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At least 1,297 records · Page 72Linked to original sources
USGS1993

Hydrology, water quality, trophic status, and aquatic plants of Fowler Lake, Wisconsin

The U.S. Geological Survey, in cooperation with the Fowler Lake Management District, completed a hydrologic and water-quality study of Fowler Lake in southeastern Wisconsin during calendar year 1984. Data on temperature, pH, specific conductance, and concentrations of dissolved oxygen, total phosphorus, dissolved orthophosphate phosphorus, and various nitrogen species were collected from January through November 1984. The water-quality data indicate that Fowler Lake can be classified as a mildly fertile lake with excellent water clarity as indicated by Secchi depth readings generally greater than 12 feet. Although phosphorus concentrations are generally less than 0.01 milligram per liter, the lake does produce dense stands of macrophytes during the open-water period. The lake is thermally stratified during the summer months, resulting in oxygen depletion in the deepest parts of the lake. The average hydraulic residence time for Fowler Lake during 1984 was 6.9 days, which is substantially less than the 305 days for upstream Okauchee Lake or the 145 days for downstream Lac La Belle. Precipitation during 1984 was about 27 percent higher than normal and streamflows in the area were about 55 percent higher than normal. The Oconomowoc River contributed 98 percent of the inflow and 88 percent of the phosphorus load to Fowler Lake. The low annual phosphorus input (28 pounds per square mile) to the lake from the Oconomowoc River shows the benefit of upstream lakes on the Oconomowoc River. Fourteen percent of the phosphorus input load to Fowler Lake is deposited in the lake sediments and the rest is transported through the lake by surface-water flow to downstream Lac La Belle. Dense growths of macrophytes in the lake change in composition seasonally; chara sp. (muskgrass) and Myriophyllum sp. (milfoil) are abundant in June and Najas marina and Vallesneria Americana (wild celery) are abundant in August.

Wisconsin↗
USGS1993

Hydrology and water quality of Wind Lake in southeastern Wisconsin

The hydrology and water quality of Wind Lake-a recreational lake in a densely populated area of southeastern Wisconsin was studied from October 1, 1987 through September 30,1989. A drought in 1988 affected the hydrologic budget of Wind Lake in water years 1988-89. Precipitation was 5.9 inches less than normal in water year 1988 but was 2.3 inches greater than normal in water year 1989. Streamflows were near normal in water year 1988 and 25 percent less than normal in water year 1989 as indicated by data from a nearby streamflow-gaging station. Surface runoff was the dominant source of water to the lake in water year 1988 and 75 percent of the inflow was from Big Muskego Lake. The water level in Big Muskego Lake was 1.1 feet below the dam crest at the start of the 1989 water year because of the 1988 drought. About 2,510 acre-feet of water had to fill Big Muskego Lake before water could discharge to Wind Lake. In water year 1989, surface runoff was still the dominant source of water to the lake, but Big Muskego Lake only contributed 52 percent of the water inflow. Streamflow dominated the outflow budget for both years. In water year 1988, 88 percent of the outflow budget left by way of Wind Lake outlet and 12 percent evaporated from the lake surface. In water year 1989, 81 percent of the outflow budget left by way of Wind Lake outlet and 19 percent evaporated from the lake surface. On the basis of outflow from Wind Lake for water year 1988, the hydraulic residence time was 0.46 year; in water year 1989 it was 1.05 years. The total phosphorus input to Wind Lake from external sources was the same for both years, 3,160 pounds. The largest percentage of the phosphorus load came from Big Muskego Lake-- 70 percent in water year 1988 and 65 percent in water year 1989. Analysis of data by use of Vollenweider's model indicates that the phosphorus loadings for each year would cause eutrophic conditions. Data from a nearby gaging station indicate that phosphorus loading to Wind Lake was less than normal. Phosphorus retention in the lake is small and averages 14 percent of the incoming load for both years. Oxygen depletion occurs in the bottom waters during winter and summer months. A maximum anoxic zone was reached on July 18, 1988, when depths greater than 15 feet (about 21 percent of the lake bottom area) were anoxic. Total phosphorus concentrations at the lake surface for both years ranged from 11 to 78 micrograms per liter. Mean total phosphorus concentrations in June, July, and August that had averaged 49 micrograms per liter in 1985 through 1987 declined to 20 micrograms per liter in water year 1988 and 22 micrograms per liter in water year 1989. This reduction was related to the drought and reduced phosphorus loadings. Phosphorus concentrations 1.5 feet above the lake bottom increase during summer anoxic periods. The phosphorus concentration increased at a rate of 5.2 and 4.8 micrograms per liter per day for total and dissolved orthophosphate phosphorus. A maximum concentration of 760 micrograms per liter of total phosphorus and 650 micrograms per liter of dissolved orthophosphate phosphorus occurred on September 21, 1988, just before autumn turnover. Internal loading of phosphorus for the period October 15, 1987 through October 14, 1988, was estimated to be 2,890 pounds. This represents 48 percent of the combined internal and external total-phosphorus input of 5,960 pounds. Algal populations in water year 1988 ranged from 28,200 to 1,610,000 cells per milliliter. A total of 143 species were identified. Blue-green algae dominated the algal population and ranged from 56 percent (February 16, 1988) to 99 percent (five other sampling dates). Aphanocapsa delicatissima caused the largest algal bloom, which reached a maximum concentration of 934,000 cells per milliliter (September 7, 1988). Zooplankton populations in water year 1988 ranged from 52.5 to 686 organisms per liter. Eighteen species were identified. The cladoceran, Daphnia, dominated 12 of the 18 samples.

