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Reply to, “Comment on ‘The 1886 Charleston, South Carolina, earthquake: Relic railroad offset reveals rupture,’ by Roger Bilham and Susan E. Hough”

We welcome this opportunity to respond to Pratt et al. (2024) (hereinafter P24). Bilham and Hough (2023) proposed a “first-cut” elastic deformation model for the 1886 earthquake, a quantitative source model constrained by identified coseismic constraints. A key observation was the measurement of a lateral offset of a railroad line south of Summerville, leading to a model with predominately dextral slip and minor convergence, from which we concluded that active faulting had raised the Penholoway Marine Terrace >6 m since ∼770 ka. P24 questioned these constraints and proposed an alternative rupture model with predominantly reverse slip. This alternative model is neither consistent with coseismic constraints nor with other geophysical data. In a revised model presented here, we recognize that uplift of the Penholoway Terrace is confined to the eastern edge of the terrace, which we conclude results from active folding and tectonic transpression centered on the dextral fault that offset the railroad in 1886.

South Carolina

Hidden system identification: Basin modeling as a tool for examining sedimentary geothermal resource potential

Three-dimensional (3D) geologic and temperature models have been developed for the onshore U.S. Gulf Coast. The results from these models identify areas of moderate- to high-temperature (90°-150°C and >150°C; respectively) geothermal resources at depths <6 km. This modeling study addresses the fundamental challenge of predicting where opportune temperature and lithology coincide. Unlike traditional geothermal systems with surface expressions of hydrothermal circulation (e.g., hot springs, fumaroles, sinter), sedimentary geothermal systems (SGS) are generally hidden. Historically, simplified efforts to predict subsurface temperatures in sedimentary basins have focused on linear temperature extrapolation that does not consider the variable thermal properties of different lithologies or lithologic changes with depth (e.g., compaction, lithification). Therefore, the need to understand basin architecture and predict temperatures in 3D within SGS is paramount to identifying geothermal resources and determining economic feasibility. Basin modeling software has long been used to characterize the subsurface conditions of sedimentary basins, including temperature, in the pursuit of finding hydrocarbons. This tool can also be adapted to evaluate the potential of geothermal resources in a sedimentary basin by predicting the confluence of desirable temperatures and reservoir lithologies. In this work, PetroMod basin modeling software was used to create a regional geologic model of the onshore U.S. Gulf Coast, covering over 500,000 km 2 calibrated to temperature data from wells. Inputs include structural surfaces from commercial databases, lithology information derived from published literature, and corrected bottom-hole temperatures (BHT) from over 6,000 wells. The resulting 3D geologic model can be used to predict temperatures throughout the basin. Maps were exported showing the depth, depositional unit, and reservoir lithology at which temperatures of 90°C and 150°C were reached, revealing over 400,000 km 2 of moderate- to high-temperature resources at depths <6 km. These maps function as a first-order screening tool to identify areas where low-, moderate-, or high-grade resource potential may exist, based on temperature and if optimal reservoir lithologies or depositional units of interest are present. Depending on the success criteria of a project, the same maps can be exported for any isotherm or incorporate other 1407 Gardner and Birdwell subsurface properties. The methodology employed in this work can be applied in any sedimentary basin with available subsurface data. Further calibration incorporating other data, including pressure and porosity, can expand the utility of basin modeling for geothermal evaluations. Basin modeling is a powerful but underutilized tool for identifying prospective geothermal resources in sedimentary basins.

