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At least 1,333 records · Page 74Linked to original sources

Catalog of earthquake hypocenters at Alaskan volcanoes: January 1 through December 31, 2011

Between January 1 and December 31, 2011, the Alaska Volcano Observatory (AVO) located 4,364 earthquakes, of which 3,651 occurred within 20 kilometers of the 33 volcanoes with seismograph subnetworks. There was no significant seismic activity above background levels in 2011 at these instrumented volcanic centers. This catalog includes locations, magnitudes, and statistics of the earthquakes located in 2011 with the station parameters, velocity models, and other files used to locate these earthquakes.

Alaska↗

Groundwater geochemical and selected volatile organic compound data, Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, June 2011

Previous investigations indicate that concentrations of chlorinated volatile organic compounds are substantial in groundwater beneath the 9-acre former landfill at Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington. Phytoremediation combined with ongoing natural attenuation processes was the preferred remedy selected by the U.S. Navy, as specified in the Record of Decision for the site. The U.S. Navy planted two hybrid poplar plantations on the landfill in spring 1999 to remove and to control the migration of chlorinated volatile organic compounds in shallow groundwater. The U.S. Geological Survey has continued to monitor groundwater geochemistry to ensure that conditions remain favorable for contaminant biodegradation as specified in the Record of Decision. This report presents groundwater geochemical and selected volatile organic compound data collected at Operable Unit 1 by the U.S. Geological Survey during June 20-22, 2011, in support of long-term monitoring for natural attenuation. In 2011, groundwater samples were collected from 13 wells and 9 piezometers. Samples from all wells and piezometers were analyzed for redox sensitive constituents and dissolved gases, and samples from 5 of 13 wells and all piezometers also were analyzed for chlorinated volatile organic compounds. Concentrations of redox sensitive constituents measured in 2011 were consistent with previous years, with dissolved oxygen concentrations all at 0.4 milligram per liter or less; little to no detectable nitrate; abundant dissolved manganese, iron, and methane; and commonly detected sulfide. The reductive declorination byproducts - methane, ethane, and ethene - were either not detected in samples collected from the upgradient wells in the landfill and the upper aquifer beneath the northern phytoremediation plantation or were detected at concentrations less than those measured in 2010. Chlorinated volatile organic compound concentrations in 2011 at most piezometers were similar to or slightly less than chlorinated volatile organic compound concentrations measured in previous years. For the upper aquifer beneath the southern phytoremediation plantation, chlorinated volatile organic compound concentrations in 2011 in groundwater from the piezometers were extremely high and continued to vary considerably over space and between years. At piezometer P1-9, the total chlorinated volatile organic compound concentrations increased from 9,500 micrograms per liter in 2010 to more than 44,000 micrograms per liter in 2011. Total chlorinated volatile organic compound concentrations decreased at piezometers P1-6, P1-7, and P1-10 compared to the concentrations measured in 2010. One or both of the reductive dechlorination byproducts ethane and ethene were detected at all piezometers and three of the four wells in the southern plantation. For the intermediate aquifer, concentrations of redox sensitive constituents and chlorinated volatile organic compounds in 2011 were consistent with concentrations measured in previous years, with the exception of notable decreases in sulfate and chloride concentrations at well MW1-28. Concentrations of the reductive dechlorination byproducts ethane and ethene decreased at wells MW1-25 and MW1-28 compared to previously measured concentrations.

Washington↗

Assessment of groundwater quality data for the Turtle Mountain Indian Reservation, Rolette County, North Dakota

The Turtle Mountain Indian Reservation relies on groundwater supplies to meet the demands of community and economic needs. The U.S. Geological Survey, in cooperation with the Turtle Mountain Band of Chippewa Indians, examined historical groundwater-level and groundwater-quality data for the Fox Hills, Hell Creek, Rolla, and Shell Valley aquifers. The two main sources of water-quality data for groundwater were the U.S. Geological Survey National Water Information System database and the North Dakota State Water Commission database. Data included major ions, trace elements, nutrients, field properties, and physical properties. The Fox Hills and Hell Creek aquifers had few groundwater water-quality data. The lack of data limits any detailed assessments that can be made about these aquifers. Data for the Rolla aquifer exist from 1978 through 1980 only. The concentrations of some water-quality constituents exceeded the U.S. Environmental Protection Agency secondary maximum contaminant levels. No samples were analyzed for pesticides and hydrocarbons. Numerous water-quality samples have been obtained from the Shell Valley aquifer. About one-half of the water samples from the Shell Valley aquifer had concentrations of iron, manganese, sulfate, and dissolved solids that exceeded the U.S. Environmental Protection Agency secondary maximum contaminant levels. Overall, the data did not indicate obvious patterns in concentrations.

