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USGS2024

Framework for implementing damping scaling factors in U.S. Geological Survey National Seismic Hazard Models

Traditionally, probabilistic seismic hazard analysis (PSHA) has focused on calculating ground motion hazard curves for elastic, 5%-damped pseudo spectral accelerations, Sa(T,5%), which are used as the basis for engineering design parameters and targets for ground motion selection and modification. However, structures and geotechnical systems can exhibit a wide range of damping ratios both above and below the 5% level, depending on the construction material, structural system, nonstructural elements, or subsurface soil properties. When spectral parameters at such damping levels are required for certain applications, 5%-damped accelerations have traditionally been extracted from PSHA-based hazard curves and adjusted outside of the hazard integral using damping scaling factors (DSF) such as those from Newmark & Hall (1982). Recent advances in the development of more rigorous and comprehensive damping scaling models (e.g., Rezaeian et al., 2014; Rezaeian et al., 2021) have allowed for the modeling of means and standard deviations of DSFs as functions of earthquake source and path properties for crustal, intraslab, and subduction interface tectonic environments. These DSF models can be applied to ground motion model (GMM) estimates of Sa(T,5%) for a given earthquake rupture scenario to produce a corresponding mean and standard deviation Sa at a specified damping ratio β, Sa(T,β). In this study, the DSF models of Rezaeian et al. (2014) and Rezaeian et al. (2021) are implemented within the U.S. Geological Survey National Seismic Hazard Model (NSHM) PSHA framework to calculate probabilistic hazard curves for spectral accelerations at damping ratios from 0.5% to 30%. The DSF models are applied directly to the mean and standard deviation of Sa(T,5%) predictions from each GMM in the NSHM logic tree. Resulting hazard curves and uniform hazard and risk spectra for Sa(T,β) are presented for several geographic locations and compared with corresponding spectra estimated using current design practices by applying the same DSFs outside of the PSHA calculation. Key differences between the two methods for estimating Sa(T,β) are discussed, and potential strategies are presented for the implementation and usage of the hazard-consistent Sa(T,β) in building codes. Comparing the results to those from DSFs used in current design practices that are mainly based on Newmark & Hall (1982) is not explored in this study.

Conference Paper↗
USGS2025

Earthquake recurrence estimates for northern Caribbean faults from combinatorial optimization

We use combinatorial optimization to find the optimal spatial distribution of random samples of earthquakes (≥6.5) that minimize the misfit in target slip rates for all faults in the northeast Caribbean, and we derive magnitude-frequency relationships with uncertainties for these faults. Slip rates for many faults are derived from GPS block models, not direct measurements, because of their underwater locations. Predicted recurrence rates for eastern Hispaniola and Puerto Rico Trench faults are 220-450 yr for M7 and 3-5 kyr for M8, with maximum feasible magnitude of M8.2. The most frequent earthquakes with magnitudes ≥7.0 are predicted on the large upper plate strike-slip faults, Enriquillo (EF) and Septentrional Fault, commensurate with the historical record. Calais et al. (2023) suggested that shortening in western Hispaniola is accommodated on the offshore Jérémie and onshore Malpasse faults north and south of EF, instead of on terrestrial faults in western Hispaniola and EF. Because of our system-modeling approach, such a configuration predicts less frequent earthquakes on EF and on western Hispaniola and Muertos convergent zones. Recurrence times of a few 100s yr for M6.7 earthquakes is predicted on the submerged faults in Mona Passage, and infrequent M>7 earthquakes are predicted on the Virgin Islands faults.

