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SlideDetect: Spatio-temporal landslide detection using a three-dimensional convolutional neural network

Landslides pose a serious and ongoing threat to both human lives and infrastructure worldwide; therefore, it is of interest to predict where and when landslides are likely to occur. Advances in machine learning techniques have spurred numerous studies aimed at estimating relative landslide propensity, but are limited to spatial (as opposed to temporal) prediction due to the sparsity of landslide timing data. We address this data gap by training SlideDetect, a 3-dimensional convolutional neural network (3D CNN), to identify landslides based on their spatial and temporal occurrence within multitemporal image stacks. We use an inventory of landsides triggered by the 2018 Hokkaido earthquake and two years of monthly composite optical imagery spanning this event. The model can identify not only landslide location but also landslide date with an area under the precision-recall curve (PR-AUC) of 0.84. We further present a new standard for presenting PR curve results that explicitly compares model performance at different confidence thresholds, allowing for clearer model evaluation and comparison. Our new approach to constraining landslide timing paired with this more consistent and objective method for evaluating model performance shows considerable promise, and with further application and testing, SlideDetect could enhance the data availability and tools needed to advance landslide hazard and risk assessments.

JGR Machine Learning and Computation

Flood-inundation maps for Río de la Plata in and near Comerío, Puerto Rico, 2025

Digital flood-inundation maps for a 3.1-mile reach of Río de la Plata in and near Comerío, Puerto Rico, were created by the U.S. Geological Survey (USGS). Water-surface profiles were computed for the stream reach by using a one-dimensional steady-state step-backwater model. The model was calibrated to the current (2025) stage-streamflow relation (rating curve 11.0) for the USGS streamgage 50043800, Río de la Plata at Comerío, Puerto Rico. The resulting hydraulic model was then used to compute 16 water-surface profiles for water levels (flood stages) ranging from 10.00 to 40.00 feet at the streamgage and ranging from “action stage” to above “major flood stage” as reported by the National Weather Service. The 40.00-foot stage was selected because it exceeds the peak stage of 34.86 ft recorded during Hurricane Maria at the USGS streamgage 50043800, Río de Plata at Comerío, Puerto Rico. The simulated water-surface profiles were then used in combination with a digital elevation model derived from light detection and ranging data to map the inundated areas associated with each flood profile. The flood-inundation maps and the supporting hydraulic model produced by this study can be used by emergency managers and local officials to assess flood mitigation strategies and to define flood hazard areas to help protect life and property, to coordinate flood response activities such as evacuations and road closures, and to aid post-flood recovery efforts.

Comerio

Upper Triassic igneous rocks of the southern Kenai Peninsula, Alaska – Prelude to Early Jurassic subduction along the western Wrangellia composite terrane margin

New U–Pb zircon geochronology identifies a latest Triassic (ca 214–201 Ma) igneous suite of tuff, hypabyssal dikes, and a pluton on the southern Kenai Peninsula, Alaska. The igneous suite was emplaced within Upper Triassic sedimentary rocks along the southern margin of Western Wrangellia, the western-most fragment of the Wrangellia composite terrane. The igneous rocks range from mafic (50.6% SiO 2 ) to felsic (78.3% SiO 2 ), characteristically have less than 1.55% K 2 O, and generally have low trace element abundances. The tonalitic and trondhjemitic magmas were largely sourced in mafic-rich lower crust and incompletely assimilated quartz and other mineral xenocrysts are common. Fractionation involving plagioclase and amphibole is indicated for some magmas and composite intrusions and igneous xenoliths indicate magma mixing was possible. Paleozoic and Precambrian inherited zircons and initial 87 Sr/ 86 Sr (0.704103–0.705609) and 143 Nd/ 144 Nd (0.512396–0.512777) ratios indicate that the Western Wrangellia crustal sources are heterogeneous and contain sialic components. The latest Triassic magmatism reflects processes that preceded Early Jurassic subduction along the Wrangellia composite terrane and Pacific Ocean plate boundary. These processes involved heating and melting of mantle lithosphere and lower crust as mantle instabilities accompanied the breaking of the plate boundary linkages. The Late Triassic transition to subduction along the Wrangellia composite terrane margin coincided with the transition to subduction cessation in the Late Triassic arcs of the western Intermontane terranes of Canada. The shift to subduction along the outboard Wrangellia composite terrane margin marks the beginning of the Pacific Ocean–Cordillera plate interactions that came to dominate the tectonic evolution of the northern Cordillera from the Early Jurassic to today.

