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At least 1,315 records · Page 73Linked to original sources
USGS2026

Effects of human activity on Khumbu Glacier: Towards a sustainable Everest Base Camp

The Everest Base Camp (EBC), a critical staging area for mountaineers attempting to summit Mount Everest, has seen a significant increase in human activity over the past few decades. The increasing number of climbers, trekkers, and support staff, particularly at the campsite area, has intensified environmental impacts on the Khumbu Glacier. This study investigates the effects of human activity at EBC, focusing on three contributors to glacier melt: global climate change, local fossil fuel consumption, and human urinary discharge. Through field data collected during the spring 2023 climbing season, this study examines the energy released through the use of liquefied petroleum gas (LPG), kerosene, and petrol for cooking, heating, and electricity, as well as the heat generated by human urinary discharge. The total heat energy released from these activities at EBC in the spring of 2023 was 849,174 ± 179,774 MJ, which would be sufficient to melt 2492 ± 528 tons of glacier ice and snow. Trends in land surface temperature at EBC and adjacent environments during the 1991–2023 period were calculated from Landsat 5, 7, and 9 satellite data. The 32-year Landsat record reveals that EBC surface temperature increased by 0.28 °C year −1 , which was roughly twice the rate of warming at the surface of Khumbu Glacier adjacent to EBC and about 15% higher than the temperature increase of the debris-covered terrain immediately to the north of EBC. The findings suggest that addressing these anthropogenic influences could help to preserve the Khumbu Glacier and support the sustainability of mountaineering in the region. This paper also takes a transformative approach and explores stable and safer locations in case there is a necessity to relocate the current EBC. Two sites have been identified southwest of the existing EBC, which, unlike the current supraglacial site, are situated on stable ground.

Everest Base Camp, Khumbu Glacier↗
USGS2013

The effect of sampling rate and anti-aliasing filters on high-frequency response spectra

The most commonly used intensity measure in ground-motion prediction equations is the pseudo-absolute response spectral acceleration (PSA), for response periods from 0.01 to 10 s (or frequencies from 0.1 to 100 Hz). PSAs are often derived from recorded ground motions, and these motions are usually filtered to remove high and low frequencies before the PSAs are computed. In this article we are only concerned with the removal of high frequencies. In modern digital recordings, this filtering corresponds at least to an anti-aliasing filter applied before conversion to digital values. Additional high-cut filtering is sometimes applied both to digital and to analog records to reduce high-frequency noise. Potential errors on the short-period (high-frequency) response spectral values are expected if the true ground motion has significant energy at frequencies above that of the anti-aliasing filter. This is especially important for areas where the instrumental sample rate and the associated anti-aliasing filter corner frequency (above which significant energy in the time series is removed) are low relative to the frequencies contained in the true ground motions. A ground-motion simulation study was conducted to investigate these effects and to develop guidance for defining the usable bandwidth for high-frequency PSA. The primary conclusion is that if the ratio of the maximum Fourier acceleration spectrum (FAS) to the FAS at a frequency f saa corresponding to the start of the anti-aliasing filter is more than about 10, then PSA for frequencies above f saa should be little affected by the recording process, because the ground-motion frequencies that control the response spectra will be less than f saa . A second topic of this article concerns the resampling of the digital acceleration time series to a higher sample rate often used in the computation of short-period PSA. We confirm previous findings that sinc-function interpolation is preferred to the standard practice of using linear time interpolation for the resamplin

Bulletin of Earthquake Engineering↗
USGS2015

Landscape-scale distribution and density of raptor populations wintering in anthropogenic-dominated desert landscapes

Anthropogenic development has great potential to affect fragile desert environments. Large-scale development of renewable energy infrastructure is planned for many desert ecosystems. Development plans should account for anthropogenic effects to distributions and abundance of rare or sensitive wildlife; however, baseline data on abundance and distribution of such wildlife are often lacking. We surveyed for predatory birds in the Sonoran and Mojave Deserts of southern California, USA, in an area designated for protection under the “Desert Renewable Energy Conservation Plan”, to determine how these birds are distributed across the landscape and how this distribution is affected by existing development. We developed species-specific models of resight probability to adjust estimates of abundance and density of each individual common species. Second, we developed combined-species models of resight probability for common and rare species so that we could make use of sparse data on the latter. We determined that many common species, such as red-tailed hawks, loggerhead shrikes, and especially common ravens, are associated with human development and likely subsidized by human activity. Species-specific and combined-species models of resight probability performed similarly, although the former model type provided higher quality information. Comparing abundance estimates with past surveys in the Mojave Desert suggests numbers of predatory birds associated with human development have increased while other sensitive species not associated with development have decreased. This approach gave us information beyond what we would have collected by focusing either on common or rare species, thus it provides a low-cost framework for others conducting surveys in similar desert environments outside of California.

