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Critical Minerals in Ores (CMiO) database

Critical minerals are commodities essential to modern industrial and strategic technologies and are highly vulnerable to supply chain disruption. The Critical Minerals Mapping Initiative (CMMI) is a collaboration among the U.S. Geological Survey (USGS), the Geological Survey of Canada, and Geoscience Australia that aims to deepen global understanding of where critical minerals are located. A key output of this initiative is the Critical Minerals in Ores (CMiO) database that is advancing our collective understanding of critical minerals distributions. For instance, publicly available data on the concentrations of many critical minerals are sparse because these commodities can only be produced in small, yet essential, quantities compared to the primary commodities like copper and zinc. The CMiO database helps bridge this gap by offering high-quality, multielement geochemical data from a wide variety of critical mineral-bearing deposits around the world. Importantly, it uses a novel consensus deposit environment, group, and type classification scheme developed by the agencies that allows comparisons among ore deposits from different regions. The CMiO database contains geochemical data for more than 20,000 samples from more than 100 deposit types comprising 10 deposit environments.

Fact Sheet

Grammar to graph—An approach for semantic transformation of annotations to triples

Data annotation is the process of labeling data to show the outcome that a related data model should predict. In this study, annotation data were transformed into semantic graph triples, mainly for use with the Resource Description Framework (RDF), a type of entity-relationship-attribute data model for graph databases. The transformation of annotation data to semantic graph triples provides complex linguistic meaning with data handling advantages such as reduced data storage needs, improved logical specification of relations between objects, and reusable classes and properties that support logic and inference. A grammar-based framework in graph form supports user questions and queries. The words defining approximately 334 topographic feature types compiled by the U.S. Geological Survey were tokenized as units of analysis and grouped by part of speech. Their dependency relations were identified for this study using natural language processing libraries. Dependency concepts are used as structured semantic relations among part-of-speech classes. Tokens, units equivalent to words, form instances of classes and were quantified within a tabular output format using PostgreSQL data storage software. Table data were logically aligned as triples following a mapping file and stored with an ontology file using Ontop virtual triplestore software. A grammar ontology schema for the data was synchronized to match queries whose results validated the graph’s structure. The text analysis produced 8 part-of-speech classes of content words for object representations and 4 classes of function words for operational applications. Dependency relations formed 27 ontology properties for topographic subgraph structures. Token occurrences shaped overall ontology salience and formed a lexicon of syntactic terms for subgraph objects and properties. The schema ontology of class and property population shapes formed the lexicon of English terms. SPARQL Protocol and RDF Query Language (SPARQL) was used with the lexicon to conform data to RDF guidelines. This study confirms the hypothesis that although linguistic logic varies from description logic, its approximation applies to ontology design. Property and query use case patterns extracted from the analysis support queries concerning complex topographic relations and patterns normally embedded within text definitions. The method used in this study could be applied to text forms in other domains, such as survey notes.

Scientific Investigations Report

Metaproteomics and metagenomics reveal microbial pathways of organic matter degradation and methanogenesis in a marginally producing natural gas well

The expansion of natural gas production and utilization worldwide has led to the decline of many once-productive wells, eventually resulting in costly well-plugging and unused infrastructure. However, in areas like the Michigan basin, MI, where the majority of natural gas is biogenically produced, microbial communities could potentially be stimulated to generate additional methane, increasing gas supply and reducing the need to drill new wells. In this study, we performed metaproteomic, metagenomic, and geochemical analyses of Antrim Shale formation water from a marginally producing natural gas well to evaluate resident microbial community functions in the context of potential bioenergy production. Functional proteins involved in methanogenesis, degradation/catabolism (including organic matter degradation), biosynthesis, energy utilization, transmembrane transport, and stress response were among the most commonly identified groups. Three metagenome-assembled genomes (MAGs) were characterized, including Methanomicrobiaceae, Methanothrix , and Smithella . For each, the identified proteins involved in methanogenesis and the degradation of diverse organic compounds, strongly suggest their role in utilizing shale-derived organic matter. These findings provide an increased understanding of the microorganisms and their metabolisms generating natural gas in the Antrim Shale and establish a foundation for future stimulation efforts aimed at enhancing biogenic methane production in marginal gas wells.

