracuse, is in developed uses. The data indicated expected relative differences among the land types for concentrations of nitrate, ammonia-plus-organic nitrogen, and orthophosphate. The data departed from the expected relations for concentrations of phosphorus and suspended sediment, and plausible explanations for these departures were posited. Snowmelt concentrations of dissolved constituents generally were greater and those of particulate constituents were less than concentrations of these constituents in storm runoff. Presumably, the snowpack acted as a short-term sink for dissolved constituents that had accumulated from atmospheric deposition, and streambed erosion and resuspension of previously deposited material, rather than land-surface erosion, were the primary sources of particulate constituents in snowmelt flows. Longitudinal assessments documented the changes in the median concentrations of constituents in base flows and event flows (combined stormflow and snowmelt) from upstream to downstream monitoring sites along the two major tributaries to Onondaga Lake - Onondaga Creek and Ninemile Creek. Median base-flow concentrations of ammonia and phosphorus and event concentrations of ammonia increased in the downstream direction in both streams. Whereas median event concentrations of other constituents in Onondaga Creek displayed no consistent trends, concentrations of ammonia-plus-organic nitrogen, orthophosphate, phosphorus, and suspended sediment in Ninemile Creek decreased from upstream to downstream sites. Springs discharging from the Onondaga and Bertie Limestone had measureable effects on water temperatures in the receiving streams and increased salinity and values of specific conductance in base flows. Loads of selected nutrients and suspended sediment transported in three tributaries of Otisco Lake were compared with loads from 1981-83. Loads of ammonia-plus-organic nitrogen and orthophosphate decreased from 1981-83 to 2005-08, but those of nitrate-plus-nitrite, phosphorus, and suspended sediment increased. The largest load increase was for suspende

Scientific Investigations Report↗

Simulation of groundwater conditions and streamflow depletion to evaluate water availability in a Freeport, Maine, watershed

In order to evaluate water availability in the State of Maine, the U.S. Geological Survey (USGS) and the Maine Geological Survey began a cooperative investigation to provide the first rigorous evaluation of watersheds deemed "at risk" because of the combination of instream flow requirements and proportionally large water withdrawals. The study area for this investigation includes the Harvey and Merrill Brook watersheds and the Freeport aquifer in the towns of Freeport, Pownal, and Yarmouth, Maine. A numerical groundwater- flow model was used to evaluate groundwater withdrawals, groundwater-surface-water interactions, and the effect of water-management practices on streamflow. The water budget illustrates the effect that groundwater withdrawals have on streamflow and the movement of water within the system. Streamflow measurements were made following standard USGS techniques, from May through September 2009 at one site in the Merrill Brook watershed and four sites in the Harvey Brook watershed. A record-extension technique was applied to estimate long-term monthly streamflows at each of the five sites. The conceptual model of the groundwater system consists of a deep, confined aquifer (the Freeport aquifer) in a buried valley that trends through the middle of the study area, covered by a discontinuous confining unit, and topped by a thin upper saturated zone that is a mixture of sandy units, till, and weathered clay. Harvey and Merrill Brooks flow southward through the study area, and receive groundwater discharge from the upper saturated zone and from the deep aquifer through previously unknown discontinuities in the confining unit. The Freeport aquifer gets most of its recharge from local seepage around the edges of the confining unit, the remainder is received as inflow from the north within the buried valley. Groundwater withdrawals from the Freeport aquifer in the study area were obtained from the local water utility and estimated for other categories. Overall, the public-supply withdrawals (105.5 million gallons per year (Mgal/yr)) were much greater than those for any other category, being almost 7 times greater than all domestic well withdrawals (15.3 Mgal/yr). Industrial withdrawals in the study area (2.0 Mgal/yr) are mostly by a company that withdraws from an aquifer at the edge of the Merrill Brook watershed. Commercial withdrawals are very small (1.0 Mgal/yr), and no irrigation or other agricultural withdrawals were identified in this study area. A three-dimensional, steady-state groundwater-flow model was developed to evaluate stream-aquifer interactions and streamflow depletion from pumping, to help refine the conceptual model, and to predict changes in streamflow resulting from changes in pumping and recharge. Groundwater levels and flow in the Freeport aquifer study area were simulated with the three-dimensional, finite-difference groundwater-flow modeling code, MODFLOW-2005. Study area hydrology was simulated with a 3-layer model, under steady-state conditions. The groundwater model was used to evaluate changes that could occur in the water budgets of three parts of the local hydrologic system (the Harvey Brook watershed, the Merrill Brook watershed, and the buried aquifer from which pumping occurs) under several different climatic and pumping scenarios. The scenarios were (1) no pumping well withdrawals; (2) current (2009) pumping, but simulated drought conditions (20-percent reduction in recharge); (3) current (2009) recharge, but a 50-percent increase in pumping well withdrawals for public supply; and (4) drought conditions and increased pumping combined. In simulated drought situations, the overall recharge to the buried valley is about 15 percent less and the total amount of streamflow in the model area is reduced by about 19 percent. Without pumping, infiltration to the buried valley aquifer around the confining unit decreased by a small amount (0.05 million gallons per day (Mgal/d)), and discharge to the streams increased by about 8 percent (0.3 Mgal/d). A 50-percent increase in pumping resulted in a simulated decrease in streamflow discharge of about 4 percent (0.14 Mgal/d). Streamflow depletion in Harvey Brook was evaluated by use of the numerical groundwater-flow model and an analytical model. The analytical model estimated negligible depletion from Harvey Brook under current (2009) pumping conditions, whereas the numerical model estimated that flow to Harvey Brook decreased 0.38 cubic feet per second (ft 3 /s) because of the pumping well withdrawals. A sensitivity analysis of the analytical model method showed that conducting a cursory evaluation using an analytical model of streamflow depletion using available information may result in a very wide range in results, depending on how well the hydraulic conductivity variables and aquifer geometry of the system are known, and how well the aquifer fits the assumptions of the model. Using the analytical model to evaluate the streamflow depletion with an incomplete understanding of the hydrologic system gave results that seem unlikely to reflect actual streamflow depletion in the Freeport aquifer study area. In contrast, the groundwater-flow model was a more robust method of evaluating the amount of streamflow depletion that results from withdrawals in the Freeport aquifer, and could be used to evaluate streamflow depletion in both streams. Simulations of streamflow without pumping for each measurement site were compared to the calibratedmodel streamflow (with pumping), the difference in the total being streamflow depletion. Simulations without pumping resulted in a simulated increase in the steady-state flow rate of 0.38 ft 3 /s in Harvey Brook and 0.01 ft 3 /s in Merrill Brook. This translates into a streamflow-depletion amount equal to about 8.5 percent of the steady-state base flow in Harvey Brook, and an unmeasurable amount of depletion in Merrill Brook. If pumping was increased by 50 percent and recharge reduced by 20 percent, the amount of streamflow depletion in Harvey Brook could reach 1.41 ft 3 /s.

