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At least 1,333 records · Page 74Linked to original sources
USGS2014

Evaluation of groundwater and surface-water interactions in the Caddo Nation Tribal Jurisdictional Area, Caddo County, Oklahoma, 2010-13

Streamflows, springs, and wetlands are important natural and cultural resources to the Caddo Nation. Consequently, the Caddo Nation is concerned about the vulnerability of the Rush Springs aquifer to overdrafting and whether the aquifer will continue to be a viable source of water to tribal members and other local residents in the future. Interest in the long-term viability of local water resources has resulted in ongoing development of a comprehensive water plan by the Caddo Nation. As part of a multiyear project with the Caddo Nation to provide information and tools to better manage and protect water resources, the U.S. Geological Survey studied the hydraulic connection between the Rush Springs aquifer and springs and streams overlying the aquifer. The Caddo Nation Tribal Jurisdictional Area is located in southwestern Oklahoma, primarily in Caddo County. Underlying the Caddo Nation Tribal Jurisdictional Area is the Permian-age Rush Springs aquifer. Water from the Rush Springs aquifer is used for irrigation, public, livestock and aquaculture, and other supply purposes. Groundwater from the Rush Springs aquifer also is withdrawn by domestic (self-supplied) wells, although domestic use was not included in the water-use summary in this report. Perennial streamflow in many streams and creeks overlying the Rush Springs aquifer, such as Cobb Creek, Lake Creek, and Willow Creek, originates from springs and seeps discharging from the aquifer. This report provides information on the evaluation of groundwater and surface-water resources in the Caddo Nation Jurisdictional Area, and in particular, information that describes the hydraulic connection between the Rush Springs aquifer and springs and streams overlying the aquifer. This report also includes data and analyses of base flow, evidence for groundwater and surface-water interactions, locations of springs and wetland areas, groundwater flows interpreted from potentiometric-surface maps, and hydrographs of water levels monitored in the Caddo Nation Tribal Jurisdictional Area from 2010 to 2013. Flow in streams overlying the Rush Springs aquifer, on average, were composed of 50 percent base flow in most years. Monthly mean base flow appeared to maintain streamflows throughout each year, but periods of zero flow were documented in daily hydrographs at each measured site, typically in the summer months. A pneumatic slug-test technique was used at 15 sites to determine the horizontal hydraulic conductivity of streambed sediments in streams overlying the Rush Springs aquifer. Converting horizontal hydraulic conductivities (Kh) from the slug-test analyses to vertical hydraulic conductivities (Kv) by using a ratio of Kv/Kh = 0.1 resulted in estimates of vertical streambed hydraulic conductivity ranging from 0.1 to 8.6 feet per day. Data obtained from a hydraulic potentiomanometer in streambed sediments and streams in August 2012 indicate that water flow was from the streambed sediments to the stream (gaining) at 6 of 15 sites, and that water flow was from the stream to the streambed sediments (losing) at 9 of 15 sites. The groundwater and surface-water interaction data collected at the Cobb Creek near Eakly, Okla., streamflow gaging station (07325800), indicate that the bedrock groundwater, alluvial groundwater, and surface-water resources are closely connected. Because of this hydrologic connection, large perennial streams in the study area may change from gaining to losing streams in the summer. The timing and severity of this change from a gaining to a losing condition probably is affected by the local or regional withdrawal of groundwater for irrigation in the summer growing season. Wells placed closer to streams have a greater and more immediate effect on alluvial groundwater levels and stream stages than wells placed farther from streams. Large-capacity irrigation wells, even those completed hundreds of feet below land surface in the bedrock aquifer, can induce surface-water flow from nearby streams by lowering alluvial groundwater levels below the stream altitude. Twenty-five new springs visible from public roads and paths were documented during a survey of springs in 2011. Most of the springs are in upland draws on the flanks of topographic ridges. Wetlands primarily were identified by using a combination of data sources including the National Wetlands Inventory, Soil Survey Geographic database frequently flooded soils maps, and aerial photographs. Regional flow directions were determined by analysis of water levels measured in 29 wells completed in the Rush 2 Springs aquifer in Caddo County and the Caddo Nation Tribal Jurisdictional Area. Water levels were monitored every 30 minutes in five wells by using a vented pressure transducer and a data-collection platform with real-time transmitting equipment in each well. Those five wells ranged in depth from 210 to 350 feet. Water levels in these five wells indicate that there was a decrease in water storage in the Rush Springs aquifer from October 2010 to June 2013.

