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At least 1,351 records · Page 75Linked to original sources

Topographic mapping of the Moon

Contour maps of the Moon have been compiled by photogrammetric methods that use stereoscopic combinations of all available metric photographs from the Apollo 15, 16, and 17 missions. The maps utilize the same format as the existing NASA shaded-relief Lunar Planning Charts (LOC-1, -2, -3, and -4), which have a scale of 1:2 750 000. The map contour interval is 500m. A control net derived from Apollo photographs by Doyle and others was used for the compilation. Contour lines and elevations are referred to the new topographic datum of the Moon, which is defined in terms of spherical harmonics from the lunar gravity field. Compilation of all four LOC charts was completed on analytical plotters from 566 stereo models of Apollo metric photographs that cover approximately 20% of the Moon. This is the first step toward compiling a global topographic map of the Moon at a scale of 1:5 000 000. ?? 1985 D. Reidel Publishing Company.

Earth, Moon and Planets↗

Description and Analytical Results for Deposited Dust Samples from a Two-Year Monitoring Program Near Deer Trail, Colorado, USA, 2006-2007

Biosolids reclaimed from municipal wastewater have been applied since 1993 on nonirrigated farmland and rangeland east of Deer Trail, Colo., by Metro Wastewater Reclamation District of Denver. The U.S. Geological Survey has monitored ground water at this site since 1993, and began monitoring the biosolids, soils, and stream sediments in 1999. To investigate the possible effects of airborne dust blowing from the application fields, passive dust samplers were deployed in 2006 and 2007. These samplers measured the quantity and composition of dust being deposited downwind of a farmed field where biosolids had been applied, compared to a farmed field upwind of the application area. The dust-deposition rates and dust compositions measured at the two study sites are consistent with rates and compositions measured elsewhere in Utah, Nevada, and California using the same methods and equipment. Higher deposition rates were measured at the biosolids site compared to the control site during 2006. Higher deposition rates at both sites appear to be associated with episodes of cultivation and harvest during dry periods. No consistent differences in elements likely to be associated with biosolids disposal were detected between the sites. However, the contents of copper, lead, and zinc in the dust samples are generally much higher than average values of these elements in crustal rocks and sediments. Such values for dust samples are consistent with measurements on modern dust samples from southern Nevada and California and probably reflect inputs from regional urban and manufacturing activities.

Open-File Report↗

Determination of nanogram per liter concentrations of volatile organic compounds in water by capillary gas chromatography and selected ion monitoring mass spectrometry and its use to define groundwater flow directions in Edwards Aquifer, Texas

A method has been developed to measure nanogram per liter amounts of selected volatile organic compounds (VOCs) including dichlorodifluoromethane, trichlorofluoromethane, cis-1,2-dichloroethene, trichloroethene, tetrachloroethene, and the isomers of dichlorobenzene in water. The method uses purge-and-trap techniques on a 100 mL sample, gas chromatography with a megabore capillary column, and electron impact, selected ion monitoring mass spectrometry. Minimum detection levels for these compounds ranged from 1 to 4 ng/L in water. Recoveries from organic-free distilled water and natural groundwater ranged from 70.5% for dichlorodifluoromethane to 107.8% for 1,4-dichlorobenzene. Precision was generally best for cis-1,2-dichloroethene, tetrachloroethene, and the dichlorobenzene isomers and worst for dichlorodifluoromethane and trichlorofluoromethane. Blank data indicated persistent, trace-level introduction of dichlorodifluoromethane, 1,4-dichlorobenzene, and tetrachloroemene to samples during storage and shipment at concentrations less than the method reporting limits. The largest concentrations of the selected VOCs in 27 water samples from the Edwards aquifer near San Antonio, TX, were from confined-zone wells near an abandoned landfill. The results defined a zone of water with no detectable VOCs in nearly all of the aquifer west of San Antonio and from part of the confined zone beneath San Antonio.