Maine↗

Water-level fluctuations and water temperature effects on young-of-year Largemouth Bass in a southwest irrigation reservoir

The effects of a warming climate will alter the hydrological cycles of arid southwestern U.S. reservoirs which primarily support agricultural needs, provide flood control, and generate hydroelectric power while secondarily supporting fish communities and sport fishing opportunities. The success of littoral spawning fishes depends on the timing and variability of water levels. The onset of drought between 2017 and 2018 provided an opportunity to evaluate the timing of hatch dates and relative abundance of young-of-year Largemouth Bass Micropterus salmoides across two water years of varying water temperatures and water levels in a southwestern U.S. reservoir. A retrospective analysis of otoliths in young-of-year Largemouth Bass revealed similar hatch dates in 2017 (14 April–29 May) and 2018 (13 April–28 May) despite differences in water temperature and water level rate of change. Median water temperature during hatch dates was greater in 2017 (median 19.0°C, range 14.3–24.4°C) than 2018 (17.6°C, range 13.5–21.7°C). Water level rate of change during hatch dates in 2017 was positive (+3.1 to +13.1 cm/d), which reflected reservoir filling. In contrast, water level rate of change during hatch dates in 2018 was negative (−8.5 to −0.6 cm/d), which reflected reservoir receding. Relative abundance of young-of-year fish was greater in 2017 (21.7 fish/h) when the reservoir was filling compared with relative abundance in 2018 (6.8 fish/h) when the reservoir was receding. The median growth rate was greater in 2017 (1.02 mm/d) when the reservoir was filling than in 2018 (0.82 mm/d) when the reservoir was receding. Despite differences in water temperature and contrasting reservoir levels between the two water years, the Largemouth Bass population in a southwest U.S. reservoir exhibited similar hatch dates reported for the species in southeastern and northeastern U.S. reservoirs. While water demand in the 21st century may exceed availability, the opportunity exists to collaborate with water managers to benefit Largemouth Bass populations in southwestern reservoirs.

New Mexico↗

Geohydrology and water quality of the unconsolidated aquifers in the Enfield Creek Valley, town of Enfield, Tompkins County, New York

From 2013 to 2018, the U.S. Geological Survey, in cooperation with the Town of Enfield and the Tompkins County Planning Department, studied the unconsolidated aquifer in the Enfield Creek Valley in the town of Enfield, Tompkins County, New York. The valley will likely undergo future development as the population of Tompkins County increases and spreads out from the metropolitan areas. The Town of Enfield, Tompkins County, and the New York State Departments of Health and Environmental Conservation need geohydrologic information to help planners develop a more comprehensive approach to water-resource management in Tompkins County. The Enfield Creek Valley is underlain by an unconfined aquifer that consists of saturated alluvium, alluvial-fan deposits, and ice-contact (kame) sand and gravel. A confined aquifer of discontinuous ice-contact sand and gravel overlies bedrock. Depth to bedrock in the valley ranges from about 50 feet below land surface from just north of the Enfield Creek divide in the northern part of the aquifer to the confluence of Fivemile Creek to at least 140 feet below land surface from Fivemile Creek to where the valley orientation changes from north-south to northwest-southeast. Depth to bedrock is much shallower from the valley orientation change to the southeastern part of the aquifer because Enfield Creek has carved through overlying sediments into bedrock as the creek drops 450 feet into the Cayuga Inlet Valley. A small buried valley running south to north was identified within the Fivemile Creek drainage along the western edge of the town. However, the valley fill consists of glacial till, and no sand-and-gravel aquifer is present. The unconfined aquifers are recharged by direct infiltration of precipitation, surface runoff, and shallow subsurface flow from hillsides, and by seepage loss from streams overlying the aquifer. The confined aquifers are recharged mostly by precipitation that enters the adjacent valley walls, by groundwater flowing from bordering till or bedrock, and by flow from the bottom of the valley. Also, some recharge may be occurring where confining units are absent or from confining units with sediments of moderate permeability. Groundwater discharges to Enfield Creek, its tributaries, and wetlands and is lost through evapotranspiration from the water table or is withdrawn from domestic, commercial, and agricultural wells. About 700 individual well owners depend on the unconsolidated aquifers for their water supply. An estimated 28,300,000 gallons per year are withdrawn. Groundwater samples were collected from eight test wells drilled for this study, and six surface-water samples were collected from five locations on Enfield Creek. Of the eight wells sampled, two were finished in unconfined sand-and-gravel aquifers, two were finished in confined sand-and-gravel aquifers, and four were finished at or near the shale bedrock surface. Water quality in the study area generally met State and Federal drinking-water standards. However, some samples exceeded maximum contaminant levels for barium (25 percent of samples) and secondary maximum containment levels for chloride (25 percent), dissolved solids (25 percent of samples), iron (70 percent of samples), and manganese (75 percent of samples). Groundwater from 75 percent of the wells sampled for methane had concentrations greater than the Office of Surface Mining Reclamation and Enforcement recommended action level of 10 to 28 milligrams per liter. The two deepest wells sampled, TM1075 and TM1077, had the highest specific conductance, chloride, and sodium concentrations of all wells sampled. The chloride/bromide ratios of these samples suggest the source may represent a mixture of saline formation waters with shallow dilute groundwater and may receive recharge contribution from two tributaries overlying bedrock to the west and southwest of the aquifer. In general, the highest yields are from wells completed within about 50 feet below land surface, which may tap either type of aquifer.