North Dakota↗

Seafloor video footage and still-frame grabs from U.S. Geological Survey cruises in Hawaiian nearshore waters

Underwater video footage was collected in nearshore waters (<60-meter depth) off the Hawaiian Islands from 2002 to 2011 as part of the U.S. Geological Survey (USGS) Coastal and Marine Geology Program's Pacific Coral Reef Project, to improve seafloor characterization and for the development and ground-truthing of benthic-habitat maps. This report includes nearly 53 hours of digital underwater video footage collected during four USGS cruises and more than 10,200 still images extracted from the videos, including still frames from every 10 seconds along transect lines, and still frames showing both an overview and a near-bottom view from fixed stations. Environmental Systems Research Institute (ESRI) shapefiles of individual video and still-image locations, and Google Earth kml files with explanatory text and links to the video and still images, are included. This report documents the various camera systems and methods used to collect the videos, and the techniques and software used to convert the analog video tapes into digital data in order to process the images for optimum viewing and to extract the still images, along with a brief summary of each survey cruise.

Hawai'i↗

Land Capability Potential Index (LCPI) and geodatabase for the Lower Missouri River Valley

The Land Capacity Potential Index (LCPI) is a coarse-scale index intended to delineate broad land-capability classes in the Lower Missouri River valley bottom from the Gavins Point Dam near Yankton, South Dakota to the mouth of the Missouri River near St. Louis, Missouri (river miles 811–0). The LCPI provides a systematic index of wetness potential and soil moisture-retention potential of the valley-bottom lands by combining the interactions among water-surface elevations, land-surface elevations, and the inherent moisture-retention capability of soils. A nine-class wetness index was generated by intersecting a digital elevation model for the valley bottom with sloping water-surface elevation planes derived from eight modeled discharges. The flow-recurrence index was then intersected with eight soil-drainage classes assigned to soils units in the digital Soil Survey Geographic (SSURGO) Database (Soil Survey Staff, 2010) to create a 72-class index of potential flow-recurrence and moisture-retention capability of Missouri River valley-bottom lands. The LCPI integrates the fundamental abiotic factors that determine long-term suitability of land for various uses, particularly those relating to vegetative communities and their associated values. Therefore, the LCPI provides a mechanism allowing planners, land managers, landowners, and other stakeholders to assess land-use capability based on the physical properties of the land, in order to guide future land-management decisions. This report documents data compilation for the LCPI in a revised and expanded, 72-class version for the Lower Missouri River valley bottom, and inclusion of additional soil attributes to allow users flexibility in exploring land capabilities.

Iowa, Kansas, Missouri, Nebraska, South Dakota↗

Electron donor concentrations in sediments and sediment properties at the agricultural chemicals team research site near New Providence, Iowa, 2006-07

The concentrations of electron donors in aquifer sediments are important to the understanding of the fate and transport of redox-sensitive constituents in groundwater, such as nitrate. For a study by the U.S. Geological Survey National Water-Quality Assessment Program, 50 sediment samples were collected from below the water table from 11 boreholes at the U.S. Geological Survey Agricultural Chemicals Team research site near New Providence, Iowa, during 2006-07. All samples were analyzed for gravel, sand (coarse, medium, and fine), silt, clay, Munsell soil color, inorganic carbon content, and for the following electron donors: organic carbon, ferrous iron, and inorganic sulfide. A subset of 14 sediment samples also was analyzed for organic sulfur, but all of these samples had concentrations less than the method detection limit; therefore, the presence of this potential electron donor was not considered further. X-ray diffraction analyses provided important semi-quantitative information of well-crystallized dominant minerals within the sediments that might be contributing electron donors.

