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Status of water-level altitudes and long-term and short-term water-level changes in the Chicot and Evangeline (undifferentiated) and Jasper aquifers, greater Houston area, Texas, 2023

Since the early 1900s, groundwater withdrawn from the primary aquifers that compose the Gulf Coast aquifer system—the Chicot, Evangeline, and Jasper aquifers—has been an important source of water in the greater Houston area, Texas. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting the status of water-level altitudes and water-level changes in these aquifers in the greater Houston area. In this report, the Chicot and Evangeline aquifers are treated as a single aquifer for the purposes of providing annual assessments of regional-scale water-level altitudes and water-level changes over time. In 2023, shaded depictions of water-level altitudes for the Chicot and Evangeline aquifers (undifferentiated) ranged from about 286 feet (ft) below the North American Vertical Datum of 1988 (NAVD 88) to about 169 ft above NAVD 88. The largest decline in water-level altitudes indicated by the 1977–2023 long-term water-level-change map was in south-central Montgomery County southeast of The Woodlands. In comparison, the 1990–2023 long-term water-level-change map depicts the largest declines in water-level altitudes in localized areas at or near certain wells in parts of northwestern Harris County and south-central Montgomery County. The largest rise in water-level altitudes for 1977–2023 is depicted in a relatively large area in southeastern Harris County, whereas the largest rise in water-level altitudes for 1990–2023 is depicted in a relatively large area in central Harris County. The 5-year short-term water-level-change map depicts the largest declines at three wells in northern Fort Bend County, one well in western Harris County, and three wells in south-central Montgomery County and the largest rise at one well in central Harris County. The 1-year short-term water-level-change map depicts the largest declines at one well in northern Fort Bend County and two wells in southwestern Harris County and the largest rises at one well in northern Brazoria County and one well in south-central Montgomery County. In 2023, shaded depictions of water-level altitudes for the Jasper aquifer ranged from about 242 ft below NAVD 88 to about 218 ft above NAVD 88. The 2000–23 long-term water-level-change map depicts water-level declines throughout the study area where water-level-measurement data from the aquifer were collected, with the largest declines in north-central Harris County and south-central Montgomery County south of The Woodlands. The 5-year short-term water-level-change map depicts the largest declines at two wells in central Montgomery County near Conroe and two wells in south-central Montgomery County southeast of The Woodlands and the largest rise at one well in western Montgomery County. The 1-year short-term water-level-change map depicts the largest declines at four wells in south-central Montgomery County southeast of The Woodlands and one well in central Montgomery County near Conroe and the largest rises at two wells in western Montgomery County.

Texas

Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA

Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.

California

Mountain goat declines in a protected, interior, native population

A shifting climate poses threats to alpine-adapted species including mountain goats. We used long-term (12 years) citizen science monitoring data and Bayesian N-mixture modeling to estimate population trends and drivers of population metrics among mountain goats in Glacier National Park (GNP). Median goats per site ( n = 37 sites) declined by 45% (95% credible interval [CRI] = 32%, 57%) from 77.8 (95% CRI = 64.4, 95.1) in 2008 to 42.3 (95% CRI = 34.3, 52.2) in 2019, with consistent declines from 2008 until 2015, when the number of estimated goats stabilized. The decline exceeds IUCN criteria for classifying a population as vulnerable, >30% declines over only two generations. Across years, relatively few goats occupied northwestern GNP. Goat numbers declined the most at northeastern sites, trended toward decline in most southern sites, and increased at only two west-central sites. The proportion of permanent snow and glaciers, the presence of natural mineral licks, and habituation strongly increased the initial abundance of goats in the area. Weather variables had the greatest influence on population growth rates, particularly precipitation between May 15 and June 15 of the previous summer, the neonatal period. Lower growth occurred with less snow water equivalent and lower mean winter temperature, early summer temperature, and early summer precipitation. Projected reductions of permanent snow, increasing spring and summer temperatures, and insufficient and variable spring precipitation raise concerns for the future of native goats in this region. Our analyses reveal ways to improve detection rates of goats during surveys, which is important for optimizing the precision of estimates and the power to detect future trends. Detection increased with goat habituation, retention of observers with experience, use of binoculars, and conducting surveys at lower temperatures and earlier dates. Improving detection will be particularly important given the lower number of goats currently observed in the park. Research to estimate park-wide population size, evaluate genetic structure and diversity, assess changing habitat, human recreation levels and forage, and forward-project climate effects on persistence will be crucial to understanding the context of these results and conserving this iconic, metapopulation at the southern edge of the distribution of native mountain goats.

