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Occurrence and distribution of arsenic and radon in water from private wells in the Rancocas aquifer, southern New Castle and northern Kent Counties, Delaware, 2015

Water samples were collected and analyzed for arsenic and radon from 36 private, mostly domestic wells that tap the Rancocas aquifer in southern New Castle and northern Kent Counties, Delaware, during the summer of 2015. Both arsenic and radon are from natural mineral sources, in particular glauconitic and other marine-derived sediments, which are important components of the geologic formations comprising the Rancocas aquifer. Routine testing of domestic wells is not required in Delaware; as a result, many homeowners are not aware of potential water-quality problems with these chemicals in their well water. Arsenic has previously been detected at levels of potential concern for human health in this aquifer in adjacent parts of Maryland where it is referred to as the Aquia aquifer. Arsenic and radon also have previously been detected in several Rancocas aquifer wells in Delaware. The Delaware Department of Natural Resources and Environmental Control intends to use the data from this project to better identify areas with potential for levels of concern for domestic well owners. This report includes chemical results and maps showing the distribution of sampled wells and concentrations of arsenic and radon. All data collected for this study also are available in the U.S. Geological Survey’s National Water Information System database. Arsenic was detected above the minimum reporting limit of 0.1 micrograms per liter (µg/L) in 34 of the 36 wells sampled with concentrations ranging from about 0.11 to 27 µg/L. In 15 of the samples, arsenic concentrations were at or above the U.S. Environmental Protection Agency (EPA) Maximum Contaminant Level (MCL) of 10 µg/L for public wells. Most of the higher concentrations are clustered along a band running from the southwest to northeast in the southern part of the study area. Radon, which is an inert gas derived from radium, was detected in all water samples with concentrations ranging from 85 to 1,870 picocuries per liter (pCi/L). Currently, the EPA has not set a MCL for radon in public water systems. There were no samples where radon was detected at a concentration exceeding the proposed alternative MCL of 4,000 pCi/L. Samples from 16 of 36 wells were above the lower proposed MCL of 300 pCi/L. Most of these samples were from wells greater than 200 feet deep located in a similar part of the aquifer as the higher concentrations of arsenic along an east-northeasterly line in the southern part of the study area.

Delaware↗

Human and ecosystem health in coastal systems

U.S. coastal economies and communities are facing an unprecedented and growing number of impacts to coastal ecosystems including beach and fishery closures, harmful algal blooms, loss of critical habitat, as well as shoreline damage. This paper synthesizes our present understanding of the dynamics of human and ecosystem health in coastal systems with a focus on the need to better understand nearshore physical process interactions with coastal pollutants and ecosystems (e.g. fate and transport, circulation, depositional environment, climate change). It is organized around two major topical areas and six subtopic areas: 1) Identifying and mitigating coastal pollutants, including fecal pollution, nutrients and harmful algal blooms, and microplastics; and 2) Resilient coastal ecosystems, which focuses on coastal fisheries, shellfish and natural and nature-based features (NNBF). Societal needs and the tools and technologies needed to address them are discussed for each subtopic. Recommendations for scientific research, observations, community engagement, and policies aim to help prioritize future research and investments. A better understanding of coastal physical processes and interactions with coastal pollutants and resilient ecosystems (e.g. fate and transport, circulation, depositional environment, climate change) is a critical need. Other research recommendations include the need to quantify potential threats to human and ecosystem health through accurate risk assessments and to quantify the resulting hazard risk reduction of natural and nature-based features; improve pollutant and ecosystem impacts forecasting by integrating frequent and new data points into existing and novel models; collect environmental data to calibrate and validate models to predict future impacts on coastal ecosystems and their evolution due to anthropogenic stressors (land-based pollution, overfishing, coastal development), climate change, and sea level rise; and develop lower cost and rapid response tools to help coastal managers better respond to pollutant and ecosystem threats.

