USGS Science⌕ Search

SEARCH · USGS Science

Results for “Complexity”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,351 records · Page 75Linked to original sources

The speciation of aqueous zinc(II) bromide solutions to 500 °C and 900 MPa determined using Raman spectroscopy

A Raman spectral study was carried out on 3 solutions of varying concentration and bromide/zinc ratios. Spectra were collected at 11 different temperature-pressure conditions ranging from ambient to 500????C-0.9??GPa. Raman band assignments for zinc(II) bromide species reported in previous studies were used to determine the relative concentrations of ZnBr42-, ZnBr3-, ZnBr2, and ZnBr+ species at various temperatures and pressures. Our results are in close agreement with X-ray absorption spectroscopic (XAS) data, and confirm that the tetrabromo zinc(II) complex, ZnBr42-, is the predominant species up to 500????C in solutions having high Zn concentrations (1??m) and high bromide/zinc molar ratios ([Br]/[Zn] = 8). In agreement with previous solubility and Raman spectroscopic experiments, our measurements indicate that species with a lower number of halide ligands and charge are favored with increasing temperature in dilute solutions, and solutions with low bromide/zinc ratios ([Br]/[Zn] < 2.5). The Raman technique provides an independent experimental means of evaluating the quality of XAS analyses of data obtained from high temperature disordered systems. The combination of these two techniques provides complementary data on speciation and the structure of zinc(II) bromide complexes. The preponderance of the ZnBr42- species in highly saline brines at high temperature is consistent with the predominance of ZnCl42- in chloride-rich brines reported in previous XAS studies. Knowledge of Zn complexing in metal-rich highly saline brines is important for numerical models of ore deposition in high temperature systems such as skarns and porphyry-type deposits. ?? 2008 Elsevier B.V.

Chemical Geology↗

The estuarine chemistry and isotope systematics of 234,238U in the Amazon and Fly Rivers

Natural concentrations of 238U and ??234U values were determined in estuarine surface waters and pore waters of the Amazon and Fly (Papua New Guinea) Rivers to investigate U transport phenomena across river-dominated land-sea margins. Discharge from large, tropical rivers is a major source of dissolved and solid materials transported to the oceans, and are important in defining not only oceanic mass budgets, but also terrestrial weathering rates. On the Amazon shelf, salinity-property plots of dissolved organic carbon, pH and total suspended matter revealed two vastly contrasting water masses that were energetically mixed. In this mixing zone, the distribution of uranium was highly non-conservative and exhibited extensive removal from the water column. Uranium removal was most pronounced within a salinity range of 0-16.6, and likely the result of scavenging and flocculation reactions with inorganic (i.e., Fe/Mn oxides) and organic colloids/particles. Removal of uranium may also be closely coupled to exchange and resuspension processes at the sediment/water interface. An inner-shelf pore water profile indicated the following diagenetic processes: extensive (???1 m) zones of Fe(III) - and, to a lesser degree, Mn(IV) - reduction in the absence of significant S(II) concentrations appeared to facilitate the formation of various authigenic minerals (e.g., siderite, rhodocrosite and uraninite). The pore water dissolved 238U profile co-varied closely with Mn(II). Isotopic variations as evidenced in ??234U pore waters values from this site revealed information on the origin and history of particulate uranium. Only after a depth of about 1 m did the ??234U value approach unity (secular equilibrium), denoting a residual lattice bound uranium complex that is likely an upper-drainage basin weathering product. This suggests that the enriched ??234U values represent a riverine surface complexation product that is actively involved in Mn-Fe diagenetic cycles and surface complexation reactions. In the Fly River estuary, 238U appears to exhibit a reasonably conservative distribution as a function of salinity. The absence of observed U removal does not necessarily imply non-reactivity, but instead may record an integration of concurrent U removal and release processes. There is not a linear correlation between ??234U vs. 1/ 238U that would imply simple two component mixing. It is likely that resuspension of bottom sediments, prolonged residence times in the lower reaches of the Fly River, and energetic particle-colloid interactions contribute to the observed estuarine U distribution. The supply of uranium discharged from humid, tropical river systems to the sea appears to be foremost influenced by particle/water interactions that are ultimately governed by the particular physiographic and hydrologic characteristics of an estuary. ?? 2004 Elsevier Ltd. All rights reserved.