Analytical Chemistry↗

A general theory of multimetric indices and their properties

1. Stewardship of biological and ecological resources requires the ability to make integrative assessments of ecological integrity. One of the emerging methods for making such integrative assessments is multimetric indices (MMIs). These indices synthesize data, often from multiple levels of biological organization, with the goal of deriving a single index that reflects the overall effects of human disturbance. Despite the widespread use of MMIs, there is uncertainty about why this approach can be effective. An understanding of MMIs requires a quantitative theory that illustrates how the properties of candidate metrics relates to MMIs generated from those metrics. 2. We present the initial basis for such a theory by deriving the general mathematical characteristics of MMIs assembled from metrics. We then use the theory to derive quantitative answers to the following questions: Is there an optimal number of metrics to comprise an index? How does covariance among metrics affect the performance of the index derived from those metrics? And what are the criteria to decide whether a given metric will improve the performance of an index? 3. We find that the optimal number of metrics to be included in an index depends on the theoretical distribution of signal of the disturbance gradient contained in each metric. For example, if the rank-ordered parameters of a metric-disturbance regression can be described by a monotonically decreasing function, then an optimum number of metrics exists and can often be derived analytically. We derive the conditions by which adding a given metric can be expected to improve an index. 4. We find that the criterion defining such conditions depends nonlinearly of the signal of the disturbance gradient, the noise (error) of the metric and the correlation of the metric errors. Importantly, we find that correlation among metric errors increases the signal required for the metric to improve the index. 5. The theoretical framework presented in this study provides the basis for understanding the properties of MMIs. It can also be useful throughout the index construction process. Specifically, it can be used to aid understanding of the benefits and limitations of combining metrics into indices; it can inform selection/collection of candidate metrics; and it can be used directly as a decision aid in effective index construction.

Methods in Ecology and Evolution↗

The Restoration Rapid Assessment Tool: An Access/Visual Basic application

Managers of parks and natural areas are increasingly faced with difficult decisions concerning restoration of disturbed lands. Financial and workforce resources often limit these restoration efforts, and rarely can a manager afford to address all concerns within the region of interest. With limited resources, managers and scientists have to decide which areas will be targeted for restoration and the restoration treatments to use in these areas. A broad range of approaches are used to make such decisions, from well-researched expert opinions (Cipollini et al. 2005) to gut feeling, with variable degrees of input from site visits, data collection, and data analysis used to support the decision. A standardized approach including an analytical assessment of site characteristics based on the best information available, with a written or electronic record of all the steps taken along the way, would make comparisons among a group of sites easier and lend credibility through use of common, documented criteria at all sites. In response to these concerns, we have developed the Restoration Rapid Assessment Tool (RRAT). RRAT is based on field observations of key indicators of site degradation, stressors influencing the site, value of the site with respect to larger management objectives, likelihood of achieving the management goals, and logistical constraints to restoration. The purpose of RRAT is not to make restoration decisions or prescribe methods, but rather to ensure that a basic set of pertinent issues are considered for each site and to facilitate comparisons among sites. Several concepts have been central to the development of RRAT. First, the management goal (also known as desired future condition) of any site under evaluation should be defined before the field evaluation begins. Second, the evaluation should be based upon readily observable indicators so as to avoid cumbersome field methods. Third, the ease with which site stressors can be ameliorated must be factored into the evaluation. Fourth, intrinsic site value must be assessed independently of current condition. Finally, logistical considerations must also be addressed. Our initial focus has been on riparian areas because they are among the most heavily impacted habitat types, and RRAT indicators reflect this focus.

Report↗

Operator's manual on the visual-accumulation tube method for sedimentation analysis of sands

The visual-tube method for sedimentation analysis of sands was developed as a part of the general investigation titled "A Study of Methods Used in Measurement and Analysis of Sediment Loads in Streams." The method is one answer to the need for a simple, rapid, and inexpensive means of determining the sedimentation-size frequency analysis of sand samples containing particles less than one millimeter in size. For analysis of coarser sands see the Appendix, Section 13, Report No. 11 "The Development and Calibration of the Visual-Accumulation-Tube" is available for those who have further interest in this analysis. The personnel who will be operating these units may have little or no previous knowledge of either the principles involved or the details of opera.ting procedure. This manual is intended as an aid to them in setting up the apparatus, learning the analytical procedure, interpreting the results, and understanding the primary principles encountered.