Shore and Beach↗

Benefits of protective fencing to plant and rodent communities of the western Mojave Desert, California

Human disturbance in the western Mojave Desert takes many forms. The most pervasive are livestock grazing and off-highway vehicle use. Over the past few decades several areas within this region have been fenced to preclude human disturbance. These areas provide opportunities to study the impact of human activities in a desert ecosystem. This paper documents the response of plant and small mammal populations to fencing constructed between 1978 and 1979 at the Desert Tortoise Research Natural Area, Kern County, California. Aboveground live annual plant biomass was generally greater inside than outside the fenced plots during April 1990, 1991, and 1992. The alien grass Schismus barbatus was a notable exception, producing more biomass in the unprotected area. Forb biomass was greater than that of alien annual grasses inside the fence during all three years of the study. Outside the fence, forb biomass was significantly higher than that of alien grasses only during spring 1992. Percent cover of perennial shrubs was higher inside the fence than outside, while no significant trend was detected in density. There was als more seed biomass inside the fence; this may have contributed to the greater diversity and density of Merriam's kangaroo rats ( Dipodomys merriami ), long-tailed pocket mice ( Chaetodipus formosus ), and southern grasshopper mice ( Onychomys torridus ) in the protected area. These results show that protection from human disturbance has many benefits, including greater overall community biomass and diversity. The significance and generality of these results can be further tested by studying other exclosures of varying age and configurations in different desert regions of the southwestern United States.

California↗

Human influences on trophic cascades along rocky shores

A three-trophic-level interaction among American Black Oystercatchers ( Haematopus bachmani ), limpets ( Lottia spp.), and erect fleshy algae in rocky intertidal communities of central and southern California was documented via manipulative and “natural” experiments. Removal of the territorial limpet ( Lottia gigantea ) initially caused large increases in the percent cover of erect fleshy algae, followed by a more gradual increase in density of small limpets ( Lottia spp.) and a decline in algal cover. Algal cover increased following the removal of small limpets at the sites from which L. gigantea had been removed earlier, thus demonstrating that the large and small limpets had similar inhibitory effects on plant populations. A comparison of sites with and without oystercatchers showed that L. gigantea occupied substrate inclinations in proportion to their availability at sites where oystercatchers were rare, whereas the distribution of L. gigantea was skewed toward vertically inclined substrates where oystercatchers were common. Survival rates of limpets translocated to horizontal and vertical substrates were similar in sites lacking oystercatcher predation, but were much lower on horizontal substrates where oystercatchers were common. Our results are consistent with those from several prior studies in demonstrating that shorelines frequented by humans typically lack oystercatchers. Humans also exploit L. gigantea and reduce populations to low densities of small individuals. These findings may explain why the midlittoral zone of rocky intertidal communities in western North America are so often dominated by high population densities of small limpets.

Ecological Applications↗

An updated stress map of the continental U.S. reveals heterogeneous intraplate stress

Knowledge of the state of stress in the Earth’s crust is key to understanding the forces and processes responsible for earthquakes. Historically, low rates of natural seismicity in the central and eastern United States have complicated efforts to understand intraplate stress, but recent improvements in seismic networks and the spread of human-induced seismicity have greatly improved data coverage. Here we compile a nationwide stress map based on formal inversions of focal mechanisms that challenges the idea that deformation in continental interiors is driven primarily by broad, uniform stress fields derived from distant plate boundaries. Despite plate-boundary compression, extension dominates roughly half of the continent, and second-order forces related to lithospheric structure appear to control extension directions. We also show that the states of stress in several active eastern United States seismic zones differ significantly from surrounding areas and that these anomalies cannot be explained by transient processes, suggesting that earthquakes are focused by persistent, locally-derived sources of stress. Such spatially variable intraplate stress appears to justify the current, spatially variable estimates of seismic hazard. Future work to quantify sources of stress, stressing-rate magnitudes, and their relationship with strain and earthquake rates could allow prospective mapping of intraplate hazard.