Conference Paper

Streamflow depletion caused by groundwater pumping: Fundamental research priorities for management-relevant science

Reductions in streamflow caused by groundwater pumping, known as “streamflow depletion,” link the hydrologic process of stream-aquifer interactions to human modifications of the water cycle. Isolating the impacts of groundwater pumping on streamflow is challenging because other climate and human activities concurrently impact streamflow, making it difficult to separate individual drivers of hydrologic change. In addition, there can be lags between when pumping occurs and when streamflow is affected. However, accurate quantification of streamflow depletion is critical to integrated groundwater and surface water management decision making. Here, we highlight research priorities to help advance fundamental hydrologic science and better serve the decision-making process. Key priorities include (a) linking streamflow depletion to decision-relevant outcomes such as ecosystem function and water users to align with partner needs; (b) enhancing partner trust and applicability of streamflow depletion methods through benchmarking and coupled model development; and (c) improving links between streamflow depletion quantification and decision-making processes. Catalyzing research efforts around the common goal of enhancing our streamflow depletion decision-support capabilities will require disciplinary advances within the water science community and a commitment to transdisciplinary collaboration with diverse water-connected disciplines, professions, governments, organizations, and communities.

Water Resource Research

Decoding the oxidative digestion mechanism for polystyrene nanoplastic detection in the Great Lakes using a customizable Raman spectral processing algorithm

Despite the concerns surging around nanoplastics (NPs) regarding their prevalence and bioavailability in freshwater systems, robust detection of NPs in complex environmental matrices is hindered by the lack of standardized sample pretreatment and a mechanistic understanding of oxidative digestion. Here, we systematically investigate the interaction between hydrogen peroxide (H 2 O 2 ) and polystyrene (PS) NPs during digestion in deionized (DI) water and four environmental matrices from in and around the Great Lakes Basin. To facilitate high-throughput analysis, we develop Pre_peak, a customizable Raman spectral processing algorithm that achieves >99% accuracy for both NP identification and interference rejection, allowing reliable NP quantification via pixel counting and systematic decoding of the oxidative digestion mechanisms. In DI water, varying H 2 O 2 doses from 0 to 30% has negligible effects on the recovery and Raman signal intensity of PS NPs over 24 hours of digestion. However, morphological changes and aggregation of PS NPs are observed when the H 2 O 2 dose exceeds 20%. Prolonged digestion further leads to progressive NP loss. In natural waters, the optimal dosage and digestion duration depend on matrix characteristics, including dissolved organic matter (DOM) and ion composition. This study provides mechanistic insights into NP–oxidant interactions and underscores the need for matrix-tailored digestion protocols to advance standardized NP detection in freshwater environments.

Great Lakes

South Carolina and Landsat

South Carolina, the eighth State admitted to the union, transcends its size with its deep, rich history; striking beauty; vast natural resources; and extensive cultural diversity. Home to part of the Blue Ridge Mountains of the Central Appalachians, the Upstate is graced with more than 100 waterfalls, while the Lowcountry borders the Atlantic Ocean with 187 miles of coastline and 35 barrier islands. Forests cover two-thirds of the State, and forestry and agriculture together, as agribusiness, make up South Carolina’s leading industry. Two historic crops—cotton and tobacco—still rank in the top 10 commodities, though corn and soybeans now rank higher. Poultry, cattle, peanuts, and flowers also make the list. South Carolina’s population totals more than five million. Other residents include a variety of wildlife, bird, reptile, and fish species, including Ursus americanus (black bears), Alligator mississippiensis (American alligators), and Tursiops truncatus (bottlenose dolphins). More than 100 tree species also reside in South Carolina, which pays homage to one with its “The Palmetto State” nickname. South Carolina’s subtropical climate, long coastline, and lower elevations make it highly susceptible to tornado and hurricane activity and coastal flooding. Projected sea-level rise is a growing concern. A view from space can help monitor and manage natural resources on the land and in rivers, marshes, and the coast. Landsat reveals not just what an area looks like now, but also insights from decades ago.