Alaska

Moment magnitude for small earthquakes in the Delaware basin of west Texas and southeast New Mexico, USA

The Delaware Basin region of west Texas and southeast New Mexico has become one of the most prolific regions of seismic activity in the continental United States due to widespread hydraulic fracturing and wastewater disposal injection. In response to the increased number of earthquakes in this region, rapid and accurate characterization of earthquake sources is necessary to understand the evolution of seismic activity and level of seismic hazard associated with these earthquakes. This study re-evaluates earthquake magnitudes, estimating moment magnitude (MW) for small earthquakes in the Delaware Basin using 1) moment-rate spectra derived from S-wave coda envelopes, and 2) a relative magnitude method that relies exclusively on the ratio of waveform amplitudes between highly correlated waveform pairs. The coda-envelope method produces accurate M W estimates for small earthquakes ( M 1.5 – 3) that are consistent with independent, waveform modeled moment magnitudes for events with M W > 3 . Using the relative amplitudes method to extend these M W magnitudes to many other events, we successfully provide relative moment magnitude ( M W,rel ) values for 81% of the Texas Seismological Network catalog in the Delaware Basin region, and 45% of the USGS Induced Seismicity Project’s catalog of events in southeast New Mexico. The adoption and integration of the calibrated M W,rel method with current magnitude estimation methods offers valuable insights into the relationships between local and moment magnitude and will contribute to improved characterization of widespread induced seismicity.

New Mexico, Texas

Polystyrene microplastics alter the accumulation and elimination dynamics of silver nanoparticles in Daphnia magna

Rationale Microplastics (MPs) can interact with engineered nanomaterials and alter their environmental fate and bioavailability. However, their influence on the bioaccumulation dynamics of silver nanoparticles (AgNPs) in aquatic filter feeders under environmentally relevant conditions remains poorly understood. We hypothesized that polystyrene microplastics (PS-MPs) alter the uptake, elimination and overall bioaccumulation dynamics of AgNPs in Daphnia magna . Methodology Adult D. magna were exposed to isotopically labeled citrate-coated 109 AgNPs in the presence and absence of PS-MPs. Waterborne uptake, dietary uptake, assimilation efficiency, food ingestion and elimination were quantified experimentally and incorporated into a biodynamic model to predict steady-state silver (Ag) concentrations under environmentally relevant exposure scenarios. Results PS-MPs increased waterborne Ag accumulation by approximately eightfold compared with AgNPs exposure alone. However, Ag elimination was substantially faster, with 98% of accumulated Ag eliminated after five days of depuration compared with 66% without PS-MPs. PS-MPs also reduced food ingestion rates (IRs), while assimilation efficiency remained largely unchanged. Biodynamic modeling predicted that steady-state Ag accumulation was approximately fivefold greater in the presence of PS-MPs, with waterborne exposure becoming the dominant accumulation pathway. Discussion These findings suggest that PS-MPs alter bioaccumulation dynamics of AgNPs in filter-feeding organisms by enhancing organism-associated Ag during waterborne exposure while accelerating Ag elimination, likely through particle-associated transport and gut egestion. Collectively, these results underscore the complexity of Ag bioaccumulation processes when MPs and AgNPs interact and highlight the importance of studies conducted under environmentally relevant conditions.

Environmental Chemistry

Top Elevation of Glacial Till and Thickness of the Big Sioux Aquifer Delineated From Electrical Resistivity Tomography Surveys Near Sioux Falls, South Dakota, 2022 and 2025