Oklahoma↗
USGS1988

Effects of fluctuating river-pool stages on ground-water levels in the adjacent alluvial aquifer in the lower Arkansas River, Arkansas

The U.S. Geological Survey conducted a study in cooperation with the U.S. Army Corps of Engineers to determine the effect of fluctuating the lower Arkansas River. A network of 41 wells was used to delineate 4 cross sections adjacent to river pools 2 and 5 of the McClellan-Kerr Arkansas River Navigation System to examine groundwater levels at various distances from the river. The hydraulic gradient of water levels in the alluvial aquifer along these cross sections indicates that the river is losing water to the adjacent aquifer. The effect on groundwater levels in the alluvial aquifer caused by pool-stage fluctuations was most pronounced at distances less than about 2 miles from the Arkansas River. At distances greater than about 2 miles, the changes in groundwater levels probably were the result of water levels rising in the aquifer since the heavy summer irrigation withdrawals have ceased. An equation useful for estimating the distribution of head change an aquifer in response to river-pool-stage changes, was applied to the study area to estimate the effect of a 1-foot rise in pool stage on water levels in the adjacent alluvial aquifer after equilibrium conditions have been established. The theoretical head change (rise) in the aquifer was estimated to range from 1-foot at the Arkansas River to 0.57 foot at a distance of 5 miles away from the river. (USGS)

Water-Resources Investigations Report↗
USGS1999

Tributary stream infiltration as a source of herbicides in an alluvial aquifer

Where Walnut Creek flows across the South Skunk River alluvial aquifer, it provides a potential source of herbicides and herbicide metabolites. This straightened reach of the creek loses water and dissolved contaminants to the alluvial aquifer through a layer of fine-grained flood plain deposits. Estimates of potential flux of chemicals were based on measurements taken during baseflow in April 1994 before herbicides were applied to the watershed and in June 1994 after chemical application and when stream discharge included runoff and tile-drainage water. Hydraulic head measurements between the creek and flood plain deposits and between the creek and aquifer confirmed the potential for downward groundwater flow during both sampling periods. Hydraulic conductivity estimates from slug tests were used to calculate an average linear groundwater velocity of 0.5 m d −1 in the fine-grained flood plain deposits. At this velocity, contaminants could be advectively transported to the aquifer within 6 d. The potential for atrazine (2-chloro-4-ethylamino-6-isopropylamino- s -triazine) flux to the aquifer from the creek was estimated to be between 60 and 3000 µg d −1 m −2 . This rate is one to three orders of magnitude greater than the estimated flux via leaching beneath a typical field. If the process of vertical stream leakage occurs in many hydrologic settings, it may constitute a substantial source of herbicides to shallow alluvial aquifers in many areas of the Midwest.

Iowa↗
USGS2014

Groundwater quality in central New York, 2012

Water samples were collected from 14 production wells and 15 private wells in central New York from August through December 2012 in a study conducted by the U.S. Geological Survey in cooperation with the New York State Department of Environmental Conservation. The samples were analyzed to characterize the groundwater quality in unconsolidated and bedrock aquifers in this area. Fifteen of the wells are finished in sand-and-gravel aquifers, and 14 are finished in bedrock aquifers. Six of the 29 wells were sampled in a previous central New York study, which was conducted in 2007. Water samples from the 2012 study were analyzed for 147 physiochemical properties and constituents, including major ions, nutrients, trace elements, radionuclides, pesticides, volatile organic compounds, dissolved gases (argon, carbon dioxide, methane, nitrogen, oxygen), and indicator bacteria. Results of the water-quality analyses are presented in tabular form for individual wells, and summary statistics for specific constituents are presented by aquifer type. The results are compared with Federal and New York State drinking-water standards, which typically are identical. The results indicate that the groundwater generally is of acceptable quality, although for all of the wells sampled, at least one of the following constituents was detected at a concentration that exceeded current or proposed Federal or New York State drinking-water standards: color (2 samples), pH (7 samples), sodium (9 samples), chloride (2 samples), fluoride (2 samples), sulfate (2 samples), dissolved solids (8 samples), aluminum (4 samples), arsenic (1 sample), iron (9 samples), manganese (13 samples), radon-222 (13 samples), total coliform bacteria (6 samples), and heterotrophic bacteria (2 samples). Drinking-water standards for nitrate, nitrite, antimony, barium, beryllium, cadmium, chromium, copper, lead, mercury, selenium, silver, thallium, zinc, gross alpha radioactivity, uranium, fecal coliform, and Escherichia coli were not exceeded in any of the samples collected. None of the pesticides or volatile organic compounds analyzed exceeded drinking-water standards. Methane was detected in 11 sand-and-gravel wells and 9 bedrock wells. Five of the 14 bedrock wells had water with methane concentrations approaching 10 mg/L; water in one bedrock well had 37 mg/L of methane.