South Carolina

Groundwater source water assessment area delineation of public supply wells in the Treasure Valley, western Idaho

The Idaho Department of Environmental Quality (IDEQ) is responsible for assessing the source water for public water supply systems including the delineation of source water assessment areas for wells, which are defined as the subsurface areas contributing water to a well during a period of time. Part of the IDEQ assessment plan is to update source water assessments over time. The U.S. Geological Survey (USGS) developed a new groundwater-flow model for part of the western Snake River Plain aquifer in southwestern Idaho. This groundwater- flow model provided a new opportunity for IDEQ to update source water assessment for public water supply wells within the model boundary. The USGS, in cooperation with IDEQ, used the USGS Treasure Valley Groundwater Flow Model along with a MODPATH particle tracking post-processing program to reassess public-water supply source water assessment areas. The USGS created an automated script that requests a well location, depth, and pumpage rate, and then incorporates that information into the Treasure Valley Groundwater Flow Model combined with the MODPATH model to create 3-, 6-, and 10-year time of travel zones that are output to a geographic information system shapefile. The TVSWA_Delineator script provides a fast, transparent tool for IDEQ to reassess or create new public-water supply source water assessment area delineations based on new and updated information and is available as a Python script and a Windows executable with the compiled script and all necessary components. TVSWA_Delineator utilizes a quadtree approach to rediscretize the Treasure Valley Groundwater Flow Model grid around the pumping well location from 1-mile cell lengths telescoped down to 1/16 mile. This rediscretization increases the source water assessment area delineation resolution near the pumping well and minimizes the effect of weak sinks in the MODPATH model. The stress inputs for each month of the final 10 years (2006 to 2015) of the Treasure Valley Groundwater Flow model historical simulation were averaged for the particle tracking analysis. The MODPATH model used backwards tracking of particles released at each stress period to create the source water assessment area delineations. This report documents the creation of the TVSWA_Delineator Python script, including adaptations made to the Treasure Valley Groundwater Flow Model, creation of a companion MODPATH model, and post-processing results to provide source water assessment areas.

Idaho

Cancer risk and estimated lithium exposure in drinking groundwater in the US

Importance Lithium is a naturally occurring element in drinking water and is commonly used as a mood-stabilizing medication. Although clinical studies have reported associations between receiving lithium treatment and reduced cancer risk among patients with bipolar disorder, to our knowledge, the association between environmental lithium exposure and cancer risk has never been studied in the general population. Objectives To evaluate the association between exposure to lithium in drinking groundwater and cancer risk in the general population. Design, Setting, and Participants This cohort study included participants with electronic health record and residential address information but without cancer history at baseline from the All of Us Research Program between May 31, 2017, and June 30, 2022. Participants were followed up until February 15, 2023. Statistical analysis was performed from September 2023 through October 2024. Exposure Lithium concentration in groundwater, based on kriging interpolation of publicly available US Geological Survey data on lithium concentration for 4700 wells across the contiguous US between May 12, 1999, and November 6, 2018. Main Outcome and Measures The main outcome was cancer diagnosis or condition, obtained from electronic health records. Stratified Cox proportional hazards regression models were used to estimate the hazard ratios (HRs) and 95% CIs for risk of cancer overall and individual cancer types for increasing quintiles of the estimated lithium exposure in drinking groundwater, adjusting for socioeconomic, behavioral, and neighborhood-level variables. The analysis was further conducted in the western and eastern halves of the US and restricted to long-term residents living at their current address for at least 3 years. Results A total of 252 178 participants were included (median age, 52 years [IQR, 36-64 years]; 60.1% female). The median follow-up time was 3.6 years (IQR, 3.0-4.3 years), and 7573 incident cancer cases were identified. Higher estimated lithium exposure was consistently associated with reduced cancer risk. Compared with the first (lowest) quintile of lithium exposure, the HR for all cancers was 0.49 (95% CI, 0.31-0.78) for the fourth quintile and 0.29 (95% CI, 0.15-0.55) for the fifth quintile. These associations were found for all cancer types investigated in both females and males, among long-term residents, and in both western and eastern states. For example, for the fifth vs first quintile of lithium exposure for all cancers, the HR was 0.17 (95% CI, 0.07-0.42) in females and 0.13 (95% CI, 0.04-0.38) in males; for long-term residents, the HR was 0.32 (95% CI, 0.15-0.66) in females and 0.24 (95% CI, 0.11-0.52) in males; and the HR was 0.01 (95% CI, 0.00-0.09) in western states and 0.34 (95% CI, 0.21-0.57) in eastern states. Conclusions and Relevance In this cohort study of 252 178 participants, estimated lithium exposure in drinking groundwater was associated with reduced cancer risk. Given the sparse evidence and unknown mechanisms of this association, follow-up investigation is warranted.

