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A cross-site comparison of ecosystem- and plot-scale methane fluxes across multiple sites

Wetland and upland ecosystems play significant but opposing roles in the global methane (CH 4 ) budget, acting as natural sources and sinks, respectively. Two of the most common approaches for measuring CH 4 fluxes (FCH 4 ) are chambers, which measure fluxes at fine spatial scales (ca. 1 m 2 ), and eddy covariance (EC) towers, which integrate fluxes across larger footprints (ca. 100–10 000 m 2 ). Although chamber and EC observations have been combined in various syntheses and databases to estimate CH 4 budgets, a unified cross-site evaluation of FCH 4 estimates at plot and ecosystem scales is lacking. As a first step toward a systematic spatiotemporal scaling of EC tower and chamber footprints, we quantified differences in site-level aggregate FCH 4 between EC and chamber measurements ( Δ FCH 4 ) across ten wetland and upland sites at half-hourly, hourly, daily, weekly, monthly, and annual timescales. We found that ecosystem-scale median FCH 4 was consistently higher than plot-scale FCH 4 at all temporal scales, with the smallest difference at the daily timescale (multi-site median Δ FCH 4 : 1.36 nmol m −2 s −1 ; median ecosystem-scale FCH 4 = 1.56 nmol m −2 s −1 , median plot-scale FCH 4 = 0.06 nmol m −2 s −1 ) and the largest at annual scales (2.58 nmol m −2 s −1 ; median ecosystem-scale FCH 4 = 25.91 nmol m −2 s −1 , median plot-scale FCH 4 = 6.55 nmol m −2 s −1 ). In general, the agreement between ecosystem- and plot-scale FCH 4 decreased with finer temporal resolution (from Spearman ρ = 0.95 at the annual scale to ρ = 0.65 at the half-hourly scale), while Δ FCH 4 variation was greatest at daily-to-annual scales. Key environmental predictors of Δ FCH 4 across the ten sites included plot-scale spatial heterogeneity, dominant vegetation type, vapor pressure deficit, atmospheric pressure, and friction velocity at the daily and monthly scales. Wind direction was a significant predictor only at the monthly scale, suggesting EC footprint effects at these sites. These findings suggest that accounting for variability in EC footprint extent, chamber measurement placement, and measurement artifacts is key to reconciling multi-scale FCH 4 observations across diverse ecosystems and refining CH 4 budgets.

Biogeosciences

Stratigraphic notes—Volume 1, 2022

This is the first volume in the U.S. Geological Survey (USGS) series of reports on stratigraphy entitled “Stratigraphic Notes,” which consists of short papers that highlight stratigraphic studies, changes in stratigraphic nomenclature, and explanations of stratigraphic names and concepts used on published geologic maps. “Stratigraphic Notes” is a long-term (multiyear), multivolume publication containing articles that address updates or revisions to stratigraphic nomenclature (and whose content ultimately will be incorporated by National Geologic Map Database personnel into Geolex, https://ngmdb.usgs.gov/Geolex/ ). We welcome papers for the “Stratigraphic Notes” series from geoscientists of the USGS, of State Geological Surveys, and from academicians. Papers can be submitted for publication in “Stratigraphic Notes” by contacting the USGS Geologic Names Committee ( gnc@usgs.gov ). As new “Stratigraphic Notes” volumes are published, links to the volumes will be posted at https://doi.org/10.3133/pp1879 . This first volume ("Stratigraphic notes—Volume 1, 2022") includes articles that provide guidance for those who wish to submit papers to “Stratigraphic Notes,” as well as information on how to make your manuscripts compliant for geologic names reviews and how to organize your paper’s content to facilitate inclusion of new or revised names in Geolex. This volume also includes some specific guidance on conducting geologic names reviews of geologic and hydrogeologic reports.

