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Fiber-imaged supershear dynamics in the 2024 Mw 7 Mendocino Fault earthquake

Fault structure and rupture physics are deeply intertwined, and observations of this coupling are critical for understanding earthquake behavior. Rupture propagation is observable at fine scales using dense seismic networks. Fiber-optic sensing allows for long-term deployments of ultradense arrays that enable high-resolution measurements of infrequent, large earthquakes. We recorded the 2024 moment magnitude ( M w ) 7 Mendocino Fault earthquake with a nearby fiber-optic array and imaged its behavior with seismic beamforming. The rupture propagated to the east at subshear velocity; stagnated near the Mendocino Triple Junction, a zone of structural complexity; and subsequently transitioned to supershear velocity. The correlation between source physics and structure shows how lithospheric heterogeneity affects first-order characteristics of earthquake ruptures. Our results also demonstrate the potential for fiber-optic sensing to improve real-time estimation of key parameters for early warning.

California

Evidence for offset of Cretaceous plutons by the Tintina fault in eastern Alaska: Implications for regional metallogeny

Cretaceous magmatism in eastern interior Alaska is voluminous, but temporally and spatially diverse – suggestive of varying sources and drivers. More than 150 new U-Pb zircon and more than 500 geochemical analyses of Cretaceous plutonic units allow for the grouping of distinct plutonic suites. Magmatism was continuous from 120-66 Ma but can be grouped into temporally distinct pulses from ca. 115-100 Ma, 100-90 Ma, and 75-66 Ma. Geochemical diversity occurs during each pulse, further distinguishing multiple suites. Diverse metallogenic epochs are strongly correlated to pluton chemistry. Mineralization is largely absent prior to 108 Ma. From 108-100 Ma, plutonism is coeval with sparse, but notable Au-quartz veins with variable Bi, As, W, and Mo. From 100-90 Ma, intrusion-related mineralization zones from Au-Cu(-Bi) and U-Th in the northwest to central Au- Bi-As-Te(-W), and Mo-W to the southeast. Porphyry style Cu-Mo(-Au) occurrences occur with the latest Cretaceous plutons emplaced from 75-66 Ma . Restoration of ~450 km of dextral movement on the Tintina fault and comparison of metallogenic and geochemical characteristics of Alaska plutons suggest 100-90 Ma plutons may be the continuation of the metallogenically significant Tombstone, Mayo, and Tungsten suites from the Yukon.

Alaska

Uranium—Deposits, production and resources, market dynamics, and supply chain risks

Introduction Interest in nuclear power for the generation of electricity has risen with the increase in the need for more diverse baseload power, enhanced energy security, and the development of new technologies, such as small modular reactors (SMRs), which could provide power for remote areas, industrial applications, and artificial intelligence (AI) data centers. In 2024, the U.S. Department of Energy received $2.7 billion in congressional funding to bolster the domestic uranium production and nuclear fuel supply chain and address reliance on imports from foreign suppliers. In 2025, the U.S. Government issued several Executive and Secretary’s orders aimed at revitalizing the U.S. nuclear sector. If SMRs are to be as widely deployed in the United States and worldwide as envisioned, demand for uranium (nuclear reactor fuel) will likely increase. After the Fukushima nuclear accident in 2011, the market spot price of uranium began a decline, followed by a decrease in U.S. and global uranium exploration and mine development expenditures that led to a uranium supply deficit until 2020, when prices started to recover, prompting a resurgence in uranium exploration and development. In January of 2024, the uranium spot price rose to a 17-year high $106 (U.S. dollars) per pound of U3O8 (triuranium oxide, commonly known as “yellowcake”), which is expected to increase uranium exploration, mine development, and uranium production domestically and worldwide.

Fact Sheet

Characterizing changes in postfire debris-flow hazard as burned areas recover

Emergency assessments of postfire debris-flow hazards that are performed by the U.S. Geological Survey (USGS) provide estimates of debris-flow likelihood and rainfall triggering conditions that are used for evaluating and managing runoff-generated debris-flow hazards in recently burned areas throughout the western United States. Although the immediate postfire period, within roughly one year after fire, is typically the most susceptible to runoff-generated debris flows, the hazard evolves in time and space as the burned area recovers. The recovery trajectory a given burned area will take depends on local climate and weather and can be difficult to predict. Some burned areas recover quickly, whereas others experience debris flows for multiple years after fire. As a result, extending our ability to update debris-flow likelihood estimates and rainfall thresholds based on observed recovery of the burned area would be beneficial. We present a method for multi-year runoff-generated debris-flow hazard assessment that leverages the USGS “M1” debris-flow likelihood model and integrates updated, satellite-derived, normalized burn ratio data to estimate vegetation recovery. We predict recovery-aware rainfall thresholds and validate them against a multi-year debris-flow hazard prediction and could be adapted for use with other debris-flow models that incorporate burn severity data.