Iowa↗

Surface-water quality in the upper San Antonio River Basin, Bexar County, Texas, 1992-98

The potential effects of chemicals in rivers and streams on human health or the ecology have long been a source of concern to water managers. Chemicals in rivers may result from natural or anthropogenic sources (such as industrial or residential practices) which are commonly associated with urbanized watersheds. The U.S. Geological Survey, in cooperation with the San Antonio Water System, examined water-quality data collected from periodic and stormflow sampling events at five sites in the upper San Antonio River Basin during 1992&ndash;98. These water-quality data were compared among sites as well as between periodic and stormflow events. The samples were collected from five continuous streamflow-gaging stations in Bexar County, Texas. Samples were analyzed for major ions, nutrients, trace elements, and organic compounds, including selected pesticides. The reported concentrations for the measured constituents varied among sites as well as between periodic and stormflow samples. Patterns for some constituents, such as nutrients, were observed; however, consistent patterns were not always observed for all analytes. For example, median concentrations for filtered ammonia, nitrate plus nitrite, organic nitrogen, and phosphorus generally were greater in periodic samples collected from the Medina and SAR Elmendorf sites as compared to samples collected from the other sites. Median concentrations of trace elements measured in periodic samples were generally less than concentrations measured in stormflow samples. In general, most of the concentrations of analyzed organic compounds were less than the laboratory reporting levels.

Texas↗

Bathymetry and acoustic backscatter data collected in 2010 from Cat Island, Mississippi

Scientists from the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center (SPCMSC), in collaboration with the U.S. Army Corps of Engineers (USACE), conducted geophysical and sedimentological surveys around Cat Island, the westernmost island in the Mississippi-Alabama barrier island chain (fig. 1). The objectives of the study were to understand the geologic evolution of Cat Island relative to other barrier islands in the northern Gulf of Mexico and to identify relationships between the geologic history, present day morphology, and sediment distribution. This report contains data from the bathymetry and side-scan sonar portion of the study collected during two geophysical cruises. Interferometric swath bathymetry and side-scan sonar data were collected aboard the RV G.K. Gilbert September 7-15, 2010. Single-beam bathymetry was collected in shallow water around the island (< 2 meter (m)) from the RV Streeterville from September 28 to October 2, 2010, to cover the data gap between the landward limit of the previous cruise and the shoreline. This report serves as an archive of processed interferometric swath and single-beam bathymetry and side scan sonar data. GIS data products include a 50-m cell size interpolated gridded bathymetry surface, trackline maps, and an acoustic side-scan sonar image. Additional files include error analysis maps, Field Activity Collection System (FACS) logs, and formal Federal Geographic Data Committee (FDGC) metadata.

Alabama;Mississippi↗

Quality of surface-water runoff in selected streams in the San Antonio segment of the Edwards aquifer recharge zone, Bexar County, Texas, 1997-2012

During 1997&ndash;2012, the U.S. Geological Survey, in cooperation with the San Antonio Water System, collected and analyzed water-quality constituents in surface-water runoff from five ephemeral stream sites near San Antonio in northern Bexar County, Texas. The data were collected to assess the quality of surface water that recharges the Edwards aquifer. Samples were collected from four stream basins that had small amounts of developed land at the onset of the study but were predicted to undergo substantial development over a period of several decades. Water-quality samples also were collected from a fifth stream basin located on land protected from development to provide reference data by representing undeveloped land cover. Water-quality data included pH, specific conductance, chemical oxygen demand, dissolved solids (filtered residue on evaporation in milligrams per liter, dried at 180 degrees Celsius), suspended solids, major ions, nutrients, trace metals, and pesticides. Trace metal concentration data were compared to the Texas Commission on Environmental Quality established surface water quality standards for human health protection (water and fish). Among all constituents in all samples for which criteria were available for comparison, only one sample had one constituent which exceeded the surface water criteria on one occasion. A single lead concentration (2.76 micrograms per liter) measured in a filtered water sample exceeded the surface water criteria of 1.15 micrograms per liter. The average number of pesticide detections per sample in stream basins undergoing development ranged from 1.8 to 6.0. In contrast, the average number of pesticide detections per sample in the reference stream basin was 0.6. Among all constituents examined in this study, pesticides, dissolved orthophosphate phosphorus, and dissolved total phosphorus demonstrated the largest differences between the four stream basins undergoing development and the reference stream basin with undeveloped land cover.

