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The Hardscrabble Creek complex: A newly discovered, mostly buried, Mesoproterozoic mafic-ultramafic pluton in the Wet Mountains, Colorado, USA

The origin of prolific ca. 1.4 Ga ferroan magmatism between the southwestern USA and eastern Canada is enigmatic and has been explained by various models, including extensional, mantle plume, and convergent plate-margin models. Rare mafic plutons are associated with the ferroan plutons, which may help constrain their mantle source and tectonic setting. In the southwestern USA, only two such mafic plutons are known to exist. We present the first evidence for a third, mostly buried, potentially layered, mafic-ultramafic Mesoproterozoic pluton, informally referred to as the Hardscrabble Creek complex, in the central Wet Mountains of Colorado, USA. Recent geophysical data show an elliptical magnetic and gravity high spatially coincident with local gabbroic outcrops. New field and petrographic analyses of these exposed rocks reveal that they consist of ultramafic to mafic cumulates, including orthopyroxenite, olivine norite, norite, and anorthosite. High-precision U-Pb dating of zircon from orthopyroxenite and norite yield weighted mean 206 Pb/ 238 U dates of 1352.36 ± 1.60 Ma and 1352.37 ± 1.71 Ma, respectively. These dates indicate that the complex formed over a narrow timeframe, after the adjacent 1362 ± 7 Ma ferroan San Isabel Granite, and during the waning stages of the regional ca. 1.4 Ga ferroan magmatism. Whole-rock geochemistry and Nd-Sr-Pb isotope compositions of samples from the Hardscrabble Creek complex are similar to those of the San Isabel Granite, suggesting that they were derived from the same or a similar mantle source. The mineral chemistry of the samples is comparable to Proterozoic massif-type anorthosites and related mafic intrusions, indicating that the Hardscrabble Creek complex and San Isabel Granite together represent a rare anorthosite-mangerite-charnockite-granite (AMCG) suite in the southwestern USA. The Hardscrabble Creek complex is unique because it formed ~80 m.y. after the other few mafic plutons in the southwestern USA, and it contains an ultramafic section that is absent from these plutons and rare to the AMCG suite in general. A combination of arc-like whole-rock geochemistry, chondrite uniform reservoir-like Nd-Sr-Pb isotopes, and ocean island basalt (OIB)-like zircon trace element chemistry suggests that the complex was derived from a partial melt of OIB-like mantle and interacted with metasomatically enriched lithospheric mantle. The enriched lithospheric mantle signature, combined with the long ~160 m.y. duration of magmatism in the region, is consistent with a period of protracted convergent tectonism.

Colorado

Constraining the earthquake recording threshold of intraslab earthquakes with turbidites in southcentral Alaska’s lakes and fjords

Strong ground motion from intraslab earthquakes, which do not produce primary paleoseismic evidence, may initiate gravity-driven turbidity flows in subaqueous basins. The resulting deposits (turbidites) can provide a paleoseismic proxy if the conditions that initiate these flows are known. To better constrain the initiating conditions, we use two recent intraslab earthquakes in southcentral Alaska, the M w 7.1 30 November 2018 Anchorage earthquake and the M w 7.1 24 January 2016 Iniskin earthquake, as calibration events. Through a multilake investigation, we document the occurrence, or the absence, of earthquake-generated turbidity flows from these two events. Both earthquakes are recorded by centimeter-scale turbidites that can be differentiated from climatically generated deposits, as well as other seismic sources based on deposit thickness, sedimentological properties, and deposit age. We show that a Modified Mercalli Intensity (MMI) of ∼V–V1/2 is the minimum shaking intensity required to generate localized sediment remobilization from deltaic slopes, and an MMI of ∼V1/2 is required to produce a deposit of sufficient thickness that a seismic origin can be confidently assigned. The documentation of seismically generated deposits in quick succession (∼2 years) with diagnostic features highlights the utility of using recent earthquakes as calibration events to investigate the subaqueous response to strong ground motion.