Continental Shelf Research↗

Influence of variable chemical conditions on EDTA-enhanced transport of metal ions in mildly acidic groundwater

Adsorption of Ni and Pb on aquifer sediments from Cape Cod, Massachusetts, USA increased with increasing pH and metal-ion concentration. Adsorption could be described quantitatively using a semi-mechanistic surface complexation model (SCM), in which adsorption is described using chemical reactions between metal ions and adsorption sites. Equilibrium reactive transport simulations incorporating the SCMs, formation of metal-ion-EDTA complexes, and either Fe(III)-oxyhydroxide solubility or Zn desorption from sediments identified important factors responsible for trends observed during transport experiments conducted with EDTA complexes of Ni, Zn, and Pb in the Cape Cod aquifer. Dissociation of Pb-EDTA by Fe(III) is more favorable than Ni-EDTA because of differences in Ni- and Pb-adsorption to the sediments. Dissociation of Ni-EDTA becomes more favorable with decreasing Ni-EDTA concentration and decreasing pH. In contrast to Ni, Pb-EDTA can be dissociated by Zn desorbed from the aquifer sediments. Variability in adsorbed Zn concentrations has a large impact on Pb-EDTA dissociation.

Environmental Pollution↗

A cross-validation package driving Netica with python

Bayesian networks (BNs) are powerful tools for probabilistically simulating natural systems and emulating process models. Cross validation is a technique to avoid overfitting resulting from overly complex BNs. Overfitting reduces predictive skill. Cross-validation for BNs is known but rarely implemented due partly to a lack of software tools designed to work with available BN packages. CVNetica is open-source, written in Python, and extends the Netica software package to perform cross-validation and read, rebuild, and learn BNs from data. Insights gained from cross-validation and implications on prediction versus description are illustrated with: a data-driven oceanographic application; and a model-emulation application. These examples show that overfitting occurs when BNs become more complex than allowed by supporting data and overfitting incurs computational costs as well as causing a reduction in prediction skill. CVNetica evaluates overfitting using several complexity metrics (we used level of discretization) and its impact on performance metrics (we used skill).

Environmental Modelling and Software↗

Isotope geochemistry of mercury in source rocks, mineral deposits and spring deposits of the California Coast Ranges, USA

We present here the first study of the isotopic composition of mercury in rocks, ore deposits, and active spring deposits from the California Coast Ranges, a part of Earth's crust with unusually extensive evidence of mercury mobility and enrichment. The Franciscan Complex and Great Valley Sequence, which form the bedrock in the California Coast Ranges, are intruded and overlain by Tertiary volcanic rocks including the Clear Lake Volcanic Sequence. These rocks contain two types of mercury deposits, hot-spring deposits that form at shallow depths (< 300??m) and silica-carbonate deposits that extend to depths of 1000??m. Active springs and geothermal areas continue to precipitate Hg and Au and are modern analogues to the fossil hydrothermal systems preserved in the ore deposits. The Franciscan Complex and Great Valley Sequence contain clastic sedimentary rocks with higher concentrations of mercury than volcanic rocks of the Clear Lake Volcanic Field. Mean mercury isotopic compositions (??202Hg) for all three rock units are similar, although the range of values in Franciscan Complex rocks is greater than in either Great Valley or Clear Lake rocks. Hot spring and silica-carbonate mercury deposits have similar average mercury isotopic compositions that are indistinguishable from averages for the three rock units, although ??202Hg values for the mercury deposits have a greater variance than the country rocks. Precipitates from spring and geothermal waters in the area have similarly large variance and a mean ??202Hg value that is significantly lower than the ore deposits and rocks. These observations indicate that there is little or no isotopic fractionation (< ?? 0.5???) during release of mercury from its source rocks into hydrothermal solutions. Isotopic fractionation does appear to take place during transport and concentration of mercury in deposits, however, especially in their uppermost parts. Boiling of hydrothermal fluids, separation of a mercury-bearing CO2 vapor or reduction and volatilization of Hg(0) in the near-surface environment are likely the most important processes causing the observed Hg isotope fractionation. This should result in the release of mercury with low ??202Hg values into the atmosphere from the top of these hydrothermal systems. Estimates of mass balance suggest that residual Hg reservoirs are not measurably enriched in heavy Hg isotopes as a result of this process because only a small amount of Hg (< 4%) leaves actively ore-forming systems. ?? 2008 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗

Geochemical evidence for evolving Proterozoic crustal thickness and orogenic styles in southwestern Laurentia

