Long-Term Oceanographic Observations in Western Massachusetts Bay Offshore of Boston, Massachusetts: Data Report for 1989-2000
No abstract available.
Data Series↗
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Formation of the Mount Weld rare earth element deposit, Western Australia: A carbonatite-derived laterite
Carbonatite-hosted rare earth element (REE) deposits are the primary source of the world’s light REEs. The Mount Weld REE deposit in Western Australia is hosted in a lateritic sequence that reflects supergene enrichment of the underlying carbonatite. Water-rock interaction is a key to the formation of this world-class deposit. REE enrichment in the laterite is controlled by the breakdown of primary minerals, the release and transport of REEs, and the formation of secondary minerals. Secondary REE-bearing phosphate minerals are the primary REE-host phases in the laterite ore with monazite as the dominant phase; other REE-bearing phases include rhabdophane, cerianite, churchite, florencite, and crandallite subgroup minerals. Profiles through the laterite show that in the REE-rich zone, apatite and primary calcite and dolomite have broken down such that the loss of Ca and Mg, as well as Si and K, leads to a relative increase in the REEs. Sequestering of REEs in secondary mineral phases formed by groundwater further enhances the REE concentration.
Mount Weld Mine↗
The 3D Elevation Program—Supporting the economy of Massachusetts
Introduction Massachusetts extends from the mountains of the Appalachian system in the west of the State to the sandy beaches and rocky shorelines of the Atlantic coast in the east. Inland topographic data support a wide range of important activities, including geologic mapping, transportation planning, forest and wildlife management, quantifying ecological services, water supply protection, commonwealth-wide infrastructure planning, local site planning, and flood-plain management. Nearshore bathymetry can be used to support coastal portions of the Commonwealth by addressing the combined threats of ocean warming, strong storm surge, and rising sea levels. The maintenance and (or) expansion of Massachusetts ports (for instance, Boston, New Bedford) and Cape Cod sediment management depends upon the accurate mapping of bathymetry and the frequent influx of sediment and redeposition. Critical applications that address the broad range of requirements depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features. The 3D Elevation Program (3DEP) is managed by the U.S. Geological Survey (USGS) in partnership with Federal, State, Tribal, U.S. territorial, and local agencies to acquire consistent lidar coverage at quality level 2 or better to meet the many needs of the Nation and Massachusetts. The status of available and in-progress 3DEP baseline lidar data in Massachusetts is shown in figure 1. 3DEP baseline lidar data include quality level 2 or better, 1-meter or better digital elevation models, and lidar point clouds, and must meet the Lidar Base Specification version 1.2 ( https://www.usgs.gov/3dep/lidarspec ) or newer requirements. The National Enhanced Elevation Assessment identified user requirements and conservatively estimated that availability of lidar data would result in at least $1.23 million in new benefits annually to Massachusetts. The top 10 Massachusetts business uses for 3D elevation data, which are based on the estimated annual conservative benefits of 3DEP, are shown in table 2.
Massachusetts↗
Factors contributing to pesticide contamination in riverine systems: The role of wastewater and landscape sources
Wastewater treatment plant (WWTP) discharges can be a source of organic contaminants, including pesticides, to rivers. An integrated model was developed for the Potomac River watershed (PRW) to determine the amount of accumulated wastewater percentage of streamflow (ACCWW) and calculate predicted environmental concentrations (PECs) for 14 pesticides in non-tidal National Hydrography Dataset Plus Version 2.1 stream segments. Predicted environmental concentrations were compared to measured environmental concentrations (MECs) from 32 stream sites that represented a range of ACCWW and land use to evaluate model performance and to assess possible non-WWTP loading sources. Statistical agreement between PECs and MECs was strongest for insecticides, followed by fungicides and herbicides. Principal component analysis utilizing optical fluorescence and ancillary water quality data identified wastewater and urban runoff sources. Pesticides that indicated relatively larger sources from WWTPs included dinotefuran, fipronil, carbendazim, thiabendazole, and prometon whereas imidacloprid, azoxystrobin, propiconazole, tebuconazole, and diuron were more related to urban runoff. In addition, PECs generally comprised a low proportion of MECs, which indicates possible dominant loading sources beyond WWTP discharges. Cumulative potential toxicity was higher for sites with greater ACCWW and/or located in developed areas. Imidacloprid, fipronil, and carbendazim accounted for the largest portion of predicted potential toxicity across sites. The chronic aquatic life toxicity benchmarks for freshwater invertebrates were exceeded for 82 % of the imidacloprid detections ( n = 28) and 47 % of the fipronil detections ( n = 19). These results highlight the ecological implications of pesticide contamination from WWTP discharges and also the potential legacy effects from accumulated soil and groundwater sources. Pesticide management strategies that mitigate both current and historical impacts may improve the health of aquatic ecosystems.