Alaska

Oligocene–Miocene northward growth of the Tibetan Plateau: Insights from intermontane basins in the West Qinling Belt, NW China

Growth of the Tibetan Plateau, Earth’s broadest and highest elevation collisional system, shapes orographic barriers, reorganizes drainage networks, and influences surface erosion and sediment delivery, whose changes in space and provenance feed back to intracontinental tectonic processes. Studies of interior basins within the northern Tibetan Plateau provide new sediment accumulation, provenance, paleodrainage, and deformation timing data that enable a reconstruction of the far-field tectono-geomorphic evolution of the rising Tibetan Plateau. Along the northern plateau margin, topographic growth in the West Qinling Belt is inferred to have initiated in the Eocene, nearly coeval with the India-Asia collision, as well as in the late Miocene. However, geological knowledge about the intervening period remains at present enigmatic, and the kinematics and dynamics are uncertain. This study presents a multidisciplinary data set from the intermontane Anhua-Huicheng Basin (AHB; Gansu Province, China) to fill this gap. Magnetostratigraphic dating, regional mapping, and sedimentological analysis imply that contractional deformation and thrust-top basin systems formed within the West Qinling Belt in the Oligocene (not later than ca. 24 Ma). A combination of observations including paleocurrent changes, detrital zircon U-Pb age variations, and appearance of growth strata along the Anhua-Huicheng Basin reveal the rapid uplift of the West Qinling Belt at ca. 15 Ma. Sedimentation in the intermontane basins ended after the late Miocene (ca. 8 Ma), when the region experienced intrabasinal deformation, uplift, and erosion with the establishment of an external drainage system. Since the late Miocene, the growth of the West Qinling Belt reached a climax with the lack of substantial contractional deformation in Cenozoic sequences heralding the onset of the modern kinematic regime and attainment of high elevation. Observed transitions in the tectonostratigraphy and paleodrainage define different phases of deformation and plateau-wide shifts in stress reorganization, which led to the northward growth and later lateral expansion of the Tibetan Plateau.

GSA Bulletin

2024 Crustal Deformation Modeling Workshop report

The 2024 Crustal Deformation Modeling Workshop was held June 10–14 at the Colorado School of Mines. The workshop included two days of tutorials on using PyLith for crustal deformation modeling, followed by three days of science talks and discussions. The workshop focused on four primary themes: ● Constraining long-term fault slip rates and their uncertainties using geodetic and geologic data; ● Earthquake cycle modeling with a focus on constraining models using seismic and geodetic data; ● Interaction of fluids and faulting; and ● Separating contributions of surface loading and tectonic loading in crustal deformation. The complete agenda is available on the CIG website.

Conference Paper

Nonpoint-source pollutant discharges of the three major tributaries to Reelfoot Lake, west Tennessee, October 1987-September 1989

An investigation of the concentration and loads of nitrogen, phosphorus, and suspended sediment in storm runoff to Reelfoot Lake, in western Tennessee, was conducted from October 1987 through September 1989. Concentrations of selected herbicides also were defined. Reelfoot Lake, with a surface area of about 15,500 acres, is the largest natural lake in Tennessee and an important recreation and fisheries resource. Previous studies showed that the lake is hypereutrophic, a condition caused by high concentrations of nutrients in water and sediments discharged from the three principal tributaries (South Reelfoot Creek, North Reelfoot Creek, and Running Slough) to the lake. Pesticides, including herbicides, have been detected in the lake's bottom sediments. Storm runoff contributed about 87percent of the total water discharge of the three main tributaries to Reelfoot Lake. South Reelfoot Creek contributed about 4.7 tons per acre per year of suspended sediment, while North Reelfoot Creek contributed about 1.9 tons per acre per year. Running Slough contributed only about 0.31 ton per acre per year of suspended sediment. Most of the suspended sediment was transported by storm runoff between October and March. About 80 percent of the annual streamflow of the three tributaries occurs during these months. The North Reelfoot Creek basin contributed 8.2 pounds per acre per year of total nitrogen and 2.4 pounds per acre per year of total phosphorus. South Reelfoot Creek basin contributed about 6.5 and 1.3 pounds per acre per year of total nitrogen and phosphorus, respectively, while Running Slough basin contributions were 3.4 and 0.86 pounds per acre per year, respectively. The differences in nutrient yields appear to result from more row-crop agriculture and the relatively steeply sloping agricultural land in the North Reelfoot Creek basin. Ninety-one percent of the total nitrogen load and 95 percent of the total phosphorus load in the three streams was transported by storm runoff. Significant differences in the mean concentrations of nutrients in runoff were defined between the active agricultural months (April through September) and the inactive months (October through March). Storm-runoff samples were analyzed for II selected triazine herbicides. Alachlor and atrazine were the most commonly detected herbicides. Thirty-two percent of the samples contained detectable levels of alachlor and 93 percent of the samples contained detectable levels of atrazine. Ninety percent of the samples collected during the active agricultural months contained detectable leveki of alachlor and all 29 samples contained detectable levels of atrazine. Sixteen samples exceeded lifetime health-advisory levels for atrazine in drinking water (3 micrograms per liter); two samples collected from the April IS, 1988, storm at North Reelfoot Creek and South Reelfoot Creek contained 42 and 57 micrograms per liter of atrazine, respectively. Concentrations of the other nine triazine herbicides were generally less than the level of detection (0.1 microgram per liter).