New York↗
USGS2021

Migration of injected wastewater with high levels of ammonia in a saline aquifer in south Florida

Treated wastewater with high levels of ammonia has been injected, since March 1983 into the deep saline units of the Lower Floridan aquifer (LFA) from a treatment plant near the east coast of Miami-Dade County in southeastern Florida. Monitoring wells in the plant recorded ammonia concentrations above ambient levels at hydrogeologic units located about 1000 ft (304.8 m) above injection depths between 2500 and 2800 ft (762 and 853 m) below sea level. A solute-transport model was developed to assess the horizontal and vertical extent of the injected ammonia, with ammonia moving from the injected zone into the overlying units: the upper semiconfining unit, the uppermost permeable zone of the LFA, and the middle semiconfining units of the Avon Park Formation. Ammonia is assumed to be transported under the effects of local heterogeneity in a porous limestone aquifer with high-salinity ambient groundwater and via upward migration through quasi-vertical pathways. A flow model of the migration of the injected ammonia was calibrated with PEST using head, salinity, and ammonia concentration data measured from 1983 to 2013. Borehole geophysical data support the high permeability of the uppermost permeable zone in the LFA. Average simulated head, normalized salinity, and ammonia concentration residuals over all monitoring wells were −1.37 ft, 0.01, and −0.67 mg/L, respectively. Model results are consistent with undetectable ammonia concentrations in the Upper Floridan aquifer.

Florida↗
USGS2003

The behavior of U- and Th-series nuclides in groundwater

Groundwater has long been an active area of research driven by its importance both as a societal resource and as a component in the global hydrological cycle. Key issues in groundwater research include inferring rates of transport of chemical constituents, determining the ages of groundwater, and tracing water masses using chemical fingerprints. While information on the trace elements pertinent to these topics can be obtained from aquifer tests using experimentally introduced tracers, and from laboratory experiments on aquifer materials, these studies are necessarily limited in time and space. Regional studies of aquifers can focus on greater scales and time periods, but must contend with greater complexities and variations. In this regard, the isotopic systematics of the naturally occurring radionuclides in the U- and Th- decay series have been invaluable in investigating aquifer behavior of U, Th, and Ra. These nuclides are present in all groundwaters and are each represented by several isotopes with very different half-lives, so that processes occurring over a range of time-scales can be studied (Table 1 ⇓ ). Within the host aquifer minerals, the radionuclides in each decay series are generally expected to be in secular equilibrium and so have equal activities (see Bourdon et al. 2003 ). In contrast, these nuclides exhibit strong relative fractionations within the surrounding groundwaters that reflect contrasting behavior during release into the water and during interaction with the surrounding host aquifer rocks. Radionuclide data can be used, within the framework of models of the processes involved, to obtain quantitative assessments of radionuclide release from aquifer rocks and groundwater migration rates. The isotopic variations that are generated also have the potential for providing fingerprints for groundwaters from specific aquifer environments, and have even been explored as a means for calculating groundwater ages.

Reviews in Mineralogy and Geochemistry↗
USGS2012

Evaluation of long-term water-level declines in basalt aquifers near Mosier, Oregon