It has long been challenging for researchers to track the crustal thickness and mode(s) of crustal modification in ancient convergent margins, limiting evaluation of the tectonic styles and processes that modify continental crust during orogenesis. We present trace element igneous geochemical crustal thickness proxies that quantitatively track the crustal thickness evolution of the long-lived Proterozoic active margin in the southwestern U.S.A. We integrate these results with geobarometric data to constrain the mode of crustal modification. The data indicate a complex record of crustal thickness change in space and time and evolving orogenic styles. Geochemical proxies at 1.84–1.72 Ga are consistent with 20–40 km thick magmatic arcs that were locally thickened to ∼50 km during ∼1.75 Ga tectonism. During the Yavapai orogeny, 1.72–1.69 Ga, a ∼200-km-wide belt of 50-60 km thick crust extended from southern California to northern Colorado and was rapidly thinned and exhumed by ∼1.68 Ga. Crustal thickening and thinning during the Yavapai orogeny largely occurred by shortening and exhumation, respectively, in the upper 25 km of the crust. Subsequent 1.68–1.60 Ga tectonism involved crustal growth, local crustal thickening, and low-P, high-T metamorphism, consistent with extensional accretionary orogenesis. The 1.47–1.37 Ga Picuris orogeny was associated with 50–60 km thick crust across much of the Southwest and involved crustal shortening with ∼10 km of magmatic underplating. Advective heat from the emplacement of ferroan granites in the mid-crust likely contributed to elevated geothermal gradients and rheologically weakened the crust. Our results suggest evolving orogenic styles in the Southwest from 1.75–1.69 Ga short-lived crustal thickening associated with terrane accretion to 1.69–1.60 Ga largely extensional accretionary orogenesis, and regional, long-lived crustal thickening at 1.47–1.37 Ga involving extensive basaltic underplating. Contrasting with some recent hypotheses, our data document a complex middle Proterozoic record for the Southwest that was not orogenically quiescent or tectonically stagnant but involved complex mountain building styles.

Earth and Planetary Science Letters↗

Quantifying form resistance is essential for estimating summer low and bankfull flow from stream survey channel morphology

Reliable estimates of low flow and flood discharge at ungaged locations are required for evaluating stream flow alteration, designing culverts and stream crossings, and interpreting regional surveys of habitat and biotic condition. Very few stream gaging stations are located on small, remote streams, which typically have complex channel morphology. Adequate gaging is also lacking on larger streams that are remote, smaller than those typically gaged, or have channel morphology not conducive to installation of gages. Complex channels typically contain large scale hydraulic roughness elements that dominate flow patterns (i.e., form roughness), making it difficult to measure channel cross-section area and water velocity, or to measure channel volume even where discharge is known. In channels with large channel form roughness, it is equally difficult to estimate discharge using commonly applied equations based on slope and channel dimensions or basin area. We employed a novel approach that explicitly accounts for hydraulic resistance from large wood and riffle-pool morphology (form roughness) in calculating low flow and bankfull discharge from stream and river physical habitat data collected from 4229 stream and river sites in the conterminous US (CONUS) sampled in 2008–9 and 2013–14 as part of the US Environmental Protection Agency's N ational R ivers and S treams A ssessment (NRSA). Hydraulic resistance derived from form roughness clearly dominated resistance derived from bed particles (particle resistance) during summer low flows in wadeable streams across the spectrum of channel slopes and substrate sizes smaller than boulders. Under bankfull conditions, the influence of form resistance relative to particle resistance was diminished, but form resistance still dominated except in large low gradient rivers lacking complex channels, and in streams or rivers with boulder-size bed particles. We validated our hydraulic resistance estimates by comparing measured discharges with calculated discharges that used those hydraulic resistance estimates along with measured NRSA channel morphology data. Morphology-based summer discharge (low flow) estimates and direct field measurements of discharge in 2333 wadeable CONUS streams showed reasonable agreement (median difference < 2.5×) for discharges ranging from 3.6 × 10 −5 to 123 m 3 /s and drainage areas of 0.12 to 171,000 km 2 . In a subset of 759 of NRSA's larger wadeable stream and non-wadeable river sites where nearby U.S. Geological Survey (USGS) gage data were available and adequate, our morphology-based summer discharge estimates agreed fairly well (median difference < 2.0×) with USGS 20-yr average August mean flows ranging from 0.003 to 16,000 m 3 /s. Similarly, morphology-based estimates of bankfull flow ranging from 0.3 to 100,000 m 3 /s agreed reasonably well with the 1.5-yr recurrence interval flood in these gaged sites (median deviation <2.2×). These findings demonstrate the importance of quantifying flow resistance from large-scale form roughness features in natural channels and provide a novel approach for estimating discharge from widely available survey data. This will allow examination of discharge and its ecological influence across the full range of stream and river sizes sampled by NRSA or other synoptic surveys where comprehensive measures of biota, physical habitat, and chemistry are also made. Although these morphology-based estimates exhibit some variability, they are adequate for examining regional patterns in discharge and flow alteration and their association with instream biota and anthropogenic disturbances, providing summer low and bankfull flow information where reliable estimates are lacking.