Tennessee

Water quality of the Quaternary and Ada-Vamoosa aquifers on the Osage Reservation, Osage County, Oklahoma, 1997

The project was to provide information on the quality of ground water from rural-domestic-water wells within the Osage Reservation and compare the water-quality to proximity to oil wells. About 38,500 oil wells have been drilled in the Reservation since drilling began in 1896. About 1,480 square miles or 64 percent of the Reservation is within a quarter mile of an oil well. The unconfined Quaternary sand aquifer covers about 315 square miles or about 14 percent of the Reservation and the confined Ada-Vamoosa sandstone aquifer covers about 800 square miles or about 35 percent of the Reservation. Fifty-eight percent of the Quaternary aquifer and 69 percent of the outcrop area of the Ada-Vamoosa aquifer are within a quarter mile of an oil well. One hundred twenty domestic ground-water wells were sampled from the Quaternary and Ada-Vamoosa aquifers. Forty-nine percent of the Reservation is underlain by the aquifers. Ground-water quality is good on most of the Reservation, but the use of domestic-water-supply wells tend to minimize water-quality problems. Existing water-supply wells commonly are located in areas that produce usable volumes of potable water. Several constituents in samples from the Ada-Vamoosa aquifer within a quarter mile of an oil well were significantly greater than from the aquifer not near oil wells. The constituents include specific conductance, dissolved solids, sodium, sulfate, chloride, bromide, and silica. These ions are probably derived from brine water. In the Ada-Vamoosa aquifer subgroups, 57 percent of the samples near oil wells and 24 percent of the samples not near oil wells had dissolved-solids concentrations greater than 500 milligrams per liter. The water quality in the Quaternary and Ada-Vamoosa aquifers is similar in areas where no oil wells have been drilled but is significantly different for several constituents. Median concentrations of major constituents from the Ada-Vamoosa aquifer not near oil wells were less than or equal to values from the Quaternary aquifer. Sixty-four percent of the water-quality samples from the Quaternary and 51 percent from the Ada-Vamoosa aquifers have dissolved-solids concentrations less than the secondary drinking water regulations of 500 milligrams per liter. Fifty-nine percent of the aquifer samples in the Quaternary aquifer subgroups not near oil wells and 70 percent of the samples near oil wells had dissolved solids less than 500 milligrams per liter. Areas in the Ada-Vamoosa aquifer near Hominy, Pershing, and Hula Lake have dissolved-solids concentrations greater than the secondary drinking water regulations. Water-quality samples from the Quaternary aquifer in these areas also have dissolved-solids concentrations greater than 500 milligrams per liter.

Oklahoma

Distribution of ancient carbon in groundwater and soil gas from degradation of petroleum near the Red Hill Bulk Fuel Storage Facility, O‘ahu, Hawai‘i

The groundwater below the Red Hill Bulk Fuel Storage Facility (the facility) in Oʻahu, Hawaiʻi, contains fuel compounds from past spills. This study used carbon-14 analyses to distinguish fuel-derived carbon from background carbon, along with other biodegradation indicators, to address two goals: (1) determine the extent and migration direction of groundwater affected by residual fuel below the facility and (2) determine if residual fuel locations in the subsurface could be identified by analyzing soil gas at the surface above the facility. Groundwater from 19 wells was sampled between September 2022 and April 2023. Nonvolatile dissolved organic carbon (NVDOC) from a well presumed to be unaffected by past spills contained 38 percent ancient carbon indicating a natural source of ancient carbon in the subsurface. The NVDOC concentrations and ancient carbon percentages indicate fuel biodegradation products are likely present on the north and south of Red Hill with the greatest effects at well RHMW02 near the 2014 spill site. The NVDOC concentrations are almost three times higher than diesel range organic (DRO) concentrations in groundwater from the same sites. Major ion data indicate that iron reduction is an important biodegradation process. Soil probe samples and soil carbon traps were used to determine the carbon-14 content of soil carbon dioxide. Ancient carbon from fuel biodegradation was not detected at any soil probe or carbon trap site in contrast to a 2017 study which reported ancient carbon detections. A reanalysis of the 2017 results using a range of local values for background carbon-14 indicates that ancient carbon from fuel biodegradation was probably only detected in lower tunnel exhaust system samples and not in any soil carbon trap samples. Measurements of carbon dioxide efflux with a dynamic closed chamber were highly variable. The soil gas results indicate that soil gas measurements at land surface were not useful for detecting residual fuel at the facility.