Arizona, California, Colorado, New Mexico, Washing

Continuous hydrologic simulation of runoff for the Middle Fork and South Fork of the Beargrass Creek basin in Jefferson County, Kentucky

The Hydrological Simulation Pro-gram-FORTRAN (HSPF) was applied to an urban drainage basin in Jefferson County, Ky to integrate the large amounts of information being collected on water quantity and quality into an analytical framework that could be used as a management and planning tool. Hydrologic response units were developed using geographic data and a K-means analysis to characterize important hydrologic and physical factors in the basin. The Hydrological Simulation Program FORTRAN Expert System (HSPEXP) was used to calibrate the model parameters for the Middle Fork Beargrass Creek Basin for 3 years (June 1, 1991, to May 31, 1994) of 5-minute streamflow and precipitation time series, and 3 years of hourly pan-evaporation time series. The calibrated model parameters were applied to the South Fork Beargrass Creek Basin for confirmation. The model confirmation results indicated that the model simulated the system within acceptable tolerances. The coefficient of determination and coefficient of model-fit efficiency between simulated and observed daily flows were 0.91 and 0.82, respectively, for model calibration and 0.88 and 0.77, respectively, for model confirmation. The model is most sensitive to estimates of the area of effective impervious land in the basin; the spatial distribution of rain-fall; and the lower-zone evapotranspiration, lower-zone nominal storage, and infiltration-capacity parameters during recession and low-flow periods. The error contribution from these sources varies with season and antecedent conditions.

Kentucky

Geophysical characterization of mine influenced groundwater and surface water in the Mayflower section of the Animas River, Bonita Peak Mining District, Silverton Colorado

This report details findings from geophysical investigations to identify possible groundwater - surface water interactions near the Mayflower Section of the Animas River in Silverton, Colorado. The Mayflower Section is a mine influenced Superfund Site in Colorado. This investigation utilized electromagnetic induction (EM or EMI), magnetic, and fiber optic distributed temperature system (FODTS) geophysical methods to measure the bulk earth electrical conductivity, magnetic susceptibility, and temperature of specific surveyed volumes of the earth near the Mayflower Section of the Animas River. These physical parameters are used to understand the groundwater – surface water interactions, which can guide decision makers in their assessment of mine-impacted surface water. This report details the results from characterization and monitoring technologies to provide high data density and continuous monitoring of bulk earth electrical conductivity and temperature in the Mayflower section of the Animas River to identify zones of groundwater – surface water interactions and potential metal loading from mine influenced water. The investigation separated right and left bank characterization for each method and indicates more groundwater is entering from the right bank than the left bank and these predominantly right bank discharges potentially contain metal-rich water compared to the left bank. Results also indicate mineral veins facilitate preferential groundwater discharge to the river due to possible jointing, fractures, and permeability differences sometimes occurring along veins relative to host rock. For example, Boulder Gulch is likely groundwater dominated and may be receive water impacted by Mayflower Impoundments #1 and #2. Additionally, the beaver ponds near Blair Gulch may influence groundwater discharge and Mayflower Impoundment #4 is possibly impacting groundwater and surface water and may be connected to the wetlands to the west of the impoundment. These data could be further analyzed for smaller spatial scale analysis within areas of interest. The identification of these locations along sections of the river likely impacted by mine influenced groundwater potentially entering the Animas River and can be used by site investigators, decision makers, and stakeholders in mitigation decisions and strategies.

