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USGS2024

Parameter ESTimation with the Gauss–Levenberg–Marquardt algorithm: An intuitive guide

In this paper, we review the derivation of the Gauss–Levenberg–Marquardt (GLM) algorithm and its extension to ensemble parameter estimation. We explore the use of graphical methods to provide insights into how the algorithm works in practice and discuss the implications of both algorithm tuning parameters and objective function construction in performance. Some insights include understanding the control of both parameter trajectory and step size for GLM as a function of tuning parameters. Furthermore, for the iterative Ensemble Smoother (iES), we discuss the importance of noise on observations and show how iES can cope with non-unique outcomes based on objective function construction. These insights are valuable for modelers using PEST, PEST++, or similar parameter estimation tools.

Groundwater↗

USGS2025

Deterministic physics-based earthquake sequence simulators match empirical ground-motion models and enable extrapolation to data poor regimes: Application to multifault multimechanism ruptures

We use the deterministic earthquake simulator RSQSim to generate complex sequences of ruptures on fault systems used for hazard assessment. We show that the source motions combined with a wave propagation code create surface ground motions that fall within the range of epistemic uncertainties for the Next Generation Attenuation‐West2 set of empirical models. We show the model is well calibrated where there are good data constraints, and has good correspondence in regions with fewer data constraints. We show magnitude, distance, and mechanism dependence all arising naturally from the same underlying friction. The deterministic physics‐based approach provides an opportunity for better understanding the physical origins of ground motions. For example, we find that reduced stress drops in shallow layers relative to constant stress drop with depth lead to peak ground velocities in the near field that better match empirical models. The simulators may also provide better extrapolations into regimes that are poorly empirically constrained by data because physics, rather than surface shaking data parameterizations, is underlying the extrapolations. Having shown the model is credible, we apply it to a problem where observations are lacking. We examine the case of crustal faults above a shallow subduction interface seen to break coseismically in simulations of the New Zealand fault system. These types of events were left out of consideration in the most recent New Zealand national seismic hazard model due to the modeling complexity and lack of observational data to constrain ground‐motion models (GMMs). Here, we show that in the model, by breaking up the coseismic crustal and interface rupturing fault motions into two separate subevents, and then recombining the resulting ground‐motion measures in a square‐root‐of‐sum‐of‐squares incoherent manner, we reproduce well the ground‐motion measures from the full event rupture. This provides a new method for extrapolating GMMs to more complex multifault ruptures.

Seismological Research Letters↗

USGS2024

Federal lands greenhouse gas emissions and sequestration in the United States: Estimates for 2005–22

In 2016, the Secretary of the U.S. Department of the Interior requested that the U.S. Geological Survey (USGS) produce a publicly available and annually updated database of estimated greenhouse gas emissions associated with the extraction and use of fossil fuels from Federal lands. The first report in this series included emissions estimates from 2005 to 2014 and were reported for 29 States and two offshore areas. Native American and Tribal lands were not included in that analysis. This report recalculates those previous years (2005–14) with updated data and methods and extends the estimates to 2022. Nationwide emissions from fossil fuels produced on Federal lands in 2022 were 1,081.2 million metric tons of carbon dioxide equivalent (MMT CO 2 Eq.) for CO 2 , 33.4 MMT CO 2 Eq. for methane (CH 4 ), and 4.3 MMT CO 2 Eq. for nitrous oxide (N 2 O). Compared to 2005, the 2022 totals represent decreases in emissions for all three greenhouse gases (by 17 percent for CO 2 , 37 percent for CH 4 , and 30 percent for N 2 O). Emissions from fossil fuels produced on Federal lands represent, on average, 21.8 percent of U.S. emissions for CO 2 , 6.1 percent for CH 4 , and 1.3 percent for N 2 O over the 18 years included in this estimate. The trends and relative magnitudes of the greenhouse gas emissions estimated are roughly parallel to the Federal lands fossil fuel production volumes. In 2021, Federal lands of the conterminous United States stored 70,424 MMT CO 2 Eq. in terrestrial ecosystems. Soils stored most of the terrestrial ecosystem carbon (66 percent), followed by live vegetation (25 percent), deadwood (5 percent), and litter (4 percent). Carbon sequestration on Federal lands was highly variable over time, owing primarily to interannual variability in climate and weather, and variability in land use and land cover (LULC) change and disturbances, among these are wildfires and logging. Between 2005 and 2021, Federal lands sequestered an average of 83 MMT CO 2 Eq./yr. By subtracting the cumulative effects of LULC and disturbance-related CO 2 losses to the atmosphere from the total, we estimate that ecosystems at the national level sequestered CO 2 at an annual mean rate of 17 MMT CO 2 Eq./yr in a term called the net ecosystem exchange (NEE). This annual NEE sequestration value represents about 1.4 percent of average fossil fuel emissions over the same period. The USGS estimates presented in this report represent an accounting for the emissions resulting from fossil fuel extraction on Federal lands and the end-use combustion of those fuels, as well as for the sequestration of carbon in terrestrial ecosystems on Federal lands. A combined net CO 2 emissions estimate, which is the difference between the emitted and sequestered CO 2 from both the fossil fuel and ecosystems estimates, provides context for evaluating the greenhouse gas contributions of activities on these lands. The estimates included in this report can provide context for future energy decisions, as well as a basis to track change in the future.

