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Water resource data, Florida, water year 1995; Volume 2B. South Florida ground water

The Water Resources Division of the U.S. Geological Survey, in cooperation with State, County, and other Federal agencies, obtains a large amount of data pertaining to the water resources of Florida each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the Geological Survey, the data are published annually in this report series entitled "Water Resources Data - Florida, Volume 2A: South Florida Surface Water and Volume 2B: South Florida Ground Water."

Florida↗

Hydrogeology and Ground-Water Quality of Brunswick County, North Carolina

Brunswick County is the southernmost coastal county in North Carolina and lies in the southeastern part of the Coastal Plain physiographic province. In this report, geologic, hydrologic, and chemical data were used to investigate and delineate the hydrogeologic framework and ground-water quality of Brunswick County. The major aquifers and their associated confining units delineated in the Brunswick County study area include, from youngest to oldest, the surficial, Castle Hayne, Peedee, Black Creek, upper Cape Fear, and lower Cape Fear aquifers. All of these aquifers, with the exception of the Castle Hayne aquifer, are located throughout Brunswick County. The Castle Hayne aquifer extends across only the southeastern part of the county. Based on available data, the Castle Hayne and Peedee confining units are missing in some areas of Brunswick County, which allows direct hydraulic contact between the surficial aquifer and underlying Castle Hayne or Peedee aquifers. The confining units for the Black Creek, upper Cape Fear, and lower Cape Fear aquifers appear to be continuous throughout Brunswick County. In examining the conceptual hydrologic system for Brunswick County, a generalized water budget was developed to better understand the natural processes, including precipitation, evapotranspiration, and stream runoff, that influence ground-water recharge to the shallow aquifer system in the county. In the generalized water budget, an estimated 11 inches per year of the average annual precipitation of 55 inches per year in Brunswick County is estimated to infiltrate and recharge the shallow aquifer system. Of the 11 inches per year that recharges the shallow system, about 1 inch per year is estimated to recharge the deeper aquifer system. The surficial aquifer in Brunswick County is an important source of water for domestic supply and irrigation. The Castle Hayne aquifer is the most productive aquifer and serves as the principal ground-water source of municipal supply for the county. The upper part of the Peedee aquifer is an important source of ground-water supply for domestic and commercial use. Ground water in the lower part of the Peedee aquifer and the underlying aquifers is brackish and is not known to be used as a source of supply in Brunswick County. Most of the precipitation that recharges the surficial aquifer is discharged to local streams that drain into the Waccamaw River, Cape Fear River, and Atlantic Ocean. Recharge to the Castle Hayne aquifer occurs primarily from the surficial aquifer. Recharge to the Peedee aquifer occurs primarily from the surficial and Castle Hayne aquifers, with some upward leakage of water also occurring from the underlying Black Creek aquifer. Discharge from the Castle Hayne and Peedee aquifers occurs to local streams, the Cape Fear River, and the Atlantic Ocean. Evaluation of water-level data for the period January 1970 through May 2002 indicated no apparent long-term temporal trends in water levels in the surficial and Castle Hayne aquifers and in the upper part of the Peedee aquifer. The most significant water-level trends were noted for wells tapping the lower part of the Peedee aquifer and tapping the Black Creek aquifer where water levels have declined as much as 41 and 37 feet, respectively. These ground-water-level declines are attributed to regional ground-water pumping in areas outside of Brunswick County. Water-level data for Brunswick County wells tapping the upper Cape Fear and lower Cape Fear aquifers tend to fluctuate within a fairly uniform range with no apparent temporal trend noted. Analysis of vertical hydraulic gradients during this same period primarily indicate downward flow of ground water within and among the surficial, Castle Hayne, and Peedee aquifers. The vertical flow of ground water in the Black Creek aquifer is upward into the overlying Peedee aquifer. Upward flow also is noted for the upper and lower Cape Fear aquifers. Historic and recent analytic data were evaluated to better understand the sources of water contained in Brunswick County aquifers and the suitability of the water for consumption. Based on analytical results obtained for recent samples collected during this study, ground water from the surficial aquifer, Castle Hayne aquifer, and upper part of the Peedee aquifer appears to be generally suitable for drinking water. Although concentrations of iron and manganese commonly exceeded the drinking-water standards, the concern generally associated with the occurrence of these analytes in a water supply is one of aesthetics. In all samples, nitrate, nitrite, and sulfate were detected at concentrations less than drinkingwater standards. Based on historic analytical data, the brackish water in the lower part of the Peedee aquifer and in the Black Creek, upper Cape Fear, and lower Cape Fear aquifers is classified as a sodium-chloride type water. The presence of brackish water in these deeper systems combined with upward vertical gradients presents the potential for upward migration of brackish water into overlying aquifers, or upconing beneath areas of pumping. The current (2001) location of the boundary between freshwater and brackish water in Brunswick County aquifers is unknown.