The City of Sioux Falls, South Dakota, requested the U.S. Geological Survey perform electrical resistivity surveys on three parcels of land north of the city. Electrical resistivity data were collected along a total of 22 transects during March 14–18, 2022, and November 17–21, 2025. Results from electrical resistivity surveys were used to delineate the top of glacial till deposits for the purpose of characterizing the Big Sioux aquifer near the city. Delineating geologic contacts provides important information on groundwater storage, flow dynamics, well design and placement, contaminant transport, groundwater–surface-water interactions, and regional water modeling. The top elevation of glacial till and the thickness of the Big Sioux aquifer varied among the three survey areas. The interpreted top elevation of glacial till in the North survey area decreases from east to west toward a slough, with elevations ranging from 1,403 to 1,418 feet (ft). The estimated thickness of the Big Sioux aquifer in the North survey area increased from east to west, with thicknesses ranging from 23 to 38 ft. The top elevation of glacial till in the Well 72 survey area generally decreases from northwest to southeast. Top elevations of the glacial till in the Well 72 survey area ranged from 1,400 to 1,409 ft along the southern end of transect W72_2. The estimated thickness of the Big Sioux aquifer in the Well 72 survey area was greatest along a southeast to northwest trending channel, with thicknesses ranging from 28 to 40 ft. The top elevation of glacial till in the Nose survey area generally decreases west toward the Big Sioux River. Top elevations of the glacial till in the Nose survey area ranged from 1,362 to 1,395 ft. The estimated thickness of the Big Sioux aquifer in the Nose survey area ranged from 33 to 70 ft.

South Dakota

Assessment of coastal and fluvial morphodynamic changes using Structure-for-Motion: A case study of the Sfȃntu Gheorghe Mouth (Danube Delta, Romania)

The ability to accurately map erosion, flooding, and habitat loss in coastal environments is crucial for formulating national strategies aimed at preventing and mitigating the impacts of natural disasters. A fundamental component of this process is the implementation of coastal morphodynamics monitoring through Structure-from-Motion (SfM) techniques, utilizing high-resolution 2D/3D data obtained from aerial photogrammetry. To assess morphodynamic changes over a three-year period (2022 – 2024), several SfM-based photogrammetric studies were conducted, each year, in the Romanian sector of the Danube-Black Sea coastal zone, specifically at the mouth of one of the Danube River distributaries (Sf Gheorghe branch) into the Black Sea, and along the left bank, near Sf Gheorghe locality, located within the Danube Delta Biosphere Reserve (DDBR). The essential equipment for aerial photogrammetry comprises Unmanned Aerial Vehicles (UAVs) and Global Navigation Satellite Systems (GNSS). In this study, the UAV used was a DJI Mavic 3T (Enterprise/Thermal) drone, complemented by two Trimble R12i and R4 GNSS systems, as well as approximately 10 Ground Control Points (GCPs). Data acquisition and processing were carried out using specialized photogrammetric software (Agisoft Metashape) along with various GIS tools (e.g., Blue Marble Geographics Global Mapper and ESRI ArcMap). The photogrammetric products generated for the study, as detailed in this paper, include Digital Elevation Models (DEMs), Digital Terrain Models (DTMs), orthomosaics (orthophotos), and others. At Sfântu Gheorghe beach, a comparison between 2023 and 2024 photogrammetric surveys revealed that the left bank of the Sf. Gheorghe Arm, at the river mouth into the Black Sea, suffered from a twist (erosion) of up to 64 metres. Additionally, on the selected perimetre (total area of 31,910 square meters ) from the beach and dune zone of Sf. Gheorghe, an area of up to 16,202 square meters was eroded between 2023 and 2024. This contrasts with the period between 2022 and 2023, during which deposition predominated. Erosion at the Danube mouths and the adjacent Black Sea coastline is driven by a complex interaction of natural and anthropogenic factors. Natural processes, including subsidence, sea-level rise, and episodic extreme storm events, contribute significantly to coastal dynamics. Meanwhile, human-induced factors, such as upstream hydrotechnical works that limits sediment transport, cutting of navigation canals, as well as the exacerbating effects of climate change, further accelerate erosion. The recent Structure-from-Motion (SfM) surveys provide essential quantitative data, enabling a detailed analysis of both short-term and long-term morphodynamic changes influenced by seasonal variations and extreme hydrometeorological events in this highly dynamic coastal system.