New York↗

Interim report on the scientific investigations in the Animas River watershed, Colorado to facilitate remediation decisions by the U.S. Bureau of Land Management and the U.S. Forest Service, March 29, 2000 meeting, Denver, Colo.

INTRODUCTION The joint U.S. Department of the Interior and U.S. Department of Agriculture Abandoned Mine Lands Initiative (AMLI) was developed as a collaborative effort between the Federal land management agencies (FLMA, that is the U.S. Bureau of Land Management and the U.S. Forest Service) and the U.S. Geological Survey (USGS) in 1996. The stated goal of the AML Initiative was to develop a strategy for gathering and communicating the scientific information needed to develop effective and cost-efficient remediation of abandoned mines within the framework of a watershed. Four primary objectives of the AMLI are to: 1. Provide the scientific information needed (in the short-term) by the FLMAs to make decisions related to the design and implementation of cleanup actions, 2. Develop a multi-disciplined, multi-division approach that integrates geologic, hydrologic, geochemical and ecological information into a knowledge base for sound decision making, 3. Transfer technologies developed within the scientific programs of the USGS to the field and demonstrate their suitability to solve real, practical problems, and 4. Establish working relationships among involved members of land management and regulatory agencies within the framework of a watershed approach to the cleanup of abandoned mines. Long-term process-based research, including development of analytical tools, is recognized as being critical to the long-term success in remediating watersheds impacted by historical mining activities (AML 5-year plan, http://amli.usgs.gov/amli). In a meeting of Federal agencies (U.S. Bureau of Land Management [BLM], U.S. Bureau of Reclamation [BOR], U.S. National Park Service [NPS], U.S. Forest Service [USFS], the U.S. Environmental Protection Agency [EPA], the U.S. Fish and Wildlife Service [F&WS]), and State agencies (Colorado Division of Public Health and Environment, Colorado Division of Mines and Geology), several watersheds were examined within the state whose water quality was presumed to be impacted by historical mining activities. The Animas River watershed (fig. 1) was selected by the State and Federal agencies as one of two watersheds in the U.S. to be studied in detail by the USGS in the AML Initiative. Beginning in October 1997, each of the four Divisions of the USGS (Water Resources, Geologic, Biological Resources, and National Mapping) initiated a collaborative integrated science study of the watershed. Funds were provided from USGS base funding to each of the four Divisions in response to the priorities set by Congressional action and within the flexibility provided by the budgetary framework funding individual research programs. The AML Initiative provides for a five-year focused scientific effort in the two watersheds with final synthesis of the scientific results from each to be published in 2001. Publications are released on the AML web site on a regular basis (http://amli.usgs.gov/amli). On March 29, 2000, the USGS hosted a meeting for the BLM and USFS to discuss remediation options that were under consideration for the summer of 2000. The purpose of this report is to provide an overview of the scientific rational provided by the USGS to meet objective one above, and to summarize our preliminary interpretations of our data. Additional information from sites on private lands have been collected by the State of Colorado, EPA, and the ARSG. Unfortunately, these data have not been fully supplied to the USGS so our conclusions are based only upon our data. These interpretations provide science-based constraints on possible remediation options to be considered by the FLMA, the State, and local property owners in the Animas River watershed. The report is presented in outline format to facilitate discussion of remediation options at the March 29, 2000 meeting. Not all historical mining sites within the watershed are on public lands. This should not be construed to be a final report of the USGS

Denver↗

The impact of anthropogenic land-cover change on the Florida Peninsula Sea Breezes and warm season sensible weather

During the twentieth century, the natural landscape of the Florida peninsula was transformed extensively by agriculture, urbanization, and the diversion of surface water features. The purpose of this paper is to present a numerical modeling study in which the possible impacts of this transformation on the warm season climate of the region were investigated. For three separate July–August periods (1973, 1989, and 1994), a pair of simulations was performed with the Regional Atmospheric Modeling System. Within each pair, the simulations differed only in the specification of land-cover class. The two different classes were specified using highly detailed datasets that were constructed to represent pre-1900 natural land cover and 1993 land-use patterns, thus capturing the landscape transformation within each pair of simulations. When the pre-1900 natural cover was replaced with the 1993 land-use dataset, the simulated spatial patterns of the surface sensible and latent heat flux were altered significantly, resulting in changes in the structure and strength of climatologically persistent, surface-forced mesoscale circulations—particularly the afternoon sea-breeze fronts. This mechanism was associated with marked changes in the spatial distribution of convective rainfall totals over the peninsula. When averaged over the model domain, this redistribution was reflected as an overall decrease in the 2-month precipitation total. In addition, the domain average of the diurnal cycle of 2-m temperature was amplified, with a noted increase in the daytime maximum. These results were consistent among all three simulated periods, and largely unchanged when subjected to a number of model sensitivity factors. Furthermore, the model results are in reasonable agreement with an analysis of observational data that indicates decreasing regional precipitation and increasing daytime maximum temperature during the twentieth century. These results could have important implications for water resource and land-use management issues in south Florida, including efforts to restore and preserve the natural hydroclimate of the Everglades ecosystem. This study also provides more evidence for the need to consider anthropogenic land-cover change when evaluating climate trends.

