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Selected trace-element and organic contaminants in streambed sediments of the Potomac River Basin, August 1992

This report describes the occurrence and distribution of five selected contaminants in streambed sediments at 22 stream sites in the Potomac River Basin. Lead, mercury, and total DDT (dichlorodiphenyltrichloroethane) were detected at all sites, and chlordane and total PCB's (polychlorinated biphenyls) were detected at most sites. At six sites, streambed-sediment concentrations of contaminants were detected at levels with the potential to cause frequent adverse effects on aquatic organisms that live in the sediments. Chlordane was detected at these high levels at sampling sites on the Anacostia River, the North Branch Potomac River, Bull Run, and Accotink Creek; mercury was detected at these levels at sites on the South River and the South Fork Shenandoah River; and total PCB's were detected at these levels at the site on the South Fork Shenandoah River. The highest concentrations of all five contaminants generally occurred at sampling sites downstream from areas with industrial plants, urban centers, or orchard and agricultural activity. The occurrence of these contaminants in streambed sediments of the Potomac River Basin is of concern because the contaminants (1) are environmentally persistent, (2) are available for downstream transport during high streamflow periods, and (3) have the potential to cause adverse effects on the health of aquatic organisms and humans through bioaccumulation.

Potomac River Basin↗

Particle morphology and elemental analysis of lung tissue from post-9/11 military personnel with biopsy-proven lung disease

The relationship between exposure to inhaled inorganic particulate matter and risk for deployment-related lung disease in military personnel is unclear due in part to difficulties characterizing individual exposure to airborne hazards. We evaluated the association between self-reported deployment exposures and particulate matter (PM) contained in lung tissue from previously deployed personnel with lung disease (“deployers”). The PM in deployer tissues was compared to normal lung tissue PM using the analytical results of scanning electron microscopy and inductively coupled plasma mass spectrometry. The majority of PM phases for both the deployers and the controls were sub-micrometer in size and were compositionally classified as aluminum and zirconium oxides, carbonaceous particles, iron oxides, titanium oxides, silica, other silicates, and other metals. The proportion of silica and other silicates was significantly higher in the retained dust from military veterans with biopsy-confirmed deployment-related lung disease compared to the control subjects. Within the deployer population, those who had combat jobs had a higher total PM burden, though the difference was not statistically significant. These findings have important implications for understanding the role of inhaled inorganic dusts in the risk for lung injury in previously deployed military veterans.

International Journal of Enviornmental Research an↗

The solubilities of some major and minor element minerals in ground waters associated with a sandstone-hosted uranium deposit

Ground-water samples from 41 wells penetrating basal Oakville sandstone (Miocene) in S Texas were chemically analysed to identify chemical changes related to nearby U orebodies. The coverage included a 240 km 2 area which contains several fault-related U deposits. Factors affecting the hydrochemistry include: 1) relatively high permeabilities of buried fluvial-channel sediments; 2) upwards leakage of brines along growth faults into the aquifer; 3) development of a redox interface (Eh = 0 volts) within the aquifer; and 4) the semi-arid climate. Variations in the saturation index (SI) for chemically reduced minerals of U, As, Mo, Se and for associated minerals such as pyrite outlined the position of known deposits. The SI increases towards zero as the deposits are approached from updip distances of 3-4.5 km, then decreases again downdip. The radiogenic pathfinders Ra and Rn showed very strong anomalies with ore, but diminished to background levels at short distances from ore. A strong He anomaly is deflected in the direction of ground-water flow away from the ore.-R.A.H.

Bulletin de Mineralogie↗

Examination of the Reelfoot Rift Petroleum System, south-central United States, and the elements that remain for potential exploration and development

The Reelfoot rift is one segment of a late Proterozoic(?) to early Paleozoic intracontinental rift complex in the south-central United States. The rift complex is situated beneath Mesozoic to Cenozoic strata of the Mississippi embayment of southeastern Missouri, northeastern Arkansas, and western Tennessee and Kentucky. The rift portion of the stratigraphic section consists primarily of synrift Cambrian and Ordovician strata, capped by a postrift sag succession of Late Ordovician to Cenozoic age. Potential synrift source rocks have been identified in the Cambrian Elvins Shale. Thermal maturity of Paleozoic strata within the rift ranges from the oil window to the dry gas window. Petroleum generation in Elvins source rocks likely occurred during the middle to late Paleozoic. Upper Cretaceous sedimentary rocks unconformably overlie various Paleozoic units and define the likely upper boundary of the petroleum system. No production has been established in the Reel-foot rift. However, at least nine of 22 exploratory wells have reported petroleum shows, mainly gas shows with some asphalt or solid hydrocarbon residue. Regional seismic profiling shows the presence of two large inversion structures (Blytheville arch and Pascola arch). The Blytheville arch is marked by a core of structurally thickened Elvins Shale, whereas the Pascola arch reflects the structural uplift of a portion of the entire rift basin. Structural uplift and faulting within the Reelfoot rift since the late Paleozoic appear to have disrupted older conventional hydrocarbon traps and likely spilled any potential conventional petroleum accumulations. The remaining potential resources within the Reelfoot rift are likely shale gas accumulations within the Elvins Shale; however, reservoir continuity and porosity as well as pervasive faulting appear to be significant future challenges for explorers and drillers.

GCSSEPM Foundation Perkins-Rosen Research Conferen↗

Trace elements, organochlorines, polycyclic aromatic hydrocarbons, dioxins, and furans in lesser scaup wintering on the Indiana Harbor Canal

During the winter of 1993a??94, male lesser scaup (Aythya affinis) were collected on the heavily polluted Indiana Harbor Canal (IHC), East Chicago, IN, USA, and examined for tissue contaminant levels. Lesser scaup collected on the IHC had higher concentrations of cadmium (Cd), mercury (Hg), selenium (Se), polychlorinated biphenyls (PCBs), selected organchlorine pesticides, polychlorinated dibenzodioxins, polychlorinated dibenzofurans, polycyclic aromatic hydrocarbons, and aliphatic hydrocarbons than reference birds. Of the scaup collected on the IHC, 44% had Cd concentrations in the liver considered above background for freshwater waterfowl (>3 I?g/g dry wt.), 50% had Se concentrations in the liver above a level possibly harmful to the health of young and adult birds (>33 I?g/g dry wt.), and 88% of the scaup carcasses exceeded the PCB human consumption guidelines for edible poultry in the USA (>3.0 I?g/g lipid wt.). The ratio of pristane:n-heptadecane concentrations in 47% of lesser scaup collected on IHC was elevated above 1.0, which is indicative of chronic exposure to petroleum hydrocarbons. Copyright A? 2009 Elsevier B.V.

Environmental Pollution↗