Scientific Investigations Report↗

USGS2024

Predicting hydrothermal reservoir depth from chemical geothermometers using a three-dimensional temperature model in the Great Basin, USA

Recent work in the Great Basin region of the western United States has made it possible to predict the depth of hydrothermal reservoirs (i.e., the depth at which heat is accumulated prior to ascent via hydrothermal upflow) identified through geochemistry and to contextualize the spatial patterns of these reservoir depths. Chemical geothermometers use the chemical and mineral constituents of hydrothermal fluids to predict the temperature at which fluids equilibrated with the host rocks at depth. Assuming that most of the Great Basin is dominated by conductive conditions until a vertically connected hydrothermal flow path is created (e.g., by faulting), geothermometers reflect the chemical and thermal conditions at the depth interval that the fluid has conductively equilibrated over a long period before a vertical conduit allows convective upflow. By pairing geothermometer temperature estimates with our recent three-dimensional temperature model of conductive heat flow in the Great Basin, we estimate the corresponding reservoir depths and construct a map of circulation depths. The predicted depths from geothermometers have spatial patterns across the Great Basin that relate to patterns seen in other geologic and geophysical data. Deeper springs generally occur disproportionately in areas with higher strain rates and in basins. We posit that current elevated strain rates reflect patterns of historic deformation where ongoing tectonic activity maintains permeable pathways to deeper reservoirs, some of which are estimated to exceed 6 km depth. Basins, as expected, contain a disproportionate number of these deep systems, because the underlying aquifers are closer to the surface in basins, thus requiring less water pressure to reach the surface than in mountain ranges. Most springs estimated to have their source in a deep reservoir occur at places known to host a hydrothermal system; these refined depth estimates of the source reservoir can help to better constrain the source depth for many known hydrothermal systems across the Great Basin.

Arizona, California, Idaho, Nevada, Oregon, Utah↗

USGS2025

Chemical and isotopic fractionation during melt inclusion formation

Melt inclusions are used to study the origin and evolution of magmas. The extent to which they represent equilibrium melt compositions, however, critically hinges on the ratio of crystal growth rate to diffusion rate in melts. If the rate of crystal growth is limited by the supply of nutrients and the dissipation of unwanted components, the trapped melt will be depleted in compatible elements and enriched in incompatible elements. Despite widespread recognition of the potential for melt inclusions to trap disequilibrium compositions, their identification remains a challenge. Here, we demonstrate how stable isotopes provide a solution to this problem. Melt inclusions in basaltic tephra from Kīlauea volcano, Hawai‘i, display Mg isotope fractionation up to 0.49‰ ( 26 Mg/ 24 Mg) relative to bulk rock. These observations indicate that kinetic processes, such as chemical diffusion, are at play, as equilibrium mineral-melt isotope fractionation at high temperatures is an order of magnitude smaller. We propose that the heavy Mg isotopic compositions of the melt inclusions were generated by the faster diffusion and thus preferential incorporation of 24 Mg by the growing olivine, leaving the slower diffusant ( 26 Mg) behind. The incompatible elements (e.g., Ca, Ti, and K) are predicted to display similarly large fractionations when boundary layer effects are significant. These findings show that stable isotopes can be a useful tool in identifying disequilibrium compositions in melt inclusions.

