USGS ScienceSearch

SEARCH · USGS Science

Results for “Geological Society of America Bulletin”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

1,666 records · Page 72Linked to original sources

Evaluating Laramide orogenesis via flexural basin response in the San Juan basin, New Mexico and Colorado

A challenge in interpreting the location, timing, and magnitude of ancient orogenic events is that ongoing uplift and erosion in the hinterlands often destroys much of the primary record of these events. However, basin-thickness patterns in the sedimentary record can provide complimentary evidence of uplift via flexural effects. Here, we deploy well-log correlation, isochores, basin modeling, flexural modeling, and subcrop mapping to evaluate the Late Cretaceous to Paleogene basin response to Laramide tectonism in the San Juan basin. A wedge of upper Campanian to Maastrichtian sedimentary rock thickens from 200 to 800 meters from southeast to northwest in the basin. This pattern can be successfully simulated via flexural modeling if we infer early Laramide uplift along the northwest basin flank that produced a 0.8 km high topographic load. The Laramide unconformity bounds the top of this Upper Cretaceous sedimentary wedge and truncates progressively older strata to the east, further supporting a westward tilt of the basin. The onset of Campanian Laramide flexure may have also contributed to the profound transgression from the upper Menefee Formation to the Lewis Shale. The Paleocene isochore map displays an approximately symmetrical pattern, with thickening towards the center of the basin. This suggests the possibility of competing flexural loads. The base Eocene structure indicates an asymmetric deep on the northeast flank of the basin, providing flexural evidence of contemporaneous uplift/loading of the Nacimiento uplift and Archuleta arch; this has been modeled as ~2.1 km load height. Both Cretaceous and Paleocene sedimentary wedges are narrow, suggesting low flexural rigidity; modeled effective elastic thicknesses (EET) are 20-30 km, comparable to estimates of modern EET for the region.

Colorado, New Mexico

Geochemical, mineralogical, and isotopic evidence for multi-stage genesis of the Hicks Dome REE + Y-HFSE-fluorite deposit, Illinois, USA

Hicks Dome hosts breccias enriched in rare earth elements (REE), Y, Th, F, Ba, Ti, Nb, and Be, alongside spatially associated lamprophyre dikes (ca. 271 Ma). Hicks Dome is located within the Illinois–Kentucky Fluorspar District, which hosts fluorite, Pb–Zn, and barite resources. This study investigates the genetic relationships between Hicks Dome mineralization in breccias, alkaline magmatism, and Illinois–Kentucky Fluorspar District mineralization. Lamprophyre dikes are light REE–enriched with chondrite-normalized abundances decreasing from La to Lu. The Host Breccia exhibits middle and heavy REE–enriched patterns that mirror those of the principal REE–Th host minerals, including fluorapatite, xenotime, and thorite. Textural evidence suggests recrystallization of phosphates, sulfates, and Ti–Nb oxides in the Host Breccia. U–Pb geochronology constrains multiple mineralizing events, with ages of 277 ± 18 Ma from low-Th apatite interpreted as main-stage mineralization, and 121.6 ± 9.7 Ma from high-Th apatite indicating later overprinting. O–H–C stable isotope data provide evidence for multiple stages of fluid-rock interaction and fluid mixing: (1) early magmatic fluids dissolved limestone country rock, (2) mixing between magmatic fluids and basinal brines led to main-stage mineralization in the Host Breccia, and (3) late-stage mineralization occurred following mixing of meteoric water and basinal brine. These results indicate that heavy REEs, high field strength elements, and fluorine precipitated proximal to its alkaline magmatic source because of fluid–rock interactions and fluid mixing. Subsequent fluid mixing drove late-stage recrystallization and additional fluorite formation, a process that may be similar to mineralization in the Illinois-Kentucky Fluorspar District.