Geomorphology↗

40 Ar/ 39 Ar geochronological constraints on the formation of the Dayingezhuang gold deposit: New implications for timing and duration of hydrothermal activity in the Jiaodong gold province, China

China's largest gold resource is located in the highly endowed northwestern part of the Jiaodong gold province. Most gold deposits in this area are associated with the NE- to NNE-trending shear zones on the margins of the 130&ndash;126 Ma Guojialing granite. These deposits collectively formed at ca. 120 &plusmn; 5 Ma during rapid uplift of the granite. The Dayingezhuang deposit is a large (> 120 t Au) orogenic gold deposit in the same area, but located along the eastern margin of the Late Jurassic Linglong Metamorphic Core Complex. New 40 Ar/ 39 Ar geochronology on hydrothermal sericite and muscovite from the Dayingezhuang deposit indicate the gold event is related to evolution of the core complex at 130 &plusmn; 4 Ma and is the earliest important gold event that is well-documented in the province. The Dayingezhuang deposit occurs along the Linglong detachment fault, which defines the eastern edge of the ca. 160&ndash;150 Ma Linglong granite&ndash;granodiorite massif. The anatectic rocks of the massif were rapidly uplifted, at rates of at least 1 km/m.y. from depths of 25&ndash;30 km, to form the metamorphic core complex. The detachment fault, with Precambrian metamorphic basement rocks in the hangingwall and the Linglong granitoids and migmatites in the footwall, is characterized by early mylonitization and a local brittle overprinting in the footwall. Gold is associated with quartz&ndash;sericite&ndash;pyrite&ndash;K-feldspar altered footwall cataclasites at the southernmost area of the brittle deformation along the detachment fault. Our results indicate that there were two successive, yet distinct gold-forming tectonic episodes in northwestern Jiaodong. One event first reactivated the detachment fault along the edge of the Linglong massif between 134 and 126 Ma, and then a second reactivated the shears along the margins of the Guojialing granite. Both events may relate to a component of northwest compression after a middle Early Cretaceous shift from regional NW&ndash;SE extension to a NE&ndash;SW extensional regime.

Gondwana Research↗

New U-series dates at the Caune de l'Arago, France

In the beginning of the 1980s, the Caune de l'Arago was the focus of an interdisciplinary effort to establish the chronology of the Homo heidelbergensis (Preneandertals) fossils using a variety of techniques on bones and on speleothems. The result was a very large spread of dates particularly on bone samples. Amid the large spread of results, some radiometric data on speleothems showed a convergence in agreement with inferences from faunal studies. We present new U-series results on the stalagmitic formation located at the bottom of Unit IV (at the base of the Upper Stratigraphic Complex). Samples and splits were collaboratively analyzed in the four different laboratories with excellent interlaboratory agreement. Results show the complex sequence of this stalagmitic formation. The most ancient part is systematically at internal isotopic equilibrium (>350 ka) suggesting growth during or before isotopic stage 9, representing a minimum age for the human remains found in Unit III of the Middle Stratigraphical Complex which is stratigraphically under the basis of the studied stalagmitic formation. Overlaying parts of the speleothem date to the beginning of marine isotope stages 7 and 5. ?? 2003 Elsevier Science Ltd. All rights reserved.

Caune de l'Arago↗

EXAFS study of mercury(II) sorption to Fe- and Al-(hydr)oxides - II. Effects of chloride and sulfate