Geology↗

USGS2024

Developments in African industrial minerals for renewable energy

Introduction Africa is emerging as a leading source for minerals used in the manufacture of batteries for electric vehicles and in other renewable energy applications. New graphite, lithium, and rare-earth mines have or could be opened in African countries from 2017 through 2026. Estimates of production capacities for graphite, lithium, and rare-earth mines for 2023 and beyond are based upon supply-side assumptions, such as announced plans for new capacity construction and bankable feasibility studies, as well as projected trends that could affect current producing facilities in 2023 and planned new facilities projected to come online by 2026. Forward-looking information, including estimates of future production capacities, graphite flake distributions, and timing of the start of operations, are subject to risk factors and uncertainties that could cause actual events or results to differ significantly from expected outcomes. Projects listed in this report are presented as an indication of industry plans and are not a U.S. Geological Survey (USGS) prediction of what will take place. Only projects with planned startup dates are included in this report; ther graphite, lithium, and rare-earth projects in Africa without startup dates were known to be in various stages of development but are not included in this fact sheet.

Fact Sheet↗

USGS2025

Insights into widespread landsliding in southern Appalachia from Hurricane Helene

Between 23 and 27 September 2024, antecedent rain followed by Hurricane Helene produced one of the most damaging weather events in southern Appalachia history. The back-to-back storm events resulted in a maximum cumulative rainfall of 848 mm and hurricane-force wind gusts over 170 km/h in western North Carolina, eastern Tennessee, and southwestern Virginia. The resulting regional flooding, landslides, and tree blowdown caused over 100 fatalities, damaged or destroyed critical infrastructure and thousands of structures, and severed connectivity across the region. Over the next several weeks, a multi-agency landslide response produced a rapid hazard assessment and mapped 2217 landslides, 55% of which damaged infrastructure or property. Orographic uplift enhanced rainfall, resulting in concentrated landsliding along the ~250 km swath of the Blue Ridge escarpment in western North Carolina. Landslides initiated predominantly on windward-facing (southeast-facing) slopes, and localized clustering of initiation points indicated a strong influence of hillslope-scale meteorological and geomorphic factors. Many shallow landslides mobilized into larger, highly mobile, and damaging debris flows that graded into floods. Here, we put our preliminary observations in the context of historical storm-driven landslide events and open new avenues for investigating the nature and extent of landslides and their effects in southern Appalachia and similar environments.

Georgia, North Carolina, South Carolina, Tennessee↗

USGS2024

Earthquake relocations delineate discrete a fault network and deformation corridor throughout Southeast Alaska and Southwest Yukon

Deformation in southeastern Alaska and southwest Yukon is governed by the subduction and translation of the Pacific-Yakutat plates relative to the North American plate in the St. Elias region. Despite notable historical seismicity and major regional faults, studies of the region between the Fairweather and Denali faults are complicated by glacial coverage and the remote setting. In the last decade, significant improvements have been made to the density of regional broadband seismometer networks. We relocate more than 5,000 earthquakes between 2010 and 2021 in the region of southeastern Alaska and southwestern Yukon utilizing these improved seismic networks. With reductions in catalog uncertainty, particularly in depth, we quantify the thickness of the seismogenic layer in the crust throughout the region and locate seismicity on a shallow network of upper-crustal faults. Relocated earthquakes, combined with an updated focal-mechanism catalog, permit estimating and classifying motion of active faults. This includes mapping the Totschunda-Fairweather “Connector” fault, which plays an important role in explaining regional deformation, and identifying new faults like the Kathleen Lake fault. We draw similarities between our seismic observations and simplified conceptual models of regional tectonics, which describe a dominant transpressional regime and localized slip partitioning. Our results support a hypothesis where current deformation is taking place on a well-defined and evolved network of shallow faults in the corridor between the Totschunda-Fairweather “Connector” and Denali faults.