contiguous United States

Analysis of factors affecting plume remediation in a sole-source aquifer system, southeastern Nassau County, New York

Several plumes of dissolved, chlorinated solvents, including trichloroethylene, have been identified in a sole-source aquifer near the former Northrop Grumman Bethpage Facility and Naval Weapons Industrial Reserve Plant sites in southeastern Nassau County, New York. Past investigations have documented that the groundwater contamination originated from this industrial area and now extends to the south, in the direction of groundwater flow. The intermixed plumes are commonly referred to as the “Navy Grumman groundwater plume.” Detailed groundwater-flow modeling was needed for the New York State Department of Environmental Conservation (NYSDEC) to evaluate design options necessary for the construction, operation, optimization, maintenance, and monitoring of a groundwater extraction and treatment cleanup plan selected in a December 2019 Amended Record of Decision by the NYSDEC to comprehensively address these plumes. Consequently, the NYSDEC began a cooperative study with the U.S. Geological Survey in 2020 to better understand the local hydrogeologic framework using two independent approaches to characterize aquifer heterogeneity and update an existing regional groundwater-flow model to provide transient boundary conditions for new inset groundwater-flow models of the plume area. We developed these detailed inset models for the two independent aquifer characterizations using history-matching techniques coupled with a novel approach to risk-based management optimization of the remedial design. We also used the updated regional model to assess this optimized groundwater extraction and treatment design for potential saltwater intrusion. The ensembles of parameters resulting from history matching provided a platform with which to evaluate capture by water-supply and remedial wells using particle-tracking techniques. Using the ensemble to select a risk stance, we performed multiobjective optimization to identify various configurations of remedial pumping that are consistent with external constraints and that favor potentially competing objectives. Multiple solutions provide tradeoffs that NYSDEC can consider. In general, pumping redistribution may help to prevent further contamination migration downgradient. These and other study results are intended to support decisions for the remedial design focused on the local area encompassing the full extent of the Navy Grumman groundwater plume.

New York

Detecting earthquakes in noisy real-time GNSS data with deep learning for improved PGD magnitude estimation

To disseminate accurate and useful warnings, earthquake early warning (EEW) systems must quickly determine the size and location of an earthquake to estimate expected shaking. Traditional seismic‐based algorithms tend to underestimate the true magnitudes of large earthquakes, a phenomenon known as magnitude saturation. This limitation motivated the recent inclusion of Global Navigation Satellite Systems (GNSS) data into the U.S. Geological Survey’s ShakeAlert EEW system with the Geodetic First Approximation of Size and Time (GFAST) algorithm because GNSS data do not saturate with large ground motions. However, the noise levels of GNSS data are very high compared with traditional seismic data, which obscures P ‐wave arrivals and can result in less accurate magnitude estimations if displacement amplitudes are low, such as for lower magnitude earthquakes or large source–station distances. In this study, we develop a deep‐learning model that detects earthquakes in GNSS data and use the Ridgecrest, California, earthquake sequence as a case study to demonstrate how the model could act as a filter to reduce the amount of low‐quality data that enters an algorithm like GFAST. To preserve our limited real earthquake data for model inference, we generated a training dataset composed of >700,000 synthetic displacement waveforms. We combined the synthetic waveforms with real‐time GNSS noise to produce realistically noisy training waveforms and then tested our model on additional synthetic data and performed inference using the real data that were held back. We discuss the performance of our trained model on both the unseen synthetic data and real inference data. Our model can be used to selectively filter only high‐quality data where an earthquake signal is observed for input into an algorithm like GFAST (outperforming a simple signal‐to‐noise ratio–based filter) to reduce the error in GFAST’s real‐time earthquake magnitude estimations.