Texas↗

USGS Arctic Ocean carbon cruise 2010: field activity H-03-10-AR to collect carbon data in the Arctic Ocean, August - September 2010

Carbon dioxide (CO 2 ) in the atmosphere is absorbed at the surface of the ocean by reacting with seawater to form carbonic acid, a weak, naturally occurring acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution (Sabine and others, 2004). Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Caldeira and Wickett, 2003; Orr and others, 2005; Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO 2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats (Raven and others, 2005; Ruttiman, 2006). The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

Data Series↗

Groundwater-quality data in the Santa Barbara study unit, 2011: Results from the California GAMA Program

Groundwater quality in the 48-square-mile Santa Barbara study unit was investigated by the U.S. Geological Survey (USGS) from January to February 2011, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The Santa Barbara study unit was the thirty-fourth study unit to be sampled as part of the GAMA-PBP. The GAMA Santa Barbara study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system, and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The primary aquifer system is defined as those parts of the aquifers corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the Santa Barbara study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. In the Santa Barbara study unit located in Santa Barbara and Ventura Counties, groundwater samples were collected from 24 wells. Eighteen of the wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and six wells were selected to aid in evaluation of water-quality issues (understanding wells). The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, and pharmaceutical compounds); constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]); naturally occurring inorganic constituents (trace elements, nutrients, major and minor ions, silica, total dissolved solids [TDS], alkalinity, and arsenic, chromium, and iron species); and radioactive constituents (radon-222 and gross alpha and gross beta radioactivity). Naturally occurring isotopes (stable isotopes of hydrogen and oxygen in water, stables isotopes of inorganic carbon and boron dissolved in water, isotope ratios of dissolved strontium, tritium activities, and carbon-14 abundances) and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 281 constituents and water-quality indicators were measured. Three types of quality-control samples (blanks, replicates, and matrix spikes) were collected at up to 12 percent of the wells in the Santa Barbara study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 82 percent of the compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH and to non-regulatory benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All organic constituents and most inorganic constituents that were detected in groundwater samples from the 18 grid wells in the Santa Barbara study unit were detected at concentrations less than drinking-water benchmarks. Of the 220 organic and special-interest constituents sampled for at the 18 grid wells, 13 were detected in groundwater samples; concentrations of all detected constituents were less than regulatory and non-regulatory health-based benchmarks. In total, VOCs were detected in 61 percent of the 18 grid wells sampled, pesticides and pesticide degradates were detected in 11 percent, and perchlorate was detected in 67 percent. Polar pesticides and their degradates, pharmaceutical compounds, and NDMA were not detected in any of the grid wells sampled in the Santa Barbara study unit. Eighteen grid wells were sampled for trace elements, major and minor ions, nutrients, and radioactive constituents; most detected concentrations were less than health-based benchmarks. Exceptions are one detection of boron greater than the CDPH notification level (NL-CA) of 1,000 micrograms per liter (μg/L) and one detection of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter (mg/L). Results for constituents with non-regulatory benchmarks set for aesthetic concerns from the grid wells showed that iron concentrations greater than the CDPH secondary maximum contaminant level (SMCL-CA) of 300 μg/L were detected in three grid wells. Manganese concentrations greater than the SMCL-CA of 50 μg/L were detected in seven grid wells. Chloride was detected at a concentration greater than the SMCL-CA recommended benchmark of 250 mg/L in four grid wells. Sulfate concentrations greater than the SMCL-CA recommended benchmark of 250 mg/L were measured in eight grid wells, and the concentration in one of these wells was also greater than the SMCL-CA upper benchmark of 500 mg/L. TDS concentrations greater than the SMCL-CA recommended benchmark of 500 mg/L were measured in 17 grid wells, and concentrations in six of these wells were also greater than the SMCL-CA upper benchmark of 1,000 mg/L.