Wisconsin↗
USGS1993

Hydrology and water quality of Reedy Creek in the Reedy Creek Improvement District, central Florida, 1986-89

The Reedy Creek Improvement District encompasses an area of about 43 sq mi in southwestern Orange and northwestern Osceola Counties in central Florida. The District operates a wastewater-treatment plant that discharges through two forested wetland areas and a percolation-pond system into Reedy Creek. Discharges from these wetland systems provide a relatively steady base flow which maintains streamflow in Reedy Creek during periods of low rainfall. Streamflows during the study were characterized by relatively long periods of below-average discharge interspersed with periods of high discharges. The highest mean discharges were recorded in 1988 and the lowest mean discharges were recorded in 1989. Water-quality data collection included the operation of four continuous water-quality monitors recording hourly water temperature, specific conductance, and dissolved oxygen concentration, and the collection of water-quality samples. Dissolved oxygen concentrations were similar for all stations on Reedy Creek and frequently were less than the minimum Florida standard of 5.0 mg/L. These low dissolved oxygen concentrations probably are the result of natural conditions. Nutrient analyses of water-quality samples were used to compute loadings into and out of a wetland conservation area in the southern part of the District and in the reach of Reedy Creek downstream from the wastewater discharges. Overall retention percentages for 1986-89, not including atmospheric and precipitation inputs, were 59.1 percent for total ammonia nitrogen: 3.4 percent for total organic nitrogen, which was the predominant nitrogen species: 33.2 percent for total nitrate nitrogen; 27.0 percent for total phosphorus; and 26.0 percent for total organic carbon. Highest loading inputs to the wetland conservation area were from the reach of Reedy Creek receiving wastewater discharge. Discharges from the wetlands receiving wastewater and entering the wetland conservation area during 1988 carried 16.3 percent of the total nitrogen load, and 25.0 percent of the total phosphorus load: during 1989 the discharges carried 22.0 percent of the total N and 21.0 percent of the total P.

Water-Resources Investigations Report↗
USGS1994

Geomorphic change caused by outburst floods and debris flows at Mount Rainier, Washington, with emphasis on Tahoma Creek valley

Debris flows have caused rapid geomorphic change in several glacierized drainages on Mount Rainier, Washington. Nearly all of these flows began as glacial outburst floods, then transformed to debris flows by incorporating large masses of sediment in channel reaches where streams have incised proglacial sediments and stagnant glacier ice. This stagnant ice is a relic of advanced glacier positions achieved during the mid-nineteenth century Little Ice Age maximum and the readvance of the 1960's and 1970's. Debris flows have been especially important agents of geomorphic change along Tahoma Creek, which drains South Tahoma Glacier. Debris flows in Tahoma Creek valley have transported downstream about 107 m3 Of sediment since 1967, causing substantial aggradation and damage to roads and facilities in Mount Rainier National Park. The average denudation rate in the upper part of the Tahoma Creek drainage basin in the same period has been extraordinarily high: more than 20 millimeters per year, a value exceeded only rarely in basins affected by debris flows. However, little or none of this sediment has yet passed out of the Tahoma Creek drainage basin. Outburst floods from South Tahoma Glacier form by release of subglacially stored water. The volume of stored water discharged during a typical outburst flood would form a layer several tens of millimeters thick over the bed of the entire glacier, though it is more likely that large linked cavities account for most of the storage. Statistical analysis shows that outburst floods usually occur during periods of atypically hot or rainy weather in summer or early autumn, and that the probability of an outburst increases with temperature (a proxy measure of ablation rate) or rainfall rate. On the basis of these results, we suggest that outburst floods are triggered when rapid input of water to the glacier bed causes transient increase in water pressure, thereby destabilizing the linked-cavity system. The probabilistic nature of the relation between water-input rate and outburst-flood occurrence suggests that the connections between englacial conduits, basal cavities and main meltwater channels may vary temporally. The correlation between outburst floods and meteorological factors casts doubt on an earlier hypothesis that melting around geothermal vents triggers outburst floods from South Tahoma Glacier. The likelihood that outburst floods from South Tahoma Glacier will trigger debris flows should decrease with time, as the deeply incised reach of Tahoma Creek widens by normal slope processes and stagnant ice decays. Drawing analogies to the geomorphic evolution of a reach of Tahoma Creek first incised by an outburst flood in 1967, we suggest the present period of debris-flow activity along Tahoma Creek will last about 25 years, that is, until about the year 2010. Comparison of geomorphic change at Tahoma Creek to that in two other glacierized alphine basins indicates that debris-rich stagnant ice can be an importantsource of sediment to debris flows as long as floods are frequent or channel slope is great.