Continental United States↗

Statewide cumulative human health risk assessment of inorganics-contaminated groundwater wells, Montana, USA

Across the United States, rural residents rely on unregulated and generally unmonitored private wells for drinking water, which may pose serious health risks due to unrecognized contaminants. We assessed the nature, degree, and spatial distribution of cumulative health risks from inorganic contaminants in groundwater. Our analysis included nearly 84,000 data points from 6500+ wells, across 51 of Montana's 98 watersheds, using a public groundwater database. We compared a drinking water screening level cumulative risk assessment (CRA) for inorganics based on the U.S. Environmental Protection Agency (EPA) protective health thresholds (Maximum Contaminant Level Goals, Health Advisories [MCLG-HAs]) to a CRA based on EPA public supply enforceable Maximum Contaminant Levels (MCLs). Based on median concentrations of 19 inorganics (antimony, arsenic, barium, beryllium, boron, cadmium, chromium, copper, fluoride, manganese, molybdenum, nickel, nitrate, lead, selenium, strontium, thallium, uranium, zinc), 75% of watersheds had MCLG-HA-based cumulative risk values > 1.0; arsenic and uranium contributed the most risk, followed by strontium, fluoride, manganese and boron. Hence, this screening level (Tier I) CRA indicated widespread potential for unrecognized human health risk to private well users from inorganic contaminants considering both carcinogenic and non-carcinogenic risks. Sensitivity analysis showed that benchmarks applied (MCLG-HAs versus MCLs) exerted the largest control on results. Our findings identify priority regions for Tier 2 risk assessments to elucidate local sources and distributions of geogenic versus anthropomorphic contaminants. Our study is the first statewide assessment of cumulative health risk from groundwater that we are aware of, and results support increased statewide drinking water education and testing to reduce human health risks from contaminated private well water.

Montana↗

Geochemistry of soils along a transect from Central Mexico to the Pacific Coast: a pilot study for continental-scale geochemical mapping

The Mexican Geological Survey (SGM), the National Institute of Statistics, Geography and Informatics (INEGI) and the Autonomous University of San Luis Potosi (UASLP) have established a multidisciplinary team with the objective of creating a national program of geochemical mapping of soils in Mexico. This is being done as part of the North American Soil Geochemical Landscapes Project in partnership with the US Geological Survey and the Geological Survey of Canada. As the first step, a pilot study was conducted over a transect that extends from the Mexico–US border near Ciudad Juarez in the north to the Pacific Ocean in the south. This pilot transect was conducted in two phases, and this paper presents results from the first phase, which sampled soils at about a 40-km spacing along a 730-km transect beginning in Central Mexico and ending at the Pacific Coast. Samples were collected from the A and C horizons at each site and 60 elements were analyzed. This pilot study demonstrates that geochemical mapping based on a 40-km spacing is adequate to identify broad-scale geochemical patterns. Geologic influence (i.e., soil parent material) was the most important factor influencing the distribution of elements along the transect, followed by the influence of regional mineralization. The study also showed that influence by human activities over the transect is minimal except possibly in large mining districts. A comparison of element abundance in the A horizon with the environmental soil guidelines in Mexico showed that the natural concentrations of the studied soils were lower than the established threshold for soil restoration with the exception of V and As. The former had a median value (75 mg/kg) approximately equal to the value established in Mexico for soil restoration in agricultural and residential lands (78 mg/kg), and the latter had three values higher than the 22 mg/kg threshold for soil restoration in agricultural and residential lands. These cases demonstrate the importance of knowing the national- and regional-scale geochemistry of Mexican soils as a support for the decision-making process, particularly for the proper formulation and application of soil guidelines designed to protect human and ecosystem health.