Montana

Effects of groundwater withdrawals for water bottling and municipal use, Wards Brook Valley, Maine and New Hampshire

Hydrologic models for the Wards Brook valley near Fryeburg, Maine were developed for historical (2016 – 2021) and hypothetical future conditions (2046 – 2065 and 2080 – 2099) to understand the effects of groundwater withdrawals for bottled water and municipal use on hydrologic conditions (stream base flows and groundwater levels). Analyses showed that the simulated base flows in Wards Brook were reduced because of pumping for both municipal water supplies and for water bottling, and about half of the total pumping impact on the base flows in Wards Brook was from the bottled water extraction. Simulated flows were greater than the minimum recommended streamflow of 2,180 cubic meters per day (400 gallons per minute) throughout the historical period. Simulated groundwater levels at two of three nearby ponds (Round Pond and Davis Pond) were minimally affected by pumping conditions, and effects were primarily from the municipal well closest to the ponds. Several estimates of future projected recharge were used to understand the potential effects of groundwater withdrawals on hydrologic conditions under multiple hypothetical climate conditions. Annual projected recharge rates in the mid- and late-21st century from two climate scenarios (stabilized greenhouse-gas emissions and high greenhouse-gas emissions) were similar to rates for 2016 – 2021. However, monthly recharge patterns for the future periods shifted toward more recharge in the winter months (December, January, and February) and less recharge in April, May, and October relative to 2016 – 2021. The lowest mean monthly base flows from the future emission scenarios all remain larger than the minimum recommended streamflow and indicate no long-term declines in flow relative to historical conditions. However, simulated base flows during hypothetical 3-year drought scenarios declined below minimum recommended streamflow during the summer months in the stabilized- and high-emission scenarios in the mid-21st century. Although water is generally plentiful in the Wards Brook valley, reduced pumping may be needed to maintain streamflows in Wards Brook under future climate conditions similar to modeled drought scenarios.

EarthArXiv

Remote sensing enables basin-scale inventories of coal mine methane

Underground coal mines are important global sources of methane, but emission estimates are uncertain. We show that emission estimates for individual mines from aircraft remote-sensing surveys in the United States agree within 40% with direct measurements used for national emission reporting (IPCC Tier 3 estimate). Such direct measurements are unavailable in most countries, which rely on estimated emission factors (EFs) applied to coal-production rates. We find that EFs from IPCC Tier 1 and the Model for Calculating Coal Mine Methane (MC2M) methods overestimate U.S. emissions 3-fold due to incorrect dependence on mine depth. An IPCC Tier 2 method using measured basin-specific mine gas content agrees with direct emission measurements but does not account for gob well emissions and requires gas content data that are generally unavailable. We show that aircraft remote sensing for a small sample of mines can successfully estimate basin-specific EFs for ventilation shafts and gob wells, enabling estimates of basin- and national-scale emissions. We discuss how the method can be applied with satellite remote sensing to quantify coal emissions worldwide.