Lesser Antilles↗
USGS2025

Enhancing mineral systems exploration through geochronology, thermochronology, and isotope analysis: USGS Geochron and USGS Isotope databases

A mineral systems approach to mineral exploration provides a comprehensive framework for understanding ore deposit formation by examining the geodynamic, magmatic, hydrothermal, and sedimentary processes responsible for mineralization, alteration, and remobilization of economic mineral deposits. Temporal and thermal constraints on ore genesis are crucial for refining mineral system models and guiding predictive exploration strategies. Geochronology and thermochronology offer invaluable insights into the timing and thermal evolution of ore-forming processes, whereas isotopic analyses provide critical information on the source and geochemical history of ore-forming fluids. Combining these methodologies have proven highly effective for mineral exploration in regions like Australia, however, their combined application has been limited in the United States. To apply these tools to mineral systems-based exploration, the U.S. Geological Survey (USGS) has developed two products: (1) The USGS Geochron Database, and (2) the USGS Isotope Database. These databases provide centralized repositories of geo/thermochronological dates and data (Geochron Database) and both radiogenic and stable isotope data (Isotope Database) generated by the USGS and partners over the past decades. Integrating these datasets together and with traditional exploration approaches provides the mineral exploration community with powerful tools for determining the temporal and thermal histories of ore systems and identifying metallogenic source provinces.

Continental United States↗
USGS1995

The distribution of bromide in water in the Floridan aquifer system, Duval County, northeastern Florida

Although Duval County, Florida, has ample ground-water resources for public supply, the potential exists for a problem with excessive disinfectant by-products. These disinfectant by-products result from the treatment of raw water containing low concentrations of bromide and naturally occurring organic compounds. Because of this potential problem, the relation of bromide concentrations to aquifer tapped, well location and depth, and chemical characteristics of water in the Floridan aquifer system underlying Duval County were studied to determine if these relations could be applied to delineate water with low-bromide concentrations for future supplies. In 1992, water samples from 106 wells that tap the Floridan aquifer system were analyzed for bromide and major dissolved constituents. A comparison of bromide concentrations from the 1992 sampling with data from earlier studies (1979-80) indicates that higher bromide concentrations were detected during the earlier studies. The difference between the old and new data is probably because of a change in analytical methodology in the analysis of samples. Bromide concentrations exceeded the detection limit (0.10 milligrams per liter) in water from 28 of the 106 wells (26 percent) sampled in 1992. The maximum concentration was 0.56 milligrams per liter. There were no relations between bromide and major dissolved constituents, well depth, or aquifer tapped that would be useful for determining bromide concentrations. Areal patterns of bromide occurrence are not clearly defined, but areas with relatively high bromide concentrations tend to be located in a triangular area near the community of Sunbeam, Florida, and along the St. Johns River throughout Duval County.

Florida↗
USGS2025

Fault displacement model for surface principal rupture of strike-slip faults

The probability distribution model for principal displacement accommodated on the surface main trace is a critical input to the fault displacement hazard analysis. This article presents a new model for strike-slip ruptures in the moment magnitude ( M ) range of 6 to 8.3. The new model is the outcome of a multi-year research effort to update the widely used model developed by Petersen and others in 2011. Updates include the adoption of the Fault Displacement Hazard Initiative database and enhancements to rupture and displacement data preparation. Statistical formulation and estimation have also been updated substantially. A three-parameter modified normal distribution that we refer to as the negative Exponentially Modified Gaussian distribution is adopted to model the probability distribution of the natural logarithm of principal displacement. Formulation for the mean parameter of the modified normal includes a random earthquake term, a nonlinear scaling relation with M , and an ellipse function for along-main-trace variation. The aleatory variability of the updated model now depends on M as well as site’s along-main-trace position. These updates not only significantly improve the fit to the distribution of the observed displacements but also yield reasonable 95th percentile predictions for M > 7.5 events. Alternative models representing the estimation uncertainty of the M -scaling relation are also developed. These new models are compared to the previous model in terms of percentile predictions and the calculated hazard curves. The steeper hazard curves from the new models yield a lower exceedance rate than the normal-distribution based model developed previously by Petersen and others.

