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Bedrock geologic map of the Bellows Falls 7.5- x 15-minute quadrangle, Windham and Windsor Counties, Vermont, and Sullivan and Cheshire Counties, New Hampshire

Introduction The bedrock geology of the Bellows Falls 7.5- x 15-minute quadrangle, Vermont and New Hampshire, consists of polydeformed Ordovician to Devonian metasedimentary, metavolcanic, and metaplutonic rocks of the Connecticut Valley trough, Bronson Hill anticlinorium (or Bronson Hill terrane), and the Central Maine terrane. Previous work in this area includes a 1:62,500-scale published map and text (1946), State geologic maps of New Hampshire (1997) and Vermont (2011), and various maps and reports presented largely as parts of field trip guidebooks. A provisional open-file map of the geology of the Vermont part of the Bellows Falls 7.5- x 15-minute quadrangle, completed in 1997, is incorporated and revised on this map based on additional fieldwork. This study recognizes three major structural levels from west to east and from lowest to highest: (1) autochthonous rocks of the Connecticut Valley trough; (2) allochthonous rocks of the New Hampshire sequence and Bronson Hill arc in the Monroe thrust sheet (or nappe), including the Skitchewaug nappe; and (3) allochthonous rocks of the Fall Mountain thrust sheet or nappe.

New Hampshire, Vermont

U.S. Geological Survey National Groundwater Climate Response Network

What is the U.S. Geological Survey National Groundwater Climate Response Network? The U.S. Geological Survey’s (USGS) National Water Monitoring Network is a network of networks that includes the Climate Response Network (CRN). The CRN is a network of wells selected to monitor the effects of climate variability, including droughts, on groundwater systems within the United States, Puerto Rico, and the U.S. Virgin Islands. The primary purpose of the CRN is to monitor these effects on groundwater levels in unconfined or near-surface confined aquifers that are minimally affected by pumping or other human-induced stresses.

Fact Sheet

Assimilation of reduced carbon triggers platinum alloy saturation in mafic and ultramafic magmas

It is generally observed that magmatic sulfide ores have higher ratios of Pd/Pt than the mantle-like values of their parental magmas. This discrepancy has defied simple explanation because the partitioning behavior of both elements between sulfide and silicate liquids is very similar. Assimilation of sulfur- and carbon-rich country rocks by mafic and ultramafic magmas is considered a critical, if not essential, step in the formation of magmatic base metal sulfide deposits. Although there is general consensus that the assimilation of external sulfur and carbon promotes sulfide saturation, the effect of carbon assimilation on the solubilities of platinum-group elements in natural S-bearing silicate melt has been overlooked. In this study, we investigate the variations of platinum and palladium solubilities during assimilation of graphite and methane through thermodynamic modeling, in comparison with data from an array of highly distinctive magmatic sulfide ore systems representing ages from Archean to Paleozoic, melt compositions from komatiite to basalt, and magmatic settings including lavas, hypabyssal intrusions, plutonic continental arc roots, and plutonic layered intrusions, namely: Raglan, Norilsk-Talnakh, Lac des Iles, and the J-M Reef of the Stillwater Complex. We model assimilation-fractional crystallization processes to estimate the reduction of oxygen fugacity ( ⁠fO2⁠ ) of the melt due to incorporation of graphite and methane. The simulations show that although Pd remains highly soluble during the progressive assimilation of reduced carbon, Pt solubility decreases significantly as the silicate melt becomes increasingly reduced. With less than 8 % of sediment assimilation, Pt alloy may saturate and then deviate from sulfide-undersaturated silicate melts, concomitantly increasing the Pd/Pt value of the remaining melts of the Raglan and Norilsk-Talnakh systems. For the Lac des Iles and Stillwater systems, a higher extent of assimilation is needed to reach Pt saturation because of the relatively carbon-poor nature of the lower crustal rocks. The assimilation of methane volatiles is shown to be more effective than graphite assimilation, and it provides a pathway to Pt alloy fractionation in the absence of detectable amounts of bulk host-rock assimilation. High Pd/Pt values have been documented in many world-class magmatic sulfide deposits whose parental magmas have demonstrably experienced crustal contamination. Our model suggests that although anomalous Pd/Pt values may be explained by other mechanisms such as incongruent melting of preexisting sulfide or differences in the diffusivities of the metals within achieving equilibration, the assimilation of graphite or methane may play an important role in the global occurrence of magmatic sulfide ores with elevated Pd/Pt values.