Potomac River watershed↗
A newly identified creeping strand of the Concord fault, San Francisco Bay Area
The Concord fault constitutes a major branch of the Pacific–North America transform plate boundary in Northern California, bridging the strike‐slip Bartlett Springs ‐ Green Valley Fault system to the north with the Greenville and Calaveras Faults to the south. Like many faults in the San Francisco Bay Area its long‐term slip is partially accommodated by aseismic slip (creep). Although creep has been recognized and monitored on the northern half of the fault for decades, the precise location of the southern half of the fault and its slip rate—whether accommodated seismically or aseismically—has remained enigmatic. How slip transfers between the Concord and Greenville or Calaveras faults to the south remains an outstanding question. New field observations presented here indicate that the active trace of the fault south of downtown Concord is not where previously interpreted and is indeed actively creeping. We report observations of shallow creep continuing >7 km farther south along the Concord fault than previously reported, along a fault strand not previously recognized for most of its length. This is evident as right‐laterally deflected concrete curbs and sidewalk slabs on both sides of every street that crosses the fault at a high angle in southeast Concord and northeast Walnut Creek. We document the magnitude and location of these deflections to estimate accumulated right‐lateral aseismic slip expressed in engineered structures. Offsets of these piercing lines range from 8 to 18 cm, over widths varying from narrow breaks along centimeter‐scale concrete joints to 10‐m‐wide zones of deflection. Significantly, this active trace is ∼400 m west of where the Quaternary active trace has previously been inferred, placing it within—rather than bounding—the built area of suburban Concord. Slip along the fault has already caused infrastructure damage. These results revise our understanding of the southern Concord fault and help constrain its seismic potential.
California↗
Mechanics and statistics of postseismic shaking
Analysis of two weeks of continuous post-seismic shaking after the 2019 M7.1 Ridgecrest, CA earthquake sequence using 4 nearby borehole seismometers reveals that continuous ground motions decay as Omori’s law in time and follow the Gutenberg-Richter distribution in logarithmic amplitude. The measured temporal decay in amplitudes agrees with predictions of the rate-and-state framework and indicates shaking amplitudes are proportional to the velocity of afterslip. Our ground motion-based statistical framework provides a basis to forecast shaking intensity in the minutes to hours after a large earthquake.
California↗
Re-Os geochronology of molybdenite by LA-ICP-MS/MS
Re-Os geochronology is a powerful tool to directly date sulphide mineralisation using phases such as molybdenite, pyrite and chalcopyrite. We present a snapshot of a method in development utilizing laser ablation inductively coupled-plasma ‘triple quad’ mass spectrometry (LA-ICP-MS/MS) for Re-Os geochronology of molybdenite. While traditional LA-(MC)-ICP-MS measurements are limited by the >90% isobaric interference correction of parent radioactive 187 Re on radiogenic daughter 187 Os, the MS/MS technology minimizes this correction through careful instrument tuning and use of a (CH 4 + H 2 + He) reaction gas mixture to mass shift 187 Os away from 187 Re. We demonstrate the potential of the MS/MS technique by presenting robust Re-Os dates for three different molybdenite samples ranging in age from ~28 to 1520 Ma.