Hawaii

Regional variations in sea ice and primary productivity in the Bering Sea during Marine Isotope Stage 11

Marine Isotope Stage (MIS) 11 (424-374 ka) has long been an analog for Holocene climate, because it is the most recent interglacial period with similar orbital conditions. However, there is significant global and regional variability in the climate response to MIS 11 warmth. Here, we review sediment core records from across the Bering Sea to investigate changes in paleoceanographic conditions during Marine Isotope Stages 12-10. Sea ice was present over much of the Bering Sea during MIS 11, but today, none of the sites investigated are ever ice-covered. This suggests that sea ice regimes in the Bering Sea during MIS 11 were different to those of the Holocene. There are also regional differences in the response of sea ice to MIS 11 warming. At the Umnak Plateau, Southeastern Bering Sea, sea ice concentrations decline during deglaciation, but they remain high at the slope sites until Peak MIS 11. Sea ice re-advances over the Umnak Plateau during peak interglacial warmth, at the same time that it declines over the slope sites. Late MIS 11 is characterized by high concentrations of seasonal sea ice at the Umnak Plateau, whilst sea ice at the slope sites fluctuates between consolidated and unconsolidated ice cover. This east-west dichotomy may be explained by changes in the behavior of the Aleutian Low. Productivity increases dramatically during deglaciation due to increased upwelling and sea level rise bringing fresh nutrients into the oceans. This is characterized by increased diatom productivity, increased terrestrial carbon deposition, and laminations at all sites.

Alaska

Hydrothermal manganese-oxide mineralization of a carbonate ooze, Samoan hotspot region, South Pacific Ocean

Low-temperature hydrothermal manganese oxides occur throughout the global oceans. However, the hydrothermal replacement of a carbonate ooze by manganese oxides is described here for the first time. The 24 samples dredged from three locations around the Territory of American Samoa in the South Pacific Ocean include six samples with remnant carbonate and volcaniclastic sediments, which we refer to as “low Mn,” and 18 samples in which the mineralization is pervasive and has replaced most original sediment, termed “high Mn.” The 18 high-Mn samples exhibit a mean Mn content of 51 wt.%. Higher Li and Mn contents and lower Fe contents in the high-Mn samples indicate a hydrothermal origin and distinguish these samples from hydrogenetic ferromanganese crusts. Mn-oxide layers are up to 90 mm thick, some with columns to 44 mm long and 10 mm wide, the magnitude of which has not been described previously. Samples are composed of birnessite and 10 Å phyllomanganate minerals. Textures of the thickest Mn layers indicate mineralization below the seabed from ascending fluids during multiple hydrothermal pulses. Mineralization took place by complete to partial replacement and cementation of foraminiferal sediments intermixed with volcaniclastic sediments in varying amounts. Our results highlight the production of carbonate sediment-hosted hydrothermal Mn oxides from multiple hydrothermal sources within the Samoan volcanic chain. The potential extensive distribution on the regional scale of this newly described mineralization process and unique element enrichments raise questions about its broader distribution globally and potential importance to hydrothermal processes, element mass balance, and seabed mineral resources.