Report↗

Bounded fractional diffusion in geological media: Definition and Lagrangian approximation

Spatiotemporal Fractional-Derivative Models (FDMs) have been increasingly used to simulate non-Fickian diffusion, but methods have not been available to define boundary conditions for FDMs in bounded domains. This study defines boundary conditions and then develops a Lagrangian solver to approximate bounded, one-dimensional fractional diffusion. Both the zero-value and non-zero-value Dirichlet, Neumann, and mixed Robin boundary conditions are defined, where the sign of Riemann-Liouville fractional derivative (capturing non-zero-value spatial-nonlocal boundary conditions with directional super-diffusion) remains consistent with the sign of the fractional-diffusive flux term in the FDMs. New Lagrangian schemes are then proposed to track solute particles moving in bounded domains, where the solutions are checked against analytical or Eularian solutions available for simplified FDMs. Numerical experiments show that the particle-tracking algorithm for non-Fickian diffusion differs from Fickian diffusion in relocating the particle position around the reflective boundary, likely due to the non-local and non-symmetric fractional diffusion. For a non-zero-value Neumann or Robin boundary, a source cell with a reflective face can be applied to define the release rate of random-walking particles at the specified flux boundary. Mathematical definitions of physically meaningful nonlocal boundaries combined with bounded Lagrangian solvers in this study may provide the only viable techniques at present to quantify the impact of boundaries on anomalous diffusion, expanding the applicability of FDMs from infinite do mains to those with any size and boundary conditions.

Water Resources Research↗

Spaceborne imaging spectroscopy enables carbon trait estimation in cover crop and cash crop residues

Purpose Cover crops and reduced tillage are two key climate smart agricultural practices that can provide agroecosystem services including improved soil health, increased soil carbon sequestration, and reduced fertilizer needs. Crop residue carbon traits (i.e., lignin, holocellulose, non-structural carbohydrates) and nitrogen concentrations largely mediate decomposition rates and amount of plant-available nitrogen accessible to cash crops and determine soil carbon residence time. Non-destructive approaches to quantify these important traits are possible using spectroscopy. Methods The objective of this study was to quantify cash and cover crop residue nitrogen and carbon traits using partial least squares regression models and a combination of 1) the band equivalent reflectance (BER) of the PRecursore IperSpettrale della Missione Applicativa (PRISMA) imaging spectroscopy sensor derived from laboratory collected ASD spectra (n = 296) of 11 cover crop species and three cash crop species, and 2) spaceborne PRISMA imagery that coincided with destructive crop residue collections in the spring of 2022 (n = 65). Spectral range was constrained to 1200 to 2400nm to reduce the likelihood of confounding relationships in wavelengths sensitive to plant pigments or those related to canopy structure for both analytical approaches. Results Models using laboratory BER of PRISMA all demonstrated high accuracies and low errors for estimation of nitrogen and carbon traits (adj. R2 = 0.86 – 0.98; RMSE = 0.24 – 4.25%) and results suggest that a single model may be used for a given trait across all species. Models using spaceborne imaging spectroscopy demonstrated that crop residue carbon traits can be successfully estimated using PRISMA imagery (adj. R2 = 0.65 – 0.75; RMSE = 2.71 – 4.16%). We found moderate relationships between nitrogen concentration and PRISMA imagery (adj. R2 = 0.52; RMSE = 0.25%), which is partly related to the range of nitrogen in these senesced crop residues (0.38 – 1.85%). PRISMA imagery models were also impacted by atmospheric absorption, variability in surface moisture content, and some presence of green vegetation. Conclusion As spaceborne imaging spectroscopy data become more widely available from upcoming missions, crop residue trait estimates could be regularly generated and integrated into decision support tools to calculate decomposition rates and associated nitrogen credits to inform precision field management, as well as to enable measurement, monitoring, reporting, and verification of net carbon benefits from climate smart agricultural practice adoption in an emerging carbon marketplace.