Applied Geochemistry↗

Sustainable growth in America's heartland: 3-D geologic maps as the foundation

The Central Great Lakes States of Illinois, Indiana, Michigan, and Ohio constitute one of the most productive and economically important regions in the country—America’s heartland. The agriculture, industry, business, recreation, and ecology of these States are based on a common geologic heritage. During the last 1.8 million years, glaciers repeatedly advanced and retreated across the region, leaving behind a thick, complex blanket of intermixed layers of mud, clay, silt, sand, and gravel. These glacial deposits contain bountiful resources—rich soils; plentiful ground water; minerals for construction; land for agriculture, development, recreation, and wildlife habitat; and lakes and rivers for recreation and wildlife habitat. These materials are also subject to natural hazards—floods, erosion, landslides, radon, and earthquakes—and manmade problems such as soil, sediment, and water contamination from point and nonpoint sources. Resulting land degradation has impaired and restricted human use and enjoyment of the land and caused degradation and loss of wildlife habitat. The continued economic growth of the region and the security of its population and environment are related to fundamental issues involving land, water, mineral, and biological resources. Addressing the conflicting demands on these resources without adequate information can result in land-use decisions that are not compatible with sustainable development and a continued high quality of life for future generations. Decisionmakers need knowledge of the glacial deposits— their characteristics, three-dimensional (3-D) distribution, and thickness. To provide this knowledge, a coalition of State and Federal Geological Surveys (Illinois State Geological Survey, Indiana Geological Survey, Michigan Geological Survey Division, Ohio Division of Geological Survey, U.S. Geological Survey) has formed to conduct the necessary studies in these four States to depict the 3-D nature of these glacial and related deposits and to interpret these data in cooperation with the user community for specific societal needs.

Illinois, Indiana, Michigan, Ohio↗

The quality of our nation's waters: Nutrients in the nation's streams and groundwater, 1992-2004

National Findings and Their Implications Although the use of artificial fertilizer has supported increasing food production to meet the needs of a growing population, increases in nutrient loadings from agricultural and, to a lesser extent, urban sources have resulted in nutrient concentrations in many streams and parts of aquifers that exceed standards for protection of human health and (or) aquatic life, often by large margins. Do NAWQA findings substantiate national concerns for aquatic and human health? National Water-Quality Assessment (NAWQA) findings indicate that nutrient concentrations in streams and groundwater in basins with significant agricultural or urban development are substantially greater than naturally occurring or “background” levels. For example, median concentrations of total nitrogen and phosphorus in agricultural streams are about 6 times greater than background levels. Findings also indicate that concentrations in streams routinely were 2 to 10 times greater than regional nutrient criteria recommended by the U.S. Environmental Protection Agency (USEPA) to protect aquatic life. Such large differences in magnitude suggest that significant reductions in sources of nutrients, as well as greater use of land management strategies to reduce the transport of nutrients to streams, are needed to meet recommended criteria for streams draining areas with significant agricultural and urban development. Nitrate concentrations above the Federal drinking-water standard—or Maximum Contaminant Level (MCL)—of 10 milligrams per liter (mg/L, as nitrogen) are relatively uncommon in samples from streams used for drinking water or from relatively deep aquifers; the MCL is exceeded, however, in more than 20 percent of shallow (less than 100 feet below the water table) domestic wells in agricultural areas. This finding raises concerns for human health in rural agricultural areas where shallow groundwater is used for domestic supply and may warn of future contamination of deeper groundwater pumped from public‑supply wells. Are levels of nutrients in water increasing or decreasing? A decadal assessment of trends in concentrations of nitrogen and phosphorus from about 1993 to 2003 shows minimal changes in those concentrations in the majority of studied streams across the Nation, and more upward than downward trends in concentrations at sites with changes. These findings underscore the need for reductions in nutrient inputs or management strategies that would reduce transport of nutrients to streams. Upward trends were evident among all land uses, including those only minimally affected by agricultural and (or) urban development, which suggests that additional protection of some of our Nation’s most pristine streams warrants consideration. The median of nitrate concentrations in groundwater from 495 wells also increased significantly from 3.2 to 3.4 mg/L (6 percent) during about the same period, and the proportion of wells with concentrations of nitrate greater than the MCL increased from 16 to 21 percent. Nitrate concentrations in water in deep aquifers are likely to increase during the next decade as shallow groundwater with elevated concentrations moves downward. The potential for future contamination of the deep aquifers requires attention because these aquifers commonly are used for public water supply, and because restoration of groundwater is costly and difficult. Long-term and consistent monitoring of nutrients, improved accounting of nutrient sources, and improved tracking and modeling of climatic and landscape changes will be essential for distinguishing trends in nutrient concentrations, understanding the causes of those trends, and accurately tracking the effectiveness of strategies implemented to manage nutrients.