Alaska, Yukon↗

USGS2025

Forecast, monitor, adapt: A multi-agency strategy to protect people from postfire debris flows

In 2020, a wildfire burned across Glenwood Canyon in Colorado, USA. A history of postfire debris flows in the region and a hazard assessment for the burn area indicated that potentially life-threatening debris flows could be triggered by rainfall within months of a wildfire. As a result, four government agencies evaluated strategies to help mitigate hazards, including the loss of human life, that may be associated with debris-flow events. After the fire, 26 large debris flows occurred in the summer of 2021 and three sediment-laden flows occurred in the summer of 2023, but there were no major injuries or fatalities reported. We found that integrating hazard assessment/ forecasting, monitoring, and adaptation scenarios was a successful strategy for reducing postfire debris-flow risks to human life (including injuries and fatalities). Weather forecasts and estimates of debris-flow triggering rainfall thresholds, likelihood, and volume were used to anticipate the timing, location, and magnitude of debris-flow events. Rainfall monitoring and detailed recordkeeping of storms that triggered debris flows were used to validate and update debris-flow warning thresholds that varied with time following the wildfire. Although the governmental agencies working in this burn area had distinct and differing agency mandates, they were able to integrate information to reduce the risk of debris-flow events to human life.

Colorado↗

USGS2000

Suspended-sediment characteristics in the Housatonic River Basin, western Massachusetts and parts of eastern New York and northwestern Connecticut, 1994-96

Suspended-sediment concentrations, discharges, loads, and yields were determined for eight subbasins in the Housatonic River Basin in western Massachusetts, eastern New York, and northwestern Connecticut from April 1994 through March 1996. Suspended-sediment samples were collected at three continuous-record sediment stations and at four partial-record sediment stations. Suspended-sediment concentrations in samples collected during the period of study ranged from less than 0.5 to 3,400 milligrams per liter, and concurrent streamflows ranged from 0.03 to 126 cubic feet per second per square mile at the seven stations. Median suspended-sediment concentrations in samples collected at each station ranged from 7 to 61 milligrams per liter. Median streamflows during suspended-sediment sampling ranged from 1.86 to 5.88 cubic feet per second per square mile. Instantaneous suspended-sediment yields ranged from less than 0.005 to 185 tons per day per square mile, and medians ranged from 0.03 to 1.12 tons per day per square mile at the seven stations. Total suspended-sediment loads (mass) from April 1994 through March 1996 at the continuous-record sediment stations were 11,603 tons at Housatonic River near Great Barrington, 7,929 tons at Green River, and 54,347 tons at Housatonic River near Ashley Falls. Suspended-sediment load during January 1996 at the Green River station accounted for about 54 percent of the total suspended-sediment load for the Green River during the 2-year study. Suspended-sediment load on January 19 and 20, 1996, at the Green River station accounted for about 50 percent of the January 1996 suspended-sediment load, or about 27 percent of the total suspended-sediment load during the 2-year study. This large suspended-sediment transport was the result of rainfall and snowmelt on January 19 and 20, 1996--the equivalent of a 5- to 6-inch rain storm in the Green River subbasin. Total suspended-sediment loads during the 2-year study at the partial-record sediment stations were 3,052 tons at Williams River, 1,758 tons at Ironworks Brook, and 17,927 tons at Konkapot River. Suspended-sediment yields from April 1994 through March 1996 at the continuous-record sediment stations were 21 (tons/yr)/mi 2 at Housatonic River near Great Barrington, 78 (tons/yr)/mi 2 at Green River, and 58 (tons/yr)/mi 2 at Housatonic River near Ashley Falls. Suspended-sediment yields during the 2- year study at the partial-record sediment stations were 35 (tons/yr)/mi 2 at Williams River, 78 (tons/yr)/mi 2 at Ironworks Brook, and 147 (tons/yr)/mi 2 at Konkapot River. Suspended-sediment yields were estimated for two subbasins in the Housatonic River Basin--Schenob Brook at Sheffield, a partial-record sediment station, and the area adjacent to the Housatonic River between Great Barrington and Ashley Falls. The estimate of suspended-sediment yield at Schenob Brook at Sheffield of 82 (tons/yr)/mi 2 is comparable to the yield determined for the Green River and Ironworks Brook. The estimate of suspended-sediment yield for the area adjacent to the Housatonic River between Great Barrington and Ashley Falls was 395 (tons/yr)/mi 2 . This estimated suspended-sediment yield was 2.7 to 18.8 times greater than that estimated for any of the other subbasins. Several basin and land-use characteristics thought to affect suspended-sediment transport in the subbasins were compared to the suspended-sediment yields. The characteristics that seemed to affect suspended-sediment discharge were dams, which contributes to decreased yields; Hadley, Limerick, Linlithgo, Saco, and Winooski silt loam soils (high erodibility soils), which contributes to increased yields; stratified-drift deposits, which contributes to increased yields; and agricultural and open land, which contributes to increased yields. The effect of stratified-drift deposits on suspended-sediment discharge is thought to be greater when those deposits are of glaciolacustrine (generally clay, silt, and fine sand), rather than glaciofluvial (clay, silt, sand, gravel, and cobbles) origin. The silt loam soils, glaciolacustrine deposits, and agricultural and open land are interrelated, inasmuch as the silt loam soils generally are associated with glaciolacustrine deposits and agricultural activities.