Colorado

Using the D-Claw software package to model lahars in the Middle Fork Nooksack River drainage and beyond, Mount Baker, Washington

Lahars, or volcanic mudflows, are the most hazardous eruption-related phenomena that will affect communities living along rivers that originate on Mount Baker. In the past 15,000 years, the largest lahars from Mount Baker have affected the Middle Fork Nooksack River drainage and beyond. Here we use the physics-based D-Claw software package to model nine lahar scenarios that are initiated as water-saturated landslides between Sherman Crater and the Roman Wall on the Mount Baker edifice and flow down the Middle Fork Nooksack River. The scenarios range in volume from 1 to 260 million cubic meters and have an initial hydraulic permeability from 10 −12 to 10 −10 meters squared. Model output includes data such as flow depth, velocity, runout distance, area inundated, arrival time, and sediment concentration as well as information that allows scientists to calculate other important hydrologic characteristics such as lahar discharge. These data are important to officials who have the responsibility to plan for, or take mitigation measures against, future Mount Baker lahars. To check the validity of the D-Claw results, we compare the scenarios to known geologic information. We also compare D-Claw results with empirical models that have been used in the past to determine potential inundation areas, runout distances, and arrival times. These comparisons highlight similarities and differences between empirical and physics-based models. We also present D-Claw scenario-based animations to help scientists, officials, and lay people alike to visualize how future lahars could affect communities.

Washington

Site response and wave propagation effects in the eastern United States

Fourier amplitude spectra from regional earthquakes in the eastern United States are used in a parametric inversion for source, path, and site effects. Five earthquakes are selected for analysis during the installation of the United States National Seismic Network (US), Earthscope’s USArray Transportable Array (TA), and other temporary arrays to maximize station coverage. A global search algorithm is used to solve for site response from 0.1 to 15 Hz, corner frequency, geometrical spreading ( r - γ ), and frequency dependent anelastic attenuation in the form Q(f) = Q o f α . Tradeoff between moment and geometric spreading is handled by fixing the moment. The tradeoff between corner frequency and Q(f) is solved by selecting the value of corner frequency that minimizes an objective function defined over all stations. Values of site response and attenuation parameters show a strong spatial correlation with the physiographic provinces of the eastern United States. Site response for the Atlantic Coastal Plain is consistent with previous work using spectral ratios relative to a reference site, defined by strong resonance peaks correlated with the thickness of sediments. Site response for the other physiographic provinces is markedly different from the coastal plain, with a lack of distinct resonance peaks and a broad moderate high at frequences from 0.1 to 0.5 Hz consistent with the hard-rock geology of the regions. Like site response, Q(f) has a strong correlation with physiographic province, showing lower values on the coastal plain and higher values inland. Geometric spreading exponent, γ, decreases with increasing hypocenter distance from just above 1 at a few tens of kilometers to 0.9 at 500 km. The limited range in geometric spreading values is attributed to starting the Fourier transform window at the S ‐wave arrival for all distances and averaging over multiple wave types.

eastern United States

Surface variable‐based machine learning for scalable arsenic prediction in undersampled areas

In the United States, private wells are not federally regulated, and many households do not test for Arsenic (As). Chronic exposure is linked with multiple health outcomes, and risk can change sharply over short distances and with well depth. Coarse maps or sparse sampling often miss exceedances. Most existing models operate at ∼1 km resolution and use groundwater chemistry or detailed geologic logs, which limits their use in undersampled areas where improved guidance is most needed. We overcome these limitations by developing a machine learning model for Minnesota, USA, that predicts As exposure risk using only surficial variables from remote sensing and global data sets. Variables related to surface water hydrology and geomorphology are selected based on mechanistic links that control redox conditions and As mobilization. Local training was essential, and surficial geology variables that are more sensitive to local conditions were needed to maximize model accuracy. The resulting complete model was sufficiently sensitive to generate accurate and detailed risk maps and depth profiles of As concentrations above the 10 μg/L maximum contaminant level. Accuracy depended on local training data density. We identified a training data density of 0.07 wells/km 2 as a practical target for stable county-level performance. Maps of exceedance probabilities highlight priority areas for testing that are particularly important in rural communities that have received less sampling. These results support public health action by guiding where to install wells and where to test them, how much new sampling is needed, and where treatment outreach is most urgent.