Washington↗
USGS1994

Sources and transport of sediment, nutrients, and oxygen-demanding substances in the Minnesota River basin, 1989-92

The Minnesota River, 10 major tributaries, and 21 springs were sampled to determine the sources and transport of sediment, nutrients, and oxygen- demanding substances. The study was part of a four-year assessment of non-point source pollution in the Minnesota River Basin. Runoff from tributary watersheds was identified as the primary source of suspended sediment and nutrients in the Minnesota River mainstem. Suspended-sediment, phosphorus, and nitrate concentrations were elevated in all major tributaries during runoff, but tributaries in the south-central and eastern part of the basin produce the highest annual loading to the mainstem because of higher annual precipitation and runoff in that part of the basin. Particle-size analyses showed that most of the suspended sediment in transport consisted of silt- and clay-size material. Phosphorus enrichment was indicated throughout the mainstem by total phosphorus concentrations that ranged from 0.04 to 0.48 mg/L with a median value of 0.22 mg/L, and an interquartile range of 0.15 to 0.29 mg/L. Nitrate concentrations periodically exceeded drinking water standards in tributaries draining the south-central and eastern part of the basin. Oxygen demand was most elevated during periods of summer low flow. Correlations between levels of biochemical oxygen demand and levels of algal productivity suggest that algal biomass comprises much of the oxygen-demanding material in the mainstem. Transport of sediment, nutrients, and organic carbon within the mainstem was found to be conservative, with nearly all tributary inputs being transported downstream. Uptake and utilization of nitrate and orthophosphorus was indicated during low flow, but at normal and high flow, inputs of these constituents greatly exceeded biological utilization.

Minnesota, South Dakota↗
USGS1995

Factors affecting water quality and net flux of solutes in two stream basins in the Quabbin Reservoir drainage basin, central Massachusetts, 1983-85

The factors that affect stream-water quality were studied at West Branch Swift River (Swift River), and East Branch Fever Brook (Fever Brook), two forested watersheds that drain into the Quabbin Reservoir, central Massachusetts, from December 1983 through August 1985. Spatial and temporal variations of chemistry of precipitation, surface water; and ground water and the linkages between chemical changes and hydrologic processes were used to identify the mechanisms that control stream chemistry. Precipitation chemistry was dominated by hydrogen ion (composite p.H 4.23), sulfate, and nitrate. Inputs of hydrogen and nitrate from pre- cipitation were almost entirely retained in the basins, whereas input of sulfate was approximately balanced by export by streamflow draining the basins. Both streams were poorly buffered, with mean pH near 5.7, mean alkalinity less than 30 microequivalents per liter, and sulfate concen- trations greater than 130 microequivalents per liter. Sodium and chloride, derived primarily from highway deicing salts, were the dominant solutes at Fever Brook. After adjustments for deicing salts, fluxes of base cations during the 21-month study were 2,014 and 1,429 equivalents per hectare in Swift River and Fever Brook, respectively. Base cation fluxes were controlled primarily by weathering of hornblende (Fever Brook) and plagioclase (Swift River). The overall weathering rate was greater in the Swift River Basin because easily weathered gabbro underlies one subbasin which comprises 11.2 percent of the total basin area but contributed about 77 percent of the total alkalinity. Alkalinity export was nearly equal in the two basins, however, because some alkalinity was generated in wetlands in the Fever Brook Basin through bacterial sulfate reduction coupled with organic-carbon oxidation.

Massachusetts↗
USGS1994

Hydrology and water quality of Whitewater and Rice lakes in southeastern Wisconsin, 1990-91

The hydrology and water quality of Whitewater and Rice Lakes was studied by the U.S. Geological Survey during November 15, 1990November 14, 1991, in cooperation with the Whitewater-Rice Lakes Management District, Walworth County, Wis. Whitewater and Rice Lakes are small, shallow lakes; surface areas are 697 and 162 acres and mean depths are 8.4 feet and 5.8 feet, respectively. Although both lakes have surface outlets, water levels were below the dam crests during the study, and no water left the lake through the outlets. The drainage basin of Whitewater Lake is 10.9 square miles and that of Rice Lake is 11.8 square miles; but, because of large amounts of depressional areas, only 1.4 square miles and 0.2 square mile, respectively, contribute surface runoff to the lakes. Whitewater Lake is an artificial lake created in 1947 by the damming of three smaller lakes. Rice Lake is an artificial lake created in 1954 by the damming of Whitewater Creek, which drains Whitewater Lake. Maintaining the lake levels at the elevations of their dam crests has been difficult since the lakes were created. For most years, water levels were below the lakes' dam crests. Ground water, precipitation, and evaporation are important components in the hydrologic budgets of the lakes. For Whitewater Lake, ground water was the dominant source of water, accounting for 57 percent of the inflow budget; precipitation accounted for 26 percent. Ground water also dominated the outflow, accounting for 81 percent of the outflow budget. The remaining 19 percent of the outflow budget was evaporation. For Rice Lake, precipitation was the dominant source of water, accounting for 88 percent of the inflow budget; ground water accounted for 8 percent. Evaporation dominated the outflow budget, at 70 percent, whereas ground water accounted for 30 percent. The external phosphorus budget for Whitewater Lake showed that shoreline drainage was the largest source of phosphorus to the lake42 percent of the total input of 558 pounds. Other sources of phosphorus were septic systems, 19 percent of the total; precipitation, 18 percent; a spring inlet at base flow, 13 percent; and ground water, 8 percent. The external phosphorus budget for Rice Lake showed that shoreline drainage also was the largest source of phosphorus to the lake-59 percent of the total input of 63 pounds; other sources were precipitation, 38 percent of the total; and ground water, 3 percent. Application of Vollenweider's phosphorus loading model fairly accurately predicted the lakes' spring turnover phosphorus concentrations and suggested that the external loading of phosphorus would result in mesotrophic to eutrophic conditions for Whitewater Lake and mesotrophic conditions for Rice Lake. Dillon and Rigler's model further suggested additional phosphorus from internal recycling was required to result in the high chlorophyll-a concentrations experienced in both systems during summer. Internal recycling of phosphorus in addition to external loading seems to also cause waterquality problems in both lakes. The amount of phosphorus recycled from the lake sediments was estimated from a mass-balance approach for April 1-November 14, 1991. For Whitewater Lake, the internal load of 582 pounds was slightly greater than the annual external load of 558 pounds. For Rice Lake, the internal load of 295 pounds far exceeded the annual external load of 63 pounds.