Connecticut, Massachusetts, New York↗

USGS1989

Techniques for simulating flood hydrographs and estimating flood volumes for ungaged basins in east and west Tennessee

A dimensionless hydrograph developed for a variety of basin conditions in Georgia was tested for its applicability to streams in East and West Tennessee by comparing it to a similar dimensionless hydrograph developed for streams in East and West Tennessee. Hydrographs of observed discharge at 83 streams in East Tennessee and 38 in West Tennessee were used in the study. Statistical analyses were performed by comparing simulated (or computed) hydrographs, derived by application of the Georgia dimensionless hydrograph, and dimensionless hydrographs developed from Tennessee data, with the observed hydrographs at 50 and 75% of their peak-flow widths. Results of the tests indicate that the Georgia dimensionless hydrography is virtually the same as the one developed for streams in East Tennessee, but that it is different from the dimensionless hydrograph developed for streams in West Tennessee. Because of the extensive testing of the Georgia dimensionless hydrograph, it was determined to be applicable for East Tennessee, whereas the dimensionless hydrograph developed from data on streams in West Tennessee was determined to be applicable in West Tennessee. As part of the dimensionless hydrograph development, an average lagtime in hours for each study basin, and the volume in inches of flood runoff for each flood event were computed. By use of multiple-regression analysis, equations were developed that relate basin lagtime to drainage area size, basin length, and percent impervious area. Similarly, flood volumes were related to drainage area size, peak discharge, and basin lagtime. These equations, along with the appropriate dimensionless hydrograph, can be used to estimate a typical (average) flood hydrograph and volume for recurrence-intervals up to 100 years at any ungaged site draining less than 50 sq mi in East and West Tennessee.

Tennessee↗

USGS2025

Factors influencing landslide occurrence in low-relief formerly glaciated landscapes: Landslide inventory and susceptibility analysis in Minnesota, USA

In landscapes recently impacted by continental glaciation, landslides may occur where topographic relief has been generated by the drainage of glacial lakes and ensuing post-glacial fluvial network development into unconsolidated glacially derived sediments and exhumed bedrock. To investigate linkages among environmental variables, post-glacial landscape development, and landslides, we created a landslide inventory of nearly 10,000 landslides in five regions of the formerly glaciated low-relief state of Minnesota, USA. Multivariate logistic regression indicates the importance of slope angle, lithology, and the development of stream valleys to landslide distribution. Areas underlain by fine-grained glaciolacustrine and nearshore deposits that are incised by streams are particularly prone to shallow (<1-2 m depth) landslides. Landslides also occur in a wide range of glacial and fluvial deposits, and as rockfall in layered Paleozoic sedimentary rocks in central and southern Minnesota and Precambrian igneous and sedimentary rocks in northeastern Minnesota. Although no more than 1-2% of the studied regions are susceptible to landslides, they can pose risk to life and safety, damage infrastructure, and impact water quality. The combination of recently generated low-relief steep slopes, extensive unconsolidated sediments, and layered sedimentary bedrock make this formerly glaciated landscape more susceptible to landslides than current national-scale models indicate.