Earthquake Spectra↗
USGS2026

Integrating detrital magnetite geochemistry and (U-Th)/He chronometry as a sediment provenance tool in geologic and metallogenic terranes

Magnetite is ubiquitous in porphyry Cu systems and in sediment sourcing both barren and mineralized regions, with potential as an indicator mineral in concealed and coarsely-mapped terranes. We develop and test a workflow for integrated geochemistry and (U–Th)/He (He) dating for inferring detrital magnetite (DMt) provenance in these settings. The ca. 70 Ma Taurus porphyry Cu–Mo(–Au) district in eastern interior Alaska serves as a test case. DMt from streams draining porphyry-related mineralization was characterized by geochemistry and mineral inclusion and microstructure observations, complemented by similar data for potential porphyry and host rock sources. Principal component analysis and clustering of DMt geochemical data resolve multiple populations in our samples geochemically and texturally compatible with derivation from metamorphic, porphyry-related hydrothermal, and igneous sources. Hydrothermal magnetite comprises ∼16–50% of DMt nearest porphyry mineralization but diminishes to ∼4% ∼15 km downstream. Subsampled grains within populations yield ∼160–110 Ma, ∼70 Ma, ∼55 Ma, and ∼20 Ma magnetite He date modes. Combined with provenance, He dates capture Early Cretaceous regional exhumation of metamorphic host rock and Late Cretaceous porphyry Cu mineralization. DMt grains showing partial hematite replacement yield ca. 55–20 Ma dates regardless of source, overlapping regional warm/wet climatic intervals. We interpret Cenozoic dates to reflect exhumation to near-surface oxidizing conditions and(or) supergene weathering. Magnetite is thus a promising target phase for (1) tracking the spatiotemporal distribution of porphyry systems, and (2) linking the formation and exhumation of these systems to a regional geologic history, both in Alaska and globally.

Alaska, Yukon↗
USGS2024

Turbidite correlation for paleoseismology

Marine turbidite paleoseismology relies on the assumption of synchronous triggering of turbidity currents by earthquake shaking to infer rupture extent and recurrence. Such inference commonly depends on age dating and correlation of the physical stratigraphy of deposits carried by turbidity currents (i.e., turbidites) across great distances. Along the Cascadia subduction zone, which lies offshore the Pacific Northwest, USA, turbidite facies in core photographs, X-ray computed tomography images, and magnetic susceptibility (MS) data exhibit differences in character over relatively short distances, which implies that not all deposits can be correlated with confidence. Thus, subjective correlation based on expected similarity over great distances and weak age constraints does not independently support paleoseismic models. We present a new method for correlating turbidites along the Cascadia margin that can yield a more objective and repeatable stratigraphic framework to underpin earthquake recurrence. We use dynamic time warping to correlate MS logs and measure correlation coefficients of core pairs to evaluate correlation strength. We then compare these measures to a distribution of correlation coefficients of randomly generated turbidite sequences and find that only a small number of core pairs can be correlated more confidently than randomly stacked turbidites. This methodology promises a more robust correlation strategy for future stratigraphic studies.

Oregon, Washington↗
USGS2023

Evaluation of models for estimating hydraulic conductivity in glacial aquifers from NMR logging

Nuclear magnetic resonance (NMR) logging is a promising method for estimating hydraulic conductivity ( K ). During the past ∼60 years, NMR logging has been used for petroleum applications, and different models have been developed for deriving estimates of permeability. These models involve calibration parameters whose values were determined through decades of research on sandstones and carbonates. We assessed the use of five models to derive estimates of K in glacial aquifers from NMR logging data acquired in two wells at each of two field sites in central Wisconsin, USA. Measurements of K , obtained with a direct push permeameter (DPP), K DPP , were used to obtain the calibration parameters in the Schlumberger-Doll Research, Seevers, Timur-Coates, Kozeny-Godefroy, and sum-of-echoes (SOE) models so as to predict K from the NMR data; and were also used to assess the ability of the models to predict K DPP . We obtained four well-scale calibration parameter values for each model using the NMR and DPP measurements in each well; and one study-scale parameter value for each model by using all data. The SOE model achieved an agreement with K DPP that matched or exceeded that of the other models. The Timur-Coates estimates of K were found to be substantially different from K DPP . Although the well-scale parameter values for the Schlumberger-Doll, Seevers, and SOE models were found to vary by less than a factor of 2, more research is needed to confirm their general applicability so that site-specific calibration is not required to obtain accurate estimates of K from NMR logging data.