Florida↗

Groundwater mining of bedrock aquifers in the Denver Basin - Past, present, and future

The Denver Basin bedrock aquifer system is an important source of water for municipal and agricultural uses in the Denver and Colorado Springs metropolitan areas. The Denver area is one of the fastest growing areas in the United States with a population of 1.2 million in 1960 that has increased to over 2.4 million by 2000. This rapid population growth has produced a corresponding increase in demand for potable water. Historically, the Denver area has relied on surface water, however, in the past 10 years new housing and recreation developments have begun to rely on groundwater from the bedrock aquifers as the surface water is fully appropriated and in short supply. The Denver Basin bedrock aquifer system consists of Tertiary and Cretaceous age sedimentary rocks known as the Dawson, Denver, Arapahoe and Laramie-Fox Hills Aquifers. The number of bedrock wells has increased from 12,000 in 1985 to 33,700 in 2001 and the withdrawal of groundwater has caused water level declines of 76 m. Water level declines for the past 10 years have ranged from 3 to 12 m per year. The groundwater supplies were once thought to last 100 years but there is concern that the groundwater supplies may be essentially depleted in 10 to 15 years in areas on the west side of the basin. Extensive development of the aquifer system has occurred in the last 25 years especially near the center of the basin in Douglas and El Paso Counties where rapid urban growth continues and surface water is lacking. Groundwater is being mined from the aquifer system because the discharge by wells exceeds the rate of recharge. Concern is mounting that increased groundwater withdrawal will cause water level declines, increased costs to withdraw groundwater, reduced well yield, and reduced groundwater storage. As the long-term sustainability of the groundwater resource is in doubt, water managers believe that the life of the Denver Basin aquifers can be extended with artificial recharge, water reuse, restrictions on lawn watering, well permit restrictions and conservation measures.

Environmental Geology↗

Legacy sediment as a potential source of orthophosphate: Preliminary conceptual and geochemical models for the Susquehanna River, Chesapeake Bay watershed, USA

Nutrient pollution from agriculture and urban areas plus acid mine drainage (AMD) from legacy coal mines are primary causes of water-quality impairment in the Susquehanna River, which is the predominant source of freshwater and nutrients entering the Chesapeake Bay. Recent increases in the delivery of dissolved orthophosphate (PO 4 ) from the river to the bay may be linked to long-term increases in pH, decreased acidity of precipitation, and decreased acidity, iron, and aluminum loading from widespread AMD. Since the 1950s, baseline pH increased from ~6.5 to ~8 in the West Branch and “North Branch” of the Susquehanna River, which drain bituminous and anthracite coalfields of Pennsylvania. A current baseline pH of ~8 and daily maxima exceeding 9 have been documented along the lower Susquehanna River. In response to improved river quality, bioavailable PO 4 now may be released into solution from legacy sediment that has filled major impoundments in lower reaches of the river. At typical pH (5–8) of natural water, aqueous PO 4 species tend to be adsorbed by hydrous iron, aluminum, and manganese oxides that coat soil and sediment particles; however, PO 4 may be substantially desorbed at pH >8. We created a geochemical model that simulates equilibrium aqueous/solid distributions of PO 4 as pH and other solution characteristics change. Considering current conditions in the lower Susquehanna River, the model demonstrates potential for extensive release of adsorbed PO 4 at pH >8. Empirical data from laboratory experiments corroborate model results. The transfer of PO 4 into the water column may increase algae growth, which removes CO 2 and drives pH to higher values, facilitating additional PO 4 release and exacerbating the potential for harmful algal blooms. Thus, legacy sediment is a currently unquantified source of PO 4 that warrants consideration by resource managers and programs collaborating to reduce phosphorus loads to the bay and similar settings worldwide.