Conference Paper↗
A model uncertainty quantification protocol for evaluating the value of observation data
The history-matching approach to parameter estimation with models enables a powerful offshoot analysis of data worth—using the uncertainty of a model forecast as a metric for the worth of data. Adding observation data will either have no impact on forecast uncertainty or will reduce it. Removing existing data will either have no impact on forecast uncertainty or will increase it. The history-matching framework makes it possible to perform this quantitative analysis leveraging the connections among observations, model parameters, and model forecasts. We show this behavior on a specific groundwater flow model of the Mississippi Alluvial Plain and show where the analysis can be informative for considering the potential design of an observation network based on existing or potential observations.
Scientific Investigations Report↗
Trends and environmental impacts of virtual water trade
Virtual water describes water embedded in the production of goods and offers meaningful insights about the complex interplay between water, trade and sustainability. In this Review, we examine the trends, major players, traded products and key drivers of virtual water trade (VWT). Roughly 20% of water used in global food production is traded virtually rather than domestically consumed. As such, agriculture dominates VWT, with livestock products, wheat, maize, soybean, oil palm, coffee and cocoa contributing over 70% of total VWT. These products are also driving VWT growth, the volume of which has increased 2.9 times from 1986 to 2022. However, the countries leading VWT contributions (with China, the United States, the Netherlands, Germany and India accounting for 34% of the global VWT in 2022) have remained relatively stable over time, albeit with China becoming an increasingly important importer. VWT can mitigate the effects of water scarcity and food insecurity, although there are concerns about the disconnect between consumers and the environmental impacts of their choices, and unsustainable resource exploitation. Indeed, approximately 16% of unsustainable water use and 11% of global groundwater depletion are virtually traded. Future VWT analyses must consider factors such as water renewability, water quality, climate change impacts and socioeconomic implications.
Nature Reviews Earth & Environment↗
Non-radiometric borehole geophysical detection of geochemical halos surrounding sedimentary uranium deposits
Roll-type uranium deposits are formed by the concentration of uranium by ground water in geochemical cells. Non-uranium minerals having different solubilities may be deposited ahead of or behind the uranium minerals, forming halos that surround the ore. In addition, oxidizing and reducing environmental conditions may cause zones of mineral alteration to develop beyond the limits of the uranium deposit. Certain physical property anomalies that are commonly associated with halos can be detected by relatively fast and inexpensive borehole geophysical measurements made either in individual holes, or between two adjacent holes. Borehole measurements that have been found to be useful include electrical resistivity, induced polarization, and magnetic susceptibility. Electrical resistivity is increased by the presence of calcite and other cementing minerals that sometimes create permeability barriers in the neighborhood of uranium deposits. Induced polarization (IP) response is increased by sulfide and clay minerals that are commonly found in anomalous concentrations near roll-type deposits. Magnetic susceptibility is usually decreased by the oxidation of magnetite to hematite or limonite in the zone of chemical alteration that is left as a trail behind roll fronts. Borehole measurements of electrical resistivity, induced polarization and magnetic susceptibility were made in the vicinity of a uranium roll-type deposit in south Texas. Results indicate that mineral halos can be detected by borehole measurements made. in wide-spaced drill holes, and that the total amount of drilling needed to find a deposit can be reduced substantially by this exploration approach.
Open-File Report↗
Surface rupture and slip distribution of the 2025 Mw7.7 Mandalay earthquake and updated length scaling of supershear earthquakes
The 2025 M w 7.7 Mandalay, Burma (Myanmar), earthquake ruptured 475 km of the central Sagaing fault and is the longest continental strike-slip rupture on record. The observed rupture length is 1.6–4.7 times the value expected (100–300 km) from existing length-magnitude scaling relations for strike-slip earthquakes. The earthquake resulted from shallow dextral faulting and ruptured bilaterally with supershear speeds south of the epicenter, rupturing close to three major cities in Myanmar and exposing over six million people to violent or extreme shaking. We report on the surface rupture character, length, and slip distribution based on sub-pixel correlation of Sentinel-2 (10 m) and Planet Dove (3 m) optical images and visual analysis of SkySat and WorldView (0.3–0.5 m) optical images. The earthquake had moderate surface slip (average = 3.3 m, maximum = 5.6 m, 25–75% range = 3.0–4.0 m), narrow deformation zone width (1–10 pixels in sub-pixel correlation and up to 190 meters for the detailed surface rupture mapping), and simple fault geometry (no stepovers or large changes in strike, 87% of the rupture that was mapped in detail is single-stranded). We attribute the extreme length of the Mandalay earthquake to supershear rupture speed, simple fault geometry, narrow down-dip width, and moderate surface slip. Based on a compilation of 25 supershear strike-slip earthquakes ( M w 6.5–8.6; 1979–2025), we find that the rupture length of supershear earthquakes does not fit empirical scaling relationships for strike-slip earthquakes that predict length from magnitude. A length-magnitude scaling relationship based on supershear earthquakes has a best fit of log 10 (surface rupture length) = 0.89 M w – 4.44, indicating that supershear earthquakes tend to be longer than their subshear counterparts for any given magnitude and thus may expose a greater population to shaking.