California↗
USGS2008

Biogeochemical response of organic-rich freshwater marshes in the Louisiana delta plain to chronic river water influx

To help evaluate effects of Mississippi River inputs to sustainability of coastal Louisiana ecosystems, we compared porewater and substrate quality of organic-rich Panicum hemitomon freshwater marshes inundated by river water annually for more than 30 years (Penchant basin, PB) or not during the same time (Barataria basin, BB). In the marshes receiving river water the soil environment was more reduced, the organic substrate was more decomposed and accumulated more sulfur. The porewater dissolved ammonium and orthophosphate concentrations were an order of magnitude higher and sulfide and alkalinity concentrations were more than twice as high in PB compared with BB marshes. The pH was higher and dissolved iron concentrations were more than an order of magnitude lower in PB marshes than in BB marshes. The influx of nutrient-rich river water did not enhance end-of-year above-ground standing biomass or vertical accretion rates of the shallow substrate. The differences in porewater chemistry and substrate quality are reasonably linked to the long-term influx of river water through biogeochemical processes and transformations involving alkalinity, nitrate and sulfate. The key factor is the continual replenishment of alkalinity, nitrate and sulfate via overland flow during high river stage each year for several weeks to more than 6 months. This leads to a reducing soil environment, pooling of the phytotoxin sulfide and inorganic nutrients in porewater, and internally generated alkalinity. Organic matter decomposition is enhanced under these conditions and root mats degraded. The more decomposed root mat makes these marshes more susceptible to erosion during infrequent high-energy events (for example hurricanes) and regular low-energy events, such as tides and the passage of weather fronts. Our findings were unexpected and, if generally applicable, suggest that river diversions may not be the beneficial mitigating agent of wetland restoration and conservation that they are anticipated to be. ?? 2008 Springer Science+Business Media B.V.

Biogeochemistry↗
USGS2014

Mechanisms of drift-feeding behavior in juvenile Chinook salmon and the role of inedible debris in a clear water Alaskan stream

Drift-feeding fish are challenged to discriminate between prey and similar-sized particles of debris, which are ubiquitous even in clear-water streams. Spending time and energy pursuing debris mistaken as prey could affect fish growth and the fitness potential of different foraging strategies. Our goal was to determine the extent to which debris influences drift-feeding fish in clear water under low-flow conditions when the distracting effect of debris should be at a minimum. We used high-definition video to measure the reactions of drift-feeding juvenile Chinook salmon (Oncorhynchus tshawytscha) to natural debris and prey in situ in the Chena River, Alaska. Among all potential food items fish pursued, 52 % were captured and quickly expelled from the mouth, 39 % were visually inspected but not captured, and only 9 % were ingested. Foraging attempt rate was only moderately correlated with ingestion rate (Kendall’s τ = 0.55), raising concerns about the common use of foraging attempts as a presumed index of foraging success. The total time fish spent handling debris increased linearly with foraging attempt rate and ranged between 4 and 25 % of total foraging time among observed groups. Our results help motivate a revised theoretical view of drift feeding that emphasizes prey detection and discrimination, incorporating ideas from signal detection theory and the study of visual attention in cognitive ecology. We discuss how these ideas could lead to better explanations and predictions of the spatial behavior, prey selection, and energy intake of drift-feeding fish.

Alaska↗
USGS2014

Temperature effects induced by climate change on the growth and consumption by salmonines in Lakes Michigan and Huron

We used bioenergetics models to investigate temperature effects induced by climate change on the growth and consumption by Chinook salmon Oncorhynchus tshawytscha , lake trout Salvelinus namaycush , and steelhead O. mykiss in Lakes Michigan and Huron. We updated biological inputs to account for recent changes in the food webs and used temperature inputs in response to regional climate observed in the baseline period (1964–1993) and projected in the future period (2043–2070). Bioenergetics simulations were run across multiple age-classes and across all four seasons in different scenarios of prey availability. Due to the increased capacity of prey consumption, future growth and consumption by these salmonines were projected to increase substantially when prey availability was not limited. When prey consumption remained constant, future growth of these salmonines was projected to decrease in most cases but increase in some cases where the increase in metabolic cost can be compensated by the decrease in waste (egestion and excretion) loss. Consumption by these salmonines was projected to increase the most during spring and fall when prey energy densities are relatively high. Such seasonality benefits their future growth through increasing annual gross energy intake. Our results indicated that lake trout and steelhead would be better adapted to the warming climate than Chinook salmon. To maintain baseline growth into the future, an increase of 10 % in baseline prey consumption was required for Chinook salmon but considerably smaller increases, or no increases, in prey consumption were needed by lake trout and steelhead.