Common complexing ligands such as chloride and sulfate can significantly impact the sorption of Hg(II) to particle surfaces in aqueous environmental systems. To examine the effects of these ligands on Hg(II) sorption to mineral sorbents, macroscopic Hg(II) uptake measurements were conducted at pH 6 and [Hg]i=0.5 mM on goethite (??-FeOOH), ??-alumina (??-Al2O3), and bayerite (??-Al(OH)3) in the presence of chloride or sulfate, and the sorption products were characterized by extended X-ray absorption fine structure (EXAFS) spectroscopy. The presence of chloride resulted in reduced uptake of Hg(II) on all three substrates over the Cl- concentration ([Cl-]) range 10-5 to 10-2 M, lowering Hg surface coverages on goethite, ??-alumina, and bayerite from 0.42 to 0.07 ??mol/m2, 0.06 to 0.006 ??mol/m2, and 0.55 to 0.39 ??mol/m2 ([Cl -]=10-5 to 10-3 M only), respectively. This reduction in Hg(II) uptake is primarily a result of the formation of stable, nonsorbing aqueous HgCl2 complexes in solution, limiting the amount of free Hg(II) available to sorb. At higher [Cl-] beam reduction of Hg(II) to Hg(I) was observed, resulting in the possible formation of aqueous Hg2Cl2 species and the precipitation of calomel, Hg 2Cl2(s). The presence of sulfate caused enhanced Hg(II) uptake over the sulfate concentration ([SO42-]) range 10-5 to 0.9 M, increasing Hg surface coverages on goethite, ??-alumina, and bayerite from 0.39 to 0.45 ??mol/m2, 0.11 to 0.38 ??mol/m2, and 0.36 to 3.33 ??mol/m2, respectively. This effect is likely due to the direct sorption or accumulation of sulfate ions at the substrate interface, effectively reducing the positive surface charge that electrostatically inhibits Hg(II) sorption. Spectroscopic evidence for ternary surface complexation was observed in isolated cases, specifically in the Hg-goethite-sulfate system at high [SO42-] and in the Hg-goethite-chloride system. ?? 2003 Elsevier Inc. All rights reserved.

Journal of Colloid and Interface Science↗

Distribution and variability of redox zones controlling spatial variability of arsenic in the Mississippi River Valley alluvial aquifer, southeastern Arkansas

Twenty one of 118 irrigation water wells in the shallow (25-30??m thick) Mississippi River Valley alluvial aquifer in the Bayou Bartholomew watershed, southeastern Arkansas had arsenic (As) concentrations (< 0.5 to 77????g/L) exceeding 10????g/L. Sediment and groundwater samples were collected and analyzed from the sites of the highest, median, and lowest concentrations of As in groundwater in the alluvial aquifers located at Jefferson County, Arkansas. A traditional five-step sequential extraction was performed to differentiate the exchangeable, carbonate, amorphous Fe and Mn oxide, organic, and hot HNO3-leachable fraction of As and other compounds in sediments. The Chao reagent (0.25??M hydroxylamine hydrochloride in 0.25??M HCl) removes amorphous Fe and Mn oxides and oxyhydroxides (present as coatings on grains and amorphous minerals) by reductive dissolution and is a measure of reducible Fe and Mn in sediments. The hot HNO3 extraction removes mostly crystalline metal oxides and all other labile forms of As. Significant total As (20%) is complexed with amorphous Fe and Mn oxides in sediments. Arsenic abundance is not significant in carbonates or organic matter. Significant (40-70????g/kg) exchangeable As is only present at shallow depth (0-1??m below ground surface). Arsenic is positively correlated to Fe extracted by Chao reagent (r = 0.83) and hot HNO3 (r = 0.85). Arsenic extracted by Chao reagent decreases significantly with depth as compared to As extracted by hot HNO3. Fe (II)/Fe (the ratio of Fe concentration in the extracts of Chao reagent and hot HNO3) is positively correlated (r = 0.76) to As extracted from Chao reagent. Although Fe (II)/Fe increases with depth, the relative abundance of reducible Fe decreases noticeably with depth. The amount of reducible Fe, as well as As complexed to amorphous Fe and Mn oxides and oxyhydroxides decreases with depth. Possible explanations for the decrease in reducible Fe and its complexed As with depth include historic flushing of As and Fe from hydrous ferric oxides (HFO) by microbially-mediated reductive dissolution and aging of HFO to crystalline phases. Hydrogeochemical data suggests that the groundwater in the area falls in the mildly reducing (suboxic) to relatively highly reducing (anoxic) zone, and points to reductive dissolution of HFO as the dominant As release mechanism. Spatial variability of gypsum solubility and simultaneous SO42- reduction with co-precipitation of As and sulfide is an important limiting process controlling the concentration of As in groundwater in the area. ?? 2008 Elsevier B.V. All rights reserved.

Journal of Contaminant Hydrology↗

Combining ash analyses with remote sensing to identify juvenile magma involvement and fragmentation mechanisms during the 2018/19 small eruption of Peteroa volcano (Southern Andes)