Alabama, Colorado, Kentucky, New Mexico, Ohio, Pen

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2019–2021

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Water availability is an important issue in the Black Mesa area because of the arid climate, past industrial water use, and continued water requirements for municipal use by a growing population. Precipitation in the area typically ranges from less than 6 to more than 16 inches per year, depending on location. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents the results of data collected as part of the monitoring program in the Black Mesa area from calendar years 2020–2021 and, additionally, uses streamflow statistics from November and December 2019. The monitoring program includes measurements of (1) groundwater withdrawals (pumping), (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In calendar year 2020, total groundwater withdrawals were estimated to be 2,680 acre-feet (acre-ft), and, in 2021, total withdrawals were estimated to be 2,570 acre-ft. Total withdrawals during 2021 were about 65 percent less than total withdrawals in 2005 because the Peabody Western Coal Company discontinued its use of water to transport coal in a coal slurry pipeline after 2005 and ceased mining operations in 2019. Owing to Navajo Nation and Hopi Reservation access restrictions during the Coronavirus pandemic, water levels were not collected from municipal wells in 2020 or 2021. Water levels measured in 2021 from wells completed in the unconfined areas of the N aquifer within the Black Mesa area showed a decline in 7 of 13 wells when compared with water levels from the prestress period (prior to 1965). The changes in water levels across all 13 wells ranged from +8.4 feet (ft) to −42.4 ft, and the median change was −0.4 ft. Water levels also showed decline in 11 of 12 wells measured in the confined area of the aquifer when compared to the prestress period. The median change for the confined area of the aquifer was −25.9 ft, with changes across all 12 wells ranging from +17.3 ft to −133.7 ft. Spring flow was measured at four springs between 2020 and 2021. Flow fluctuated during the period of record for Burro Spring and Pasture Canyon Spring, but a decreasing trend was statistically significant (p<0.05) at Moenkopi School Spring and Unnamed Spring near Dennehotso, Arizona. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s, and discharge at Pasture Canyon Spring has fluctuated for the period of record. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976–2021), Dinnebito Wash near Sand Springs 09401110 (1993–2020), Polacca Wash near Second Mesa 09400568 (1994–2020), and Pasture Canyon Springs 09401265 (2004–2021). Median winter flows (November through February) of each winter were used as an estimate of the amount of groundwater discharge at the above-named sites. For the period of record, the median winter flows have generally remained constant at Polacca Wash and Pasture Canyon Springs, whereas a decreasing trend was observed at Moenkopi Wash and Dinnebito Wash. In 2020 and 2021, water samples were collected from a total of four springs in the Black Mesa area and analyzed for selected chemical constituents. Results from the four springs were compared with previous analyses from the same springs. Dissolved solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 30 years of record at that site. Concentrations of dissolved solids and sulfate at Pasture Canyon Spring have not varied significantly (p>0.05) since the early 1980s, and there is no increasing or decreasing trend in those data. However, concentrations of chloride from Pasture Canyon Spring show a diminishing trend. Concentrations of dissolved solids, chloride, and sulfate at Unnamed Spring near Dennehotso have varied for the period of record, but there is no statistical trend in the data. Concentrations of dissolved solids at Burro Spring have varied for the period of record, but there is no statistical trend in the data. However, concentrations of chloride and sulfate from Burro Spring show a trend towards lower concentrations.

Arizona

Groundwater-level elevations in the bedrock aquifers of the Denver Basin aquifer system, Elbert County, Colorado, 2015–23

Water users in Elbert County, Colorado, rely on groundwater from bedrock aquifers in the Denver Basin aquifer system (upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers) for approximately half of their water uses. Withdrawals from the bedrocks aquifers have increased to meet the water use needs of expanding regional population growth and development. The U.S. Geological Survey, in cooperation with the Elbert County Board of County Commissioners, began a study in 2015 to monitor groundwater levels within Elbert County. The primary purpose of this report is to present a summary of groundwater levels measured during the study period (2015–23) and present results from statistical analyses of changes in groundwater-level elevations through time. Discrete groundwater levels were measured at 36 wells within Elbert County. Seven of those wells contained equipment to make and record continuous groundwater-level measurements at hourly intervals. All aquifers, except the lower Dawson aquifer, had only declining groundwater-level elevations in discrete measurements for wells with statistically significant trends. Of the eight statistically significant trends in the lower Dawson aquifer, two wells indicated increasing groundwater-level elevation from discrete measurements. The groundwater-level elevation trend medians in the upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers were −0.23, −0.66, −0.64, −0.39, and −0.63 feet per year, respectively, for discrete groundwater-level elevation measurements. Trends in continuous groundwater-level elevations were in agreement with statistically significant trends in discrete groundwater-level elevations for all wells. The groundwater-level elevation trend medians in this study, compared to the overall trends in a 2015−2018 study, both indicated declining groundwater-level elevations except in the upper Dawson aquifer, where the trend direction was opposite, a positive trend from 2015 to 2018 and a negative trend (declining groundwater elevations) from 2015 to 2023. The change in trends within the upper Dawson aquifer may be affected by differences in the study period and the trend analysis applied. Trends during the 2015–23 study period were compared to departures from the median 2015 groundwater-level elevation for each site in each aquifer. In general, the departures from the 2015 median supported trends observed at each site and correlated spatially with greater departures near the western border of Elbert County. Additionally, 30-year precipitation data showing wet and dry periods were overlaid with the departure from the 2015 median to assess groundwater-level patterns in wells in the five aquifers. Departures from the 2015 median groundwater-level elevations appeared greatest during the dry period between 2020 and 2023. Potentiometric-surface maps of the upper and lower Dawson aquifers created from static April 2023 groundwater elevations indicated groundwater-flow direction is generally from the south to the north. Results of this study could be used to guide additional groundwater monitoring in Elbert County and could aid in long-term planning of water resources.