Illinois

Climate-adaptive urban planning: Quantitative assessment of drought impacts and practical strategies for climate-resilient urban green spaces

Urban green spaces (UGSs) are vital for enhancing a city’s resilience and livability; however, their functionality is increasingly jeopardized by drought, particularly in water-scarce regions. This study evaluates drought impact on UGSs in Metropolitan Adelaide, Australia, a representative semi-arid urban system, using satellite-derived Normalized Difference Vegetation Index (NDVI) time-series data spanning 2000–2020. Vegetation dynamics were analyzed through Seasonal-Trend decomposition using Loess (STL), standardized anomaly assessment, lagged Pearson correlation, Ordinary Least Squares (OLS) regression, and Mann–Kendall trend analysis. To isolate climatically sensitive signals, 29 urban lawn patches were examined separately from mixed urban canopy, given their shallow root systems and direct dependence on surface moisture. NDVI declined by approximately 0.09 units during the Millennium Drought (2001–2009), with summer greenness deficits reaching 24% below the 20-year benchmark. Temperature was the dominant driver of lawn NDVI variability (r = −0.863, R 2 = 74.5%), substantially exceeding the effect of rainfall (r = 0.156, R 2 = 2.4%). El Niño–Southern Oscillation (ENSO) cycles modulated vegetation responses, with La Niña years supporting recovery and El Niño years amplifying decline. Post-drought recovery remained incomplete, with NDVI deficits of 8–20% persisting through 2020; full recovery was observed only in 2017, coinciding with the highest recorded summer rainfall. No significant directional trend was detected over the full study period (Mann–Kendall τ = 0.005, p = 0.908). These findings demonstrate that heat, rather than water limitation alone, is the primary driver of vegetation stress in urban systems, highlighting the benefits of integrated management strategies that address both warming and moisture deficits to sustain urban green infrastructure under future climate conditions. We introduce the concept of “urban greenery drought,” referring to a form of vegetation stress in managed urban landscapes where greenness is reduced primarily by elevated temperature and atmospheric demand despite water availability.

Adelaide

Petrogenesis and mineralization potential of spinifex komatiitic basalts in the Bradley Peak greenstone terrane, Wyoming Province

Komatiitic volcanic rocks are important hosts of Ni sulfide mineralization and record early Earth evolution; however, those in the well-studied Archean Wyoming Province have received little attention. Here, we elucidate the timing and petrogenesis of the Bradley Peak komatiitic volcanic rocks using field and textural observations, geochronology, and geochemistry. Detrital and igneous zircon U-Pb ages for two samples from previously undated units support published age determinations, placing the eruption age at 2.72 Ga. Stratigraphy of the volcanic flows was mapped and 36 samples including cumulates, greenschists, and spinifex-textured rocks were collected. Whole-rock geochemistry was used to classify the spinifex-textured samples as Al-undepleted komatiitic basalts (11–17 wt% MgO). Platinum-group element concentrations (n = 25) are like those in global Al-undepleted komatiitic basalts, and PGE/Ti ratios do not indicate the volcanic flows likely host sulfide mineralization. Initial ε Nd values of −0.5 to +4.7 (n = 16), indicate that these lavas were derived from a depleted mantle source and have negligible evolved crust contamination. The primary magma to the komatiitic basalt flows is estimated to have had 19 wt% MgO and be derived from ∼15 to 25 % mantle partial melting at 3–4 GPa. Trace element chemistry and thermodynamic modeling suggest the primary melt assimilated local banded iron formation. Although the Bradley Peak komatiitic basalts do not contain positive evidence of magmatic sulfide deposits, depleted Au in the flows suggests they could be source rocks for nearby orogenic gold deposits.

Wyoming

Microtextural characteristics of adularia in banded quartz veins from the Midas low-sulfidation epithermal deposit, Nevada

High-grade ores at the Miocene Midas low-sulfidation epithermal deposit in northern Nevada are confined to crustiform quartz veins containing abundant adularia. Micro-X-ray fluorescence elemental mapping reveals that adularia is a common gangue mineral occurring in colloform bands, bands showing bladed textures, and bands with dendritic terminations. The adularia aggregates have delicate shapes and are comprised of stacked, submillimeter crystals hosted by fine-grained quartz. The textural evidence suggests that the adularia aggregates originally formed within a gel-like, noncrystalline silica matrix, which subsequently transformed into quartz. This indicates that the adularia did not precipitate in open space along the vein walls. Correlative microscopy, involving scanning electron microscopy-based automated mineralogy and optical petrography, demonstrates that bands containing abundant adularia are not the primary host to ore minerals. The ore minerals occur in different bands within the crustiform veins, implying that adularia and ore mineral precipitation did not always occur simultaneously. It is hypothesized here that fluid flow at Midas involved intermittent short-lived events of fluid flashing, causing rapid solute supersaturation in the liquid. During each flashing event, different amounts of vapor were produced along a given vein. Compositional differences between adjacent bands in the crustiform quartz veins may, therefore, be linked to variations in the amount of vapor formed during each flash event.