The Planchón Peteroa Volcanic Complex (PPVC) is located on the border of Chile and Argentina, and is one of the most active volcanic systems in the Andes. Holocene activity has included magma-water interaction with an evolving series of crater lakes, mainly sourced from Peteroa volcano. This study examines data from the 2018/19 eruption, together with the volcanic history of the PPVC, to elucidate the complex interplay between magmatic activity and summit water and ice. From February 2016 to mid-2019, three seismic swarms occurred in the PPVC, preceding the explosive eruption from September 2018 to April 2019. The activity originated from a small vent nested within the easternmost crater, the most active portion of the complex (Peteroa). The explosions interacted with a crater lake, producing ash plumes up to 2 km above the crater and building a small tephra cone. To investigate the eruption mechanisms, we performed remote sensing analysis of plume dispersal, thermal anomalies and ground deformation, and characterized the volcanic products, including grain size, componentry, morphology, internal textures, composition and mineralogy. Our results suggest that the precursory seismicity beginning in 2016 was related to the intrusion of a new magma batch that reached the surface during the 2018/19 eruption. The eruption was also preceded by thermal anomalies, geomorphic changes and increased hydrothermal activity at the surface, though without any ground deformation recognized through radar interferometry (InSAR). The eruption initially produced predominantly recycled ash (phreatic activity), then evolved to increasing proportions of juvenile magma (phreatomagmatic) by April 2019. The juvenile clasts had a trachyandesite composition (~59 wt% SiO 2 ), with vesicular and dense scoria containing plagioclase and pyroxene. The ash surfaces show external quenching cracks and step fractures consistent with phreatomagmatic fragmentation within the active crater lake. Textural characteristics also point to a slowly ascending batch of magma that was relatively viscous by the time it interacted with water in the crater lake. Notably, these juvenile particles are distinctive from the pre-2018 products. Ash erupted from 2010/11 did not contain recognizable juvenile material, and is inferred to have been a mainly phreatic eruption. Our findings suggest that the interplay between phreatic and phreatomagmatic eruptions fed by small magma batches intruding at shallow levels characterize much of the eruptive behavior of the PPVC during the last three decades. Multi-parametric assessment is a powerful tool to discriminate between phreatic and phreatomagmatic eruptions.

Southern Andes↗

The 2013−2020 seismic activity at Sabancaya Volcano (Peru): Long lasting unrest and eruption

Sabancaya volcano is the youngest and second most active volcano in Peru. It is part of the Ampato-Sabancaya volcanic complex which sits to the south of the ancient Hualca Hualca volcano and several frequently active faults, thus resulting in complex volcano-tectonic interactions. After 15 years of repose, in 2013, a series of 4 earthquakes with magnitude >4.5 occurred within 24 h, marking the beginning of a new episode of unrest. Several additional swarms of earthquakes occurred in the following years until magmatic eruptive activity started on 6 November 2016. This activity is ongoing as of this writing, with an average of 50 explosions per day. In this study, we present results of multiparametric monitoring of Sabancaya's activity observed during 2013–2020. Seismic data are used to create a one-dimensional seismic velocity model, to catalog, locate, and characterize earthquakes, to detect repeating earthquake families, and to monitor seismic velocity variations by ambient noise cross-correlation. These analyses are complemented by visual and remote sensing observations and ground deformation measurements. All monitored parameters showed significant changes on 6 November 2016, the day of eruption onset, thus dividing the eruptive activity into pre-eruptive and eruptive stages. The unrest is characterized by high levels of seismic activity with hundreds of events detected per day. Volcano-tectonic (VT) earthquakes were dominant during the pre-eruptive period while long-period (LP) events and explosions have been most numerous since the eruption onset. Earthquake locations highlight long-lasting seismogenic zones along multiple previously active regional faults, as well as along newly identified faults. This VT seismicity is mainly distributed in a sector from the northwest to the east of the volcanic complex at distances of up to 30 km from the crater. We focus our analysis on two eruptive episodes: the eruption onset and subsequent crater migration from south to north, and the increase of lava dome extrusion rate in 2019. Both episodes are accompanied by seismic velocity decreases of up to 0.2% and are preceded by a few weeks by bursts of distal VT activity, including numerous repeating earthquakes. These repeated events were located on several remote tectonic faults (5–25 km from the vent). We suggest that these phenomena could be due to the injection of a batch of magma in the deep reservoir and/or conduit, which would generate 1) a pressure wave propagating in the hydrothermal system, triggering the bursts of seismic activity and 2) slow rising of magma by melting old material filling the conduit that eventually produced the eruptive and dome growth acceleration events.

Andes Mountains, Sabancaya Volcano↗

The challenges associated with developing science-based landscape scale management plans

Planning activities over large landscapes poses a complex of challenges when trying to balance the implementation of a conservation strategy while still allowing for a variety of consumptive and nonconsumptive uses. We examine a case in southeast Alaska to illustrate the breadth of these challenges and an approach to developing a science-based resource plan. Not only was the planning area, the Tongass National Forest, USA, exceptionally large (approximately 17 million acres or 6.9 million ha), but it also is primarily an island archipelago environment. The water system surrounding and going through much of the forest provides access to facilitate the movement of people, animals, and plants but at the same time functions as a barrier to others. This largest temperate rainforest in the world is an exceptional example of the complexity of managing at such a scale but also illustrates the role of science in the planning process. As we enter the 21st century, the list of questions needing scientific investigation has not only changed dramatically, but the character of the questions also has changed. Questions are contentious, cover broad scales in space and time, and are highly complex and interdependent. The provision of unbiased and objective information to all stakeholders is an important step in informed decision-making.