Colorado

Scientific opportunities in the National Landscape Conservation System

The National Landscape Conservation System consists of unique and beautiful places across America’s landscapes where identified resources and values are protected and science is highlighted. The mission of the National Landscape Conservation System (NLCS), which is managed by the Bureau of Land Management and is often referred to as the agency’s National Conservation Lands, is to conserve, protect, and restore nationally significant landscapes for their cultural, ecological, and scientific values. This clear inclusion of science in the NLCS mission sets the stage for individual units to serve as places of learning, teaching, discovery, and innovation. Science is an integral part of managing the National Conservation Lands, and science conducted within and across the more than 900 units that make up the NLCS can inform and influence conservation and public land management well beyond its boundaries. Here, we highlight seven core aspects of National Conservation Lands that present valuable science opportunities: (1) the scientific values for which individual units are designated; (2) the many other resources, objects, and values within units; (3) the value of units as “control” sites for understanding the effects of activities such as mineral extraction that commonly occur elsewhere on multiple-use public lands but are often prohibited within National Conservation Lands; (4) the value of units for studying the effects of activities such as recreation that regularly occur and may be intensified on National Conservation Lands; (5) the high visibility of units, which draws strong interest and engagement from scientists, partners, and the public; (6) the functioning of the units as a network managed for a common purpose, which provides an opportunity to explore cross-cutting science questions across widely varying contexts and geographies; and (7) the opportunities units provide to promote and apply Indigenous Knowledge to scientific research to manage natural and cultural resources. Because of all of these characteristics, National Conservation Lands can serve as hubs for basic and applied science that can inform management of all public lands and resources into the future. We highlight these science opportunities through examples from existing units and suggest two actions that could help further science activities and impact on National Conservation Lands.

Parks Stewardship Forum

Stream sediment sources in Medicine Creek, northern Missouri and southern Iowa

This report presents the results of a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources to quantify sediment transport source contributions in the Medicine Creek drainage basin. Understanding relative source contributions provides valuable information for selecting the conservation practices that may be most effective in reducing sediment and sediment-associated nutrient transport in the Medicine Creek drainage basin and similar areas of the Lower Grand River drainage basin. Sediment samples were collected from potential contributing areas (source samples) and from fluvial-transported samples (target samples). Source sample types included streambanks, row crop fields, and a combined pastures and forests category. Samples were analyzed for particle size and quantity of carbon, nitrogen, stable isotopes of carbon and nitrogen, and 49 mineral elements as potential tracers. Results for the carbon stable isotope ratio of carbon-13/carbon-12 (δ 13 C) and concentrations of total carbon, total nitrogen, calcium, potassium, and copper were selected by discriminant function analysis as the best combination of multiple tracers to differentiate each source type. The discriminant function analysis poorly differentiated pastures and forests, so these source types were combined. The sources defined by the discriminant function analysis were then used in an unmixing model to apportion sources for each target sample. In the study area, transported sediment was predominantly bank sediment, with an overall average of 86.9 percent of suspended-sediment samples and depositional streambed samples attributed to bank material. Suspended-sediment samples from the mainstem of Medicine Creek were dominated by bank sediments (average of 95.8 percent), and depositional streambed samples from throughout the drainage basin had more variable source contributions with an average of 71.1 percent attributed to bank material. The relative importance of upland sources (row crop fields and the combined pastures and forests category) varied seasonally and with streamflow but was not related to land use or drainage basin size. Relative contributions from upland sources were greater in the summer through winter rather than spring and during lower streamflow, though this may be driven by the seasonality of streamflow. These results indicate management practices that reduce bank erosion could be effective strategies for managing the dominant source of sediment and sediment-associated phosphorus.