Nevada

The GorDAS Distributed Acoustic Sensing experiment above the Cascadia locked zone and subducted Gorda Slab

The southernmost portion of the Cascadia Subduction zone in Northern California produces high rates of moderate and large earthquakes owing to subduction of the Gorda slab and deformation associated with the Mendocino Triple Junction. Distributed Acoustic Sensing (DAS) is rapidly advancing as a method for detecting earthquakes and imaging crustal structure. We have begun a long-term DAS monitoring experiment on buried telecom fiber in Arcata, California, with the goal of increasing the available recordings of moderate to large earthquakes as well as imaging seismogenic structures. We have recorded over a year's worth of data, including most aftershocks of the 2022 M w 6.4 Ferndale earthquake, though not the mainshock itself. The dataset includes numerous magnitude 3.5 and larger earthquakes including the 2023/01/01 M w 5.4 Rio Dell earthquake. Here we present initial results comparing an earthquake detection algorithm, run in real-time on the processing unit of the interrogator system, with both the ShakeAlert earthquake early warning system as well as a post-processed earthquake catalog developed with deep-learning phase-picker algorithms. The rapid onboard processing of the detector demonstrates the potential utility of DAS-based edge computing for earthquake early warning. We also verify the quality of the strain waveforms both in terms of peak amplitudes and waveform similarity using about five months of nodal seismometer data. These instruments were deployed roughly every 300 m along the ~15km long cable and validate large variations in peak strain over short distances that are seen in the DAS data. All data from time windows surrounding both the local and teleseismic earthquakes are publicly available, which will improve our understanding of both the performance of DAS systems in moderate earthquakes and earthquake hazards associated with the Gorda subduction zone.

California

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma — Nutrients, bacteria, organic carbon, and suspended sediment in surface water, 1993-95

Nutrient, bacteria, organic carbon, and suspended- sediment samples were collected from 1993-95 at 43 surface-water-quality sampling sites within the Ozark Plateaus National Water- Quality Assessment Program study unit. Most surface-water-quality sites have small or medium drainage basins, near-homogenous land uses (primarily agricultural or forest), and are located predominantly in the Springfield and Salem Plateaus. The water-quality data were analyzed using selected descriptive and statistical methods to determine factors affecting occurrence in streams in the study unit. Nitrogen and phosphorus fertilizer use increased in the Ozark Plateaus study unit for the period 1965-85, but the application rates are well below the national median. Fertilizer use differed substantially among the major river basins and physiographic areas in the study unit. Livestock and poultry waste is a major source of nutrient loading in parts of the study unit. The quantity of nitrogen and phosphorus from livestock and poultry wastes differed substantially among the river basins of the study unit's sampling network. Eighty six municipal sewage-treatment plants in the study unit have effluents of 0.5 million gallons per day or more (for the years 1985-91). Statistically significant differences existed in surface-water quality that can be attributed to land use, physiography, and drainage basin size. Dissolved nitrite plus nitrate, total phosphorus, fecal coliform bacteria, and dissolved organic carbon concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. A large difference in dissolved nitrite plus nitrate concentrations occurred between streams draining basins with agricultural land use in the Springfield and Salem Plateaus. Streams draining both small and medium agricultural basins in the Springfield Plateau had much larger concentrations than their counterparts in the Salem Plateau. Drainage basin size was not a significant factor in affecting total phosphorus, fecal coliform bacteria, or dissolved organic carbon concentrations. Suspended-sediment concentrations generally were small and indicative of the clear water in streams in the Ozark Plateaus. A comparison of the dissolved nitrite plus nitrate, total phosphorus, and fecal coliform data collected at the fixed and synoptic sites indicates that generally the data for streams draining basins of similar physiography, land-use setting, and drainage basin size group together. Many of the variations are most likely the result of differences in percent agricultural land use between the sites being compared or are discharge related. The relation of dissolved nitrite plus nitrate, total phosphorus, and fecal coliform concentration to percent agricultural land use has a strong positive 2 Water-Quality Assessment-Nutrients, Bacteria, Organic Carbon, and Suspended Sediment in Surface Water, 1993-95 correlation, with percent agricultural land use accounting for between 42 and 60 percent of the variation in the observed concentrations.