Sfȃntu Gheorghe Mouth (Danube Delta)

The U.S. Geological Survey 2025 Puerto Rico and U.S. Virgin Islands time-independent earthquake rupture forecast

We present the 2025 U.S. Geological Survey Puerto Rico and U.S. Virgin Islands (PRVI) time‐independent earthquake rupture forecast (ERF), developed for the 2025 update to the National Seismic Hazard Model (NSHM) for PRVI. The updated ERF improves upon a prior model from 2003, including an expanded fault inventory with slip‐rate estimates, updated seismicity catalogs, and refined subduction zone geometries and deformation models. It applies the fault‐system inversion methodology to solve for rates of ruptures on modeled faults, adapted from the 2023 NSHM (NSHM23) for the western United States, including the first application of the inversion to model rates on a U.S. subduction interface. Off‐fault and intraslab seismicity are constrained by observed seismicity and use updated methods developed for NSHM23. Uncertainties in model components are substantial, and the ERF represents epistemic uncertainties through a comprehensive logic tree consisting of 1.7 billion logic‐tree branches combined across all sources.

Puerto Rico, U.S. Virgin Islands

Pesticide occurrence in shallow groundwater in three regions of agricultural land use: Baldwin County, the Wiregrass region, and the Tennessee River valley region of Alabama, 2009–20

As part of a cooperative investigation between the U.S. Geological Survey and the Alabama Department of Agriculture and Industries, a network of 22 groundwater wells were sampled from 2014 through 2020 for about 230 pesticide and pesticide degradate compounds. Wells were located in three regions of intensive agricultural land use in Alabama: Baldwin County, the Wiregrass region, and the Tennessee River valley region. Metolachlor sulfonic acid, a degradate of the herbicide metolachlor, was the most frequently detected compound, occurring in about 70 percent of the samples. Three other compounds, metolachlor, atrazine, and 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in more than half of the samples. Metolachlor and its degradates accounted for 33 of the 50 greatest compound concentrations study-wide, including the maximum pesticide concentration across all compounds (62,500 nanograms per liter). The frequency and magnitude of detections of many specific pesticide compounds varied among the three regions, but all detected pesticide concentrations were well below the U.S. Environmental Protection Agency maximum contaminant levels and applicable human health benchmarks. Sample results were combined with results of previous (2009–13) sampling to provide a continuous time-series of data for 2009–20. More than half of the 289 pesticide compounds analyzed during 2009–20 were not detected in any samples. Only four compounds were detected at great enough frequency throughout the 10 sampling years to evaluate patterns of change through time. Metolachlor and its degradate, metolachlor sulfonic acid, were frequently detected in all regions. Atrazine and its degradate, 2-chloro-4-isopropylamino-6-amino-s-triazine, were also detected in wells from all regions, but the variability and magnitude of concentrations were greatest in the Tennessee River valley region. No apparent temporal pattern in concentrations was found.

Alabama

Examining the role of elevated and sustained strain in dynamically triggering earthquakes on the Anza section of the San Jacinto fault

Microearthquakes can be dynamically triggered in southern California by remote earthquakes. However, directly connecting dynamic triggering mechanisms with observational data remains challenging. One proposed failure mechanism suggests that both the amplitude and duration of cyclic fatigue caused by the passing seismic wave contribute to triggering occurrence. Here, we measure dynamic strains recorded by borehole strainmeters in the Anza section of the San Jacinto fault zone from 710 earthquakes that occurred over 300 km away between 2008 and 2017 to systematically investigate the role of elevated and sustained strain in controlling dynamic triggering. We design a suite of tests to evaluate whether specific amplitude thresholds and durations of strain can predict dynamic triggering cases. We further test whether the peak dynamic strain (PDS) can predict triggering occurrence in combination with the strain amplitude and duration. Based on these tests, there is no strain amplitude–duration threshold that can distinguish triggering occurrence in Anza. Dynamic triggering is more likely to occur if a remote earthquake causes a PDS above 100 nanostrain, though many cases were triggered at smaller PDSs. The lack of clear correlation between triggering and characteristics of the dynamic strain field suggests that the tested features of the incoming waves do not determine triggering occurrence and local fault conditions and slip processes are more important in controlling dynamic triggering in Anza.