Lake Huron, Lake Michigan↗
USGS2019

Energetic status and bioelectrical impedance modeling of Arctic grayling Thymallus arcticus in interior Alaska Rivers

The energetic status of fishes represents energy stored as protein and lipids and reflects the ability of an individual to reproduce, migrate, and transition through life stages, ultimately influencing survival. However, traditional measurement methods, while highly accurate, are time consuming, expensive, and lethal, and nonlethal methods such as condition factor may not adequately characterize energetic status. We collected 161 Arctic grayling ( Thymallus arcticus ) from four interior Alaska river basins with varying hydrologic regimes during early summer and autumn seasons, and used multiple regression and model selection to evaluate the efficacy of bioelectrical impedance analysis (BIA), a nonlethal condition assessment method, to predict percent dry mass and percent lipid content estimated from proximate analysis. We found that Arctic grayling energetic status varied across seasons, by sex, and fish from sites with spawning runs of Pacific salmon had higher energy content than those from sites without salmon, potentially due to the influence of salmon-derived food subsidies. Electrical measurements explained 82% and 80% of the variability in percent dry mass and percent total lipids, respectively, and top models showed high predictive performance (observed vs. predicted root mean squared error ≤2.2%). Overall, we found the BIA approach to provide rapid, precise, and non-lethal estimates of Arctic grayling body condition. Such an approach may be useful for future work to characterize Arctic grayling bioenergetics and monitor fish condition under a rapidly changing Arctic environment.

Alaska↗
USGS2012

The influence of external subsidies on diet, growth and Hg concentrations of freshwater sport fish: implications for management and fish consumption advisories

Mercury (Hg) contamination in sport fish is a global problem. In freshwater systems, food web structure, sport fish sex, size, diet and growth rates influence Hg bioaccumulation. Fish stocking is a common management practice worldwide that can introduce external energy and contaminants into freshwater systems. Thus, stocking can alter many of the factors that influence Hg concentrations in sport fish. Here we evaluated the influence of external subsidies, in the form of hatchery-raised rainbow trout Oncorhynchus mykiss on walleye Sander vitreus diet, growth and Hg concentrations in two freshwater systems. Stocking differentially influenced male and female walleye diets and growth, producing a counterintuitive size-contamination relationship. Modeling indicated that walleye growth rate and diet were important explanatory variables when predicting Hg concentrations. Thus, hatchery contributions to freshwater systems in the form of energy and contaminants can influence diet, growth and Hg concentrations in sport fish. Given the extensive scale of fish stocking, and the known health risks associated with Hg contamination, this represents a significant issue for managers monitoring and manipulating freshwater food web structures, and policy makers attempting to develop fish consumption advisories to protect human health in stocked systems.

Ecotoxicology↗
USGS2020

Resource segregation at fine spatial scales explains Karner blue butterfly (Lycaeides melissa samuelis) distribution

The resource concentration hypothesis predicts that herbivorous insect density scales positively with plant density because insects are better able to identify, and remain longer in, patches with denser plant resources. While some studies support this hypothesis, others do not. Different explanations have been proposed for this discrepancy, including variation in insect dispersal ability and diet breadth. We test the resource concentration hypothesis using the Karner blue butterfly ( Lycaeides melissa samuelis ), a specialist that relies on wild blue lupine ( Lupinus perennis ) as its sole host plant. We extended this hypothesis to test whether Karner blue density also scales positively with nectar plant resources. Our findings did not support the resource concentration hypothesis and demonstrate that the spatial segregation of nectar and host plant resources relative to each other can influence the location and abundance of Karner blues on the landscape. This is because the location of resources relative to each other influences the energy and time butterflies expend for flight activity, and thereby influences resource acquisition. During early summer when first brood Karner blues emerge, nectar and host plants were spatially segregated, and Karner blue density peaked at intermediate densities of nectar and host plants occurring at ratios approximately equal to 1:1. During late summer, we found no significant relationships between second brood Karner blues and nectar plants or host plants when there was no correlation between nectar and host plants. Conservation practitioners of specialist insects with low vagility can strategically manage the distribution of plant resources to minimize insect time and energy expenditure and promote resource acquisition for all of an insect’s life stages.