Landscape and Urban Planning↗

C–O stable isotope geochemistry and 40Ar/39Ar geochronology of the Bear Lodge carbonatite stockwork, Wyoming, USA

The carbonatite dike swarm and vein stockwork at the center of the Paleogene Bear Lodge alkaline complex (BLAC), Wyoming, USA, is host to diverse REE mineral assemblages that are largely a result of subsolidus modification and REE redistribution. Pseudomorphic replacement of primary burbankite by an assemblage of ancylite, strontianite, and barite is the result of interaction with late-stage hydrothermal fluids that added Sr, Ba, S, F, and REE, analogous to the replacement processes described for some carbonatite complexes of Russia's Kola Peninsula. Carbon and oxygen stable isotope ratios indicate that the primary carbonatite mineralogy experienced degassing/pneumatolysis and alteration by fluids of variable temperature, CO 2 /H 2 O ratios, and/or meteoric water content. Isotopic differences of matrix calcite between Group 1 carbonatites (avg. δ 13 C = −7.3‰; δ 18 O = 9.1‰) and Group 2 carbonatites (avg. δ 13 C = −9.9‰; δ 18 O = 10.2‰) are consistent with loss of CO 2 during degassing. The open-system alteration of burbankite caused a pronounced positive δ 18 O-shift in bulk ancylite pseudomorphs (δ 18 O: 14.3–25.7‰) relative to matrix calcite (δ 18 O: 8.7–11.2‰). Oxygen isotope compositions of biotite (δ 18 O: 4.5–5.9‰) and K-feldspar (δ 18 O: 7.3–7.9‰) in unoxidized carbonatite are typical of primary magmatic silicates and suggest that fluids responsible for the burbankite-to-ancylite conversion remained predominantly magmatic (carbohydrothermal). Concomitant increases toward the surface in 13 C and 18 O, oxidation, matrix carbonate dissolution, and the replacement of REE carbonates (ancylite, carbocernaite, and burbankite) by Ca-REE fluorocarbonates (bastnäsite, parisite, synchysite) suggest interaction with late-stage, low temperature (<250 °C) fluids characterized by lower CO 2 /H 2 O ratios, and an increasing meteoric water component. The first 40 Ar/ 39 Ar ages from carbonatite-hosted biotite and K-feldspar at the BLAC are between 51.45 ± 0.08 and 51.89 ± 0.14 Ma. Although carbonatite is commonly observed as the final intrusive phase in alkaline igneous complexes, relative-age relationships and previously published geochronology for Bear Lodge rocks indicate that alkaline silicate magmatism both preceded and followed carbonatite emplacement.

Wyoming↗

Aeromagnetic expression of the central Nagssugtoqidian Orogen, South-East Greenland

The Paleoproterozoic Nagssugtoqidian Orogen is one of the principal tectonic features related to the assembly of Nuna, extending across Greenland from east to west and forming an orogenic belt separating the North Atlantic Craton on the south from the Rae Craton on the north. In South-East Greenland, the Ammassalik Intrusive Complex (AIC) (∼1910 to 1870 Ma) occupies the central part of the orogenic belt, was formed by subduction- and magmatic arc-related processes, and has significant potential for undiscovered deposits of critical minerals. Previous interpretations of aeromagnetic data have been hindered by terrain effects, and we use a novel mix of geophysical analysis tools to develop new tectonomagmatic interpretations of the central Nagssugtoqidian Orogen in South-East Greenland. These interpretations extend into areas covered by ocean and ice. Results show that Archean rocks of the juxtaposed North Atlantic (Isertoq Terrane) and Rae (Kuummiut Terrane) Cratons are relatively weakly magnetized (with the exception of rocks of the Schweizerland Terrane) and have a NW-striking structural fabric that likely formed or was enhanced during the Nagssugtoqidian Orogeny. The AIC is structurally complex, with weakly magnetized metasedimentary rocks, and both weakly and strongly magnetized intrusions, arrayed in a NW-striking tectonic fabric. The strongly magnetized intrusions are largely concealed and distributed in a broader and more spatially complex fashion than previously known, suggesting that additional areas may be considered for mineral exploration. Strongly magnetized NW-striking dikes are imaged within the AIC, where they are spatially closely related to the strongly magnetized intrusions, and extend southward into the North Atlantic Craton (Isertoq Terrane). This spatial pattern of arc magmatism is consistent with previously developed models of SW-directed subduction that preceded collision during the Nagssugtoqidian Orogeny. The strongly magnetized Ammassalik Batholith (∼1670 Ma) and related intrusions form a cluster of plutons within ∼ 50 km of the Nagssugtoqidian suture. Their tectonomagmatic setting is unknown, although are speculatively related to delamination of a lithospheric keel formed during the Nagssugtoqidian Orogeny ∼ 200 m.y. prior. Numerous strongly magnetized NNE-striking Paleogene dikes, related to the opening of the Atlantic Ocean, are imaged cutting most other geologic units.