Arkansas, Kansas, Missouri, Oklahoma

Nodal seismic deployment on Mauna Loa volcano, Hawaii: Dataset and preliminary insights

Mauna Loa is the largest active volcano on Earth, comprising ∼51% of the Island of Hawai‘i’s landmass and posing significant risks to the island’s communities, infrastructure, and natural environment. Historical eruptions have produced lava flows that have reached the ocean in as little as 3 hr. The timing and location of such lava flows in the past 200 yr underscore how critical determination of the location and geometry of magma storage and structure is for volcanic hazard assessment and eruption forecasting. Now, after nearly 38 yr of volcanic quiescence, Mauna Loa has erupted again. On 27 November 2022, fissures initiated within the summit caldera and then migrated to the northeast rift zone, where they generated a large lava flow that threatened a major highway. To improve our understanding of the geometry of this magma system, we deployed a temporary nodal array on Mauna Loa in the summer of 2024. This increased our seismic coverage sufficiently to image this magmatic system. This nodal array consists of 33 seismometers distributed on and around the volcano and was deployed for over three months to record seismic signals. The primary objective of this project is to resolve the high‐resolution seismic velocity structure and characterize seismic features associated with magma storage and ascent pathways. In this article, we present an overview of the deployment, evaluate the quality of the data, and show example recordings to evaluate the suitability of the data set for future seismic investigations, including earthquake relocation, seismic tomography, and receiver function analysis. Comparisons with nearby permanent broadband and short‐period seismic stations demonstrate that the nodal array recorded high‐quality waveforms, making it a valuable resource for constraining the magmatic system beneath Mauna Loa at multiple scales.

Hawaii

Testing megathrust rupture models using tsunami deposits

The 26 January 1700 CE Cascadia subduction zone earthquake ruptured much of the plate boundary and generated a tsunami that deposited sand in coastal marshes from northern California to Vancouver Island. Although the depositional record of tsunami inundation is extensive in some of these marshes, few sites have been investigated in enough detail to map the inland extent of sand deposition and depict variability in tsunami deposit thickness and grain size. We collected 129 cores in marshes of the Salmon River estuary in Oregon and reanalyzed 114 core logs from a 1987–88 study that mapped the inland extent of circa 1700 CE sandy tsunami deposits. The ca. 1700 CE tsunami deposit in the Salmon River estuary is easily recognized in cores ≤1 m deep in which a buried marsh peat is overlain by a well sorted sand bed with a sharp lower contact that thins and fines inland. We use tsunami deposit data and models of sandy tsunami sediment transport (using Delft3D-FLOW) to test 15 rupture models that could represent a ca. 1700 CE earthquake. At least 12–16 m of slip offshore of the Salmon River, which results in 0.8–1.0 m of coastal coseismic subsidence, is required to match the ca. 1700 CE sand deposit's inland extent, which is consistent with models of heterogeneous megathrust slip in ca. 1700 CE. Our methods of detailed tsunami deposit mapping, combined with sediment transport modeling, can be used to test models of megathrust ruptures and their tsunamis to potentially improve earthquake and tsunami hazard assessments.

