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At least 1,297 records · Page 72Linked to original sources

Bryophyte abundance, composition and importance to woody plant recruitment in natural and restoration forests

Restoration of tropical forests can lead to enhanced ecosystem services and increases in native biodiversity. Bryophytes may be an integral part of the forest restoration process and can serve a critical role in forest functioning. However, the recovery of bryophytes and their ability to facilitate woody plant establishment during restoration remains poorly studied, especially in the tropics. We investigate how bryophyte abundance and community composition, as well as woody plant seedling associations with bryophyte mats and other ground cover types change from under the canopy of intact forest to under trees in restoration corridor plantings in Hawaii. Restoration corridors consisted of corridors of koa (Acacia koa) trees that were planted roughly 30 years ago. Some corridors were planted around remnant ʻōhiʻa trees (Metrosideros polymorpha) that can be several hundred years old. We sampled under ʻōhiʻa in intact forest and both koa and ʻōhiʻa trees in restoration corridors. In restoration corridors, bryophyte abundance was low relative to intact forest and species diversity was a subset of that found in intact forest despite restoration corridors being several decades old. Seedlings strongly associated with bryophytes across all habitats suggesting that bryophytes may significantly enhance forest seedling establishment when present in restoration corridors. Other ground cover types like woody litter and nurse logs also had a positive association with forest seedlings but were rare in restoration corridors. Grass remained a dominant ground cover type in restoration corridors under koa and remnant ʻōhiʻa trees and only a single seedling was ever found growing in this grass. Enhancing bryophyte growth and recovery within restoration plantings through the reduction of grass cover could facilitate native plant establishment.

Hawaii↗

The ubiquitous nature of accessory calcite in granitoid rocks: Implications for weathering, solute evolution, and petrogenesis

Calcite is frequently cited as a source of excess Ca, Sr and alkalinity in solutes discharging from silicate terrains yet, no previous effort has been made to assess systematically the overall abundance, composition and petrogenesis of accessory calcite in granitoid rocks. This study addresses this issue by analyzing a worldwide distribution of more than 100 granitoid rocks. Calcite is found to be universally present in a concentration range between 0.028 to 18.8 g kg −1 (mean = 2.52 g kg −1 ). Calcite occurrences include small to large isolated anhedral grains, fracture and cavity infillings, and sericitized cores of plagioclase. No correlation exists between the amount of calcite present and major rock oxide compositions, including CaO. Ion microprobe analyses of in situ calcite grains indicate relatively low Sr (120 to 660 ppm), negligible Rb and 87 Sr/ 86 Sr ratios equal to or higher than those of coexisting plagioclase. Solutes, including Ca and alkalinity produced by batch leaching of the granitoid rocks (5% CO 2 in DI water for 75 d at 25°C), are dominated by the dissolution of calcite relative to silicate minerals. The correlation of these parameters with higher calcite concentrations decreases as leachates approach thermodynamic saturation. In longer term column experiments (1.5 yr), reactive calcite becomes exhausted, solute Ca and Sr become controlled by feldspar dissolution and 87 Sr/ 86 Sr by biotite oxidation. Some accessory calcite in granitoid rocks is related to intrusion into carbonate wall rock or produced by later hydrothermal alteration. However, the ubiquitous occurrence of calcite also suggests formation during late stage (subsolidus) magmatic processes. This conclusion is supported by petrographic observations and 87 Sr/ 86 Sr analyses. A review of thermodynamic data indicates that at moderate pressures and reasonable CO 2 fugacities, calcite is a stable phase at temperatures of 400 to 700°C.