Wisconsin↗
USGS2024

Relatively stable pressure effects and time-increasing thermal contraction control Heber geothermal field deformation

Due to geological complexities and observational gaps, it is challenging to identify the governing physical processes of geothermal field deformation including ground subsidence and earthquakes. In the west and east regions of the Heber Geothermal Field (HGF), decade-long subsidence was occurring despite injection of heat-depleted brines, along with transient reversals between uplift and subsidence. These observed phenomena contradict current knowledge that injection leads to surface uplift. Here we show that high-yield production wells at the HGF center siphon fluid from surrounding regions, which can cause subsidence at low-rate injection locations. Moreover, the thermal contraction effect by cooling increases with time and eventually overwhelms the pressure effects of pressure fluctuation and poroelastic responses, which keep relatively stable during geothermal operations. The observed subsidence anomalies result from the siphoning effect and thermal contraction. We further demonstrate that thermal contraction dominates long-term trends of surface displacement and seismicity growth, while pressure effects drive near-instantaneous changes.

California↗
USGS2026

Site response models based on geometric parameters for southern California sedimentary basins

Site response in sedimentary basins is influenced by complex three-dimensional (3D) features, including trapping of seismic waves, focusing of seismic energy and basin resonance. Current ground motion models (GMMs) incorporate basin effects using one-dimensional parameters like V S30 and shear wave velocity isosurface depths, which are limited in capturing lateral and 3D effects. To address these limitations, we develop seismic site response models based on novel parameters that represent multi-dimensional properties of the Los Angeles Basin (LAB) geometry and shear wave velocity. We define a basin shape for the LAB using depth to subsurface geologic interfaces associated with the oldest sedimentary deposits (depth to a particular shear wave velocity horizon, i.e., 1.5 km/s - z 1.5 ) and the depth to the crystalline basement ( z cb ) which are determined using geologic cross sections and community seismic velocity model profiles. We explore a suite of geometric descriptors computed for the LAB and southern California, from which three parameters with the greatest predictive potential are selected and evaluated using empirical ground motion residual analyses in combination with the Boore et al. GMM. The results demonstrate that the zonal heterogeneity index ( ), standard deviation of the absolute difference between z 1.5 and z cb ( ) and standard deviation of z cb ( ) each provide a reduction in site-to-site variability ( ϕ S2S ) of empirical GMMs. The reduction in ϕ S2S is period-dependent, with average decreases of 3%, 26% and 6% for , , and , respectively. Although these reductions are modest from an engineering application perspective, they are statistically significant, underscoring the inherent difficulty in fully characterising complex basin effects. Collectively, these findings indicate that the inclusion of basin-specific geometric parameters yields measurable, albeit incremental, improvements in site response prediction and establishes a framework for the progressive refinement of seismic hazard characterisation within sedimentary basins.

California↗
USGS2026

Miocene evolution of the Humboldt Current

Diatom records from the East Pisco Basin (EPB) of southern Peru and offshore Ocean Drilling Program (ODP) Hole 682 A reveal stepwise increases in the primary productivity of the Humboldt Current during the middle and late Miocene. Although diatoms are present back through the late middle Eocene, successively enhanced diatom production occurs during the Miocene in four steps. The first step between 14.2 and 13.8 Ma marks the onset of diatom deposition in the Pisco-0 sequence. A second step at ∼12.9 Ma coincides with a major drop in global sea level during which diatom deposition ceased in the EPB but continued in ODP 682 A as well as in Chile, Ecuador, and Colombia. Beginning at 10.4 to 10.0 Ma, a major increase in diatom sedimentation rates in both the EPB and in ODP 682 A signals an abrupt intensification of the Humboldt Current productivity, which may be related to the closure of the Central American Seaway to deeper water circulation. A fourth step coincides with the transgressive deposition of the diatom-rich Pisco-2 sequence at 8.4 Ma and is enhanced by the onset of the global Late Miocene Biogenic Bloom (8.0–4.5 Ma). Between 7 and 6 Ma, common subtropical diatoms in ODP 682 A contrast with high diatom deposition rates in the EPB, suggesting variable El Niño-La Niña conditions. During this time, fossil vegetation evidence from southern Peru supports the presence of seasonal periods of enhanced rainfall typical of El Niño conditions. The Miocene trend of increasing sea mammal diversity in the EPB parallels these steps, further supporting stepwise enhancement of primary productivity in the Humboldt Current during the Miocene.