Journal of Insect Conservation↗
USGS2005

Landscape characteristics of Rhizophora mangle forests and propagule deposition in coastal environments of Florida (USA)

Field dispersal studies are seldom conducted at regional scales even though reliable information on mid-range dispersal distance is essential for models of colonization. The purpose of this study was to examine the potential distance of dispersal of Rhizophora mangle propagules by comparing deposition density with landscape characteristics of mangrove forests. Propagule density was estimated at various distances to mangrove sources (R. mangle) on beaches in southwestern Florida in both high-and low-energy environments, either facing open gulf waters vs. sheltered, respectively. Remote sensing and Geographic Information Systems were used to identify source forests and to determine their landscape characteristics (forest size and distance to deposition area) for the regression analyses. Our results indicated that increasing density of propagules stranded on beaches was related negatively to the distance of the deposition sites from the nearest stands of R. mangle and that deposition was greatly diminished 2 km or more from the source. Measures of fragmentation such as the area of the R. mangle forests were related to propagule deposition but only in low-energy environments. Our results suggest that geographic models involving the colonization of coastal mangrove systems should include dispersal dynamics at mid-range scales, i.e., for our purposes here, beyond the local scale of the forest and up to 5 km distant. Studies of mangrove propagule deposition at various spatial scales are key to understanding regeneration limitations in natural gaps and restoration areas. Therefore, our study of mid-range propagule dispersal has broad application to plant ecology, restoration, and modeling. ?? Springer 2005.

Landscape Ecology↗
USGS2019

Individual based modelling of fish migration in a 2-D river system: Model description and case study

Context: Diadromous fish populations in the Pacific Northwest face challenges along their migratory routes from declining habitat quality, harvest, and barriers to longitudinal connectivity. These stressors complicate the prioritization of proposed management actions intended to improve conditions for migratory fishes including anadromous salmon and trout. Objectives: We describe a multi-scale hybrid mechanistic–probabilistic simulation model linking migration corridor conditions to fish fitness outcomes. We demonstrate the model’s utility using a case study of salmon and steelhead adults in the Columbia River migration corridor exposed to spatially- and temporally-varying stressors. Methods: The migration corridor simulation model is based on a behavioral decision tree that governs individual interactions with the environment, and an energetic submodel that estimates the hourly costs of migration. Emergent properties of the migration corridor simulation model include passage time, energy use, and survival. Results: We observed that the simulated fish’s initial energy density, the migration corridor temperatures they experienced, and their history of behavioral thermoregulation were the primary determinants of their fitness outcomes. Insights gained from use of the model might be exploited to identify management interventions that increase successful migration outcomes. Conclusions: This paper describes new methods that extend the suite of tools available to aquatic biologists and conservation practitioners. We have developed a 2-dimensional spatially-explicit behavioral and physiological model and illustrated how it can be used to simulate fish migration within a river system. Our model can be used to evaluate trade-offs between behavioral thermoregulation and fish fitness at population scales.

Landscape Ecology↗
USGS2005

Fundamental challenges to methane recovery from gas hydrates

The fundamental challenges, the location, magnitude, and feasibility of recovery, which must be addressed to recover methane from dispersed hydrate sources, are presented. To induce dissociation of gas hydrate prior to methane recovery, two potential methods are typically considered. Because thermal stimulation requires a large energy input, it is less economically feasible than depressurization. The new data will allow the study of the effect of pressure, temperature, diffusion, porosity, tortuosity, composition of gas and water, and porous media on gas-hydrate production. These data also will allow one to improve existing models related to the stability and dissociation of sea floor hydrates. The reproducible kinetic data from the planned runs together with sediment properties will aid in developing a process to economically recover methane from a potential untapped hydrate source. The availability of plentiful methane will allow economical and large-scale production of methane-derived clean fuels to help avert future energy crises.

