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At least 1,351 records · Page 75Linked to original sources

USGS1985

Storm-induced response of a nearshore-bar system

A nearshore-bar system was surveyed periodically through a storm and the following recovery period. The data showed a very rapid response of morphology to changing wave conditions and allowed various models on bar formation to be tested. Under low-energy conditions prior to the storm a small bar was surveyed 13 m offshore. Both the high reflectivity of the beach and the cross-shore distance to the bar are consistent with a model of sediment convergence at the node or antinode of a standing wave of incident period. Such a small-scale bar may be a common feature on beaches with steep foreshores and more gentle offshore slopes. With the increase in wave height during the storm, the bar became better developed and migrated offshore at rates up to 2.2 m h −1 . The bar maintained its form in that the ratio of trough depth to crest depth ( h t h c "> h t h c ) remained roughly constant. The bar was in no way related to processes which would cause the convergence of sediment in the breaker zone; through most of the storm the bar-crest distance offshore was typically only 10% of the surf-zone width. Analysis of the bar distance offshore in terms of a standing wave motion showed that the causative wave period must have been much longer than that of incident waves, probably on the order of a minute. Surf-zone wave data showed significant energy in the infragravity band at these periods although no definite link has been made. After the height of the storm, the bar had a crescentic morphology. The development of this morphology occurred very rapidly with parts of the bar migrating onshore at rates up to 1.2 m h −1 . In contrast to the storm, during the recovery period h t h c "> h t h c varied by nearly a factor of three. Analysis of the offshore and longshore length scales showed the bar to be similar to one which would be generated by a standing mode 1 edge wave of period on the order of one minute.

Marine Geology↗

USGS1988

Coastal erosion: Processes, timing and magnitudes at the bluff toe

Five Lake Erie bluffs (one interlaminated clay and silt, three clay-rich diamicts and one shale) were surveyed at about 2-week intervals and after wind storms for up to 5 years. Erosion of the bluff toes along this low-energy coast occurred during northeast wind storms, which produced surges of up to 1 m and surf-zone waves of up to 1.2 m. Wave impact and/or uprush caused quarrying, which removed most of the toe material, and abrasion. There were from 1 to 23 erosion events/sites, with maximum magnitudes of erosion ranging from 12 to 55 cm/event. Timing and magnitude were linked to erodibility, maximum water level, storm surge, storm duration and beach width. A threshold maximum water level and a threshold surge were necessary for erosion. At these thresholds, the beach was submerged and wave energy was directly expended on the toe. Erosion did not take place when there was shorefast ice or when debris slopes shielded the toe from waves. The originally cohesive toe materials are easily eroded when they weather to an essentially noncohesive state. Wave erosion is the crucial erosion process; removal of material from the toe prevents the development of a stable slope.

Marine Geology↗

USGS1989

High-resolution seismic-reflection interpretations of some sediment deposits, Antarctic continental margin: Focus on the western Ross Sea

High-resolution seismic-reflection data have been used to a varying degree by geoscientists to interpret the history of marine sediment accumulations around Antarctica. Reconnaissance analysis of 1-, 3.5-, and 12-kHz data collected by the U.S. Geological Survey in the western Ross Sea has led to the identification of eight echo-character facies and six microtopographic facies in the sediment deposits that overlie the Ross Sea unconformity. Three depositional facies regions, each characterized by a particular assemblage of echo-character type and microtopographic facies, have been identified on the continental shelf. These suites of acoustic facies are the result of specific depositional processes that control type and accumulation of sediment in a region. Evidence of glacial processes and products is uncommon in regions 1 and 2, but is abundant in region 3. McMurdo Sound, region 1, is characterized by a monospecific set of acoustic facies. This unique assemblage probably represents turbidity current deposition in the western part of the basin. Most of the seafloor in region 2, from about latitude 77°S to 75°S, is deeper than 600 m below sealevel. The microtopographic facies and echo-character facies observed on the lower slopes and basin floor there reflect the thin deposits of pelagic sediments that have accumulated in the low-energy conditions that are typical of deep-water environments. In shallower water near the boundary with region 3, the signature of the acoustic facies is different from that in deeper water and probably indicates higher energy conditions or, perhaps, ice-related processes. Thick deposits of tills emplaced by lodgement during the most recent advance of the West Antarctic Ice Sheet are common from latitude 75°S to the northern boundary of the study area just south of Coulman Island (region 3). The signature of microtopographic facies in this region reflects the relief of the base of the grounded ice sheet prior to decoupling from the seafloor. Current winnowing and scour of shallow parts of the seafloor inhibits sediment deposition and maintains the irregular, hummocky relief that characterizes much of the region. Seafloor relief of this type in other polar areas could indicate the former presence of grounded ice.