Humboldt Current↗
USGS2026

PFAS remediation in a bioelectrochemical system inoculated with the west branch consortium (WBC-2)

Groundwater contamination by per - and polyfluoroalkyl substances (PFAS) poses a persistent environmental and public health concern. This study evaluates a two-chambered bioelectrochemical system (BES) inoculated with the West Branch Consortium (WBC-2) for PFAS remediation. Under an applied cathodic potential of −450 mV (versus Ag/AgCl), the BES with active WBC-2 achieved >99.0% perfluorooctanesulfonic acid (PFOS) removal within 21 days in deionized water with culture medium and > 98.9% removal of PFOS, perfluorooctanoic acid (PFOA), perfluorohexanoic acid (PFHxA), and perfluorohexanesulfonic acid (PFHxS) in contaminated groundwater after 102 days. Intermediate formation (e.g., PFOA, 6:2 fluorotelomer sulfonate (6:2 FTS), perfluoropropionic acid (PFPrA), perfluorobutanoic acid (PFBA)) and background-corrected fluoride release were consistent with PFOS transformation under anaerobic reducing conditions potentially involving defluorination. Following repeated PFOS spikes (100 μg/L on Days 0, 50, and 399), PFOA, PFPrA, and PFBA accumulated over 664 days. Despite being the dominant accumulated compound, PFOA accounted for <1.8% of the total spiked PFOS mass. Minimal PFOS transformation occurred in controls without active WBC-2, highlighting the importance of microbial metabolism. Biofilm analysis revealed dense colonization of rod-shaped bacteria on carbon fiber brushes. Enrichment of Bacillus , Agrobacterium , and other low-abundance taxa suggests selective adaptation to BES and PFAS conditions. These findings highlight BES driven by electrochemically stimulated microbial activity as a promising strategy for PFAS remediation.

Journal of Water Process Engineering↗
USGS2024

The 3D National Topography Model Call for Action—Part 1. The 3D Hydrography Program

The U.S. Geological Survey is initiating the 3D Hydrography Program (3DHP), the first systematic remapping of the Nation’s surface waters since the original 1:24,000-scale topographic mapping program was active from 1947 to 1992. Building on decades of experience maintaining the National Hydrography Dataset (NHD), the Watershed Boundary Dataset (WBD), and the NHDPlus High Resolution (NHDPlus HR), the 3DHP will completely refresh the Nation’s hydrography data and improve discovery and sharing of water-related data. The design of the 3DHP is based on the results of a study that estimated that the fully implemented program would have the potential to provide more than $1 billion in benefits to Federal, State, Tribal, Territorial, and local governments and to private and nonprofit organizations every year, in addition to myriad societal benefits. The 3DHP would directly support better decision making regarding water resources by providing more accurate, complete, and integrated information than is currently available. The 3DHP datasets will include a three-dimensional (3D) hydrography network generated from and integrated with elevation data from the 3D Elevation Program (3DEP) to better represent stream gradients and channel conditions, along with waterbodies, hydrologic units, hydrologically enhanced elevation and other surfaces, and more consistent and accurate attributes. The 3DHP datasets will inherit key attributes of the NHD, WBD, and NHDPlus HR, and they also will include new attributes and links to other data such as the U.S. Fish and Wildlife Service National Wetlands Inventory, groundwater data, and engineered hydrologic systems such as stormwater networks. The 3DHP will be designed to provide a set of open and interoperable web-based tools, maps, and data catalogs, creating a robust system for users to reference their information about water; the system elements are collectively referred to as the “infostructure.” The 3DHP and the infostructure can provide a foundational geospatial underpinning for the Internet of Water, a community-based effort to modernize tools and technologies to share water data. As proposed, the 3DHP would begin providing products and services to the public in 2024.