Geochemistry, Geophysics, Geosystems

Hydraulic properties of the Madison aquifer system in the western Rapid City area, South Dakota

Available information on hydrogeology, data from borehole geophysical logs, and aquifer tests were used to determine the hydraulic properties of the Madison aquifer. From aquifer-test analysis, transmissivity and storage coefficient were determined for the Minnelusa and Madison aquifers, and vertical hydraulic conductivity (K v ') along with specific storage (Ss') for the Minnelusa confining bed. Borehole geophysical well logs were used to determine the thickness and location of the Minnelusa aquifer, the lower Minnelusa confining bed, and the Madison aquifer within the Madison Limestone. Porosity values determined from quantitative analysis of borehole geophysical well logs were used in analyzing the aquifer-test data. The average porosity at the two aquifer-test sites is about 10 percent in the Minnelusa aquifer, 5 percent in the lower Minnelusa confining bed, and 35 percent in the Madison aquifer. The first aquifer test, which was conducted at Rapid City production well #6, produced measured drawdown in the Minnelusa and Madison aquifers. Neuman and Witherspoon's method of determining the hydraulic properties of leaky two-aquifer systems was used to evaluate the aquifer-test data by assuming the fracture and solution-opening network is equivalent to a porous media. Analysis of the aquifer test for the Minnelusa aquifer yielded a transmissivity value of 12,000 feet squared per day and a storage coefficient of 3 x 10 -3 . The specific storage of the Minnelusa confining bed was 2 x 10 -7 per foot, and its vertical hydraulic conductivity was 0.3 foot per day. The transmissivity of the Madison aquifer at this site was 17,000 feet squared per day, and the storage coefficient was 2 x 10 -3 . The second aquifer test, which was conducted at Rapid City production well #5 (RC-5) produced measured drawdown only in the Madison aquifer. Hantush and Jacob's method of determining the hydraulic properties of leaky confined aquifers with no storage in the confining bed was used to evaluate the aquifer-test data by assuming the fracture and solution-opening network is equivalent to a porous media. The analysis of data from the RC-5 aquifer test showed that transmissivity was not equal in all directions. Hantush's method was used to determine the direction of radial anisotropy and magnitude of the major and minor axes of transmissivity. The major axis of transmissivity is at an angle of 42° east of north, and the transmissivity along this axis is about 56,000 feet squared per day. The minor axis of transmissivity is at an angle of 48° west of north, and the transmissivity along this axis is about 1,300 feet squared per day. The major axis of transmissivity intersects Cleghorn Springs, a large resurgent spring on the west edge of Rapid City. The shape of the potentiometric contours of the Madison aquifer near RC-5 agree with the orientation of the transmissivity ellipse. The average value of the storage coefficient from the isotropic analysis of the aquifer-test data was 3.5 x 10 -4 , and the average vertical hydraulic conductivity of the lower Minnelusa confining bed was 9.6 x 10 -3 foot per day.

South Dakota

From exploration to production: Understanding the development dynamics of lithium mining projects

Recently, there has been considerable recent controversy whether current and new lithium mines will be able to supply the rapidly growing needs of the electromobility transition. Mineral exploration projects are typically active for many years, and only some become operational mines. From exploration to production, the projects go through several stages of characterisation and evaluation. At each stage, decisions are made by companies and stakeholders to advance, continue or stop the project. This is a complex process, and even projects with very similar geological and technical characteristics may take very different trajectories, depending on external factors such as global market conditions and local regulatory environments. The present study investigates the dynamics of this process for lithium exploration projects. A global database of 397 lithium projects was compiled, covering their progression through major development stages between 2004 and 2022. Ordinal logistic regression was used for the statistical analysis of this data. Different explanatory variables were tested, including economic, geological, technical, and geographic factors, to identify the best predictors for project progress at each development stage. The results suggest an essential role for lithium carbonate prices, and a variable role for other factors at each stage. Critically, the already elapsed lead time and project economics, which are traditionally considered important for the prediction of the start-up of individual mines, do not appear to be relevant in all cases. The results provide important insights into the dynamics of lithium supply and may eventually allow more realistic forecasts to be made for future lithium market dynamics.

Resources Policy

Triple-oxygen isotopic evidence of prolonged direct bioleaching of pyrite with O2

Sulfate is often touted as containing atmospheric oxygen whose isotopic signature can constrain redox, environmental conditions, and biological activity. Yet, the amount and isotopic fractionation associated with air-O 2 incorporation during sulfate formation is still debated, making its verification difficult. In this study, we identify a distinct, microbially dominated environment with the potential to preserve maximum signals of air-O 2 in sulfate. We report triple-oxygen isotope data for sulfate produced from pyrite oxidation in microbial and abiotic experiments, and from natural dissolved sulfate from the Rio Tinto, Spain, an acid mine drainage site. The oxygen isotope systematics of sulfate in these environments define a unique kinetic isotope effect associated with initial stage pyrite oxidation by Acidithiobacillus ferrooxidans that preserves >80 % oxygen from air-O 2 in sulfate. Unlike experiments, which evolve toward water-oxygen dominated sulfate on short time scales, Rio Tinto, Spain hosts a microbe rich environment with distinct geochemistry that maintains high O 2 -oxygen in sulfate. Therefore, in addition to containing isotopic records from water and air, sulfates can also contain a biosignature that is promising for understanding conditions on Mars and early Earth.