Geochimica et Cosmochimica Acta↗

Characterization of calcium isotopes in natural and synthetic barite

The mineral barite (BaSO4) accommodates calcium in its crystal lattice, providing an archive of Ca-isotopes in the highly stable sulfate mineral. Holocene marine (pelagic) barite samples from the major ocean basins are isotopically indistinguishable from each other (??44/40Ca = -2.01 ?? 0.15???) but are different from hydrothermal and cold seep barite samples (??44/40Ca = -4.13 to -2.72???). Laboratory precipitated (synthetic) barite samples are more depleted in the heavy Ca-isotopes than pelagic marine barite and span a range of Ca-isotope compositions, ??44/40Ca = -3.42 to -2.40???. Temperature, saturation state, a Ba2 + / a SO42 -, and aCa2+/aBa2+ each influence the fractionation of Ca-isotopes in synthetic barite; however, the fractionation in marine barite samples is not strongly related to any measured environmental parameter. First-principles lattice dynamical modeling predicts that at equilibrium Ca-substituted barite will have much lower 44Ca/40Ca than calcite, by -9??? at 0 ??C and -8??? at 25 ??C. Based on this model, none of the measured barite samples appear to be in isotopic equilibrium with their parent solutions, although as predicted they do record lower ??44/40Ca values than seawater and calcite. Kinetic fractionation processes therefore most likely control the extent of isotopic fractionation exhibited in barite. Potential fractionation mechanisms include factors influencing Ca2+ substitution for Ba2+ in barite (e.g. ionic strength and trace element concentration of the solution, competing complexation reactions, precipitation or growth rate, temperature, pressure, and saturation state) as well as nucleation and crystal growth rates. These factors should be considered when investigating controls on isotopic fractionation of Ca2+ and other elements in inorganic and biogenic minerals. ?? 2008 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗

The addition of 144Nd atomic mass to routine ICP-MS analysis as a Quick Screening Tool for Approximating Rare Earth Elements (Q-STAR) in natural waters

Rare earth elements (REEs) are a class of critical minerals, all of which can have supply chain vulnerability that impacts economic security. These elements are widely measured in environmental matrices via inductively coupled plasma mass spectrometry (ICP-MS); however, successful quantification can require time-consuming, sample-specific optimization. While a sample-by-sample approach is appropriate for targeted quantification studies, this approach is not suitable for mineral exploration efforts where rapidly screening thousands of samples for the presence of REEs is desired. Here, we demonstrated the use of a Quick Screening Tool for Approximating REEs (Q-STAR) to detect REEs in surface water and groundwater matrices, collected as part of existing environmental studies. A mass-to-charge ratio of 144 ( m / z = 144) was added to an ICP-MS method to screen for REEs in filtered water samples submitted for metals analyses to the U.S. Geological Survey (USGS) National Water Quality Laboratory. We detected the presence of REEs above a reference threshold of 1200 counts per second in 18 % of pre-selected 6626 samples. Using this screened dataset, we mapped estimated dissolved REE concentrations across the United States in relation to ecoregions and underlying geology. Data are constrained to where sample collection took place but nevertheless show estimated aqueous dissolved REE concentrations on a geographic scale that has not yet been studied. To validate Q-STAR, REEs were measured in a USGS standard reference sample, a subset of 88 archived filtered water samples, and in fresh filtered surface water samples. Our targeted analyses demonstrated a strong linear relationship between Q-STAR predicted and measured values in all archived samples for Nd (r 2 = 0.94), and light REEs (LREEs) such as lanthanum (La) (r 2 = 0.93), praseodymium (Pr) (r 2 = 0.94) and samarium (Sm) (r 2 = 0.94). Using Q-STAR screen values, nine field sites were identified and surface water samples recollected to confirm the continued presence of Nd and LREEs. Q-STAR can be used to screen an unlimited number of water samples for the presence of REEs prior to time-intensive and costly quantitative analyses and to generate large REE datasets for further investigation.