The Mosier area lies along the Columbia River in northwestern Wasco County between the cities of Hood River and The Dalles, Oregon. Major water uses in the area are irrigation, municipal supply for the city of Mosier, and domestic supply for rural residents. The primary source of water is groundwater from the Columbia River Basalt Group (CRBG) aquifers that underlie the area. Concerns regarding this supply of water arose in the mid-1970s, when groundwater levels in the orchard tract area began to steadily decline. In the 1980s, the Oregon Water Resources Department (OWRD) conducted a study of the aquifer system, which resulted in delineation of an administrative area where parts of the Pomona and Priest Rapids aquifers were withdrawn from further appropriations for any use other than domestic supply. Despite this action, water levels continued to drop at approximately the same, nearly constant annual rate of about 4 feet per year, resulting in a current total decline of between 150 and 200 feet in many wells with continued downward trends. In 2005, the Mosier Watershed Council and the Wasco Soil and Water Conservation District began a cooperative investigation of the groundwater system with the U.S. Geological Survey. The objectives of the study were to advance the scientific understanding of the hydrology of the basin, to assess the sustainability of the water supply, to evaluate the causes of persistent groundwater-level declines, and to evaluate potential management strategies. An additional U.S. Geological Survey objective was to advance the understanding of CRBG aquifers, which are the primary source of water across a large part of Oregon, Washington, and Idaho. In many areas, significant groundwater level declines have resulted as these aquifers were heavily developed for agricultural, municipal, and domestic water supplies. Three major factors were identified as possible contributors to the water-level declines in the study area: (1) pumping at rates that are not sustainable, (2) well construction practices that have resulted in leakage from aquifers into springs and streams, and (3) reduction in aquifer recharge resulting from long-term climate variations. Historical well construction practices, specifically open, unlined, uncased boreholes that result in cross-connecting (or commingling) multiple aquifers, allow water to flow between these aquifers. Water flowing along the path of least resistance, through commingled boreholes, allows the drainage of aquifers that previously stored water more efficiently. The study area is in the eastern foothills of the Cascade Range in north central Oregon in a transitional zone between the High Cascades to the west and the Columbia Plateau to the east. The 78-square mile (mi 2 ) area is defined by the drainages of three streams - Mosier Creek (51.8 mi 2 ), Rock Creek (13.9 mi 2 ), and Rowena Creek (6.9 mi 2 ) - plus a small area that drains directly to the Columbia River.The three major components of the study are: (1) a 2-year intensive data collection period to augment previous streamflow and groundwater-level measurements, (2) precipitation-runoff modeling of the watersheds to determine the amount of recharge to the aquifer system, and (3) groundwater-flow modeling and analysis to evaluate the cause of groundwater-level declines and to evaluate possible water resource management strategies. Data collection included the following: 1. Water-level measurements were made in 37 wells. Bi-monthly or quarterly measurements were made in 30 wells, and continuous water-level monitoring instruments were installed in 7 wells. The measurements principally were made to capture the seasonal patterns in the groundwater system, and to augment the available long-term record. 2. Groundwater pumping was measured, reported, or estimated from irrigation, municipal and domestic wells. Flowmeters were installed on 74 percent of all high-capacity irrigation wells in the study area. 3. Borehole geophysical data were collected from a known commingling well. These data measured geologic properties and vertical flow through the well. 4. Streamflow measurements were made in Rock, Rowena, and Mosier Creeks. A long-term recording stream-gaging station was reestablished on Mosier Creek to provide a continuous record of streamflow. Streamflow measurements also were made along the creeks periodically to evaluate seasonal patterns of exchange between streams and the groundwater system. Major findings from the study include: 1. Annual average precipitation ranges from 20 to 54 inches across the study area with an average value of about 30 inches. Based on rainfall-runoff modeling, about one-third of this water infiltrates into the aquifer system. 2. Currently, about 3 percent of the water infiltrated into the groundwater system is extracted for municipal, agricultural, and rural residential use. The remainder of the water flows through the aquifer system, discharging into local streams and the Columbia River. About 80 percent of recent pumping supports crop production. The city of Mosier public supply wells account for about 10 percent of total pumping, with the remaining 10 percent being pumped from the private wells of rural residents. 3. Groundwater-flow simulation results indicate that leakage through commingling wells is a significant and likely the dominant cause of water level declines. Leakage patterns can be complex, but most of the leaked water likely flows out the CRBG aquifer system through very permeable sediments into Mosier Creek and its tributary streams in the OWRD administrative area. Model-derived estimates attribute 80-90 percent of the declines to commingling, with pumping accounting for the remaining 10-20 percent. Although decadal trends in precipitation have occurred, associated changes in aquifer recharge are likely not a significant contributor to the current water level declines. 4. As many as 150 wells might be commingling. To evaluate whether or not the local combination of geology and well construction have resulted in aquifer commingling at a particular well, the well needs to be tested by measuring intraborehole flow. During geophysical testing of one known commingling well, the flow rate through the well between aquifers ranged between 70 and 135 gallons per minute (11-22 percent of total annual pumping in the study area). Historically, when aquifer water levels were 150-200 feet higher, this flow rate would have been correspondingly higher. 5. Because aquifer commingling through well boreholes is likely the dominant cause of aquifer declines, flow simulations were conducted to evaluate the benefit of repairing wells in specified locations and the benefit of recharging aquifers using diverted flow from study area creeks. As part of this analysis, maps were generated that show which areas are more vulnerable to commingling. These maps indicate that the value of repairing wells in the area generally coincident with the OWRD administrative area is higher than in areas farther upstream in the watershed. Simulation results also indicate that artificial recharge of the aquifers using diverted creek water will not significantly improve water levels in the aquifer system unless at least some commingling wells are repaired first. Repairs would entail construction of wells in a manner that prevents commingling of multiple aquifers. The value of artificially recharging the aquifers improves as more wells are repaired because the aquifer system more efficiently stores water.