Minnesota↗

USGS2026

Preface to the focus section on intraplate earthquakes

More than a half century after plate tectonics provided an overarching framework to explain earthquakes along active plate boundaries, numerous theories have been proposed to explain where, why, and how often earthquakes occur well away from active plate boundaries, but a paradigm remains elusive. Even the classification of earthquakes away from active plate boundaries as "intraplate" raises issues, with potentially important distinctions between Stable Continental Regions and more actively deforming regions including passive margins and failed rifts. Some of the largest known intraplate earthquakes themselves remain enigmatic, having occurred before the modern instrumental era. Hazard assessments are often data-limited: low fault-slip rates relative to landscape modification rates result in poor discoverability of fault sources, challenging the characterization of source zones and earthquake recurrence; the completeness and homogenization of instrumental earthquake catalogs using uncertain magnitude conversions can lead to uncertainties in earthquake recurrence; and, limited strong-motion observations for large-magnitude events at near-source distances leads to uncertainties in the selection and development of ground-motion models for seismic hazard studies. Data from recent intraplate earthquakes around the world—from the moment magnitude M 7.7 2001 Bhuj, India, earthquake 25 years ago to the 2024 M 4.8 Tewksbury, New Jersey earthquake—have yielded both new insights and new questions. The papers in this special focus discuss many of the long-standing challenges involved with intraplate earthquake investigations and provide a snapshot of the state of the art with current research to advance our understanding.

Seismological Research Letters↗

USGS2024

The new self-anchored suspension (SAS) San Francisco Bay Bridge- Its response to a small earthquake

This paper presents a summary of previously published work (Celebi 2023) related to the new Self-Anchored Suspension (SAS) bridge that went into service within the last decade as a replacement for the older truss bridge spanning between Yerba Buena Island and Oakland, California, within the San Francisco Bay Area. During the October 19, 1989 M6.9 Loma Prieta earthquake, which occurred ~100 km south of the Bay Bridge, a section of the upper deck of the truss bridge fell onto the lower deck – thus closing this important lifeline between San Francisco and Oakland. The SAS is unique, self-anchored, and suspended by a single tower that is pivotal in trafficking the cable and hanger system to support the decks. The SAS bridge is extensively instrumented by the California Geological Survey’s Strong Motion Instrumentation Program (CSMIP). There are approximately 85 channels of accelerometers in the seismic monitoring system that recorded the October 14, 2019 Mw4.6 Pleasant Hill earthquake. The data allow a complex but identifiable coupled response of the deck, tower, and cable system. Both acceleration and displacement time-history data are used to extract significant frequencies using system identification methods, including spectral analyses. Results are compared to those from finite-element-model (FEM) analyses carried out during the design and analysis process of the bridge in 2002 (Nader et al. 2002). There are differences between FEM analyses results and those from the low amplitude shaking caused by a seismic event. An apparent frequency (period) of the SAS bridge is assessed (approximately 5.2 seconds). In a plot of deck length versus period, there is an almost linear relationship with periods of other regular suspension bridges, such as the Golden Gate Bridge and the Carquinez Bridge, both in the San Francisco Bay.