Circular↗
USGS2024

Deep-ocean macrofaunal assemblages on ferromanganese and phosphorite-rich substrates in the Southern California Borderland

Mineral-rich hardgrounds, such as ferromanganese (FeMn) crusts and phosphorites, occur on seamounts and continental margins, gaining attention for their resource potential due to their enrichment in valuable metals in some regions. This study focuses on the Southern California Borderland (SCB), an area characterized by uneven and heterogeneous topography featuring FeMn crusts, phosphorites, basalt, and sedimentary rocks that occur at varying depths and are exposed to a range of oxygen concentrations. Due to its heterogeneity, this region serves as an optimal setting for investigating the relationship between mineral-rich hardgrounds and benthic fauna. This study characterizes the density, diversity, and community composition of macrofauna (>300 μm) on hardgrounds as a function of substrate type and environment (depth and oxygen ranges). Rocks and their macrofauna were sampled quantitatively using remotely operated vehicles (ROVs) during expeditions in 2020 and 2021 at depths above, within, and below the oxygen minimum zone (OMZ). A total of 3,555 macrofauna individuals were counted and 416 different morphospecies (excluding encrusting bryozoans and hydrozoans) were identified from 82 rocks at depths between 231 and 2,688 m. Average density for SCB macrofauna was 11.08 ± 0.87 ind. 200 cm −2 and mean Shannon-Wiener diversity per rock (H′ [loge] ) was 2.22 ± 0.07. A relationship was found between substrate type and macrofaunal communities. Phosphorite rocks had the highest H′ of the four substrates compared on a per-rock basis. However, when samples were pooled by substrate, FeMn crusts had the highest H′ and rarefaction diversity. Of all the environmental variables examined, water depth explained the largest variance in macrofaunal community composition. Macrofaunal density and diversity values were similar at sites within and outside the OMZ. This study is the first to analyze the macrofaunal communities of mineral-rich hardgrounds in the SCB, which support deep-ocean biodiversity by acting as specialized substrates for macrofaunal communities. Understanding the intricate relationships between macrofaunal assemblages and mineral-rich substrates may inform effects from environmental disruptions associated with deep-seabed mining or climate change. The findings contribute baseline information useful for effective conservation and management of the SCB and will support scientists in monitoring changes in these communities due to environmental disturbance or human impact in the future.

California↗
USGS2026

Aspergillosis (Avian) case definition for wildlife

Diagnostic laboratories receive carcasses and samples for diagnostic evaluation and pathogen/toxin detection. Case definitions bring clarity and consistency to the evaluation process. Their use within and between organizations allows more uniform reporting of diseases and etiologic agents. The intent of a case definition is to provide scientifically based criteria for determining: (a) if an individual carcass has a specific disease and degree of confidence in that diagnosis and (b) if there is evidence of a pathogen or toxin in a carcass or sample (for example, swab, tissue sample, skin scraping, blood/serum sample, environmental sample, or other). This case definition is specific to aspergillosis and applies to all avian species.

Techniques and Methods↗
USGS2026

Cruise summary—Samoa Basin abyssal mapping—Box coring leg, Pago Pago, Territory of American Samoa to Pago Pago, American Samoa, April 11– May 1, 2026

Expedition Summary U.S. Geological Survey scientists led a box coring effort to the Samoa Basin to characterize minerals and the surrounding abyssal sediments and fauna. Thirty-eight box cores were deployed between April 13, 2026, and April 28, 2026. Thirty-six box cores recovered sufficient material to determine nodule density, and 35 recovered sufficient material for subcores to be collected. The purpose of this Data Report is to provide a summary of samples collected, initial results that were obtained shipboard, and briefly mention planned future analyses from this expedition.