Mandalay↗
Geology and coal resources of the Gulnare, Cuchara Pass, and Stonewall area, Huerfano and Las Animas Counties, Colorado
No abstract available.
Colorado↗
Nanometer-scale relationships between sedimentary organic matter molecular composition, fluorescence, cathodoluminescence, and reflectance: The importance of oxygen content at low thermal maturities
Molecular characterization of sedimentary organic matter (SOM), termed macerals, is a common goal when seeking to understand petroleum generation as well as other geologic processes in deep time. However, unambiguous measurement of discrete macerals is challenging due to the small size of organic particles in sedimentary rocks, the proximity of different organic matter types to one another, mineral-organic matter interactions, and maceral mixing that occurs during SOM isolation prior to ex situ analysis. The recent advent of infrared spectrometers capable of nanometer-scale resolution and the application of these technologies to geologic samples has enabled advances in rapid, in situ molecular characterization of SOM allowing for insights into paleoenvironmental processes, such as organic matter productivity and preservation, among others. Here we employ one such technology, optical photothermal infrared (OPTIR) spectroscopy, to map SOM functional group distributions at 500-nm resolution in a sample from the Lower Cretaceous Sunniland Limestone of the South Florida Basin. Examined fields of view include occurrences of amorphous organic matter (AOM), inertinite, micrinite, solid bitumen, telalginite, and vitrinite. OPTIR data from these macerals are compared against traditional organic petrographic data from the same organic grains including fluorescence intensity and white light reflectance as well as against cathodoluminescence response, an emerging organic petrographic approach. Maceral oxygen content (using carbonyl functional group abundance as a proxy) is observed to vary widely between maceral types but correlates strongly with fluorescence and cathodoluminescence intensity as well as against reflectance. These findings highlight the important role that oxygen content plays in determining the optical properties of SOM and further demonstrate the ability of OPTIR to discriminate subtle molecular differences between SOM types.
Organic Geochemistry↗
Natural attenuation of chlorinated volatile organic compounds in ground water at Area 6, Naval Air Station Whidbey Island, Washington
Natural attenuation is a viable alternative to pump and treat for meeting remediation objectives in the vicinity of the southern contaminant plume. The combination of historically low contaminant concentrations in ground water, a landfill cap that limits source area contributions, favorable conditions for degradation of VC, and a relatively long downgradient distance to potential receptors are all favorable for natural attenuation as a remediation alternative. Natural attenuation could effectively meet all but one remediation goal that extraction wells PW- 2, PW-4, PW-6, PW-7, PW-8 and PW-9 are currently being employed to meet. The goal of preventing migration of all VC across the site boundary could not be met by natural attenuation. Some VC would migrate south of the Navy boundary, but the potential for subsequent VC mineralization downgradient of the base and the existing institutional controls would result in minimal additional risk from using natural attenuation. In the western contaminant plume natural attenuation is not currently a viable alternative to pump and treat for meeting remediation objectives. There is a possibility that rates for reductive dechlorination of TCE and TCA could increase substantially if the plume was allowed to migrate beneath the Oak Harbor landfill, but there are not enough data to be certain of such an increase. TCA and TCE concentrations at the leading edge of the western plume need to be reduced to at least 25 and 40 µg/L, respectively, to be protective of potential downgradient receptors. Source area TCA and TCE concentrations have decreased substantially over the past ten years, and the extraction wells PW-3 and PW-5 in particular are removing a significant mass of contaminants from ground water, so natural attenuation may be a viable alternative for the western plume in the future. There would be some possible side benefits of using natural attenuation as an alternative to pump and treat in the southern contaminant plume. The first would be that the resulting decrease in the amount of treated water that would need to be recharged in the swale north of the landfill would result in less off-base migration of