Maryland↗

Linking aquifer spatial properties and non-Fickian transport in mobile-immobile like alluvial settings

Time-nonlocal transport models can describe non-Fickian diffusion observed in geological media, but the physical meaning of parameters can be ambiguous, and most applications are limited to curve-fitting. This study explores methods for predicting the parameters of a temporally tempered Lévy motion (TTLM) model for transient sub-diffusion in mobile–immobile like alluvial settings represented by high-resolution hydrofacies models. The TTLM model is a concise multi-rate mass transfer (MRMT) model that describes a linear mass transfer process where the transfer kinetics and late-time transport behavior are controlled by properties of the host medium, especially the immobile domain. The intrinsic connection between the MRMT and TTLM models helps to estimate the main time-nonlocal parameters in the TTLM model (which are the time scale index, the capacity coefficient, and the truncation parameter) either semi-analytically or empirically from the measurable aquifer properties. Further applications show that the TTLM model captures the observed solute snapshots, the breakthrough curves, and the spatial moments of plumes up to the fourth order. Most importantly, the a priori estimation of the time-nonlocal parameters outside of any breakthrough fitting procedure provides a reliable “blind” prediction of the late-time dynamics of subdiffusion observed in a spectrum of alluvial settings. Predictability of the time-nonlocal parameters may be due to the fact that the late-time subdiffusion is not affected by the exact location of each immobile zone, but rather is controlled by the time spent in immobile blocks surrounding the pathway of solute particles. Results also show that the effective dispersion coefficient has to be fitted due to the scale effect of transport, and the mean velocity can differ from local measurements or volume averages. The link between medium heterogeneity and time-nonlocal parameters will help to improve model predictability for non-Fickian transport in alluvial settings.

Journal of Hydrology↗

Analysis of changes in water-level dynamics at selected sites in the Florida Everglades

The historical modification and regulation of the hydrologic patterns in the Florida Everglades have resulted in changes in the ecosystem of South Florida and the Florida Everglades. Since the 1970s, substantial focus has been given to the restoration of the Everglades ecosystem. The U.S. Geological Survey through its Greater Everglades Priority Ecosystem Science and National Water-Quality Assessment Programs has been providing scientific information to resource managers to assist in the Everglades restoration efforts. The current investigation included development of a simple method to identify and quantify changes in historical hydrologic behavior within the Everglades that could be used by researchers to identify responses of ecological communities to those changes. Such information then could be used by resource managers to develop appropriate water-management practices within the Everglades to promote restoration. The identification of changes in historical hydrologic behavior within the Everglades was accomplished by analyzing historical time-series water-level data from selected gages in the Everglades using (1) break-point analysis of cumulative Z-scores to identify hydrologic changes and (2) cumulative water-level frequency distribution curves to evaluate the magnitude of those changes. This analytical technique was applied to six long-term water-level gages in the Florida Everglades. The break-point analysis for the concurrent period of record (1978–2011) identified 10 common periods of changes in hydrologic behavior at the selected gages. The water-level responses at each gage for the 10 periods displayed similarity in fluctuation patterns, highlighting the interconnectedness of the Florida Everglades hydrologic system. While the patterns were similar, the analysis also showed that larger fluctuations in water levels between periods occurred in Water Conservation Areas 2 and 3 in contrast to those in Water Conservation Area 1 and the Everglades National Park. Results from the analysis indicate that the cumulative Z-score curve, in conjunction with cumulative water-level frequency distribution curves, can be a useful tool in identifying and quantifying changes in historical hydrologic behavior within the Everglades. In addition to the analysis, a spreadsheet application was developed to assist in applying these techniques to time-series water-level data at gages within the Everglades and is included with this report.

Florida↗

dMODELS, a MATLAB software package for modeling crustal deformation near volcanic centers and active faults using Global Navigation Satellite System data—User guide

dMODELS is a MATLAB software package that implements the most common analytical models used to interpret deformation measurements near faults and active volcanic centers. This manual focuses on inversion of deformation data from the Global Navigation Satellite System (GNSS). The included case studies emphasize the GNSS inversion component of the software. Source models include pressurized spherical, spheroidal, and horizontal sill (penny-crack) magma reservoirs in a homogeneous, elastic, isotropic, flat half-space. A topography correction is available for the spherical source. Dikes and faults are described following the mathematical notation for the rectangular dislocations in a homogeneous, elastic, flat half-space. Equations have been reviewed for typographical errors present in the original literature and verified against finite-element method numerical models. GNSS data from the 2006 eruption at Augustine Volcano, Alaska; the 1998–2000 unrest at Taal Volcano, Philippines; and the 2009 earthquake in L’Aquila, Italy, are used to demonstrate the application of the software package.