Michigan

Continental-scale prediction of hydrologic signatures and processes

Understanding how dominant hydrologic processes and their drivers vary across diverse continental-scale landscapes is critical for hydrologic modeling and water management applications. Our research addresses this question by synthesizing large-sample watershed datasets, Caravan and GAGES-II, and developing random forest models to identify patterns in hydrologic function. We assessed dominant processes by examining hydrologic signatures – summary indicators of watershed function derived from hydroclimatic time series and random forest models across 14 146 gauged United States watersheds. The results reveal clear continental-scale gradients in hydrologic processes, including baseflow, overland flow, storage, and water balance losses. Our map of dominant processes highlights, for example, the transition from baseflow to fast responses and back to baseflow along the elevation gradient from the Appalachian spine, through the Piedmont, to the Eastern Coastal Plain; a distinct outer ring around the Great Lakes region; and sharp contrasts between coastal and inland processes in the West. Variable importance analysis from random forest models show that processes in the western U.S. are primarily controlled by climate, whereas in the eastern U.S., soil, geology, and topography play larger roles, with distinct human influences apparent in urban areas. Our approach of estimating dominant processes and their drivers facilitates extending process knowledge from research watersheds to the continental scale, assessing current hydrological understanding, and evaluating hydrological model structures.

conterminous United States

Assessing natural recharge in Indian Wells Valley, California: A Basin Characterization Model case study

The communities in Indian Wells Valley (IWV), in the northern Mojave Desert in California, rely on groundwater for domestic and agricultural use. Mountain front recharge from the surrounding Sierra Nevada is the main source of natural recharge to the valley. Increased urbanization, agricultural development, and groundwater pumping during recent decades put IWV in a state of critical overdraft. The U.S. Geological Survey Basin Characterization Model, version 8 (BCMv8) was used to evaluate historical and future climate and hydrologic conditions in IWV. The BCMv8 estimated natural recharge in IWV at 10.7 million cubic meters (Mm 3 ) per year for the period from 1981 to 2010. Future patterns of water balance variables using three future climate scenarios, hot-wet, hot-dry, and warm-moderately wet, were calculated for mid-century (2040–69) and end-of-century (2070–99) periods. Results for both wet models projected an increase in recharge in both periods, whereas the hot-dry model projected a decrease in recharge in both periods. All models reported a large increase in seasonal variability in recharge, indicating more future availability and frequent occurrences of drought years. All climate scenarios projected an increase in climatic water deficit in both periods. These increases in irrigation demand and variability of water supply highlight the importance of strategic management planning for the sustainability of water resources in IWV.

California

Lunar analog study using portable gamma-ray neutron detector: Radiochemical mapping of silicic-to-basaltic volcanic terrains in the San Francisco Volcanic Field, Arizona