North Carolina↗

A special planning technique for stream-aquifer systems

The potential effects of water-management plans on stream-aquifer systems in several countries have been simulated using electric-analog or digital-computer models. Many of the electric-analog models require large amounts of hardware preparation for each problem to be solved and some become so bulky that they present serious space and access problems. Digital-computer models require no special hardware preparation but often they require so many repetitive solutions of equations that they result in calculations that are unduly unwieldy and expensive, even on the latest generation of computers. Further, the more detailed digital models require a vast amount of core storage, leaving insufficient storage for evaluation of the many possible schemes of water-management. A concept introduced in 1968 by the senior author of this report offers a solution to these problems. The concept is that the effects on streamflow of ground-water withdrawal or recharge (stress) at any point in such a system can be approximated using two classical equations and a value of time that reflects the integrated effect of the following: irregular impermeable boundaries; stream meanders; aquifer properties and their areal variations; distance of the point from the stream; and imperfect hydraulic connection between the stream and the aquifer. The value of time is called the stream depletion factor ( sdf ). Results of a relatively few tests on detailed models can be summarized on maps showing lines through points of equal sdf . Sensitivity analyses of models of two large stream-aquifer systems in the State of Colorado show that the sdf technique described in this report provides results within tolerable ranges of error. The sdf technique is extremely versatile, allowing water managers to choose the degree of detail that best suits their needs and available computational hardware. Simple arithmetic, using, for example, only a slide rule and charts or tables of dimensionless values, will be sufficient for many calculations. If a large digital computer is available, detailed description of the system and its stresses will require only a fraction of the core storage, leaving the greater part of the storage available for sophisticated analyses, such as optimization. Once these analyses have been made, the model then is ready to perform its principal task--prediction of streamflow and changes in ground-water storage. In the two systems described in this report, direct diversion from the streams is the principal source of irrigation water, but it is supplemented by numerous wells. The streamflow depends largely on snowmelt. Estimates of both the amount and timing of runoff from snowmelt during the irrigation season are available on a monthly basis during the spring and early summer. These estimates become increasingly accurate as the season progresses, hence frequent changes of stress on the predictive model are necessary. The sdf technique is especially well suited to this purpose, because it is very easy to make such changes, resulting in more up-todate estimates of the availability of streamflow and ground-water storage. These estimates can be made for any time and any location in the system.