Techniques and Methods↗

Isotope and Chemical Methods in Support of the U.S. Geological Survey Science Strategy, 2003-2008

Principal functions of the Mineral Resources Program are providing information to decision-makers related to mineral deposits on federal lands and predicting the environmental consequences of the mining or natural weathering of those deposits. Performing these functions requires that predictions be made of the likelihood of undiscovered deposits. The predictions are based on geologic and geoenvironmental models that are constructed for the various types of mineral deposits from detailed descriptions of actual deposits and detailed understanding of the processes that formed them. Over the past three decades the understanding of ore-forming processes has benefitted greatly from the integration of laboratory-based geochemical tools with field observations and other data sources. Under the aegis of the Evolution of Ore Deposits and Technology Transfer Project (EODTTP), a five-year effort that terminated in 2008, the Mineral Resources Program provided state-of-the-art analytical capabilities to support applications of several related geochemical tools.

Fact Sheet↗

A three-dimensional method-of-characteristics solute-transport model (MOC3D)

This report presents a model, MOC3D, that simulates three-dimensional solute transport in flowing ground water. The model computes changes in concentration of a single dissolved chemical constituent over time that are caused by advective transport, hydrodynamic dispersion (including both mechanical dispersion and diffusion), mixing (or dilution) from fluid sources, and mathematically simple chemical reactions (including linear sorption, which is represented by a retardation factor, and decay). The transport model is integrated with MODFLOW, a three-dimensional ground-water flow model that uses implicit finite-difference methods to solve the transient flow equation. MOC3D uses the method of characteristics to solve the transport equation on the basis of the hydraulic gradients computed with MODFLOW for a given time step. This implementation of the method of characteristics uses particle tracking to represent advective transport and explicit finite-difference methods to calculate the effects of other processes. However, the explicit procedure has several stability criteria that may limit the size of time increments for solving the transport equation; these are automatically determined by the program. For improved efficiency, the user can apply MOC3D to a subgrid of the primary MODFLOW grid that is used to solve the flow equation. However, the transport subgrid must have uniform grid spacing along rows and columns. The report includes a description of the theoretical basis of the model, a detailed description of input requirements and output options, and the results of model testing and evaluation. The model was evaluated for several problems for which exact analytical solutions are available and by benchmarking against other numerical codes for selected complex problems for which no exact solutions are available. These test results indicate that the model is very accurate for a wide range of conditions and yields minimal numerical dispersion for advection-dominated problems. Mass-balance errors are generally less than 10 percent, and tend to decrease and stabilize with time.

Water-Resources Investigations Report↗

Inference of distributional parameters from compositional samples containing nondetects

Low concentrations of elements in geochemical analyses have the peculiarity of being compositional data and, for a given level of significance, are likely to be beyond the capabilities of laboratories to distinguish between minute concentrations and complete absence, thus preventing laboratories from reporting extremely low concentrations of the analyte. Instead, what is reported is the detection limit, which is the minimum concentration that conclusively differentiates between presence and absence of the element. A spatially distributed exhaustive sample is employed in this study to generate unbiased sub-samples, which are further censored to observe the effect that different detection limits and sample sizes have on the inference of population distributions starting from geochemical analyses having specimens below detection limit (nondetects). The isometric logratio transformation is used to convert the compositional data in the simplex to samples in real space, thus allowing the practitioner to properly borrow from the large source of statistical techniques valid only in real space. The bootstrap method is used to numerically investigate the reliability of inferring several distributional parameters employing different forms of imputation for the censored data. The case study illustrates that, in general, best results are obtained when imputations are made using the distribution best fitting the readings above detection limit and exposes the problems of other more widely used practices. When the sample is spatially correlated, it is necessary to combine the bootstrap with stochastic simulation.