Economic Geology

Assessment of the interconnection between Tampa Bay and the Floridan aquifer system: Historical groundwater data compilation and analysis, 1976–2022

The U.S. Geological Survey used existing data collected after the last major navigational channel modification in the mid-1980s to investigate groundwater levels and chloride concentrations in wells in the Floridan aquifer system and other aquifers beneath and near Tampa Bay. Tampa Bay is located on the west-central coast of Florida and provides access for commercial shipping. In 2021, the U.S. Army Corps of Engineers began to investigate alternatives to improve the efficiency of the deep-draft navigation channels within Tampa Bay, reduce costs, improve safety, and analyze the implications of modifying navigational channels. The Floridan aquifer system underlies Tampa Bay and is the primary source of public water supply in the region. Modifications to the channels have the potential to expose the Floridan aquifer system to the saltwater in Tampa Bay, with the potential to increase salinity in wells in the region. Other factors affecting the groundwater levels and the location of the freshwater/saltwater interface were also examined, including changes in sea level, groundwater extraction, and variations in climate. Groundwater levels and well-construction reports were used to identify whether different aquifer units are well-connected. Twelve wells had available data before and after the last major channel modifications, which took place in the 1980s, with six datasets of chloride concentration available in areas along the northern and eastern coastline of Tampa Bay, which is nearest to historical dredging activities. Of these six, Kendall’s τ and p -values indicated increasing trends in chloride concentration for three datasets (TR 11-2, TR 10-2, 51), no trend in chloride concentration for two datasets (TR 9-3, 50), and a decreasing trend in chloride concentration for one dataset (TR 9-1). The upward trends in chloride concentration observed for TR 10-2 and 51 are likely the result of changes in local groundwater withdrawals. Well TR 11-2 had a gradual increasing trend in chloride concentration, fresh groundwater throughout the period of record, and a 3- to 4-foot increase in hydraulic head during the period of record, possibly caused by the construction and control of the Tampa Bypass Canal, resulting in changes to the regional potentiometric surface.

Florida

Ground-motion aleatory-variability models for Puerto Rico and the U.S. Virgin Islands

I develop independent logic trees for aleatory variability for crustal and subduction-zone (interface and intraslab) earthquakes for seismic hazards analyses in Puerto Rico and the U.S. Virgin Islands (PRVI) from existing suites of ground-motion models (GMMs) and from ground-motion datasets, including a regional PRVI dataset. The aleatory variability models are parameterized using a partially nonergodic partitioning of standard deviation that consists of independently developed between-event ( ), site-to-site ( ), and event-corrected single-station ( ) standard deviation components. The effects of nonlinear site response on aleatory variability are incorporated through additional terms that modify the standard deviation components. Because one goal of this work is to develop independent logic trees for aleatory variability that synthesize the aleatory variability models from GMMs, I make use of the functional forms of the input GMMs. The PRVI dataset contains a limited number of stations with high-quality site metadata and does not contain records from earthquakes with magnitudes greater than 6.1, so I choose not to develop the aleatory variability models from the regional dataset alone. Instead, the standard deviation components from regional ground-motion data are evaluated against the components derived from GMMs and from available global datasets, and regionalized standard deviation components are incorporated where there is evidence that regional effects exhibit substantial differences. The resulting logic trees for aleatory variability consist of models of and that are consistent with semiempirical GMMs for active crustal and subduction-zone regimes, and two alternative models of , including one model that exhibits site-to-site variability informed by PRVI data, with values that exceed global models. The aleatory variability models may be considered in future hazards assessments in PRVI to simplify the hazard calculations, to incorporate regional ground-motion variability effects, and to enable direct logic-tree weighs of aleatory variability.