Marine Geology↗

USGS1990

Stability of giant sand waves in eastern Long Island Sound, U.S.A.

A combination of a highly accurate bathymetric surveying technique and in-situ submersible observations and measurements were used to assess the migrational trends and morphological changes of large sand waves ( Ht ≤ 17 m) in eastern Long Island Sound. Although residing in a high-energy tidal environment characterized by a net westward sediment flux, the large bedforms are relatively stable over the short term. Over a 7 month period, 55.1% of a total 2942 m of sand wave crestline lengths migrated less than the horizontal accuracy limits of navigation (2 m). Approximately 35% of the remaining sand wave crests migrated less than 4 m. Net migration of the sand wave crests in the study area was 0.2 m. In addition, the bulk form (center of area in profile view) or the base of the sand waves showed little, if any, movement. These data, in conjunction with flow data within the sand wave field, suggest that net migration rates are greater than the time span of this study and/or the sand waves move in response to large residual flows created by high-energy, aperiodic storm events. The latter scenerio suggests that day to day processes only serve to rework and modify the sand waves.

Marine Geology↗

USGS1991

Shoreline deposits and diagenesis resulting from two Late Pleistocene highstands near +5 and +6 metres, Durban, South Africa

In exposures of Pleistocene rocks on the east coast of South Africa, eight sedimentary facies were distinguished on the basis of petrology, grain size, internal structures and field relationships. These are interpreted as deposits of surf zone, breaker zone, swash zone, backbeach, boulder beach and dune environments. Three phases of deposition and diagenesis are recognized. As a result of the stabilising effect of pre-existing coastal facies, the deposits from successive sea level stands are stacked vertically in a narrow coast-normal strip. Early cementation prevented erosion of the deposits during subsequent transgressions. Deposition of subsequent facies took place on an existing coastal dune (Facies 1). A terrace was cut into this dune at a sea level 4.5 to 5 m above present. At this sea level, clastic shoreline sediments were deposited which make up the main sedimentary sequence exposed (Facies 2–7). The steep swash zone, coarse grain size, and comparison with modern conditions in the study area indicate clastic deposition on a high-energy, wave-dominated, microtidal coastline. Vertical stacking of progressively shallower water facies indicates progradation associated with slightly regressive conditions, prior to stranding of the succession above sea level. During a subsequent transgression to 5.5 or 6 m above present sea level, a second terrace was cut across the existing facies, which by then were partly lithified. A boulder beach (Facies 8) deposited on this terrace is indicative of high wave energy and a rocky coastline, formed by existing cemented coastal facies. Comparison with dated deposits from other parts of the South African coast suggest a Late Pleistocene age for Facies 2–8. Deposition was terminated by subsequent regression and continuing low sea levels during the remainder of the Pleistocene. Cementation of the facies took place almost entirely by carbonate precipitation. The presence of isopachous fibrous cements suggests early cementation of Facies 1, 2, 3 and 4 under marine conditions, initially as aragonite which has since inverted to calcite. Facies 5, 6 and 7 are cemented only by equant calcite spar, evidence of cementation in the meteoric phreatic and vadose zones. Lowering of the water table during regression caused the remaining pore space in Facies 1, 2, 3 and 4 to be filled with equant calcite spar. Decementation in a 130 cm wide zone is attributed to water table shifts associated with the later transgression which deposited Facies 8. The vertical stacking of the two depositional sequences may be attributed to rapid cementation of Facies 2, 3, 4, 5, 6 and 7 under humid, subtropical conditions. This lithified sequence then acted as a focus for deposition of coarse-grained shoreline facies (Facies 8) during the subsequent transgression.