contamination across the western site boundary. The second benefit would be a substantial reduction in the amount of dissolved iron and manganese being extracted from the shallow aquifer and run through the treatment system. Removing that source of operation and maintenance problems would result in more effective containment and removal of contamination in the western contaminant plume. The most critical data gap identified in this evaluation is the paucity of contaminant chemistry information downgradient of the Navy boundary in the vicinity of the southern contaminant plume. Without such data, the behavior of the plume and the protectiveness of natural attenuation to downgradient receptors cannot be verified, and field attenuation rates for VC cannot be determined directly. The existing long-term monitoring plan would need to be reviewed and revised if natural attenuation is selected as a remedy for the contamination in the southern plume. In particular, additional performance monitoring wells may be required downgradient of the property.
Washington↗
The use of fluorite geochemistry and machine learning to identify critical mineral systems
Fluorite (CaF 2 ) is a potential pathfinder to critical mineral and rare earth element (REE) deposits but its application has been limited to a narrow range of mineralization types. I show that fluorite is a robust recorder of mineralization fertility by applying statistical and machine-learning methods to a new global fluorite geochemical database. Distinct median rare earth and trace element patterns are observed among deposit types and genetic environments. Fluorite associated with carbonatites and REE deposits are relatively enriched in Sr and have minimal Eu anomalies. These characteristics define new bivariate discrimination diagrams that correctly identify 78% of carbonatite-related fluorite and 88% of fluorite from REE deposits. Random forest classifiers were developed for a wide range of mineralization types and genetic settings. Trained solely on rare earth element patterns, these models achieve accuracies of 77–79%. Higher classification accuracies (up to 88–96%) are obtained when including elements such as Sr, highlighting the significance of trace elements for optimal fluorite classification. The recognition of diagnostic fluorite compositional fingerprints, particularly in REE-fertile systems, underscores its potential as a pathfinder and indicator for critical mineral exploration in F-bearing environments.
Mineralium Deposita↗
How does the onset of offset influence geologic slip rates?
Geologic slip rates are typically based on the displacement accrued by a geomorphic or stratigraphic feature and the age of the offset feature. Because slip rates are commonly calculated by dividing the displacement of a faulted marker by its age, they contain two open time intervals: the elapsed time between the age of an offset feature and the age of the earthquake that displaced the feature, and the time between the present‐day and the most recent earthquake. Here, we explore the influence of including unconstrained open intervals in geologic slip rate calculations. We test the degree to which these open intervals affect geologic slip rates and their uncertainties, and we find that their influence depends primarily on mean earthquake recurrence intervals (RIs). Slip rates on faults with longer RIs, such as the Wasatch fault, can be greatly influenced by an increase of up to 20% when accounting for open intervals. In contrast, slip rates on faults with shorter RIs, such as the San Andreas fault, are only slightly influenced by the assumption that slip rates calculated over open intervals approximate those calculated over closed intervals. Our analyses indicate that faults with moderate slip rates (∼0.2–5 mm/yr) are sensitive to both open interval effects themselves, as well as methods to quantify and account for these effects. We re‐evaluate how slip rates are calculated and defined in displacement–time space using published deformation records. We explore the utility of assigning a probability distribution to the initiation of offset of the oldest faulted feature and the timing of the most recent earthquake (MRE). We find that calculating geologic slip rates without using probability distributions that capture the timing of the MRE and the onset of offset of the oldest faulted feature, especially on slow‐to‐moderate slip rate faults, can lead to systematic underestimation of average geologic slip rates.
Seismological Research Letters↗
Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee
Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.
Tennessee↗