Earth and Planetary Science Letters

Assessment of long-term changes in surface-water extent within Klamath Marsh, south-central Oregon, 1985–2021

The annual maximum extent of surface water in Klamath Marsh has naturally fluctuated in response to periods of wet and dry conditions in the surrounding basin. Field observations during the 2010s indicate that the annual maximum extent of surface water has been declining and the marsh is not responding to hydrologic inputs as it had historically. This report describes the results of a hydrologic evaluation of Klamath Marsh to characterize and understand multi-year declines in the surface-water extent and increased intermittency of streamflow exiting the marsh. Landsat imagery collected during 1985–2021 was processed to create a time series of annual maximum surface-water extent to assess changes in surface-water inundation within the marsh. A 50-percent decrease in the mean surface area of annual total open-water extent (TOWE) during the latter half of the study period (2003–21) compared to the first half (1985–2003) was observed in this 37-year time-series dataset. The change in open-water extent was offset by a corresponding increase in dry land in the marsh. Time series of streamflow, groundwater level, total annual precipitation, annual mean temperature, and anthropogenic water use and water management were compiled and evaluated to improve understanding of the factors affecting TOWE. Statistically significant downward trends in the regional groundwater table and streamflow into and out of the marsh were identified as well as statistically significant upward trends in annual mean temperature. Statistically significant correlations among TOWE, streamflow, and groundwater level also were identified. The decreasing trends could not be attributed to changes in total annual precipitation or changing anthropogenic groundwater use within the study area. Declines in the open-water extent of Klamath Marsh since 2000 principally are due to a decoupling of the groundwater and surface-water system beneath the marsh because of regional declines in groundwater level. Regional increases in air temperature and the reestablishment of more than 55,000 acres of forested land within the study area have likely contributed to increasing evapotranspiration, leaving less water available for groundwater recharge and stream base flow and resulting in basin-wide declines in streamflow and groundwater levels.

Oregon

Helium detection as a guide for uranium exploration

Helium, a byproduct of radioactive decay, may prove to be a valuable indicator of the presence and distribution of uranium deposits. Recent technological advances permit the development of instrumentation not previously adapted for this purpose. Commercially available equipment can provide high sensitivity at low cost and allow reasonable mobility for field use. A truck-mounted mass-spectrometer, tuned for helium-4, permits immediate adjustment or modification of sampling patterns in response to accumulating data. The inlet system of the spectrometer has been designed to allow flexibility in gas analyses from various sample types--soil gas, atmosphere, or gases in water. Sensitivity of the instrument is better than 50 parts of helium per 10 9 parts of gas. Replicate samples and standards can be analyzed in only 3 minutes. Helium in soil gas is being used for the initial evaluation of the technique. A hollow probe, as much as 2 m long, is driven into the ground; and a 10-cc syringe is used to purge the probe and extract the gas. This sample is then injected into the inlet system and introduced into the spectrometer at constant pressure. The output signal is displayed on a chart recorder. Investigations can be performed on a qualitative, relative basis, or on a quantitative basis by comparison to calibrated helium standards. Preliminary field testing includes studies of the responses to variations in wind speed, temperature, barometric pressure, moisture, and sampling depth over extended time periods, as well as studies of geologic controls on the helium content in soil gas. Surveys over known uranium occurrences reveal some anomalous helium distributions. This report describes an updated technological approach to an old idea: that of using helium, a byproduct of uranium radioactive decay, as an exploration tool for uranium. Helium is the sixth most abundant gas found in the earth's atmosphere (Table 1). It is an inert gas and very mobile, mixing rapidly. When the alpha particles from the radioactive decay of uranium and thorium pick up two electrons, atoms of the isotope helium-4 are formed. Several helium-4 atoms are produced from each decay series of U-238, U-235, and Th-232 (fig. 1). The half-lives of the parent isotopes are5also shown in figure 1. One gram of uranium will produce ~10 5 atoms of helium-4 per second, and one gram of thorium produces ~2.5 x 10 4 atoms of helium-4 per second (fig. 2). Calculations of the helium produced from the crust and mantle reveal that 1,125 x 10 30 atoms per year are produced, but only 7 x 10 30 atoms per year escape from the earth (Damon and Kulp, 1958). More is being produced than is being lost; in fact, the total atmospheric content of helium could be produced in only 2 million years (MacDonald, 1963)! However, all the crustal and mantle helium-4 does not degas into the atmosphere as it is formed. It is trapped in crystal lattices and in pore spaces within the earth. What this means is that there is excess helium-4 in the earth--excess, that is, compared to the atmospheric concentration in equilibrium with the helium-4 escape rate into space and the helium-4 flux from the crust and mantle (Nicolet, 1957). Near-surface pockets of high helium-4 concentrations are known, and some natural gas fields are so enriched that they are the source for commercial production of helium. Work by Roberts and others (1975) has shown high helium concentration in the soil gas associated with geothermal areas; and work by Clark and Kugler (1973), Dyck (1975), and Goldak (1974), for example, has noted high helium concentrations in soils and waters in the vicinity of uranium deposits. These latter studies certainly indicate the potential of helium detection for use as an exploration tool for uranium.