Studying lunar silicic volcanism provides key insights into the Moon’s crustal evolution, magmatic processes, and volcanic history. The Lunar-VISE (Lunar Vulkan Imaging and Spectroscopy Explorer) mission will investigate the Gruithuisen domes, a unique lunar region hypothesized to have formed through silicic volcanism. Using instruments on a Firefly Aerospace lander and a Honeybee Robotics rover, Lunar-VISE will analyze mineralogy, geochemistry, and surface properties to determine the origin and evolution of the domes, with a gamma-ray and neutron spectrometer (LV-GRNS) among its payload instruments. In preparation for this mission, we conducted preliminary fieldwork using a handheld gamma-ray neutron detector with NaI(Tl) and Cs LiYCl :Ce (CLYC) scintillators. This study focuses on various rhyolitic and basaltic volcanic centers in the San Francisco Volcanic Field (SFVF) near Flagstaff, Arizona—specifically Sugarloaf Peak, Bonito Lava Flow, and Robinson Mountain, a region containing several well-characterized lunar analog sites. The SFVF was selected for this study due to its broad compositional diversity spanning basaltic to rhyolitic compositions, its well-preserved volcanic morphologies, and its extensive use in previous NASA field campaigns and astronaut training exercises, making it an ideal terrestrial laboratory for testing planetary exploration techniques. We measured natural radioactivity, specifically from potassium (K), thorium (Th), and uranium (U) and other elements in their decay chains, which serve as diagnostic tracers of magmatic differentiation and crustal evolution processes, to assess geochemical variability across compositionally diverse terrains. The detector’s sensitivity was assessed across varying concentration levels. Regionally averaged concentrations of radioisotopes were determined by gamma-ray spectroscopy at selected sites. Our measurements reveal significant compositional variations between sites, with Sugarloaf Peak (rhyolitic, silicic dome) exhibiting the highest average radioisotope concentrations (K: 3.29 ± 0.24 wt%, U: 14.35 ± 1.81 ppm, Th: 27.14 ± 2.43 ppm), while Bonito Lava Flow (K: 1.13 ± 0.08 wt%, U: 3.86 ± 0.52 ppm, Th: 7.52 ± 1.02 ppm), and Robinson Mountain (K: 1.46 ± 0.16 wt%, U: 5.59 ± 1.06 ppm, Th: 11.75 ± 1.98 ppm) show lower concentrations aligned with basaltic compositions. Gamma-ray fluxes were elevated by a factor of approximately three to four at Sugarloaf Peak relative to nearby basaltic terrains, consistent with expected geochemical differentiation patterns. Furthermore, at meter scales, proximity to geological features significantly affects measurements. Th concentrations adjacent to a cliff face at Sugarloaf’s base were 28% higher than values measured 3-5 meters away from the same feature, demonstrating localized compositional heterogeneity. Analysis of station-by-station measurements reveals that K, U, and Th concentrations show an elevation trend at Robinson Mountain and generally higher concentrations near Sugarloaf Peak’s summit, suggesting progressive magmatic differentiation and/or the presence of more evolved lithologies at higher elevations. By mapping these elements on Earth using GRNS, we aim to optimize measurement techniques for Lunar-VISE and similar rover-borne missions by demonstrating the applicability of portable GRNS instruments for planetary surface exploration in an analog environment.

Arizona

Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain

VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey's (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite . Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.

Texas

Spatial variation in effectiveness and costs of sagebrush restoration treatments across the western United States

Natural resource managers strive to improve restoration efficiency across the vast network of public lands of the United States, seeking the best return on investment through innovation, geographic prioritization, and adaptive management. This challenge is exemplified by ecosystems dominated by sagebrush ( Artemisia spp.), which occur across the western United States and have been degraded by increasing wildfire frequency driven by invasive plant spread, among other factors. However, both costs and effectiveness of sagebrush restoration can vary spatially due to management practices in addition to biotic and abiotic factors, and characterizing this variation could inform broad-scale planning. We leveraged published models of sagebrush recovery and treatment costs to predict and evaluate cost-effectiveness of aerial and drill seeding Artemisia spp. across 429 718 km 2 that overlapped 12 US states. Compared to natural recovery, effectiveness for both methods was generally low, yet effectiveness was often greater, and costs were always greater, for drill than aerial seeding, resulting in slightly higher cost-effectiveness on average for drill seeding. Cost-effectiveness for both treatments increased near major roads and in areas with more repeated burns. Cost-effectiveness also increased with predisturbance cover of sagebrush but decreased with herbaceous cover. However, we also identified areas where aerial seeding was more cost-effective than drill seeding, particularly with greater slope. Our results provide spatially explicit estimates and potential mechanisms of cost-effectiveness for two common seeding methods for sagebrush, which can help prioritize limited resources, guide land use, and improve restoration efficiency and effectiveness across public rangelands of the western United States.