Minnesota

Diverging mineral chemistry of iron and nickel throughout Earth’s changing redox conditions reveals foundation for their evolution as protein cofactors

Iron (Fe) and nickel (Ni) were both foundational to early metabolism, yet their biological trajectories diverged as Earth’s surface redox state changed. Here, we integrate mineral chemistry network analysis, protein metal-site coordination-sphere analysis, and curated redox comparisons to test how geochemistry and metalloprotein architecture co-evolved. Mineral network analyses show broader electronegativity variation and network diversity for Fe-bearing minerals through time relative to Ni-bearing minerals. In structural analyses of protein metal centers in a combined Fe/Ni protein structure set, it is shown that Fe- and Ni-associated environments differ in amino-acid composition, hydropathy structure, and cysteine representation. The greater chemical diversity and electronegativity variation in Fe minerals mirror the higher redox and structural versatility of Fe-binding proteins. The presence of Fe in a broader range of mineral and protein environments demonstrates the chemical adaptability of the metal, from the anoxic Archean to oxidative Earth surface conditions following the Great Oxidation Event. Iron, with its broad redox potential range in Fe-oxidoreductases, has a central role in both anaerobic and aerobic metabolisms. Nickel, by contrast, is less widespread in biology. Today, Ni is predominantly employed in deeply branching anaerobic pathways and by proteins with narrower redox potential ranges. Our results show that evolutionary processes, constrained by metal chemistry, habitually utilize Fe as a redox generalist while retaining Ni in specialized roles. The divergent paths of Ni and Fe, from rocks to proteins, demonstrate the intimate relationship between planetary geochemistry and metabolic origins on Earth and suggest that Fe/Ni geochemistry may inform habitability assessments in extraterrestrial environments when interpreted within specific planetary environmental contexts.

Life

Unraveling protracted modification of Archean and Paleoproterozoic crust in central Laurentia, Penokean orogen, with garnet and accessory mineral geochronology and microstructural analysis

Proterozoic metamorphism and deformation of the southern margin of the Superior craton in the Lake Superior region is attributed to the Penokean orogeny (1890−1830 Ma). This model includes a period of crustal inversion in which Archean basement blocks were exhumed through overlying Paleoproterozoic strata, producing the corridor of gneiss domes that parallels the trend of the Penokean orogen across the northern Midcontinent, USA. However, recent geologic mapping and 40 Ar/ 39 Ar geochronology challenge this interpretation, suggesting instead that the gneiss dome structures reflect younger episodes of tectonic activity along the southern margin of Laurentia. In absence of integrated pressure-temperature-time-deformation constraints for these rocks, interpretations are largely limited to their final cooling history, making it difficult to both identify the tectonic forces that shaped the architecture of the Penokean orogenic belt and assess the extent to which later Proterozoic tectonism modified the southern Superior craton. We address this problem with an approach joining thermodynamic modeling, garnet and accessory mineral geochronology, and microstructural analysis for several metamorphic rocks across the gneiss dome corridor. The U-Pb ages of titanite reveal that the Proterozoic geometries of exhumed basement gneiss domes are governed by preexisting Archean structures. Garnet Lu-Hf geochronology constrains the timing of prograde-to-peak metamorphism in the Penokean orogenic belt. Granulite facies metamorphism is related to the final stages of the Penokean orogeny at 1837 Ma and localized in a belt of high-grade rocks near a major Penokean suture. Garnet Lu-Hf ages of samples adjacent to gneiss domes reflect regional metamorphism following the accretionary phase of the Penokean orogeny, between 1825 Ma and 1782 Ma, which we suggest reflects continued crustal thickening related to convergence farther south during this time interval. Combination of garnet microstructures and Sm-Nd ages reflects later exhumation of gneiss domes and buried metasedimentary rocks by ca. 1750 Ma, consistent with previously published 40 Ar/ 39 Ar cooling ages across the region. Reset Lu-Hf and Sm-Nd garnet ages and U-Pb ages of syn-kinematic titanite reflect reactivation of primary Penokean structures during this period of basement uplift. These data document significant modification of the Penokean orogen and the Archean crust of the southern Superior province between 1800 Ma and 1700 Ma. Tectonic activity during this interval coincides with collisional events recognized in western Laurentia, suggesting that the period immediately following the Penokean orogeny may be a broadly important time for crustal growth and modification in proto-North America.