California

Preface to the focus section on intraplate earthquakes

More than a half century after plate tectonics provided an overarching framework to explain earthquakes along active plate boundaries, numerous theories have been proposed to explain where, why, and how often earthquakes occur well away from active plate boundaries, but a paradigm remains elusive. Even the classification of earthquakes away from active plate boundaries as "intraplate" raises issues, with potentially important distinctions between Stable Continental Regions and more actively deforming regions including passive margins and failed rifts. Some of the largest known intraplate earthquakes themselves remain enigmatic, having occurred before the modern instrumental era. Hazard assessments are often data-limited: low fault-slip rates relative to landscape modification rates result in poor discoverability of fault sources, challenging the characterization of source zones and earthquake recurrence; the completeness and homogenization of instrumental earthquake catalogs using uncertain magnitude conversions can lead to uncertainties in earthquake recurrence; and, limited strong-motion observations for large-magnitude events at near-source distances leads to uncertainties in the selection and development of ground-motion models for seismic hazard studies. Data from recent intraplate earthquakes around the world—from the moment magnitude M 7.7 2001 Bhuj, India, earthquake 25 years ago to the 2024 M 4.8 Tewksbury, New Jersey earthquake—have yielded both new insights and new questions. The papers in this special focus discuss many of the long-standing challenges involved with intraplate earthquake investigations and provide a snapshot of the state of the art with current research to advance our understanding.

Seismological Research Letters

Groundwater-storage change in the north Phoenix aquifer, Arizona, 2020–23

The city of Phoenix, Arizona, relies primarily on surface water for municipal water supply. The city also maintains wells to withdraw groundwater, particularly in times of drought and reduced surface-water supply, and to recharge groundwater when excess surface water is available. As of 2023, withdrawals from the aquifer in the northeastern part of the city are a small volume of water, less than 3,000 acre-feet in most years. Each year a similar volume of water is recharged through injection wells. The withdrawal wells are permitted to produce in total more than 20,000 acre-feet per year; increased pumping could lead to future groundwater-storage declines. To better understand groundwater-storage change in the north Phoenix aquifer, a repeat microgravity monitoring network was established in 2020. Measurements of changes in Earth’s gravity provide a direct, non-invasive measurement of subsurface mass change. Groundwater-storage changes were small during the 2020–23 study period, consistent with the relatively small volumes of pumping and recharge. Groundwater levels measured in monitoring wells were stable or increased slightly during this period, although the number of monitoring wells within the area of the gravity monitoring network is sparse. In total, about 15,000 acre-feet of water were pumped and 31,000 acre-feet recharged through injection in the north Phoenix aquifer during the 2020–22 period. Within the monitored area, groundwater storage increased by a small amount, about 1,000 acre-feet, in 2020, and decreased by a larger amount, about 6,000 acre-feet, each year in 2021 and 2022. Storage decreased at 89 of 102 stations from 2020 to 2023. Groundwater-storage decreases greater than the volume of net pumping indicate down-gradient subflow from the aquifer is greater than recharge plus incoming subflow, drying of the unsaturated zone resulting from decreased land-surface recharge, or both. At present (2023), the aquifer appears able to store and supply the relatively small amounts of water needed without excessive drawdown or harmful effects, such as land subsidence and surface inundation. If pumping or recharge increases in the future, the established repeat microgravity network is well suited to capture the spatial extent and magnitude of groundwater-storage changes in the aquifer.