JGR Earth Surface

Base flow and ground water in upper Sweetwater Valley, Tennessee

The upper Sweetwater Valley area has a flow system with complex interaction between surface and ground water. A water budget study indicated that during dry years approximately three-fourths of the annual flow to Sweetwater Creek may be derived from ground-water sources. Hydrograph analysis showed seasonal variation of recharge to the ground-water flow system. Streamflow records were analyzed to estimate the frequency of low flow of Sweetwater Creek at river mile 16.7, and indicated the lowest average flow for 1 day in 20 years to be about 5.1 cubic feet per second. Two periods of base-flow measurements of Sweetwater Creek identified channel reaches with significant gains and losses of streamflow. Base flow measurements also showed interbasin transfer of water among sub-basins of the valley. Major flow surpluses were associated with areas in which the majority of flow originated at a spring. Topographically low areas adjacent to the main stem of Sweetwater Creek generally have surplus flow. Topographically higher areas generally have deficient surface outflow unless significant spring flow occurs in the basin. Ground-water recharge occurs by water draining into sinkholes, faults, and fractures. Ground-water flow is regionally diffused across formation strikes from the topographically low areas unless the water is exposed to highly permeable formations or impervious formations. Ground water infiltrates the highly permeable formations and flows along strike. Ground water encountering impervious formations may discharge at small springs at the contact, or may reroute along the contact if the upgradient rock is sufficiently permeable or has well developed secondary porosity. Groundwater discharges to streams at innumerable seeps and at a few large springs. Areas of ground-water flow up-gradient of large springs are hypothesized as likely areas of significant ground-water reservoirs.

Tennessee

Earthquake probabilities and hazards in the U.S. Pacific Northwest

Earthquakes and their cascading consequences pose a significant threat to the people, environment, infrastructure, and economy of the U.S. Pacific Northwest. The Pacific Northwest is susceptible to three types of earthquakes: deep (intraslab) earthquakes, subduction zone (megathrust) earthquakes, and shallow crustal earthquakes. For each of these earthquake types, earth scientists can use a variety of methods to estimate the probability of occurrence for future events, which constrains seismic hazard and informs building codes. The timing of past earthquakes indicates that there is an 85-percent chance of a magnitude 6.5 or greater deep earthquake in the Puget Sound region; a 10-15-percent chance of an approximately magnitude 9 earthquake on the Cascadia Subduction Zone; and a 17-percent chance of a magnitude 6.5 or greater crustal fault earthquake in the Puget Sound region in the next 50 years. Individuals and communities can take simple steps to prepare for and reduce the impact of future earthquakes.

California, Oregon, Washington

Dynamic baseflow storage estimates and the role of topography, geology and evapotranspiration on streamflow recession characteristics in the Neversink Reservoir Watershed, New York

Estimates of dynamic groundwater volumes supplying baseflow to streams are important for water availability projections during extended periods of drought. The primary goals of this study were to provide dynamic storage volume estimates, inferred from streamflow recession analysis, for baseflow regimes within seven gaged catchments within the Neversink Reservoir Watershed (NRW), a critical municipal water source for New York City. Additionally, geomorphological properties, surficial geology and hydro-meteorological processes were quantified and described in relation to time and spatially variable recession behaviour and storage estimates across the NRW. To explore these relationships, we (1) evaluated seasonal trends in streamflow recession behaviour in relation to modelled potential evapotranspiration (PET) and catchment runoff rates, (2) derived empirical streamflow models for cool-season runoff using both linear and nonlinear reservoir assumptions for baseflow and (3) calculated metrics related to the geology and geomorphology of each catchment and compared these metrics to area normalised baseflow dynamic storage estimates. Results show that baseflow recession behaves as a nonlinear reservoir, and applying linear groundwater reservoir assumptions may underestimate the total dynamic storage volumes compared to what would be predicted for a nonlinear reservoir. Increases in PET caused decreases in storage conditions that resulted in increased recession rates and nonlinearity in streamflow recession during the growing season. Additionally, we found that while no single physical catchment characteristic solely predicted catchment storage dynamics, sediment volume and stream gradients were stronger predictors of normalised storage volumes than catchment surface area or surface topography alone. Within the NRW, catchments with the highest sediment volume exhibited the lowest recession rates and higher dynamic storage volumes, while the smallest catchment, mostly devoid of sediment, had the fastest recession rate and lowest dynamic storage volume.