Professional Paper

The 3D Elevation Program—Supporting Rhode Island’s economy

Introduction High-resolution elevation data are critical to applications of landscape modeling and planning, both of which have a significant effect on Rhode Island’s economy. In these and other enterprises, program managers, while aiming to strike a balance between accuracy and cost, strive to obtain the best available elevation data to help them address a range of issues. Programs focused on climate change, environmental management, transportation design and asset management, aviation navigation and safety, riverine ecosystem management, wildlife habitat characterization and management, shellfish aquaculture, and the management and mapping of forests, parks and recreation areas, soils, wetlands, and impervious surfaces are also among the critical applications that meet the State’s management needs and depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features. The 3D Elevation Program (3DEP) is managed by the U.S. Geological Survey (USGS) in partnership with Federal, State, Tribal, U.S. territorial, and local agencies to acquire consistent lidar coverage at quality level 2 or better to meet the many needs of the Nation and Rhode Island. The status of available and in-progress 3DEP baseline lidar data in Rhode Island is shown in figure 1. 3DEP baseline lidar data include quality level 2 or better, 1-meter or better digital elevation models, and lidar point clouds, and must meet the Lidar Base Specification version 1.2 ( https://www.usgs.gov/3dep/lidarspec ) or newer requirements. The National Enhanced Elevation Assessment identified user requirements and conservatively estimated that availability of lidar data would result in at least $178,560 in new benefits annually to the State. The top 10 Rhode Island business uses for 3D elevation data, which are based on the estimated annual conservative benefits of 3DEP, are shown in table 2.

Rhode Island

Land cover change within wetland complexes at Dixie Meadows, Churchill County, Nevada: 2015 – 2023

Dixie Meadows, Nevada, is a system of geothermal springs and seeps that feed a complex of marshes and wetland meadows that are located within lands managed by the Bureau of Land Management (BLM) and the Department of Defense (DOD). A previous U.S. Geological Survey report documented variability in satellite imagery-based land cover classifications for seven wetland complexes at near monthly time intervals between October 2015 and January 2022. This report presents additional data, extending analysis to November 2023. Land cover classifications between October 2015 and November 2023 demonstrated an association between vegetation cover characteristics and surface moisture, with Class 1 having dry, bare soil or sparse upland vegetation, Class 2 having moist, bare soil or sparse to small vegetation, Class 3 having dense green vegetation with potentially saturated soil conditions, Class 4 having a mix of shallow surface water, saturated soil, and dense green vegetation, and Class 5 having open surface water. Most of the wetland complexes occur close to spring outflows primarily within land managed by the DOD, though portions are also within BLM lands. The intervening and surrounding landscape outside of the wetland complexes assessed in this study are managed by the BLM. As a result, Class 1 land covers had the largest areal coverage for BLM managed lands. Classes 2 and 3 land covers were primarily mapped inside the wetland complexes and thus had the largest area coverage within DOD managed lands. Class 4 was almost exclusively mapped within the wetland complexes and thus was largely contained within DOD managed lands. Class 5 (open water) was exclusively mapped in and adjacent to a single wetland complex with catchment ponds on land managed by the BLM. The distribution of these land cover classes over the study period was seasonally and annually variable. Land cover areas of Classes 1 and 2 were larger during the spring months. Conversely, land cover areas of Classes 3 and 4 tended to be greatest during the summer or fall. These patterns might be influenced by differences in seasonal water sources and phenology.

Nevada

Birds, breakpoints, and baselines: How citizen science data can reveal ecological boundaries in Kenya’s Upper Tana watershed

Tropical watersheds are increasingly threatened by climate change, land-use conversion, and resource extraction, yet conventional biodiversity monitoring in these systems is often spatially and temporally limited. Citizen science offers a complementary approach, enabling biodiversity data collection over large areas that can supplement professional scientific surveys. We analyzed 10 years (2012–2022) of Upper Tana Watershed bird data from the Kenya Bird Map project, covering 114 pentads (9 × 9 km) within a 17,000 km 2 watershed to assess patterns of bird community composition and distribution across this watershed and to also evaluate the effects of environmental variables, seasonality, and sampling effort to help inform improvements in future citizen science projects. Citizen (or community) scientists recorded 575 species (>50% of Kenya’s total avifauna) in 74 families. Asymptotic species accumulation indicates that most probable species present in the watershed were detected. Threshold indicator taxa analysis revealed distinct ecological boundaries along elevation (∼1,500 m), precipitation (∼1,100 mm), and mean temperature (∼19°C) gradients, corresponding to a turnover from xeric savanna to mesic montane forest assemblages. Notably, bird communities showed little seasonal differentiation between wet and dry periods, consistent with dominance by resident year-round species. Data limitations including uneven survey distribution and frequency, absence of abundance metrics, and coarse representation of local environmental conditions that likely reduced our ability to detect fine-scale species–habitat relationships. Addressing these gaps through spatially balanced sampling at greater resolution, greater survey frequency in underrepresented areas, and improved capture of habitat metrics could strengthen the use of citizen-science bird data for watershed bioassessment. Our findings demonstrate that structured citizen-science initiatives can identify ecological boundaries and inform adaptive management of tropical socio-ecological systems under rapid environmental change.