Chesapeake Bay watershed↗

Ground Water Atlas of the United States: Segment 7, Idaho, Oregon, Washington

The States of Idaho, Oregon, and Washington, which total 248,730 square miles, compose Segment 7 of this Atlas. The area is geologically and topographically diverse and contains a wealth of scenic beauty, natural resources, and ground and surface water that generally are suitable for all uses. Most of the area of Segment 7 is drained by the Columbia River, its tributaries, and other streams that discharge to the Pacific Ocean. Exceptions are those streams that flow to closed basins in southeastern Oregon and northern Nevada and to the Great Salt Lake in northern Utah. The Columbia River is one of the largest rivers in the Nation. The downstream reach of the Columbia River forms most of the border between Oregon and Washington. In 1990, Idaho, Oregon, and Washington had populations of 1.0 million, 2.8 million, and 4.9 million, respectively. The more densely populated parts are in lowland areas and stream valleys. Many of the mountains, the deserts, and the upland areas of Idaho, Oregon, and Washington lack major population centers. Large areas of Idaho and Oregon are uninhabited and are mostly public land (fig. 1) where extensive ground-water development is restricted. Surface water is abundant in Idaho, Oregon, and Washington, though not always available when and where needed. In some places, surface water provides much of the water used for public-supply, domestic and commercial, agricultural (primarily irrigation and livestock watering), and industrial purposes. In arid parts of Segment 7, however, surface water has long been fully appropriated, chiefly for irrigation. Ground water is used when and where surface-water supplies are lacking. Ground water is commonly available to shallow wells that are completed in unconsolidated-deposit aquifers that consist primarily of sand and gravel but contain variable quantities of clay and silt. Many large-yield public-supply and irrigation wells and thousands of domestic wells are completed in these types of aquifers, generally in areas of privately owned land (fig. 1). In many places, deeper wells produce water from underlying volcanic rocks, usually basalt. Most irrigation (fig. 2) is on lowlands next to streams and on adjacent terraces. Generally, lowlands within a few miles of a main stream are irrigated with surface water diverted by gravity flow from the main stream or a reservoir and distributed through a system of canals and ditches. In some areas, water is pumped to irrigate lands farther from the stream at a higher altitude. Along the Snake and Columbia Rivers, large pumping systems withdraw billions of gallons of water per day from the rivers to irrigate adjacent uplands that are more than 500 feet higher than the rivers. Elsewhere, irrigation water is obtained from large-capacity wells, where depth to water might exceed 500 feet below land surface. Aquifers in Idaho, Oregon, and Washington, as in most other States, differ considerably in thickness and permeability, and well yields differ accordingly. Ground-water levels in a few areas have declined as a result of withdrawals by wells. State governments have taken steps to alleviate declines in some areas by enacting programs that either limit the number of additional wells that can be completed in a particular aquifer (Ground-Water Management Area) or prevent further ground-water development (Critical Ground-Water Area). Segment 7 includes some of the driest parts of the Nation, as well as some of the wettest. Average annual precipitation (1951-80) ranges from less than 10 inches in arid parts of Idaho, Oregon, and Washington to more than 80 inches in the western parts of Oregon and Washington (fig. 3). Most storms generally move eastward through the area. The eastward-moving air absorbs the moisture that evaporates from the Pacific Ocean. As this air encounters the fronts of mountain ranges, it rises, cools, and condenses. Accordingly, the western sides of the mountain ranges receive the most precipitation. Much of the annual precipitation moves directly to streams as overland runoff. Some of the precipitation is returned to the atmosphere by evapotranspiration, which is the combination of evaporation from the surface and transpiration from the plants. A small part of the precipitation infiltrates the soil and percolates downward to recharge underlying aquifers. Average annual runoff ( 1951-80) in the segment varies considerably (fig. 4), and the distribution of the runoff generally parallels that of precipitation. In the arid and the semiarid parts of Segment 7, most precipitation replenishes soil moisture, evaporates, or is transpired by vegetation. Little is left to maintain streamflow or to recharge aquifers. In the wetter parts, much of the precipitation runs off the land surface to maintain streamflow, and because evaporation is usually less in wetter areas, more water is available to recharge aquifers. Precipitation that falls as snow generally does not become runoff until spring thaws begin. Reservoirs constructed on major streams to mitigate flooding and to store water for irrigation, hydroelectric-power generation, and recreation also affect the timing of runoff. The runoff is stored and subsequently released during drier periods to maintain downstream flow.

Idaho, Oregon, Washington↗

Vulnerabilities of national parks in the American Midwest to climate and land use changes

Many national parks in the American Midwest are surrounded by agricultural or urban areas or are in highly fragmented or rapidly changing landscapes. An environmental stressor is a physical, chemical, or biological condition that affects the functioning or productivity of species or ecosystems. Climate change is just one of many stressors on park natural resources; others include urbanization, land use change, air and water pollution, and so on. Understanding and comparing the relative vulnerability of a suite of parks to projected climate and land use changes is important for region-wide planning. A vulnerability assessment of 60 units in the 13-state U.S. National Park Service Midwestern administrative region to climate and land use change used existing data from multiple sources. Assessment included three components: individual park exposure (5 metrics), sensitivity (5 metrics), and constraints to adaptive capacity (8 metrics) under 2 future climate scenarios. The three components were combined into an overall vulnerability score. Metrics were measures of existing or projected conditions within park boundaries, within 10-kilometer buffers surrounding parks, and within ecoregions that contain or intersect them. Data were normalized within the range of values for all assessed parks, resulting in high, medium, and low relative rankings for exposure, sensitivity, constraints to adaptive capacity, and overall vulnerability. Results are consistent with assessments regarding patterns and rates of climate change nationwide but provide greater detail and relative risk for Midwestern parks. Park overall relative vulnerability did not differ between climate scenarios. Rankings for exposure, sensitivity, and constraints to adaptive capacity varied geographically and indicate regional conservation planning opportunities. The most important stressors for the most vulnerable Midwestern parks are those related to sensitivity (intrinsic characteristics of the park) and constraints on adaptive capacity (characteristics of the surrounding landscape) rather than exposure to external forces, including climate change. Output will allow individual park managers to understand which metrics weigh most heavily in the overall vulnerability of their park and can be used for region-wide responses and resource allocation for adaptation efforts.