Open-File Report

From hydrated silica to quartz: Potential hydrothermal precipitates found in Jezero crater, Mars

On Earth, silica-rich phases from opal to quartz are important indicators and tracers of geological processes. Hydrated silica, such as opal, is a particularly good matrix for the preservation of molecular and macroscopic biosignatures. Cherts, a type of silica-dominated rocks, provide a unique archive of ancient terrestrial life while quartz is the emblematic mineral of the Earth's continental crust. On Mars, hydrated silica has been detected in several locations based on remote sensing and rover-based studies. In the present article we report on the detection of cobbles made of hydrated silica (opal or chalcedony), as well as well-crystallized quartz. These detections were made with the SuperCam instrument onboard Perseverance (Mars 2020 mission), using a combination of LIBS, infrared and Raman spectroscopy. Quartz-dominated stones are detected unambiguously for the first time on the Martian surface, and based on grain size and crystallinity are proposed to be of hydrothermal origin. Although these rocks were all found as float, we propose that these detections are part of a common hydrothermal system, and represent different depths / temperatures of precipitation. This attests that hydrothermal processes were active in and around Jezero crater, possibly triggered by the Jezero crater-forming impact. These silica-rich rocks, in particular opaline silica, are very promising targets for sampling and return to Earth given their high biosignature preservation potential.

Earth and Planetary Science Letters

Do Graviquakes exist?

The “Graviquake” model, proposed in 2015 as an alternative to the elastic dislocation model, posits that normal faults are passive features dominated by coseismic gravitational collapse into a dilated crustal wedge, and that normal faulting is fundamentally distinct from strike‐slip and reverse faulting. Developed using finite‐element modeling before the 2016 central Apennines earthquake sequence, the model was revamped based on interpreted Differential Interferometric Synthetic Aperture Radar data from these events and used as evidence for a gravitational collapse episode. However, this interpretation relies on miscalculated elevation changes and is not corroborated by independent geophysical and seismological observations. Our analysis exposes fundamental flaws in the Graviquake model. By assuming that faults are passive players, it underrepresents the dynamic role of strain accumulation and release in rocks adjacent to faults. The hypothesized rapid expulsion of overpressurized fluids appears inconsistent with observed diffusion rates and lacks supporting seismological evidence. Part of the uplifted–subsided volume imbalance is likely an artifact arising from data processing, and in part is a transient effect due to the delayed response of the lower crust. Moment tensor analyses detect no isotropic components indicative of gravitational collapse, and observed ground motion and stress‐drop levels remain fully consistent with elastic dislocation theory. In addition, finite‐element modeling of normal faulting replicates observed surface deformation without invoking a collapsing wedge. The Graviquake model proposes a representation of normal‐faulting mechanics that differs significantly from established models and observations. Gravity does play a role in normal faulting, but the elastic dislocation theory remains the definitive framework of fault mechanics. Reinterpreting the 2016 earthquakes as a cascade of gravitational episodes, based on incorrect data processing and modeling, fails to substantiate the Graviquake hypothesis. Persistence in advocating this model could mislead seismic hazard assessment and undermine our understanding of normal faulting.