Topics in Catalysis↗
USGS2011

Assessment of two nonnative poeciliid fishes for monitoring selenium exposure in the endangered desert pupfish

We assessed the suitability of two nonnative poeciliid fishes—western mosquitofish ( Gambusia affinis ) and sailfin mollies ( Poecilia latipinna )—for monitoring selenium exposure in desert pupfish ( Cyprinodon macularius ). Our investigation was prompted by a need to avoid lethal take of an endangered species (pupfish) when sampling fish for chemical analysis. Total selenium (SeTot) concentrations in both poeciliids were highly correlated with SeTot concentrations in pupfish. However, mean SeTot concentrations varied among fish species, with higher concentrations measured in mosquitofish than in mollies and pupfish from one of three sampled agricultural drains. Moreover, regression equations describing the relationship of selenomethionine to SeTot differed between mosquitofish and pupfish, but not between mollies and pupfish. Because selenium accumulates in animals primarily through dietary exposure, we examined fish trophic relationships by measuring stable isotopes ( δ 13 C and δ 15 N) and gut contents. According to δ 13 C measurements, the trophic pathway leading to mosquitofish was more carbon-depleted than trophic pathways leading to mollies and pupfish, suggesting that energy flow to mosquitofish originated from allochthonous sources (terrestrial vegetation, emergent macrophytes, or both), whereas energy flow to mollies and pupfish originated from autochthonous sources (filamentous algae, submerged macrophytes, or both). The δ 15 N measurements indicated that mosquitofish and mollies occupied similar trophic levels, whereas pupfish occupied a slightly higher trophic level. Analysis of gut contents showed that mosquitofish consumed mostly winged insects (an indication of terrestrial taxa), whereas mollies and pupfish consumed mostly organic detritus. Judging from our results, only mollies (not mosquitofish) are suitable for monitoring selenium exposure in pupfish.

Water, Air, & Soil Pollution↗
USGS2019

A mosaic of estuarine habitat types with prey resources from multiple environmental strata supports a diversified foraging portfolio for juvenile Chinook salmon

Estuaries provide vital nursery habitat for threatened Chinook salmon (Oncorhynchus tshawytscha) by promoting an ecological portfolio effect, whereby multiple habitat types and environmental strata maximize foraging opportunities for out-migrating salmon by varying the abundance and composition of prey through space and time. To study this portfolio effect, we evaluated the foraging capacity of five estuarine habitat types within the Nisqually River Delta (Puget Sound, Washington, USA). Within each habitat, we sampled invertebrate prey resources from the terrestrial, aquatic, benthic, and epifaunal strata and compared them to juvenile salmon diets from corresponding sampling events. We found that the emergent salt marsh supplied twice as much aquatic prey biomass as any other habitat (720–5523 mg/m3), followed by the mudflat (246–2543 mg/m3) and eelgrass (Zostera marina; 141–2694 mg/m3) habitats. Despite some evidence for selectivity, juvenile salmon diets exhibited substantial compositional overlap, especially when compared to among-habitat differences in available prey resources. Fish that were captured in salt marsh, mudflat, and eelgrass consumed aquatic crustaceans such as mysids, while fish captured upriver in forested and transitional marshes ate a higher proportion of adult and larval insects. The availability and consumption of greater quantities of energy-poor crustaceans in the salt marsh and lower quantities of energy-rich insects upriver highlights a quantity-for-quality tradeoff among estuarine habitats. Our findings indicate that the timing, productivity, and diversity of prey across multiple habitat types and environmental strata determine an estuary’s capacity to support foraging for multiple life history strategies, size classes, and cohorts of juvenile salmon.

Washington↗
USGS2024

Identifying and constraining marsh-type transitions in response to increasing erosion over the past century

Marsh environments, characterized by their flora and fauna, change laterally in response to shoreline erosion, water levels and inundation, and anthropogenic activities. The Grand Bay coastal system (USA) has undergone multiple large-scale geomorphic and hydrologic changes resulting in altered sediment supply, depositional patterns, and degraded barrier islands, leaving wetland salt marshes vulnerable to increased wave activity. Two shore-perpendicular transect sites, one along a low-activity shoreline and the other in a high activity area of the same bay-marsh complex, were sampled to investigate how the marshes within 50 m of the modern shoreline have responded to different levels of increased wave activity over the past century. Surface sediments graded finer and more organic with increased distance from the shoreline while cores generally exhibited a coarsening upwards grain-size trend; all cores contained multiple large sedimentological shifts. 210 Pb-based mass accumulation rates over the last two decades were greater than the long-term (centurial) average at each site with the fastest accumulation rates of 7.81 ± 1.58 and 7.79 ± 1.63 kg/m 2 /year at the sites nearest the shoreline. A shoreline change analysis of three time-slices (1848–2017, 1957–2017, 2016–2017) shows increased erosion at both sites since 1848 with modern rates of −0.95 and −0.88 m/year. Downcore sedimentology, mass accumulation rates, and shoreline change rates paired with foraminiferal biofacies and identification of local estuarine indicator species, Paratrochammina simplissima , aided in identifying paleo marsh types, their relative proximity to the shoreline, and sediment provenance. The high-energy marsh site transitioned from middle marsh to low marsh in the 1960s, and the low-energy marsh site transitioned later, at the end of the twentieth and early twenty-first century, due to its more protected location. Marsh type transition corresponds chronologically with the coarsening upwards grain-size trend observed and the degradation of Grand Batture Island; since its submergence, signatures of multiple storm event have been preserved downcore.