California↗

Lead isotope determinations from sulfide mineral occurrences--Russian Far East

The lead isotope database for sulfide deposits and occurrences in the Russian Far East was funded by the Mineral Resources Program, U.S. Geological Survey (USGS) in conjunction with the collaborative studies of mineral resources by the Russian Academy of Sciences and the U. S. Geological Survey (Nokleberg and others, 1996). Comparisons of these data with similar lead isotope data from Alaska published in Church, Delevaux, and others (1987) and Gaccetta and Church (1989) provide a basis for the following three-fold project objectives: 1. To utilize lead isotope signatures, in conjunction with regional mapping, to assess the relative ages and to categorize the types of mineral deposits studied, 2. To relate the lead isotope and trace-element geochemical signatures of specific deposits and occurrences to ore-forming processes, and 3. To use the lead isotope data to correlate lithotectonic terranes within the northern Cordillera (Alaska, Yukon Territories and British Columbia in Canada, and the western Cordillera of the United States). The report by Church, Gray, and others (1987) shows how this fingerprinting methodology can be applied to trace the offset of lithotectonic (or lithostratigraphic as labeled by some authors) terranes.The lead isotope data presented in table 1 represent the work completed on sulfide mineral deposits located in the Russian Far East from 1993 to 1995, when this study was terminated due to lack of funding. The lead isotope data are reported here for use by investigators who may find them of value in mineral exploration. No attempt is made to summarize the voluminous literature on these mineral deposits.

Data Series↗

Summary of suspended-sediment concentration data, San Francisco Bay, California, water year 2009

Suspended-sediment concentration data were collected by the U.S. Geological Survey in San Francisco Bay during water year 2009 (October 1, 2008–September 30, 2009). Optical sensors and water samples were used to monitor suspended-sediment concentration at two sites in Suisun Bay, one site in San Pablo Bay, two sites in Central San Francisco Bay, and one site in South San Francisco Bay. Sensors were positioned at two depths at most sites to help define the vertical variability of suspended sediments. Water samples were collected periodically and analyzed for concentrations of suspended sediment. The results of the analyses were used to calibrate the output of the optical sensors so that a record of suspended-sediment concentrations could be derived. This report presents the data-collection methods used and summarizes, in graphs, the suspended-sediment concentration data collected from October 2008 through September 2009. Calibration curves and plots of the processed data for each sensor also are presented.

California↗

Classifications for Coastal Wetlands Planning, Protection and Restoration Act (CWPPRA) site-specific projects: 2010

The Coastal Wetlands Planning, Protection and Restoration Act (CWPPRA) funds over 100 wetland restoration projects across Louisiana. Integral to the success of CWPPRA is its long-term monitoring program, which enables State and Federal agencies to determine the effectiveness of each restoration effort. One component of this monitoring program is the classification of high-resolution, color-infrared aerial photography at the U.S. Geological Survey’s National Wetlands Research Center in Lafayette, Louisiana. Color-infrared aerial photography (9- by 9-inch) is obtained before project construction and several times after construction. Each frame is scanned on a photogrametric scanner that produces a high-resolution image in Tagged Image File Format (TIFF). By using image-processing software, these TIFF files are then orthorectified and mosaicked to produce a seamless image of a project area and its associated reference area (a control site near the project that has common environmental features, such as marsh type, soil types, and water salinities.) The project and reference areas are then classified according to pixel value into two distinct classes, land and water. After initial land and water ratios have been established by using photography obtained before and after project construction, subsequent comparisons can be made over time to determine land-water change.

Louisiana↗

Historical rock falls in Yosemite National Park, California (1857-2011)

Inventories of rock falls and other types of landslides are valuable tools for improving understanding of these events. For example, detailed information on rock falls is critical for identifying mechanisms that trigger rock falls, for quantifying the susceptibility of different cliffs to rock falls, and for developing magnitude-frequency relations. Further, inventories can assist in quantifying the relative hazard and risk posed by these events over both short and long time scales. This report describes and presents the accompanying rock fall inventory database for Yosemite National Park, California. The inventory database documents 925 events spanning the period 1857–2011. Rock falls, rock slides, and other forms of slope movement represent a serious natural hazard in Yosemite National Park. Rock-fall hazard and risk are particularly relevant in Yosemite Valley, where glacially steepened granitic cliffs approach 1 km in height and where the majority of the approximately 4 million yearly visitors to the park congregate. In addition to damaging roads, trails, and other facilities, rock falls and other slope movement events have killed 15 people and injured at least 85 people in the park since the first documented rock fall in 1857. The accompanying report describes each of the organizational categories in the database, including event location, type of slope movement, date, volume, relative size, probable trigger, impact to humans, narrative description, references, and environmental conditions. The inventory database itself is contained in a Microsoft Excel spreadsheet (Yosemite_rock_fall_database_1857-2011.xlsx). Narrative descriptions of events are contained in the database, but are also provided in a more readable Adobe portable document format (pdf) file (Yosemite_rock_fall_database_narratives_1857-2011.pdf) available for download separate from the database.