Arkansas, Illinois, Indiana, Iowa, Kansas, Michiga↗

Comparison of two methods for delineating land use near monitoring wells used for assessing quality of shallow ground water

Two methods were compared for delineating land use near shallow monitoring wells. These wells were used to assess the effects of agricultural cropland on the quality of recently recharged ground water in two sand and gravel aquifers located near land surface. The two methods for delineating land use near wells were (1) the sector method, which used potentiometric-surface maps to estimate average flow direction and a ground-water-flow model to estimate maximum length of contributing area to the monitoring well within an upgradient sector; and (2) the circle method, which used a 500- meter radius circle around the well based on a national empirical analysis. Land uses were compiled for 29 wells in each of two surficial aquifers in the Red River of the North Basin within the area defined by each method. Land use near each well was interpreted from orthorectified photographs and site inspection for both delineation methods. Land use near individual wells characterized by each method varied greatly, which can affect the results of statistical correlations between land use and water quality. Land use determined by the circle method related more closely to the land use for each entire study area. Land use determined by the sector method (within 200 meters from the wells) compared more favorably to ground-water quality based on nitrate concentrations. The maximum length of contributing areas to wells estimated in this study may be of value for other studies of unconsolidated sand and gravel aquifers with similar hydrogeological characteristics of permeability, water-table slopes, recharge, and depth to water. The additional effort required for estimating the model delineation of land use and land cover for the sector method must be weighed against the improved confidence in statistical correlation between land use and the quality of shallow ground water. Improved scientific confidence and understanding of relations between land use and quality of ground water may encourage more effective implementation of land and water management for protecting water quality

Minnesota, North Dakota↗

Assessing winter cover crop nutrient uptake efficiency using a water quality simulation model

Winter cover crops are an effective conservation management practice with potential to improve water quality. Throughout the Chesapeake Bay Watershed (CBW), which is located in the Mid-Atlantic US, winter cover crop use has been emphasized and federal and state cost-share programs are available to farmers to subsidize the cost of winter cover crop establishment. The objective of this study was to assess the long-term effect of planting winter cover crops at the watershed scale and to identify critical source areas of high nitrate export. A physically-based watershed simulation model, Soil and Water Assessment Tool (SWAT), was calibrated and validated using water quality monitoring data and satellite-based estimates of winter cover crop species performance to simulate hydrological processes and nutrient cycling over the period of 1991–2000. Multiple scenarios were developed to obtain baseline information on nitrate loading without winter cover crops planted and to investigate how nitrate loading could change with different winter cover crop planting scenarios, including different species, planting times, and implementation areas. The results indicate that winter cover crops had a negligible impact on water budget, but significantly reduced nitrate leaching to groundwater and delivery to the waterways. Without winter cover crops, annual nitrate loading was approximately 14 kg ha −1 , but it decreased to 4.6–10.1 kg ha −1 with winter cover crops resulting in a reduction rate of 27–67% at the watershed scale. Rye was most effective, with a potential to reduce nitrate leaching by up to 93% with early planting at the field scale. Early planting of winter cover crops (~30 days of additional growing days) was crucial, as it lowered nitrate export by an additional ~2 kg ha −1 when compared to late planting scenarios. The effectiveness of cover cropping increased with increasing extent of winter cover crop implementation. Agricultural fields with well-drained soils and those that were more frequently used to grow corn had a higher potential for nitrate leaching and export to the waterways. This study supports the effective implement of winter cover crop programs, in part by helping to target critical pollution source areas for winter cover crop implementation.

Chesapeake Bay Watershed↗

Regional rainfall-runoff relations for simulation of streamflow for watersheds in Du Page County, Illinois

Rainfall and streamflow data collected from July 1986 through September 1993 were utilized to calibrate and verify a continuous-simulation rainfall-runoff model for three watersheds (11.8--18.0 square miles in area) in Du Page County. Classification of land cover into three categories of pervious (grassland, forest/wetland, and agricultural land) and one category of impervious subareas was sufficient to accurately simulate the rainfall-runoff relations for the three watersheds. Regional parameter sets were obtained by calibrating jointly all parameters except fraction of ground-water inflow that goes to inactive ground water (DEEPFR), interflow recession constant (IRC), and infiltration (INFILT) for runoff from all three watersheds. DEEPFR and IRC varied among the watersheds because of physical differences among the watersheds. Two values of INFILT were obtained: one representing the rainfall-runoff process on the silty and clayey soils on the uplands and lake plains that characterize Sawmill Creek, St. Joseph Creek, and eastern Du Page County; and one representing the rainfall-runoff process on the silty soils on uplands that characterize Kress Creek and parts of western Du Page County. Regional rainfall-runoff relations, defined through joint calibration of the rainfall-runoff model and verified for independent periods, presented in this report, allow estimation of runoff for watersheds in Du Page County with an error in the total water balance less than 4.0 percent; an average absolute error in the annual-flow estimates of 17.1 percent with the error rarely exceeding 25 percent for annual flows; and correlation coefficients and coefficients of model-fit efficiency for monthly flows of at least 87 and 76 percent, respectively. Close reproduction of the runoff-volume duration curves was obtained. A frequency analysis of storm-runoff volume indicates a tendency of the model to undersimulate large storms, which may result from underestimation of the amount of impervious land cover in the watershed and errors in measuring rainfall for convective storms. Overall, the results of regional calibration and verification of the rainfall-runoff model indicate the simulated rainfall-runoff relations are adequate for stormwater-management planning and design for watersheds in Du Page County.