Wisconsin↗
USGS1995

Estimates of ground-water recharge rates for two small basins in central Nevada

Estimates of ground-water recharge rates developed from hydrologic modeling studies are presented for 3-Springs and East Stewart basins. two small basins (analog sites) located in central Nevada. The analog-site studies were conducted to aid in the estimation of recharge to the paleohydrologic regime associated with ground water in the vicinity of Yucca Mountain under wetter climatic conditions. The two analog sites are located to the north and at higher elevations than Yucca Mountain, and the prevailing (current) climatic conditions at these sites is thought to be representative of the possible range of paleoclimatic conditions in the general area of Yucca Mountain during the Quaternary. Two independent modeling approaches were conducted at each of the analog sites using observed hydrologic data on precipitation, temperature, solar radiation stream discharge, and chloride-ion water chemistry for a 6-year study period (October 1986 through September 1992). Both models quantify the hydrologic water-balance equation and yield estimates of ground-water recharge, given appropriate input data. The first model uses a traditional approach to quantify watershed hydrology through a precipitation-runoff modeling system that accounts for the spatial variability of hydrologic inputs, processes, and responses (outputs) using a dailycomputational time step. The second model is based on the conservative nature of the dissolved chloride ion in selected hydrologic environments, and its use as a natural tracer allows the computation of acoupled, water and chloride-ion, mass-balance system of equations to estimate available water (sum ofsurface runoff and groundwater recharge). Results of the modeling approaches support the conclusion that reasonable estimates of average-annual recharge to ground water range from about 1 to 3 centimeters per year for 3-Springs basin (the drier site), and from about 30 to 32 centimeters per year for East Stewart basin (the wetter site). The most reliable results are those derived from a reduced form of the chloride-ion model because they reflect integrated, basinwide processes in terms of only three measured variables: precipitation amount, precipitation chemistry, and streamflow chemistry.

Nevada↗
USGS1995

A computer program (MACPUMP) for interactive aquifer-test analysis

This report introduces MACPUMP (Version 1.0), an aquifer-test-analysis package for use with Macintosh4 computers. The report outlines the input- data format, describes the solutions encoded in the program, explains the menu-items, and offers a tutorial illustrating the use of the program. The package reads list-directed aquifer-test data from a file, plots the data to the screen, generates and plots type curves for several different test conditions, and allows mouse-controlled curve matching. MACPUMP features pull-down menus, a simple text viewer for displaying data-files, and optional on-line help windows. This version includes the analytical solutions for nonleaky and leaky confined aquifers, using both type curves and straight-line methods, and for the analysis of single-well slug tests using type curves. An executable version of the code and sample input data sets are included on an accompanying floppy disk.

Water-Resources Investigations Report↗
USGS1995

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma: Analysis of information on nutrients, suspended sediment, and suspended solids, 1970-92

Water-quality data collected during water years 1970-90 (October 1 to September 30) for 83 surface-water sites and during 1970-92 for 395 ground-water sites in the 48,000 square mile Ozark Plateaus study unit of the National Water Quality Assessment Program were analyzed using selected descriptive and statistical methods. The water- quality data include nutrient (nitrogen and phosphorus), suspended sediment, and suspended- solids data, and ancillary information such as fertilizer use, animal waste, sewage treatment plant, and land use. Statistically significant differences exist in surface-water quality that can be attributed to physiography, land use, and other effects. The sites that were considered to be substantially affected by sewage treatment plants had the largest concentrations of nutrients. Nutrient concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. Statistically significant differences existed in the quality of ground water that can be attributed to hydrogeologic and land-use effects. Nutrient concentrations generally were largest where the water source is indicated to be shallow in origin and where parts of the hydrogeologic units are in agricultural land-use areas. Water quality has changed at several surface-water sites since 1970. Nutrient concentrations appear to have increased at some sites and decreased at other sites. Causes of these apparent trends are not known, but many of the sites with apparent trends are in agricultural areas. Surface-water loads of nutrients and suspended sediment were affected by several factors including streamflow, climate, drainage area, reservoir operation, and inputs from point and nonpoint sources. Annual loads were largest in large basins, with large inputs of nutrients or sediment during periods of high streamflows at locations where reservoir operation effects are not substantial.