Marine Geology↗

USGS1991

Modes of cross-shore sediment transport on the shoreface of the Middle Atlantic Bight

The mechanisms responsible for onshore and offshore sediment fluxes across the shoreface zone seaward of the surf zone were examined in a 3-year field study. The study was conducted in the southern part of the Middle Atlantic Bight in the depth region 7–17 m using instrumented tripods supporting electromagnetic current meters, pressure sensors, suspended sediment concentration sensors, and sonar altimeters. The observations embraced fairweather, moderate energy, swell-dominated, and storm conditions. Cross-shore mean flows ranged from near zero during fairweather to > 20 cm s −1 during the storm; oscillatory flows were on the order of 10 cm s −1 during fairweather and 100 cm s −1 during the storm. Suspended sediment concentrations at about 10 cm above the bed were < 0.1 kg m −3 under fairweather conditions, 1–2 kg m −3 under moderate swell conditions, and > 5 kg m −3 during the storm. Three methods were applied to evaluate the relative importance of incident waves, long-period oscillations, mean flows and gravity in effecting shoreward or seaward sediment flux: (1) an energetics transport model was applied to instantaneous near-bottom velocity data, (2) higher moments of near-bottom flows were estimated and compared, and (3) suspended sediment fluxes were estimated directly from the instantaneous products of cross-shore velocity and suspended sediment concentration. The results show that measurable contributions were made by all four of the processes. Most significantly, mean flows were seen to dominate and cause offshore fluxes during the storm and to contribute significantly to onshore and offshore flux during fairweather and moderate energy. Incident waves were, in all cases, the major source of bed shear stress but also caused shoreward as well as seaward net sediment advection. Low-frequency effects involving wave groups and long-period waves made secondary contributions to cross-shore sediment flux. Contrary to expectations, low-frequency fluxes were just as often shoreward as seaward. Whereas cross-correlations between suspended sediment concentration and the instantaneous near-bottom current speed were high and in phase under storm conditions, they were weak and out of phase during fairweather conditions. This suggests that simple energetics models are probably inadequate for predicting fairweather transport of suspended sediment.

Middle Atlantic Bight↗

USGS1989

The Richter scale: its development and use for determining earthquake source parameters

The M L scale, introduced by Richter in 1935, is the antecedent of every magnitude scale in use today. The scale is defined such that a magnitude-3 earthquake recorded on a Wood-Anderson torsion seismometer at a distance of 100 km would write a record with a peak excursion of 1 mm. To be useful, some means are needed to correct recordings to the standard distance of 100 km. Richter provides a table of correction values, which he terms -log A o , the latest of which is contained in his 1958 textbook. A new analysis of over 9000 readings from almost 1000 earthquakes in the southern California region was recently completed to redetermine the -log A o values. Although some systematic differences were found between this analysis and Richter's values (such that using Richter's values would lead to under and overestimates of M L at distances less than 40 km and greater than 200 km, respectively), the accuracy of his values is remarkable in view of the small number of data used in their determination. Richter's corrections for the distance attenuation of the peak amplitudes on Wood-Anderson seismographs apply only to the southern California region, of course, and should not be used in other areas without first checking to make sure that they are applicable. Often in the past this has not been done, but recently a number of papers have been published determining the corrections for other areas. If there are significant differences in the attenuation within 100 km between regions, then the definition of the magnitude at 100 km could lead to difficulty in comparing the sizes of earthquakes in various parts of the world. To alleviate this, it is proposed that the scale be defined such that a magnitude 3 corresponds to 10 mm of motion at 17 km. This is consistent both with Richter's definition of M L at 100 km and with the newly determined distance corrections in the southern California region. Aside from the obvious (and original) use as a means of cataloguing earthquakes according to size, ML has been used in predictions of ground shaking as a function of distance and magnitude; it has also been used in estimating energy and seismic moment. There is a good correlation of peak ground velocity and the peak motion on a Wood-Anderson instrument at the same location, as well as an observationally defined (and theoretically predicted) nonlinear relation between M L and seismic moment. An important byproduct of the establishment of the M L scale is the continuous operation of the network of Wood-Anderson seismographs on which the scale is based. The records from these instruments can be used to make relative comparisons of amplitudes and waveforms of recent and historic earthquakes; furthermore, because of the moderate gain, the instruments can write onscale records from great earthquakes at teleseismic distances and thus can provide important information about the energy radiated from such earthquakes at frequencies where many instruments have saturated.