Journal of Geochemical Exploration↗

Two Holocene paleofire records from Peten, Guatemala: Implications for natural fire regime and prehispanic Maya land use

Although fire was arguably the primary tool used by the Maya to alter the landscape and extract resources, little attention has been paid to biomass burning in paleoenvironmental reconstructions from the Maya lowlands. Here we report two new well-dated, high-resolution records of biomass burning based on analysis of macroscopic fossil charcoal recovered from lacustrine sediment cores. The records extend from the early Holocene, through the full arc of Maya prehistory, the Colonial, and post-Colonial periods (~ 9000 cal yr BP to the present). (Hereafter BP) The study sites, Lago Paixban and Lago Puerto Arturo, are located in northern Peten, Guatemala. Results provide the first quantitative analysis from the region demonstrating that frequent fires have occurred in the closed canopy forests since at least the early Holocene (~ 9000 BP), prior to occupation by sedentary agriculturalists. Following the arrival of agriculture around 4600 BP, the system transitioned from climate controlled to anthropogenic control. During the Maya period, changes in fire regime are muted and do not appear to be driven by changes in climate conditions. Low charcoal influx and fire frequency in the Earliest Preclassic period suggest that land use strategies may have included intensive agriculture much earlier than previously thought. Preliminary results showing concentrations of soot/black-carbon during the middle and late Preclassic periods are lower than modern background values, providing intriguing implications regarding the efficiency of Maya fuel consumption.

Peten↗

Nature, distribution, and origin of Titan’s Undifferentiated Plains

The Undifferentiated Plains on Titan, first mapped by Lopes et al. (Lopes, R.M.C. et al., 2010. Icarus, 205, 540–588), are vast expanses of terrains that appear radar-dark and fairly uniform in Cassini Synthetic Aperture Radar (SAR) images. As a result, these terrains are often referred to as “blandlands”. While the interpretation of several other geologic units on Titan – such as dunes, lakes, and well-preserved impact craters – has been relatively straightforward, the origin of the Undifferentiated Plains has remained elusive. SAR images show that these “blandlands” are mostly found at mid-latitudes and appear relatively featureless at radar wavelengths, with no major topographic features. Their gradational boundaries and paucity of recognizable features in SAR data make geologic interpretation particularly challenging. We have mapped the distribution of these terrains using SAR swaths up to flyby T92 (July 2013), which cover >50% of Titan’s surface. We compared SAR images with other data sets where available, including topography derived from the SARTopo method and stereo DEMs, the response from RADAR radiometry, hyperspectral imaging data from Cassini’s Visual and Infrared Mapping Spectrometer (VIMS), and near infrared imaging from the Imaging Science Subsystem (ISS). We examined and evaluated different formation mechanisms, including (i) cryovolcanic origin, consisting of overlapping flows of low relief or (ii) sedimentary origins, resulting from fluvial/lacustrine or aeolian deposition, or accumulation of photolysis products created in the atmosphere. Our analysis indicates that the Undifferentiated Plains unit is consistent with a composition predominantly containing organic rather than icy materials and formed by depositional and/or sedimentary processes. We conclude that aeolian processes played a major part in the formation of the Undifferentiated Plains; however, other processes (fluvial, deposition of photolysis products) are likely to have contributed, possibly in differing proportions depending on location.

Icarus↗

Spectral nature of CO 2 adsorption onto meteorites

Previous studies have identified carbon dioxide (CO 2 ) on the surfaces of Jovian and Galilean satellites in regions of non-ice material that are too warm for CO 2 ice to exist. CO 2 ice would quickly sublimate if not retained by a less-volatile material. To ascertain what non-ice species may be responsible for stabilizing this CO 2 , we performed CO 2 gas adsorption experiments on thirteen powdered CM, CI, and CV carbonaceous chondrite meteorites. Reflectance spectra of the ν 3 feature associated with adsorbed CO 2 near 4.27 μm were recorded. Results show that many meteorites adsorbed some amount of CO 2 , as evidenced by an absorption feature that was stable over several hours at ultra-high vacuum (UHV) and high vacuum, (1.0×10 −8 and 1.0×10 −7 Torr, respectively). Ivuna, the only CI chondrite studied, adsorbed significantly more CO 2 than the others. We found that CO 2 abundance did not vary with ‘water’ abundance, organics, or carbonates as inferred from the area of the 3-μm band, the 3.2-3.4 μm C-H feature, and the ∼3.8-μm band respectively, but did correlate with hydrous/anhydrous phyllosilicate ratios. Furthermore, we did not observe CO 2 ice because the position of the CO 2 feature was generally shifted 3-10 nm from that of the 4.27 μm absorption characteristic of ice. The strongest compositional relationship observed was a possible affinity of CO 2 for total FeO abundance and complex clay minerals, which make up the bulk of the CI chondrite matrix. This finding implies that the most primitive refractory materials in the Solar System may also act as reservoirs of CO 2 , and possibly other volatiles, delivering them to parts of the Solar System where their ices would not be stable.