Arkansas, Kansas, Missouri, Oklahoma↗
USGS1995

User's guide to PHREEQC, a computer program for speciation, reaction-path, advective-transport, and inverse geochemical calculations

PHREEQC is a computer program written in the C programming language that is designed to perform a wide variety of aqueous geochemical calculations. PHREEQC is based on an ion-association aqueous model and has capabilities for (1) speciation and saturation-index calculations, (2) reaction-path and advective-transport calculations involving specified irreversible reactions, mixing of solutions, mineral and gas equilibria surface-complex-ation reactions, and ion-exchange reactions, and (3) inverse modeling, which finds sets of mineral and gas mole transfers that account for composition differences between waters, within specified compositional uncertainties. PHREEQC is derived from the Fortran program PHREEQE, but it has been completely rewritten in C with the addition many new capabilities. New features include the capabilities to use redox couples to distribute redox elements among their valence states in speciation calculations; to model ion-exchange and surface-complex-ation reactions; to model reactions with a fixed-pressure, multicomponent gas phase (that is, a gas bubble); to calculate the mass of water in the aqueous phase during reaction and transport calculations; to keep track of the moles of minerals present in the solid phases and determine automatically the thermodynamically stable phase assemblage; to simulate advective transport in combination with PHREEQC's reaction-modeling capability; and to make inverse modeling calculations that allow for uncertainties in the analytical data. The user interface is improved through the use of a simplified approach to redox reactions, which includes explicit mole-balance equations for hydrogen and oxygen; the use of a revised input that is modular and completely free format; and the use of mineral names and standard chemical symbolism rather than index numbers. The use of (2) eliminates nearly all limitations on army sizes, including numbers of elements, aqueous species, solutions, phases, and lengths of character strings. A new equation solver that optimizes a set of equalities subject to both equality and inequality constraints is used to determine the thermodynamically stable set of phases in equilibrium with a solution. A more complete Newton-Raphson formulation, master-species switching, and scaling of the algebraic equations reduce the number of failures of the numerical method in PHREEQC relative to PHREEQE. This report presents the equations that are the basis for chemical equilibrium and inverse-modeling calculations in PHREEQC, describes the input for the program, and presents twelve examples that demonstrate most of the program's capabilities.

Water-Resources Investigations Report↗
USGS1996

Assessment of water quality, nutrients, algal productivity, and management alternatives for low-flow conditions, South Umpqua River basin, Oregon, 1990-92

This report is an evaluation of the effects of nutrient loading on water quality in the South Umpqua River Basin. The study was done by the U.S. Geological Survey in cooperation with Douglas County, Oregon. Five wastewater-treatment plants were shown to contribute less than 15 percent of the flow, but more than 90 percent of the nitrogen and phosphorus, in the South Umpqua River during low streamflows in summer. These nutrient inputs were associated with, and largely responsible for, the dense growth of periphytic algae that covered the rocky channel and produced biomass values as large as 340 grams of ash-free dry weight per square meter. The nighttime respiration of periphytic algae caused violations of the Oregon water-quality standard, which requires a dissolved oxygen concentration of at least 90 percent of saturation, at most sites along the South Umpqua River. Photosynthesis by algae during daylight resulted in many exceedances of the Oregon pH standard of 8.5. Net productivity, calculated from hourly measurements of dissolved oxygen concentrations, was as much as 3.8 grams of oxygen per square meter per day. The magnitude of productivity increased with increases in dissolved inorganic nitrogen concentration and load. The large amount of nutrient uptake by algae resulted in lowered nutrient concentrations downstream from nutrient point sources. Management alternatives for the South Umpqua River Basin include several methods to reduce nutrient concentrations and loads. The reduction of dissolved-inorganic-nitrogen and soluble- reactive-phosphorus loads from wastewater- treatment-plant effluent would reduce the frequency of violations of water-quality standards. Flow augmentation probably would decrease water-quality problems in the river, but it is difficult to predict the magnitude of the effects of increased velocity and decreased temperature on algal growth. Land application and storage of wastewater-treatment-plant effluent during the summer months would reduce the input of nutrients from point sources. Three exceedances of the Oregon standard for fecal coliform of 200 colonies per 100 milliliters were associated with large streamflows, suggesting that nonpoint sources affect the river during periods of high runoff. Fecal-streptococcus counts were larger than historical values and require confirmation. Ammonia from wastewater-treatment-plant effluent, high pH values, and high temperatures present a potential for chronic ammonia toxicity in the lower reaches of the South Umpqua River; however, actual violations of standards for chronic concentrations were not detected because of diel fluctuations in pH and water temperature.