Water-Resources Investigations Report↗

Quality of groundwater used for domestic supply in the western Central Valley, California—2023

More than 2 million Californians rely on groundwater from domestic wells for their drinking-water supply. This report summarizes a 2023 California Groundwater Ambient Monitoring and Assessment Priority Basin Project water-quality survey of 44 domestic and small-system drinking-water supply wells in the western Sacramento Valley (basin number 5-021) and San Joaquin Valley (basin number 5-022) groundwater basins in the Central Valley, California, where more than 88,000 residents are estimated to utilize privately owned, domestic wells. The study area includes the Corning, Colusa, Yolo, and Solano subbasins (subbasin numbers 5-021.51, 5-021.52, 5-021.67, and 5-021.66, respectively) of the Sacramento Valley groundwater basin, and the East Contra Costa, Tracy, Delta-Mendota, and Westside subbasins (subbasin numbers 5-022.19, 5-022.15, 5-022.07, and 5-022.09, respectively) of the San Joaquin Valley groundwater basin. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of the aquifer system rather than groundwater resources used for public drinking-water supply, which are typically drawn from deeper parts. This assessment characterized the quality of ambient groundwater used for domestic supply, rather than the quality of drinking water at a tap or faucet, which may be filtered or treated after extraction. To provide context, concentrations of constituents in groundwater were compared to Federal and State of California regulatory and non-regulatory benchmarks for drinking-water quality. Regulatory benchmarks were U.S. Environmental Protection Agency and State of California maximum contaminant levels (MCLs) for drinking water. Non-regulatory benchmarks were State of California secondary maximum contaminant levels (SMCLs) for managing aesthetic conditions, such as taste, odor, or color. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking supply that have water-quality constituents present at high concentrations (greater than the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth of the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other California Groundwater Ambient Monitoring and Assessment Priority Basin Project study areas. In this study, inorganic constituents in groundwater were greater than regulatory benchmarks for public drinking-water quality in 30 percent of domestic groundwater resources. Inorganic constituents present at concentrations greater than MCLs for drinking water were hexavalent chromium, total chromium, and nitrate. Total dissolved solids, manganese, and iron were present at concentrations greater than their SMCL in 27 percent of domestic groundwater resources. 1,2,3-trichloropropane was present at concentrations greater than State of California MCLs for drinking water in 2.3 percent of domestic groundwater resources and was the only volatile organic compound detected at concentrations greater than a benchmark. Per-and polyfluoroalkyl substances were detected in 16 percent of domestic groundwater resources, and 2.3 percent had concentrations greater than U.S. Environmental Protection Agency MCLs. Total coliform bacteria and enterococci were detected in 9.1 and 2.3 percent of domestic groundwater resources, respectively. To understand groundwater quality in the study area, factors that affect groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential physical and chemical variables. Relevant factors include the oxidation-reduction conditions of groundwater, agricultural land use, and geologic sources of aquifer sediments. Manganese and iron concentrations were affected by oxidation-reduction state. Nitrate concentrations were affected by the interplay of agricultural practices and denitrification, where denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Ultramafic aquifer sediments in the western Central Valley provide a geogenic source for chromium and hexavalent chromium. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials, but agricultural practices may also contribute to these concentrations.

California↗

Hydrology of the San Luis Valley, south-central Colorado

An investigation of the water resources of the Colorado part of the San Luis Valley was begun in 1966 by the U.S. Geological Survey, in cooperation with the Colorado Water Conservation Board. (See index map, fig. 1). The purpose of the investigation is to provide information for planning and implementing improved water-development and management practices. The major water problems in the San Luis Valley include (1) waterlogging, (2) waste of water by nonbeneficial evapotranspiration, (3) deterioration of ground-water chemical quality, and (4) failure of Colorado to deliver water to New Mexico and Texas in accordance with the Rio Grande Compact. This report describes the hydrologic environment, extent of water-resource development, and some of the problems related to that development. Information presented is based on data collected from 1966 to 1968 and on previous studies. Subsequent reports are planned as the investigation progresses. The San Luis Valley extends about 100 miles from Poncha Pass near the northeast corner of Saguache County, Colo., to a point about 16 miles south of the Colorado-New Mexico State line. The total area is 3,125 square miles, of which about 3,000 are in Colorado. The valley is nearly flat except for the San Luis Hills and a few other small areas. The Colorado part of the San Luis Valley, which is described in this report, has an average altitude of about 7,700 feet. Bounding the valley on the west are the San Juan Mountains and on the east the Sangre de Cristo Mountains. Most of the valley floor is bordered by alluvial fans deposited by streams originating in the mountains, the most extensive being the Rio Grande fan (see block diagram, fig. 2 in pocket). Most of the streamflow is derived from snowmelt from 4,700 square miles of watershed in the surrounding mountains. The northern half of the San Luis Valley is internally drained and is referred to as the closed basin. The lowest part of this area is known locally as the "sump." The remainder of the valley is drained by the Rio Grande and its tributaries. The climate of the San Luis Valley is arid, and a successful agricultural economy would not be possible without irrigation. It is characterized by cold winters, moderate summers, and much sunshine. The average annual precipitation on the valley floor ranges from 7 to 10 inches. More than half the precipitation occurs from July to September. Moisture deficiency in the valley is shown by the graph comparing pan evaporation and precipitation {fig. 3}. For the years 1961-67 average pan evaporation for the period April through September was 52.25 inches, but average precipitation for the period was only 5.02 inches. Average annual precipitation was 7.8 inches. Owing to the short growing season (90-120 days), crops a.re restricted mainly to barley, oats, potatoes, and other vegetables.