Arizona

Subducting plate structure and megathrust morphology from deep seismic imaging linked to earthquake rupture segmentation at Cascadia

The origin of rupture segmentation along subduction zone megathrusts and linkages to the structural evolution of the subduction zone are poorly understood. Here, regional-scale seismic imaging of the Cascadia margin is used to characterize the megathrust spanning ~900 km from Vancouver Island to the California border, across the seismogenic zone to a few tens of kilometers from the coast. Discrete domains in lower plate geometry and sediment underthrusting are identified, not evident in prior regional plate models, which align with changes in lithology and structure of the upper plate and interpreted paleo-rupture patches. Strike-slip faults in the lower plate associated with oblique subduction mark boundaries between regions of distinct lower plate geometry. Their formation may be linked to changes in upper plate structure across long-lived upper plate faults. The Juan de Fuca plate is fragmenting within the seismogenic zone at Cascadia as the young plate bends beneath the heterogeneous upper plate resulting in structural domains that coincide with paleo-rupture segmentation.

Oregon, Washington

Utilizing downhole datasets for modelling the aeromagnetic signature of the Iron Creek Co-Cu deposit in the Idaho Cobalt Belt

The Idaho Cobalt Belt in east-central Idaho is host to some of the largest domestic Co resources, including the informal Iron Creek deposit. The two main ore zones of this deposit, the Iron Creek and the Ruby, are hosted in greenschist-grade interbedded argillite/siltstone and quartz-rich units of the Mesoproterozoic Apple Creek Formation of Lemhi Group. The primary ore mineral is cobalt-bearing pyrite, which occurs with pyrrhotite, chalcopyrite, and magnetite. This study integrates mineralogical and core-scale geophysical measurements with regional-scale aeromagnetic surveys. The high magnetite content within the Ruby zone produces elevated magnetic susceptibility, but the relatively limited spatial footprint of the ore zone would produce a small-scale anomaly that may be overlooked in regional surveys. The low magnetite content in the Iron Creek zone results in low magnetic susceptibility, creating a relatively low amplitude geophysical response. By characterizing the magnetic properties and mineralogy of these ore zones, this study enhances the interpretation of aeromagnetic data, enabling the identification of small or faint anomalies as potential Co targets. These findings improve can improve exploration strategies, both within the Idaho Cobalt Belt as well as for similar deposit types globally.

Idaho

Forecasting volcanic activity in Germany—A multi-criteria approach

Igneous activity, including shallow intrusions and volcanism, has the potential to disrupt underground critical infrastructure. Notably, future underground infrastructure projects like high-level radioactive waste repositories must be sited in areas of extremely low disruption probability by igneous activity. In Germany, according to the Repository Site Selection Act of 2017 (Standortauswahlgesetz, or StandAG), areas in which Quaternary volcanism is either present or future volcanic activity is expected within the next 1 million years (m.y.) must be excluded from the site selection process. Although the locations of regions with Quaternary volcanism are reasonably well known in Germany, forecasting potential igneous activity at intraplate volcanic fields is challenging, as many processes and their interactions control the spatial distribution of volcanic centers. Here, a semi-quantitative, multi-criteria approach is proposed for a regional evaluation of the relative potential of future igneous activity in Germany. A variety of geoscientific indicators are used, including seismic anomalies in Earth’s mantle, gravity data, tectonic activity, sutures, ground motion, earthquakes, mantle degassing centers, and geochronological data of volcanic rocks. The indicators describe the sequence of processes from potential melt generation in Earth’s mantle, through ascent and accumulation of melt within the lithosphere, to eruption at Earth’s surface. In total, 15 out of 30 proposed geoscientific indicators are selected and quantified using 20 total assigned parameters. Defined threshold values are used to spatially delimit relevant parameter properties to focus on areas with higher potential of future magmatic activity. To consider uncertainties of parameters and their underlying processes, which are usually more spatially extensive below ground, buffer zones are defined in which values of relevance decrease with increasing distance from the initial lateral shape of a parameter. Normalized parameters are combined into an index, whose spatial value distribution is used to differentiate the relative potential of future igneous activity (within the next 1 m.y.). The sensitivity of the results is shown by varying the weighting factors for the relevant parameters in country-wide index maps. Thereby, profiles illustrate the distribution of the resulting index values and respective index fractions of various parameters. Different index maps for the relative potential of future igneous activity are presented and can be used for hazard assessments.