Michigan, Wisconsin

Identifying overlap between native fish movements and a possible seasonal Grass Carp deterrent in the Sandusky River, Ohio, USA

Riverine fishes are vulnerable to habitat fragmentation caused by interrupted access to vital habitats. Fragmentation using artificial structures can be used to limit the spread of invasive fishes by inhibiting movement between critical habitats. Thus, tradeoffs exist between maintaining connectivity for native species and restricting movement of invasive fishes. A nonphysical deterrent has been proposed to prevent invasive Grass Carp ( Ctenopharyngodon idella ) from reaching spawning habitats in the Sandusky River, a tributary to Lake Erie, during late spring–summer. However, this timing overlaps with spawning periods of a suite of native fishes. We used acoustic telemetry and ichthyoplankton surveys to examine movement and spawning activity of multiple native species and to assess potential impacts of deterrent operation on reproduction. All species used the proposed deterrent location during the Grass Carp spawning period, and their movements corresponded with larval fish collections, indicating upstream spawning. These findings suggest the deterrent could unintentionally restrict native species’ access to essential habitats. Balancing habitat connectivity and invasive species control will likely depend on species-specific responses and careful timing of deterrent operation.

Ohio

The impact of burial diagenesis on soil-formed minerals in paleosols using stable isotopes of phyllosilicates and carbonate clumped isotopes

To understand the effects of burial diagenesis on the stable isotope geochemistry of soil-formed clay and carbonate minerals in paleosols, samples were collected from seven cores, spanning middle- to upper-Pennsylvanian strata of the Illinois Basin, with varied maximum burial depths of 1–3 km. Mixed-layer illite-smectite and kaolinite mixtures give δ 2 H and δ 18 O values of −83 ‰ to −36 ‰ and 11.9 ‰ to 21.1 ‰ (VSMOW), respectively. After carbonates were screened petrographically for diagenetic textures using transmitted light and cathodoluminescence, measured clumped isotope Δ 47 values range from 0.504 to 0.563 ‰ (I-CDES). Resulting mineral formation temperatures for phyllosilicate mineral mixtures are 28 to 66 °C (mean = 47 °C), whereas T(Δ 47 ) estimates for calcites are 36 to 61 °C (mean = 45 °C). Calculated δ 18 O water values from which phyllosilicate minerals and calcites precipitated under isotopic equilibrium ranges from −7.1 to −1.2 ‰ and − 1.4 to +4.9 ‰, respectively. Closed and open-system phyllosilicate-fluid exchange modeling indicates that phyllosilicate alteration occurred in the presence of a low temperature brine or meteoric water and is interpreted to occur in a layer-by-layer illitization transformation. Due to the lack of diagenetic textures and positively correlated T(Δ 47 ) and δ 18 O water , calcites are interpreted to have undergone solid-state bond reordering. Despite low to moderate temperatures (<125 °C) and varying depths of shallow burial (1–3 km), solid-state transformation of phyllosilicates and calcites indicates paleosols had prolonged exposure to burial conditions which has implications for the use of paleosol minerals for paleoenvironmental reconstructions.

Illinois, Indiana, Kentucky

Biome-scale spatial patterns of avian abundance reveal proactive conservation opportunities in North American grasslands

North American grassland birds have experienced steeper population declines than any other avian guild, yet conservation efforts remain largely reactive and fragmented. We used nearly four decades of North American Breeding Bird Survey data to identify biome-scale spatial patterns (clustering) of grassland bird abundance for the Great Plains. Our results reveal an ecological core in the north-central Plains where community-level abundance is either increasing by >100% or remains high and stable, providing a strategic roadmap for a “Defend the Core” conservation approach. This approach flips the script from reactive triage centered on isolated population fragments to a proactive strategy of maintaining large-scale ecosystem integrity. Conversely, we found that population losses are more spatially clustered than wins, reflecting the relentless, one-way movement of woody encroachment and agricultural conversion. This asymmetry supports prioritizing intact landscapes, as current restoration rates are often outpaced by the scale of habitat loss. Notably, we found that community-level spatial clustering is a more robust indicator of biome condition than trends of individual flagship species, suggesting that managing for ecosystem integrity provides a more effective multi-species umbrella. Given our results, there is an opportunity for operationalizing a Great Plains Conservation Design that is ecosystem-centric and rooted in the sustainability of the private-land cattle production that maintains these open spaces. By leveraging avian abundance as a biological sensor, managers and producers can deploy a shared vision that matches the spatial scale of the threats, moving from reactive triage to proactive defense of core working grasslands in North America.