Circular↗

Subduction zones: Not relevant to present-day problems of waste disposal

SUBDUCTION zones are considered to be sites of disposal for vast areas of the Earth's surface 1 , while new surface is generated simultaneously at rise crests 2 . Bostrom and Sherif 3 suggest that the world's industrial and domestic waste be dumped into subduction zones at deep sea trenches to allow nature to complete the recycling process at geologically rapid rates of 5 to 10 cm/yr. They also point out that trenches are often sites of rapid rates of deposition and suggest that the dumped wastes would, speaking geologically, soon be buried. Francis 4 suggests that canisters of toxic chemical and radioactive wastes could be dumped onto trench sediments and be expected to sink at rates of 20 m/yr, assuming that the mass of turbidites in the trench fill often spontaneously liquefies on shaking by earthquakes. The assumption is based on the supposed lack of evidence for deformed sediment in trenches. I will argue that the suggestion of Bostrom and Sherif 3 is not useful for the next few dozen generations of human populations and will point out observational evidence to show that Francis's 4 assumption is incorrectly founded.

Nature↗

Anthropogenic disturbance and environmental associations with fish assemblage structure in two nonwadeable rivers

Nonwadeable rivers are unique ecosystems that support high levels of aquatic biodiversity, yet they have been greatly altered by human activities. Although riverine fish assemblages have been studied in the past, we still have an incomplete understanding of how fish assemblages respond to both natural and anthropogenic influences in large rivers. The purpose of this study was to evaluate associations between fish assemblage structure and reach-scale habitat, dam, and watershed land use characteristics. In the summers of 2011 and 2012, comprehensive fish and environmental data were collected from 33 reaches in the Iowa and Cedar rivers of eastern-central Iowa. Canonical correspondence analysis (CCA) was used to evaluate environmental relationships with species relative abundance, functional trait abundance (e.g. catch rate of tolerant species), and functional trait composition (e.g. percentage of tolerant species). On the basis of partial CCAs, reach-scale habitat, dam characteristics, and watershed land use features explained 25.0–81.1%, 6.2–25.1%, and 5.8–47.2% of fish assemblage variation, respectively. Although reach-scale, dam, and land use factors contributed to overall assemblage structure, the majority of fish assemblage variation was constrained by reach-scale habitat factors. Specifically, mean annual discharge was consistently selected in nine of the 11 CCA models and accounted for the majority of explained fish assemblage variance by reach-scale habitat. This study provides important insight on the influence of anthropogenic disturbances across multiple spatial scales on fish assemblages in large river systems.

Iowa↗

The INI North American Regional Nitrogen Center: 2011–2015 nitrogen activities in North America

The North American Nitrogen Center (NANC) carries out three main charges: (1) conducting assessments on nitrogen (N) flows within North America and the consequences for human health, water resources, biodiversity, and greenhouse gas emissions; (2) facilitating efforts to develop solutions to the problem of excess nitrogen in agricultural, institutional, and natural resource management sectors; and (3) presenting these results to policy makers. There are formidable challenges in reducing N loss from all parts of the North American food production and supply chain, including altering consumer behavior. The NANC is working with producers, trade groups, universities, and supply chains to develop effective practices for minimizing loss of reactive nitrogen (N r ) to the environment. The NANC is also helping public land management and regulatory agencies prepare effective policy approaches toward minimizing ecological damage from atmospheric N r deposition.

Book chapter↗

Connectivity of mule deer (Odocoileus hemionus) populations in southern California: A genetic survey of a mobile ungulate in a highly fragmented urban landscape

Urbanization is a substantial force shaping the genetic and demographic structure of natural populations. Urban development and major highways can limit animal movements, and thus gene flow, even in highly mobile species. Characterizing varying species responses to human activity and fragmentation is important for maintaining genetic continuity in wild animals and for preserving biodiversity. As one of the only common and wide-ranging large wild herbivores in much of urban North America, deer play an important ecological role in urban ecosystems, yet the genetic impacts of development on deer are not well known.