Upper Tana watershed

The Sedimentary Geochemistry and Paleoenvironments Project Phase 2 data release: An open data resource for the study of Earth's environmental history

Geochemical data from sedimentary rocks are the primary source of information regarding Earth's surface evolution through time, including its air and water envelopes and interactions with life and deep Earth processes. The Sedimentary Geochemistry and Paleoenvironments Project (SGP) is a scientific consortium centered around open data and community-driven development of cyberinfrastructure tools and resources for sedimentary geochemistry and Earth history. Here we describe the SGP Phase 2 data release, which focused on incorporating Paleoproterozoic and Mesoproterozoic (2500–1000 million years ago) data and better accommodating carbonate data. This data release was built through the involvement of >200 researchers worldwide in academia, government, and industry, and provides the largest available public data resource for our user community in the academic fields of geochemistry, sedimentology, tectonics, paleontology, Earth history, and paleoclimate, as well as the petroleum and minerals industries. The dataset now encompasses 126,006 samples and 4,132,371 geochemical analyses. In addition to direct entry by SGP Team Members, we have ingested and incorporated datasets from the Geoscience Australia OZCHEM database, the Alberta Geological Survey, and the Deep-Time Marine Sedimentary Element Database (DM-SED) compilation. This paper details sampling in the Phase 2 dataset with respect to age, geography, lithology, and other geological characteristics, documents access via our search website and API, discusses possible issues and/or biases in the dataset that could impact analyses, describes plans for governance and stewardship of data from Indigenous lands, and serves as the citable reference paper for the data release.

Chemical Geology

On connecting hydro-social parameters to vegetation greenness differences in an evolving groundwater-dependent ecosystem

Understanding groundwater-dependent ecosystems (i.e., areas with a relatively shallow water table that plays a major role in supporting vegetation health) is key to sustaining water resources in the western United States. Groundwater-dependent ecosystems (GDEs) in Colorado have non-pristine temporal and spatial patterns, compared to agro-ecosystems, which make it difficult to quantify how these ecosystems are impacted by changes in water availability. The goal of this study is to examine how key hydrosocial parameters perturb GDE water use in time and in space. The temporal approach tests for the additive impacts of precipitation, surface water discharge, surface water mass balance as a surrogate for surface–groundwater exchange, and groundwater depth on the monthly Landsat normalized difference vegetation index (NDVI). The spatial approach tests for the additive impacts of river confluences, canal augmentation, development, perennial tributary confluences, and farmland modification on temporally integrated NDVI. Model results show a temporal trend (monthly, 1984–2019) is identifiable along segments of the Arkansas River at resolutions finer than 10 km. The temporal impacts of river discharge correlate with riparian water use sooner in time compared to precipitation, but this result is spatially variable and dependent on the covariates tested. Spatially, areal segments of the Arkansas River that have confluences with perennial streams have increased cumulative vegetation density. Quantifying temporal and spatial dependencies between the sources and effects of GDEs could aid in preventing the loss of a vulnerable ecosystem to increased water demand, changing climate, and evolving irrigation methodologies.

Colorado

Preliminary depth to basement modeling at Salton Sea, California

The San Andreas Fault – Imperial Fault (SAF-IF) transtensional step-over zone along the southern margin of the Salton Sea hosts substantial geothermal production and lithium brine resources. Recent volcanism at the Salton Buttes and active seismicity along the SAFIF fault system highlight active tectonic and magmatic processes that pose natural hazards and may impact energy and mineral production. Characterizing the subsurface architecture and extent of concealed alteration associated with this tectono-magmatic system enhances understanding of these active processes, associated hazards, and resources. We have compiled a gravity database, consisting of new and re-processed existing data, from which we have constructed a new isostatic residual gravity anomaly map of the Salton trough. We have used this new gravity dataset together with a compilation of publicly available borehole data to develop new depth to basement inversion models for the region. These depth to basement models help to constrain basin geometries, inform alteration mapping, and reveal variations in basement rocks. Due to the concealed nature of the complex tectonic framework at the Salton trough, it is necessary to utilize geophysical methods for subsurface characterization. These new depth to basement models are a first step toward constructing 2D and 3D geophysical and geologic models of the Imperial Valley and Salton Sea geothermal area. This analysis complements other geophysical initiatives, including magnetotelluric (MT) modeling (Tokmakoff et al., 2024), magnetic mapping (Glen and Earney, 2023, 2024) and potential field modeling, and seismic studies focused on hazard and resource investigations in the Imperial Valley.