western United States

Induced earthquakes are generally not tidally triggered in Oklahoma and Kansas

Human-induced earthquakes occur along critically stressed faults as injected wastewater simultaneously heightens fluid pressure and pushes faults to failure. We investigate the possibility that small stresses imposed by Earth tides could trigger earthquakes in the induced seismicity region of Oklahoma and Kansas from 2011 to 2018. We decluster a catalog consisting of ∼110,000 earthquakes using three methods (Reasenberg, nearest-neighbor distance, and phase-bin). We find no significant tidal earthquake triggering using Schuster's p -value test for the declustered catalogs as a whole. We search for localized triggering using discretized space-time cells and find ∼0–6% of cells have significant tidal triggering which is close to what is randomly expected (5%) and indicates there is an insignificant amount of tidal triggering for the full study region. One area that has significant p -values across multiple time windows, ∼2014–2016 is ∼15 km from a region of large wastewater injection volume. It is possible that localized tidal triggering occurs for this time and area because faults remain critically stressed and are particularly susceptible to slip under the small stress load from the semidiurnal tide. Possible explanations for the lack of tidal triggering in our broader study are that the pre-seismic stressing rate in the earthquake nucleation area is faster than the tidal stressing rate (∼3 kPa/day), faults are not close enough to critically stressed to be affected by tidal forcing, and that nucleation occurs over longer periods than the tides considered in this study (∼1, ∼14 days). Fluid injection could be the source of a higher pre-seismic stress rate.

Kansas, Oklahoma

Kiloyear cycles of carbonate and Mg-silicate replacement at Von Damm hydrothermal vent field

The Von Damm vent field (VDVF) on the Mid-Cayman Rise in the Caribbean Sea is unique among modern hydrothermal systems in that the chimneys and mounds are almost entirely composed of talc. We analyzed samples collected in 2020 and report that in addition to disordered talc of variable crystallinity, carbonates are a major class of mineral at VDVF. The carbonate minerals include aragonite, calcite, magnesium-rich calcite, and dolomite. Talc and carbonate mineral textures indicate that, rather than replacing volcanic host rock, they precipitate from the mixing of hydrothermal fluids and seawater at the seafloor, occurring in chimneys and surrounding rubble. Alternating precipitation of this mineral assemblage is pervasive, with carbonate minerals typically being succeeded by talc, and with indications that in some cases talc and carbonate minerals replace one another. Stable carbon isotopic data indicate the carbonate minerals originate from the mixing of seawater and hydrothermal fluid, which is supported by U-Th data. Radiocarbon calcite ages and talc 234 U- 230 Th isochron ages indicate mineral ages spanning over thousands to tens of thousands of years. Analyses of these samples illustrate a dynamic system that transitions from carbonate-dominated to Mg-silicate−dominated precipitation over time scales of thousands of years. Our observations raise questions regarding the eventual fate of seafloor precipitates and whether carbonate and silicate minerals in such settings are sequestered and represented in the rock record.

Geology

New Hampshire and Landsat

At its widest point, a mere 80 miles separate the eastern and western borders of New Hampshire. Its northern and southern borders are just 175 miles apart. Even so, few States can boast as much rugged natural beauty per mile as the Nation’s fifth smallest. Nestled within New Hampshire are 93 State parks teeming with moose, Ursus americanus (Pallas, 1780; black bears), coyotes, beavers, river otters, and foxes. The largest section of White Mountain National Forest cuts across north-central New Hampshire, drawing visitors to its lakes, streams, mountain peaks, and hardwood forests. New Hampshire also is home to Lake Winnipesaukee, the State’s largest lake, notable for its floating post offices, the annual “ice-out” contest that sees residents vying to guess the date its surface ice dissipates, and its supporting role in films such as “On Golden Pond” and “What About Bob?” However, the scenic forests of New Hampshire face challenges in the form of invasive species such as Lymantria dispar (Linnaeus, 1758; spongy moth), Adelges piceae (balsam woolly adelgid), and Agrilus planipennis (emerald ash borer). In recent years, New Hampshire’s lakes and streams have seen more cyanobacterial blooms as well. The U.S. Geological Survey Landsat Program offers a consistent, reliable, and historically unmatched source of Earth observations that can aid in the mapping, monitoring, and management of New Hampshire’s land and water resources. Here are a few ways Landsat data have been used in the Granite State.