Icarus↗

Risk at the margins: A natural hazards perspective on the Syrian refugee crisis in Lebanon

Quantitative landslide risk analysis is a key step in creating appropriate land use policies. The forced migration of those displaced by recent armed conflict in Syria has highlighted the need for studies to guide humanitarian aid and resettlement policies. Over 1.5 million displaced Syrians now reside in Lebanon, self-settling throughout the country through urban integration and informal encampment due to Lebanon's prohibition of formal refugee camps. The Syrian-Lebanon refugee crisis coincides with the recent reexamination of the established aid practice of camp-based resettlement, focused on issues of aid efficacy, security, and human dignity but lacking an environmental hazards perspective. In light of these issues, we quantitatively assess the landslide risk profile of Lebanon, finding a 75% increase in landslide risk since the start of the Syrian crisis. The risk is highest in the debris flow-prone mountains of central and northeastern Lebanon. Additionally, Syrian refugees settled in informal camps experience 9–11 times greater risk then urban populations due to sub-standard shelter, suggesting that urban rather than camp-based resettlement policies are preferable from an environmental-hazards perspective.

International Journal of Disaster Risk Reduction↗

Recovery of Renibacterium salmoninarum from naturally infected salmonine stocks in Michigan using a modified culture protocol

Renibacterium salmoninarum, the causative agent of bacterial kidney disease (BKD), is a fastidious and slow-growing bacterium that is extremely difficult to grow in vitro. Herein, we describe a modified primary culture protocol that encompasses a modified bacteriological culture medium and a tissue processing procedure. In order to facilitate the release of R. salmoninarum from granulomatous tissues, kidneys of infected fish were homogenized in a high speed stomacher. The kidney disease medium (KDM2), routinely used for primary culture of R. salmoninarum was modified by the addition of antibiotics and metabolites. When a relatively large inoculum of diluted kidney homogenate was streak-plate inoculated onto the modified KDM2, colonial growth of R. salmoninarum was achieved within 5-7. days, compared to the standard of two weeks or more. The modified procedure was then used to determine the prevalence of R. salmoninarum among representative captive and feral salmonid stocks in Michigan. Prevalence and clinical manifestations varied among species, strains of fish, and locations; however, R. salmoninarum isolates were biochemically homogenous. The improved primary culture procedure described in this study enabled selective and quick isolation of R. salmoninarum. Also, the isolates retrieved in this study constitute a unique biological resource for future studies of R. salmoninarum in the Laurentian Great Lakes. ?? 2009 University of Cairo.

Journal of Advanced Research↗

Composition of aeolian dust in natural traps on isolated surfaces of the central Mojave Desert - Insights to mixing, sources, and nutrient inputs

The recognition and characterization of aeolian dust in soil contribute to a better understanding of landscape and ecosystem dynamics of drylands. Results of this study show that recently deposited dust, sampled in isolated, mostly high-ground settings, is chemically and mineralogically similar on varied geologic substrates over a large area (15 000 km2) in the Mojave Desert. The silt-plus-clay fraction (fines) on these isolated surfaces is closely alike in magnetic-mineral composition, in contrast to greatly dissimilar magnetic compositions of rock surfaces of vastly different lithologies, on which the fines have accumulated. The fines, thus, are predominantly deposited dust. The amounts of potential nutrients in the sampled dust are much more uniform than might be provided by direct, local weathering of bedrock or by dust locally derived from nearby weathered products. The compositional similarity of the dust on these surfaces is interpreted to result from mixing of fines in the atmosphere as well as in fluvial, alluvial, and lacustrine depositional settings prior to dust emission.