California

Seismic velocity changes from repetitive seismicity at Mauna Loa prior to and during its 2022 eruption

Mauna Loa’s short-lived eruption from late November to early December 2022 marked the culmination of nearly a decade of elevated seismic activity and geodetic inflation. The volcano has been monitored by a network of permanent, short period and broadband seismometers. I used the continuous waveform data from that network starting in 2012 to generate a catalog of seismicity that enhances the US Geological Survey Hawaiian Volcano Observatory’s public seismic catalog with four times the number of earthquakes, which were then grouped by waveform similarity. Analysis of subtle delays in the timing of arrivals of scattered waves between pairs of earthquakes in this catalog yields a history of small changes in the shallow seismic velocity structure of the volcano. Seismic velocities have been shown at other volcanoes to change during unrest and eruption. My results show a decrease in seismic velocity centered on the summit beginning in September 2022, corresponding to the onset of a vigorous precursory swarm of seismic activity and shallow inflation. During the eruption itself, I observe large changes due likely to dike opening along the northeast rift zone and deflation of the summit reservoir. However, seismic velocity changes associated with non-volcanic sources such as ground shaking from large earthquakes and meteorological influences at seasonal and diurnal time scales are also observed, and these dominate the velocity changes prior to the eruption. Proper accounting of these effects will be a requirement for use in real-time monitoring, and this work serves as a starting point in that endeavor for Mauna Loa.

Hawaii

Wetter winters, drier summers: Quantifying the change in hydrological response around the Puget Sound area using the wflow_sbm hydrological model and CMIP6 projections

Climate change is expected to impact hydrological regimes worldwide, including the Pacific Northwest of the United States. This study investigates how climate change will affect river discharge in the Puget Sound region of the State of Washington, with a focus on King and Pierce Counties. We simulated river discharge under historical and future conditions using the physically based, spatially distributed wflow_sbm hydrological model, which was calibrated and validated against U.S. Geological Survey discharge records. Future forcing was based on an ensemble of six high-resolution CMIP6 climate models, which were bias corrected using empirical quantile mapping. The results indicate a decrease in summer discharges (5–10%) and an increase in winter discharges (5–10%) across the study region. The high discharges (90th percentile) are projected to increase in winter, and the low discharges are projected to decrease in summer, due to shifts in precipitation regimes, snowpack hydrology, and evapotranspiration. However, variability between individual CMIP6 models often exceeds the magnitude of ensemble mean changes, underscoring substantial uncertainty in climate projections and the importance of including multiple climate models in climate change analysis. Furthermore, model consensus increased with elevation, which could be the result of the higher elevation areas being driven by less diverse hydrological processes. These findings highlight potential challenges for regional water management, ecosystem health, and flood risk mitigation in the Puget Sound region under future climate conditions.

EarthArXiv

The Great Salt Lake (Utah, USA) acoustic and sedimentary archive of Wasatch Front earthquakes

As the largest low-relief basin in the western United States, the Great Salt Lake offers an opportunity to explore acoustic and sedimentary archives of earthquake ruptures in a shallow terminal basin. Here, we use subbottom compressed high intensity radiated pulse (Chirp) profiles and sedimentary cores to address questions related to how Great Salt Lake sediments respond to surface rupture and earthquake shaking and whether the lake is sensitive to both Great Salt Lake fault (GSLF) and Wasatch fault zone (WFZ) earthquakes. Chirp profiles reveal laterally continuous seismic stratigraphy with vertically displaced strata, onlap surfaces, and growth stratigraphy produced by GSLF surface ruptures. We identify and date two ruptures on the Fremont Island section and three on the Antelope Island section; temporal overlap of these ruptures supports synchronous rupture of both sections. Combined with previous data, our results yield a record of four Holocene surface-rupturing (M W 6.9−7.3) earthquakes on the GSLF with a mean recurrence of ∼3.2 k.y. Sediment cores include ≤41-cm-thick, massive, homogeneous to normally graded disturbance beds that interrupt laminated bioclastic sediment. Disturbance bed correlations yield four lacustrine earthquake deposits since ca. 1.7 ka; the youngest possibly records the most recent GSLF surface rupture whereas older deposits were likely produced by WFZ earthquakes. Modeled historical earthquakes yield a Great Salt Lake sediment disturbance shaking threshold of MMI ∼VI, controlled in part by the lake-bottom expression of the GSLF scarp. Our integration of primary (fault-related) and secondary (shaking-related) earthquake evidence improves our understanding of sediment disturbance processes and the archival potential of low-relief lake basins.