California

Uncertainty in ground-motion-to-intensity conversions significantly affects earthquake early warning alert regions

We examine how the choice of ground‐motion‐to‐intensity conversion equations (GMICEs) in earthquake early warning (EEW) systems affects resulting alert regions. We find that existing GMICEs can underestimate observed shaking at short rupture distances or overestimate the extent of low‐intensity shaking. Updated GMICEs that remove these biases would improve the accuracy of alert regions for the ShakeAlert EEW system for the West Coast of the United States. ShakeAlert uses ground‐motion prediction equations (GMPEs), which calculate spatial distributions of peak ground acceleration (PGA) and peak ground velocity (PGV) from earthquake source estimates, combined with GMICEs to translate GMPE output into modified Mercalli intensity (MMI). We find significant epistemic uncertainty in alert distances; near‐source MMI estimates from different GMICEs can differ by over 1 MMI unit, and MMI extents used for public EEW alerts can differ by hundreds of kilometers for larger magnitude earthquakes ( M ∼6.5+). We use a catalog of “Did You Feel It?” shaking reports to evaluate how well GMICEs predict observed shaking. Our preferred GMICE is the one that computes MMI using PGV for high intensities and transitions to using PGA for nondamaging intensities. These results motivate updating GMICE relationships more generally, including in ShakeMap applications.

The Seismic Record

Deep subsurface organic-rich shale supports abundant, diverse, and novel fungi

As Earth’s principal reservoir of organic carbon and microbial biomass, the deep subsurface hosts microorganisms capable of mobilizing this once-sequestered carbon. Contrary to standard assumptions of eukaryotic scarcity, this study documents abundant fungal communities, ranging from 4.2 × 10 3 to 6.8 × 10 3 fungal cells mL −1 , across a methane-producing organic-rich shale 247–556 meters below the surface. Although fungal:bacterial cell ratios ranged from 1:7028 to 1:713, application of biomass conversion factors developed for oceanic systems yielded a median fungal:bacterial biomass ratio of 1:4.7. 16S rRNA gene amplicons revealed bacterial and archaeal communities mirroring those found in well-characterized extremophilic, carbon-degrading environments, while sequencing of 18S rRNA gene and ITS rRNA spacer amplicons collectively identified a eukaryotic hotspot with 689 fungal OTUs across six phyla. The dominant fungal classes, Agaricomycetes and Dothideomycetes, are well-established degraders of recalcitrant carbon compounds at the surface, suggesting they may similarly contribute to organic matter degradation and ecosystem maintenance in the subsurface. Cultivation and isolation efforts yielded 205 fungal strains, including 13 candidate novel taxa, underscoring the deep subsurface as an underexplored eukaryotic habitat. Stable carbon isotopes indicate methane is predominantly generated via microbial conversion of the fossil carbon, while water isotopes suggest in situ geochemical conditions have been relatively stable since the Late Pleistocene, with subglacial recharge as a plausible mechanism for microbial introduction. Collectively, these findings suggest that fungi are underrecognized contributors to organic matter transformation and functional diversity in the deep biosphere, revealing a critical gap in our understanding of deep subsurface ecosystem processes.