Landscape Ecology↗

Emergent biogeochemical risks from Arctic permafrost degradation

The Arctic cryosphere is collapsing, posing overlapping environmental risks. In particular, thawing permafrost threatens to release biological, chemical and radioactive materials that have been sequestered for tens to hundreds of thousands of years. As these constituents re-enter the environment, they have the potential to disrupt ecosystem function, reduce the populations of unique Arctic wildlife and endanger human health. Here, we review the current state of the science to identify potential hazards currently frozen in Arctic permafrost. We also consider the cascading natural and anthropogenic processes that may compound the impacts of these risks, as it is unclear whether the highly adapted Arctic ecosystems have the resilience to withstand new stresses. We conclude by recommending research priorities to address these underappreciated risks.

Nature Climate Change↗

Shoreline retreat of the Corte Madera marshes, 1853 to 2016, Marin County, California

The greater San Francisco Bay estuary, prior to human intervention, encompassed about 2,200 km 2 of tidal and salt marshes. Over time, these areas became increasingly diked, developed, and altered from their natural state. In addition, natural forces are always driving a continually shifting equilibrium. This study area, the Corte Madera marshes, is a tidal marsh or wetland located in southeastern Marin County, and it borders an embayment of central San Francisco Bay along about 2.8 km of shoreline. Most of this shoreline is located within the Corte Madera Marsh Ecological Reserve, managed by the California Department of Fish and Wildlife. Other areas within the marsh include (1) unincorporated Greenbrae (at the boardwalk), (2) diked land (that is, isolated from tidal action) owned by the Golden Gate Bridge Highway and Transportation District, and (3) urbanized areas such as in the Mariner Cove subdivision of Corte Madera. The present tidal marsh area was historically subdivided into the following informally named tracts, listed from north to south: Heerdt marsh, north Muzzi marsh, inner and outer Muzzi marshes, Marta’s marsh, and Triangle marsh. The purpose of this study is to derive the magnitudes and rates of shoreline change (both erosion and accretion) for the Corte Madera shoreline, with particular emphasis on the time period from 1931 to 2016. The rates of change are then related to different shoreline types (that is, natural or diked) and (or) locations on the shoreline.