Open-File Report↗

Ground-water resources of Saipan, Commonwealth of the Northern Mariana Islands

Saipan has an area of 48 mi 2 and is the largest of the 14 islands in the Commonwealth of the Northern Mariana Islands (CNMI). The island is formed by volcanic rocks overlain by younger limestones. The island is situated in the western Pacific Ocean at latitude 15 o 12'N and longitude 145 o 45'E, about 3,740 mi west-southwest of Honolulu and midway between Japan and New Guinea (fig. 1). The climate on Saipan is classified as tropical marine with an average temperature of 80 o F. The natural beauty of the island and surrounding waters are the basis for a growing tourist-based economy. The resulting rapid development and increases in resident and tourist populations have added stresses to the island's limited water supplies. Freshwater resources on Saipan are not readily observable because, aside from the abundant rainfall, most freshwater occurs as ground water. Fresh ground water is found in aquifers composed mainly of fragmental limestones. About 90 percent of the municipal water supply comes from 140 shallow wells that withdraw about 11 Mgal/d. The chloride concentration of water withdrawn from production wells ranges from less than 100 mg/L for wells in the Akgak and Capital Hill well fields, to over 2,000 mg/L from wells in the Puerto Rico, Maui IV, and Marpi Quarry well fields. The chloride concentrations and rates of ground-water production are not currently adequate for providing island residents with a potable 24-hour water supply and future demands are expected to be higher. To better understand the ground-water resources of the island, and water resources on tropical islands in general, the U.S. Geological Survey (USGS) entered into a cooperative program with the Commonwealth Utilities Corporation (CUC). The objective of the program, initiated in 1989, is to assess the ground-water resources of Saipan and to make hydrologic information available to the CUC in support of their ongoing efforts to improve the quality and quantity of the municipal water supply. This report presents some of the results of the program including descriptions of (1) the geography and geology, (2) the occurrence of fresh ground water in permeable limestones that extend to some distance below sea level where water-level elevation is affected by ocean tides (coastal aquifers) and in limestones that overlie volcanic basement rocks above sea level (high-level aquifers), (3) the water-table configuration and directions of ground-water flow, and (4) the rainfall, ground-water withdrawal, and chloride concentrations in well water. Also described is the relation of the changes in water-table elevations to changes in sea level, rainfall, and ground-water withdrawal.

Saipan↗

Quality of shallow ground water in areas of recent residential and commercial development, Wichita, Kansas, 2000

Water samples from 30 randomly distributed monitoring wells in areas of recent residential and commercial development (1960–96), Wichita, Kansas, were collected in 2000 as part of the High Plains Regional Ground-Water Study conducted by the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. The samples were analyzed for about 170 water-quality constituents that included chlorofluorocarbons, physical properties, dissolved solids and major ions, nutrients and dissolved organic carbon, trace elements, pesticide compounds, and volatile organic compounds. The purpose of this report is to provide an assessment of water quality in recharge to shallow ground water underlying areas of recent residential and commercial development and to determine the relation of ground-water quality to overlying urban land use. Analyses of water from the 30 monitoring wells for chlorofluorocarbons were used to estimate apparent dates of recharge. Water from 18 wells with nondegraded and uncontaminated chlorofluorocarbon concentrations had calculated apparent recharge dates that ranged from 1979 to 1990 with an average date of 1986. Water from 14 monitoring wells (47 percent) exceeded the 500-milligrams-per-liter Secondary Maximum Contaminant Level established by the U.S. Environmental Protection Agency for dissolved solids in drinking water. The Secondary Maximum Contaminant Levels of 250 milligrams per liter for chloride and sulfate were exceeded in water from one well. The source of the largest concentrations of dissolved solids and associated ions, such as chloride and sulfate, in shallow ground water in the study area probably is highly mineralized water moving out of the Arkansas River into the adjacent, unconsolidated deposits and mixing with the dominant calcium bicarbonate water in the deposits. Concentrations of most nutrients in water from the sampled wells were small, with the exception of nitrate. Although water from the sampled wells did not have nitrate concentrations larger than the 10-milligram-per-liter Maximum Contaminant Level for drinking water, water from 50 percent of the sampled wells showed nitrate enrichment (concentrations greater than 2.0 milligrams per liter). Most trace elements in water from the sampled wells were detected only in small concentrations, and few exceeded respective water-quality standards. Twenty percent of iron concentrations, 40 percent of manganese concentrations, 3 percent of arsenic concentrations, and 13 percent of uranium concentrations exceeded respective Maximum Contaminant Levels or Secondary Maximum Contaminant Levels. A total of 47 pesticide compounds were analyzed in ground-water samples during this study. Water from 73 percent of the wells sampled had detectable concentrations of one or more of 8 of these 47 compounds. The herbicide atrazine or its degradation product deethylatrazine were detected most frequently (in water from 70 percent of the sampled wells). Metolachlor was detected in water from 10 percent of the wells, and simazine was detected in water from 30 percent of the wells sampled. Other pesticides detected included dieldrin, pendimethalin, prometon, and tebuthiuron (each in water from 3 percent of the wells). All concentrations of these compounds were less than established Maximum Contaminant Levels. A total of 85 volatile organic compounds (VOCs) were analyzed in ground-water samples during this study. Water from 43 percent of the wells had a detectable concentration of one or more VOCs. Chloroform was the most frequently detected VOC (23 percent of the wells sampled).Seven other VOCs were detected in water at frequencies of 13 percent or less in the wells sampled. Concentrations of VOCs were less than respective Maximum Contaminant Levels, except one sample with a concentration of 9.0 micrograms per liter for tetrachloroethylene (Maximum Contaminant Level of 5.0 micrograms per liter). An analysis of hydraulic gradient, flow velocity, and residence time of the ground water indicated potential recharge areas that ranged from 0.8 to 2.8 miles upgradient of monitoring-well locations. Nineteen (63 percent) of these potential recharge areas were in agricultural areas or areas in transition from agricultural to residential and (or) commercial land use at the time water sampled from the monitoring wells was recharged to the shallow ground water. The occurrence of atrazine or deethylatrazine in water from 70 percent of the monitoring wells may indicate a historical agricultural land-use relation. This agricultural relation also may affect concentrations of other water-quality constituents of possible agricultural origin such as nitrate, which generally were in excess of background concentrations in shallow ground water.