Indiana, Michigan, Ohio

Introduction to recommended capabilities and instrumentation for volcano monitoring in the United States

Introduction The National Volcano Early Warning System (NVEWS) was authorized and partially funded by the U.S. Government in 2019. In response, the U.S. Geological Survey (USGS) Volcano Hazards Program asked its scientists to reflect on and summarize their views of best practices for volcano monitoring. The goal was to review and update the recommendations of a previous report (Moran and others, 2008) and to provide a more detailed analysis of capabilities and instrumentation for monitoring networks for U.S. volcanoes. This Scientific Investigations Report and its chapters reflect those USGS scientists’ views and summaries and will serve as a guide for future network upgrades funded through NVEWS. Given the well-documented hazards posed by volcanoes to population centers and aviation (for example, Blong, 1984; Scott, 1989; Neal and others, 1997, 2019; Guffanti and others, 2010; Shroder and Papale, 2014; Prata and Rose, 2015; Palmer, 2020), volcano monitoring is critical for ensuring public safety and for mitigating the impacts of volcanic activity. Accurate and timely forecasts are facilitated by well-designed monitoring networks that are in place long enough to allow for background behavior to be recognized and understood. Because precursory signals may be limited and unrest may progress rapidly to an eruption, our goal is to deploy monitoring systems that enable detection of the reactivation of dormant volcanoes as early as possible, allowing for public safety and risk mitigation. NVEWS planning is also informed by the results of Ewert and others (2005, 2018), whereby 161 U.S. volcanoes are currently categorized and ranked commensurate with their relative threat. In each chapter, author(s) considered the need for some redundancy of instrumentation and telemetry, given the likelihood of occasional equipment failure, particularly in extreme and remote environments. Establishing digital telemetry networks requires advanced planning, sighting, radio-shot testing, and, inevitably, troubleshooting in the field. This is harder to achieve rapidly during a crisis; thus, an important goal for monitoring U.S. volcanoes is to establish digital telemetry backbones with redundancy and extra capacity to absorb additional instruments should a volcano begin to exhibit signs of unrest (fig. A1). The National Telecommunications and Information Administration (NTIA) imposed new regulations in the United States, eliminating the use of older analog radios for many purposes, which had been one previous means for redundant data delivery. However, the resulting conversion from analog to digital systems usefully enables stations to accommodate new and multivariate real-time data streams (for example, Global Navigation Satellite System [GNSS] receivers, infrasound arrays, gas spectrometers, visible and infrared cameras, and broadband seismometers). We note that other USGS and broader national and international hazard programs can leverage NVEWS instrumentation plans. Examples of this include the following: Improved seismic coverage of volcanoes will increase the capability of the USGS Earthquake Hazards Program to detect and locate earthquakes, estimate ground shaking, and provide timely early warnings through the ShakeAlert Earthquake Early Warning System (Given and others, 2018). The National Oceanic and Atmospheric Administration’s Tsunami Program will benefit from additional seismic stations, particularly within the sparsely instrumented Aleutian Islands, Northern Mariana Islands, and American Samoa. Infrasound stations can detect signals from landslides, debris flows and lahars, floods, and weather events, providing benefits to the National Weather Service and the USGS Landslide Hazards Program.

Scientific Investigations Report

Forecasting water levels using the ConvLSTM algorithm in the Everglades, USA

Forecasting water levels in complex ecosystems like wetlands can support effective water resource management, ecological conservation, and understanding surface and groundwater hydrology. Predictive models can be used to simulate the complex interactions among natural processes, hydrometeorological factors, and human activities. The Greater Everglades in the USA is a well-known example of an ecosystem where complexity has motivated adoption of machine learning algorithms in water level prediction studies. This paper aims to contribute to extending existing machine learning algorithms by integrating spatiotemporal data with deep-learning algorithms in the forecasting process. In this study, a deep-learning model is developed to predict water levels on a regional scale, covering a large area of approximately 9,138 square kilometers in the Everglades ecosystem. This model has the architecture of Convolutional Long Short-Term Memory which can deal with spatiotemporal data by capturing both spatial and temporal dependencies in the training data. The forecasting capabilities of this model (referred to as the global model) are assessed by comparing the global model to two Artificial Neural Networks developed at two different gaging stations, referred to here as local models. One local model is developed at a gaging station directly influenced by nearby water control structures, whereas the other is developed at a gaging station located farther away from these structures. By leveraging data from the Everglades Depth Estimation Network spanning from January 2002 to May 2023, the global and local models were trained to forecast water levels with a two-day lead time. Our findings suggest that both the global and local models perform with approximately the same level of accuracy, with Mean Absolute Relative Error values ranging from 0.38% to 1.4% at the selected stations. The developed global model has demonstrated strong potential as a standalone forecasting tool for the entire study area in the Everglades and could eliminate the need for developing multiple local models. This finding also highlights how machine learning can capture complex spatial and temporal relationships to generate accurate water level predictions on a regional scale.