Mississippi↗
USGS2014

Evaluating abiotic influences on soil salinity of inland managed wetlands and agricultural croplands in a semi-arid environment

Agriculture and moist-soil management are important management techniques used on wildlife refuges to provide adequate energy for migrant waterbirds. In semi-arid systems, the accumulation of soluble salts throughout the soil profile can limit total production of wetland plants and agronomic crops and thus jeopardize meeting waterbird energy needs. This study evaluates the effect of distinct hydrologic regimes associated with moist-soil management and agricultural production on salt accumulation in a semi-arid floodplain. We hypothesized that the frequency of flooding and quantity of floodwater in a moist-soil management hydroperiod results in a less saline soil profile compared to profiles under traditional agricultural management. Findings showed that agricultural croplands differed ( p -value < 0.001, df = 9) in quantities of total soluble salts (TSS) compared to moist-soil impoundments and contained greater concentrations (TSS range = 1,160-1,750 (mg kg-1)) at depth greater than 55 cm below the surface of the profile, while moist-soil impoundments contained lower concentrations (TSS range = 307-531 (mg kg-1)) at the same depths. Increased salts in agricultural may be attributed to the lack of leaching afforded by smaller summer irrigations while larger periodic flooding events in winter and summer flood irrigations in moist-soil impoundments may serve as leaching events.

Wetlands↗
USGS2016

On the sustainability of inland fisheries: Finding a future for the forgotten

At present, inland fisheries are not often a national or regional governance priority and as a result, inland capture fisheries are undervalued and largely overlooked. As such they are threatened in both developing and developed countries. Indeed, due to lack of reliable data, inland fisheries have never been part of any high profile global fisheries assessment and are notably absent from the Sustainable Development Goals. The general public and policy makers are largely ignorant of the plight of freshwater ecosystems and the fish they support, as well as the ecosystem services generated by inland fisheries. This ignorance is particularly salient given that the current emphasis on the food-water-energy nexus often fails to include the important role that inland fish and fisheries play in food security and supporting livelihoods in low-income food deficit countries. Developing countries in Africa and Asia produce about 11 million tonnes of inland fish annually, 90 % of the global total. The role of inland fisheries goes beyond just kilocalories; fish provide important micronutrients and essentially fatty acids. In some regions, inland recreational fisheries are important, generating much wealth and supporting livelihoods. The following three key recommendations are necessary for action if inland fisheries are to become a part of the food-water-energy discussion: invest in improved valuation and assessment methods, build better methods to effectively govern inland fisheries (requires capacity building and incentives), and develop approaches to managing waters across sectors and scales. Moreover, if inland fisheries are recognized as important to food security, livelihoods, and human well-being, they can be more easily incorporated in regional, national, and global policies and agreements on water issues. Through these approaches, inland fisheries can be better evaluated and be more fully recognized in broader water resource and aquatic ecosystem planning and decision-making frameworks, enhancing their value and sustainability for the future.

Ambio↗
USGS1969

Thermochemical study of the system Fe-As-S

The results of Toulmin and Barton (1964) for the Fe-S system have been combined with a series of new measurements on As-bearing assemblages in the 500°–850°C temperature range to derive data on the free energies, enthalpies, and entropies of formation for arsenopyrite, loellingite, orpiment, realgar, FeAs, and Fe 2 As. The enthalpies and free energies of formation of orpiment and realgar are only approximately one-half as large as indicated in recent compilations of thermochemical data ( Wagman et al ., 1965). Data are also presented for the covariation of activity of S 2 (g) with temperature and composition of the sulfur-arsenic liquid.

Geochimica et Cosmochimica Acta↗