Oregon↗
USGS2014

Spatially distributed groundwater recharge estimated using a water-budget model for the Island of Maui, Hawai`i, 1978–2007

Demand for freshwater on the Island of Maui is expected to grow. To evaluate the availability of fresh groundwater, estimates of groundwater recharge are needed. A water-budget model with a daily computation interval was developed and used to estimate the spatial distribution of recharge on Maui for average climate conditions (1978–2007 rainfall and 2010 land cover) and for drought conditions (1998–2002 rainfall and 2010 land cover). For average climate conditions, mean annual recharge for Maui is about 1,309 million gallons per day, or about 44 percent of precipitation (rainfall and fog interception). Recharge for average climate conditions is about 39 percent of total water inflow consisting of precipitation, irrigation, septic leachate, and seepage from reservoirs and cesspools. Most recharge occurs on the wet, windward slopes of Haleakalā and on the wet, uplands of West Maui Mountain. Dry, coastal areas generally have low recharge. In the dry isthmus, however, irrigated fields have greater recharge than nearby unirrigated areas. For drought conditions, mean annual recharge for Maui is about 1,010 million gallons per day, which is 23 percent less than recharge for average climate conditions. For individual aquifer-system areas used for groundwater management, recharge for drought conditions is about 8 to 51 percent less than recharge for average climate conditions. The spatial distribution of rainfall is the primary factor determining spatially distributed recharge estimates for most areas on Maui. In wet areas, recharge estimates are also sensitive to water-budget parameters that are related to runoff, fog interception, and forest-canopy evaporation. In dry areas, recharge estimates are most sensitive to irrigated crop areas and parameters related to evapotranspiration.

Hawai'i↗
USGS1989

Geohydrology of the regional aquifer system, western Snake River plain, southwestern Idaho

A three dimensional groundwater flow model was developed to simulate steady state and nonsteady-state hydrologic conditions of the regional aquifer system in the western Snake River Plain of Idaho. Water budget analysis showed that groundwater recharge was about 1,400,000 acre-ft in 1980; groundwater pumpage was estimated to be 300,000 acre-ft. Two mass water level measurements were made in March and August 1980 to define the water table in the regional system. The model was discretized into 25 rows, 72 columns, and 3 layers. Each cell represented 4 sq mi. The model was calibrated to 1980 hydrologic conditions. Calibrated transmissivity of layer 1 (500 ft thick) ranged from 1,500 to 21,500 sq ft/day. Calibrated specific yield of unconfined aquifers was 0.10 and calibrated storage coefficient of confined aquifers ranged from 0.0004 to 0.007. The calibrated model was verified by simulating monthly water-level fluctuations for 1980. Simulated water levels matched measured levels in the Boise River Valley, but the match in other areas was poor. (USGS)

Open-File Report↗
USGS2010

Hydrogeology and groundwater quality of Highlands County, Florida

Groundwater is the main source of water supply in Highlands County, Florida. As the demand for water in the county increases, additional information about local groundwater resources is needed to manage and develop the water supply effectively. To address the need for additional data, a study was conducted to evaluate the hydrogeology and groundwater quality of Highlands County. Total groundwater use in Highlands County has increased steadily since 1965. Total groundwater withdrawals increased from about 37 million gallons per day in 1965 to about 107 million gallons per day in 2005. Much of this increase in water use is related to agricultural activities, especially citrus cultivation, which increased more than 300 percent from 1965 to 2005. Highlands County is underlain by three principal hydrogeologic units. The uppermost water-bearing unit is the surficial aquifer, which is underlain by the intermediate aquifer system/intermediate confining unit. The lowermost hydrogeologic unit is the Floridan aquifer system, which consists of the Upper Floridan aquifer, as many as three middle confining units, and the Lower Floridan aquifer. The surficial aquifer consists primarily of fine-to-medium grained quartz sand with varying amounts of clay and silt. The aquifer system is unconfined and underlies the entire county. The thickness of the surficial aquifer is highly variable, ranging from less than 50 to more than 300 feet. Groundwater in the surficial aquifer is recharged primarily by precipitation, but also by septic tanks, irrigation from wells, seepage from lakes and streams, and the lateral groundwater inflow from adjacent areas. The intermediate aquifer system/intermediate confining unit acts as a confining layer (except where breached by sinkholes) that restricts the vertical movement of water between the surficial aquifer and the underlying Upper Floridan aquifer. The sediments have varying degrees of permeability and consist of permeable limestone, dolostone, or sand, or relatively impermeable layers of clay, clayey sand, or clayey carbonates. The thickness of the intermediate aquifer system/ intermediate confining unit ranges from about 200 feet in northwestern Highlands County to more than 600 feet in the southwestern part. Although the intermediate aquifer system is present in the county, it is unclear where the aquifer system grades into a confining unit in the eastern part of the county. Up to two water-bearing units are present in the intermediate aquifer system within the county. The lateral continuity and water-bearing potential of the various aquifers within the intermediate aquifer system are highly variable. The Floridan aquifer system is composed of a thick sequence of limestone and dolostone of Upper Paleocene to Oligocene age. The top of the aquifer system ranges from less than 200 feet below NGVD 29 in extreme northwestern Highlands County to more than 600 feet below NGVD 29 in the southwestern part. The principal source of groundwater supply in the county is the Upper Floridan aquifer. As of 2005, about 89 percent of the groundwater withdrawn from the county was obtained from this aquifer, mostly for agricultural irrigation and public supply. Over most of Highlands County, the Upper Floridan aquifer generally contains freshwater, and the Lower Floridan aquifer contains more mineralized water. The potentiometric surface of the Upper Floridan aquifer is constantly fluctuating, mainly in response to seasonal variations in rainfall and groundwater withdrawals. The potentiometric surface of the Upper Floridan aquifer in May 2007, which represents the hydrologic conditions near the end of the dry season when water levels generally are near their lowest, ranged from about 79 feet above NGVD 29 in northwestern Highlands County to about 40 feet above NGVD 29 in the southeastern part of the county. The potentiometric surface of the Upper Floridan aquifer in September 2007 was about 3 to 10 feet high