Iowa, Missouri

Evaluating machine learning approaches to identify and predict oil and gas produced water lithium concentrations

Recently, the demand for battery-grade lithium has substantially increased, largely due to electrification of the transportation sector. The search for new lithium sources has turned to produced waters (frequently brines), a large-volume wastewater by-product of oil and gas extraction. Geochemical analysis indicates the presence of varying concentrations of lithium from produced water samples collected across the United States and represented in the U.S. Geological Survey’s National Produced Water Geochemical Database, as well as mixtures of Marcellus Shale produced water included in the Pennsylvania Department of Environmental Protection’s Oil and Gas Well Waste Reports. We first examined whether the geochemical signature of the lithium-bearing produced waters is sufficiently distinct so that machine learning (ML) can be used to correctly classify samples to the formation of origin. The produced water sample data used to assess classification accuracy were from the Marcellus Shale, Utica Shale and Point Pleasant Formation (Utica), and Smackover Formation oil and gas wells. Further, we evaluated the potential for ML to accurately classify Marcellus Shale produced water spatially (i.e., northeast versus southwest Pennsylvania). We then investigated whether ML algorithms applied to a suite of geochemical concentration data (i.e. Ba, Br, Cl, K, Mg, Sr) may be used to predict the lithium concentration of an unknown sample. Finally, we applied an estimated economic lithium grade cutoff of 150 milligrams per liter (mg/l) and assessed the utility of ML to predict whether a produced water sample would fall above or below the grade cutoff based on the suite of geochemical parameters. Four machine learning algorithms—Random Forest (RF), Gradient Boosting Trees (GBT), Extreme Boosting (XGBoost), and Deep Neural Networks (DNN) were assessed. This study successfully demonstrates that all four machine learning methods can precisely and accurately estimate lithium concentrations and geologic formation classification. The products of this study contribute to the growing body of knowledge aimed at expanding the lithium resource base within the United States.

Alabama, Arkansas, Florida, Georgia, Louisiana, Mi

Simulated effects of future water availability and protected species habitat in a perennial wetland, Santa Barbara County, California

This study evaluates the potential water availability in Barka Slough and the effects of changing hydrological conditions on the aquatic habitat of five protected species. Barka Slough is a historically perennial wetland at the downstream western end of the San Antonio Creek Valley watershed (SACVW). A previously published hydrologic model of the SACVW for 1948–2018 was extended to include 2019–2021 and then modified to simulate the future years of 2022–2051. Two models simulating the future years of 2022–2051 were constructed, each with different climate inputs: (1) a repeated historical climate and (2) a 2070-centered Drier Extreme Warming climate (2070 DEW). The model with the 2070 DEW climate had warmer temperatures and an increase in average annual precipitation driven by larger, albeit more infrequent, precipitation events than the model with the historical climate. Simulated groundwater pumpage resulted in cumulative groundwater storage depletion and groundwater-level decline in Barka Slough in both future models. The simulations indicate that Barka Slough may transition from a perennial to an ephemeral wetland. Streamflow, stream disconnection, and depth to groundwater are key habitat metrics for federally listed species in Barka Slough. Future seasonal conditions for each metric are more likely to affect federally listed species’ habitats under 2070 DEW climatic conditions. Future seasonal streamflow volume may negatively impact unarmored threespine stickleback ( Gasterosteus aculeatus williamsoni ) and tidewater goby ( Eucyclogobis newberryi) habitats. Future seasonal stream disconnection may negatively impact the unarmored threespine stickleback habitat. Future groundwater-level decline may negatively impact Gambel’s watercress ( Nasturtium gambelii ) and La Graciosa thistle ( Cirsium scariosum var. loncholepis ) habitats and could influence the ability to use Barka Slough as a restoration or reintroduction site for these species. Results from this study can be used to inform water management decisions to sustain future groundwater availability in the SACVW.