Colorado↗

Quantifying time-varying ground-water discharge and recharge in wetlands of the northern Florida Everglades

Developing a more thorough understanding of water and chemical budgets in wetlands depends in part on our ability to quantify time-varying interactions between ground water and surface water. We used a combined water and solute mass balance approach to estimate time-varying ground-water discharge and recharge in the Everglades Nutrient Removal project (ENR), a relatively large constructed wetland (1544 hectare) built for removing nutrients from agricultural drainage in the northern Everglades in South Florida, USA. Over a 4-year period (1994 through 1998), ground-water recharge averaged 13.4 hectare-meter per day (ha-m/day) or 0.9 cm/day, which is approximately 31% of surface water pumped into the ENR for treatment. In contrast, ground-water discharge was much smaller (1.4 ha-m/day, or 0.09 cm/day, or 2.8% of water input to ENR for treatment). Using a water-balance approach alone only allowed net ground-water exchange (discharge — recharge) to be estimated (−12±2.4 ha-m/day). Discharge and recharge were individually determined by combining a chloride mass balance with the water balance. For a variety of reasons, the ground-water discharge estimated by the combined mass balance approach was not reliable (1.4±37 ha-m/day). As a result, ground-water interactions could only be reliably estimated by comparing the mass-balance results with other independent approaches, including direct seepage-meter measurements and previous estimates using ground-water modeling. All three independent approaches provided similar estimates of average ground-water recharge, ranging from 13 to 14 ha-m/day. There was also relatively good agreement between ground-water discharge estimates for the mass balance and seepage meter methods, 1.4 and 0.9 ha-m/day, respectively. However, ground-water-flow modeling provided an average discharge estimate that was approximately a factor of four higher (5.4 ha-m/day) than the other two methods. Our study developed an initial understanding of how the design and operation of the ENR increases interactions between ground water and surface water. A considerable portion of recharged ground water (73%) was collected and returned to the ENR by a seepage canal. Additional recharge that was not captured by the seepage canal only occurred when pumped inflow rates to ENR (and ENR water levels) were relatively high. Management of surface water in the northern Everglades therefore clearly has the potential to increase interactions with ground water.

Florida↗

Estimating Flow-Duration and Low-Flow Frequency Statistics for Unregulated Streams in Oregon

Flow statistical datasets, basin-characteristic datasets, and regression equations were developed to provide decision makers with surface-water information needed for activities such as water-quality regulation, water-rights adjudication, biological habitat assessment, infrastructure design, and water-supply planning and management. The flow statistics, which included annual and monthly period of record flow durations (5th, 10th, 25th, 50th, and 95th percent exceedances) and annual and monthly 7-day, 10-year (7Q10) and 7-day, 2-year (7Q2) low flows, were computed at 466 streamflow-gaging stations at sites with unregulated flow conditions throughout Oregon and adjacent areas of neighboring States. Regression equations, created from the flow statistics and basin characteristics of the stations, can be used to estimate flow statistics at ungaged stream sites in Oregon. The study area was divided into 10 regression modeling regions based on ecological, topographic, geologic, hydrologic, and climatic criteria. In total, 910 annual and monthly regression equations were created to predict the 7 flow statistics in the 10 regions. Equations to predict the five flow-duration exceedance percentages and the two low-flow frequency statistics were created with Ordinary Least Squares and Generalized Least Squares regression, respectively. The standard errors of estimate of the equations created to predict the 5th and 95th percent exceedances had medians of 42.4 and 64.4 percent, respectively. The standard errors of prediction of the equations created to predict the 7Q2 and 7Q10 low-flow statistics had medians of 51.7 and 61.2 percent, respectively. Standard errors for regression equations for sites in western Oregon were smaller than those in eastern Oregon partly because of a greater density of available streamflow-gaging stations in western Oregon than eastern Oregon. High-flow regression equations (such as the 5th and 10th percent exceedances) also generally were more accurate than the low-flow regression equations (such as the 95th percent exceedance and 7Q10 low-flow statistic). The regression equations predict unregulated flow conditions in Oregon. Flow estimates need to be adjusted if they are used at ungaged sites that are regulated by reservoirs or affected by water-supply and agricultural withdrawals if actual flow conditions are of interest. The regression equations are installed in the USGS StreamStats Web-based tool (http://water.usgs.gov/osw/streamstats/index.html, accessed July 16, 2008). StreamStats provides users with a set of annual and monthly flow-duration and low-flow frequency estimates for ungaged sites in Oregon in addition to the basin characteristics for the sites. Prediction intervals at the 90-percent confidence level also are automatically computed.

Scientific Investigations Report↗

Geomorphic controls on floodplain connectivity, ecosystem services, and sensitivity to climate change: An example from the lower Missouri River

Floodplains of large rivers are exploited for agricultural production, industrial and municipal development, and transportation infrastructure. Recently, increased frequency of costly floods has prompted consideration of whether offsetting benefits might accrue from management of floodplains for ecosystem services. We employed a simple inundation model for 800 km of the Lower Missouri River, USA, to evaluate spatial and temporal distributions of ecological floodplain inundation metrics and how those distributions might vary with levee removal and climatic change. The model evaluates inundation at 30 × 30 m resolution on a daily basis over 82 years of record. We quantified provisioning of waterfowl habitat and potential denitrification. Spatial variability is affected by ongoing geomorphic adjustments that affect floodplain connectivity. Statistical models indicate that available floodplain area and recent aggradation are predictive of most inundation metrics. Connectivity is sensitive to climate-change scenarios that predict increased floodplain inundation during spring waterfowl migrations; the greatest sensitivity to future climate exists where channel-floodplain geomorphology presently enhances floodplain connectivity. Evaluation of floodplain denitrification indicates that on average, the nonleveed part of the floodplain could denitrify 0.05%–1.7% of the mean annual nitrogen load of the river. Levee removal could increase this rate to only 3.6% of the nitrogen load. The capacity of floodplain connectivity to influence certain ecosystem services is highly variable in space along the Lower Missouri River and may be appreciably influenced by climate change. Hence, decisions to optimize management of large-river floodplains are likely to be highly location dependent.

Illinois, Iowa, Kansas, Missouri, Nebraska, South ↗