California↗

USGS2025

Earthquake recurrence estimates for northern Caribbean faults from combinatorial optimization

We use combinatorial optimization to find the optimal spatial distribution of random samples of earthquakes (≥6.5) that minimize the misfit in target slip rates for all faults in the northeast Caribbean, and we derive magnitude-frequency relationships with uncertainties for these faults. Slip rates for many faults are derived from GPS block models, not direct measurements, because of their underwater locations. Predicted recurrence rates for eastern Hispaniola and Puerto Rico Trench faults are 220-450 yr for M7 and 3-5 kyr for M8, with maximum feasible magnitude of M8.2. The most frequent earthquakes with magnitudes ≥7.0 are predicted on the large upper plate strike-slip faults, Enriquillo (EF) and Septentrional Fault, commensurate with the historical record. Calais et al. (2023) suggested that shortening in western Hispaniola is accommodated on the offshore Jérémie and onshore Malpasse faults north and south of EF, instead of on terrestrial faults in western Hispaniola and EF. Because of our system-modeling approach, such a configuration predicts less frequent earthquakes on EF and on western Hispaniola and Muertos convergent zones. Recurrence times of a few 100s yr for M6.7 earthquakes is predicted on the submerged faults in Mona Passage, and infrequent M>7 earthquakes are predicted on the Virgin Islands faults.

Lesser Antilles↗

USGS2025

RioM-1: A new calcite reference material for U-Pb LA-ICP-MS geochronology

Determining absolute ages of carbonate diagenesis, faulting, fossil formation, speleothem growth, carbonate-hosted hydrocarbon deposits, vein mineralisation and hydrothermal alteration has become increasingly accessible through LA-ICP-MS U-Pb dating of calcite, complementing traditional isotope dilution methods still applicable to certain materials (e.g., speleothems via micro-drilling). However, well-calibrated reference materials for LA-ICP-MS calcite geochronology remain scarce. Here, we characterise the Rio Maior calcite, designated ‘RioM-1’, as a potential reference material for U-Pb dating by LA-ICP-MS. Fragments (0.1 to 1 cm 3 ) from a single scalenohedral crystal were analysed by ID-TIMS (U-Pb), LA-ICP-MS (U-Pb and 87 Sr/ 86 Sr), and SIMS (O isotopes). RioM-1 displays high U mass fraction and low, though variable, proportions of common Pb. Combined ID-TIMS analyses from two independent laboratories yielded a Tera-Wasserburg lower intercept date of 63.93 ± 0.11 Ma (2 s , MSWD = 1.3, n = 16). LA-ICP-MS U-Pb data from three independent laboratories are concordant with the TIMS age, producing a pooled date of 64.10 ± 0.12/1.2 Ma (2 s , MSWD = 7.7, n = 708) and an initial 207 Pb/ 206 Pb ratio of 0.85 ± 0.01. Other calcite reference materials, when normalised to RioM-1, yielded dates within uncertainty of their published values. SIMS measurements returned a mean 18 O/ 16 O of 0.002044450 ± 181 (1 s ) and δ 18 O SMOW of 19.57 ± 0.92‰ (1 s ), while LA-ICP-MS strontium isotope measurement yielded a mean 87 Sr/ 86 Sr of 0.708177 ± 9 (2 s ).