Journal of Arid Environments↗

Effects of natural flooding and manual trapping on the facilitation of invasive crayfish-native amphibian coexistence in a semi-arid perennial stream

Aquatic amphibians are known to be vulnerable to a myriad of invasive predators. Invasive crayfish are thought to have eliminated native populations of amphibians in some streams in the semi-arid Santa Monica Mountains of southern California. Despite their toxic skin secretions that defend them from native predators, newts are vulnerable to crayfish attacks, and crayfish have been observed attacking adult newts, and eating newt egg masses and larvae. For 15 years, we have observed invasive crayfish and native California newts coexisting in one stream in the Santa Monica Mountains. During that period, we monitored the densities of both crayfish and newt egg mass densities and compared these to annual rainfall totals. After three seasons of below average rainfall, we reduced crayfish numbers by manual trapping. Our long-term data indicated that crayfish did not fare well in years when rainfall is above the historic average. This invasive predator did not evolve with high velocity streams, and observations indicated that southern California storm events washed crayfish downstream, killing many of them. Newts exhibit increased reproduction in years when crayfish numbers were reduced. A comparison with a nearby stream that does not contain crayfish indicated that newt reproduction positively responded to increased rainfall, but that fluctuations were much greater in the stream that contains crayfish. We suggest that rainfall patterns help explain invasive crayfish/newt coexistence and that management for future coexistence may benefit from manual trapping.

Journal of Arid Environments↗

Protozoal meningoencephalitis in sea otters (Enhydra lutris): A histopathological and immunohistochemical study of naturally occurring cases

Protozoal meningoencephalitis is considered to be an important cause of mortality in the California sea otter ( Enhydra lutris ). Thirty nine of 344 (11.3%) California (CA) and Washington state (WA) sea otters examined from 1985 to 2004 had histopathological evidence of significant protozoal meningoencephalitis. The aetiological agents and histopathological changes associated with these protozoal infections are described. The morphology of the actively multiplicative life stages of the organisms (tachyzoites for Toxoplasma gondii and merozoites for Sarcocystis neurona ) and immunohistochemical labelling were used to identify infection with S. neurona ( n =22, 56.4%), T. gondii ( n =5, 12.8%) or dual infection with both organisms ( n =12, 30.8%). Active S. neurona was present in all dual infections, while most had only the latent form of T. gondii . In S. neurona meningoencephalitis, multifocal to diffuse gliosis was widespread in grey matter and consistently present in the molecular layer of the cerebellum. In T. gondii meningoencephalitis, discrete foci of gliosis and malacia were more widely separated, sometimes incorporated pigment-laden macrophages and mineral, and were found predominantly in the cerebral cortex. Quiescent tissue cysts of T. gondii were considered to be incidental and not a cause of clinical disease and mortality. Protozoal meningoencephalitis was diagnosed more frequently in the expanding population of WA sea otters (10 of 31, 32.3%) than in the declining CA population (29 of 313, 9.3%). Among sea otters with protozoal meningoencephalitis, those that had displayed neurological signs prior to death had active S. neurona encephalitis, supporting the conclusion that S. neurona is the most significant protozoal pathogen in the central nervous system of sea otters.

California, Washington↗

Uranium mill tailings: Nuclear waste and natural laboratory for geochemical and radioecological investigations

Uranium mill tailings (UMT) are a high volume, low specific activity radioactive waste typically disposed in surface impoundments. This review focuses on research on UMT and related earth materials during the past decade relevant to the assessment of: (1) mineral hosts of radionuclides; (2) the use of soil analogs in predicting long-term fate of radionuclides; (3) microbial and diagenetic processes that may alter radionuclide mobility in the surficial environment; (4) waste-management technologies to limit radionuclide migration; and (5) the impact of UMT on biota.