Kansas↗

Field tests of diffusion samplers for inorganic constituents in wells and at a ground-water discharge zone

Field tests were performed on two types of diffusion samplers to collect representative samples of inorganic constituents from ground water in wells and at an arsenic-contaminated ground-water-discharge zone beneath a stream. Nylon-screen samplers and dialysis samplers were tested for the collection of arsenic, calcium, chloride, iron, manganese, sulfate, and dissolved oxygen. The investigations were conducted at the Naval Industrial Reserve Ordnance Plant (NIROP), Fridley, Minnesota, and at the Naval Air Station Fort Worth Joint Reserve Base (NAS Fort Worth JRB), Texas. Data indicate that, in general, nylon-screen and dialysis diffusion samplers are capable of obtaining concentrations of inorganic solutes in ground water that correspond to concentrations obtained by low-flow sampling. Diffusion samplers offer a potentially time-saving approach to well sampling. Particular care must be taken, however, when sampling for iron and other metals, because of the potential for iron precipitation by oxygenation and when dealing with chemically stratified sampling intervals. Simple nylon-screen jar samplers buried beneath creekbed sediment appear to be effective tools for locating discharge zones of arsenic contaminated ground water. Although the LDPE samplers have proven to be inexpensive and simple to use in wells, they are limited by their inability to provide a representative sample of ionic solutes. The success of nylon-screen samplers in sediment studies suggests that these simple samplers may be useful for collecting water samples for inorganic constituents in wells. Results using dialysis bags deployed in wells suggest that these types of samplers have the potential to provide a representative sample of both VOCs and ionic solutes from ground water (Kaplan and others, 1991; Theodore A. Ehlke, U.S. Geological Survey, written commun., 2001). The purpose of this report is to provide results of field tests investigating the potential to use diffusion samplers to collect representative samples of inorganic constituents from ground water in wells and at an arsenic-contaminated ground-water-discharge zone beneath a stream. The investigations were performed at NIROP, Fridley, Minn. (fig. 1) and at NAS Fort Worth JRB, Texas (fig. 2). Two types of samplers were tested. One type was a nylon-screen sampler, which consisted of a 30-mL jar filled with deionized water, with its opening covered by a nylon screen. The second type was a dialysis sampler that consisted of a tube of dialysis membrane filled with deionized water. The nylon-screen samplers were deployed in wells at NIROP Fridley and NAS Fort Worth JRB and beneath the ground-water/surface water interface of a stream at NAS Fort Worth JRB. The dialysis samplers were deployed only in wells at NAS Fort Worth JRB.