Data Report↗
USGS1995

Effects of waste-disposal practices on ground-water quality at five poultry (broiler) farms in north-central Florida, 1992-93

Waste-disposal areas such as chicken-house floors, litter stockpiles, fields that receive applications of litter, and dead-chicken pits are potential sources of nitrates and other chemical constituents in downward-percolating recharge water. Broiler- farms in north-central Florida are concentrated in a region where the Upper Floridan aquifer is unconfined and susceptible to contamination. Eighteen monitoring wells installed at five sites were sampled quarterly from March 1992 through January 1993. Increases in median concentrations of constituents relative to an upgradient well were used to determine the source of the nitrate at two sites. At these sites, increases in the median concentrations of nitrate as nitrogen in ground water in the vicinity of waste-disposal areas at these sites were: 5.4 mg/L for one chicken house; 9.0 mg/L for a second chicken house; 2.0 mg/L for a fallow field that received an application of litter; and, 2.0 mg/L for a dead-chicken pit. At the three remaining sites where the direction of local ground-water flow could not be ascertained, the sources of concentrations of nitrate and other constituents could not be determined. However, median nitrate concentrations in the vicinity of waste-disposal areas at these sites were: 45.5 mg/L for a set of two chicken houses; 3.0 mg/L for a stockpile area; and 2.1 mg/L for a hayfield that received an application of litter. The nitrate concentration in ground water in the vicinity of a field that had previously received heavy applications of litter increased from 3.0 mg/L to 105 mg/L approximately 4 months after receiving an application of commercial fertilizer. Increases in concentrations of organic nitrogen in ground water in the vicinity of waste-disposal areas may be related to the decomposition of litter and subsequent movement with downward percolating recharge water.

Florida↗
USGS2026

Evidence for organic and igneous carbon sources in the Mesoproterozoic Adirondack Highlands graphite district, New York

This study examined the origin of graphite mineralization in the Mesoproterozoic Adirondack Highlands. Flake graphite was mined from the historic mining district around Ticonderoga, New York, USA, from the 1850s to the 1920s. Most of the production and reserves from the district are disseminated graphite from feldspathic quartz schists (e.g., Dixon-American Graphite Co. mine, Faxon property, Flake Graphite Company). Protolith sediments of the schists were deposited in the Trans-Adirondack backarc basin at ca. 1.25 Ga and were metamorphosed to high grade at 1.18–1.15 Ga during the accretionary Shawinigan orogeny and at 1.09–1.02 Ga during the Ottawan phase of the Grenvillian orogeny. Major elements and carbon isotopes of graphite from schists (δ 13 C = −28.1‰ to −5.4‰ relative to Vienna Peedee belemnite) are consistent with derivation from organic carbon in protolith sandstones that devolatilized during metamorphism. Some small mines and prospects in the district mined graphitic calcite marbles and clinopyroxene ± scapolite skarns associated with a pegmatite suite dated by U-Pb in zircon to 1.04–1.01 Ga (e.g., Lead Hill and Crown Point deposits), and rare graphite veins are observed at several deposits. Hydrothermal flake graphite from pegmatites, skarns, and veins are distinct from graphite in schist-hosted deposits and have δ 13 C values that cluster around −7‰ to −5‰, consistent with deposition from igneous CO 2 . Covariation of carbon and oxygen stable isotopes and U-Pb zircon geochronology are not compatible with precipitation from fluids derived from country rock metapelites or marbles. Some graphite districts elsewhere show compelling evidence for remobilization and redeposition of sedimentary-derived carbon as hydrothermal graphite, sometimes as thick veins producing world-class, high-grade deposits. In the Adirondacks, there is evidence for two generations of graphite mineralization with distinct carbon sources: syngenetic graphite with an organic origin in Shawinigan quartz schists and epigenetic graphite with an igneous origin in Ottawan skarns and pegmatites.

New York↗