Professional Paper

A partially nonergodic ground-motion model for Fourier amplitude spectra for the San Francisco Bay area, California, USA

We develop a partially nonergodic ground-motion model (GMM) for Fourier amplitude spectra for the San Francisco Bay Area, California, USA, using the Bayless and Abrahamson (2019) GMM as a reference ergodic GMM and developing location-dependent adjustments to the predicted median and variance. We compile regional ground-motion data from moment magnitude (𝑀 w ) >3 earthquakes occurring during 2000–2022 for which magnitude information is available in the U.S. Geological Survey Comprehensive Catalog (Guy et al., 2015). The data set predominantly consists of records from 𝑀 w 3.5–4.5 earthquakes but includes three well-recorded 𝑀 w > 5 events. Ground-motion residuals are evaluated using the time-averaged shear-wave velocity in the top 30 m (𝑉 S30 ) from the California-specific map of Thompson et al. (2018) and basin-depth site parameters from the seismic velocity model of Aagaard and Hirakawa (2021). The 𝑉 S30 dependence and basin-depth scaling of the reference ergodic GMM of Bayless and Abrahamson (2019) are evaluated and modified with the updated data set. We compute maps of site adjustments using a varying-coefficient model that considers the spatial correlation structure and uncertainties at each observation location. The spatial covariance model is developed using ground-motion residuals that are standardized by the uncertainty model, which allows for consideration of the aleatory variability in developing the site adjustments. The covariance model is fit considering the means and standard deviations of the site terms at all locations. The use of partially nonergodic median adjustments results in modified variance components of the within-event variability. Due to the low number of large-magnitude earthquakes that control seismic hazard in the data set, we do not modify between-event variance; however, we present adjustments to site-to-site variability for use in partially nonergodic hazard assessments.

California

RioM-1: A new calcite reference material for U-Pb LA-ICP-MS geochronology

Determining absolute ages of carbonate diagenesis, faulting, fossil formation, speleothem growth, carbonate-hosted hydrocarbon deposits, vein mineralisation and hydrothermal alteration has become increasingly accessible through LA-ICP-MS U-Pb dating of calcite, complementing traditional isotope dilution methods still applicable to certain materials (e.g., speleothems via micro-drilling). However, well-calibrated reference materials for LA-ICP-MS calcite geochronology remain scarce. Here, we characterise the Rio Maior calcite, designated ‘RioM-1’, as a potential reference material for U-Pb dating by LA-ICP-MS. Fragments (0.1 to 1 cm 3 ) from a single scalenohedral crystal were analysed by ID-TIMS (U-Pb), LA-ICP-MS (U-Pb and 87 Sr/ 86 Sr), and SIMS (O isotopes). RioM-1 displays high U mass fraction and low, though variable, proportions of common Pb. Combined ID-TIMS analyses from two independent laboratories yielded a Tera-Wasserburg lower intercept date of 63.93 ± 0.11 Ma (2 s , MSWD = 1.3, n = 16). LA-ICP-MS U-Pb data from three independent laboratories are concordant with the TIMS age, producing a pooled date of 64.10 ± 0.12/1.2 Ma (2 s , MSWD = 7.7, n = 708) and an initial 207 Pb/ 206 Pb ratio of 0.85 ± 0.01. Other calcite reference materials, when normalised to RioM-1, yielded dates within uncertainty of their published values. SIMS measurements returned a mean 18 O/ 16 O of 0.002044450 ± 181 (1 s ) and δ 18 O SMOW of 19.57 ± 0.92‰ (1 s ), while LA-ICP-MS strontium isotope measurement yielded a mean 87 Sr/ 86 Sr of 0.708177 ± 9 (2 s ).