California↗

Chemical and isotopic characteristics of methane in groundwater of Ohio, 2016

In 2016, the U.S. Geological Survey, in cooperation with the Ohio Water Development Authority, investigated the hydrogeologic setting, chemical and isotopic characteristics, and origin of methane in groundwater of Ohio. Understanding the occurrence and distribution of methane in groundwater is important in terms of public safety because methane in water wells can pose a risk of explosion. In addition, documenting the chemical and isotopic characteristics of methane in groundwater can make an important contribution to future stray gas investigations. Water samples were collected from 15 domestic water wells known to produce methane, which were in 12 counties in diverse parts of Ohio. The wells were 75–345 feet deep and tapped a range of aquifer types, including glacial deposits and bedrock of Upper Ordovician, Upper Devonian, Lower Mississippian, and Pennsylvanian ages. Although the hydrogeologic settings were varied, there was a broad similarity among the well sites in that the bedrock was predominantly shale and the glacial deposits were predominantly clay. The wells were sampled for dissolved inorganic constituents; dissolved organic carbon; methane and other dissolved gases; stable isotopes (carbon, hydrogen, and oxygen) of methane, water, and dissolved inorganic carbon; and carbon-14 of methane. Gas composition and stable isotopes of methane were used to differentiate thermogenic and microbial methane. The degree of fractionation of hydrogen and carbon isotopes was used to evaluate the pathway of microbial methanogenesis (carbon dioxide [CO 2 ] reduction or acetate fermentation) and the effects of secondary processes such as oxidation, mixing, and migration. The concentration of carbon-14 of methane was used to evaluate the relative age of the carbon source. The quality of water from the 15 wells differed greatly; water types ranged from CaMgHCO 3 to NaCl, and total dissolved solids concentrations ranged from 318 to 2,940 milligrams per liter (mg/L). Methane concentrations ranged from 1.2 to 120 mg/L. Of the 15 samples, 12 had methane concentrations greater than 28 mg/L, the level that can pose a risk of explosion. Of the 15 samples, 12 had chemical and isotopic characteristics or "signatures" consistent with microbial methane formed by CO 2 reduction. CO 2 reduction is commonly associated with microbial degradation of organic matter in anaerobic aquifers and with the formation of microbial shale gas and coalbed methane along margins of sedimentary basins. Two of 15 samples were interpreted as having a component of thermogenic methane based on the δ 13 C of methane (−50.96 and −47.74 parts per thousand [per mil]) and gas dryness (28 and 5). One of 15 samples (from the shallowest well) had chemical and isotopic characteristics consistent with methane oxidation by sulfate reduction based on light δ 13 C of dissolved inorganic carbon (−31.6 per mil) and evidence of sulfate reduction in terms of the odor and appearance of the water. For the 12 samples interpreted as microbial methane formed by CO 2 reduction, the δ 13 C of methane varied from −75 to −56 per mil. Multiple samples from the same aquifer demonstrated a general trend of increasing δ 13 C of methane with depth. Samples with lighter δ 13 C of methane (−75 to −62 per mil) were from shallower wells (or wells with shallow open intervals), and the isotopic signature of the water was consistent with modern or postglacial groundwater recharge. Three samples with heavier δ 13 C of methane (−61 to −56 per mil) were from deeper wells or more confined aquifers where the isotopic signature of water was consistent with older (glacial) recharge. In addition, δ 13 C of dissolved inorganic carbon was enriched (+12 to +18.9 per mil), and carbon-14 of methane was consistent with carbon associated with Paleozoic bedrock or older glacial deposits. These observations are generally consistent with increased Rayleigh-type fractionation at greater depths; however, other interpretations are possible. Isotopic signatures can be ambiguous, especially in areas with complex geologic histories that include multiple episodes of migration, mixing, and (or) oxidation. Many of the wells were in proximity to multiple potential natural and anthropogenic pathways of methane migration; however, it is not possible to determine if the methane in any of the wells is related to human activities based on the chemical and isotopic data collected for this study.

Ohio↗

Preliminary review of adaptation options for climate-sensitive ecosystems and resources. A report by the U.S. Climate Change Science Program and the Subcommittee on Global Change Research

Climate variables are key determinants of geographic distributions and biophysical characteristics of ecosystems, communities, and species. Climate change is therefore affecting many species attributes, ecological interactions, and ecosystem processes. Because changes in the climate system will continue into the future regardless of emissions mitigation, strategies for protecting climate-sensitive ecosystems through management will be increasingly important. While there will always be uncertainties associated with the future path of climate change, the response of ecosystems to climate impacts, and the effects of management, it is both possible and essential for adaptation to proceed using the best available science. This report provides a preliminary review of adaptation options for climate-sensitive ecosystems and resources in the United States. The term “adaptation” in this document refers to adjustments in human social systems (e.g., management) in response to climate stimuli and their effects. Since management always occurs in the context of desired ecosystem conditions or natural resource management goals, it is instructive to examine particular goals and processes used by different organizations to fulfill their objectives. Such an examination allows for discussion of specific adaptation options as well as potential barriers and opportunities for implementation. Using this approach, this report presents a series of chapters on the following selected management systems: National Forests, National Parks, National Wildlife Refuges, Wild and Scenic Rivers, National Estuaries, and Marine Protected Areas. For these chapters, the authors draw on the literature, their own expert opinion, and expert workshops composed of resource management scientists and representatives of managing agencies. The information drawn from across these chapters is then analyzed to develop the key synthetic messages presented below.

Synthesis and Assessment Product↗

Science needs for continued development of total nitrogen deposition budgets in the United States

The objectives of this white paper are to describe the state of the science with respect to total Nr deposition budgets in North America and the research needed to improve these budgets from both a measurement and modeling standpoint. The document is intended to serve as a plan for TDep research activities but also, more broadly, to provide program managers, natural resource managers, policy makers and scientists with an understanding of the need for complete and accurate Nr deposition budgets to protect ecosystem health and human welfare, and the linkages between the underlying policy-relevant science questions and the specific knowledge and data gaps needed to improve Nr deposition budgets.

Report↗