Journal of Environmental Radioactivity↗

Natural and anthropogenic processes affecting radon releases during mining and early stage reclamation activities, Pinenut uranium mine, Arizona, USA

Radon (Rnair) was monitored in open air in publicly accessible areas surrounding the Pinenut uranium (U) mine during mining and reclamation activities in 2015–16 to address concerns about mining related effects to areas surrounding Grand Canyon National Park (GCNP) in Arizona, USA. During July 2015, Rnair concentrations associated with the ore storage pile monitoring site were larger than those at the mine vent monitoring site and likely resulted from the relatively large amount of ore stored on site during this period. Higher wind velocities at the ore pile monitoring site generally resulted in lower Rnair concentrations; however, wind velocity did not appear to be an important factor in controlling Rnair concentrations at the mine vent monitoring site. Physical disturbances of the ore pile by heavy equipment did not coincide with elevated Rnair concentrations at the ore storage pile or mine vent monitoring sites. The relative size of the ore storage pile showed a positive trend with the daily mean Rnair concentration measured at the ore pile monitoring site. Principal component analysis (PCA) was applied to the ore pile and mine vent multivariate data sets for simultaneous comparison of all measured variables during 230 days of the study period. A significant positive coefficient for Rnair was associated with a significant negative coefficient for wind speed for principal component (PC) 2ore pile. Significant, positive PC2mine vent coefficients included Rnair, wind direction, and relative ore pile size indicating that Rnair variations at the mine vent monitoring site may be affected by Rn sourced from the ore pile. The ore pile is located about 200 m south of the mine vent Rn monitor with the prevalent wind direction coming from the south. All data generated during the field study and laboratory verification tests were published by Naftz et al. (2018) and are available online at:

Journal of Environmental Radioactivity↗

Natural uranium and strontium isotope tracers of water sources and surface water-groundwater interactions in arid wetlands: Pahranagat Valley, Nevada, USA

Near-surface physical and chemical process can strongly affect dissolved-ion concentrations and stable isotope compositions of water in wetland settings, especially under arid climate conditions. In contrast, heavy radiogenic isotopes of strontium ( 87 Sr/ 86 Sr) and uranium ( 234 U/ 238 U) remain largely unaffected and can be used to help identify unique signatures from different sources and quantify end-member mixing that would otherwise be difficult to determine. The utility of combined Sr and U isotopes are demonstrated in this study of wetland habitats on the Pahranagat National Wildlife Refuge, which depend on supply from large-volume springs north of the Refuge, and from small-volume springs and seeps within the Refuge. Water budgets from these sources have not been quantified previously. Evaporation, transpiration, seasonally variable surface flow, and water management practices complicate the use of conventional methods for determining source contributions and mixing relations. In contrast, 87 Sr/ 86 Sr and 234 U/ 238 U remain unfractionated under these conditions, and compositions at a given site remain constant. Differences in Sr- and U-isotopic signatures between individual sites can be related by simple two- or three-component mixing models. Results indicate that surface flow constituting the Refuge’s irrigation source consists of a 65:25:10 mixture of water from two distinct regionally sourced carbonate aquifer springs, and groundwater from locally sourced volcanic aquifers. Within the Refuge, contributions from the irrigation source and local groundwater are readily determined and depend on proximity to those sources as well as water management practices.

Nevada↗

TiO 2 as a photocatalyst for control of the aquatic invasive alga, Cladophora, under natural and artificial light

Cladophora, a nuisance and invasive, filamentous algae (Chlorophyta), massively accumulates along the shores of the lower Great Lakes each summer causing great economic damage and compromising recreational opportunity and perhaps public health. In vitro experiments showed that Cladophora samples were physically and biologically degraded when subjected to TiO 2 -mediated photocatalysis. For the most successful photocatalytic process, TiO 2 was immobilized on a glass surface and used in combination with either sunlight or artificial UV light. The loss of vital algal pigments was monitored using UV–vis spectrophotometry, and cell structural changes were determined by microscopic observation. Cladophora, in the presence of TiO 2 -covered glass beads, experienced a loss of chloroplast pigments after 2 h of UV lamp light irradiation. In a separate experiment, sunlight exposure over 4 days (∼24 h) resulted in the complete oxidative degradation of the green chloroplast pigments, verified by the UV spectra of the algal extracts. These results suggest that TiO 2 , mobilized on sunlit silicates may be useful in controlling growth and survival of this alga in the Great Lakes, thus mitigating many of the economic, aesthetic ecological impacts of this invasive alga.