Florida

Modeling legacy nitrogen transport under instantaneous, steady-state, and transient groundwater flow conditions

In hydrologic settings where groundwater discharge contributes substantially to surface waters, legacy nitrogen in groundwater can confound surface water nitrogen loads estimated exclusively from current terrestrial sources. Additionally, legacy nitrogen in groundwater can contribute to lagged responses to nitrogen management efforts. Some methods of estimating groundwater contributions to surface water nitrogen loads account for legacy nitrogen, while others do not. The resulting differences are rarely quantified. We used a numerical modeling framework to compare three methods of estimating time-varying annual groundwater nitrogen loads to surface water receptors on eastern Long Island, New York. The instantaneous load method used steady-state contributing areas and includes no temporal groundwater lag. The second method used numerical simulations of nitrogen loads under steady-state flow, which captures groundwater transport lags but omits the annual variability in transient hydrologic stresses. The third method numerically simulated both transient groundwater flow and nitrogen transport to explicitly capture the effects of legacy nitrogen in groundwater. Depending on antecedent nitrogen and hydrologic conditions, historical nitrogen loads estimated from the numerical simulations were sometimes similar (<10% difference) and other times substantially different (±100%) from the instantaneous load estimates. Additionally, simulated future surface water nitrogen loads responded asymptotically over several decades following reductions in terrestrial nitrogen sources, further highlighting the effect of groundwater transport lag times. The comparison of the three methods, quantification of historical interannual variability, and prediction of lagged responses to nitrogen source reductions provide important context for decision makers using estimated groundwater nitrogen loads to help evaluate nitrogen management efficacy.

New York

Collaborative drought science planning in the Colorado River Basin

The U.S. Geological Survey (USGS) is using collaborative, interdisciplinary planning to develop data and tools needed to optimize the management of water resources and land use by resource management agencies during an ongoing, multidecadal drought in the Colorado River Basin. The USGS Actionable and Strategic Integrated Science and Technology team works to build relationships with resource management agencies and other stakeholders who can benefit from the use of USGS data and products. In 2023, the Actionable and Strategic Integrated Science and Technology team hosted a series of collaborative workshops to bring together representatives of resource management agencies and other stakeholders (any person or entity with interests in a resource or location) with USGS program managers, scientists, and multidisciplinary subject matter experts to codevelop concepts for interdisciplinary drought science and technology projects to address pressing needs related to drought in the Colorado River Basin. Workshop participants identified current and recent scientific data that could be shared through a centralized online data portal. Workshop participants also identified drought science and technology needs and developed project concepts to address those science needs. Participants categorized project concepts based on their potential to develop short-, mid-, and long-term drought science data and tools, provide for the spatial or temporal expansion of ongoing USGS science projects, and address high-priority science needs. Participants developed nine project concepts: (1) understanding shifting ecohydrologic baselines, (2) San Juan River Basin synthesis, (3) incorporating dynamic land cover into hydrologic models, (4) aridification compared to drought, (5) surface water-groundwater interactions, (6) cascading effects of drought on dust, (7) cascading effects of drought on water availability, (8) cascading effects of drought on socioeconomic factors, and (9) the value of water in the Colorado River Basin. This report provides an overview of the 2023 Codesign Workshop Series, synthesized outcomes from workshop materials and discussions, and science project concepts that emerged from the collaborative meetings that will continue to be refined into science project proposals through codevelopment processes. This report also highlights lessons learned and next steps needed to receive feedback and testing of the USGS Science Collaboration Portal, continue collaboration to develop detailed specifics and steps for short-term wins, develop interdisciplinary project proposals, and implement science planning and studies.

Arizona, California, Colorado, Nevada, New Mexico,

Microplastics undergo fragmentation during pressurized membrane filtration

Low-micrometer microplastics (<10 μm) have been detected in drinking water, driving growing interest in using pressure-driven membrane filtration to remove these particles and ensure drinking water safety. However, little attention is paid to the fate of microplastics concentrated in the filtration byproduct. In this study, using well-defined polystyrene (PS) and poly(methyl methacrylate) microspheres as model particles, we observed microplastic fragmentation during nanofiltration and the subsequent release of smaller fragments. After operating for 3 h at 20 bar, 67.9 ± 8.0% of the PS spheres in the concentrate, based on particles counted in selected fields of view, were transformed into fractured particles. The characteristic Raman band signals of microplastics were significantly weakened after fragmentation, leading to detection challenges. To address this, a data processing algorithm was developed to identify PS fragments as small as 1 μm. Preliminary statistical analysis reveals that within the tested pressure range, operation time has a stronger influence on fragmentation than pressure magnitude alone and that fragmentation is further governed by the intrinsic mechanical properties of the tested model polymers. This work provides direct evidence that pressure-driven membrane processes induce microplastic fragmentation and highlights the environmental risks associated with the discharge of fragmented microplastics into the concentrate.