New York

Seasonal and hydrologic variation influences habitat and functional structure of stream fish assemblages

Introduction: Hydrologic variability is a key driver of ecological structure in lotic systems, shaping habitat conditions, taxonomic diversity, and the functional traits that mediate species’ persistence and performance (e.g., reproductive success). While many studies examine taxonomic responses to variation in flows, few evaluate how spatiotemporal hydrologic variation influences the functional organization within stream fish communities. Methods: We quantified seasonal habitat structure and functional trait diversity of fish assemblages across six Ozark Plateau headwater streams representing two contrasting flow regimes: Groundwater Flashy and Runoff/Intermittent Flashy. Fish and habitat data were collected seasonally during a dry year (2002) and a wet year (2003). Functional space was constructed using PCoA of morphological, ecological, and life-history traits, and functional diversity was measured using community weighted means (CWMs), functional richness (FRic), functional evenness (FEve), and functional divergence (FDiv). Results: We found that habitat structure differed strongly by flow regime and season, with Runoff/Intermittent streams exhibiting pronounced reductions in depth, area, and velocity, while groundwater streams remained structurally stable. Functional identity of assemblages was similar across flow regimes, dominated by benthic, hydrodynamic taxa with opportunistic and periodic life-history strategies. However, functional structure differed significantly: FEve and FDiv were consistently lower in Runoff/Intermittent Flashy streams in both years, indicating assemblage dominance of species with similar trait combinations and reduced trait partitioning under variable flow. FRic and taxonomic richness remained stable across seasons and flow regimes, suggesting high functional redundancy despite species turnover. Discussion: Together, results show that flow regime mediates both habitat structural stability and functional organization. As climatic warming and extreme drought increase hydrologic instability in headwaters, functional trait approaches provide a sensitive tool for detecting losses of functional roles that may not be evident by using taxonomic metrics alone.

Arkansas, Kansas, Missouri, Oklahoma

Predictions of anthropogenic background PFAS concentrations in soil and relation to bedrock lithology and groundwater quality

Detectable concentrations of per- and polyfluoroalkyl substances (PFAS) have been observed in soils in remote areas and presumably originate from atmospheric deposition. These anthropogenic background concentrations may enable some PFAS to leach to groundwater at levels that exceed regulatory criteria for drinking water. However, anthropogenic background soil concentrations and their connection to groundwater are not well characterized. We developed a boosted regression tree model to predict perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA) concentrations in shallow soils across northern New England. Low soil pH was the most important predictor of elevated anthropogenic PFOS and PFOA concentrations in background soils, rather than potential PFAS sources, land use, or population density. Total organic carbon (TOC) was also an important predictor for PFOS soil concentrations. Model predictions indicate that 73% of the shallow soils within Maine, Vermont, and New Hampshire exceed New Hampshire’s Soil Remediation Standard for PFOS (0.5 ng/g) and 41% exceed the PFOA standard (0.4 ng/g). Analysis of soil model results and groundwater data suggests that areas with high soil pH are associated with higher groundwater detection frequencies, illustrating how areas with less retention in soil are, conversely, also areas with potentially greater groundwater vulnerability. Further analysis indicates that groundwater may be more vulnerable in calcareous lithologies.

Maine, New Hampshire, Vermont

Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA

Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.