Scientific Investigations Report↗
USGS2022

Natural inactivation of MS2, poliovirus type 1 and Cryptosporidium parvum in an anaerobic and reduced aquifer

Aims The study of microbial inactivation rates in aquifer systems has most often been determined in aerobic and oxidized systems. This study examined the inactivation (i.e. loss of infectivity) of MS2, poliovirus type 1 (PV1) and Cryptosporidium parvum in an anaerobic and reduced groundwater system that has been identified as storage zones for aquifer storage and recovery (ASR) facilities. Methods and Results Anaerobic and reduced (ORP < − 250 mV) groundwater from an artesian well was diverted to an above-ground, flow-through mesocosm that contained diffusion chambers filled with MS2, PV1 or Cryptosporidium parvum . The respective infectivity assays were performed on microorganisms recovered from the diffusion chambers during 30- to 58-day experiments. The net reduction in infectivity was 5.73 log 10 over 30 days for MS2, 5.00 log 10 over 58 days for PV1 and 4.07 log 10 over 37 days for C . parvum . The best fit inactivation model for PV1 was the log-linear model and the Weibull model for MS2 and C . parvum , with respective inactivation rates (95% confidence interval) of 0.19 (0.17–0.21) log 10 day −1 , 0.31 (0.19–0.89) log 10 day −1 and 0.20 (0.14–0.37) log 10 day −1 . Conclusions The groundwater geochemical conditions in this aquifer enhanced the inactivation of MS2, PV1, and C . parvum at rates approximately 2.0–5.3-fold, 1.2–17.0-fold, and 4.5–5.6-fold greater, respectively, than those from published studies that used diffusion chambers in aerobic-to-anoxic groundwater systems, with positive redox potentials. Significance and Impact of the Study Geochemical conditions like those in the aquifer zone in this study can naturally and significantly reduce concentrations of microbial indicators and pathogens of human health concern in injected surface water. Appropriate storage times for injected surface water could complement above-ground engineered processes for microorganism removal and inactivation (e.g. filtration, disinfection) by naturally increasing overall microorganism log-inactivation rates of ASR facilities.

Journal of Applied Microbiology↗
USGS2008

Influence of variable chemical conditions on EDTA-enhanced transport of metal ions in mildly acidic groundwater

Adsorption of Ni and Pb on aquifer sediments from Cape Cod, Massachusetts, USA increased with increasing pH and metal-ion concentration. Adsorption could be described quantitatively using a semi-mechanistic surface complexation model (SCM), in which adsorption is described using chemical reactions between metal ions and adsorption sites. Equilibrium reactive transport simulations incorporating the SCMs, formation of metal-ion-EDTA complexes, and either Fe(III)-oxyhydroxide solubility or Zn desorption from sediments identified important factors responsible for trends observed during transport experiments conducted with EDTA complexes of Ni, Zn, and Pb in the Cape Cod aquifer. Dissociation of Pb-EDTA by Fe(III) is more favorable than Ni-EDTA because of differences in Ni- and Pb-adsorption to the sediments. Dissociation of Ni-EDTA becomes more favorable with decreasing Ni-EDTA concentration and decreasing pH. In contrast to Ni, Pb-EDTA can be dissociated by Zn desorbed from the aquifer sediments. Variability in adsorbed Zn concentrations has a large impact on Pb-EDTA dissociation.