Greenland↗

Geochronologic evidence for a possible MIS-11 emergent barrier/beach-ridge in southeastern Georgia, USA

Predominantly clastic, off-lapping, transgressive, near-shore marine sediment packages that are morphologically expressed as subparallel NE-trending barriers, beach ridges, and associated back-barrier areas, characterize the near-surface stratigraphic section between the Savannah and the Ogeechee Rivers in Effingham County, southeastern Georgia. Each barrier/back-barrier (shoreline) complex is lower than and cut into a higher/older complex. Each barrier or shoreline complex overlies Miocene strata. No direct age data are available for these deposits. Previous researchers have disagreed on their age and provenance. Using luminescence and meteoric beryllium-10 ( 10 Be) inventory analyses, we estimated a minimum age for the largest, westernmost, morphologically identifiable, and topographically-highest, barrier/beach-ridge (the Wicomico shoreline barrier) and constrained the age of a suite of younger barrier/beach-ridges that lie adjacent and seaward of the Wicomico shoreline barrier. At the study site, the near-shore marine/estuarine deposits underlying the Wicomico shoreline barrier are overlain by eolian sand and an intervening zone-of-mixing. Optically stimulated luminescence (OSL) data indicate ages of ≤43 ka for the eolian sand and 116 ka for the zone-of-mixing. Meteoric 10Be and pedostratigraphic data indicate minimum residence times of 33.4 ka for the eolian sand, 80.6 ka for the zone-of-mixing, and 247 ka for the paleosol. The combined OSL and 10Be age data indicate that, at this locality, the barrier/beach ridge has a minimum age of about 360 ka. This age for the Wicomico shoreline-barrier deposit is the first for any Pleistocene near-shore marine/estuarine deposit in southeast Georgia that is conclusively older than 80 ka. The 360-ka minimum age is in agreement with other geochronologic data for near-coastline deposits in Georgia and South Carolina. The geomorphic position of this barrier/beach-ridge is similar to deposits in South Carolina considered to be ~450 ka to >1 Ma. The age and geomorphic data for Georgia and South Carolina possibly suggest the presence of MIS-11 (~420−360 ka) shoreline deposits between 15 m and 28 m above present sea level in the Southeastern Atlantic Coastal Plain.

Georgia↗

Multi-site evaluation of IKONOS data for classification of tropical coral reef environments

Ten IKONOS images of different coral reef sites distributed around the world were processed to assess the potential of 4-m resolution multispectral data for coral reef habitat mapping. Complexity of reef environments, established by field observation, ranged from 3 to 15 classes of benthic habitats containing various combinations of sediments, carbonate pavement, seagrass, algae, and corals in different geomorphologic zones (forereef, lagoon, patch reef, reef flats). Processing included corrections for sea surface roughness and bathymetry, unsupervised or supervised classification, and accuracy assessment based on ground-truth data. IKONOS classification results were compared with classified Landsat 7 imagery for simple to moderate complexity of reef habitats (5-11 classes). For both sensors, overall accuracies of the classifications show a general linear trend of decreasing accuracy with increasing habitat complexity. The IKONOS sensor performed better, with a 15-20% improvement in accuracy compared to Landsat. For IKONOS, overall accuracy was 77% for 4-5 classes, 71% for 7-8 classes, 65% in 9-11 classes, and 53% for more than 13 classes. The Landsat classification accuracy was systematically lower, with an average of 56% for 5-10 classes. Within this general trend, inter-site comparisons and specificities demonstrate the benefits of different approaches. Pre-segmentation of the different geomorphologic zones and depth correction provided different advantages in different environments. Our results help guide scientists and managers in applying IKONOS-class data for coral reef mapping applications. ?? 2003 Elsevier Inc. All rights reserved.

Remote Sensing of Environment↗