California↗

Groundwater-quality data in the Bear Valley and Selected Hard Rock Areas study unit, 2010: Results from the California GAMA Program

Groundwater quality in the 112-square-mile Bear Valley and Selected Hard Rock Areas (BEAR) study unit was investigated by the U.S. Geological Survey (USGS) from April to August 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The BEAR study unit was the thirty-first study unit to be sampled as part of the GAMA-PBP. The GAMA Bear Valley and Selected Hard Rock Areas study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system and to facilitate statistically consistent comparisons of untreated groundwater quality throughout California. The primary aquifer system is defined as the zones corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the BEAR study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallow or deep water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. In the BEAR study unit, groundwater samples were collected from two study areas (Bear Valley and Selected Hard Rock Areas) in San Bernardino County. Of the 38 sampling sites, 27 were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the primary aquifer system in the study unit (grid sites), and the remaining 11 sites were selected to aid in the understanding of the potential groundwater-quality issues associated with septic tank use and with ski areas in the study unit (understanding sites). The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, pharmaceutical compounds, and wastewater indicator compounds [WICs]), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), and inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], alkalinity, and arsenic and iron species), and uranium and other radioactive constituents (radon-222 and activities of tritium and carbon-14). Isotopic tracers (of hydrogen and oxygen in water, of nitrogen and oxygen in dissolved nitrate, of dissolved boron, isotopic ratios of strontium in water, and of carbon in dissolved inorganic carbon) and dissolved noble gases (argon, helium-4, krypton, neon, and xenon) were measured to help identify the sources and ages of sampled groundwater. In total, groundwater samples were analyzed for 289 unique constituents and 8 water-quality indicators in the BEAR study unit. Quality-control samples (blanks, replicate pairs, or matrix spikes) were collected at 13 percent of the sites in the BEAR study unit, and the results for these samples were used to evaluate the quality of the data from the groundwater samples. Blank samples rarely contained detectable concentrations of any constituent, indicating that contamination from sample collection or analysis was not a significant source of bias in the data for the groundwater samples. Replicate pair samples all were within acceptable limits of variability. Matrix-spike sample recoveries were within the acceptable range (70 to 130 percent) for approximately 84 percent of the compounds. This study did not evaluate the quality of water delivered to consumers. After withdrawal, groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-health-based benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All concentrations of organic and special-interest constituents from grid sites sampled in the BEAR study unit were less than health-based benchmarks. In total, VOCs were detected in 17 of the 27 grid sites sampled (approximately 63 percent), pesticides and pesticide degradates were detected in 4 grid sites (approximately 15 percent), and perchlorate was detected in 21 grid sites (approximately 78 percent). Inorganic constituents (trace elements, major and minor ions, nutrients, and uranium and other radioactive constituents) were sampled for at 27 grid sites; most concentrations were less than health-based benchmarks. Exceptions include one detection of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 micrograms per liter (μg/L), three detections of uranium greater than the MCL-US of 30 μg/L, nine detections of radon-222 greater than the proposed MCL-US of 4,000 picocuries per liter (pCi/L), and one detection of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter. Concentrations of inorganic constituents with non-health-based benchmarks (iron, manganese, chloride, and TDS) were less than the CDPH secondary maximum contaminant level (SMCL-CA) in most grid sites. Exceptions include two detections of iron greater than the SMCL-CA of 300 μg/L and one detection of manganese greater than the SMCL-CA of 50 μg/L.

California↗

USGS Arctic Ocean carbon cruise 2011: field activity H-01-11-AR to collect carbon data in the Arctic Ocean, August - September 2011

Carbon dioxide (CO 2 ) in the atmosphere is absorbed at the surface of the ocean by reacting with seawater to form a weak, naturally occurring acid called carbonic acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution (Sabine and others, 2004). Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Caldeira and Wickett, 2003; Orr and others, 2005; Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO 2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats (Raven and others, 2005; Ruttiman, 2006). The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

Data Series↗