Environmental Pollution↗
USGS2004

Direct-push geochemical profiling for assessment of inorganic chemical heterogeneity in aquifers

Discrete-depth sampling of inorganic groundwater chemistry is essential for a variety of site characterization activities. Although the mobility and rapid sampling capabilities of direct-push techniques have led to their widespread use for evaluating the distribution of organic contaminants, complementary methods for the characterization of spatial variations in geochemical conditions have not been developed. In this study, a direct-push-based approach for high-resolution inorganic chemical profiling was developed at a site where sharp chemical contrasts and iron-reducing conditions had previously been observed. Existing multilevel samplers (MLSs) that span a fining-upward alluvial sequence were used for comparison with the direct-push profiling. Chemical profiles obtained with a conventional direct-push exposed-screen sampler differed from those obtained with an adjacent MLS because of sampler reactivity and mixing with water from previous sampling levels. The sampler was modified by replacing steel sampling components with stainless-steel and heat-treated parts, and adding an adapter that prevents mixing. Profiles obtained with the modified approach were in excellent agreement with those obtained from an adjacent MLS for all constituents and parameters monitored (Cl, NO3, Fe, Mn, DO, ORP, specific conductance and pH). Interpretations of site redox conditions based on field-measured parameters were supported by laboratory analysis of dissolved Fe. The discrete-depth capability of this approach allows inorganic chemical variations to be described at a level of detail that has rarely been possible. When combined with the mobility afforded by direct-push rigs and on-site methods of chemical analysis, the new approach is well suited for a variety of interactive site-characterization endeavors. ?? 2003 Elsevier B.V. All rights reserved.

Journal of Contaminant Hydrology↗
USGS1987

Growth determinations for unattached bacteria in a contaminated aquifer

Growth rates of unattached bacteria in groundwater contaminated with treated sewage and collected at various distances from the source of contamination were estimated by using frequency of dividing cells and tritiated-thymidine uptake and compared with growth rates obtained with unsupplemented, closed-bottle incubations. Estimates of bacterial generation times [(In 2)/ μ ] along a 3-km-long transect in oxygen-depleted (0.1 to 0.7 mg of dissolved oxygen liter -1 ) groundwater ranged from 16 h at 0.26 km downgradient from an on-land, treated-sewage outfall to 139 h at 1.6 km and correlated with bacterial abundance ( r 2 = 0.88 at P < 0.001). Partitioning of assimilated thymidine into nucleic acid generally decreased with distance from the contaminant source, and one population in heavily contaminated groundwater assimilated little thymidine during a 20-h incubation. Several assumptions commonly made when frequency of dividing cells and tritiated-thymidine uptake are used were not applicable to the groundwater samples.

Massachusetts↗
USGS1986

Quality of ground water in the Payette River basin, Idaho

As part of a study to obtain groundwater quality data in areas of Idaho were land- and water-resource development is expected to increase, water quality, geologic, and hydrologic data were collected for 74 wells in the Payette River basin, west-central Idaho, from July to October 1982. Historical (pre-1982) data from 13 wells were compiled with more recent (1982) data to define, on a reconnaissance level, water quality conditions in major aquifers and to identify factors that may have affected groundwater quality. Water from the major aquifers generally contains predominantly calcium, magnesium, and bicarbonate plus carbonate ions. Sodium and bicarbonate or sulfate are the predominant ions in groundwater from 25% of the 1982 samples. Areally, groundwater from the upper Payette River basin has proportionately lower ion concentrations than water from the lower Payette River basin. Water samples from wells < 100 ft deep generally have lower ion concentrations than samples from wells > 100 ft deep. Variations in groundwater quality probably are most affected by differences in aquifer composition and proximity to source(s) of recharge. Groundwater in the study area is generally suitable for most uses. In localized areas, pH and concentrations of hardness, alkalinity, dissolved solids, or dissolved nitrite plus nitrate as nitrogen, sulfate, fluoride, iron, or manganese exceed Federal drinking water limits and may restrict some uses of the water.