Oregon↗
USGS1996

Use of frequency-volume analyses to estimate regionalized yields and loads of sediment, phosphorus, and polychlorinated biphenyls to lakes Michigan and Superior

In most rivers, transport of various constituents occurs largely during short-term, high-intensity events. A method is described to make regionalized estimates of the long-term average loads of selected streamwater constituents, as well as loads occurring during high-flow events with specified recurrence intervals. This method is used to estimate the load of suspended sediment, total phosphorus, and sediment-borne constituents, such as poly chlorinated biphenyls (PCB's), from all the rivers in the United States that drain into Lake Michigan and Lake Superior whose drainage basins are greater than 325 square kilometers. Statistical comparisons of estimated loads and environmental factors indicate that suspendedsediment loads were primarily affected by river gradient and secondarily affected by the texture of surficial deposits, whereas total phosphorus loadings were primarily affected by the texture of surficial deposits and secondarily affected by river gradient. Total phosphorus loads were highest in rivers entering into the middle to southern part of Lake Michigan, especially rivers in areas draining clay surficial deposits and agricultural areas. During high flow, inputs of phosphorus and suspended sediment from rivers entering the southwestern part of Lake Superior become very important to the total input of these constituents; these rivers have steep gradients and drain surficial deposits with high clay content. The single largest contributor of PCB's during the entire period and during each type of high-flow event was the Fox River, which supplied 46 to 64 percent of the total PCB load to both lakes.

Michigan, Wisconsin↗
USGS1996

Water-quality assessment of the Albermarle-Pamlico drainage basin, North Carolina and Virginia— A summary of selected trace element, nutrient, and pesticide data for bed sediments, 1969-90

Spatial distributions of metals and trace elements, nutrients, and pesticides and polychiorinated biphenyls (PCB's) in bed sediment were characterized using data collected from 1969 through 1990 and stored in the U.S. Geological Survey's National Water Data Storage and Retrieval (WATSTORE) system and the U.S. Environmental Protection Agency's Storage and Retrieval (STORET) system databases. Bed-sediment data from WATSTORE and STORET were combined to form a single database of 1,049 records representing 301 sites. Data were examined for concentrations of 16 metals and trace elements, 4 nutrients, 10 pesticides, and PCB's. Maximum bed-sediment concentrations were evaluated relative to sediment-quality guidelines developed by the National Oceanic and Atmospheric Administration, the Ontario Ministry of Environment and Energy, and the Virginia Department of Environmental Quality. Sites were not selected randomly; therefore, results should not be interpreted as representing average conditions. Many sites were located in or around lakes and reservoirs, urban areas, and areas where special investigations were conducted. Lakes and reservoirs function as effective sediment traps, and elevated concentrations of some constituents occurred at these sites. High concentrations of many metals and trace elements also occurred near urban areas where streams receive runoff or inputs from industrial, residential, and municipal activities. Elevated nutrient concentrations occurred near lakes, reservoirs, and the mouths of major rivers. The highest concentrations of arsenic, beryllium, chromium, iron. mercury, nickel, and selenium occurred in the Roanoke River Basin and may be a result of geologic formations or accumulations of bed sediment in lakes and reservoirs. The highest concentrations of cadmium, lead, and thallium were detected in the Chowan River Basin; copper and zinc were reported highest in the Neuse River Basin. Total phosphorus and total ammonia plus organic nitrogen concentrations exceeded the sediment evaluation guidelines in each major river basin, possibly resulting from wastewater inputs and agricultural applications. Exceedances of pesticide guidelines were detected in the upper Neuse River Basin near Falls Lake and in the lower Tar River Basin.

North Carolina, Virginia↗
USGS1996

Water-quality assessment of southern Florida: An overview of available information on surface- and ground-water quality and ecology

This report summarizes water-quality conditions, issues of concern, and management efforts underway in southern Florida. The report is designed to provide a conceptual framework for the Southern Florida National Water Quality Assessment (NAWQA) study that began in 1994. The report makes reference to the most important water-quality literature pertaining to southern Florida, to water-quality studies that are underway or planned, and to topics which are of high priority in the study unit. These topics include: the availability and suit ability of water for competing demands; nutrient enrichment of the Everglades; transport, degradation, and effects of pesticides; and the sources and cycling of mercury in the ecosystem. The report also includes a retrospective analysis and conceptual presentation of nutrient loading, which is a high priority for the national NAWQA Program and for regional water-quality managers. Nutrient contributions from point and nonpoint sources are estimated for nine basins in the study area and are discussed in relation to land use. Fertilizer is the dominant source of phosphorus in eight basins and the dominant source of nitrogen in at least five basins. Atmospheric sources of nitrogen contribute more than 20 percent of the total nitrogen input to all basins and are the dominant source of nitrogen input to Lake Okeechobee and the Everglades. Nutrient loads are also estimated in selected canal and river outflows in southern Florida to provide a spatial overview of the magnitude of nutrient loading to coastal waters. Annual phosphorus loads from the Peace River are the highest in the study unit; annual phosphorus loads from the Caloosahatchee River and the major Palm Beach canals are also high, compared to other parts of southern Florida. Estimated annual loads of phosphorus from parts of the Big Cypress Basin and the S-12 water-control structures of the Tamiami Canal are low compared with estimated phosphorus loads in outflows in the northern part of the study unit. Annual nitrogen loads in southern Florida were highest in outflows from the Caloosahatchee River Basin and the major Palm Beach canals. Nitrogen loads in outflows from parts of the Big Cypress subbasin were lower than those estimated to the north.