Puerto Rico, U.S. Virgin Islands

Neogene hydrothermal Fe- and Mn-oxide mineralization of Paleozoic continental rocks, Amerasia Basin, Arctic Ocean

Rocks dredged from water depths of 1,605, 2,500, 3,300, and 3,400 m in the Arctic Ocean included Paleozoic continental rocks pervasively mineralized during the Neogene by hydrothermal Fe and Mn oxides. Samples were recovered in three dredge hauls from the Chukchi Borderland and one from Mendeleev Ridge north of Alaska and eastern Siberia, respectively. Many of the rocks were so pervasively altered that the protolith could not be identified, while others had volcanic, plutonic, and metamorphic protoliths. The mineralized rocks were cemented and partly to wholly replaced by the hydrothermal oxides. The Amerasia Basin, where the Chukchi Borderland and Mendeleev Ridge occur, supports a series of faults and fractures that serve as major zones of crustal weakness. We propose that the stratabound hydrothermal deposits formed through the flux of hydrothermal fluids along Paleozoic and Mesozoic faults related to block faulting along a rifted margin during minor episodes of Neogene tectonism and were later exposed at the seafloor through slumping or other gravity processes. Tectonically driven hydrothermal circulation most likely facilitated the pervasive mineralization along fault surfaces via frictional heating, hydrofracturing brecciation, and low- to moderate temperature Fe- and Mn-rich hydrothermal fluids, which mineralized the crushed, altered, and brecciated rocks.

Geochemistry, Geophysics, Geosystems

Leveraging wildfire to augment forest management and amplify forest resilience

Successive catastrophic wildfire seasons in western North America have escalated the urgency around reducing fire risk to communities and ecosystems. In historically frequent-fire forests, fuel buildup as a result of fire exclusion is contributing to increased fire severity. The probability of high-severity fire can be reduced by active forest management that reduces fuels, prompting federal and state agencies to commit significant resources to increase the pace and scale of fuel reduction treatments. However, lower severity areas of wildfires also have the potential to act as “treatments,” and even catastrophic fires with large areas of high severity can still have substantial areas of lower severity fire that may be improving forest conditions locally. We quantified active management and wildfire severity across yellow pine and mixed conifer (YPMC) forests in the Sierra Nevada of California over a 22-year period (2001–2022). We did not detect increases in the area treated through time, but the area of beneficial wildfire (low to moderate severity) increased substantially, exceeding active treatment area in 8 of 22 years. Overall, beneficial wildfire treated ~17% more area than all treatments combined, and roughly four times more area than fire-related treatments alone. We then used disturbance history to evaluate resistance to high-severity wildfire and forest loss across the YPMC range. Of the 2.3 million ha YPMC of forests in 2001, 20% lost mature forests due to high-severity fire by 2022, which is nearly half of all YPMC area burned. Most of the landscape (47%) remains at risk of high-severity fire because it had no restorative disturbances, but 33% of the study area has some level of resistance to high-severity wildfire. In these areas, resistance will need to be enhanced and maintained over time via active management or managed wildfire, but these treatment needs will likely outpace capacity even under optimistic implementation scenarios. Given limited resources for implementing active management and the likelihood of a more fiery future, incorporating beneficial wildfire into landscape-level treatment planning has the potential to amplify the impact of active management treatments.