California↗

USGS1992

Speculations on the origin of the North American Midcontinent rift

The Midcontinent rift is an example of lithospheric extension and flood basalt volcanism induced when a new mantle plume arrived near the base of the lithosphere. Very large volumes of basaltic magma were generated and partly erupted before substantial lithospheric extension began. Volcanism continued, along with extension and deep rift subsidence, for the ensuing 15 m.y. Much of the basaltic magma, including some of the earliest flows, was formed by partial melting of isotopically primitive asthenosphere contained in the plume head. The intense but relatively short duration of rifting and magmatism is a result of the dissipation of thermal and mechanical energy in the plume head. As the plume head spread beneath the lithosphere, it stretched the overlying lithosphere radially away from the Lake Superior region, the triple junction of the rift system, and partially melted to form the great volume of basalt and related intrusive rocks of the region. The plume arrived beneath a continent that was under compression as a result of the ongoing Grenville orogeny that affected a large region east of the rift. That compression prevented full continental separation and eventually returned the region to compressional tectonics as the energy of the plume head waned.

Midcontinental rift↗

USGS1968

The relationship of geophysical measurements to engineering and construction parameters in the Straight Creek Tunnel pilot bore, Colorado

Seismic-refraction and electrical-resistivity measurements made along the walls of the Straight Creek Tunnel pilot bore indicate that both a low-velocity and a high-resistivity layer exist in the disturbed rock surrounding the excavation. Seismic measurements were analyzed to obtain the thickness and seismic velocity of rock in the low-velocity layer, the velocity of rock behind the layer and the amplitude of seismic energy received at the detectors. Electrical-resistivity measurements were analyzed to obtain the thickness and electrical resistivity of the high-resistivity layer and the resistivity of rock behind the layer. The electrical resistivity and the seismic velocity of rock at depth, the thickness of rock in the low-velocity layer, and the relative amplitude of seismic energy were correlated against the following parameters, all of which are important in tunnel construction: height of the tension arch, stable vertical rock load, rock quality, rate of construction and cost per foot, percentage of lagging and blocking, set spacing, and type and amount of steel support required, The correlations were statistically meaningful, having correlation coefficients ranging in absolute value from about 0·7 to nearly 1·0. This finding suggests the possibility of predicting parameters of interest in tunnel construction from geophysical measurements made in feeler holes drilled ahead of a working face. Predictions might be based on correlations established either during the early stages of construction or from geophysical surveys in other tunnels of similar design in similar geologic environments.

Colorado↗

USGS1995

Woody vegetation and channel morphogenesis in low-gradient, gravel-bed streams in the Ozarks Plateaus, Missouri and Arkansas

Woody vegetation affects channel morphogenesis in Ozark streams of Missouri and Arkansas by increasing local roughness, increasing bank strength, providing sedimentation sites, and creating obstructions to flow. Variations in physiographic controls on channel morphology result in systematic changes in vegetation patterns and geomorphic functions with increasing drainage basin area. In upstream reaches, streams have abundant bedrock control and bank heights that typically are less than or equal to the rooting depth of trees. In downstream reaches where valleys are wider and alluvial banks are higher vegetation has different geomorphic functions. At drainage areas of greater than 100–200 kM 2 , Ozarks streams are characterized by longitudinally juxtaposed reaches of high and low lateral channel migration rates, referred to as disturbance reaches and stable reaches, respectively. Whereas stable reaches can develop stable forested floodplains (if they are not farmed), disturbance reaches are characterized by dynamic vegetation communities that interact with erosion and deposition processes. Disturbance reaches can be subdivided into low-gradient and high-gradient longitudinal zones. Low-energy zones are characterized by incremental, unidirectional lateral channel migration and deposition of gravel and sand bars. The bars are characterized by prominent bands of woody vegetation and ridge and swale topography. Channel monitoring data indicate that densely vegetated bands of woody vegetation formed depositional sites during bedload-transporting events. The same floods caused up to 20 m of erosion of adjacent cutbanks, scoured non-vegetated areas between vegetation bands, and increased thalweg depth and definition. In high-energy (or riffle) zones, channel movement is dominantly by avulsion. In these zones, vegetation creates areas of erosional resistance that become temporary islands as the channel avulses around or through them. Woody vegetation on islands creates steep, root-defended banks that contribute to narrow channels with high velocities. Calculation of hydraulic roughness from density and average diameter of woody vegetation groups of different ages indicates that flow resistance provided by vegetation decreases systematically with group age, mainly through decreasing stem density. If all other factors remain constant, the stabilizing effect of a group of woody vegetation on a gravel bar decreases with vegetation age.