Water-Resources Investigations Report↗

Geographic information system data sets of hydrogeologic conditions in Pequea and Mill Creek watersheds, Pennsylvania; Part II, Hydrogeologic interpretations

This report describes Geographic Information System data sets of ground-water levels, unsaturated-zone thickness, and regolith thickness in the Pequea and Mill Creek watersheds, a 210-square-mile area in Lancaster and Chester Counties, Pa. The data sets, which represent hydrogeologic interpretations, were developed by the use of ARC/INFO software during 1990-93 by the U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Resources. The U.S. Environmental Protection Agency proposes to use these interpretive data sets, and those from other sources, to aid in the assessment of ground-water vulnerability to pesticides in the Pequea and Mill Creek watersheds.

Open-File Report↗

Resource and land information for south Dade County, Florida

South Dade County, at the southeast corner of Florida, exemplifies many of the environmental concerns that have developed throughout the United States. Considerable environmental information has recently been assembled from this region, and some of it is presented in this experimental report in folio form.

Florida↗

Geology and ground water of the Savannah River Plant and vicinity, South Carolina

The area described in this report covers approximately 2,600 square miles in west-central South Carolina and includes the site of the Savannah River Plant, a major production facility of the U.S. Atomic Energy Commission. The climate, surface drainage, and land forms of the study area are typical of the southern part of the Atlantic Coastal Plain. Precipitation is normally abundant and fairly evenly distributed throughout the year, and the mean annual temperature is moderately warm (64?F). The major streams that drain the area (the Savannah, Salkehatchie, and Edisto Rivers) have low gradients and flow in a southeasterly direction toward the Atlantic Ocean. Surface features of the area include narrow, flat-bottomed, steep-sided valleys and broad gently rolling interfluvial areas. Those parts of the Coastal Plain included within the report area can be subdivided into the Aiken Plateau, the Congaree Sandhills, and the Coastal Terraces. The area is underlain by a sequence of unconsolidated and partly consolidated sediments of Late Cretaceous, Tertiary, and Quaternary age. The unconsolidated sediments were deposited unconformably on a basement of igneous and metamorphic rocks of Precambrian and Paleozoic age and sedimentary rocks of Triassic age. The basement rocks are similar to the granite-diorite complex of the Charlotte Belt, the metamorphosed rocks of the Carolina Slate Belt, and the consolidated sediments of the Newark Group. The unconsolidated sediments strike about N. 60 ? E. and dip 6-20 feet per mile to the southeast. They form a wedge-shaped mass that increases in thickness toward the southeast to slightly more than 1,200 feet in the vicinity of Allendale, S.C., on the southeast or downdip side of the study area. The oldest or lowermost unconsolidated sedimentary unit, the Tuscaloosa Formation of Late Cretaceous age, is overlain in the subsurface by beds that are also probably Late Cretaceous in age and that herein are named the Ellenton Formation. The Upper Cretaceous deposits are, in turn, overlain by the, McBean Formation and the Congaree(?) Formation of middle Eocene age, the Barnwell Formation of late Eocene age, the Hawthorn Formation of early and middle Miocene age, and by fluvial and marine(?) terrace deposits of Pliocene(?), Pleistocene, and Recent age. In the mapped area, the Congaree(?) Formation includes undifferentiated rocks (mostly Congaree and Barnwell Formations and some Mcbean outliers). (See map explanation.) Structurally, the Upper Cretaceous sediments are overlapped to the northwest by Tertiary deposits. A preliminary geologic map of the general area is included in the report. The principal aquifer in the area is composed of the beds of medium to coarse sand and gravel contained in the Tuscaloosa and Ellenton Formations. Subordinate aquifers include deposits of sand and limestone of Tertiary and Quaternary age. The ground water in the principal aquifer occurs under water-table conditions in the outcrop area of the Tuscaloosa Formation in the northern and western parts of the study area, but it is under artesian pressure downdip in the southern and eastern parts of the study area. Contours drawn on the piezometric surface of the water in the principal aquifer indicate that water is recharged to the aquifer mainly by leakage through the overlying Tertiary formations. Likewise, the piezometric contours show that the outcrop area of the Tuscaloosa Formation functions chiefly as an area of discharge. Doubtless, water is also discharged from the aquifer by moving downdip to areas near the coast where the prevailing hydraulic gradient may favor the upward leakage of water through the upper confining beds. The hydraulic properties of the principal aquifer were determined by a series of pumping tests. The results indicate that the aquifer is highly productive and could supply 15 million gallons per day in the vicinity of the Savannah River Plant without exceeding the available drawdown.