California

Potential for leakage among principal aquifers in the Memphis area, Tennessee

The principal aquifers in the Memphis area consist primarily of sand or sand and gravel, and the confining beds consist of clay, silt, sand, and lignite. The Jackson Formation and upper part of the Claiborne Group serve as the confining bed separating the water table aquifers from the Memphis Sand; the Flour Island Formation separates the Memphis Sand from the Fort Pillow Sand. Differences in total hydraulic head among the principal aquifers in the Memphis urban area result in vertical hydraulic gradients which create a potential for inter-aquifer exchange of water. Throughout this area, the gradient is downward from the water table aquifers to the Memphis Sand. In the central part of the Memphis urban area, the vertical hydraulic gradient is upward from the Fort Pillow Sand to the Memphis Sand, and in the eastern and western parts, it is downward from the Memphis Sand to the Fort Pillow Sand. The vertical distribution of carbon-14 data for water from the fluvial deposits, Memphis Sand, and Fort Pillow Sand shows an increase in the relative age of the water with depth. The areal distribution of carbon-14 data for water from the upper part of the Memphis Sand indicates that relatively recent water has been brought into the major cone of depression in the potentiometric surface of the Memphis Sand, either by horizontal movement or from downward vertical leakage. The normal, near-surface geothermal gradient in the Memphis area was determined to be 0.6 C/100 ft. Deviations from the normal geothermal gradient, in areas affected by intense pumping from the Memphis Sand, indicate that downward vertical leakage occurs from the water table aquifers through the Jackson-upper Claiborne confining bed to the Memphis Sand. The velocity of downward vertical leakage of water from the Memphis Sand through the Flour Island confining bed to the Fort Pillow Sand was determined to be 0.0066 ft/day by analysis of borehole temperature data from an observation well in the northeastern part of the Memphis area. From this velocity and the head difference between the Memphis Sand and the Fort Pillow Sand at this locality, the hydraulic conductivity of the Flour Island confining bed was determined to be 0.00114 ft/day. (Lantz-PTT)

Tennessee

Airborne geophysics for geologic mapping of critical mineral systems in the United States southern midcontinent

The increased demand for clean energy technology and a significant reliance on foreign supply chains have given impetus to understanding critical mineral systems and locating potential resources within the United States. At least thirteen critical mineral-bearing systems have been identified throughout the U.S. southern Midcontinent (Hofstra and Kreiner, 2020) but much of the region’s geologic framework is concealed by vegetation and sedimentary cover that hinder traditional geologic mapping efforts. Airborne geophysical data provide an effective way to overcome these obstacles and to provide additional insight into the deeper structures that underlie shallow mineralization. However, legacy airborne magnetic and radiometric data were collected using now-outdated instruments and methods, inconsistent survey parameters, and large flight-line spacings resulting in low-resolution data that present challenges to regional-scale study and interpretation. Over the last decade, the U.S. Geological Survey Earth Mapping Resources Initiative (EMRI) and National Cooperative Geologic Mapping Program have conducted a series of high-resolution airborne magnetic and radiometric surveys across the southern Midcontinent (Fig. 1) as part of an effort to improve understanding of the geophysical framework and natural resource potential in the region. These surveys are designed using modern survey methods and instruments with consistent parameters for flight-line spacing and flight height relative to magnetic sources. The EMRI airborne surveys are planned in collaboration with State geological surveys based on focus areas (Dicken et al., 2022) according to the presence of or potential for critical mineral deposits. High-resolution airborne magnetic and radiometric data cover focus areas such as the southeast Missouri iron metallogenic province and South-Central iron-oxide-apatite (IOA) – iron-oxide-copper-gold (IOCG) province, the Magnet Cove alkaline-carbonatite complex, the Midwest Permian ultramafic dike district, the Illinois-Kentucky fluorspar district, and several Mississippi Valley-type lead-zinc deposits and districts (Fig. 1). These focus areas represent known deposits or prospective host systems of critical minerals including rare earth elements (REEs), platinum-group elements (PGEs), cobalt, lithium, fluorspar, niobium, titanium, vanadium, lead, zinc, gallium, germanium, and many more. Other significant geologic and geophysical features covered include the Reelfoot rift, the New Madrid seismic zone, the Illinois basin, the Arkoma basin, the South-Central magnetic lineament, and the Kentucky-Tennessee magnetic anomaly (Fig. 1). This presentation focuses on new airborne magnetic and radiometric data with continuous coverage across parts of six states, preliminary interpretations, examples of geologic mapping applications, and discussion of newly discovered magnetic anomalies and follow-up investigations.