California, Nevada

Reduced injection rates and shallower depths mitigated induced seismicity in Oklahoma

The proximity of wastewater disposal to the Precambrian basement is a critical factor influencing induced earthquake rates in the Central United States, but the impact of reducing injection depths has not been widely demonstrated. Beginning in 2015, state regulatory efforts in Oklahoma and Kansas mandated that wells injecting into the lower Arbuckle Group, a basal sedimentary unit, be backfilled with cement (i.e. “plugged back”) so that they inject into shallower formations. This plug back activity gives us a unique opportunity to investigate the relationship between injection depth and induced seismicity rate. To evaluate the impact that decreased injection rates and plug backs had on the seismicity rates, we create a suite of rate-state earthquake models. Observed seismicity rates are best fit when only lower Arbuckle volumes are considered, suggesting the lower Arbuckle injectors were primarily responsible for the seismicity and that plug backs were effective at isolating the injected volumes to shallower formations. Our models demonstrate that if these wells had not been plugged back, seismicity rates would be multiple times larger than they are today. We find that the combination of well plug backs and injection volume decreases can be effective strategies for reducing induced seismicity rates.

Oklahoma

Integrating Sr isotopes, microchemistry, and genetics to reconstruct Salmonidae species and life history

Recent approaches to fisheries research emphasize the importance of the coproduction of knowledge in building resilient and culturally mindful fisheries management frameworks. Despite widespread recognition of the need for Indigenous knowledge and historical reference points as baseline data, archaeological data are rarely included in conservation biology research designs. Here we propose a novel multiproxy method to learn from former fisheries stewards by generating archaeological data on past salmonid population parameters. We used a newly developed, high throughput qPCR (HT-qPCR) chip, originally designed for environmental DNA (eDNA), for species identification of archaeological salmonid vertebrae. We combine this with the laser ablation split-stream (LASS) approach to identify ocean-migration versus freshwater residency. We test this multidisciplinary approach using both contemporary and archaeological salmonid samples and new radiocarbon dates from the Tronsdal Site on the Skagit River, Washington State, USA. This is a useful approach for extracting information about Salmonidae species and life history diversity from archaeological remains to reconstruct historic baselines for several population parameters in anadromous species with long periods of freshwater residency. The approach outlined in this paper may be particularly useful for research investigating past fisheries dynamics, offering hundreds to thousands of years of temporal depth for modern fisheries management, harvest policies, restoration ecology, and conservation biology.

Idaho, Oregon, Washington

Leachate plumes in ground water from Babylon and Islip landfills, Long Island, New York

Landfills operated by the Towns of Babylon and Islip in southwest and central Suffolk County contain urban refuse, incinerated garbage, and scavenger (cesspool) waste; some industrial refuse is deposited at the Babylon site. The Islip landfill was started in 1933, the Babylon landfill in 1947. The landfills are in contact with and discharge leachate into the highly permeable upper glacial aquifer (hydraulic conducitvity 190 to 500 ft/d [feet per day]). The aquifer is 74 feet thick at the Babylon landfill and 170 feet thick at the Islip landfill. The leachate-enriched water occupies the entire thickness of the aquifer beneath both landfills, but hydrologic boundaries retard downward migration of the plumes to deeper aquifers. The Babylon plume is 1,900 feet wide at the landfill and narrows to about 700 feet near its terminus 10,000 feet from the landfill. The Islip plume is 1,400 feet wide at the landfill and narrows to 500 feet near its terminus 5,000 feet from the landfill. Hydrochemical maps and sections show the distribution of the major chemical constituents of the plumes. The most highly leachate-enriched ground water obtained was from the Babylon site; it contained 860 mg/L (milligrams per liter) sodium, 110 mg/L potassium, 565 mg/L calcium, 100 mg/L magnesium, 2,700 mg/L bicarbonate, and 1,300 mg/L chloride. Sulfate was notably absent or in low concentration in most parts of both plumes. Nitrogen in plume water was mostly in the form NH4+, and concentrations as high as 90 mg/L were found; concentrations of nitrogen as N in the plume were less than 10 mg/L. As much as 440 mg/L iron and 190 mg/L manganese were found in the leachate-enriched water. Samples were also tested for arsenic, boron, cadmium, cobalt, chromium, copper, mercury, nickel, lead, selenium, strontium, and zinc. Boron was more or less ubiquitous and was found in concentrations as high as 2 mg/L. Organic carbon was found in concentrations as high as 2,250 mg/L in the most highly leachate-enriched water but attenuated rapidly to less than 20 mg/L. Dissolved-solids concentrations near the landfills were between 400 and 3,000 mg/L at Babylon and between 500 and 1,500 mg/L at Islip. Ground-water temperatures near the landfills exceed those in ambient water by as much as 7°C at Babylon and 16°C at Islip. Heat contributed by the landfills was mostly dissipated within 0.4 mi of the landfill, butat Islip, the warm leachate-enriched water extended 0.5 mi downgradient. The entrance of leachate into the less dense ground water as pulsations after rainfall may explain the presence of high leachate enrichment near the bottom of the aquifer. A comparison of the physical characteristics of leachate-enriched ground water with those of ambient water suggests that the downward movement of leachate results from its greater density. Simulation of the movement and dispersion of the Babylon plume with a mathematical dispersion model indicated the coefficient of longitudinal dispersion to be about 60 ft 2 /d (feet squared per day) and the ground-water velocity to be 1 ft/d. However, the velocity determined from the hydraulic gradient and public-supply wells in the area was 4 ft/d, which would cause a plume four times as long as that predicted by the mathmatical dispersion model. At the Islip site, the plume was one-third the length calculated on the basis of the age of the landfill. The shortness of the plumes has not been explained; it may be a result of the leachate's having been too dilute to form a plume during the early years of the landfills.