Geomorphology↗

USGS1990

Collection and analysis of colloidal particles transported in the Mississippi River, U.S.A.

Sediment transport has long been recognized as an important mechanism for the transport of contaminants in surface waters. Suspended sediment has traditionally been divided into three size classes: sand-sized (>63 ??m), silt-sized (<63 ??m but settleable) and clay-sized (non-settleable). The first two classes are easily collected and characterized using screens (sand) and settling (silt). The clay-sized particles, more properly called colloids, are more difficult to collect and characterize, and until recently received little attention. From the hydrologic perspective, a colloid is a particle, droplet, or gas bubble with at least one dimension between 0.001 and 1 ??m. Because of their small size, colloids have large specific surface areas and high surface free energies which may facilitate sorption of hydrophobic materials. Understanding what types of colloids are present in a system, how contaminants of interest interact with these colloids, and what parameters control the transport of colloids in natural systems is critical if the relative importance of colloid-mediated transport is to be understood. This paper describes the collection, concentration and characterization of colloidal materials in the Mississippi River. Colloid concentrations, particle-size distributions, mineral composition and electrophoretic mobilities were determined. Techniques used are illustrated with samples collected at St. Louis, Missouri, U.S.A.Sediment transport has long been recognized as an important mechanism for the transport of contaminants in surface waters. Suspended sediment has traditionally been divided into three size classes: sand-sized (> 63 ??m), silt-sized (< 63 ??m but settleable) and clay-sized (non-settleable). The first two classes are easily collected and characterized using screens (sand) and settling (silt). The clay-sized particles, more properly called colloids, are more difficult to collect and characterize, and until recently received little attention. From the hydrologic perspective, a colloid is a particle, droplet, or gas bubble with at least one dimension between 0.001 and 1 ??m. Because of their small size, colloids have large specific surface areas and high surface free energies which may facilitate sorption of hydrophobic materials. Understanding what types of colloids are present in a system, how contaminants of interest interact with these colloids, and what parameters control the transport of colloids in natural systems is critical if the relative importance of colloid-mediated transport is to be understood. This paper describes the collection, concentration and characterization of colloidal materials in the Mississippi River. Colloid concentrations, particle-size distributions, mineral composition and electrophoretic mobilities were determined. Techniques used are illustrated with samples collected at St. Louis, Missouri, U.S.A.

Journal of Contaminant Hydrology↗

USGS1985

Catastrophic eruptions of the directed-blast type at Mount St. Helens, Bezymianny and Shiveluch volcanoes

This paper describes catastrophic eruptions of Mount St. Helens (1980), Bezymianny (1955–1956), and Shiveluch (1964) volcanoes. A detailed description of eruption stages and their products, as well as the quantitative characteristics of the eruptive process are given. The eruptions under study belong to the directed-blast type. This type is characterized by the catastrophic character of the climatic stage during which a directed blast, accompanied by edifice destruction, the profound ejection of juvenile pyroclastics and the formation of pyroclastic flows, occur. The climatic stage of all three eruptions has similar characteristics, such as duration, kinetic energy of blast (10 17 −10 18 J), the initial velocity of debris ejection, morphology and size of newly-formed craters. But there are also certain differences. At Mount St. Helens the directed blast was preceeded by failure of the edifice and these events produced separable deposits, namely debris avalanche and directed blast deposits which are composed of different materials and have different volumes, thickness and distribution. At Bezymianny, failure did not precede the blast and the whole mass of debris of the old edifice was outburst only by blast. The resulting deposits, represented by the directed blast agglomerate and sand facies, have characteristics of both the debris avalanche and the blast deposit at Mount St. Helens. At Shiveluch directed-blast deposits are represented only by the directed-blast agglomerate; the directed-blast sand facies, or blast proper, seen at Mount St. Helens is absent. During the period of Plinian activity, the total volumes of juvenile material erupted at Mount St. Helens and at Besymianny were roughly comparable and exceeded the volume of juvenile material erupted at Shiveluch, However, the volume of pyroclastic-flow deposits erupted at Mount St. Helens was much less. The heat energy of all three eruptions is comparable: 1.3 × 10 18 , 3.8−4.8 × 10 18 and 1 × 10 17 J for Shiveluch, Bezymianny, and Mount St. Helens, respectively.