Geostandards and Geoanalytical Research

Indirect mineral import reliance and provenance

Mineral commodity supply chain analyses rely on international trade data reported by individual countries as quantities of a mineral commodity form imported from (or exported to) a partner. However, export quantities frequently exceed a country’s domestic production, or occur when no production data are reported, suggesting that the trade partner is merely an intermediary in a transshipment. These discrepancies can result in misleading conclusions regarding supply chain vulnerabilities and dependencies. We present a two-stage methodology to reconcile gaps between reported material sources and actual producers. First, we construct trade networks for specific mineral forms, treating production as a type of import to distinguish producing nations from entrepôts. By tracing flows through these networks, we attribute a target country’s imports to original producers via both direct (in a single trade link) and indirect (transferring through intermediaries) pathways. Second, these production-attributed flows are incorporated into multi-stage supply chains to determine the upstream provenance of feedstock for domestic refining and processing. This approach provides a more representative picture of trade reliance. For example, while the United States (U.S.) Geological Survey reports no imports of unwrought antimony metal from Russia in 2022 (U.S. Geological Survey (2025). Mineral Commodity Summaries 2025. 10.3133/mcs2025), our analysis reveals that over 16% of U.S. imports can be traced back to Russian mining through intermediate processing in countries such as China, India, and Vietnam. Additionally, our analysis of the aluminum supply chain shows that while the U.S. is reported as 52% net import reliant on aluminum materials in 2022, it is 100% reliant on foreign bauxite, 7% of which arrived indirectly. This unreported reliance, which is predominantly tied to bauxite mined in Brazil (43%) and Jamaica (28%), highlights our methods ability to capture the supply chain’s dependence on foreign feedstock that may be missing in single-stage trade data.

Mineral Economics

Igneous differentiation in arcs

This chapter assesses crystallization-differentiation of convergent-margin magmas both from the standpoints of natural rock suites and from laboratory phase-equilibrium experiments. Crystallization-differentiation of dry subalkaline and alkaline basalts are summarized at the beginning for reference and context. Experiments crystallizing arc basalts through andesites at middle to upper crustal pressures (100–400 MPa), saturated either with H 2 O or mixed H 2 O-CO 2 , produce liquid lines of descent similar to arc igneous suites, with higher f O 2 s giving results closer to calc-alkaline magma series. Early enrichment of melts in SiO 2 with little or no enrichment in FeO* (total Fe as FeO) comes about by the combined effects of H 2 O suppressing crystallization of plagioclase relative to olivine, shifting plagioclase to more calcic – therefore lower SiO 2 – compositions, and suppressing silicate minerals to greater extents than Fe-rich spinel. Also contributing to SiO 2 enrichment is crystallization near the liquidus of higher proportions of olivine relative to calcic clinopyroxene, compared with MORB, but it is unclear if this is brought about by H 2 O or elevated pressure. Exhumed arc terranes, however, generally fail to expose evidence for primitive liquids having reached and differentiated at middle to upper crustal depths, at least in any abundance. Instead, most differentiation in arcs appears to take place in the lower crust or near the crust-mantle transition, and although hydrous experiments at such pressures produce liquids broadly similar to arc suites in their SiO 2 enrichment, the experimental liquids differ in becoming peraluminous at early stages of differentiation while melts have basaltic, basaltic andesitic, or andesitic SiO 2 concentrations. Crystallization of abundant calcic clinopyroxene close to the liquidus causes the high-pressure experimental liquids to become peraluminous with only small increases in SiO 2 concentration. In contrast, natural arc volcanic and plutonic suites become gradually less metaluminous with increasing SiO 2 , crossing to peraluminous at dacitic to rhyolitic SiO 2 concentrations. Hybridism, encompassing magma-mixing, assimilation of old crust, and incorporation of near-solidus melts from only shortly older deep, antecedent arc intrusions may accompany natural crystallization-differentiation, preventing melts from attaining peraluminous compositions at low-SiO 2 concentrations. If so, then nearly all arc suites are to substantial extents composites, rather than preserving simple, progressive liquid lines of descent. Some comments and assessments are also made on the participation of garnet in arc differentiation and on the production of arc batholiths.

Book chapter