New Hampshire

Benthic habitat map of Olowalu Reef, Maui, Hawaii—Geomorphological structure, biological cover, and geologic zonation determined with spectral, lidar, and acoustic data

The fringing coral reef off Olowalu, Maui, Hawaii, has been identified as a local conservation priority site. In 2007, the National Oceanic and Atmospheric Administration (NOAA) produced a benthic habitat map of the Hawaiian Islands that was used as a foundation for this study. To support place-based management of the reef in the future, the U.S. Geological Survey (USGS) mapped the geologic zone, major and dominant geomorphological structure, biological cover type, and percent of biological cover for 11 square kilometers (km 2 ) of Olowalu Reef at a minimum mapping unit (MMU) of 100 square meters (m 2 ) to create a benthic habitat map. Heads-up digitization was employed on 0.50-meter (m) natural color satellite orthoimagery with ancillary 1-m acoustic backscatter imagery from single-scan sonar (sound navigation and ranging). A 1-m, 4-m, and 8-m digital bathymetric model (DBM) was interpolated from bathymetric lidar (light detection and ranging), and various geomorphometric layers derived from the DBMs were used for habitat interpretation. Still-frame imagery of the seafloor extracted from vessel-towed underwater video transects on Olowalu Reef served as ground validation points ( n =870) during active mapping and accuracy assessment points ( n =216) for thematic accuracy assessment. Thematic accuracy was cross-validated by the Hawai‘i Department of Land and Natural Resources Division of Aquatic Resources. Final thematic accuracy was 88.8 percent for major structure, 85.6 percent for dominant structure, 86.0 percent for major biological cover, and 78.6 percent for type and percent of major biological cover. Reef and hardbottom constituted 52 percent of the total mapped habitat, comprising mostly aggregate reef (31 percent) and pavement (11 percent), with large swaths of spur-and-groove (9 percent). Of this hardbottom, 17 percent was covered with moderate (10 to <50 percent) coral and 27 percent with high coral cover (50 to <90 percent). High (50 to <90 percent) macroalgae cover dominated the continuous sand sheets in offshore bank/shelf zones. The map created in this study supplements the NOAA 2007 map and expands on the observations made by USGS sampling of the reef. The NOAA 2007 map and our map differed in total areal extent by a negligible 6 m 2 and were in general thematic agreement. Our map is intended to serve as a baseline for public access, general research, local-level management, and reef change for future studies.

Hawaii

ShakeAlert® and schools: Incorporating earthquake early warning in school districts in Alaska, California, Oregon, and Washington

The U.S. Geological Survey-managed ShakeAlert® earthquake early warning system is the first public alerting system in the United States to provide rapid mass notification when an earthquake is detected. Although public alert delivery via mobile phones began in California in 2019 followed by Oregon and Washington in 2021, little is known about what might drive widespread implementation in at-risk institutional settings such as schools. For example, there has been limited research on how to best integrate earthquake early warning into existing emergency plans, alert systems, and drills to keep school children and personnel safe in an earthquake. To address this gap, in the spring of 2022, every school district superintendent in Alaska, California, Oregon, and Washington was sent a 15-min online survey. The survey assessed superintendent knowledge of ShakeAlert, preferences for alert messaging, and perceived opportunities and barriers to incorporating the system in schools. The results showed that superintendents had low awareness of ShakeAlert but held positive perceptions of the system's potential to enable life-saving protective actions. A major barrier to adoption included the perceived financial cost of implementing and maintaining the system. There were some statistically significant differences in state responses, and future research could investigate the specific needs of each state based on school district size and composition, hazard exposure, and earthquake experience. Together these findings can help inform targeted strategies to increase ShakeAlert adoption in schools and ultimately improve the safety of school children and staff during earthquakes.