Geostandards and Geoanalytical Research↗

USGS2024

Volcanic gas monitoring

Introduction As magma rises through the crust, decreasing pressure conditions allow volatiles to exsolve from the magma. These volatiles then migrate upward through the crust, where they can be stored at shallower levels or escape to the atmosphere. Rising magma also heats rock masses beneath volcanic centers, causing water in shallow aquifers and hydrothermal systems to boil and release additional gases and steam (see chapter F , this volume; Ingebritsen and Hurwitz, 2024). The chemistry and quantity of gases that reach the surface during periods of quiescence or volcanic unrest can reveal that gas-rich magma is ascending, crystallizing, or alternatively stalling, with important implications for volcanic hazard (for example, Sutton and others, 1992; Aiuppa and others, 2007, 2021; Werner and others, 2009, 2011, 2012; Moretti and others, 2013; de Moor and others, 2016; Lewicki and others, 2019; Edmonds and others, 2022; Kern and others, 2022; Kunrat and others, 2022). Most volcanoes in Alaska and the western United States are characterized by weak degassing, with one or more low-temperature fumaroles (typically near the local boiling temperature of water) and connect to a deeper and sometimes extensive hydrothermal system (for example, McGee and others, 2001; Symonds and others, 2003a, b). Hydrothermal systems will affect the chemistry of rising gases exsolved from deeper magma (Symonds and others, 2001), including sulfur dioxide (SO 2 ), hydrogen chloride (HCl), and water vapor (for example, Doukas and Gerlach, 1995; Gerlach and others, 1998, 2008; Symonds and others, 2001; Werner and others, 2013). As an example, depending on factors such as temperature, pressure, and oxidation state, rising SO 2 will react with groundwater to form hydrogen sulfide (H 2 S) gas, dissolved sulfate (SO 4 2− ), or elemental sulfur (Christenson, 2000; Symonds and others, 2001; Werner and others, 2008). The reaction and dissolution of SO 2 into shallow groundwater is commonly referred to as scrubbing, and can reduce the likelihood that ascending, degassing magma can be detected. Carbon dioxide, however, in addition to exsolving from magma early in the ascent process, is not easily removed by hydrothermal fluids (Lowenstern, 2001). As scrubbing and other processes take place, the SO 2 /H 2 S, CO 2 /SO 2 , and CO 2 /H 2 S ratios may change. High rates of SO 2 emission indicate that magma has moved to relatively shallow levels in the volcano and that the system has heated up enough to establish dry pathways from depth to the surface. Monitoring multiple gas species and the total output of those species is thereby useful for volcano monitoring during both periods of quiescence, to establish background degassing conditions, and during unrest, when gas geochemistry and emission rates can provide information on changing conditions, such as magma ascent. To provide context for multidisciplinary volcano forecasts, we focus on the following two key required capabilities: (1) characterizing baseline geochemistry and gas discharge from volcanoes and volcanic regions and (2) monitoring changes in gas geochemistry and discharge to inform forecasts of volcanic eruptions and their effects. Sufficient baseline data must be collected to identify and interpret anomalous degassing associated with volcanic unrest (for example, Sorey and others, 1998; Rouwet and others, 2014). Differences in volcano type, baseline degassing rates, local hydrology, and geography (for example, high versus low latitude) will result in a different baseline for each volcano. Volcanoes of any threat level that exhibit one or more degassing phenomena would ideally be monitored by techniques needed to establish baseline degassing data, with the sampling frequency of baseline data dictated by the threat level (table E1). Additional monitoring techniques become necessary during periods of unrest. In general, three of the most important techniques for gas monitoring are (1) direct sampling of fumarole, spring, and soil gases for laboratory geochemical measurements, (2) measurements of the chemical composition of the volcanic plume and emission rates of major gas species (for example, H 2 O, CO 2 , SO 2 , and H 2 S) by satellite, airborne, or ground-based techniques, and (3) measurements of diffuse emissions of CO 2 and other gases through soils. Various methods and instruments may be useful both for baseline studies and during unrest.

Scientific Investigations Report↗

USGS2026

Black rails in Baja California

Summarizing records from 1905 to 2025, we document the presence and distribution of the California black rail ( Laterallus jamaicensis coturniculus ) in northwestern México, particularly Baja California and the Colorado River Delta. This subspecies has a restricted distribution in the western U.S. and northwestern México. We found few records over the past century: sparse detections in the early 1900s and an increase in reported records after 2000. Over 120 years, we compiled 35 documented records of California black rail occurrence in Baja California with a minimum reported count of 56 rails. Our call-broadcast survey methods reconfirmed previously occupied sites and documented the species at a previously unreported site. Surveys in the Baja California portion of the Colorado River Delta yielded 20 detections across nine survey events between 2000 and 2022. In April 2003, standardized surveys detected 12 California black rails: 7 in Bahía de San Quintín, 3 in Arroyo San Telmo, and 2 in Arroyo El Rosario. Our recent survey work (2022–2025) recorded maximum monthly counts of 31 detections at Bahía de San Quintín and 15 detections at Estero de Punta Banda, the latter representing a previously undocumented location for the subspecies. These surveys also yielded the first photographic and acoustic documentation of California black rail in México. The contribution of spatial and temporal data provided by citizen science platforms increased our understanding of the subspecies’ distribution. Enforceable protection of this subspecies’ habitat is needed to safeguard its persistence.

Baja California↗