Journal of Geodynamics↗

USGS1996

Amplitude blanking in seismic profiles from Lake Baikal

Imaging of the deepest sedimentary section in Lake Baikal using multichannel seismic profiling was hampered by amplitude blanking that is regionally extensive, is associated with water depths greater than about 900 m and occurs at sub-bottom depths of 1-2 km in association with the first water-bottom multiple. Application of a powerful multiple suppression technique improved the quality of occasional discontinuous, dipping primary reflections, but failed to substantially alter the non-reflective character of the blanking zone. Detailed analysis of amplitudes from original data and synthetic models show that the threshold for detecting primary energy in deep water of Lake Baikal occurs when the primary is about 14-20 dB less than the multiple energy. The blanking occurs because of anomalously low reflectivities of the deep sediments coupled with this 20 dB limitation in real data processing. The blanking cuts across seismic stratal boundaries, and is therefore probably unrelated to depositional lithologies. The deepest, early rift deposits, inferred to come from a mixed fluvial and lacustrine setting, do not easily explain the widespread and uniform character of the blanked deposits. More likely, blanking occurs because of processes or phenomena that physically alter the deposits, causing them to be non-reflective and/or highly attenuating. No single process explains all the observations, but a combination of diagenesis, overpressure, and the presence of dispersed free gas at sub-bottom depths of 1-2 km, offer plausible and possible conditions that contribute to blanking. Copyright ?? 1996 Published by Elsevier Science Ltd.

Marine and Petroleum Geology↗

USGS1984

Thermal modeling of Halley's comet

The comet thermal model of Weissman and Kieffer is used to calculate gas production rates and other parameters for the 1986 perihelion passage of Halley's Comet. Gas production estimates are very close to revised pre-perihelion estimates by Newburn based on 1910 observations of Halley; the increase in observed gas production post-perihelion may be explained by a variety of factors. The energy contribution from multiply scattered sunlight and thermal emission by coma dust increases the total energy reaching the Halley nucleus at perihelion by a factor of 2.4. The high obliquity of the Halley nucleus found by Sekanina and Larson may help to explain the asymmetry in Halley's gas production rates around perihelion. ?? 1984.

Advances in Space Research↗

USGS1988

Near-bottom currents over the continental slope in the Mid-Atlantic Bight

From a set of 28 current meter records we have found that near-bottom currents faster than 0.2 m s-1 occur frequently over the outer continental shelf of the Mid-Atlantic Bight (bottom depth <210 m) but very rarely (<1% of the time) between bottom depths of 500 m and 2 km over the slope. The rarity of strong near-bottom flow over the middle and lower slope allows the accumulation of fine-grained sediment and organic carbon in this region. Fast near-bottom currents which do occur over the slope are invariably associated with topographic waves, although it is often superimposed inertial oscillations which increase current speed above the level of 0.2 m s-1. Episodes of intense inertial oscillations occur randomly and last typically for 10-20 days. Their energy source is unknown. Topographic wave energy exhibits a slight, but statistically significant, minimum over the mid-slope. These waves appear irregularly and vary both along isobaths and in time. The irregularity is presumably a consequence of random topographic wave generation by Gulf Stream instability. The current regime within sea-floor depressions in the slope (canyons and gullies) is distinctly different from that of the open slope; most notable is the near absence of topographic wave motion within depressions.