Environmental Science & Technology Letters

Streamflow, base-flow, and precipitation trends and simulated effects of groundwater withdrawals from the North Fork Red River aquifer on base flows upgradient from Lake Altus, western Oklahoma, 1980–2022

The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, used five scenarios created from a previously published numerical groundwater-flow model (1980–2013) and historical streamflow records (1980–2022) to investigate the relation between groundwater withdrawals from the North Fork Red River aquifer and inflows to Lake Altus from the North Fork Red River in western Oklahoma. The five scenarios were (1) a scaled-equal-proportionate-share (EPS) groundwater-withdrawal scenario, (2) a study-area-scaled-reported groundwater-withdrawal scenario, (3) a zonal-scaled-reported groundwater-withdrawal scenario, (4) a historical drought-threshold scenario, and (5) a base-flow and evapotranspiration depletion scenario. For the scaled-EPS groundwater-withdrawal scenario, EPS groundwater withdrawals were often much higher than reported groundwater withdrawals and greatly decreased base flows for most scale factors. For the study-area-scaled-reported groundwater-withdrawal scenario, base flows were reduced more but by smaller percentages during wet periods than during dry periods when scaling simulated reported groundwater withdrawals. For the zonal-scaled-reported groundwater-withdrawal scenario, scaling simulated reported groundwater withdrawals within selected zones with more groundwater withdrawals did not always affect base flows more than scaling reported groundwater withdrawals within zones with less groundwater withdrawals. For the historical drought-threshold scenario, curtailing groundwater withdrawals at the drought thresholds increased annual base flows to Lake Altus by about 1,169 to 3,665 acre-feet. For the base-flow and evapotranspiration depletion scenario, the distance between a groundwater well and a stream was a major factor affecting base flow to the North Fork Red River when increasing groundwater withdrawals; however, spatially variable hydrologic properties and saturated-zone evapotranspiration could also affect the relation between base flows and groundwater withdrawals.

Oklahoma

A global database of soil microbial phospholipid fatty acids and enzyme activities

Soil microbes drive ecosystem function and play a critical role in how ecosystems respond to global change. Research surrounding soil microbial communities has rapidly increased in recent decades, and substantial data relating to phospholipid fatty acids (PLFAs) and potential enzyme activity have been collected and analysed. However, studies have mostly been restricted to local and regional scales, and their accuracy and usefulness are limited by the extent of accessible data. Here we aim to improve data availability by collating a global database of soil PLFA and potential enzyme activity measurements from 12,258 georeferenced samples located across all continents, 5.1% of which have not previously been published. The database contains data relating to 113 PLFAs and 26 enzyme activities, and includes metadata such as sampling date, sample depth, and soil pH, total carbon, and total nitrogen. This database will help researchers in conducting both global- and local-scale studies to better understand soil microbial biomass and function.

Scientific Data

A robust quantitative method to distinguish runoff-generated debris flows from floods

Debris flows and floods generated by rainfall runoff occur in rocky mountainous landscapes and burned steeplands. Flow type is commonly identified post-event through interpretation of depositional structures, but these may be poorly preserved or misinterpreted. Prior research indicates that discharge magnitude is commonly amplified in debris flows relative to floods due to volumetric bulking and increased frictional resistance. Here, we use this flow amplification to develop a metric ( Q* ) to separate debris flows from floods based on the ratio of observed peak discharge to the theoretical maximum water discharge from rainfall runoff. We compile 642 observations of floods and debris flows and demonstrate that Q* distinguishes flow type to ∼92% accuracy. Q* allows for accurate identification of debris flows through simple channel cross-section surveys rather than through qualitative interpretation of deposits, and therefore should increase the performance of models and engineered structures that require accurate flow-type observations.

Geophysical Research Letters