Florida↗
USGS1997

Assessment of nutrients, suspended sediment, and pesticides in surface water of the upper Snake River basin, Idaho and western Wyoming, water years 1991-95

A water-quality investigation of the upper Snake River Basin began in 1991 as part of the U.S. Geological Survey's National Water- Quality Assessment Program. As part of the investigation, intensive monitoring was conducted during water years 1993 through 1995 to assess surface-water quality in the basin. Sampling and analysis focused on nutrients, suspended sediments, and pesticides because of nationwide interest in these constituents. Concentrations of nutrients and suspended sediment in water samples from 19 sites in the upper Snake River Basin, including nine on the main stem, were assessed. In general, concentrations of nutrients and suspended sediment were smaller in water from the 11 sites upstream from American Falls Reservoir than in water from the 8 sites downstream from the reservoir where effects from land-use activities are most pronounced. Median concentrations of dissolved nitrite plus nitrate as nitrogen at the 19 sites ranged from less than 0.05 to 1.60 milligrams per liter; total phosphorus as phosphorus, less than 0.01 to 0.11 milligrams per liter; and suspended sediment, 4 to 72 milligrams per liter. Concentrations of nutrients and suspended sediment in the main stem of the Snake River, in general, increased downstream. The largest concentrations in the main stem were in the middle reach of the Snake River between Milner Dam and the outlet of the upper Snake River Basin at King Hill. Significant differences (p<0.05) in nutrient and suspended sediment concentrations were noted among groups of sites categorized by the quantity of agricultural land in their upstream drainage basins. Water samples collected from sites in drainage basins where agricultural land constituted less than 10 percent of the land use contained significantly smaller concentrations of nutrients and suspended sediment than samples from sites in drainage basins where agricultural land constituted more than 10 percent of the land use. Significant differences in nutrient and suspended sediment concentrations were inconsistent among groups representing 10 to 19 percent, 20 to 29 percent, and greater than 29 percent agricultural land use. Seasonal concentrations of dissolved nitrite plus nitrate, total phosphorus, and suspended sediment were significantly different among most of the agricultural land-use groups. Concentrations of dissolved nitrite plus nitrate were largest during the nonirrigation season, October through March. Concentrations of total phosphorus and suspended sediment, in general, were largest during high streamflow, April through June. Nutrient and suspended sediment inputs to the middle Snake reach were from a variety of sources. During water year 1995, springs were the primary source of water and total nitrogen to the river and accounted for 66 and 60 percent of the total input, respectively. Isotope and water-table information indicated that the springs derived most of their nitrogen from agricultural activities along the margins of the Snake River. Aquacultural effluent was a major source of ammonia (82 percent), organic nitrogen (30 percent), and total phosphorus (35 percent). Tributary streams were a major source of organic nitrogen (28 percent) and suspended sediment (58 percent). In proportion to its discharge (less than 1 percent), the Twin Falls sewage-treatment plant was a major source of total phosphorus (13 percent). A comparison of discharge and loading in water year 1995 with estimates of instream transport showed a good correlation (relative difference of less than 15 percent) for discharge, total organic nitrogen, dissolved nitrite plus nitrate, total nitrogen, and total phosphorus. Estimates of dissolved ammonia and suspended sediment loads correlated poorly with instream transport; relative differences were about 79 and 61 percent, respectively. The pesticides EPTC, atrazine, desethylatrazine, metolachlor, and alachlor were the most commonly detected in the upper Snake River Basin and accounted for about 75 percent of all pesticide detections. All pesticides detected were at concentrations less than 1 microgram per liter and below water-quality criteria established by the U.S. Environmental Protection Agency. In samples collected from two small agriculturally dominated tributary basins, the largest number and concentrations of pesticides were detected in May and June following early growing season applications. At one of the sites, the pesticide atrazine and its metabolite desethylatrazine were detected throughout the year. On the basis of 37 samples collected basinwide in May and June 1994, total annual subbasin applications and instantaneous instream fluxes of EPTC and atrazine showed logarithmic relations with coefficients of determination (R2 values) of 0.55 and 0.62, respectively. At the time of sampling, the median daily flux of EPTC was about 0.0001 percent of the annual quantity applied, whereas the median daily flux of atrazine was between 0.001 and 0.01 percent.