Alaska, California, Oregon, Washington

Dynamic feedbacks between river meandering and landsliding in northwestern Washington glacial terraces

Landsliding in river valleys poses unique risks for cascading hazards and can damage infrastructure and cause fatalities. In postglacial valleys, many landslides are posited to occur in relation to lateral river erosion, but the dynamics of fluvial-hillslope interactions are not well understood. Here, we investigate a section of the Nooksack River in western Washington State where the channel is flanked by landslide-prone glacial terraces similar to those that failed in the 2014 State Route 530 “Oso” landslide. We map 216 landslides through time across 17 aerial imagery data sets (1933–2022) and analyze them in relation to river meandering and curvature. We observe dynamic feedbacks between lateral river meandering and valley-adjacent landsliding. Terrace lateral retreat rates of up to 25 m/year owing to combined fluvial erosion and slope failure occur on pinned, outer meander bends immediately downstream from peaks in river curvature (>0.0075 1/m); these locations are predisposed to both shallow and deep-seated landslides. Deep-seated landslides extending 17%–32% of the active valley width into the floodplain can displace the river away from the floodplain margin and change the channel planform. River-displacing landslides relocate meanders up- or downstream, thereby conditioning the location of subsequent landslides. This conceptual model of coupled landslide-driven meander displacement and valley-adjacent landsliding is exemplified across western Washington river systems. The distance between up- and downstream valley-adjacent landsliding scales with valley width, meander wavelength, and terrace height. Our results can advance our understanding of the river-hillslope interface in landscape evolution and can be used to inform hazard management in river corridors.

Washington

Enhanced microplastic fragmentation along human built structures in an urban waterway

Plastic pollution and microplastic (MP, 1 µm to 5 mm) generation are growing problems affecting the global community and a wide range of natural and disturbed environments. Urban and suburban waterways are directly impacted by plastic pollution due to their proximity to population centers and many different types single use plastic waste sources. In this study, plastic waste accumulation and fragmentation was investigated along the Cooper River in Camden County, NJ. Polymer composition was identified for individual plastic waste particles collected along the Cooper River using Fourier transform infrared (FTIR) spectrometry. Multiple human-built structures (Wallworth Lake, Evans Pond and Hopkins Pond dams) along the Cooper River were found to accumulate different types of plastic waste. The accumulation of plastic waste along these structures resulted in the initial stages of plastic fragmentation and the identification of large MP particles (1 to 5 mm). Quantitative analysis revealed that fragmented polystyrene (PS) particles constituted 82.8% of the total plastic fragments identified, most of which were identified at the Wallworth Lake dam. Many other types of fragmented plastic litter, including polyethylene and polypropylene, were identified at the Wallworth Lake dam, as well. This research demonstrates that engineered structures within urban and suburban aquatic ecosystems serve as significant aggregators of plastic debris, thereby catalyzing its breakdown into microplastics. Considering the escalating ecological and human health ramifications of microplastic proliferation, the fragmentation of plastic waste in an urban and suburban waterway observed in this study can also result in potentially toxic smaller MP particles, and increased exposure to aquatic organisms and humans.

New Jersey

The addition of 144Nd atomic mass to routine ICP-MS analysis as a Quick Screening Tool for Approximating Rare Earth Elements (Q-STAR) in natural waters

Rare earth elements (REEs) are a class of critical minerals, all of which can have supply chain vulnerability that impacts economic security. These elements are widely measured in environmental matrices via inductively coupled plasma mass spectrometry (ICP-MS); however, successful quantification can require time-consuming, sample-specific optimization. While a sample-by-sample approach is appropriate for targeted quantification studies, this approach is not suitable for mineral exploration efforts where rapidly screening thousands of samples for the presence of REEs is desired. Here, we demonstrated the use of a Quick Screening Tool for Approximating REEs (Q-STAR) to detect REEs in surface water and groundwater matrices, collected as part of existing environmental studies. A mass-to-charge ratio of 144 ( m / z = 144) was added to an ICP-MS method to screen for REEs in filtered water samples submitted for metals analyses to the U.S. Geological Survey (USGS) National Water Quality Laboratory. We detected the presence of REEs above a reference threshold of 1200 counts per second in 18 % of pre-selected 6626 samples. Using this screened dataset, we mapped estimated dissolved REE concentrations across the United States in relation to ecoregions and underlying geology. Data are constrained to where sample collection took place but nevertheless show estimated aqueous dissolved REE concentrations on a geographic scale that has not yet been studied. To validate Q-STAR, REEs were measured in a USGS standard reference sample, a subset of 88 archived filtered water samples, and in fresh filtered surface water samples. Our targeted analyses demonstrated a strong linear relationship between Q-STAR predicted and measured values in all archived samples for Nd (r 2 = 0.94), and light REEs (LREEs) such as lanthanum (La) (r 2 = 0.93), praseodymium (Pr) (r 2 = 0.94) and samarium (Sm) (r 2 = 0.94). Using Q-STAR screen values, nine field sites were identified and surface water samples recollected to confirm the continued presence of Nd and LREEs. Q-STAR can be used to screen an unlimited number of water samples for the presence of REEs prior to time-intensive and costly quantitative analyses and to generate large REE datasets for further investigation.