Idaho↗
USGS2000

Mechanism and rate of denitrification in an agricultural watershed: Electron and mass balance along groundwater flow paths

The rate and mechanism of nitrate removal along and between groundwater flow paths were investigated using a series of well nests screened in an unconfined sand and gravel aquifer. Intensive agricultural activity in this area has resulted in nitrate concentrations in groundwater often exceeding drinking water standards. Both the extent and rate of denitrification varied depending on the groundwater flow path. While little or no denitrification occurred in much of the upland portions of the aquifer, a gradual redox gradient is observed as aerobic upland groundwater moves deeper in the aquifer. In contrast, a sharp shallow redox gradient is observed adjacent to a third‐order stream as aerobic groundwater enters reduced sediments. An essentially complete loss of nitrate concurrent with increases in excess N 2 provide evidence that denitrification occurs as groundwater enters this zone. Electron and mass balance calculations suggest that iron sulfide (e.g., pyrite) oxidation is the primary source of electrons for denitrification. Denitrification rate estimates were based on mass balance calculations using nitrate and excess N 2 coupled with groundwater travel times. Travel times were determined using a groundwater flow model and were constrained by chlorofluorocarbon‐based age dates. Denitrification rates were found to vary considerably between the two areas where denitrification occurs. Denitrification rates in the deep, upland portions of the aquifer were found to range from <0.01 to 0.14 m M of N per year; rates at the redoxcline along the shallow flow path range from 1.0 to 2.7 m M of N per year. Potential denitrification rates in groundwater adjacent to the stream may be much faster, with rates up to 140 m M per year based on an in situ experiment conducted in this zone.

Water Resources Research↗
USGS2023

Occurrence of pharmaceutical compounds in the San Antonio segment of the Edwards (Balcones fault zone) aquifer, south-central Texas, June 2018–August 2020

The occurrence of pharmaceutical compounds (hereinafter referred to as “pharmaceuticals”) in surface water that recharges the San Antonio segment of the Edwards aquifer in south-central Texas is of concern with respect to potential effects on groundwater quality. This study, conducted during June 2018–August 2020 by the U.S. Geological Survey in cooperation with the San Antonio Water System, used a source-to-sink approach (that is, from aquifer recharge to aquifer discharge) to compare the occurrences and concentrations of pharmaceuticals in recharging (losing) streams to those in relatively shallow and relatively deep groundwater. Individual pharmaceutical concentrations in surface water were all less than 200 nanograms per liter, and most were less than 50 nanograms per liter. The two most common pharmaceuticals in surface water were metformin (50-percent detection frequency) and caffeine (25-percent detection frequency). In contrast to surface-water sites, few detections of pharmaceuticals above the detection limit were quantified at groundwater sites. On the basis of studied sample sites that are considered to be representative of the Edwards aquifer recharge zone, groundwater results collectively indicate that pharmaceuticals currently (2020) do not substantially impair water quality in the shallow unconfined part of the Edwards aquifer. Although groundwater pharmaceutical detections were not common, two detections of acetaminophen occurred in samples collected from a relatively deep confined part of the aquifer, indicating that this part of the aquifer is potentially vulnerable to pharmaceutical contamination. The near absence of wastewater treatment plant discharges and Texas Land Application Permit facilities within the drainage areas of streams in this study could explain reduced inputs of pharmaceuticals relative to pesticides on the Edwards aquifer recharge zone and their reduced occurrence in unconfined groundwater. In the western part of the study area, numerous pharmaceutical detections in the Frio River indicate that pharmaceutical sources in rural areas also exist with potential water-quality effects. Although reported pharmaceutical concentrations for the San Antonio segment of the Edwards aquifer are currently (2020) low, ongoing development in the region has the potential to increase contaminant loads, including for pharmaceuticals.

Texas↗
USGS2009

Patterns of Tamarix water use during a record drought

During a record drought (2006) in southwest Kansas, USA, we assessed groundwater dynamics in a shallow, unconfined aquifer, along with plant water sources and physiological responses of the invasive riparian shrub Tamarix ramosissima. In early May, diel water table fluctuations indicated evapotranspirative consumption of groundwater by vegetation. During the summer drought, the water table elevation dropped past the lowest position previously recorded. Concurrent with this drop, water table fluctuations abruptly diminished at all wells at which they had previously been observed despite increasing evapotranspirative demand. Following reductions in groundwater fluctuations, volumetric water content declined corresponding to the well-specific depths of the capillary fringe in early May, suggesting a switch from primary dependence on groundwater to vadose-zone water. In at least one well, the fluctuations appear to re-intensify in August, suggesting increased groundwater uptake by Tamarix or other non-senesced species from a deeper water table later in the growing season. Our data suggest that Tamarix can rapidly shift water sources in response to declines in the water table. The use of multiple water sources by Tamarix minimized leaf-level water stress during drought periods. This study illustrates the importance of the previous hydrologic conditions experienced by site vegetation for controlling root establishment at depth and demonstrates the utility of data from high-frequency hydrologic monitoring in the interpretation of plant water sources using isotopic methods. ?? Springer-Verlag 2009.

Oecologia↗