New York

Development of USGS NSHMs: Do small changes in hazard imply small changes in risk?

One of the flagship products from the U.S. Geological Survey (USGS) is the National Seismic Hazard Model (NSHM). Since 1976, the NSHM has been periodically updated to reflect newly published earthquake science and provide probabilistic estimates of seismic hazard for the United States. During each update cycle, alternative models are deliberated, analyzed, and documented through logic trees and their corresponding logic tree branch weights. For example, the decision to modify a logic tree branch weight may be influenced by sensitivity analyses of the logic tree branches in their effects on the mean hazard. However, do small changes in traditional measures of hazard imply small changes in risk? In this study, we make use of two update cycles of the USGS NSHMs and a National Bridge Inventory (NBI) from the Federal Highway Administration (FHWA) to explore the preceding question. Specifically, we first identify geographic locations in the conterminous United States in which the change in hazard from one cycle to another is relatively small. Next, we model the seismic risk to highway bridges for these locations and for each update cycle, while simultaneously distinguishing low hazard environments from high hazard environments. These data enable quantitative analysis of how much changes in risk can be expected given small changes in hazard, investigating the importance of risk models in decision-making during development of the USGS NSHMs.

Conference Paper

The effects of line simplification on planform geometry

Data on maps should retain accuracy regardless of scale. Yet, as cartographic lines are generalized, there can be impacts on properties such as topology, density, and planform geometry. Here, we investigate the use of the Scale Specific Sinuosity (S3) metric (Stanislawski et al., 2023) to evaluate the effects of line simplification on planform geometry, which is the bends of streams in map view. We employ an open-source Python S3 workflow to characterize the geometry of five diverse stream channels in the United States. The original data are extracted from the U.S. Geological Survey National Hydrography Dataset 1:24,000-scale vector data (U.S. Geological Survey, 2000) (Table 1), and the simplification is done using the Visvalingam and Whyatt method (2017) with a simplification tolerance of 0.5, 1.0, 1.5, and 2.0 km. The S3 analysis is calculated at each level of simplification and S3 derivatives are generated. Derivatives include measures of sinuosity, fractal dimension, and the dominant bend wavelength. The findings show that the change in planform geometry is scale-dependent, though simplification will have little effect on straighter lines. The change becomes more apparent in complex lines as the degree of simplification aligns with the scale of the dominant bend geometries. These logical conclusions are evidence that the S3 is a useful metric for automated characterization of bend geometry regardless of line complexity.