Journal of Photochemistry and Photobiology A: Chem↗

Integrating thermal infrared stream temperature imagery and spatial stream network models to understand natural spatial thermal variability in streams

Under a warmer future climate, thermal refuges could facilitate the persistence of species relying on cold-water habitat. Often these refuges are small and easily missed or smoothed out by averaging in models. Thermal infrared (TIR) imagery can provide empirical water surface temperatures that capture these features at a high spatial resolution (<1 m) and over tens of kilometers. Our study examined how TIR data could be used along with spatial stream network (SSN) models to characterize thermal regimes spatially in the Middle Fork John Day (MFJD) River mainstem (Oregon, USA). We characterized thermal variation in seven TIR longitudinal temperature profiles along the MFJD mainstem and compared them with SSN model predictions of stream temperature (for the same time periods as the TIR profiles). TIR profiles identified reaches of the MFJD mainstem with consistently cooler temperatures across years that were not consistently captured by the SSN prediction models. SSN predictions along the mainstem identified ~80% of the 1-km reach scale temperature warming or cooling trends observed in the TIR profiles. We assessed whether landscape features (e.g., tributary junctions, valley confinement, geomorphic reach classifications) could explain the fine-scale thermal heterogeneity in the TIR profiles (after accounting for the reach-scale temperature variability predicted by the SSN model) by fitting SSN models using the TIR profile observation points. Only the distance to the nearest upstream tributary was identified as a statistically significant landscape feature for explaining some of the thermal variability in the TIR profile data. When combined, TIR data and SSN models provide a data-rich evaluation of stream temperature captured in TIR imagery and a spatially extensive prediction of the network thermal diversity from the outlet to the headwaters.

Oregon↗

Origins and nature of large explosive eruptions in the lower East Rift Zone of Kīlauea volcano, Hawaii: Insights from ash characterization and geochemistry

Several powerful explosive eruptions have taken place in the populated lower East Rift Zone of Kīlauea within the past ∼750 years. These have created distinctive landforms, including a tephra rim enclosing Puʻulena Crater immediately south of the Puna Geothermal Venture power station, a tuff cone at Kapoho Crater near the eastern cape of the Island of Hawaiʻi, and a set of littoral cones, the Sand Hill in Nānāwale, where the 1840 lava flow poured into the ocean. Kapoho Crater tuff cone is the largest of these recent pyroclastic features. Mineral, glass, and melt inclusion analyses of tuff cone ash and later fissure-related scoriaceous materials also found within the crater indicate slightly evolved basaltic magmas (1120–1130 °C) that are compositionally similar to parts of the effusive lower East Rift Zone eruptions in 1955 and 2018. Tuff cone magmas were stored at depths of ∼2.5–3.5 km and had pre-eruptive volatile contents (0.5–0.8 wt% H 2 O, 280–340 ppm CO 2 , 1400–1800 ppm S) similar to other Kīlauea eruptions (e.g., 1959, 1960), suggesting that internal magma properties were unlikely to account for the unusual explosiveness of this eruption. Tephra componentry, grain-size analyses, and field observations confirm that the cone grew during a phreatomagmatic eruption mostly of vitric ash, probably where a fissure opened across the coastline or shallow ocean floor nearby. Supporting this hypothesis is the identification of at least two genera of marine diatoms within tuff cone strata. Sand Hill littoral cone ash is also vitric like that of Kapoho Crater, but distinctly coarser with abundant fluidal ejecta represented. In contrast, the Puʻulena Crater eruption deposited lithic ash and related blocks with minor juvenile magmatic contribution; a phreatomagmatic eruption that was dominantly phreatic. Differences in eruption styles are related to unique mechanics that tephra analyses help us interpret. While powerful explosive eruptions in the lower East Rift Zone are rare, they present a definite future hazard for inhabitants in this part of Hawaii.

Hawaii↗