California

Mountain goat declines in a protected, interior, native population

A shifting climate poses threats to alpine-adapted species including mountain goats. We used long-term (12 years) citizen science monitoring data and Bayesian N-mixture modeling to estimate population trends and drivers of population metrics among mountain goats in Glacier National Park (GNP). Median goats per site ( n = 37 sites) declined by 45% (95% credible interval [CRI] = 32%, 57%) from 77.8 (95% CRI = 64.4, 95.1) in 2008 to 42.3 (95% CRI = 34.3, 52.2) in 2019, with consistent declines from 2008 until 2015, when the number of estimated goats stabilized. The decline exceeds IUCN criteria for classifying a population as vulnerable, >30% declines over only two generations. Across years, relatively few goats occupied northwestern GNP. Goat numbers declined the most at northeastern sites, trended toward decline in most southern sites, and increased at only two west-central sites. The proportion of permanent snow and glaciers, the presence of natural mineral licks, and habituation strongly increased the initial abundance of goats in the area. Weather variables had the greatest influence on population growth rates, particularly precipitation between May 15 and June 15 of the previous summer, the neonatal period. Lower growth occurred with less snow water equivalent and lower mean winter temperature, early summer temperature, and early summer precipitation. Projected reductions of permanent snow, increasing spring and summer temperatures, and insufficient and variable spring precipitation raise concerns for the future of native goats in this region. Our analyses reveal ways to improve detection rates of goats during surveys, which is important for optimizing the precision of estimates and the power to detect future trends. Detection increased with goat habituation, retention of observers with experience, use of binoculars, and conducting surveys at lower temperatures and earlier dates. Improving detection will be particularly important given the lower number of goats currently observed in the park. Research to estimate park-wide population size, evaluate genetic structure and diversity, assess changing habitat, human recreation levels and forage, and forward-project climate effects on persistence will be crucial to understanding the context of these results and conserving this iconic, metapopulation at the southern edge of the distribution of native mountain goats.

Montana

Identifying overlap between native fish movements and a possible seasonal Grass Carp deterrent in the Sandusky River, Ohio, USA

Riverine fishes are vulnerable to habitat fragmentation caused by interrupted access to vital habitats. Fragmentation using artificial structures can be used to limit the spread of invasive fishes by inhibiting movement between critical habitats. Thus, tradeoffs exist between maintaining connectivity for native species and restricting movement of invasive fishes. A nonphysical deterrent has been proposed to prevent invasive Grass Carp ( Ctenopharyngodon idella ) from reaching spawning habitats in the Sandusky River, a tributary to Lake Erie, during late spring–summer. However, this timing overlaps with spawning periods of a suite of native fishes. We used acoustic telemetry and ichthyoplankton surveys to examine movement and spawning activity of multiple native species and to assess potential impacts of deterrent operation on reproduction. All species used the proposed deterrent location during the Grass Carp spawning period, and their movements corresponded with larval fish collections, indicating upstream spawning. These findings suggest the deterrent could unintentionally restrict native species’ access to essential habitats. Balancing habitat connectivity and invasive species control will likely depend on species-specific responses and careful timing of deterrent operation.

Ohio

Effects of groundwater withdrawals for water bottling and municipal use, Wards Brook Valley, Maine and New Hampshire

Hydrologic models for the Wards Brook valley near Fryeburg, Maine were developed for historical (2016 – 2021) and hypothetical future conditions (2046 – 2065 and 2080 – 2099) to understand the effects of groundwater withdrawals for bottled water and municipal use on hydrologic conditions (stream base flows and groundwater levels). Analyses showed that the simulated base flows in Wards Brook were reduced because of pumping for both municipal water supplies and for water bottling, and about half of the total pumping impact on the base flows in Wards Brook was from the bottled water extraction. Simulated flows were greater than the minimum recommended streamflow of 2,180 cubic meters per day (400 gallons per minute) throughout the historical period. Simulated groundwater levels at two of three nearby ponds (Round Pond and Davis Pond) were minimally affected by pumping conditions, and effects were primarily from the municipal well closest to the ponds. Several estimates of future projected recharge were used to understand the potential effects of groundwater withdrawals on hydrologic conditions under multiple hypothetical climate conditions. Annual projected recharge rates in the mid- and late-21st century from two climate scenarios (stabilized greenhouse-gas emissions and high greenhouse-gas emissions) were similar to rates for 2016 – 2021. However, monthly recharge patterns for the future periods shifted toward more recharge in the winter months (December, January, and February) and less recharge in April, May, and October relative to 2016 – 2021. The lowest mean monthly base flows from the future emission scenarios all remain larger than the minimum recommended streamflow and indicate no long-term declines in flow relative to historical conditions. However, simulated base flows during hypothetical 3-year drought scenarios declined below minimum recommended streamflow during the summer months in the stabilized- and high-emission scenarios in the mid-21st century. Although water is generally plentiful in the Wards Brook valley, reduced pumping may be needed to maintain streamflows in Wards Brook under future climate conditions similar to modeled drought scenarios.

EarthArXiv