Conference Paper

Critical minerals memory match game

An educational information packet about the 2025 List of Critical Minerals, which includes a memory match game about select critical minerals and how they are used.

General Information Product

Layered intrusions in the Precambrian: Observations and perspectives

Layered intrusions are plutonic bodies of cumulates that form by the crystallization of mantle-derived melts. These intrusions are characterized by igneous layering distinguishable by shifts in mineralogy, texture, or composition. Layered intrusions have been fundamental to our understanding of igneous petrology; however, it is their status as important repositories of critical metals – such as platinum-group elements, chromium, and vanadium – that has predominantly driven associated research in recent decades. Many layered intrusions were emplaced during the Precambrian, predominantly at the margins of ancient cratons during intervals of supercontinent accretion and destruction. It appears that large, layered intrusions require rigid crust to ensure their preservation, and their geometry and layering is primarily controlled by the nature of melt emplacement. Layered intrusions are best investigated by integrating observations from various length-scales. At the macroscale, intrusion geometries can be discerned, and their presence understood in the context of the regional geology. At the mesoscale, the layering of an intrusion may be characterized, intrusion-host rock contact relationships studied, and the nature of stratiform mineral occurrences described. At the microscale, the mineralogy and texture of cumulate rocks and any mineralization are elucidated, particularly when novel microtextural and mineral chemical datasets are integrated. For example, here we demonstrate how mesoscale observations and microscale datasets can be combined to understand the petrogenesis of the perplexing snowball oiks outcrop located in the Upper Banded Series of the Stillwater Complex. Our data suggest that the orthopyroxene oikocrysts did not form in their present location, but rather formed in a dynamic magma chamber where crystals were transported either by convective currents or within crystal-rich slurries. Critical metals may be transported to the level of a nascent intrusion as dissolved components in the melt. Alternatively, ore minerals are entrained from elsewhere in a plumbing system, potentially facilitated by volatile-rich phases. There are many ore-forming processes propounded by researchers to occur at the level of emplacement; however, each must address the arrival of the ore mineral, its concentration of metals, and its accumulation into orebodies. In this contribution, several of these processes are described as well as our perspectives on the future of layered intrusion research.

Precambrian Research

Tracing mercury from land to river: Global sources, retention, and implications for sustainability

Mercury (Hg) pollution in river systems is a global sustainability challenge. Yet the transport, transformation, and retention of Hg within global rivers remain poorly quantified, particularly in regions with sparse observations such as Southeast Asia and Africa, hindering effective pollution mitigation and reinforcing geographic inequities in scientific knowledge and environmental governance. Here, we present the first global, high-resolution simulation of riverine Hg dynamics using a process-based model that traces Hg from land-based sources through river networks to the ocean. Under a realistic scenario, we estimate that ~1,900 megagrams per year (Mg/yr) of Hg enters global rivers, including 1,500 Mg/yr from human-induced sources and 400 Mg/yr from soil erosion. Nearly half of this flux (~1,000 Mg/yr) is retained in reservoirs and dams, which act as major sinks. While such retention limits downstream delivery to the oceans, it also heightens in-reservoir Hg methylation risks. By bridging the gap between Hg releases and observed riverine exports, our framework offers a scalable tool for data-limited regions, promotes data access, and supports global freshwater and pollution-management strategies.