Conference Paper

Perchlorate, metals, organic compounds, and lead isotopes in groundwater, surface water, shallow groundwater, and soil within and near the Middleton Municipal Airport–Morey Field (C29), Middleton, Wisconsin, 2022

The Middleton Municipal Airport–Morey Field (C29) is in the City of Middleton and adjacent to the towns of Middleton and Springfield, Wisconsin. Nearby homes in the towns rely on private drinking water wells, and residents are concerned about the potential contamination of groundwater and surface water by airport activities, including flights by small aircraft that use leaded aviation fuel and a fireworks display in July 2021. The U.S. Geological Survey, in cooperation with the Town of Middleton, completed a study in 2022 to characterize the occurrence and sources of perchlorate, metals (including lead), and organic compounds in samples of groundwater, surface water, shallow groundwater, and soils within and near the airport. Lead isotopes were also measured to determine sources of lead by comparing samples to environmental references. Magnitudes of concentrations from samples of water and soil collected in 2022, and their spatial patterns across site locations, indicate the fireworks display in July 2021 was a likely source of perchlorate and metals in the airport study area. The highest perchlorate concentration was measured in surface water at the southeastern corner of the airport near the fireworks launch site; the highest concentrations of fireworks-associated metals were measured in shallow groundwater near the same location. Fireworks were not the only possible source of perchlorate and metals in the airport study area because both were also detected upgradient and away from the fireworks launch site. Ratios of lead isotopes indicate that lead measured in water and soil within the airport study area was primarily sourced from background atmospheric lead deposition or Wisconsin galena lead ore. However, two groundwater samples (one upgradient and one downgradient from the airport; both with concentrations less than 1 microgram per liter) had isotopic signatures matching leaded aviation fuel sold at the airport.

Wisconsin

Temperature

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface-water and groundwater resources. This chapter, NFM A6.1, provides guidance and protocols for the measurement of temperature of air, of a surface-water body or in groundwater, which include the scientific basis of the measurement, selection and maintenance of equipment, calibration verification, troubleshooting, and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.1, version 2.0, by Franceska D. Wilde. Temperature of air and water is routinely measured when water samples are collected, is often measured continually at USGS streamgages, and is a parameter regularly measured during laboratory and field experiments. The field method for measuring temperature described in this chapter is applicable to air and most natural waters. Before 2017, the NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.usgs.gov/ . Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods

A benchmark dataset and workflow for landslide susceptibility zonation

Landslide susceptibility shows the spatial likelihood of landslide occurrence in a specific geographical area and is a relevant tool for mitigating the impact of landslides worldwide. As such, it is the subject of countless scientific studies. Many methods exist for generating a susceptibility map, mostly falling under the definition of statistical or machine learning. These models try to solve a classification problem: given a collection of spatial variables, and their combination associated with landslide presence or absence, a model should be trained, tested to reproduce the target outcome, and eventually applied to unseen data. Contrary to many fields of science that use machine learning for specific tasks, no reference data exist to assess the performance of a given method for landslide susceptibility. Here, we propose a benchmark dataset consisting of 7360 slope units encompassing an area of about 4,100 km 2 "> 4,100 km 2 in Central Italy. Using the dataset, we tried to answer two open questions in landslide research: (1) what effect does the human variability have in creating susceptibility models; (2) how can we develop a reproducible workflow for allowing meaningful model comparisons within the landslide susceptibility research community. With these questions in mind, we released a preliminary version of the dataset, along with a “call for collaboration,” aimed at collecting different calculations using the proposed data, and leaving the freedom of implementation to the respondents. Contributions were different in many respects, including classification methods, use of predictors, implementation of training/validation, and performance assessment. That feedback suggested refining the initial dataset, and constraining the implementation workflow. This resulted in a final benchmark dataset and landslide susceptibility maps obtained with many classification methods. Values of area under the receiver operating characteristic curve obtained with the final benchmark dataset were rather similar, as an effect of constraints on training, cross–validation, and use of data. Brier score results show larger variability, instead, ascribed to different model predictive abilities. Correlation plots show similarities between results of different methods applied by the same group, ascribed to a residual implementation dependence. We stress that the experiment did not intend to select the “best” method but only to establish a first benchmark dataset and workflow, that may be useful as a standard reference for calculations by other scholars. The experiment, to our knowledge, is the first of its kind for landslide susceptibility modeling. The data and workflow presented here comparatively assess the performance of independent methods for landslide susceptibility and we suggest the benchmark approach as a best practice for quantitative research in geosciences.

Earth-Science Reviews

An orbital comparison of a late mantling unit on Aeolis Mons with other erosion-resistant strata explored by MSL in Gale crater, Mars

Previous investigations along Curiosity 's traverse in Gale crater have explored the relationship between orbital and in situ observations. This work aims to better understand the geologic environment of units only observable from orbit and compare them to the properties of units examined by Curiosity . Here, we map an erosion-resistant dark-toned mantling unit that overlies the modern topography of Aeolis Mons (informally known as Mt. Sharp) and compare this unit to two other previously mapped dark-toned resistant units, the marker band and the mound skirting unit (MSU), that have been inferred to represent different geologic environments (lacustrine and aeolian, respectively). Visible to short wave infrared spectra from the Compact Reconnaissance Imaging Spectrometer for Mars and visual images from the High Resolution Imaging Science Experiment and Context Cameras aboard the Mars Reconnaissance Orbiter are used for this comparison. Spectral data suggest a mafic composition with minor alteration, although the composition varies more with location around Mt. Sharp rather than between units. Morphologically, the mantling unit has strong similarities to the marker band based on their consistent low-albedo, erosion-resistance, and smooth appearance, contrasting with the highly variable surface texture of the MSU. We hypothesize that all three units had a similar sediment source but experienced aqueous alteration at different times: early ubiquitous cementation in a surface aqueous environment in the mantling unit and marker band versus patchy late diagenesis in the MSU. If true, these results suggest that water activity continued within the Gale crater long after the erosion of Mt. Sharp.

JGR Planets

Mineral commodity summaries 2025

Introduction Each mineral commodity chapter of the 2025 edition of the U.S. Geological Survey (USGS) Mineral Commodity Summaries (MCS) includes information on events, trends, and issues for each mineral commodity as well as discussions and tabular presentations on domestic industry structure, Government programs, tariffs, 5-year salient statistics, and world production, reserves, and resources. The MCS is the earliest comprehensive source of 2024 mineral production data for the world. More than 90 individual minerals and materials are covered by two-page synopses. Abbreviations and units of measure and definitions of selected terms used in the report are in Appendix A and Appendix B, respectively. Reserves and resources information is in Appendix C, which includes “Part A—Resource and Reserve Classification for Minerals” and “Part B—Sources of Reserves Data.” A directory of USGS minerals information country specialists and their responsibilities is in Appendix D. The USGS continually strives to improve the value of its publications to users. Constructive comments and suggestions by readers of the MCS 2025 are welcomed.

Mineral Commodity Summaries