Idaho;Wyoming↗
USGS1997

Review of selected features of the natural system model, and suggestions for applications in south Florida

A study was conducted to review selected features of the Natural System Model, version 4.3. The Natural System Model is a regional-scale model that uses recent climatic data and estimates of historic vegetation and topography to simulate pre-canal-drainage hydrologic response in south Florida. Equations used to represent the hydrologic system and the numerical solution of these equations in the model were documented and reviewed. Convergence testing was performed using 1965 input data, and selected other aspects of the model were evaluated. Some conclusions from the evaluation of the Natural System Model include the following observations. Simulations were generally insensitive to the temporal resolution used in the model. However, reduction of the computational cell size from 2-mile by 2-mile to 2/3-mile by 2/3-mile resulted in a decrease in spatial mean ponding depths for October of 0.35 foot for a 3-hour time step. Review of the computer code indicated that there is no limit on the amount of water that can be transferred from the river system to the overland flow system, on the amount of seepage from the river to the ground-water system, on evaporation from the river system, or on evapotranspiration from the overland-flow system. Oscillations of 0.2 foot or less in simulated river stage were identified and attributed to a volume limiting function which is applied in solution of the overland-flow equations. The computation of the resistance coefficient is not consistent with the computation of overland-flow velocity. Ground-water boundary conditions do not always ensure a no-flow condition at the boundary. These inconsistencies had varying degrees of effects on model simulations, and it is likely that simulations longer than 1 year are needed to fully identify effects. However, inconsistencies in model formulations should not be ignored, even if the effects of such errors on model results appear to be small or have not been clearly defined. The Natural System Model can be a very useful tool for estimating pre-drainage hydrologic response in south Florida. The model includes all of the important physical processes needed to simulate a water balance. With a few exceptions, these hydrologic processes are represented in a reasonable manner using empirical, semiempirical, and mechanistic relations. The data sets that have been assembled to represent physical features, and hydrologic and meteorological conditions are quite extensive in their scope. Some suggestions for model application were made. Simulation results from the Natural System Model need to be interpreted on a regional basis, rather than cell by cell. The available evidence suggests that simulated water levels should be interpreted with about a plus or minus 1 foot uncertainty. It is probably not appropriate to use the Natural System Model to estimate pre-drainage discharges (as opposed to hydroperiods and water levels) at a particular location or across a set of adjacent computational cells. All simulated results for computational cells within about 10 miles of the model boundaries have a higher degree of uncertainty than results for the interior of the model domain. It is most appropriate to interpret the Natural System Model simulation results in connection with other available information. Stronger linkages between hydrologic inputs to the Everglades and the ecological response of the system would enhance restoration efforts.

Florida↗
USGS1998

Seasonal and spatial variability of nutrients and pesticides in streams of the Willamette Basin, Oregon, 1993-95

From April 1993 to September 1995, the U.S. Geological Survey conducted a study of the occurrence and distribution of nutrients and pesticides in surface water of the Willamette and Sandy River Basins, Oregon, as part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program. About 260 samples were collected at 51 sites during the study; of these, more than 60 percent of the pesticide samples and more than 70 percent of the nutrient samples were collected at 7 sites in a fixed-station network (primary sites) to characterize seasonal water-quality variability related to a variety of land-use activities. Samples collected at the remain ing 44 sites were used primarily to characterize spatial water- quality variability in agricultural river subbasins located throughout the study area.This report describes concentrations of 4 nutrient species (total nitrogen, filtered nitrite plus nitrate, total phosphorus, and soluble reactive phosphorus) and 86 pesticides and pesticide degradation products in streams, during high- and low-flow conditions, receiving runoff from urban, agricultural, forested, and mixed-use lands. Although most nutrient and pesticide concentrations were relatively low, some concentrations exceeded maximum contaminant levels for drinking water and water-quality criteria for chronic toxicity established for the protection of freshwater aquatic life. The largest number of exceedances generally occurred at sites receiving predominantly agricultural inputs. Total nitrogen, filtered nitrite plus nitrate, total phosphorus, and soluble reactive phosphorus concentrations were detected in 89 to 98 percent of the samples; atrazine, simazine, metolachlor, and desethylatrazine were detected in 72 to 94 percent of the samples. Fifty different pesticides and degradation products was detected during the 2-1/2 year study.Seasonally, peak nutrient and pesticide concentrations at the seven primary sites were observed during winter and spring rains. With the exception of soluble reactive phosphorus, peak nutrient concentrations were recorded at agricultural sites during winter rains, whereas peak pesticide concentrations occurred at agricultural sites during spring rains.Spatially, although nutrients were detected slightly more often in samples from the northern Willamette Basin relative to the southern Willamette Basin, concentration distributions in the two areas were similar. About 75 percent more pesticides were detected in the northern basin; however, two-thirds of the pesticide detections in the southern basin were larger in concentration than for the same pesticides detected in the northern basin.Nutrient and pesticide concentrations were associated with percent of upstream drainage area in forest, urbanization, and agriculture. Nutrient concentrations at forested sites were among the smallest observed at any of the sites sampled. In addition, only one pesticide and one pesticide degradation product were detected at forested sites, at concentrations near the method detection limits. The highest nutrient concentrations were observed at agricultural sites. Further, the largest numbers of different pesticides detected were at agricultural sites, at concentrations generally larger than at most other land-use sites. Three pesticides--dichlobenil, prometon, and tebuthiuron--were detected more frequently at a site receiving predominantly urban inputs.

Water-Resources Investigations Report↗