Bulletin of the Seismological Society of America

Estimation of dynamic geologic CO2 storage resources in the Illinois Basin, including effects of brine extraction, anisotropy, and hydrogeologic heterogeneity

Since the vast majority of carbon dioxide (CO 2 ) storage resources in the United States are in deep saline aquifers, optimizing the use of these saline storage resources could be crucial for efficient development of geologic CO 2 storage (GCS) resources and basin- or larger-scale deployment of GCS in the country. Maximum CO 2 injection rates can be enhanced by extracting brine from the CO 2 storage unit. However, disposal of the extracted brine is both a technological and economic challenge. The lowest-cost option would likely be reinjection of the extracted brine into another formation above or below the CO 2 storage unit. Therefore, it is important to estimate brine injectivity as it will constrain the potential to increase CO 2 injectivity at an injection site that has access to multiple geologic storage units where either CO 2 or brine can be injected. Using a simulation-optimization framework, coupled with a non-isothermal, multiphase CO 2 -water-salt equation-of-state module, we developed a computationally efficient method for evaluating optimization of simultaneous CO 2 injection, brine extraction, and brine (re)injection at hypothetical injection sites deployed across a geologic basin. The Illinois basin is ideal for testing our methodology because it contains multiple geologic storage units with seals in between them to isolate injection of CO 2 in one unit from interfering with the injection of either brine or CO 2 in another unit above or below it. In addition, we investigated the relative effects of variation in key geologic parameters as well as two reservoir structures (hydrogeologic heterogeneity/anisotropy and homogeneity/isotropy) on CO 2 injectivities and enhancement of CO 2 injectivity through extracting brine. Results suggest that permeability, depth, and especially thickness of the storage unit could be the most influential parameters determining CO 2 injectivity. They also suggest that only injecting CO 2 into the storage unit with the greatest injectivity, enhancing that unit’s injectivity by extracting brine, and disposing of the produced brine in other suitable units could maximize total CO 2 injectivity in limited regions of the basin. At the majority of simulated injection sites, however, we found that injecting CO 2 into all of the accessible and suitable storage units was more likely to maximize the CO 2 storage resource.

Illinois, Kentucky, Indiana

Water use across the conterminous United States, water years 2010–20

Withdrawals of water for human use are fundamental to the evaluation of the Nation’s water availability. This chapter provides an analysis of public supply, crop irrigation, and thermoelectric power water use for the conterminous United States (CONUS) during water years 2010–20. These three categories account for about 90 percent of water withdrawals in the Nation. The values presented here are based on modeling approaches that estimate water use at temporal (monthly) and spatial scales (12-digit hydrologic unit code—small watersheds sized 50–100 square kilometers) compatible for integration into a broader national assessment of water availability. Models also provide an understanding of factors that influence water use. An estimated 244,817 million gallons per day (Mgal/d; 28,677 million cubic meters per month [Mm 3 /mo]) were withdrawn on average within the CONUS during water years 2010–20 from fresh water and saline water for crop irrigation, public supply, and thermoelectric power, with shares of 43, 14.5, and 42.5 percent for each of these categories, respectively. In the same period, estimated withdrawals and consumptive use (1) for public supply were 35,400 and 4,219 Mgal/d (4,081 and 486 Mm 3 /mo), respectively; (2) for crop irrigation were 105,497 and 75,698 Mgal/d (12,147 and 8,716 Mm 3 /mo), respectively; and (3) for thermoelectric power from fresh water were 82,656 and 2,904 Mgal/d (9,952 and 345 Mm 3 /mo), respectively. Withdrawals for these categories of water use are highly spatially variable, with western States dominated by crop irrigation and eastern States dominated by thermoelectric-power water use. Public supply accounts for the largest percentage of water use in several heavily populated northeastern States. Reliance on groundwater compared to surface water depends on the availability of water sources and the type of water use. For public supply, withdrawals from groundwater are greater than withdrawals from surface water in the Western aggregated hydrologic regions, whereas the balance shifts to more surface water for the rest of the CONUS. In all aggregated hydrologic regions, the predominant source of water for crop irrigation is groundwater. Most thermoelectric power facilities in the eastern half of the CONUS use surface water from freshwater and saline sources; most thermoelectric power facilities in the western half of the CONUS use groundwater.

conterminous United States