Continental Shelf Research↗

USGS1982

Analytical electron microscopy in mineralogy; exsolved phases in pyroxenes

Analytical scanning transmission electron microscopy has been successfully used to characterize the structure and composition of lamellar exsolution products in pyroxenes. At operating voltages of 100 and 200 keV, microanalytical techniques of x-ray energy analysis, convergent-beam electron diffraction, and lattice imaging have been used to chemically and structurally characterize exsolution lamellae only a few unit cells wide. Quantitative X-ray energy analysis using ratios of peak intensities has been adopted for the U.S. Geological Survey AEM in order to study the compositions of exsolved phases and changes in compositional profiles as a function of time and temperature. The quantitative analysis procedure involves 1) removal of instrument-induced background, 2) reduction of contamination, and 3) measurement of correction factors obtained from a wide range of standard compositions. The peak-ratio technique requires that the specimen thickness at the point of analysis be thin enough to make absorption corrections unnecessary (i.e., to satisfy the “thin-foil criteria”). In pyroxenes, the calculated “maximum thicknesses” range from 130 to 1400 nm for the ratios Mg/Si, Fe/Si, and Ca/Si; these “maximum thicknesses” have been contoured in pyroxene composition space as a guide during analysis. Analytical spatial resolutions of 50–100 nm have been achieved in AEM at 200 keV from the composition-profile studies, and analytical reproducibility in AEM from homogeneous pyroxene standards is ± 1.5 mol% endmember.

Ultramicroscopy↗

USGS1980

Emission spectra of the cations of some fluoro-substituted phenols in the gaseous phase

Emission spectra of the cations of 2,5- and 3,5-difluorophenol, of 2,3,4- and 2,4,5-trifluorophenol, of 2,3,5,6-tetrafluorophenol and of 2,3,4,5,6-pentafluorophenol have been obtained in the gas phase using low-energy electron beam excitation. The band systems are assigned to the B̃ (π −1 ) → X̃ (π −1 ) electronic transitions of these cations by reference to photoelectron spectroscopic data. The He(Iα) photoelectron spectra and the ionisation energies of ten fluoro-substituted phenols are reported. The symmetries of the four lowest electronic states of these cations are inferred from the radiative decay studies. The lifetimes of the lowest vibrational levels of the B̃ (π −1 ) state of the six fluoro-substituted phenol cations above have also been measured.

Journal of Electron Spectroscopy and Related Pheno↗

USGS1995

Graphical and PC-software analysis of volcano eruption precursors according to the Materials Failure Forecast Method (FFM)

The Materials Failure Forecasting Method for volcanic eruptions (FFM) analyses the rate of precursory phenomena. Time of eruption onset is derived from the time of “failure” implied by accelerating rate of deformation. The approach attempts to fit data, Ω, to the differential relationship Ω Ω ¨ = A Ω ˙ "> ¨ = AΩ˙ , where the dot superscript represents the time derivative, and the data Ω may be any of several parameters describing the accelerating deformation or energy release of the volcanic system. Rate coefficients, A and α, may be derived from appropriate data sets to provide an estimate of time to “failure”. As the method is still an experimental technique, it should be used with appropriate judgment during times of volcanic crisis. Limitations of the approach are identified and discussed. Several kinds of eruption precursory phenomena, all simulating accelerating creep during the mechanical deformation of the system, can be used with FFM. Among these are tilt data, slope-distance measurements, crater fault movements and seismicity. The use of seismic coda, seismic amplitude-derived energy release and time-integrated amplitudes or coda lengths are examined. Usage of cumulative coda length directly has some practical advantages to more rigorously derived parameters, and RSAM and SSAM technologies appear to be well suited to real-time applications. One graphical and four numerical techniques of applying FFM are discussed. The graphical technique is based on an inverse representation of rate versus time. For α = 2, the inverse rate plot is linear; it is concave upward for α < 2 and concave downward for α > 2. The eruption time is found by simple extrapolation of the data set toward the time axis. Three numerical techniques are based on linear least-squares fits to linearized data sets. The “linearized least-squares technique” is most robust and is expected to be the most practical numerical technique. This technique is based on an iterative linearization of the given rate-time series. The hindsight technique is disadvantaged by a bias favouring a too early eruption time in foresight applications. The “log rate versus log acceleration technique”, utilizing a logarithmic representation of the fundamental differential equation, is disadvantaged by large data scatter after interpolation of accelerations. One further numerical technique, a nonlinear least-squares fit to rate data, requires special and more complex software. PC-oriented computer codes were developed for data manipulation, application of the three linearizing numerical methods, and curve fitting. Separate software is required for graphing purposes. All three linearizing techniques facilitate an eruption window based on a data envelope according to the linear least-squares fit, at a specific level of confidence, and an estimated rate at time of failure.

Journal of Volcanology and Geothermal Research↗