South Carolina↗

Chemical quality of ground water in the Dos Palos-Kettleman City area, San Joaquin Valley, California

The Dos Palos-Kettleman City area of this report includes approximately 1,350 square miles on the central-western side of the San Joaquin Valley, California. Large-scale farming operations in the area have used ground water as the major source of irrigation water for nearly three quarters of a century. In 1968, completion of the San Luis Canal part of the California Aqueduct, made surface water available to farmers. In time the widespread use of this imported water may cause chemical-quality changes in the native ground water. To document conditions prior to any possible changes, 361 samples of ground water were taken before deliveries of surface water were begun. The data will serve as a base to which future investigations can be compared. To establish any trends, the results were compared to earlier chemical data for the area. The results indicated that only minor changes in chemical quality had occurred between 1951 and 1968. Water from an upper water-bearing zone is markedly different from water in a lower water-bearing zone. Water in the upper zone is of various chemical types, and the concentration of dissolved solids increases from east to west across the area. Water in the lower zone is a sodium sulfate type and is fairly consistent throughout the zone.

California↗

Toxicity of hexahydro-1,3,5-trinitro-1,3,5-triazine to larval zebrafish (Danio rerio)

Hexahydro-1,3,5-trinitro-1,3,5-triazine, a cyclonitramine commonly known as RDX, is used in the production of military munitions. Contamination of soil, sediment, and ground and surface waters with RDX has been reported in different places around the world. Acute and subacute toxicities of RDX have been relatively well documented in terrestrial vertebrates, but among aquatic vertebrates the information available is limited. The objective of this study was to characterize the acute toxicity of RDX to larval zebrafish. Mortality (LC50) and incidence of vertebral column deformities (EC50) were two of the end points measured in this study. The 96-h LC50 was estimated at 22.98 and 25.64 mg l-1 in two different tests. The estimated no-observed-effective- concentration (NOEC) values of RDX on lethality were 13.27 ?? 0.05 and 15.32 ?? 0.30 mg l-1; and the lowest-observed-effective- concentration (LOEC) values were 16.52 ?? 0.05 and 19.09 ?? 0.23 mg l-1 in these two tests, respectively. The 96-h EC50 for vertebral deformities on survivors from one of the acute lethality tests was estimated at 20.84 mg l-1, with NOEC and LOEC of 9.75 ?? 0.34 and 12.84 ?? 0.34 mg l-1, respectively. Behavioral aberrations were also noted in this acute toxicity study, including the occurrence of whirling movement and lethargic behavior. The acute effects of RDX on survival, incidence of deformities, and behavior of larval zebrafish occurred at the high end of the most frequently reported concentrations of RDX in aquatic environments. The chronic effects of RDX in aquatic vertebrates need to be determined for an adequate assessment of the ecological risk of environmental RDX. ?? 2005 Elsevier Ltd. All rights reserved.

Chemosphere↗

Hydrogeologic, soil, and water-quality data for j-field, Aberdeen Proving Ground, Maryland, 1989-94

Disposal of chemical-warfare agents, munitions, and industrial chemicals in J-Field, Aberdeen Proving Ground, Maryland, has resulted in ground-water, surface-water, and soil contamination. This report presents data collected by the U.S. Geological Survey from Novembr 1989 through September 1994 as part of a remedial investigation of J-Field in response to the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA). Hydrogeologic data, soil-gas and soil-quality data, and water-qualtiy data are included.

Open-File Report↗

Water resources data Minnesota water year 2001

Water resources data for the 2001 water year for Minnesota consist of records of stage, discharge, and water quality of streams; stage of lakes and reservoirs; ground-water quality; and water quality in wells. This report contains discharge records for 100 stream-gaging stations; stage for 13 lakes and reservoirs; water quality for 24 stream-gaging stations; peak flow data for 88 highflow partial-record stations, and water levels for 4 groundwater observation wells. Additional water data were collected at various sites that are not part of the systematic data collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey for cooperating State and Federal agencies in Minnesota.

Minnesota↗