EarthArXiv

Distributed faulting of the northern West Napa Fault Zone in Napa Valley, California

Mapped surface ruptures from the 24 August 2014 M w 6.0 South Napa earthquake in the Napa Valley, California, show a 2‐km‐wide zone of distributed faulting in the southern and central West Napa fault zone (WNFZ). In the northern WNFZ at Hendry Winery (HW), however, the mapped 2014 surface ruptures encompass an ∼100‐m‐wide zone, implying significant narrowing of the near‐surface fault zone to the north. We present a tomographic shear‐wave velocity ( ⁠⁠ V S ) model and guided‐wave data that indicate the northern WNFZ is at least 400‐m wide, with multiple near‐surface fault traces. Our V S model shows that the 2014 surface ruptures are underlain by discrete low‐velocity zones (LVZs), and coincident guided‐wave data show that the LVZs carry fault‐zone guided waves. If nearby (<500 m) mapped faults to the east of HW are part of the WNFZ, the entire WNFZ is more than 1 km wide in the northern Napa Valley. WNFZ guided waves travel up to 38% slower than S body waves, and low‐strain guided‐wave shaking is up to five times stronger than the associated body‐wave shaking. Our data suggest that guided waves, traveling along distributed faults, may result in an increased shaking hazard over a 1‐km‐wide area of the northern Napa Valley during future significant earthquakes. In places, the 2014 surface ruptures were difficult to find one year after the earthquake, and paleoseismic trenching showed only weak evidence for faulting, which may not have been identified in trenches if the locations of the 2014 surface ruptures had not been previously mapped ( Prentice et al. , 2015 ). Guided‐wave and V S tomography data, however, show strong evidence for faulting beneath the 2014 surface ruptures and at locations to the east. Although paleoseismic trenching is the gold standard for identifying near‐surface faulting, methods such as peak ground velocities of guided waves may better identify immature near‐surface fault traces.

California

Tracing mercury from land to river: Global sources, retention, and implications for sustainability

Mercury (Hg) pollution in river systems is a global sustainability challenge. Yet the transport, transformation, and retention of Hg within global rivers remain poorly quantified, particularly in regions with sparse observations such as Southeast Asia and Africa, hindering effective pollution mitigation and reinforcing geographic inequities in scientific knowledge and environmental governance. Here, we present the first global, high-resolution simulation of riverine Hg dynamics using a process-based model that traces Hg from land-based sources through river networks to the ocean. Under a realistic scenario, we estimate that ∼1900 megagrams per year (Mg/yr) of Hg enters global rivers, including 1500 Mg/yr from human-induced sources and 400 Mg/yr from soil erosion. Nearly half of this flux (∼1000 Mg/yr) is retained in reservoirs and dams, which act as major sinks. While such retention limits downstream delivery to the oceans, it also heightens in-reservoir Hg methylation risks. By bridging the gap between Hg releases and observed riverine exports, our framework offers a scalable tool for data-limited regions, promotes data access, and supports global freshwater and pollution-management strategies.

Environmental Science & Technology

Kiloyear cycles of carbonate and Mg-silicate replacement at Von Damm hydrothermal vent field

The Von Damm vent field (VDVF) on the Mid-Cayman Rise in the Caribbean Sea is unique among modern hydrothermal systems in that the chimneys and mounds are almost entirely composed of talc. We analyzed samples collected in 2020 and report that in addition to disordered talc of variable crystallinity, carbonates are a major class of mineral at VDVF. The carbonate minerals include aragonite, calcite, magnesium-rich calcite, and dolomite. Talc and carbonate mineral textures indicate that, rather than replacing volcanic host rock, they precipitate from the mixing of hydrothermal fluids and seawater at the seafloor, occurring in chimneys and surrounding rubble. Alternating precipitation of this mineral assemblage is pervasive, with carbonate minerals typically being succeeded by talc, and with indications that in some cases talc and carbonate minerals replace one another. Stable carbon isotopic data indicate the carbonate minerals originate from the mixing of seawater and hydrothermal fluid, which is supported by U-Th data. Radiocarbon calcite ages and talc 234 U- 230 Th isochron ages indicate mineral ages spanning over thousands to tens of thousands of years. Analyses of these samples illustrate a dynamic system that transitions from carbonate-dominated to Mg-silicate−dominated precipitation over time scales of thousands of years. Our observations raise questions regarding the eventual fate of seafloor precipitates and whether carbonate and silicate minerals in such settings are sequestered and represented in the rock record.

Geology