Utah

Ordovician stratigraphy, structure, and karst of the Falling Spring Valley, Alleghany County, Virginia, USA

This one-day trip highlights new findings on a preliminary bedrock geologic map that shows results from ongoing geologic mapping in the Falling Spring Valley of Alleghany County, Virginia, USA, which is the southern end of the larger Warm Springs Valley, an elongated anticlinal valley rimmed by Ordovician and Silurian siliciclastic rocks, and which is famous for its thermal springs. This mapping includes stratigraphic, structural, and karst field and lab research focused on the Ordovician strata exposed in the area, the oldest of which is the dolomitic upper part of the Beekmantown Formation (Lower Ordovician, Darriwilian), and the youngest of which is the Juniata Formation (Upper Ordovician, Katian), a sequence of siliciclastic redbeds. Warm Springs Valley is the location of the only known caves in the eastern United States—three at present—with thermal waters flowing in some of their passages. Stops on the trip will highlight key details from mapping efforts, primarily within the structurally deformed Ordovician carbonate sequence that is exposed in the core and limbs of the anticline, as well as the associated karst features that are developed in those carbonate rocks, including results of recent dye traces and water temperature monitoring that have improved our understanding of the karst hydrogeologic systems developed in these strata.

Virginia

S/P amplitude ratios with Distributed Acoustic Sensing and application to earthquake focal mechanisms

Distributed acoustic sensing (DAS), which transforms a fiber optic cable into an array of high frequency strainmeters, has the potential to help us characterize earthquakes with a dense sampling of measurements. While earthquake focal mechanisms are frequently determined using P -wave polarities and S / P amplitude ratios with inertial seismometers, the dense sampling of DAS over potentially large portions of the focal sphere can aid our solutions. Here, we consider ∼200 regional earthquakes and thousands of S / P measurements on a DAS cable colocated with a network of inertial seismometers near Arcata, California. We demonstrate the S / P ratio measurements made on DAS are similar to those made on the inertial seismometers and can be used to constrain focal mechanism solutions.

California

Small-volume tephra deposits of the May 1924 explosions from Halemaʻumaʻu, Kīlauea volcano, and their origin

More than 50 explosive eruptions occurred from Halemaʻumaʻu at Kīlauea volcano over 17 days from May 11 to 27, 1924. Ballistics weighing as much as 14,000 kg were ejected and most landed within 2 km of the vent. Fine ash made up a major component of the tephra and was dispersed tens of kilometers downwind. Draining of the Halemaʻumaʻu lava lake occurred in late February 1924, with the crater floor eventually subsiding by a further ∼70 m (to ∼180 m below the crater rim) by the time the first explosions took place during the night of May 10–11. The largest explosions occurred on May 17–18 and smaller explosions continued until May 27, at which point Halemaʻumaʻu had more than doubled in width and depth. The explosions generated plumes reaching up to ∼10 km high with ballistics ejected up to 2 km from the crater. Almost 100 years later, we investigate and characterize the preserved tephra deposits within ∼3 km of the 1924 crater rim. Grain size and shape analyses were performed on 202 samples collected from 34 tephra profiles using dynamic image analysis, with a subset of layers from nine tephra profiles used for componentry (200 grains per layer in the 0.5–1 mm size fraction). Additionally, we characterize the average diameters (using the five largest clasts) at 216 locations and measure the average diameters of 2291 ballistics (largest per ∼100 m 2 area). Physical descriptions from fieldwork and grain size distributions were used to subdivide the tephra layers into five lithofacies: coarse homogeneous, fine homogenous, red ash, accretionary lapilli-bearing, and finely laminated. Grain size versus shape data show a range of values that demonstrate most grains are dense, smooth, and equant, in alignment with lithic clasts dominating the tephra componentry. The fine grained and accretionary lapilli-bearing nature of some of these lithofacies confirms that water influenced the style of the explosions. However, we also note juvenile clasts within many of the tephra layers, indicating that many of the layers were formed during phreatomagmatic explosions (sensu stricto), despite the eruptive mechanism being dominantly phreatic. Juvenile clasts are more abundant higher in the tephra profiles, suggesting that juvenile magma was more involved later in the explosive sequence. Thermal and hydrologic modeling indicate that groundwater inflow into a short-lived, small-diameter volcanic conduit (10-m to 120-m-diameter used for modeling) during the 78–85 days preceding the first explosion provides a physically plausible mechanism for this eruptive sequence.