Conference Paper↗

Analytical sensitivities and energies of thermal neutron capture gamma rays II

A table of the analytical sensitivities of the principal lines in the thermal neutron capture gamma-ray spectrum from 0 to 3 MeV has been compiled for most of the elements. A tabulation of the full-energy, single-escape, and double-escape peaks has also been made according to energy. The tables are useful for spectral interpretation and calibration.

Nuclear Instruments and Methods↗

Determination of the common and rare alkalies in mineral analysis

Methods are described which afford a determination of each member of the alkali group and are successful in dealing with the quantities of the rare alkalies found in rocks and minerals. The procedures are relatively rapid and based chiefly on the use of chloroplatinic acid, absolute alcohol and ether, and ammonium sulfate. The percentages of all the alkalies found in a number of minerals are given.

Industrial And Engineering Chemistry Analytical Ed↗

U-Pb SHRIMP dating of uraniferous opals

U-Pb and U-series analyses of four U-rich opal samples using sensitive high-resolution ion microprobe (SHRIMP) demonstrate the potential of this technique for the dating of opals with ages ranging from several tens of thousand years to millions of years. The major advantages of the technique, compared to the conventional thermal ionisation mass spectrometry (TIMS), are the high spatial resolution (???20 ??m), the ability to analyse in situ all isotopes required to determine both U-Pb and U-series ages, and a relatively short analysis time which allows obtaining a growth rate of opal as a result of a single SHRIMP session. There are two major limitations to this method, determined by both current level of development of ion probes and understanding of ion sputtering processes. First, sufficient secondary ion beam intensities can only be obtained for opal samples with U concentrations in excess of ???20 ??g/g. However, this restriction still permits dating of a large variety of opals. Second, U-Pb ratios in all analyses drifted with time and were only weakly correlated with changes in other ratios (such as U/UO). This drift, which is difficult to correct for, remains the main factor currently limiting the precision and accuracy of the U-Pb SHRIMP opal ages. Nevertheless, an assumption of similar behaviour of standard and unknown opals under similar analytical conditions allowed successful determination of ages with precisions of ???10% for the samples investigated in this study. SHRIMP-based U-series and U-Pb ages are consistent with TIMS dating results of the same materials and known geological timeframes. ?? 2005 Elsevier B.V. All rights reserved.

Chemical Geology↗

An interactive viewer to improve operational aftershock forecasts

The U.S. Geological Survey (USGS) issues forecasts for aftershocks about 20 minutes after most earthquakes above M 5 in the United States and its territories, and updates these forecasts 75 times during the first year. Most of the forecasts are issued automatically, but some forecasts require manual intervention to maintain accuracy. It is important to identify the sequences whose forecasts will benefit from a modified approach so the USGS can provide accurate information to the public. The oaftools R package ( Paris and Michael, 2022 ) includes functions that analyze and plot earthquake sequences and their forecasts to identify which sequences require such intervention. The package includes the Operational Aftershock Forecast (OAF) Viewer, which incorporates the functions into an interactive web environment that can be used to explore aftershock sequences. The OAF Viewer starts with a global map and table of mainshocks. After a mainshock has been selected, the map and a new table show its aftershocks and the OAF Viewer generates five analytical plots: (1) magnitude–time, which is used to look for patterns in the data; (2) cumulative number, to see how the productivity of the sequence compares to a Reasenberg and Jones (1989) aftershock model over time; (3) magnitude–frequency, to compare the ratio of large to small magnitudes and extrapolate to higher magnitudes with sparse data and lower magnitudes with incomplete data; (4) forecast success, to compare the forecasts with observations for a sequence; and (5) parameter–time, which examines the temporal evolution of the forecast model parameters. The user can interact with the functions provided by the oaftools package through the OAF Viewer or by incorporating the functions into their own analysis methods. The OAF Viewer will help seismologists understand complexities in the data, communicate with the public and emergency managers, and improve the OAF system by maintaining operational awareness.

Seismological Research Letters↗