Journal of Geochemical Exploration

Quantifying groundwater response and uncertainty in beaver-influenced mountainous floodplains using machine learning-based model calibration

Beavers ( Castor canadensis ) alter river corridor hydrology by creating ponds and inundating floodplains, and thereby improving surface water storage. However, the impact of inundation on groundwater, particularly in mountainous alluvial floodplains with permeable gravel/cobble layers overlain by a soil layer, remains uncertain. Numerical modeling across various floodplain structures considers topographic and sediment complexity and multidirectional flow, linking inundation to groundwater response. This study develops a model-data integration workflow to address uncertainty in groundwater response to beaver-induced inundations in a mountainous alluvial floodplain in the Upper Colorado River Basin. Uncertain factors include seasonal hydrologic dynamics, hydraulic conductivities, floodplain structures, and meteorological forcings. We employed an ensemble of groundwater models, based on geophysical and hydrologic data, with machine learning-based calibration using a neural density estimator. This allowed us to quantify the vertical flux from the soil layer to the permeable gravel bed, the down-valley underflow within the gravel bed, and their ratios. Results show a significant increase in the vertical flux relative to down-valley underflow, from 2% during dry pond periods to 20% during wet periods, serving as an analogy for conditions without and with beaver ponds. The study highlights the influence of floodplain structure on groundwater storage, water balance, and water quality impacted by beaver ponds. A thick gravel bed layer, with a large down-valley underflow, minimizes the effect of beaver-induced inundation on water quality. We emphasize the need for field-scale measurements of floodplain structure and improved characterization of evapotranspiration changes to reduce uncertainty in groundwater response.

Colorado

Evidence for nonlocal sediment transport on hillslopes from fault scarp morphology

Hillslope sediment transport processes such as bioturbation, rainsplash, and granular mechanics occur across the entire planet. Yet, it remains uncertain how these small-scale processes act together to shape landscapes. Longstanding hillslope diffusion theory posits that hillslope processes are spatially limited, whereas new concepts of nonlocal sediment transport argue otherwise. However, each theory produces subtly different, but distinct, predictions for the evolution of fault scarps. We use the topographic change of fault scarps to demonstrate that hillslope processes produce nonlocal sediment transport. Analysis of a global compilation of 340 dated single-earthquake scarp profiles reveals a statistically significant ( p < 0.05 ) relationship between scarp age and scarp asymmetry, here defined as the ratio of imaginary to real components of the Fourier transform of absolute slope. Numerical simulations show that nonlocal models predict this relationship, whereas hillslope diffusion models do not. To further investigate this result, we examined the depositional geometry of a well-exposed colluvial wedge along the Wasatch fault in central Utah, United States. Our quantitative comparison between the exposure and numerical simulations reveals better agreement with the nonlocal model. Nonlocal sediment transport theory appears to best capture the physics of how hillslope processes shape fault scarps, yet hillslope diffusion provides a useful approximation in many cases. As the processes that act on fault scarps are nearly identical to those acting on hillslopes, our results provide evidence supporting nonlocality as a generalized model of hillslope sediment transport.

Utah