Hawaii

Stream sediment geochemistry in mineral exploration: A review of fine-fraction, clay-fraction, bulk leach gold, heavy mineral concentrate and indicator mineral chemistry

Stream sediment surveys support early-stage reconnaissance mineral exploration and regional assessment programmes, enhanced by recent improvements in analytical method detection limits, continuously improving mineral chemistry, and new approaches to the interpretation of geochemical data. Sediment surveys may be used to predict catchment basin lithology, mineralization type based on pathfinder geochemistry, and geological features based on indicator mineral chemistry. Sediment surveys that target a finer-fraction sediment sample led to the discovery of the La Colosa gold deposit, Colombia. The Batu Hijau porphyry Cu–Au deposit in Indonesia was discovered based on an anomalous clay-sized fraction sample 12 km downstream. In an arid region with poorly developed drainages and minor topographic relief, the Ag-base-metal Navidad District in Argentina was discovered with clay-fraction sediment geochemistry. Heavy mineral concentrate (HMC) sediment surveys that include mineral chemistry determinations have led to global diamond discoveries. HMC surveys contributed to discovery of the Ring of Fire Ni–Cu–PGE and chromite district, Ontario, Canada. Discoveries and geochemical mapping can assist advancement of the application of stream sediment geochemistry in those global areas for which lithologies and deposits are exposed. Stream sediment surveys continue to be one of the most cost-effective geochemical methods for covering large areas for mineral exploration.

Geochemistry: Exploration, Environment, Analysis

A cross-site comparison of ecosystem- and plot-scale methane fluxes across multiple sites

Wetland and upland ecosystems play significant but opposing roles in the global methane (CH 4 ) budget, acting as natural sources and sinks, respectively. Two of the most common approaches for measuring CH 4 fluxes (FCH 4 ) are chambers, which measure fluxes at fine spatial scales (ca. 1 m 2 ), and eddy covariance (EC) towers, which integrate fluxes across larger footprints (ca. 100–10 000 m 2 ). Although chamber and EC observations have been combined in various syntheses and databases to estimate CH 4 budgets, a unified cross-site evaluation of FCH 4 estimates at plot and ecosystem scales is lacking. As a first step toward a systematic spatiotemporal scaling of EC tower and chamber footprints, we quantified differences in site-level aggregate FCH 4 between EC and chamber measurements ( Δ FCH 4 ) across ten wetland and upland sites at half-hourly, hourly, daily, weekly, monthly, and annual timescales. We found that ecosystem-scale median FCH 4 was consistently higher than plot-scale FCH 4 at all temporal scales, with the smallest difference at the daily timescale (multi-site median Δ FCH 4 : 1.36 nmol m −2 s −1 ; median ecosystem-scale FCH 4 = 1.56 nmol m −2 s −1 , median plot-scale FCH 4 = 0.06 nmol m −2 s −1 ) and the largest at annual scales (2.58 nmol m −2 s −1 ; median ecosystem-scale FCH 4 = 25.91 nmol m −2 s −1 , median plot-scale FCH 4 = 6.55 nmol m −2 s −1 ). In general, the agreement between ecosystem- and plot-scale FCH 4 decreased with finer temporal resolution (from Spearman ρ = 0.95 at the annual scale to ρ = 0.65 at the half-hourly scale), while Δ FCH 4 variation was greatest at daily-to-annual scales. Key environmental predictors of Δ FCH 4 across the ten sites included plot-scale spatial heterogeneity, dominant vegetation type, vapor pressure deficit, atmospheric pressure, and friction velocity at the daily and monthly scales. Wind direction was a significant predictor only at the monthly scale, suggesting EC footprint effects at these sites. These findings suggest that accounting for variability in EC footprint extent, chamber measurement placement, and measurement artifacts is key to reconciling multi-scale FCH 4 observations across diverse ecosystems and refining CH 4 budgets.

Biogeosciences