Great Plains biome

The advantages of electric-grade heat storage in long closed-loop wells

Though long (e.g., tens of kilometers) closed-loop geothermal wells are under consideration for the extraction of subsurface heat, these wells might also serve as an efficient energy storage mechanism for electricity generation. Using a semi-analytic model solution, the potential for electric-grade heat storage as a function of ambient temperature (e.g., corresponds to depth of loop), well length, well diameter, and flow rate is evaluated. The following simplified cases for comparison of standard closed loop operation with energy storage operation were considered: [1] constant flow rate and constant temperature (90 °C) injection to represent the standard closed-loop base-case; and [2] constant flow rate and annual cycle sinusoidal temperature (90-150 °C) to represent seasonal (summer) charging while solar resources are peak. Initial temperatures for all scenarios considered herein are a uniform 175 °C. Electric-grade heat is assumed to be delivered whenever temperatures at the extraction point exceed 90 °C. For calculation purposes only, if temperature falls below 100 °C, it is assumed that heat delivered is sub-economic, so no electricity would be produced. For all scenarios, temperatures at the extraction well asymptotically approach the flow-weighted average injection temperature, but energy storage scenarios exhibited a damped time-varying signal that diminishes in magnitude with length of the loop. The asymptotic approach depends on initial temperatures in the rock and the heat extraction rate (a function of well diameter and flowrate). This analysis demonstrates that shorter closed loops can produce more electricity over time than longer closed-loops previously proposed for electricity production over typical engineering design lifetimes (e.g., 30 years). Although only a high-temperature scenario is considered herein, rock that is initially below boiling temperature would not host a standard closed-loop resource, but injection of hot water seasonally would asymptotically heat this low-temperature system to temperatures capable of electricity production. In other words, regardless of initial temperatures, closed loops could be used to store electricity with no critical minerals in the geothermal battery.

Conference Paper

Quantitative mineral resource assessment of lithium pegmatite deposits in the Appalachian Orogen, USA

Lithium is classified as a U.S. critical mineral commodity, and its demand is projected to drastically increase through 2040, driven by electric vehicle production and energy storage applications (IEA 2021).Most global lithium production is not in the United States increasing vulnerability to a supply disruption. The U.S. Geological Survey is actively assessing domestic lithium deposits including lithium-bearing pegmatites in the Appalachian orogen. Permissive tracts for lithium pegmatite deposits were delineated by integrating lithological, tectonic, geochemical, geophysical, and mineral occurrence data. The geospatial data and permissive tracts were used to estimate the number of undiscovered lithium pegmatite deposits. Estimates were then integrated into probabilistic simulations along with a new global lithium pegmatite grade and tonnage dataset to quantify potential contained undiscovered lithium resources. An economic filter was used to estimate the amount of potentially recoverable undiscovered resources. Preliminary computations for the northern Appalachians, including application of the economic filter to the median recoverable contained resource, yields 900,000 metric tons of Li 2 O that correspond to enough Li 2 O to replace 127 years of import reliance at the current rate (7,100 t Li 2 O/yr; USGS, 2025). For the southern Appalachians, preliminary computations yielded 1,430,000 metric tons of Li 2 O, which corresponds to 201 years of import reliance.

Alabama, Connecticut, Delaware, Georgia, Maine, Ma

Low-sulfidation epithermal deposits of the central Basin and Range Province, USA

The Basin and Range Province is host to many important low-sulfidation epithermal deposits. Within this broad zone of extension, epithermal deposits are hosted by specific areas of Miocene and younger bimodal volcanism. In northern Nevada, rifting and related volcanic activity occurred in response to thermal bulging during the development of the Yellowstone hotspot. The Colorado River Extensional Corridor in southern Nevada, adjoining eastern California and northwestern Arizona, is a major zone of Miocene crustal extension formed during the transformation of the western margin of North America from a convergent to a transform plate boundary. The style of mineralization in the low-sulfidation epithermal deposits in these areas is strongly controlled by the nature of the volcanic successions. Highgrade, low-tonnage deposits are commonly found in flow-dominated volcanic successions where ore deposition occurred through short-lived periods of fluid flashing. In contrast, low-grade, large-tonnage deposits are more commonly located in clastic-dominated successions where fluid infiltration of the permeable hosts and cooling predominated.

Arizona, California, Nevada, Oregon

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee